Treating Carbon Patents (Class 423/460)
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Patent number: 8309052Abstract: Methods for producing devolatilized and/or activated carbon in a reactor or reaction vessel of a heat treatment system from a suitable carbonaceous feedstock by introducing the feedstock into the reactor tangentially at a rotational velocity of at least 90 RPM. The methods include the steps of providing a combination of conveying means and a gas flow having various compositions and creating distinct carbonaceous feedstock material flow patterns and process conditions such that the feedstock is conveyed through the reactor or reaction vessel and heated via combustion, thereby producing activated carbon or other heat-treated carbons while concurrently avoiding adverse reaction conditions. Single and two-stage heat treatment systems may be used to heat a carbon feedstock, to which one or more industrial minerals may be added to co-produce compositions such as lime with the heat-treated carbon.Type: GrantFiled: July 2, 2009Date of Patent: November 13, 2012Assignee: Pneumatic Processing Technologies, L.L.C.Inventor: Michael A. Jones
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Patent number: 8308955Abstract: Embodiments described herein generally relate to the separation of carbon nanotubes by reversible gelation.Type: GrantFiled: July 20, 2009Date of Patent: November 13, 2012Assignee: Empire Technology Development LLCInventor: Seth Adrian Miller
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Patent number: 8309644Abstract: A method of treating carbon fibers includes introducing a functional group to a carbon fiber surface, and reacting the functional group with a silane to incorporate a silanol moiety to the carbon fiber surface. The functional group is chosen from amine groups, carboxyl groups, hydroxyl groups, and/or carbonyl groups. Also disclosed herein are a fiber-reinforced resin and a method of making the same.Type: GrantFiled: August 29, 2011Date of Patent: November 13, 2012Assignee: GM Global Technology Operations LLCInventor: Xiaosong Huang
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Patent number: 8303836Abstract: A process of preparing magnetic graphitic materials from graphite in a second container (3) that reacts with one of more transition metal oxide and in a first container (2) at a volume ratio of 1:1, in a closed reactor (1), heated up to a temperature between 600° C. and the melting temperature of the transition oxide (s) for 6 to 36 hours, under a pressure of 10 atmospheres with the help of a transfer inert gas through an inlet (5) and vacuum between 10?2 torr to 10?7 torr through an outlet (6), obtaining at the end of the process a graphitic material with long-lasting magnetic properties at room temperature. The material obtained exhibits a complex structure, with pores, bunches, pilings and edges of exposed graphenes and finds application in nanotechnology, magnetic images in medical science, applications in communication, electronics, sensors, even biosensors, catalysis or separation of magnetic materials.Type: GrantFiled: November 16, 2011Date of Patent: November 6, 2012Assignees: Universidade Federal de Sao Carlos, Universidad de la RepublicaInventors: Fernando Manuel Araujo Moreira, Helena Pardo Minetti, Alvaro Washington Mombru Rodriguez
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Publication number: 20120275988Abstract: The present invention provides a method for producing an activated carbon for an electric double layer capacitor, with which the wettability of a carbon material with an alkali activator is improved, thereby improving contact efficiency between the carbon material and the alkali activator and efficiently promoting reaction between the carbon material, which is a starting material and the activator. The method comprises adjusting a carbon material as it is or after having been calcined to produce a carbon powder having an average particle diameter of 0.5 to 15 ?m, oxidizing the carbon powder to contain 3 percent by mass or more of oxygen, and activating the oxidized product with an alkali activator.Type: ApplicationFiled: December 24, 2010Publication date: November 1, 2012Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Masaki Fujii, Noriyuki Kiuchi, Shinya Taguchi, Keizo Ikai
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Patent number: 8282796Abstract: A carbonaceous substrate of the present invention is such that an X-ray diffraction pattern thereof is a complex profile and includes at least two (002) diffraction lines; and the substrates contains crystallites with different interlayer spacings. Further, in the X-ray diffraction pattern, (002) diffraction lines between 2?=10° and 2?=30° have an asymmetric shape; and the X-ray diffraction pattern includes at least two pattern components which are a diffraction line whose center is at 2?=26° and a diffraction line whose center is at a lower angle than 2?=26°. Further, the carbonaceous substrate contains crystals wherein the periodic distance d002 is 0.34 nm or more and the crystallite size Lc002 is 20 nm or less based on the X-ray diffraction lines. An electrodes for fluorine electrolysis of the present invention includes the carbonaceous substrate on which a conductive diamond thin film is formed.Type: GrantFiled: September 19, 2008Date of Patent: October 9, 2012Assignee: Toyo Tanso Co., Ltd.Inventors: Rie Tao, Takanori Kawano, Yoshio Shodai
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Patent number: 8273319Abstract: An improved method for enriched chirality of single wall carbon nanotubes is described. Genomic DNA, particularly salmon DNA (SaDNA) is shown to sort out single wall carbon nanotubes of specific chirality by a process of solubilization (dissolving in solution) and separation (such as centrifuging), without requiring more complex processes such as anion exchange chromatography. A possible reason for enhanced chirality separation using DNA may be attributed to its lowered GC (guanine-cytosine) content.Type: GrantFiled: July 26, 2010Date of Patent: September 25, 2012Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Sang N. Kim, Rajesh R. Naik, James G. Grote, Barry L. Farmer
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Patent number: 8263038Abstract: A method for controlling volatiles in recycled carbon black, such as from pyrolysis of tires, includes deagglomerating the recycled carbon black to substantially reduce the carbon black particle size and impinging an air current on the carbon black particles, preferably in a countercurrent direction, to increase the processing temperature and thereby enhance the release of volatiles. Associated apparatus is disclosed.Type: GrantFiled: March 7, 2007Date of Patent: September 11, 2012Assignee: Delta-energy Holdings, LLCInventors: Daniel Steinmeyer, Alan Levine, Duane Erickson
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Patent number: 8246928Abstract: Embodiments herein describe a composition including at least one water-soluble complex having a water-soluble separation agent including a planar portion, at least one pi electron on the planar portion and at least one electron withdrawing group; and a semiconducting single-walled carbon nanotube in an aqueous solution. Further embodiments describe a method of separating metallic single-walled carbon nanotubes and semiconducting single-walled carbon nanotubes including providing carbon nanotubes having an admixture of semiconducting single-walled carbon nanotubes and metallic single-walled carbon nanotubes; and combining the admixture with a water-soluble separation agent in an aqueous solution to form a mixture, in which the water-soluble separation agent includes a planar portion, at least one pi electron on the planar portion and at least one electron withdrawing group.Type: GrantFiled: April 1, 2011Date of Patent: August 21, 2012Assignee: Jawaharlal Nehru Centre for Advanced Scientific ResearchInventors: Chintamani Nagesa Ramachandra Rao, Subi Jacob George, Rakesh Voggu, K. Venkata Rao
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Patent number: 8236275Abstract: Provided is a production process for a carbon material comprising an alkali activation reaction step in which a carbon precursor containing an activator selected from alkali metal compounds is heated under flow of inert gas. The above alkali activation reaction is carried out while allowing carbon dioxide gas to flow into a downstream part of an alkali activation reaction region on the condition that the carbon dioxide gas is not substantially brought into contact with the carbon precursor and the activator. This makes it possible to carry out alkali activation treatment safely and stably and obtain a carbon material useful for producing an electric double layer capacitor electrode having a high electrostatic capacity.Type: GrantFiled: April 27, 2006Date of Patent: August 7, 2012Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Takuo Ohshida, Koichi Kanno
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Patent number: 8221715Abstract: A compound containing at least two pyridinium derivatives in its molecular structure and being in a reduced form thereof may be used as a CNT n-doping material. The compound may donate electrons spontaneously to CNTs to n-dope the CNTs, while being oxidized into its stable state. An n-doped CNT that is doped with the CNT n-doping material may maintain a stable n-doped state for a long time without being dedoped even in the air and/or water. Further, the n-doped state may be easily controlled when using the CNT n-doping material.Type: GrantFiled: May 7, 2009Date of Patent: July 17, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Hyeon Jin Shin, Young Hee Lee, Jaeyoung Choi, Seonmi Yoon, Soo Min Kim
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Publication number: 20120177563Abstract: The Invention relates to an apparatus or installation for producing active carbon, in particular by carbonization and subsequent activation of polymeric, organic, preferably sulphonated, starting materials, wherein the apparatus or installation comprises optionally a drying device for drying the starting materials, optionally a sulphonating device, arranged downstream of the optionally present drying device, for sulphonating and/or peptizing the optionally previously dried starting materials, a carbonizing device, arranged downstream of the optionally present drying device and/or the optionally present sulphonating device, for carbonizing the optionally previously dried and/or sulphonated and/or peptized starting materials, as well as an activating device, arranged downstream of the carbonizing device, for activating the starting materials previously carbonized in the carbonizing device, wherein the apparatus or installation also comprises at least one exhaust-gas treatment device for treating the exhaust gasType: ApplicationFiled: October 6, 2009Publication date: July 12, 2012Applicant: BLUCHER GMBHInventors: Hasso von Blucher, Raik Schönfeld
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Patent number: 8216541Abstract: The present invention provides a process for producing nano graphene platelets (NGPs) that are both dispersible and electrically conducting. The process comprises: (a) preparing a pristine NGP material from a graphitic material; and (b) subjecting the pristine NGP material to an oxidation treatment to obtain the dispersible NGP material, wherein the NGP material has an oxygen content no greater than 25% by weight. Conductive NGPs can find applications in transparent electrodes for solar cells or flat panel displays, additives for battery and supercapacitor electrodes, conductive nanocomposite for electromagnetic wave interference (EMI) shielding and static charge dissipation, etc.Type: GrantFiled: September 3, 2008Date of Patent: July 10, 2012Assignee: Nanotek Instruments, Inc.Inventors: Bor Z. Jang, Aruna Zhamu
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Patent number: 8206624Abstract: A method for producing carbon nanotubes uses a polymer as a raw material to undergo in situ thermal decomposition. The method includes steps of mixing the polymer and metallic catalyst through a multiple heating stage process of in-situ thermal decomposition to carbonize the polymer and release carbon elements to produce carbon nanotubes. Advantages of the present invention include easy to prepare, low temperature in manipulation, low production cost, and high safety.Type: GrantFiled: February 7, 2009Date of Patent: June 26, 2012Assignee: National Chung Cheng UniversityInventors: Yuan-Yao Li, Chao-Wei Huang
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Patent number: 8197787Abstract: A method includes producing an isolation atmosphere in a phase changing area above a reactant liquid and then injecting a feed material into the reactant liquid. The feed material includes a carbon-bearing material. The method further includes maintaining the molecules of the injected carbon-bearing material and any reaction products in contact with the reactant liquid for a period of time sufficient to liberate carbon atoms from the carbon-bearing material or reaction products from that material, and place the liberated carbon atoms in an excited state. Liberated carbon atoms in the excited state are then allowed to traverse a surface of the reactant liquid and flow along a particle formation path through the phase changing area so that the liberated carbon atoms may phase change to the ground state while suspended in the phase changing area.Type: GrantFiled: September 14, 2009Date of Patent: June 12, 2012Assignee: Clean Technology International CorporationInventor: Anthony S. Wagner
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Patent number: 8197788Abstract: The present invention provides a raw coke having such a structure that the graphitized product resulting from graphitization of the raw coke at a temperature of 2800° C. under an inactive gas atmosphere will have ratios of the crystallite size to the lattice constant of 360 or less in the (002) plane and 1500 or less in the (110) plane, as a raw coke providing active carbon produced by alkali-activating the raw coke, which is reduced in remaining alkali content and can simplify washing operation because washing liquid can easily pass through the activated carbon, or as a raw coke for the production of needle coke.Type: GrantFiled: June 10, 2011Date of Patent: June 12, 2012Assignees: Nippon Oil Corporation, Nippon Petroleum Refining Company, LimitedInventors: Takashi Oyama, Kazuhisa Nakanishi, Tamotsu Tano, Keiji Higashi, Ippei Fujinaga, Hiromitsu Hashisaka, Toshitaka Fujii, Takashi Noro, Akio Sakamoto, Kiwamu Takeshita, Keizou Ikai, Masaki Fujii, Hideki Ono
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Patent number: 8197790Abstract: A method of making a filter material for producing potable water comprises providing activated carbon particles, depositing one or more nanofilament precursors at least partially onto the surface of the activated carbon particles, agitating the activated carbon particles and deposited nanofilament precursors in the presence of carbonaceous vapor, and heating the activated carbon particles and the deposited nanofilament precursors in the presence of carbonaceous vapor at a temperature and time sufficient to produce the filter material comprising activated carbon particles having carbon nanofilaments on the surface of the particles.Type: GrantFiled: April 13, 2009Date of Patent: June 12, 2012Assignee: PUR Water Purification Products, Inc.Inventors: Michael Donovan Mitchell, Dimitris Ioannis Collias
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Patent number: 8192712Abstract: A method for producing carbon using less thermal energy is disclosed. Crystalline cellulose and acidic electrolyzed water are introduced into a reaction vessel. The mixture is heated until it reaches a predetermined temperature (230° C. to 250° C.) while being stirred. When the mixture reached the predetermined temperature, this temperature is maintained, and the mixture is kept heated while being stirred for a predetermined period of time (30 minutes). Thereby, carbon is produced in the reaction vessel.Type: GrantFiled: April 13, 2011Date of Patent: June 5, 2012Assignee: Honda Motor Co., Ltd.Inventor: Kohichi Miyashita
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Publication number: 20120135224Abstract: Systems and methods for the formation of carbon-based nanostructures using large-scale active growth structures are generally described. In addition, systems and methods related to the formation of carbon-based nanostructures using basalt and/or titanium (e.g., elemental titanium) are generally described. The carbon-based nanostructures can be grown by exposing the large-scale active growth structures, basalt, and/or titanium to a set of conditions selected to cause formation of carbon-based nanostructures on (e.g., directly on) the large-scale active growth structure, basalt, and/or titanium. When basalt and/or titanium are used as all or part of an active growth structure, the basalt and/or titanium can be in any suitable form such as, for example, a planar or non-planar active growth structure (which can have, in some cases, a first cross-sectional dimension of at least about 1 mm) comprising basalt and/or titanium (e.g., a fiber comprising basalt and/or titanium) and/or particles (e.g.Type: ApplicationFiled: October 28, 2011Publication date: May 31, 2012Applicant: Massachusetts Institute of TechnologyInventors: Roberto Guzman de Villoria, Brian L. Wardle
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Patent number: 8178466Abstract: The present disclosure provides methods for pre-treating activated carbon before it is used in a dehydrochlorination process. The methods can comprise mixing the activated carbon with an acid, an oxidizing agent in a liquid phase, or an oxidizing agent in a gas phase. Activated carbons undergoing one or more of these methods can exhibit improved stability during the dehydrochlorination process.Type: GrantFiled: January 14, 2011Date of Patent: May 15, 2012Assignee: Honeywell International Inc.Inventors: Haiyou Wang, Hsueh S. Tung
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Patent number: 8173096Abstract: A carbon nanosphere has at least one opening. The carbon nanosphere is obtained by preparing a carbon nanosphere and treating it with an acid to form the opening. The carbon nanosphere with at least one opening has higher utilization of a surface area and electrical conductivity and lower mass transfer resistance than a conventional carbon nanotube, thus allowing for higher current density and cell voltage with a smaller amount of metal catalyst per unit area of a fuel cell electrode.Type: GrantFiled: October 25, 2010Date of Patent: May 8, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Hyuk Chang, Chan-ho Pak, Jian Nong Wang
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Publication number: 20120082614Abstract: There is provided a fabrication method for an AA stacked graphene-diamond hybrid material by converting, through a high temperature treatment on diamond, a diamond surface into graphene. According to the present invention, if various types of diamond are maintained at a certain temperature having a stable graphene phase (approximately greater than 1200° C.) in a hydrogen gas atmosphere, two diamond {111} lattice planes are converted into one graphene plate (2:1 conversion), whereby the diamond surface is converted into graphene in a certain thickness, thus to fabricate the AA stacked graphene-diamond hybrid material.Type: ApplicationFiled: December 12, 2011Publication date: April 5, 2012Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Jae-Kap LEE, So-Hyung LEE, Seung-Cheol LEE, Jae-Pyoung AHN, Jeon-Kook LEE, Wook-Seong LEE
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Patent number: 8137652Abstract: The invention provides a method of functionalizing the sidewalls of a plurality of carbon nanotubes with oxygen moieties, the method comprising: exposing a carbon nanotube dispersion to an ozone/oxygen mixture to form a plurality of ozonized carbon nanotubes; and contacting the plurality of ozonized carbon nanotubes with a cleaving agent to form a plurality of sidewall-functionalized carbon nanotubes.Type: GrantFiled: June 27, 2006Date of Patent: March 20, 2012Assignee: The Research Foundation of State University of New YorkInventors: Stanislaus S. Wong, Sarbajit Banerjee
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Publication number: 20120049127Abstract: The present invention is directed to a fluoropolymer tape having an electrically conductive surface. More specifically, the present invention is directed to a polytetrafluoroethylene (PTFE) tape and method for producing an electrically conductive tape by blending vapor-grown carbon fiber or carbon nanotubes or combinations of both with PTFE.Type: ApplicationFiled: November 4, 2011Publication date: March 1, 2012Applicant: COMPAGNIE PLASTIC OMNIUMInventors: Jiaxiang Ren, Bernd Schulte-Ladbeck
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Patent number: 8119555Abstract: The invention provides a method of increasing the mesopore volume of a porous activated carbon, comprising coating a porous activated carbon with a metal oxide or metal oxide precursor to form a treated activated carbon; and calcining the treated activated carbon, in a dry atmosphere, for a time and at a temperature sufficient to increase the mesopore volume of the treated activated carbon. The invention also provides an activated carbon having a total mesopore volume of at least about 0.10 cc/g and less than about 0.25 cc/g, and a percentage of mesopore volume per total pore volume of at least about 15% and less than about 35%. Activated carbon modified according to the invention, cigarette filters incorporating such activated carbon, and smoking articles made with such filters are included in the invention.Type: GrantFiled: November 20, 2008Date of Patent: February 21, 2012Assignee: R. J. Reynolds Tobacco CompanyInventors: Chandra Kumar Banerjee, Stephen Benson Sears, Thaddeus Jude Jackson
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Patent number: 8114373Abstract: Disclosed is a method of exfoliating a layered material (e.g., graphite and graphite oxide) to produce nano-scaled platelets having a thickness smaller than 100 nm, typically smaller than 10 nm, and often between 0.34 nm and 1.02 nm. The method comprises: (a) subjecting the layered material in a powder form to a halogen vapor at a first temperature above the melting point or sublimation point of the halogen at a sufficient vapor pressure and for a duration of time sufficient to cause the halogen molecules to penetrate an interlayer space of the layered material, forming a stable halogen-intercalated compound; and (b) heating the halogen-intercalated compound at a second temperature above the boiling point of the halogen, allowing halogen atoms or molecules residing in the interlayer space to exfoliate the layered material to produce the platelets.Type: GrantFiled: January 4, 2011Date of Patent: February 14, 2012Inventors: Bor Z. Jang, Aruna Zhamu
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Patent number: 8114375Abstract: The present invention provides a process for producing nano graphene platelets (NGPs) that are dispersible and conducting. The process comprises: (a) preparing a graphite intercalation compound (GIC) or graphite oxide (GO) from a laminar graphite material; (b) exposing the GIC or GO to a first temperature for a first period of time to obtain exfoliated graphite; and (c) exposing the exfoliated graphite to a second temperature in a protective atmosphere for a second period of time to obtain the desired dispersible nano graphene platelet with an oxygen content no greater than 25% by weight, preferably below 20% by weight, further preferably between 5% and 20% by weight. Conductive NGPs can find applications in transparent electrodes for solar cells or flat panel displays, additives for battery and supercapacitor electrodes, conductive nanocomposite for electromagnetic wave interference (EMI) shielding and static charge dissipation, etc.Type: GrantFiled: September 3, 2008Date of Patent: February 14, 2012Assignee: Nanotek Instruments, Inc.Inventors: Bor Z. Jang, Aruna Zhamu
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Patent number: 8105512Abstract: An infiltrated carbon foam composite and method for making the composite is described. The infiltrated carbon foam composite may include a carbonized carbon aerogel in cells of a carbon foam body and a resin is infiltrated into the carbon foam body filling the cells of the carbon foam body and spaces around the carbonized carbon aerogel. The infiltrated carbon foam composites may be useful for mid-density ablative thermal protection systems.Type: GrantFiled: July 21, 2009Date of Patent: January 31, 2012Assignee: Touchstone Research Laboratory, Ltd.Inventors: Rick D. Lucas, Harry E. Danford, Janusz W. Plucinski, Douglas J. Merriman, Jesse M. Blacker
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Publication number: 20120009115Abstract: Cohesive assemblies comprising carbon are prepared by obtaining carbon in the form of powder, particles, flakes, or loose agglomerates, dispersing the carbon in a liquid halogen by mechanical mixing and/or sonication, and substantially removing the liquid halogen, typically by evaporation, whereby the cohesive assembly of carbon is formed. The method is especially suitable for preparing free-standing, monolithic assemblies of carbon nanotubes in the form of films, wafers, or discs, having high carbon packing density and low electrical resistivity. The assemblies have various potential applications, such as electrodes in batteries or supercapacitors or as electromagnetic interference shielding materials.Type: ApplicationFiled: September 2, 2011Publication date: January 12, 2012Inventors: Leonid Grigorian, Steven Colbern, Sean Imtiaz Brahim
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Publication number: 20110318258Abstract: A method for making a carbon nanotube structure is introduced. The method includes the following steps. A carbon nanotube precursor including a number of carbon nanotubes is provided. The carbon nanotube precursor is placed in a chamber with low oxygen environment. The carbon nanotube precursor is heated in the chamber.Type: ApplicationFiled: December 6, 2010Publication date: December 29, 2011Applicants: HON HAI PRECISION INDUSTRY CO., LTD., TSINGHUA UNIVERSITYInventors: KAI LIU, KAI-LI JIANG, YING-HUI SUN, SHOU-SHAN FAN
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Patent number: 8084012Abstract: The present invention provides a method for selectively placing carbon nanotubes on a substrate surface by using functionalized carbon nanotubes having an organic compound that is covalently bonded to such carbon nanotubes. The organic compound comprises at least two functional groups, the first of which is capable of forming covalent bonds with carbon nanotubes, and the second of which is capable of selectively bonding metal oxides. Such functionalized carbon nanotubes are contacted with a substrate surface that has at least one portion containing a metal oxide. The second functional group of the organic compound selectively bonds to the metal oxide, so as to selectively place the functionalized carbon nanotubes on the at least one portion of the substrate surface that comprises the metal oxide.Type: GrantFiled: August 14, 2009Date of Patent: December 27, 2011Assignee: International Business Machines CorporationInventors: Alina Afzali-Ardakani, Phaedon Avouris, James B. Hannon, Christian Klinke
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Patent number: 8084097Abstract: A method of preparing a silicone resin film comprising coating a release liner with a nanomaterial-filled silicone composition comprising (i) a free radical-curable silicone composition comprising a silicone resin and (ii) a carbon nanomaterial, and curing the silicone resin of the coated release liner; a silicone resin film prepared according to the preceding method; and a nanomaterial-filled silicone composition.Type: GrantFiled: January 11, 2007Date of Patent: December 27, 2011Assignee: Dow Corning CorporationInventors: Mark Fisher, Bizhong Zhu
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Publication number: 20110311431Abstract: A crystalline carbon material with controlled interlayer spacing and a method of manufacturing the crystalline carbon material are disclosed. The crystalline carbon material has peaks of a (002) plane at 2?=23°±5.0° and 2?=26.5°±1.0° when X-ray diffraction is measured using a CuK? ray. The peak height at 2?=23°±5.0° is higher than the one at 2?=26.5°±1.0°.Type: ApplicationFiled: January 12, 2011Publication date: December 22, 2011Applicant: SAMSUNG SDI CO., LTD.Inventors: Bok-Hyun Ka, Kyeu-Yoon Sheem, Da-Un Han, Hyun-Uk Jo, Sumihito Ishida, Eui-Hwan Song
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Publication number: 20110311432Abstract: A method for manufacturing graphene is disclosed, which comprises the following steps: putting graphite material and an organic solvent, a surfactant, or a combination thereof in a reaction tank and introducing a supercritical fluid in the reaction tank to allow the organic solvent, the surfactant, or the combination thereof to dissolve in the supercritical fluid and to permeate into the graphite material; and removing the supercritical fluid by depressurization to form graphene. The method of the present invention has simple steps and reduced consumption of manufacturing time, and also can promote the quality of the resultant graphene in large-scale manufacturing.Type: ApplicationFiled: June 18, 2010Publication date: December 22, 2011Inventors: Nen-Wen Pu, Chung An Wang, Yuh Sung, Ming-Der Ger
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Patent number: 8080127Abstract: A carbon foam evaporator is described which can be used in a wide variety of operating conditions. The evaporator utilizes a carbon foam with a bi-model pore distribution. The carbon foam is thermally stable up to temperatures of at least 300° C., is rigid, and has a compressive strength of at least 100 psi. The carbon foam is also resistant to chemical attacks.Type: GrantFiled: April 15, 2007Date of Patent: December 20, 2011Assignee: GrafTech International Holdings Inc.Inventor: Chong Chen
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Patent number: 8075793Abstract: A process of preparing magnetic graphitic materials from graphite in a second container (3) that reacts with one of more transition metal oxide and in a first container (2) at a volume ratio of 1:1, in a closed reactor (1), heated up to a temperature between 600° C. and the melting temperature of the transition oxide (s) for 6 to 36 hours, under a pressure of 10 atmospheres with the help of a transfer inert gas through an inlet (5) and vacuum between 10?2 torr to 10?7 torr through an outlet (6), obtaining at the end of the process a graphitic material with long-lasting magnetic properties at room temperature. The material obtained exhibits a complex structure, with pores, bunches, pilings and edges of exposed graphenes and finds application in nanotechnology, magnetic images in medical science, applications in communication, electronics, sensors, even biosensors, catalysis or separation of magnetic materials.Type: GrantFiled: June 15, 2005Date of Patent: December 13, 2011Assignee: Universidade Federal De Sao CarlosInventors: Fernando Manuel Araújo Moreira, Helena Pardo Minetti, Álvaro Washington Mombrú Rodriguez
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Patent number: 8057901Abstract: The invention relates to a carbon nanotube composite material, to methods of its production and to uses of such composite material.Type: GrantFiled: May 13, 2005Date of Patent: November 15, 2011Assignee: Sony Deutschland GmbHInventors: William E. Ford, Jurina Wessels, Akio Yasuda, Jack Barger
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Patent number: 8052952Abstract: Provided is a nanotube-polymer composite which can effectively utilize characteristics of a carbon nanotube structure. The composite includes a carbon nanotube structure and a polymer, in which: the carbon nanotube structure has a network structure constructed by mutually cross-linking functional groups bonded to multiple carbon nanotubes through chemical bonding of the functional groups together; and the polymer is filled in the network structure.Type: GrantFiled: February 1, 2010Date of Patent: November 8, 2011Assignee: Fuji Xerox Co., Ltd.Inventors: Miho Watanabe, Kentaro Kishi, Chikara Manabe, Kazunori Anazawa, Masaki Hirakata, Taishi Shigematsu, Hiroyuki Watanabe, Takashi Isozaki, Shigeki Ooma, Shinsuke Okada
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Patent number: 8052918Abstract: A method of producing a carbon-based material having an activated surface includes: (a) mixing an elastomer and a carbon material, and dispersing the carbon material by applying a shear force to obtain a composite elastomer; and (b) heat-treating the composite elastomer at a temperature for vaporising an elastomer to vaporize the elastomer in the composite elastomer.Type: GrantFiled: July 19, 2005Date of Patent: November 8, 2011Assignee: Nissin Kogyo Co., Ltd.Inventors: Akira Magario, Toru Noguchi
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Patent number: 8029758Abstract: There is provided a process for producing single-walled carbon nanotubes with an increased diameter, characterized in that it comprises a diameter-increasing treatment step of heating carbon nanotubes of a raw material at a degree of vacuum of 1.3×10?2 Pa or below and at a temperature ranging from 1500 to 2000° C., preferably 1700 to 2000° C.Type: GrantFiled: December 4, 2006Date of Patent: October 4, 2011Assignee: Toyota Jidosha Kabushiki KaishaInventors: Kyoichi Tange, Shizuka Takeuchi, Jiro Mizuno
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Publication number: 20110189078Abstract: An apparatus for continuous high temperature gas treatment of particulate matter including a starting material supply port (1) through which starting particulate matter is supplied from an upper part of the apparatus; a treatment, gas supply port (2) through which a treating gas is supplied; a product discharge port (3) through which a product after treatment is discharged from a lower part of the apparatus; a treatment chamber (4) in which the particulate matter is treated with the treatment gas; a gas-solid separation chamber (5) provided in fluid communication with an upper part of the treatment chamber (4); and a cooling chamber (6) provided in fluid communication with a lower part of the treatment chamber (4). A heater (7) is provided on the outer periphery of the upper part of the treatment chamber (4), and a cooler (8) is provided on the outer periphery of the cooling chamber (6).Type: ApplicationFiled: March 30, 2011Publication date: August 4, 2011Inventors: Hiroaki OHASHI, Masaru Kagoshima, Yoshiki Shigaki
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Patent number: 7985324Abstract: A system and method for treating unmarketable fly ash and improve its properties as an additive for concrete is disclosed. The method includes the steps of creating a gas stream containing ionized air through a plasma reactor and exposing an amount of fly ash containing carbon to the ionized air while in the reactor. The exposure of the carbon to the ionized air promotes the attachment of the ions to the carbon to reduce the adsorption capacity of the carbon.Type: GrantFiled: October 16, 2007Date of Patent: July 26, 2011Assignee: Matrix LLCInventor: John G. Whellock
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Patent number: 7981835Abstract: A system and method for producing activated carbon comprising carbonizing a solid carbonaceous material in a carbonization zone of an activated carbon production apparatus (ACPA) to yield a carbonized product and carbonization product gases, the carbonization zone comprising carbonaceous material inlet, char outlet and carbonization gas outlet; activating the carbonized product via activation with steam in an activation zone of the ACPA to yield activated carbon and activation product gases, the activation zone comprising activated carbon outlet, activation gas outlet, and activation steam inlet; and utilizing process gas comprising at least a portion of the carbonization product gases or a combustion product thereof; at least a portion of the activation product gases or a combustion product thereof; or a combination thereof in a solid fuel boiler system that burns a solid fuel boiler feed with air to produce boiler-produced steam and flue gas, the boiler upstream of an air heater within a steam/electricity gType: GrantFiled: May 14, 2008Date of Patent: July 19, 2011Assignee: Energy & Environmental Research Center FoundationInventors: Srivats Srinivasachar, Steven Benson, Charlene Crocker, Jill Mackenzie
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Patent number: 7981395Abstract: A negative electrode carbon material for a lithium ion secondary battery manufactured by calcinating a rice starch portion obtained by removing the pericarp and tests from unpolished rice and a method for manufacturing the same. The rice starch portion is preferably middle-grade white bran or high-grade white bran each obtained when unpolished rice is polished. The above negative electrode carbon material may have a relatively broad peak at a 2? of 40 to 50° and a sharp peak at a 2? of 42 to 44° in its powder X-ray (CuK?) diffraction. According to the present invention, a negative electrode carbon material for a lithium ion secondary battery which has the same quality as the prior art product can be manufactured at a low cost by making effective use of middle-grade white bran or high-grade white bran of rice.Type: GrantFiled: January 12, 2006Date of Patent: July 19, 2011Assignee: Enax, Inc.Inventors: Shoji Sasaki, Tsuyoshi Temma, Munehiro Kadowaki, Hironori Ozawa, Kazunori Ozawa, Syujun Shikano, Kanji Matsuda
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Patent number: 7976816Abstract: A method for functionalizing the wall of single-wall or multi-wall carbon nanotubes involves the use of acyl peroxides to generate carbon-centered free radicals. The method allows for the chemical attachment of a variety of functional groups to the wall or end cap of carbon nanotubes through covalent carbon bonds without destroying the wall or endcap structure of the nanotube. Carbon-centered radicals generated from acyl peroxides can have terminal functional groups that provide sites for further reaction with other compounds. Organic groups with terminal carboxylic acid functionality can be converted to an acyl chloride and further reacted with an amine to form an amide or with a diamine to form an amide with terminal amine. The reactive functional groups attached to the nanotubes provide improved solvent dispersibility and provide reaction sites for monomers for incorporation in polymer structures. The nanotubes can also be functionalized by generating free radicals from organic sulfoxides.Type: GrantFiled: May 12, 2010Date of Patent: July 12, 2011Assignee: William Marsh Rice UniversityInventors: Valery N. Khabashesku, Haiqing Peng, John L. Margrave, Mary Lou Margrave, legal representative, Wilbur Edward Billups, Yunming Ying
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Patent number: 7968073Abstract: Methods of producing stable dispersions of single-walled carbon nanotube structures in solutions are achieved utilizing dispersal agents. The dispersal agents are effective in substantially solubilizing and dispersing single-walled carbon nanotube structures in aqueous solutions by coating the structures and increasing the surface interaction between the structures and water. Exemplary agents suitable for dispersing nanotube structures in aqueous solutions include synthetic and natural detergents having high surfactant properties, deoxycholates, cyclodextrins, chaotropic salts and ion pairing agents. The dispersed nanotube structures may further be deposited on a suitable surface in isolated and individualized form to facilitate easy characterization and further processing of the structures.Type: GrantFiled: November 2, 2004Date of Patent: June 28, 2011Assignee: Battelle Memorial InstituteInventors: Mark S. F. Clarke, Daniel L. Feeback
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Patent number: 7964173Abstract: The present invention provides feedstock compositions for use of the production of an activated carbon for electric double layer capacitor electrodes or the production of needle coke, comprising a first heavy oil with an initial boiling point of 300° C. or higher, an asphalten content of 12 percent by mass or less, a saturate content of 50 percent by mass or more and a sulfur content of 0.3 percent by mass or less, produced as a residue resulting from vacuum-distillation of a petroleum-based oil and a second heavy oil with an initial boiling point of 150° C. or higher and a sulfur content of 0.5 percent by mass or less, produced by subjecting a hydrocarbon oil to fluidized catalytic cracking.Type: GrantFiled: December 27, 2006Date of Patent: June 21, 2011Assignees: Nippon Oil Corporation, Nippon Petroleum Refining Company, LimitedInventors: Takashi Oyama, Kazuhisa Nakanishi, Tamotsu Tano, Keiji Higashi, Ippei Fujinaga, Hiromitsu Hashisaka, Kiwamu Takeshita, Masaki Fujii, Hideki Ono
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Patent number: 7959888Abstract: The present invention provides a raw coke having such a structure that the graphitized product resulting from graphitization of the raw coke at a temperature of 2800° C. under an inactive gas atmosphere will have ratios of the crystallite size to the lattice constant of 360 or less in the (002) plane and 1500 or less in the (110) plane, as a raw coke providing active carbon produced by alkali-activating the raw coke, which is reduced in remaining alkali content and can simplify washing operation because washing liquid can easily pass through the activated carbon, or as a raw coke for the production of needle coke.Type: GrantFiled: December 27, 2006Date of Patent: June 14, 2011Assignees: Nippon Oil Corporation, Nippon Petroleum Refining Company, LimitedInventors: Takashi Oyama, Kazuhisa Nakanishi, Tamotsu Tano, Keiji Higashi, Ippei Fujinaga, Hiromitsu Hashisaka, Toshitaka Fujii, Takashi Noro, Akio Sakamoto, Kiwamu Takeshita, Keizou Ikai, Masaki Fujii, Hideki Ono
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Publication number: 20110112339Abstract: The present disclosure provides methods for pre-treating activated carbon before it is used in a dehydrochlorination process. The methods can comprise mixing the activated carbon with an acid, an oxidizing agent in a liquid phase, or an oxidizing agent in a gas phase. Activated carbons undergoing one or more of these methods can exhibit improved stability during the dehydrochlorination process.Type: ApplicationFiled: January 14, 2011Publication date: May 12, 2011Applicant: HONEYWELL INTERNATIONAL INC.Inventors: HAIYOU WANG, HSUEH SUNG TUNG
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Patent number: 7939595Abstract: A method for reducing cure shrinkage of a thermoset resin includes forming a plurality of surface modified nanofibers. The surface modified nanofibers are formed by soaking nanofibers in an oxidizing acidic solvent. An oxidizing agent is added to the soaking nanofibers, thereby generating heat sufficient for at least one of in-situ oxidation and in-situ exfoliation of a subsurface of each of the nanofibers. Excess oxidizing agent and acidic solvent are removed from the nanofibers, which are then dried. The dried nanofibers have reduced surface hydrophobicity. The surface modified nanofibers are substantially uniformly dispersed into the thermoset resin. The surface modified nanofibers are adapted to reduce cure shrinkage of the thermoset resin during subsequent curing processes.Type: GrantFiled: August 14, 2009Date of Patent: May 10, 2011Assignee: GM Global Technology Operations LLCInventors: Gholam-Abbas Nazri, Chen-Shih Wang