And Addition Of Gaseous Reactant Patents (Class 423/243.02)
-
Patent number: 10655850Abstract: The present invention relates to an air purification apparatus for a coal-fired electric power plant, and more specifically to an air purification apparatus for a coal-fired electric power plant, which, first, can filter out wastes of contaminated smoke by using limewater, which, second, can filter out fine dust and carbon dioxide included in the smoke, which, third, can convert waste gas including carbon monoxide in a state in which only smoke remains into carbon dioxide by reacting oxygen with the waste gas and purify the smoke into clean air by allowing a sodium hydroxide solution to absorb the carbon dioxide, and which, fourth, can eliminate humidity from the clean air by passing the clean air through a moisture condenser a plurality of times and discharge clean air in a pure smoke state from the power plant.Type: GrantFiled: January 10, 2018Date of Patent: May 19, 2020Inventor: Bing Ji Dong
-
Patent number: 9200347Abstract: Provided is a recycling method for producing calcite and ammonium sulfate having a high purity of at least 95% and generated by means of a carbonation reaction for fixing carbon dioxide inside the crystal structure of a mineral, and in which waste gypsum is reacted with carbon dioxide, which is a greenhouse gas, such that the carbon dioxide is fixed as a stable mineral, and high-purity calcite and ammonium sulfate are produced as resultant products.Type: GrantFiled: July 13, 2012Date of Patent: December 1, 2015Assignee: Korea Institute of Geoscience and Mineral ResourcesInventors: Young Nam Jang, Kyung Won Ryu, Myung Kyu Lee
-
Patent number: 8927637Abstract: A polymer, a composition, and uses for either are disclosed. The polymer is derived from at least two monomers: acrylic-x and an alkylamine, and has attached to the polymer backbone a functional group capable of scavenging at least one metal. The polymer has a polymer backbone with a fluorescing quantity of conjugated double bonds, thereby providing a method for controlling metal scavenging via fluorescence. These polymers have many uses in various media, including wastewater systems.Type: GrantFiled: June 29, 2012Date of Patent: January 6, 2015Assignee: Nalco CompanyInventors: Paul J. Zinn, Winston Su, Rebecca L. Stiles, Darlington Mlambo
-
Patent number: 8795416Abstract: An in-situ forced oxidation wet flue gas desulfurization apparatus, method and arrangement for utilization with oxy-fuel combustion power plants. The apparatus is a tower-like structure having a flue gas scrubbing zone and a reaction zone located subjacent to the gas scrubbing zone. A sulfur oxide absorbing liquid slurry is supplied to the gas scrubbing zone to react with and scrub the sulfur oxides from the flue gas. The partially reacted liquid slurry reagent and the scrubbed products drain into the reaction zone, rising to a set level. Oxidation air is introduced into the liquid slurry in the reaction zone to force the in-situ oxidation of sulfur compounds collected in the reaction zone.Type: GrantFiled: October 12, 2009Date of Patent: August 5, 2014Assignee: Babcock & Wilcox Power Generation Group, Inc.Inventors: Dennis K. McDonald, Kevin J. Rogers
-
Patent number: 8753599Abstract: A method and composition for the reduction of the emission of selenium into the environment from the burning of fossil fuels with the use of two chemistries, either individually or in combination with each other. The method uses polydithiocarbamic compounds, including polydithiocarbamic compounds derived from a polymer produced from acrylic-x and alkylamine in conjunction with a scrubber process to capture selenium and reduce its emission in aqueous phase blowdown. The method and composition also helps reduce corrosion in the scrubber process.Type: GrantFiled: February 6, 2012Date of Patent: June 17, 2014Assignee: Nalco CompanyInventors: Bruce A. Keiser, Jitendra T. Shah, John V. Meier, Paul J. Zinn, Jianwei Yuan, Raul Espinosa, Rebecca L. Stiles, Richard Mimna, Wayne M. Carlson
-
Patent number: 8747789Abstract: A composition comprising a polymer derived from at least two monomers: acrylic-x and an alkylamine, wherein said polymer is modified to contain a functional group capable of scavenging one or more compositions containing one or more metals is disclosed. These polymers have many uses in various mediums, including wastewater systems.Type: GrantFiled: April 6, 2010Date of Patent: June 10, 2014Assignee: Nalco CompanyInventors: Paul J. Zinn, Jitendra T. Shah, William J. Andrews
-
Patent number: 8609050Abstract: A method and composition for the reduction of the emission of selenium into the environment from the burning of fossil fuels with the use of two chemistries, either individually or in combination with each other. The method uses polydithiocarbamic compounds, including polydithiocarbamic compounds derived from a polymer produced from acrylic-x and alkylamine in conjunction with a scrubber process to capture selenium and reduce its emission in aqueous phase blowdown. The method and composition also helps reduce corrosion in the scrubber process.Type: GrantFiled: February 6, 2012Date of Patent: December 17, 2013Assignee: Nalco CompanyInventors: Bruce A. Keiser, Jitendra T. Shah, John V. Meier, Paul J. Zinn, Jianwei Yuan, Raul Espinosa, Rebecca L. Stiles, Richard Mimna, Wayne M. Carlson
-
Patent number: 8597603Abstract: The present invention provides a new method for decomposing and/or removing hazardous substances using a photocatalytic material. The method of the present invention is sufficiently useful in fields requiring quick decomposition and/or removal of hazardous substances in gas and/or liquid phases. The decomposition method of the present invention using a photocatalytic material enables significantly efficient and rapid decomposition of hazardous substances in gas and/or liquid phases by causing a photocatalytic material to coexist with a dilute hydrogen peroxide solution.Type: GrantFiled: May 30, 2011Date of Patent: December 3, 2013Assignee: Showa Co., Ltd.Inventors: Teruki Takayasu, Teruo Arai, Kinji Onoda
-
Patent number: 8518357Abstract: Methods, systems, and apparatus for managing sulfur are disclosed. In some embodiments, the method comprise the following: obtaining material containing sulfur; refining the material to develop a high sulfur content heavy fraction fuel oil and a low sulfur content light fraction fuel oil; burning the low sulfur content light fraction fuel oil in apparatus that emit to the atmosphere; burning the high sulfur content heavy fraction fuel oil to produce energy thereby generating flue gas containing sulfur oxide; and removing and disposing of sulfur in the flue gas using a sulfur sequestration system that includes utilizing sulfur removed from the flue gas to form a brine material.Type: GrantFiled: May 5, 2009Date of Patent: August 27, 2013Assignee: The Trustees of Columbia University in the City of New YorkInventors: Klaus S. Lackner, Tim A. Rappold
-
Publication number: 20130078174Abstract: The present invention provides a new method for decomposing and/or removing hazardous substances using a photocatalytic material. The method of the present invention is sufficiently useful in fields requiring quick decomposition and/or removal of hazardous substances in gas and/or liquid phases. The decomposition method of the present invention using a photocatalytic material enables significantly efficient and rapid decomposition of hazardous substances in gas and/or liquid phases by causing a photocatalytic material to coexist with a dilute hydrogen peroxide solution.Type: ApplicationFiled: May 30, 2011Publication date: March 28, 2013Applicant: SHOWA CO., LTD.Inventors: Teruki Takayasu, Teruo Arai, Kinji Onoda
-
Patent number: 8353980Abstract: An apparatus and process for removing acidic gases from flue gases produced by, for example, utility and industrial facilities. The acidic gases are removed as the flue gas flows upward through a contact zone within a passage, where the flue gas is contacted with an ammonium sulfate-containing scrubbing solution to absorb the acidic gases from the flue gas. The scrubbing solution and absorbed acidic gases therein are then accumulated, and ammonia and an oxygen-containing gas are injected into the accumulated scrubbing solution to react the absorbed acidic gases and produce ammonium sulfate. An acid solution is flowed across the passage above the contact zone of the passage, and the scrubbed flue gas is flowed upward through the acid solution to remove unreacted ammonia from the scrubbed flue gas. The acid solution is then removed from the passage after the acid solution has been contacted by the scrubbed flue gas.Type: GrantFiled: December 3, 2009Date of Patent: January 15, 2013Assignee: Marsulex Environmental Technologies CorporationInventor: David William Murphy
-
Patent number: 7837965Abstract: A process for reducing hydrogen sulfide from a gas comprising contacting the gas with an aqueous scrubbing liquid recycled from a sour water stripper. The aqueous scrubbing liquid comprises ammonia. The contacting of the gas with the aqueous scrubbing liquid thereby produces a semi-sweet gas with reduced concentration of hydrogen sulfide and a rich liquid solution.Type: GrantFiled: December 10, 2008Date of Patent: November 23, 2010Assignee: Thiosolv, LLCInventor: Mark C. Anderson
-
Patent number: 7766995Abstract: The present invention provides for an improved process for producing ozone which can be used to remove contaminants from gas streams in industrial processes. The improved process uses a separation device after the ozone generating system to separate the ozone from the oxygen gas and directs the ozone to the industrial process and the oxygen back to the feedstream entering the ozone generating system. The improved process further provides for the use of ozone so generated to removed contaminants from industrial process flue gas streams.Type: GrantFiled: April 10, 2007Date of Patent: August 3, 2010Assignee: Linde LLCInventors: Naresh J. Suchak, Ravi Jain, Kelly Visconti, Steven Finley
-
Publication number: 20100061909Abstract: An exhaust gas treating method removes sulfur dioxide from exhaust gas containing at least sulfur dioxide and mercury by bringing the exhaust gas into contact with absorption liquid. Persulfate is added into the absorption liquid or alternatively, iodine gas is added to the exhaust gas before the exhaust gas is brought into contact with the absorption liquid. A high removal rate for both sulfur dioxide and mercury is stably maintained if the load of power generation and the composition of exhaust gas fluctuate.Type: ApplicationFiled: March 5, 2008Publication date: March 11, 2010Applicant: CHIYODA CORPORATIONInventors: Kazushige Kawamura, Dai Takeda, Eiji Awai, Akira Kumagai
-
Patent number: 7628969Abstract: An apparatus and a method that uses generated alkaline, alkaline-earth, and/or silica/alumina aerosols as a multifunctional additive to scavenge sulfur oxides in flue gas, minimize poisoning effects of sulfur oxides on mercury sorbent performance, and enhance particulate matter capture in electrostatic precipitators and other particulate filter devices by conditioning the fly ash.Type: GrantFiled: July 22, 2008Date of Patent: December 8, 2009Assignee: Energy & Environmental Research Center FoundationInventors: Michael J. Holmes, John H. Pavlish, Ye Zhuang, Steven A. Benson, Edwin S. Olson, Jason D. Laumb
-
Publication number: 20090148373Abstract: A process for reducing hydrogen sulfide from a gas comprising contacting the gas with an aqueous scrubbing liquid recycled from a sour water stripper. The aqueous scrubbing liquid comprises ammonia. The contacting of the gas with the aqueous scrubbing liquid thereby produces a semi-sweet gas with reduced concentration of hydrogen sulfide and a rich liquid solution.Type: ApplicationFiled: December 10, 2008Publication date: June 11, 2009Inventor: Mark C. Anderson
-
Publication number: 20080267846Abstract: Processes comprising: providing a crude gas comprising hydrogen chloride and at least one sulfur compound; and passing the crude gas across a sacrificial material such that at least a portion of the at least one sulfur compound is oxidized and precipitated as sulfate onto the sacrificial material to provide a hydrogen chloride product gas.Type: ApplicationFiled: April 28, 2008Publication date: October 30, 2008Applicant: Bayer MaterialScience AGInventors: Michel Haas, Knud Werner
-
Patent number: 7416716Abstract: SO2 and/or NOx are removed from gaseous CO2 at elevated pressure(s) in the presence of molecular oxygen and water and, when SO2 is to be removed, NOx, to convert SO2 to sulfuric acid and/or NOx to nitric acid. The sulfuric acid and/or nitric acid is/are then removed from the gaseous carbon dioxide to produce SO2-free, NOx-lean carbon dioxide gas. The invention has particular application in the removal of SO2 and/or NOx from carbon dioxide flue gas produced in an oxyfuel combustion process, for example, in a pulverized coal fired power station.Type: GrantFiled: November 28, 2005Date of Patent: August 26, 2008Assignee: Air Products and Chemicals, Inc.Inventors: Rodney John Allam, Vincent White, Edwin John Miller
-
Patent number: 6863875Abstract: In a flue gas treating system, an absorption tower (21), a reheating section (22) and a fan (23) are arranged in line on a vertical axis so as to function as at least a part of a stack for emitting the treated flue gas into the atmosphere. Moreover, in a flue gas treating process, the amount of ammonia injected in the denitration step (a denitrator (2)) and/or the amount of ammonia at a point downstream of the denitration step are determined so as to be on such an excessive level that ammonia or ammonium salt will remain in the flue gas introduced into the desulfurization step (absorption tower (21)). Thus, the size and cost of the equipment can be reduced.Type: GrantFiled: September 11, 2000Date of Patent: March 8, 2005Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Shinichiro Kotake, Kazuaki Kimura, Kazumitsu Suzuki, Naohiko Ukawa, Toru Takashina
-
Patent number: 6773555Abstract: The present invention relates to a flue gas treatment method and apparatus for removing sulfur oxides by injecting ammonia into flue gas containing sulfur oxides. In the flue gas treatment method for removing sulfur oxides contained in the flue gas using ammonia, the present invention is characterized in that ammonia is injected into the flue gas containing sulfur oxides to react sulfur oxides with ammonia to produce ammonium compounds containing ammonium sulfate, and after recovering the produced ammonium compounds from the flue gas, the flue gas is brought into contact with an absorption liquid to remove residual sulfur oxides and/or ammonia contained in the flue gas.Type: GrantFiled: February 12, 2002Date of Patent: August 10, 2004Assignee: Ebara CorporationInventors: Masahiro Izutsu, Ryoji Suzuki, Shinji Aoki, Daisuke Saku, Kazuaki Hayashi
-
Patent number: 6503471Abstract: Malodorous gases such as amines, organosulfur compounds, hydrogen sulfide, styrene and aldehydes are economically and efficiently treated at ambient temperature and pressure by a catalytic absorption and oxidation process comprising: (a) bringing the malodorous gases into contact with a scrubbing water containing a heterogeneous catalyst to absorb the malodorous components catalytically, and (b) subjecting the resulting solution containing the malodorous components to a catalytic oxidation by contacting it with an oxidizing agent such as hydrogen peroxide, ozone, oxygen, air, nitrogen oxides, and NaOCl in the presence of the catalyst at a temperature ranging from 0 to 100 □ under an ambient pressure, the heterogeneous catalyst comprising an active metal element selected from alkali, alkaline earth and transition metals, and an oxide support material.Type: GrantFiled: October 6, 2000Date of Patent: January 7, 2003Assignee: Korea Institute of Science & TechnologyInventors: Seong-Hwan Han, Kwang-Deog Jung, Oh-Shim Joo, Seong-Hoon Cho, Jun-Woo Oh
-
Patent number: 6447740Abstract: The invention is directed to a process for oxidizing gaseous pollutants in a flue gas stream composed of flue gases, water vapour and one or more gaseous pollutants selected from the group consisting of SO2, NO, NO2, H2S, and mercury vapour, the oxidized form of the pollutants being more readily removable from the flue gas stream by water absorption than the non-oxidized form thereof, comprising: (a) injecting sufficient chlorine in a gaseous form, a liquid form, or as a chlorine water solution, into the flue gas stream while the flue gas stream is at a temperature greater than 100° C.Type: GrantFiled: October 25, 2000Date of Patent: September 10, 2002Assignee: ISCA Management Ltd.Inventors: Douglas Caldwell, John W. Biggar, Brian W. McIntyre