Abstract: A catalyst comprising a physical mixture of particles of a catalytic material and particles of char is provided. The catalyst can be used in various processes, including the reforming of tars present in syngas generated during biomass gasification. The catalyst is produced through a mechanical mixing of the catalytic material and char particles, which results in significant time and energy savings over methods of catalyst preparation that involve impregnation and calcining of a support material.

Abstract: A chemical reactor, comprising: a) an ionic liquid, supported on a porous solid; and b) a Brønsted acid; wherein the ionic liquid serves as an adsorbent and promoter for the Brønsted acid, and the Brønsted acid is a catalyst for alkylation, oligomerization, or a combination thereof of a hydrocarbon mixture comprising at least one alkylatable hydrocarbon and at least one alkylating agent in the chemical reactor. Also, a chemical reactor, comprising: a) a gaseous HCl, which is a catalyst for oligomerization of olefins; b) a chloroaluminate ionic liquid, supported on a porous solid, wherein the chloroaluminate ionic liquid serves as an adsorbent and promoter for the catalyst; and c) a volatile hydrocarbon, which evaporates to control a heat of reaction in the chemical reactor.

Abstract: An apparatus and method for contacting a fluid stream with particulate solids are provided. The apparatus comprises a vessel having an upper portion and a lower portion and an inlet for receiving particulate solids and an outlet for discharging the particulate solids. An inner cone is coaxially positioned within an inverted truncated outer cone forming an annulus in the lower portion of the vessel. A truncated conical baffle is disposed within the lower portion of the vessel and at least partially above the inverted truncated outer cone and the inner cone. The truncated conical baffle has a downwardly and inwardly sloping wall with a lower portion thereof overlapping interiorly an upper portion of the inverted truncated outer cone. A plurality of guide tents are spaced apart in the annulus, each guide tent having sloped guide surfaces oriented to guide the flow of particulate solids into the outlet.

Abstract: Integrated Combustion Reactors (ICRs) and methods of making ICRs are described in which combustion chambers (or channels) are in direct thermal contact to reaction chambers for an endothermic reaction. Particular reactor designs are also described. Processes of conducting reactions in integrated combustion reactors are described and results presented. Some of these processes are characterized by unexpected and superior results, and/or results that can not be achieved with any prior art devices.

Abstract: Multiple catalytic processing stations couple with a system which produces volatile gas streams from biomass decomposition at discrete increasing temperatures. These catalytic processing stations can be programmed to maximize conversion of biomass to useful renewable fuel components based on input feedstock and desired outputs.

Abstract: The invention is a hydrogen generator including a housing, a reaction area, a fluid reservoir, a pellet comprising a first reactant within the reaction area, a fluid comprising a second reactant within the fluid reservoir, a fluid flow path between the fluid reservoir and the reaction area, and a hydrogen outlet. The fluid flow path comprises a follower assembly biased toward the pellet, the follower assembly includes an articulated joint and a follower, and the second reactant can react with the first reactant in the reaction area to produce hydrogen gas and byproducts.

Abstract: Disclosed is a reactor, a retained catalyst structure, and a method for increasing the rate of decomposition of polysulfides and removal of hydrogen sulfide in liquid sulfur. The reactor, the retained catalyst structure, and the method include a retained catalyst structure arranged and disposed for contacting a first stream and a second stream in a reactor including a catalyst. The catalyst increases the rate of decomposition of polysulfides and facilitates the removal of hydrogen sulfide in the liquid sulfur of the first stream with the second stream. The first stream includes liquid sulfur containing polysulfides and dissolved hydrogen sulfide. The second stream includes an inert gas or a low oxygen-containing gas.

Abstract: Systems and methods for treating a fluid with a body are disclosed. Various aspects involve treating a fluid with a porous body. In select embodiments, a body comprises ash particles, and the ash particles used to form the body may be selected based on their providing one or more desired properties for a given treatment. Various bodies provide for the reaction and/or removal of a substance in a fluid, often using a porous body comprised of ash particles. Computer-operable methods for matching a source material to an application are disclosed. Certain aspects feature a porous body comprised of ash particles, the ash particles have a particle size distribution and interparticle connectivity that creates a plurality of pores having a pore size distribution and pore connectivity, and the pore size distribution and pore connectivity are such that a first fluid may substantially penetrate the pores.

Abstract: A reactor vessel for subjecting a first gas and a second gas to a chemical reaction to produce a third gas is provided. The reactor vessel includes a catalyst bed, an inlet for receiving the first gas and the second gas, and a first outlet for discharging the third gas. The first outlet includes a selective microporous conduit to separate the third gas from products of incomplete reaction or unreacted first gas and unreacted second gas. A second outlet for discharging one or more of the following: unseparated third gas is also included in this invention. The products of incomplete reaction, unreacted first gas, or unreacted second gas are removed from the system. At least one helical tube is disposed within the reactor vessel and in direct contact with the catalyst bed. The helical tube has an inlet end communicating with a hot gas source, and an outlet end exhausting cooled gas. Indirect heat exchange between the helical tube and the first and second gas, promoted by the catalyst, generates the third gas.

Abstract: In operating the carbon monoxide removal reactor or the fuel reforming system, there is provided a technique for removing carbon monoxide in a stable manner for an extended period of time. In a method of removing carbon monoxide including an introducing step of introducing a reactant gas including mixture gas and an oxidizer added thereto to a carbon monoxide removal reactor forming in its casing a catalyst layer comprising a carbon monoxide removal catalyst for removing carbon monoxide contained in the mixture gas and a removing step of removing the carbon monoxide by causing the oxidizer to react with the mixture gas on the carbon monoxide removal catalyst, in said introducing step, the reactant gas of 100° C. or lower is introduced to the carbon monoxide removal reactor.

Abstract: A catalyst with large surface area structure, in particular for steam-reforming catalysts, which is characterized in that the large surface area structure is formed of a large number of round or parallel penetrating holes of polygonal cross-section, wherein the catalyst carrier is prepared in the injection molding process, coated with a washcoat and then impregnated with the active component. The catalyst carrier includes at least one sinterable material and has a lateral pressure resistance of at least 700 N. Also, a process for the preparation of such catalysts and the use thereof in a reactor.

Abstract: Methods and systems for preparing catalyst, such as chromium catalysts, are provided. The valence of at least a portion of the catalyst sent to an activator is changed from Cr(III) to Cr(VI). The catalyst is prepared or activated continuously using a fluidization bed catalyst activator.

Abstract: Methods and systems for hydrogen generation from solid hydrogen storage compositions which generate hydrogen in an exothermic reaction wherein the heat released can be absorbed by solid endothermic compositions are disclosed. The solid hydrogen storage compositions comprise mixtures of chemical hydrides and water surrogate compounds. Fuel cartridges suitable for use with compositions which generate hydrogen upon the application of thermal initiation and methods for operating the fuel cartridges are also disclosed.

Abstract: A method for manufacturing green-energy water, including: conducting water flow through a self-support visible-light photocatalytic reaction device, which decomposes the water into hydrogen ions and hydroxide ions; conducting the hydrogen ions and the hydroxide ions through an ion separation device, which separates the hydrogen ions and the hydroxide ions from each other; and conducting the separated hydroxide ions into an amount of water to form an amount of alkaline green-energy water and conducting the separated hydrogen ions into another amount of water to form an amount of acidulous green-energy water. The green-energy water manufactured in this way is environmentally friendly and can be used in cleaning purposes of photoelectric and semiconductor industries, processing of waste water, organic cultivation, organic agriculture, purification of water, sterilization of medical facility.

Abstract: Ammonia oxidizers are disclosed that can include gas distributors and distribution rings to improve the distribution of the flow of a gas feedstream across a catalyst bed in the ammonia oxidizer. The gas distributors include circular plates that have holes through which the gas feedstream is distributed across the catalyst bed. In some examples, the gas distributors also have a sidewall. The distribution rings are attached to the inner wall of the ammonia oxidizer at a predetermined distance below the gas distributor.

Abstract: The present invention relates to a process for an epimerization of a saccharide in a microdevice consisting of a network of micron-sized channels in presence of molybdenum containing catalyst. It further relates to the use of a microdevice consisting of a network of micron-sized channels for the epimerization reaction of saccharides and the oligomerisation of the thus obtained epimerized saccharide, preferably into manno-oligosaccharides.

Abstract: A gas-generating apparatus (10) includes a reaction chamber (18) containing a solid fuel component (24) and a liquid fuel component (22) that is introduced into the reaction chamber by a fluid path, such as a tube, nozzle, or valve. The flow of the liquid fuel to the solid fuel is self-regulated. Other embodiments of the gas-generating apparatus are also disclosed.

Abstract: A method is disclosed for making styrene and/or ethylbenzene by reacting toluene with a C1 source in the presence of a catalyst in a reactor sized and configured to provide for a moving catalyst bed therethrough to form a product stream including styrene and/or ethylbenzene.

Abstract: A method of hydroprocessing hydrocarbons is provided using a substantially liquid-phase reactor having first and second catalyst beds with a heat transfer section positioned therebetween. The first and second catalyst beds and the heat transfer section are combined within the same reactor vessel. Each catalyst bed having an inlet temperature and an exit temperature and having a hydroprocessing catalyst therein with a maximum operating temperature range.

Abstract: The water gas shift reactor includes a gas reaction tank including a reaction chamber formed in the shape of a hollow body provided with a porous plate installed therein to divide the inside of the reaction chamber into an upper reaction space and a lower collection space and a catalyst stacked on the upper surface of the porous plate to convert carbon monoxide into hydrogen, and an insulating layer provided at the outer surface of the reaction chamber, a syngas storage tank to store the syngas, a syngas supply pipe to supply the syngas to the gas reaction tank, after the syngas is heated by a preheater, a steam supply pipe to supply steam generated from a steam generator to the gas reaction tank such that the steam reacts with the syngas, after the steam is heated by a preheater, and a reaction gas discharge pipe.

Abstract: The present invention concerns an isothermal reactor (1) comprising a pressure vessel (2) closed at the opposite ends by respective bottoms (3, 4), a reaction zone (9) in said pressure vessel (2) in which at least one catalytic basket (10) is positioned, and at least one heat exchange unit (13) embedded in said at least one catalytic basket (10), each heat exchange unit (13) comprising a plurality of heat exchangers (14) each having an inner chamber intended to be crossed by an operating heat exchange fluid, the reactor being characterized in that it comprises means (17, 18) for picking up samples of operating heat exchange fluid from groups (16) of pre-established exchangers in each heat exchange unit (13), so as to ascertain the possible existence of damaged exchangers (14) in said groups (16) of exchangers through analysis of respective samples of operating heat exchange fluid.

Abstract: With the help of a fixing device for catalyzer particles, wherein the catalyzer particles are packed in a bed which can be passed through by a gas flow in the direction of gravity, it is intended to achieve a minimum specific pressure loss which will remain low even if dirt should arise from the operating process; a fixing device which has a minimum influence on the period of presence of the gas flowing through; which ensures the reliable hold-down of the catalyzer particles even at high approach velocities; and which is flexible to a certain degree in order to adapt to bed changes. This is achieved by placing at least one layer of a metal braiding on the packed bed of the catalyzer particles, and the metal braiding consisting of individual metal braiding elements which are firmly braided together.

Abstract: The present invention is directed to systems and methods of synthesizing trichlorosilane. The disclosed systems and methods can involve increasing the concentration of the solids in the slurry to recover or separate the volatilized metal salts and reduce the obstructions created by the solidification of the metal salts in downstream operations of the during trichlorosilane synthesis. Rather than heating to raise the temperature to vaporize chlorosilane compounds, and subsequently condensing the volatilized chlorosilane compounds, the present invention can involve increasing the solids concentration in the slurry stream by utilizing a non-condensable gas, such as hydrogen, to volatilize the chlorosilane components, which can consequently promote evaporative conditions that can reduce the slurry temperature. The lower slurry temperature results in a lower volatility of the metal salts, which reduces the likelihood of carryover to downstream unit operations.

Abstract: The invention relates mainly to a process for the in situ generation of a catalyst (Pd(0)) and the deposition of said catalyst on the internal wall(s) of a glass, glass-ceramic or ceramic reactor. The invention further relates to a reactor, preferably a microfluidic device, as may be obtained by the in situ generation and deposition of palladium Pd(0) on its internal wall(s) carried out according to said process. The invention also globally concerns catalytic processes including said process.

Abstract: A vessel comprising a bed of randomly oriented ceramic media having fluid distribution channels incorporated in the outer surface of the media is disclosed. The channels capture and redirect the fluid thereby improving distribution of the fluid in the vessel.

Abstract: A reactor design and process for the dehydrogenation of hydrocarbons is presented. The reactor design includes a multibed catalytic reactor, where each of the reactor beds are fluidized. The catalyst in the reactor cascades through the reactor beds, with fresh catalyst input into the first reactor bed, and the spent catalyst withdrawn from the last reactor bed. The hydrocarbon feedstream is input to the reactor beds in a parallel formation, thereby decreasing the thermal residence time of the hydrocarbons when compared with a single bed fluidized reactor, or a series reactor scheme.

Abstract: The invention relates to a catalytic reactor including at least two catalytic cellular architectures and at least one structural element, inserted between the two catalytic cellular architectures, in which the entire outer perimeter is in contact with the inner wall of the reactor, the cellular architecture and the structural element being arranged coaxially.

Abstract: A method of fabricating visible light absorbed TiO2/CNT photocatalysts and photocatalytic filters is disclosed, in which the method of fabricating the photocatalysts comprises steps: (a) providing a substrate; (b) forming a plurality of carbon nanotubes on the substrate; (c) providing a titanium source and an oxygen source; and (d) forming at least one titanium dioxide layer on the carbon nanotubes. The filter of the present invention comprises: a substrate, a plurality of carbon nanotubes, and a titanium dioxide layer. The plurality of carbon nanotubes form on the surface of the substrate, one end of each carbon nanotube connects to the substrate, and the titanium dioxide layer covers the surface of the carbon nanotubes. The filter of the present invention is a visible light absorbed filtering net, the titanium dioxide layer formed on the CNTs has high uniformity and therefore the photodegradation efficiency of the filter is an improvement.

Abstract: Systems and methods for fabricating bodies (e.g., porous bodies) are described. Various aspects provide for reactors and the fabrication of reactors. Some reactors include surfaces that provide for heterogeneous reactions involving a fluid (and/or components thereof). A fluid may be a gas and/or a liquid. A contaminant in the fluid (e.g., a dissolved or suspended substance) may react in a reaction. Some reactors provide for independent control of heat transfer (between the fluid, the reactor, and the environment) with respect to mass transfer (e.g., fluid flow through the reactor).

Abstract: The present invention relates to a fluidized bed reactor system made up of at least two fluidized bed reactors, comprising at least one main reactor (1) in the form of a circulating fluidized bed and a secondary reactor (2) in the form of a circulating fluidized bed, and also a particle line comprising a particle separator for transporting fluidized bed particles from the main reactor into the secondary reactor, characterized in that, in the lower region of the respective reactor, a line (10) connects the secondary reactor (2) to the main reactor (1) for transporting fluidized bed particles.

Abstract: One exemplary embodiment can be a process for contacting one or more fluids in a vessel. The process may include passing one or more fluids into a chamber from an overhead tray and providing a conduit outside the chamber coupling a respective spillway to a respective hole for increasing contact time inside the conduit. Typically, the chamber forms one or more sidewalls forming at least one hole and the overhead tray forms at least one spillway.

Abstract: The invention relates to a catalytic reactor including: at least one first architecture/microstructure including a ceramic and/or metal cellular architecture having a pore size of 2 to 80 ppi and a macroporosity of more than 85%, and a microstructure having a grain size of 100 nm to 5 microns, and skeleton densification of more than 95%, and a catalytic layer; and at least one second architecture/microstructure including a spherical or cylindrical architecture having a pore size of 0.1 to 100 ?m and a macroporosity of less than 60%, and a microstructure having a grain size of 20 nm to 10 ?m and a skeleton densification of 20% to 90%, and a catalytic layer; the first and second architecture/microstructure being stacked inside said reactor.

Abstract: Embodiments of a hydrocarbon conversion apparatus are provided, as are embodiments of a hydroprocessing conversion process. In one embodiment, the hydrocarbon conversion apparatus includes a reaction vessel having a reaction chamber and a feed distribution chamber. A riser fluidly couples the feed distribution chamber to the reaction chamber, and a catalyst recirculation standpipe fluidly couples the reaction chamber to the feed distribution chamber. The catalyst recirculation standpipe forms a catalyst recirculation circuit with the reaction chamber, the feed distribution chamber, and the riser. A catalyst is circulated through the catalyst recirculation circuit during operation of the hydrocarbon conversion apparatus.

Abstract: A system (100) of the present invention for producing an iodine compound includes: a raw material adjusting unit (1) for supplying hydrogen-containing gas to at least one of liquid iodine in an iodine melting pot (4) and gaseous iodine obtained by evaporating liquid iodine so as to obtain a mixture gas; a hydrogen iodide producing unit (10) including a hydrogen iodide producing tower (12) having a catalyst layer (12a) for converting the introduced mixture gas into crude hydrogen iodide gas; a hydrogen iodide refining unit for removing unreacted iodine from the introduced crude hydrogen iodide gas so as to obtain hydrogen iodide gas; and an iodine compound producing unit (30) for producing a target iodine compound from the obtained hydrogen iodide gas and a reaction material. This allows producing an iodine compound with high purity easily, efficiently, and with low cost.

Abstract: A processing apparatus that is formed from a plurality of metal layers that are stacked and aligned together and then connected together to form one or more portions of the processing apparatus.

Abstract: A reactor is provided comprising a reactor substrate and upper and lower manifold structures. The upper manifold structure and the lower manifold structure each comprise at least one flow directing cavity that reverses a flow direction of a fluid flowing through the relatively short open-ended channels of the substrate between the upper and lower manifold structures. The flow directing cavities of the upper and lower manifold structures are configured to direct fluid from the inlet region of the upper manifold structure to the outlet region of the lower manifold structure in an additional serpentine path defined by the flow direction reversals introduced by the upper and lower manifold structures. Additional embodiments are disclosed and claimed.

Abstract: The present invention provides a structure in which the surface of a solid substrate of any shape is covered with metal oxide, in particular, a nanostructure composite in which polyethyleneimine, which is an organic substance, and metal oxide, which is an inorganic substance, are combined in nano-meter scale, spreads at the entire surface of a substrate, and the nanostructure composite forms a nano-boundary of complex shapes so as to thoroughly cover the entire surface of the substrate; a structure in which metal ions, metal nano-particles, organic pigment molecules are contained in the nanostructure composite; a process for producing these structures which can produce these structures with ease and efficiently; and an application method for the structures as an immobilized catalyst type reactor.

Abstract: Hydrogen-producing fuel processing systems, hydrogen purification membranes, hydrogen purification devices, fuel processing and fuel cell systems that include hydrogen purification devices, and methods for operating the same. In some embodiments, operation of the fuel processing system is initiated by heating at least the reforming region of the fuel processing system to at least a selected hydrogen-producing operating temperature. In some embodiments, an electric heater is utilized to perform this initial heating. In some embodiments, use of the electric heater is discontinued after startup, and a burner or other combustion-based heating assembly combusts a fuel to heat at least the hydrogen producing region, such as due to the reforming region utilizing an endothermic catalytic reaction to produce hydrogen gas.

Abstract: One exemplary embodiment can be an alkylation unit. The alkylation unit can include at least one alkylation reaction zone having an alkylation catalyst, at least one cooler communicating with the at least one alkylation reaction zone, a settler communicating with the at least one alkylation reaction zone and the at least one cooler, a fractionation zone receiving an effluent from the settler passing through a line, and a boot coupled to a substantially horizontal portion of the line. Generally, the boot receives an effluent portion rich in the alkylation catalyst.

Abstract: Methods and systems for the preparation of chlorohydrins are described herein. The method includes introducing a liquid stream into a high shear device, wherein the liquid stream has an aqueous phase; introducing a gas stream into the high shear device, wherein the gas stream has an olefin gas; forming a dispersion in the high shear device, the dispersion comprising gas bubbles dispersed in the liquid stream; and reacting at least a portion of the dispersion to produce chlorohydrin.

Abstract: A decomposition apparatus and a decomposition system for high-efficiency decomposition of waste plastic and organic matter, in particular medical waste formed of varieties of plastic, are provided by introduction of a catalyst circulating means using a rotary wheel and/or introduction of a mixing vessel.

Abstract: A process for cracking a hydrocarbon feed in a reactor assembly comprising: a reactor vessel; a solid catalyst inlet by which catalyst is introduced and a solid catalyst outlet by which catalyst is removed from the reactor vessel; a plurality of feed nozzles by which feed is introduced at the bottom of the vessel; a product outlet for removing a product mixture of gas and solid catalyst at the upper part of the reactor; at least one partition plate, that divides the interior of the reactor vessel into two or more compartments, wherein the partition plate intersects the solid catalyst inlet.

Abstract: Herein disclosed is an apparatus having a first porous rotor positioned about an axis of rotation, wherein the first porous rotor comprises a first catalyst; an outer casing, wherein the outer casing and the first porous rotor are separated by an annular space; and a motor configured for rotating the first porous rotor about the axis of rotation.

Abstract: A structured packing for a reactor is formed from a metal sheet to promote heat and mass transfer near the wall of the reactor. The structured packing causes lateral flow of fluids flowing through the packing such that jet impingement of at least one reactor wall is promoted. The packing may be used in a cylindrical, annular or plate-type reactor, e.g., a catalytic reactor, or a heat exchanger.

Abstract: Material withdrawal apparatus, methods, and systems of regulating material inventory in one or more units are provided. A material withdrawal apparatus includes a heat exchanger and transport medium junction configured to provide transport medium to transport the withdrawn material from the unit to the heat exchanger. Another material withdrawal apparatus includes a heat exchanger and shock coolant junction configured to provide shock coolant to the material withdrawn from the unit. Another material withdrawal apparatus includes a heat exchanger, shock coolant junction, and transport medium junction. Another embodiment of a material withdrawal apparatus includes a vessel and shock coolant junction. Another material withdrawal apparatus includes a vessel and transport medium junction. The vessel includes a wall, liner with heat insulating refractory material, fill port, and a discharge port.

Abstract: Surface-active solid-phase catalyst activity may be substantially improved by creating deliberate repetitive surface-to-surface contact between portions of the active surfaces of catalyst objects. While they are immersed in reactant material such contact between portions of the active surfaces of catalyst objects can substantially activate the surfaces of many heterogeneous catalysts. Examples are given of such action employing a multitude of predetermined shapes, supported catalyst structures, etc. agitated or otherwise brought into contact to produce numerous surface collisions. One embodiment employs a gear pump mechanism with catalytically active-surfaced gear teeth to create the repetitive transient contacting action during pumping of a flow of reactant. The invention is applicable to many other forms for creating transient catalytic surface contacting action. Optionally catalytic output of such systems may be significantly further improved by employing radiant energy or vibration.

Abstract: A hydrogen generator working by hydrolysis of the metal borohydride is described comprising a reaction chamber (7) which in its bottom part has a liquid collecting area (30) and leads by short and non-complex connecting components to a conduit end (38) through which the exhaust products (31) of the reaction are discharged into the environment, generally the atmosphere and thereby saving weight and volume. By using given high pressures and temperatures for the reaction, the danger of crystallization of exhaust products is prevented.

Abstract: Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures.

Abstract: Catalyst-coated support, method for producing the same, reactor comprising the same and use thereof. Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.

Abstract: An apparatus for producing trichlorosilane includes a reaction container in which a supply gas containing silicon tetrachloride and hydrogen is supplied therein and a reaction product gas containing trichlorosilane and hydrogen chloride is produced; a heat transfer body which is filled in the reaction container, which is formed of a material having a melting point of at least higher than 1,400° C., and which has a void part which enables a gas to be passed; and a heating mechanism heating the heat transfer body in the reaction container.