Utilizing Aqueous Reactant To Remove Or Modify Sulfur Or Sulfur Containing Component Patents (Class 423/243.01)
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Patent number: 7772449Abstract: The present invention provides a process for treating a hydrocarbon feed gas stream containing acid gases (CO2, H2S and mercaptans) by contacting the feed gas stream in a multi-section caustic tower, the bottom sections employing a recirculating caustic solution to remove the CO2 and H2S down to low single digits parts per million concentration and the upper sections employing a stronger caustic solution on a once-through basis to produce a mercaptans depleted gas stream.Type: GrantFiled: August 1, 2007Date of Patent: August 10, 2010Assignee: Stone & Webster Process Technology, Inc.Inventors: Sabah A. Kurukchi, Joseph M. Gondolfe, Ming Wang
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Patent number: 7758830Abstract: The invention relates to a mercury removing apparatus and a mercury removing method in which a mercury removing ratio is improved with low cost, the mercury removing apparatus removes mercury from exhaust gas generated by coal combustion, an acidic solution spraying nozzle for spraying sulfuric acid into exhaust gas is provided on the down stream side of an absorption tower for removing sulfur oxide from the exhaust gas.Type: GrantFiled: December 22, 2008Date of Patent: July 20, 2010Assignee: IHI CorporationInventors: Toshiyuki Naito, Hiroyuki Kamata, Shunichiro Ueno
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Patent number: 7731926Abstract: Flue gas of boiler is introduced through gas inlet part of flue-gas desulfurization apparatus, and absorbent liquid sprayed from spray nozzle is trapped in recirculation tank. There, agitation is performed by oxidation agitator to thereby oxidize SO2 absorbed from the flue gas into gypsum. In the tank, oxidation air is fed from posterior air pipe and anterior air pipe behind and ahead of liquid propulsion by the propeller. Thus, even when the amount of oxidation air must be increased in accordance with an increase of boiler load, the oxidation efficiency can be enhanced without increasing the number of agitators. Then the apparatus with which even when the amount of oxidation air fed to the liquid trapping section is increased, highly efficient oxidation can be performed without increasing the number of agitators installed and the operating cost.Type: GrantFiled: September 20, 2006Date of Patent: June 8, 2010Assignee: Babcock-Hitachi Kabushiki KaishaInventors: Naoki Oda, Takanori Nakamoto, Hiroyuki Nosaka
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Patent number: 7722843Abstract: A process, system and sorbent for removal of mercury from a combustion exhaust gas stream in a combustion exhaust gas purification scheme that includes a combustion exhaust scrubber system that uses an aqueous liquid to remove acid gases from the combustion exhaust gas. A powdered mercury sorbent is used. The sorbent is introduced into the aqueous scrubber liquid in the scrubber system. After introduction of the mercury sorbent into the scrubber liquid, at least some of the mercury sorbent is separated from the scrubber liquid.Type: GrantFiled: November 26, 2007Date of Patent: May 25, 2010Inventor: Srivats Srinivasachar
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Patent number: 7718151Abstract: An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.Type: GrantFiled: October 13, 2008Date of Patent: May 18, 2010Inventor: Liang Hu
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Publication number: 20100120095Abstract: The present invention relates to an electromagnetic bioaccelerator for obtaining biomass by simulating environmental marine conditions, comprising at least the following elements: octagonal biomass converters (1), seawater reserve tanks (3), particle filters (4), UV light filters (5), feedback and mixture tanks (6), pressurization feed tanks (8), manometers (9), pressure controllers (10), buffer tanks (11), expansion tanks with a safety valve (12), heat exchangers (13), temperature control thermostats (14), recycled water feedback tanks (15), reinjection pumps (16), centrifuges for separating the biomass from the water (17), desuperheaters (18); control panels (25), recirculation pumps (26), densimeters (27), biomass mechanical extraction systems by means of centrifugation (32) and biomass accumulation tanks (33).Type: ApplicationFiled: December 14, 2007Publication date: May 13, 2010Inventors: Bernard A. J. Stroïazzo-Mougin, Cristian Gomis Catala
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Publication number: 20100111797Abstract: A process is disclosed for the preparation of an additive-containing anionic clay generally comprising the steps of: a) milling a physical mixture of a divalent metal compound and a trivalent metal compound, b) calcining the milled physical mixture at a temperature in the range of about 200 to about 8000 C, and c) rehydrating the calcined mixture in aqueous suspension to form the additive-containing anionic clay, wherein an additive is optionally present in the physical mixture of step (a) and present in the aqueous suspension of step (c), and the additive is essentially free of vanadium.Type: ApplicationFiled: March 20, 2008Publication date: May 6, 2010Applicant: Albemarle Netherlands B.V.Inventors: Elbert Arjan De Graaf, Jorge Alberto Conzalez, Julie Ann Francis, Maria Margaret Ludvig
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Patent number: 7698004Abstract: A controller is provided for directing control of a process performed to control an amount of a pollutant emitted into the air. The process has multiple process parameters (MPPs) The controller includes either a neural network process model or a non-neural network process model. Whichever type model is included, it will represent a relationship between one of the MPPs and other of the MPPs. The controller also includes a control processor having the logic to determine the validity of a measured value of the one MPP based on the one model. The control processor directs control of the process in accordance with the measured value of the one MPP only if the measured value of the one MPP is determined to be valid. On the other hand, if the measured value is determined to be invalid, the control processor may direct control of the process in accordance with an estimated value of the one MPP.Type: GrantFiled: December 3, 2004Date of Patent: April 13, 2010Assignee: ALSTOM Technology Ltd.Inventors: Scott A. Boyden, Stephen Piche
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Publication number: 20100061909Abstract: An exhaust gas treating method removes sulfur dioxide from exhaust gas containing at least sulfur dioxide and mercury by bringing the exhaust gas into contact with absorption liquid. Persulfate is added into the absorption liquid or alternatively, iodine gas is added to the exhaust gas before the exhaust gas is brought into contact with the absorption liquid. A high removal rate for both sulfur dioxide and mercury is stably maintained if the load of power generation and the composition of exhaust gas fluctuate.Type: ApplicationFiled: March 5, 2008Publication date: March 11, 2010Applicant: CHIYODA CORPORATIONInventors: Kazushige Kawamura, Dai Takeda, Eiji Awai, Akira Kumagai
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Patent number: 7655072Abstract: A process for purifying CO2 offgas streams to free them of chemical compounds, and to the recycling of the purified gas streams into the production process.Type: GrantFiled: July 20, 2005Date of Patent: February 2, 2010Assignee: Degussa AGInventors: Hans-Joachim Hasselbach, Jose Vanrobaeys, Martin Körfer
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Patent number: 7655202Abstract: A process for treating flue gas containing fly ash and carbon dioxide is disclosed. In the process, carbon dioxide and fly ash are contacted with an aqueous metal hydroxide solution to convert carbon dioxide into a metal carbonate, and wherein the metal carbonate and the metal hydroxide cause the fly ash to undergo a geopolymerization reaction and form a geopolymerized fly ash. The geopolymerized fly ash is recovered for disposal or for further use, such as a concrete additive.Type: GrantFiled: October 9, 2007Date of Patent: February 2, 2010Assignee: Ceramatec, Inc.Inventors: Ashok V. Joshi, Chett Boxley
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Patent number: 7651389Abstract: An exhaust smoke processing system comprises air preheater for heating combustion air by exhaust smoke discharged from a boiler, a heat recoverer for heating a heat medium by exhaust smoke discharged from the air preheater, a dust collector for collecting soot and dust in exhaust smoke discharged from the heat recoverer, a wet-type exhaust smoke processing apparatus for processing exhaust smoke discharged from the dust collector, a reheater for heating exhaust smoke discharged from the wet-type exhaust smoke processing apparatus by the heat medium, and a heat medium circulation pipe passage for circulating the heating medium between the reheater and the heat recoverer. the system measures a heavy metal concentration in the exhaust smoke and adjusts the temperature of exhaust smoke at an outlet of the heat recoverer such that the measured value falls within a predetermined range.Type: GrantFiled: September 8, 2003Date of Patent: January 26, 2010Assignee: Babcock-Hitachi Kabushiki KaishaInventors: Hirofumi Kikkawa, Takanori Nakamoto, Toshio Katsube
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Patent number: 7651329Abstract: In an exhaust gas processing device wherein in order to efficiently outwardly discharge heat at high temperatures of about 90-150° C. released from a GGH reheater during the shutdown of a desulfurizer, to prevent damage to equipment and corrosion preventive lining material, and to ensure long-term stabilized use of the exhaust gas processing device, at least a GGH heat recovery unit, an absorption tower, a mist eliminator (M/E), and the GGH reheater are placed in a duct for exhaust gases discharged from a fire furnace, in the order named as seen from the upstream side of a flow of exhaust gases, an exhaust gas duct between the M/E and the reheater is provided with a heat radiation device or the like having a heat suppression function for suppressing dissipated heat from the reheater.Type: GrantFiled: January 29, 2004Date of Patent: January 26, 2010Assignee: Babcock-Hitachi Kabushiki KaishaInventors: Hajime Okura, Toshio Katsube, Takayuki Saito
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Patent number: 7645430Abstract: Horizontal gas-liquid scrubbing systems and associated gas scrubbing methodologies are provided. In one embodiment, a horizontal duct scrubbing system includes a horizontally disposed housing having a waste gas inlet and a treated gas outlet, a liquid inlet manifold disposed within the horizontally disposed housing, the liquid inlet manifold comprising a plurality of nozzles oriented to spray a scrubbing liquor co-current to the flow of a gas stream flowing through the horizontally disposed housing, and a demister located proximal the treated gas outlet, where the horizontally disposed housing is substantially free of flow deflection members between the liquid inlet manifold and the demister. The gas stream may include sulfur dioxide, and the system may be capable of removing at least 71 vol. % sulfur dioxide from the gas stream.Type: GrantFiled: October 8, 2007Date of Patent: January 12, 2010Assignee: Alcoa Inc.Inventors: Rajat Ghosh, Peter Bowen, Charles Dobbs, Roger Nichols, Neal Richard Dando, John R. Smith, Richard R. Lunt, Gregory Charles Kraft
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Patent number: 7641877Abstract: A method for enlarging the particle diameters of sulfuric acid mists in waste gas and collecting the sulfuric acid mists in high efficiency is provided. A process for disposing waste gas containing sulfur oxides that introduces the waste gas in dry type electrostatic precipitator to remove dusts and then introduces the waste gas in a wet desulfurization apparatus to carry out desulfurization, wherein the waste gas temperature of a smoke channel at a more upstream side than the wet desulfurization apparatus is measured, the flow channel length is variable based on the measurement value of the waste gas temperature, the waste gas is flown to a flow channel means that is adjusted at a channel length capable of cooling the waste gas to the dew point of acid by heat release and then, the waste gas is introduced into the wet desulfurization apparatus.Type: GrantFiled: October 1, 2007Date of Patent: January 5, 2010Assignee: Hitachi Plant Technologies, LTD.Inventors: Sachio Maekawa, Shinichi Kawabata, Keigo Orita
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Patent number: 7641876Abstract: One aspect of the invention relates to a method for removing contaminants from a flue gas stream (22). The method includes: removing fly ash from a flue gas stream (22) utilizing a particle collector (24); contacting the flue gas stream with an alkaline reagent in a wet scrubber (26); discharging a purge liquid (30) from the wet scrubber (26); and, combining at least a portion of the purge liquid with at least a portion of fly ash circulating within a dry circulating fluid bed scrubber (48) to form moistened fly ash (60).Type: GrantFiled: March 5, 2009Date of Patent: January 5, 2010Assignee: ALSTOM Technology LtdInventors: Kelly L. Barger, Gregg R. Doule, Michael G. Varner
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Patent number: 7628969Abstract: An apparatus and a method that uses generated alkaline, alkaline-earth, and/or silica/alumina aerosols as a multifunctional additive to scavenge sulfur oxides in flue gas, minimize poisoning effects of sulfur oxides on mercury sorbent performance, and enhance particulate matter capture in electrostatic precipitators and other particulate filter devices by conditioning the fly ash.Type: GrantFiled: July 22, 2008Date of Patent: December 8, 2009Assignee: Energy & Environmental Research Center FoundationInventors: Michael J. Holmes, John H. Pavlish, Ye Zhuang, Steven A. Benson, Edwin S. Olson, Jason D. Laumb
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Patent number: 7625537Abstract: A process and system for removing sulfur oxide, other gases, and particulate from a flue gas. The process includes treating flue gas with a slurry formed from water, an alkaline reagent, and the purge stream from a wet scrubber in a spray dryer, thereby producing a dry by-product. The process further includes filtering the flue gas to remove at least a portion of the dry by-product, wet scrubbing the flue gas exiting the filter in a wet scrubber, adding a lime or limestone reagent to the wet scrubber, and producing gypsum. Activated carbon may be injected into the flue gas upstream of the filtering step and particulate may be removed from the flue gas upstream of the spray dryer.Type: GrantFiled: June 12, 2006Date of Patent: December 1, 2009Assignee: ALSTOM Technology LtdInventors: Philip C. Rader, Raymond R. Gansley
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Publication number: 20090291872Abstract: The present invention provides compositions comprising ionic liquids and an amine compound, and methods for using and producing the same. In some embodiments, the compositions of the invention are useful in reducing the amount of impurities in a fluid medium or a solid substrate.Type: ApplicationFiled: December 11, 2008Publication date: November 26, 2009Applicant: The Regents of the University of ColoradoInventors: Jason E. Bara, Dean E. Camper, Douglas L. Gin, Richard D. Noble
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Patent number: 7622093Abstract: Zonal injection of varying compositions of chemicals, particularly an ammonia-based reagent and hydrocarbon, through injection lances arranged in a grid formation to define planar zones in a furnace convective pass of a furnace. The supply of chemicals is controlled so as to be individually determined for each discrete zone of the grid depending on conditions in that zone.Type: GrantFiled: October 29, 2008Date of Patent: November 24, 2009Assignee: Doosan Babcock Energy America LLCInventors: Stuart Arrol, Peter Melling, George Anthony Yates, Michael J. Smith, Gerard J. W. C. Hesselmann, Barbara Lefebvre, John Macphail, Keith W. Morris
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Patent number: 7618604Abstract: An object of the present invention is to provide a method for removing gaseous mercury in flue gas that make it possible to remove mercury in flue gas extremely satisfactorily while handling is made easy and cost increases are kept under control. In order to accomplish the object, the present invention adopts the method of removing gaseous mercury in flue gas, in which, after water-insoluble mercury in the flue gas is converted into water-soluble mercury by placing the flue gas in contact with a solid catalyst formed by a metal oxide, wet-type absorption is performed on the water-soluble mercury.Type: GrantFiled: July 14, 2005Date of Patent: November 17, 2009Assignees: IHI Corporation, Central Research Institute of Electric Power IndustryInventors: Takashi Kiga, Noriyuki Iiyama, Kenji Takano, Akimasa Yamaguchi, Yoshihisa Tochihara, Shigeo Ito
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Patent number: 7618602Abstract: A process of using solutions containing thiosulfate and/or chloride salt reagents to remove SO3 and H2SO4 acid gases from a flue gas. The solution is injected into a moving volume of flue gas to achieve a droplet size that enables the solution to dry on contact with the flue gas, generating dried particles of the reagent that react with the SO3 and H2SO4 acid gases yielding a salt precipitate. SO2 present in the flue gas may also be absorbed with the solution, with a subsequent reaction yielding bisulfite species that, upon drying of the droplet, react with the SO3 and H2SO4 acid gases to form salts that are removed from the gas. The removal of these acid gases from a flue gas reduce corrosion of equipment used in coal or oil fired power plants downstream of the injection cite.Type: GrantFiled: April 3, 2006Date of Patent: November 17, 2009Assignee: Codan Development LLCInventors: Frank B. Meserole, Robert E. Moser, James H. Wilhelm
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Patent number: 7611685Abstract: The inventive method for hydrogen sulphide and/or mercaptans decomposition consists in passing hydrogen sulphide and/or mercaptan-containing gas at a temperature less than 200° C. through a hard material layer (catalyst) which decomposes said hydrogen sulphide or mercaptans in such a way that hydrogen or hydrocarbons are released and sulphur-containing compounds are formed on a material surface. Said hard material is placed in a liquid medium layer. Said invention makes it possible to use a hard material (catalyst) without a periodical regeneration thereof.Type: GrantFiled: March 31, 2005Date of Patent: November 3, 2009Assignee: Institu Kataliza Imeni G. K. Boreskova Sibirskogo Otdeleniya Rossiiskoi Akademii NaukInventors: Anatolii Nikolaevich Startsev, Anastasia Viktorovna Pashigreva, Olga Valeryevna Voroshina, Ivan Ivanovich Zakharov, Valentin Nikolaevich Parmon
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Patent number: 7604788Abstract: The invention provides a process for the removal of polysulfanes from gas streams formed during H2S synthesis.Type: GrantFiled: October 26, 2007Date of Patent: October 20, 2009Assignee: Evonik Degussa GmbHInventors: Alexander Möller, Wolfgang Böck, Wolfgang Taugner, Harald Heinzel, Stephan Rautenberg
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Publication number: 20090257932Abstract: A process for desulfurizing an SO2-comprising gaseous stream comprising the steps of: a. providing an aqueous feed comprising an anion selected from a group consisting of carbonate, bicarbonate, hydroxide, sulfite, and hydrogen sulfite; b. providing an SO2-comprising gaseous feed; and c. contacting the aqueous feed and the gaseous feed to generate a desulfurized gaseous product comprising less than 40% of the feed SO2 content, and an aqueous product; wherein the contacting is carried out in a cyclone unit comprising a housing defined by a cylindrical peripheral wall and provided with at least one inlet opening for receiving fluids thereinto and with at least one swirling means, and wherein the cyclone unit is characterized in that the velocity of the gaseous stream inside the cyclone unit is between 20 m/sec and 120 m/sec.Type: ApplicationFiled: September 4, 2007Publication date: October 15, 2009Applicants: CLUE AS, EYAL RESEARCH CONSULTANTS LTD.Inventors: Riki Canari, Aharon Eyal
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Patent number: 7601317Abstract: A method for enlarging the particle diameters of sulfuric acid mists in waste gas and collecting the sulfuric acid mists in high efficiency is provided. A process for disposing waste gas containing sulfur oxides that introduces the waste gas in dry type electrostatic precipitator to remove dusts and then introduces the waste gas in a wet desulfurization apparatus to carry out desulfurization, wherein outside air with a flow rate at which the waste gas introduced in the wet desulfurization apparatus is the dew point of acid is taken in from an introducing tube to mix the outside air in the waste gas.Type: GrantFiled: October 1, 2007Date of Patent: October 13, 2009Assignee: Hitachi Plant Technologies, Ltd.Inventors: Keigo Orita, Sachio Maekawa, Shinichi Kawabata
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Patent number: 7595033Abstract: A process and device for purifying flue gases in refuse incineration plants during regeneration of a catalyst which serves for reducing nitrogen oxides, by, in a first step, removing acidic pollutant gases from the flue gas in a wet or dry manner, in a second step adding ammonia for reducing nitrogen oxides to the flue gas purified in the first step, in a third step feeding the flue gas admixed with the ammonia to a catalyst, where the catalyst is heated at a controlled heat-up rate for regeneration, which leads to liberation of ammonia, where the amount of ammonia added in the second step and the heat-up rate in the third step are controlled by the amount of a pollutant gas selected from the group of ammonia, and which the purified flue gas contains.Type: GrantFiled: June 21, 2007Date of Patent: September 29, 2009Assignee: Von Roll Umwelttechnik AGInventors: Ruedi Frey, Sandrine Person
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Patent number: 7588627Abstract: The invention relates to a process for the removal of, H2S and mercaptans from a gas stream comprising these compounds, which process comprises the steps of: (a) removing H2S from the gas stream by contacting the gas stream in a H2S-removal zone with a first aqueous alkaline washing liquid to obtain a H2S-depleted gas stream and a sulphide-comprising aqueous stream; (b) removing mercaptans from the H2S-depleted gas stream obtained in step (a) by contacting the H2S-depleted gas stream in a mercaptan-removal zone with a second aqueous alkaline washing liquid to obtain a mercaptan-depleted gas stream and an thiolate—comprising aqueous stream; (c) contacting the combined aqueous streams comprising sulphide and thiolates obtained in step (a) and step (b) with sulphide-oxidizing bacteria in the presence of oxygen in an oxidation reactor to obtain a sulphur slurry and a regenerated aqueous alkaline washing liquid; (d) separating at least part of the sulphur slurry obtained in step (c) from the regenerated aqueous alType: GrantFiled: April 13, 2004Date of Patent: September 15, 2009Assignee: Shell Oil CompanyInventors: Wiebe Sjoerd Kijlstra, Josephus Norbertus Johannes Jacobus Lammers, Clas Ingemar Wernersson
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Patent number: 7585476Abstract: The present invention is related to a system for removal of moisture and contaminants from recirculated flue gas. The system includes a spray tower for spraying the flue gas with a liquid reagent to remove contaminants from the flue gas. A heat exchanger, integrally connected to the spray tower, cools the liquid reagent before the reagent is sprayed onto the flue gas stream. Cooled liquid reagent improves the condensation of the water vapor in the flue gas during the spraying process and provides a lower moisture content flue gas exiting the system. Combustion process efficiency improves as flue gas redirected to the burner for combustion contains.Type: GrantFiled: April 11, 2007Date of Patent: September 8, 2009Assignee: Babcock & Wilcox Power Generation Group Inc.Inventors: William Downs, Douglas J. Devault, Dennis K. McDonald, Hamid Farzan
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Patent number: 7582271Abstract: Methods and apparatus utilizing hydrogen peroxide are useful to reduce SOx and mercury (or other heavy metal) emissions from combustion flue gas streams. The methods and apparatus may further be modified to reduce NOx emissions. Continuous concentration of hydrogen peroxide to levels approaching or exceeding propellant-grade hydrogen peroxide facilitates increased system efficiency. In this manner, combustion flue gas streams can be treated for the removal of SOx and heavy metals, while isolating useful by-products streams of sulfuric acid as well as solids for the recovery of the heavy metals. Where removal of NOx emissions is included, nitric acid may also be isolated for use in fertilizer or other industrial applications.Type: GrantFiled: January 14, 2005Date of Patent: September 1, 2009Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Clyde F. Parrish, J. Landy Chung
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Patent number: 7569198Abstract: The removal of particulates and acidic gases from the effluent from a fluid catalytic cracking process regenerator. The effluent is treated in two contacting stages with an effective amount of both a caustic solution as well as ammonia and the composition of the contacting solutions in the two stages is independently controlled.Type: GrantFiled: July 24, 2007Date of Patent: August 4, 2009Assignee: ExxonMobil Research & Engineering CompanyInventors: Michael W. Bedell, Patrick J. Maher
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Patent number: 7560084Abstract: A system for separating sulfur dioxide from a gas using an aqueous absorption liquid. The system includes a housing, an apertured plate, an outlet box, a distribution mechanism, a container, and a pump. The housing has an inlet and an outlet. The apertured plate is positioned between the inlet and the outlet and includes a lower side, an upper side, and apertures fluidly connecting the lower and upper sides. The outlet box includes a distribution mechanism that is arranged so that the absorption liquid draining from the outlet box contacts the gas from the inlet before the gas passes through the apertures in the apertured plate. The container contains the absorption liquid and is fluidly connected with the housing. The pump draws the absorption liquid from the container through the pump and through a conduit to the upper side of the apertured plate.Type: GrantFiled: March 30, 2007Date of Patent: July 14, 2009Assignee: Alstom Technology LtdInventors: Dennis J. Laslo, Michael Chiang, David J. Muraskin, Michael J. Rini, Michael G. Varner
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Patent number: 7550123Abstract: Methods and apparatuses are described for contacting an oxidizing solution such as an aqueous hydrogen peroxide composition of hydrogen peroxide and at least one additive that catalyzes the decomposition of the hydrogen peroxide into hydroxyl radicals with an atmospheric effluent containing odorous and/or noxious components. These components are absorbed by the aqueous hydrogen peroxide composition to produce an atmospheric effluent having reduced amounts of the odorous and/or noxious components. Various methods are described for adding the hydrogen peroxide and the decomposition additive.Type: GrantFiled: May 26, 2006Date of Patent: June 23, 2009Assignee: Steen Research, LLCInventors: Stephen R. Temple, Michael J. Stoltz
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Publication number: 20090143211Abstract: A method of sequestering a greenhouse gas is described, which comprises: (i) providing a solution carrying a first reagent that is capable of reacting with a greenhouse gas; (ii) contacting the solution with a greenhouse gas under conditions that promote a reaction between the at least first reagent and the greenhouse gas to produce at least a first reactant; (iii) providing a porous matrix having interstitial spaces and comprising at least a second reactant; (iv) allowing a solution carrying the at least first reactant to infiltrate at least a substantial portion of the interstitial spaces of the porous matrix under conditions that promote a reaction between the at least first reactant and the at least second reactant to provide at least a first product; and (v) allowing the at least first product to form and fill at least a portion of the interior spaces of the porous matrix, thereby sequestering a greenhouse gas.Type: ApplicationFiled: November 14, 2008Publication date: June 4, 2009Inventors: Richard E. Riman, Vahit Atakan
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Patent number: 7541011Abstract: The present invention is directed to an improved method and system for separating and purifying gas using gas-liquid absorption. According to this invention, the method is carried out in an absorber, where a liquid absorbent, a gas mixture containing a gas to be absorbed were introduced from an inlet. During absorption, the second liquid phase was separated out from the absorbent. The absorbed gas was accumulated in one of liquid phases. After absorption, two liquid phases were separated. One of the liquids with rich absorbed gas was forward to regenerator. After regeneration, the liquid was cycled back to absorber. The liquid phase with lean absorbed gas was back to absorber directly to complete the cycle.Type: GrantFiled: April 7, 2006Date of Patent: June 2, 2009Inventor: Liang Hu
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Patent number: 7531154Abstract: A method of removing SO2 from a flue gas stream including SO2 includes providing a source of trona and injecting the trona into the flue gas stream. The temperature of the flue gas is between about 600° F. and about 900° F. The trona is maintained in contact with the flue gas for a time sufficient to react a portion of the trona with a portion of the SO2 to reduce the concentration of the SO2 in the flue gas stream.Type: GrantFiled: August 18, 2005Date of Patent: May 12, 2009Assignee: Solvay ChemicalsInventor: John Maziuk, Jr.
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Patent number: 7524470Abstract: One aspect of the invention relates to a method for removing contaminants from a flue gas stream (22). The method includes: removing fly ash from a flue gas stream (22) utilizing a particle collector (24); contacting the flue gas stream with an alkaline reagent in a wet scrubber (26); discharging a purge liquid (30) from the wet scrubber (26); combining at least a portion of the purge liquid (30) with at least a portion of the fly ash (48) to form moistened fly ash (60); and injecting at least a portion of the moistened fly ash (60) into the flue gas stream (22) upstream of the particle collector (24), whereby the moistened fly ash (60) removes at least a portion of contaminants present in the flue gas stream (22).Type: GrantFiled: July 13, 2006Date of Patent: April 28, 2009Assignee: Alstom Technology LtdInventors: Kelly L. Barger, Gregg Robert Doulé, Michael G. Varner
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Publication number: 20090092529Abstract: Horizontal gas-liquid scrubbing systems and associated gas scrubbing methodologies are provided. In one embodiment, a horizontal duct scrubbing system includes a horizontally disposed housing having a waste gas inlet and a treated gas outlet, a liquid inlet manifold disposed within the horizontally disposed housing, the liquid inlet manifold comprising a plurality of nozzles oriented to spray a scrubbing liquor co-current to the flow of a gas stream flowing through the horizontally disposed housing, and a demister located proximal the treated gas outlet, where the horizontally disposed housing is substantially free of flow deflection members between the liquid inlet manifold and the demister. The gas stream may include sulfur dioxide, and the system may be capable of removing at least 71 vol. % sulfur dioxide from the gas stream.Type: ApplicationFiled: October 8, 2007Publication date: April 9, 2009Applicant: Alcoa Inc.Inventors: Rajat Ghosh, Peter Bowen, Charles Dobbs, Roger Nichols, Neal Richard Dando, John R. Smith, Richard R. Lunt
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Patent number: 7514054Abstract: A flue gas purification device includes a receptacle, which has an absorption zone, through which the supplied glue gas can flow in an essentially horizontal direction.Type: GrantFiled: November 23, 2005Date of Patent: April 7, 2009Assignee: Lentjes GmbHInventors: Theo Risse, Christian Moser
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Publication number: 20090081093Abstract: The disclosure provides methods and systems for sequestering and/or reducing sulfur oxides, nitrogen oxides and/or carbon dioxide present in industrial effluent fluid streams. A solid particulate material comprising a slag component, a binder component (distinct from the slag component), and optionally water is formed and then contacted with the effluent fluid stream to reduce at least one of the sulfur oxides, nitrogen oxides, and/or carbon dioxide. The contacting of the effluent stream may occur in a packed bed reactor with the solid dry particulate material. Methods of reducing pollutants from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided.Type: ApplicationFiled: September 18, 2008Publication date: March 26, 2009Inventor: Douglas C. Comrie
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Patent number: 7501104Abstract: A discharge gas treatment apparatus and method which lower treatment cost and which attain efficient removal of mercury contained in a discharge gas are provided. The discharge gas treatment apparatus, includes a cooling apparatus for controlling the temperature of the discharge gas to a predetermined temperature in accordance with the hydrogen chloride concentration of the discharge gas; an NOx removal catalyst unit for reducing nitrogen oxide contained in the discharge gas and for causing reaction between mercury and hydrogen chloride contained in the discharge gas, the discharge gas having been controlled to the predetermined temperature and having been introduced to the apparatus, with ammonia being added thereto; and a wet-format desulfurization apparatus, disposed on the downstream side with respect to the NOx removal catalyst unit, for removing sulfur oxide and mercury chloride contained in the discharge gas through dissolving sulfur oxide and mercury chloride in a liquid absorbent.Type: GrantFiled: August 30, 2006Date of Patent: March 10, 2009Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Yoshiaki Obayashi, Kozo Iida, Toshio Koyanagi
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Patent number: 7498008Abstract: A process for the removal of a pollutant from a gas is provided that includes contacting a gas comprising a pollutant with a cataloreactant wherein the cataloreactant reacts with the pollutant and wherein an oxidation state of the cataloreactant is reduced. The cataloreactant may be regenerated with an oxidizing agent.Type: GrantFiled: February 23, 2006Date of Patent: March 3, 2009Assignee: GRT, Inc.Inventors: Jeffrey H. Sherman, Sagar B. Gadewar, Peter K. Stoimenov
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Patent number: 7488461Abstract: An exhaust gas treatment system is provided that can sufficiently remove pollutants such as SO3 contained in combustion exhaust gas at low cost. In the exhaust gas treatment system for removing pollutants such as SO3 contained in combustion exhaust gas, there is provided dissolved salt aqueous solution sprays 35A, 35B, and 35C, that spray an Na2SO4 aqueous solution obtained from desulfurization effluent of a wet desulfurization system, into a flue though which the combustion exhaust gas flows.Type: GrantFiled: April 19, 2006Date of Patent: February 10, 2009Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Hiromitsu Nagayasu, Yasutoshi Ueda, Morio Kagami, Toshihide Noguchi
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Patent number: 7476372Abstract: A method for reducing acid gases in a flue gas, the method comprising reacting biosolids comprising a scrubbing agent with a flue gas comprising an acid gas, thereby reducing the amount of acid gas in the flue gas is disclosed. Also disclosed is a flue gas scrubbing process comprising: combusting a fossil fuel and biosolids comprising a scrubbing agent, thereby producing a flue gas comprising an acid gas, wherein the flue gas has a reduced amount of acid gas compared with flue gas produced from the combustion of the fossil filet alone. A flue gas scrubbing process comprising providing a stream of biosolids that includes a hydroxide or an oxide of a Group IA or IIA element, providing a flue gas comprising an acid gas, and reacting the biosolids stream with the flue gas so as to reduce the amount of acid gas in the flue gas is also disclosed.Type: GrantFiled: June 28, 2006Date of Patent: January 13, 2009Assignee: Holloman CorporationInventor: Eric Prim
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Publication number: 20080311016Abstract: A method for enlarging the particle diameters of sulfuric acid mists in waste gas and collecting the sulfuric acid mists in high efficiency is provided. A process for disposing waste gas containing sulfur oxides that introduces the waste gas in dry type electrostatic precipitator to remove dusts and then introduces the waste gas in a wet desulfurization apparatus to carry out desulfurization, wherein the waste gas temperature of a smoke channel at a more upstream side than the wet desulfurization apparatus is measured, the flow channel length is variable based on the measurement value of the waste gas temperature, the waste gas is flown to a flow channel means that is adjusted at a channel length capable of cooling the waste gas to the dew point of acid by heat release and then, the waste gas is introduced into the wet desulfurization apparatus.Type: ApplicationFiled: October 1, 2007Publication date: December 18, 2008Applicant: HITACHI PLANT TECHNOLOGIES, LTD.Inventors: Sachio Maekawa, Shinichi Kawabata, Keigo Orita
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Patent number: 7459134Abstract: The combustion fume flowing in through line 1 is decarbonated by contacting with a solvent in column C2. The solvent laden with carbon dioxide is regenerated in zone R. The purified fume discharged through line 9 comprises part of the solvent. The method allows to extract the solvent contained in the purified fume. The purified fume is contacted in zone ZA with a non-aqueous ionic liquid of general formula Q+ A?; Q+ designates an ammonium, phosphonium and/or sulfonium cation, and A? an anion likely to form a liquid salt. The solvent-depleted purified fume is discharged through line 17. The solvent-laden ionic liquid is regenerated by heating in evaporation device DE. The solvent separated from the ionic liquid in device DE is recycled.Type: GrantFiled: January 23, 2006Date of Patent: December 2, 2008Inventors: Renaud Cadours, Fabrice Lecomte, Lionel Magna, Cécile Barrere-Tricca
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Patent number: 7455820Abstract: Disclosed herein is a process for removing sulfur dioxide (SO2) and nitrogen oxides (NOx) from flue gas using chlorine dioxide (ClO2). In the process, chlorine dioxide is allowed to react with flue gas in an alkaline solution so as to be able to simultaneously remove sulfur dioxide and nitrogen oxides from the flue gas. In the simultaneous removal of sulfur dioxide and nitrogen oxides from flue gas using the process, chlorine dioxide is produced by side reactions, and the produced chlorine dioxide can be used to remove sulfur dioxide and nitrogen oxides from flue gas.Type: GrantFiled: December 30, 2005Date of Patent: November 25, 2008Assignee: Korea Institute of Energy ResearchInventors: Hyung-Keun Lee, Won-Kil Choi, Hang-Dae Jo, Dong-Seop Jin, Bal Raj Deshwal
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Patent number: 7438879Abstract: A device provides the purification of flue gas comprising a scrubbing liquid sump divided into several basins and a pump device, which pumps the scrubbing liquid from at least one basin of the scrubbing liquid sump to scrubbing liquid nozzles.Type: GrantFiled: November 23, 2005Date of Patent: October 21, 2008Assignee: Lentjes GmbHInventors: Theo Risse, Christian Moser
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Patent number: 7431757Abstract: A combustion turbine power plant (10) incorporating a desiccating scrubber (140) for simultaneously removing water and sulfur from a flue gas (20) of the power plant (10). The desiccating scrubber (140) may include an inlet nozzle (145) for spraying an aqueous solution (142) containing a desiccant and a base into flue gas (20) so the aqueous solution (142) makes direct contact with flue gas (20). A filter (162) may be provided to collect sulfur compounds downstream of the desiccating scrubber (140) and a regenerator (164) may be provided for recovering water. A controller (148) may control a base supply (170) and a desiccant supply (172) to regulate the respective amounts of each introduced into the aqueous solution (142). Controller (148) may be responsive to sensors (142) measuring the water and sulfur content of flue gas (20) exhausted to atmosphere (144). The desiccating scrubber (140) may include a demister (160) to entrain carryover droplets from a sprayed aqueous solution (142).Type: GrantFiled: October 18, 2005Date of Patent: October 7, 2008Assignee: Siemens Power Generation, Inc.Inventor: James C. Bellows
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Publication number: 20080241036Abstract: A system for separating sulfur dioxide from a gas using an aqueous absorption liquid. The system includes a housing, an apertured plate, an outlet box, a distribution mechanism, a container, and a pump. The housing has an inlet and an outlet. The apertured plate is positioned between the inlet and the outlet and includes a lower side, an upper side, and apertures fluidly connecting the lower and upper sides. The outlet box includes a distribution mechanism that is arranged so that the absorption liquid draining from the outlet box contacts the gas from the inlet before the gas passes through the apertures in the apertured plate. The container contains the absorption liquid and is fluidly connected with the housing. The pump draws the absorption liquid from the container through the pump and through a conduit to the upper side of the apertured plate.Type: ApplicationFiled: March 30, 2007Publication date: October 2, 2008Inventors: Dennis J. Laslo, Michael Chiang, David J. Muraskin, Michael J. Rini, Michael G. Varner