Zinc Patents (Class 423/622)
  • Publication number: 20100144088
    Abstract: Provided is a method for forming a metal oxide. A method for forming a metal oxide according to embodiments of the present invention includes preparing a metal oxide precursor solution including a dopant chemical species, preparing an alcohol-based solution including a basic chemical species, reacting the alcohol-based solution with the metal oxide precursor solution to form a reactant, and purifying the reactant to form a metal oxide.
    Type: Application
    Filed: December 4, 2009
    Publication date: June 10, 2010
    Applicant: ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTE
    Inventors: Jiyoung Oh, Jonghyurk Park, Seung Youl Kang, Chul Am Kim, In-Kyu You, Kyoung Ik Cho
  • Patent number: 7713912
    Abstract: The present invention relates to a nano-sized photocatalytic sol and application thereof. The invention utilizes spherical nano-photocatalyst and non-spherical photocatalytic sol for coating a photocatalyst layer on a substrate. Because of the stereo, interlaced and composite structure between spherical photocatalyst and non-spherical photocatalyst, a hard and well adhesion coated layer of photocatalyst with good photocatalytic activity can be obtained without using binder.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: May 11, 2010
    Assignee: Industrial Technology Research Institute
    Inventors: Chia-Hung Huang, Yao-Ling Huang, Yao-Hsuan Tseng, Yu-Ming Lin, Shu-Ling Liu
  • Patent number: 7708974
    Abstract: Nanoparticles comprising tungsten, methods of manufacturing nanoparticles comprising tungsten, and applications of nanoparticles comprising tungsten, such as electronics, optical devices, photonics, reagents for fine chemical synthesis, pigments, and catalysts are provided.
    Type: Grant
    Filed: May 10, 2005
    Date of Patent: May 4, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Tapesh Yadav
  • Patent number: 7708975
    Abstract: There is described a process for preparing metal oxide particles which are substantially free of coarse tail from an oxidizing agent and a vaporous metal reactant in a flow reactor; comprising, (a) directing a flow of the metal reactant into a contacting region of the flow reactor; comprising (a) passing a flow of oxidizing agent through a high temperature zone of the flow reactor to form a flow of hot oxidizing agent and directing the flow of the hot oxidizing agent onto the contacting region of the flow reactor at a flow condition sufficient to form a reaction stream comprising a flow of hot oxidizing agent, a flow of metal reactant and a diffusive flow of the hot oxidizing agent and the metal reactant, the temperature of the hot oxidizing agent being at least sufficient to initiate oxidation of the metal reactant in the diffusive flow; (c) passing the reaction stream into a reaction zone of the flow reactor, while simultaneously introducing a flow of an upper cooling fluid substantially coaxially with the
    Type: Grant
    Filed: July 18, 2005
    Date of Patent: May 4, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Juergen Kurt Plischke, Stephan Claude de la Veaux, Scott Rickbeil Frerichs, Jodi Lynn Witt, Christian Normand
  • Patent number: 7691910
    Abstract: There is provided an acidic zirconia sol having compatibility of particle properties and binding properties, and a production method of the same. The present invention relates to a production method of an acidic zirconia sol containing zirconia particles having a particle diameter of less than 20 nm in a content of 10 to 50% by mass, based on the mass of all zirconia particles including: a first process in which an alkaline zirconia sol (A) and a zirconium salt (B) are mixed in a mass ratio (Bs/As) ranging from 0.2 to 5.0 of a mass of a solid content (Bs) which is converted into an amount of ZrO2 in the zirconium salt (B) to a mass of a solid content (As) which is converted into an amount of ZrO2 in the alkaline zirconia sol (A); and a second process in which the resultant mixture is reacted at 80 to 250° C. to produce an acidic zirconia sol.
    Type: Grant
    Filed: April 11, 2006
    Date of Patent: April 6, 2010
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yutaka Ohmori, Hirokazu Kato, Kenji Yamaguchi
  • Patent number: 7691353
    Abstract: Low dielectric constant group II-VI compounds, such as zinc oxide, and fabrication methods are disclosed. Low dielectric constant insulator materials are fabricated by doping zinc oxide with at least one mole % p-type dopant ion. Low dielectric constant zinc oxide insulator materials are fabricated by doping zinc oxide with silicon having a concentration of at least 1017 atoms/cm3. Low dielectric zinc oxide insulator materials are fabricated by doping zinc oxide with a dopant ion having a concentration of at least about 1018 atoms/cm3, followed by heating to a temperature which converts the zinc oxide to an insulator. The temperature varies depending upon the choice of dopant. For arsenic, the temperature is at least about 450° C.; for antimony, the temperature is at least about 650° C. The dielectric constant of zinc oxide semiconductor is lowered by doping zinc oxide with a dopant ion at a concentration at least about 1018 to about 1019 atoms/cm3.
    Type: Grant
    Filed: June 17, 2005
    Date of Patent: April 6, 2010
    Inventors: Robert H. Burgener, II, Roger L. Felix, Gary M. Renlund
  • Publication number: 20100074837
    Abstract: It is to provide a production method of zinc oxide powder excellent in UV protection ability and transparency and to provide cosmetics containing the same. The fine particle zinc oxide powder is produced by subjecting either an aqueous solution containing both a water-soluble zinc salt and a carboxylic acid or an aqueous solution containing a water-soluble zinc carboxylate to pH adjustment with an alkali carbonate agent and aging the resulting mixture without calcining. The alkali carbonate agent may be 0.1 to 2 mol/L aqueous solution and the carboxylate group is 1 to 5 times in moles with respect to zinc. The pH adjustment can be carried out by dropwise addition of the alkali carbonate aqueous solution at 0.5 to 5 mL/min per 100 mL of either the aqueous solution containing both the water-soluble zinc salt and the carboxylic acid or the aqueous solution containing the water-soluble zinc carboxylate.
    Type: Application
    Filed: November 22, 2007
    Publication date: March 25, 2010
    Applicant: SHISEIDO COMPANY LTD.
    Inventors: Shoichiro Shio, Atsushi Nakahira, Hideaki Murase
  • Publication number: 20100055016
    Abstract: Provided is a method of manufacturing oxide-based nano-structured materials using a chemical wet process, and thus, the method can be employed to manufacture oxide-based nano-structured materials having uniform composition and good electrical characteristics in large quantities, the method having a relatively simple process which does not use large growing equipment. The method includes preparing a first organic solution that comprises a metal, mixing the first organic solution with a second organic solution that contains hydroxyl radicals (—OH), filtering the mixed solution using a filter in order to extract oxide-based nano-structured materials formed in the mixed solution, drying the extracted oxide-based nano-structured materials to remove any remaining organic solution, and heat treating the dried oxide-based nano-structured materials.
    Type: Application
    Filed: February 1, 2008
    Publication date: March 4, 2010
    Inventors: Sang-Hyeob Kim, Hye-Jin Myoung, Sung-Lyul Maeng, G.A.J. Amaratunga, Sunyoung Lee
  • Publication number: 20100051583
    Abstract: Disclosed herein is a method for preparing a porous material using nanostructures. The method comprises the steps of producing nanostructures using a porous template, dispersing the nanostructures in a source or precursor material for the porous material, aligning the nanostructures in a particular direction, and removing the nanostructures by etching. According to the method, the size, shape, orientation and regularity of pores of the porous material can be easily controlled, and the preparation of the porous material is simplified, leading to a reduction in preparation costs. Further disclosed is a porous material prepared by the method.
    Type: Application
    Filed: May 31, 2006
    Publication date: March 4, 2010
    Inventors: Kyung Sang Cho, Byoung Lyong Choi, Eun Kyung Lee, Soon Jae Kwon, Jae Ho Lee
  • Publication number: 20100047191
    Abstract: The use of an oral care composition comprising particulate zinc oxide (suitably in nanoparticulate form) optionally in the presence of a source of fluoride ions is described for combating dental erosion and/or tooth wear. Such compositions are also of use in combating dental caries.
    Type: Application
    Filed: April 3, 2008
    Publication date: February 25, 2010
    Inventor: Christabel Fowler
  • Publication number: 20100040534
    Abstract: Provided are: a radical generating apparatus that increases a purity of emitted plasma atoms, prevents contamination with impurities, and is improved in controllability over ion concentration; and a ZnO-based thin film prevented from being contaminated with impurities. A high-frequency coil (4) is wound around an outer side of a discharging tube (10), and a terminal of the high-frequency coil (4) is connected to a high-frequency power source (9). The discharging tube (10) is constituted by a discharging cylinder (1), a lid (2) and a gas introducing bottom plate (3). Additionally, a support base (8) is provided, a support post (6) is arranged on the support base (8), and a shutter (5) is connected to the support post (6). With respect to shaded components, that is, the shutter (5), the lid (2), the discharging cylinder (1) and the gas introducing bottom plate (3), an entirety or a part thereof is formed of a silicon-based compound such as quartz.
    Type: Application
    Filed: March 14, 2008
    Publication date: February 18, 2010
    Applicant: ROHM Co., LTD.
    Inventors: Ken Nakahara, Hiroyuki Yuji, Kentaro Tamura, Shunsuke Akasaka, Masashi Kawasaki, Akira Ohtomo, Atsushi Tsukazaki
  • Publication number: 20100034730
    Abstract: The present subject matter provides a time- and energy-saving paste-state mechanochemical process to synthesize zinc oxide nanoparticles. Our nanoparticles are small, have abundant surface hydroxyl groups and exhibit excellent UV blocking characteristics. One embodiment involves a process for preparing zinc oxide nanoparticles comprising grinding, milling, or a combination thereof a mixture comprising (a) at least one zinc salt, (b) at least one additional inorganic salt, and (c) at least one alkali hydroxide compound.
    Type: Application
    Filed: May 1, 2008
    Publication date: February 11, 2010
    Applicant: The Hong Kong University of Science and Technology
    Inventors: Jun Lu, Ka Ming Ng, Shihe Yang, Jiyun Feng
  • Publication number: 20100028254
    Abstract: The present invention provides zinc oxide particles having a large specific surface area, and a zinc oxide composite material, and processes for producing these, and the invention is zinc oxide particles formed by crystal growth into a multi-needle shape and having a larger specific surface area than hexagonal columnar particles; to a zinc oxide composite material comprising the zinc-containing thin film and the zinc oxide particles; to processes for producing the zinc oxide particles and the composite material, and an advantage of the present invention is that a larger specific surface area can be obtained than with hexagonal columnar particles, and a particle film of a specified thickness with fewer grain boundaries can be formed, thereby achieving less reduction in dielectric constant due to grain boundaries.
    Type: Application
    Filed: September 26, 2007
    Publication date: February 4, 2010
    Applicant: National Institute of Adv. Ind. Science and Tech.
    Inventors: Yoshitake Masuda, Kazumi Kato
  • Publication number: 20100028236
    Abstract: There is disclosed a process of making nano-sized or micro-sized precipitate particles. The process comprising the steps of mixing, in a reaction zone, a metal salt solution with a precipitant solution to form a precipitate, said precipitate being at least one of a metal chalcogenide, metal hydroxide and metal oxide; and applying a shear force to said mixing solutions in said reaction zone during said mixing step, wherein said shear force and the conditions within said reaction zone form said nano-sized or micro-sized precipitate particles.
    Type: Application
    Filed: October 2, 2007
    Publication date: February 4, 2010
    Applicant: NANOMATERIALS TECHNOLOGY PTE LTD
    Inventors: Zhigang Shen, Jiyao Zhang, Giawen Sim, Jimmy Sung Lai Yun, Jianfeng Chen
  • Publication number: 20100008847
    Abstract: A process comprises (a) combining (1) at least one base and (2) at least one metal carboxylate salt comprising (i) a metal cation selected from metal cations that form amphoteric metal oxides or oxyhydroxides and (ii) a carboxylate anion comprising from one to four alkyleneoxy moieties, or metal carboxylate salt precursors comprising (i) at least one metal salt comprising the metal cation and a non-interfering anion and (ii) at least one carboxylic acid comprising from one to four alkyleneoxy moieties, at least one salt of the carboxylic acid and a non-interfering, non-metal cation, or a mixture thereof; and (b) allowing the base and the metal carboxylate salt or metal carboxylate salt precursors to react.
    Type: Application
    Filed: December 18, 2007
    Publication date: January 14, 2010
    Inventor: Timothy D. Dunbar
  • Publication number: 20100003203
    Abstract: The present invention relates to methods of producing surface-modified nanoparticulate particles at least of one metal oxide, metal hydroxide and/or metal oxide hydroxide, and aqueous suspensions of these particles. The invention further relates to the surface-modified nanoparticulate particles, obtainable by these methods, at least of one metal oxide, metal hydroxide and/or metal oxide hydroxide and aqueous suspensions of these particles, and to their use for cosmetic sunscreen preparations, as stabilizer in plastics and as antimicrobial active ingredient.
    Type: Application
    Filed: October 10, 2007
    Publication date: January 7, 2010
    Applicant: BASF SE
    Inventors: Andrey Karpov, Hartmut Hibst, Jutta Kissel, Bernd Bechtloff, Hartwig Voss, Kerstin Schierle-Arndt, Valerie Andre
  • Publication number: 20100003179
    Abstract: Process for preparing a metal oxide powder, in which starting materials are evaporated and oxidized, wherein a metal melt in the form of droplets and one or more combustion gases are fed to the evaporation zone of a reactor, where the metal melt is evaporated completely under nonoxidizing conditions, subsequently, the mixture flowing out of the evaporation zone is reacted in the oxidation zone of this reactor with a stream of a supplied oxygen-containing gas whose oxygen content is at least sufficient to oxidize the metal and the combustion gases completely.
    Type: Application
    Filed: May 16, 2007
    Publication date: January 7, 2010
    Applicant: EVONIK DEGUSSA GMBH
    Inventors: Stipan Katusic, Guido Zimmermann, Michael Kraemer, Heiko Gottfried, Peter Kress
  • Patent number: 7638112
    Abstract: A method for making zinc aluminate nano-material, the method comprises the following steps. Firstly, providing a growing substrate and a growing device, and the growing device comprising a heating apparatus and a reacting room. Secondly, placing the growing substrate and a quantity of reacting materials into the reaction room, and the reacting materials comprising zinc and aluminum. Thirdly, introducing an oxygen-containing gas into the reaction room. Lastly, heating the reaction room to a temperature of 660˜1100° C.
    Type: Grant
    Filed: November 6, 2008
    Date of Patent: December 29, 2009
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Hai-Lin Sun, Kai-Li Jiang, Qun-Qing Li, Shou-Shan Fan
  • Publication number: 20090297626
    Abstract: The disclosed subject matter provides a method for preparing a metal oxide, the method includes (a) contacting a metal salt precursor with an alcohol to provide a metal oxide; and (b) removing the metal oxide from the alcohol.
    Type: Application
    Filed: November 5, 2007
    Publication date: December 3, 2009
    Applicant: The Trustees of Columbia University in the City of New York
    Inventors: Stephen O'Brien, Limin Huang
  • Patent number: 7608237
    Abstract: A process for synthesizing nanostructures is disclosed. The process involves forming a liquid crystalline template by combining a block copolymer, a first reactant in a polar phase, and a nonpolar phase, then contacting the template with a gas phase composed of a second reactant, under conditions effective to form nanostructures.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: October 27, 2009
    Assignee: The Research Foundation of State University of New York
    Inventors: Paschalis Alexandridis, Georgios N. Karanikolos, Triantafillos J. Mountziaris
  • Patent number: 7601324
    Abstract: The method for synthesizing metal oxide nanopowder produces powders of nanoparticle size from metals having relatively low boiling temperatures, such as zinc, tellurium, bismuth, and strontium by vapor-phase oxidation using a conventional 2.45 GHz microwave oven. The energy that initiates the combustion comes from the microwave through a susceptor tube that absorbs radiant microwave energy and transfers it to the metal, which evaporates to small particles inside the susceptor tube and then combusts in air to form nanosize powder. The susceptor is made of silicon carbide composite material.
    Type: Grant
    Filed: July 11, 2008
    Date of Patent: October 13, 2009
    Assignee: King Fahd University of Petroleum and Minerals
    Inventor: Saleh I. Al-Quraishi
  • Patent number: 7595036
    Abstract: Novel, monodispersed, spherical ZrO2 particles in the size range of approximately 10 to approximately 600 nm exhibiting metastable tetragonal crystal structure at room temperature and novel methods of preparation. The ZrO2 particles are approximately 100% in the tetragonal phase at room temperature and can be pure and free of foreign oxides. The novel method can include mixing zirconium-alkoxide and an alcohol, forming preparation one, followed by separately dissolving completely de-ionized water and a polymeric steric stabilizer in an alcohol forming preparation two. Next the preparations can be mixed with vigorous stirring while subjecting the materials to hydrolysis and condensation reactions with very slow stirring. Next, there is waiting for the formation of a sol from the mixture, followed by drying at approximately 80 degrees C. to form resultant material followed by crushing the resultant material.
    Type: Grant
    Filed: January 15, 2009
    Date of Patent: September 29, 2009
    Assignee: University of Central Florida Research Foundation, Inc.
    Inventors: Sudipta Seal, Satyajit Shukla
  • Publication number: 20090238747
    Abstract: The invention relates to a method for producing (semi)metal oxides and hydroxides, such as Si02, Ti02, Zr02, Zn0 and other (semi)metal salts such as BaSO4, which can be produced by emulsion precipitation in the form of nanoparticles from an aqueous solution. The invention also relates to the use of the same.
    Type: Application
    Filed: November 11, 2005
    Publication date: September 24, 2009
    Inventors: Matthias Koch, Ralf Anselmann
  • Patent number: 7582276
    Abstract: The invention relates to nanoscale rutile or oxide powder that is obtained by producing amorphous TiO2 by mixing an alcoholic solution with a titanium alcoholate and with an aluminum alcohalate and adding water and acid. The amorphous, aluminum-containing TiO2 is isolated by removing the solvent, and is redispersed in water in the presence of a tin salt. Thermal or hydrothermal post-processing yields rutile or oxide that can be redispersed to primary particle size. The n-rutile or the obtained oxide having a primary particle size ranging between 5 and 20 nm can be incorporated into all organic matrices so that they remain transparent. Photocatalytic activity is suppressed by lattice doping with trivalent ions. If the amorphous precursor is redispersed in alcohol, or not isolated, but immediately crystallized, an anatase is obtained that can be redispersed to primary particle size.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: September 1, 2009
    Assignee: ITN Nanovation AG
    Inventor: Ralph Nonninger
  • Publication number: 20090202427
    Abstract: Process for preparing mixed metal oxide powders Abstract Process for preparing a mixed metal oxide powder, in which oxidizable starting materials are evaporated in an evaporation zone of a reactor and oxidized in the vaporous state in an oxidation zone of this reactor, the reaction mixture is cooled after the reaction and the pulverulent solids are removed from gaseous substances, wherein at least one pulverulent metal, together with one or more combustion gases, is fed to the evaporation zone, the metal is evaporated completely in the evaporation zone under nonoxidizing conditions, an oxygen-containing gas and at least one metal compound are fed, separately or together, in the oxidation zone to the mixture flowing out of the evaporation zone, the oxygen content of the oxygen-containing gas being at least sufficient to oxidize the metal, the metal compound and the combustion gas completely.
    Type: Application
    Filed: May 16, 2007
    Publication date: August 13, 2009
    Applicant: EVONIK DEGUSSA GMBH
    Inventors: Stipan Katusic, Guido Zimmermann, Michael Krämer, Horst Miess, Edwin Staab
  • Patent number: 7553474
    Abstract: It is an object to provide a method for producing stable alkaline metal oxide sols having a uniform particle size distribution. The method comprises the steps of: heating a metal compound at a temperature of 60° C. to 110° C. in an aqueous medium that contains a carbonate of quaternary ammonium; and carrying out hydrothermal processing at a temperature of 110° C. to 250° C. The carbonate of quaternary ammonium is (NR4)2CO3 or NR4HCO3 in which R represents a hydrocarbon group, or a mixture thereof. The metal compound is one, or two or more metal compounds selected from a group of compounds based on a metal having a valence that is bivalent, trivalent, or tetravalent.
    Type: Grant
    Filed: August 8, 2005
    Date of Patent: June 30, 2009
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yutaka Ohmori, Hirokazu Kato, Yoshinari Koyama, Kenji Yamaguchi
  • Publication number: 20090136757
    Abstract: A method of fractionating a dispersion of oxidic nanoparticles wherein at least one step of the method is a membrane crossflow filtration step, the flow of the dispersion over the membrane being brought about by means of driven rotating parts; and dispersions of oxidic nanoparticles that are obtainable by the method.
    Type: Application
    Filed: November 14, 2008
    Publication date: May 28, 2009
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Roland WURSCHE, Goetz Baumgarten, Wolfgang Lortz, Michael Kroell
  • Publication number: 20090123354
    Abstract: A solid material is presented for the partial oxidation of natural gas. The solid material includes a solid oxygen carrying agent and a hydrocarbon activation agent. The material precludes the need for gaseous oxygen for the partial oxidation and provides better control over the reaction.
    Type: Application
    Filed: November 14, 2007
    Publication date: May 14, 2009
    Inventors: Deng-Yang Jan, Joel T. Walenga, Kurt M. Vanden Bussche, Joseph A. Kocal, Lisa M. King
  • Publication number: 20090098043
    Abstract: Example embodiments provide a method for preparing zinc oxide nanostructures. According to the method, zinc oxide nanostructures are prepared by dipping a substrate having a zinc (Zn) seed layer thereon in an aqueous solution of hexamethyleneamine and dropwise adding an aqueous solution of zinc nitrate to the aqueous solution of hexamethyleneamine. In addition, zinc ions can be continuously supplied in a constant amount as the reactions of the reactants proceed to prepare high-quality zinc oxide nanostructures at a high growth rate. Furthermore, zinc oxide nanostructures can be prepared on a large-area substrate at a low processing temperature regardless of the substrate material. Example embodiments also provide zinc oxide nanostructures prepared by the method.
    Type: Application
    Filed: March 24, 2008
    Publication date: April 16, 2009
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Byong Gwon SONG, Seung Nam CHA, Jae Eun JUNG, Jae Eun JANG
  • Patent number: 7510635
    Abstract: Provided is a manufacturing method of high purity oxide powder including the steps of subjecting a raw material such as Zn-containing scrap to acid leaching or electrolytic extraction, thereafter performing solvent extraction and activated carbon treatment thereto in order to remove impurities, neutralizing the resultant solution freed of impurities with an alkaline solution to obtain zinc hydroxide, and firing the zinc hydroxide to obtain zinc oxide. Provided are high purity zinc oxide efficiently freed of impurities, in particular C, Cl, S and Pb impurities, at low cost and the manufacturing method thereof; a target manufactured by firing the high purity zinc oxide; and a high purity zinc oxide thin film obtained by the sputtering the target.
    Type: Grant
    Filed: September 8, 2004
    Date of Patent: March 31, 2009
    Assignee: Nippon Mining & Metals Co., Ltd.
    Inventors: Yuichiro Shindo, Kouichi Takemoto
  • Patent number: 7488464
    Abstract: Methods and systems for processing metal oxides from metal containing solutions. Metal containing solutions are mixed with heated aqueous oxidizing solutions and processed in a continuous process reactor or batch processing system. Combinations of temperature, pressure, molarity, Eh value, and pH value of the mixed solution are monitored and adjusted so as to maintain solution conditions within a desired stability area during processing. This results in metal oxides having high or increased pollutant loading capacities and/or oxidation states. These metal oxides may be processed according to the invention to produce co-precipitated oxides of two or more metals, metal oxides incorporating foreign cations, metal oxides precipitated on active and inactive substrates, or combinations of any or all of these forms.
    Type: Grant
    Filed: July 28, 2004
    Date of Patent: February 10, 2009
    Assignee: EnviroScrub Technologies Corporation
    Inventors: Charles F. Hammel, Richard M. Boren
  • Publication number: 20090032801
    Abstract: An in situ approach toward connecting and electrically contacting vertically aligned nanowire arrays using conductive nanoparticles is provided. The utility of the approach is demonstrated by development of a gas sensing device employing the nanowire assembly. Well-aligned, single-crystalline zinc oxide nanowires were grown through a direct thermal evaporation process at 550° C. on gold catalyst layers. Electrical contact to the top of the nanowire array was established by creating a contiguous nanoparticle film through electrostatic attachment of conductive gold nanoparticles exclusively onto the tips of nanowires. A gas sensing device was constructed using such an arrangement and the nanowire assembly was found to be sensitive to both reducing (methanol) and oxidizing (nitrous oxides) gases. This assembly approach is amenable to any nanowire array for which a top contact electrode is needed.
    Type: Application
    Filed: April 29, 2008
    Publication date: February 5, 2009
    Applicant: University of Maryland
    Inventors: Prahalad Parthangal, Michael R. Zachariah, Richard E. Cavicchi
  • Patent number: 7482382
    Abstract: The present invention is directed to novel sol-gel methods in which metal oxide precursor and an alcohol-based solution are mixed to form a reaction mixture that is then allowed to react to produce nanosized metal oxide particles. The methods of the present invention are more suitable for preparing nanosized metal oxide than are previously-described sol-gel methods. The present invention can provide for nanosized metal oxide particles more efficiently than the previously-described sol-gel methods by permitting higher concentrations of metal oxide precursor to be employed in the reaction mixture. The foregoing is provided by careful control of the pH conditions during synthesis and by ensuring that the pH is maintained at a value of about 7 or higher.
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: January 27, 2009
    Assignees: The Texas A&M University System, Kaneka Corporation
    Inventors: Yuntao Li, Hung-Jue Sue, Riichi Nishimura, Nobuo Miyatake
  • Publication number: 20090017303
    Abstract: The present invention relates to a method for increasing a photocatalytic activity of zinc oxide, which comprises preparing zinc oxide nanoplate crystals having a planar morphology on their (0001) crystal faces. In addition, the present invention relates to a process for synthesizing zinc oxide nanoplate crystals, a tooth whitening composition and a composition for degrading organic pollutants.
    Type: Application
    Filed: June 12, 2008
    Publication date: January 15, 2009
    Applicant: FAS Alliances, Inc.
    Inventors: Jin Ho CHOY, Tae Un Park, Eue Soon Jang
  • Publication number: 20090010971
    Abstract: The method for producing a disintegratable zinc oxide powder of the present invention is characterized by comprising: neutralizing an aqueous solution containing a water-soluble zinc salt and a carboxylic acid or an aqueous solution containing a water-soluble zinc carboxylate with an alkali carbonate to produce precipitate; and firing the precipitate to obtain zinc oxide powder. As a water-soluble zinc salt, zinc chloride or zinc acetate is preferably used. As an acid, acetic acid is preferably used. As an alkali carbonate, sodium carbonate is preferably used. The disintegratable zinc oxide powder has the morphology in which the primary particles of zinc oxide are aggregated to form secondary particles, and these secondary particles are further aggregated to form the zinc oxide powder. The powder can achieve excellent UV protection capability, excellent transparency, and excellent feeling in use through its disintegration. Also, it has good usability and good handling properties.
    Type: Application
    Filed: June 2, 2006
    Publication date: January 8, 2009
    Applicant: SHISEIDO CO., LTD.
    Inventors: Shoichiro Shio, Yuko Ishikawa, Yukimitsu Suda, Masayoshi Wada
  • Publication number: 20080311031
    Abstract: The invention provides a method for the formation of small-size metal oxide particles, comprising the steps of a) preparing a starting aqueous solution comprising at least one of metallic ions and complexes thereof, at a concentration of at least 0.1 % w/w of the metal component; b) maintaining the solution at a temperature lower than 50° C. for a retention time in which hydrolysis takes place, the extent of the hydrolysis being sufficient to produce O.1 mmol protons per mmol of metal present in solution, wherein the time does not exceed 14 days, to form a system containing a retained solution; and c) adjusting the conditions in the system by at least one of the steps of: i) heating the retained solution to elevate the temperature thereof by at least 1° C.; ii) changing the pH of the retained solution by at least 0.1 units; and iii) diluting the retained solution by at least 20% whereby there are formed particles, wherein the majority of the particles formed are between about 2 nm and about 500 nm in size.
    Type: Application
    Filed: December 21, 2006
    Publication date: December 18, 2008
    Applicant: JOMA INTERNATIONAL AS
    Inventors: Asher Vitner, Aharon Eyal
  • Publication number: 20080305025
    Abstract: The invention provides a method for the formation of small-size metal oxide particles, comprising the steps of: a) preparing a starting aqueous solution comprising at least one of metallic ion and complexes thereof, at a concentration of at least 0.1% w/w of the metal component; b) preparing a modifying aqueous solution having a temperature greater than 50° C.; c) contacting the modifying aqueous solution with the starting aqueous solution in a continuous mode in a mixing chamber to form a-modified system; d) removing the modified system from the mixing chamber in a plug-flow mode; wherein the method is characterized in that: i) the residence time in the mixing chamber is less than about 5 minutes; and iii) there are formed particles or aggregates thereof, wherein the majority of the particles formed are between about 2 nm and about 500 nm in size.
    Type: Application
    Filed: December 21, 2006
    Publication date: December 11, 2008
    Applicant: Joma International AS
    Inventors: Asher Vitner, Aharon Eyal
  • Publication number: 20080274041
    Abstract: A method for making a dispersion of zinc oxide particles in hydrocarbon is provided. A zinc compound that thermally disintegrates is dispersed in a hydrocarbon solvent with a selected organic acid and the mixture is heated to a temperature range to cause the zinc compound to thermally disintegrate into nano-sized particles.
    Type: Application
    Filed: May 4, 2007
    Publication date: November 6, 2008
    Inventors: Mark D. Hughes, Kenneth W. Koch, Kenneth D. Miller, Daniel T. Smith, Frederick F. Tripp
  • Publication number: 20080260612
    Abstract: Multi-step metal compound oxidation process to produce compounds and enhanced metal oxides from various source materials, e.g. metal sulfides, carbides, nitrides and other metal containing materials with metal oxides from secondary reaction steps being utilized as an oxidation agent in the first reactions.
    Type: Application
    Filed: April 18, 2008
    Publication date: October 23, 2008
    Applicant: Orchard Material Technology, LLC
    Inventor: Lawrence F. McHugh
  • Publication number: 20080241054
    Abstract: A method for making the metal oxide includes the following steps: mixing a metal nitrate with a solvent of octadecyl amine, and achieving a mixture; agitating and reacting the mixture at a reaction temperature for a reaction period; cooling the mixture to a cooling temperature, and achieving a deposit; and washing the deposit with an organic solvent, drying the deposit at a drying temperature and achieving a metal oxide nanocrystal. The present method for making a metal oxide nanocrystal is economical and timesaving, and has a low toxicity associated therewith. Thus, the method is suitable for industrial mass production.
    Type: Application
    Filed: November 2, 2007
    Publication date: October 2, 2008
    Applicants: Tsinghua University, HON HAI Precision Industry Co., Ltd.
    Inventors: Ya-Dong Li, Ding-Sheng Wang
  • Publication number: 20080226220
    Abstract: The present disclosure includes methods, devices, and systems for zinc oxide diodes for optical interconnections. One system includes a ZnO emitter confined within a circular geometry in an oxide layer on a silicon substrate. An optical waveguide is formed in the oxide layer and has an input coupled to the ZnO emitter. A detector is coupled to an output of the optical waveguide.
    Type: Application
    Filed: March 13, 2007
    Publication date: September 18, 2008
    Inventors: Leonard Forbes, Kie Y. Ahn
  • Patent number: 7423512
    Abstract: A collection of zinc oxide nanoparticles have been produced by laser pyrolysis. The zinc oxide nanoparticles have average particle diameters of less than about 95 nm and a very narrow particle size distribution. The laser pyrolysis process is characterized by the production of a reactant stream within the reaction chamber, where the reactant stream includes a zinc precursor and other reactants. The zinc precursor can be delivered as an aerosol.
    Type: Grant
    Filed: March 10, 1999
    Date of Patent: September 9, 2008
    Assignee: NanoGram Corporation
    Inventors: Hariklia Dris Reitz, Sujeet Kumar, Xiangxin Bi, Nobuyuki Kambe
  • Publication number: 20080206124
    Abstract: Disclosed is a method of exfoliating a layered material (e.g., graphite and graphite oxide) to produce nano-scaled platelets having a thickness smaller than 100 nm, typically smaller than 10 nm, and often between 0.34 nm and 1.02 nm. The method comprises: (a) subjecting the layered material in a powder form to a halogen vapor at a first temperature above the melting point or sublimation point of the halogen at a sufficient vapor pressure and for a duration of time sufficient to cause the halogen molecules to penetrate an interlayer space of the layered material, forming a stable halogen-intercalated compound; and (b) heating the halogen-intercalated compound at a second temperature above the boiling point of the halogen, allowing halogen atoms or molecules residing in the interlayer space to exfoliate the layered material to produce the platelets.
    Type: Application
    Filed: February 22, 2007
    Publication date: August 28, 2008
    Inventors: Bor Z. Jang, Aruna Zhamu
  • Publication number: 20080193760
    Abstract: Disclosed is a method of manufacturing a metal oxide nano powder comprising preparing a first dispersed solution by adding a nano-sized metal powder to water and dispersing the metal powder within the water, performing a hydration reaction of the first dispersed solution at a temperature of about 30 to about 70° C. to generate a precipitation, and filtering and drying the precipitation to prepare a metal oxide powder. Also, disclosed is a metal oxide nano powder manufactured by the method described above, and having any one of a bar-form, a cube-form, and a fiber-form.
    Type: Application
    Filed: November 6, 2007
    Publication date: August 14, 2008
    Inventors: Chang Kyu Rhee, Min Ku Lee, Young Rang Uhm, Jin Ju Park, Byung Sun Han, Hi Min Lee, Seung-Hee Woo
  • Publication number: 20080193759
    Abstract: The present invention relates to surface-modified nanoparticulate metal oxides where the metal is chosen from the group consisting of aluminum, cerium, iron, titanium, zinc and zirconium, wherein the surface modification comprises a coating with a copolymer P comprising, as monomers, A) 1 to 99 mol % of a N-vinylamide N-vinylpyrrolidone and B) 99 to 1 mol % of a monomer comprising, per molecule, a free-radically polymerizable ?,?-ethylenically unsaturated double bond and an anionogenic and/or anionic group, with the proviso that the copolymer P must comprise no further monomers chosen from the group consisting of C8-C30-alkyl esters of monoethylenically unsaturated C3-C8-carboxylic acids, N-alkyl- or N,N-dialkyl-substituted amides of acrylic acid or of methacrylic acid with C8-C18-alkyl radicals, or vinyl esters of aliphatic C8-C30-carboxylic acids.
    Type: Application
    Filed: May 30, 2006
    Publication date: August 14, 2008
    Applicant: BASF AKTIENGESELLSCHAFT
    Inventors: Jens Rieger, Jutta Kissel, Valerie Andre, Nathalie Bouillo
  • Publication number: 20080138272
    Abstract: It is an object to provide a method for producing stable alkaline metal oxide sols having a uniform particle size distribution. The method comprises the steps of: heating a metal compound at a temperature of 60° C. to 110° C. in an aqueous medium that contains a carbonate of quaternary ammonium; and carrying out hydrothermal processing at a temperature of 110° C. to 250° C. The carbonate of quaternary ammonium is (NR4)2CO3 or NR4HCO3 in which R represents a hydrocarbon group, or a mixture thereof. The metal compound is one, or two or more metal compounds selected from a group of compounds based on a metal having a valence that is bivalent, trivalent, or tetravalent.
    Type: Application
    Filed: August 8, 2005
    Publication date: June 12, 2008
    Applicant: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventors: Yutaka Ohmori, Hirokazu Kato, Yoshinari Koyama, Kenji Yamaguchi
  • Patent number: 7371337
    Abstract: Pyrogenically prepared zinc oxide powder having a BET surface area of from 10 to 200 m2/g, which is in the form of aggregates, the aggregates being composed of particles having different morphologies, and 0-10% of the aggregates being in a circular form, 30-50% being in an ellipsoidal form, 30-50% being in a linear form and 20-30% being in a branched form. It is prepared by reacting a starting mixture containing zinc vapour, a combustible gas and steam or a mixture of steam and carbon dioxide in a flame with an oxygen-containing gas in an oxidation zone, cooling the hot reaction mixture in a quenching zone and separating the solid material from the gas stream, the amount of oxygen in the oxidation zone being greater than the amount necessary for the complete oxidation of the combustible gas and the zinc vapour. The zinc oxide powder can be used as a constituent of sun protection compositions for protection against UV radiation.
    Type: Grant
    Filed: September 2, 2004
    Date of Patent: May 13, 2008
    Assignee: Evonik Degussa GmbH
    Inventors: Stipan Katusic, Michael Kraemer, Peter Kress, Horst Miess, Guido Zimmermann, Peter Albers
  • Publication number: 20080031832
    Abstract: A particle of TiO2 or ZnO which has been doped with one or more other elements such that the concentration of dopant in the surface of the particle is greater than that at the core of the particle, and compositions containing such particles for use as sunscreens or in veterinary, agricultural or horticultural compositions or as coatings for plastics and other materials.
    Type: Application
    Filed: January 26, 2005
    Publication date: February 7, 2008
    Applicant: Oxonica Limited
    Inventors: Gareth Wakefield, George Barry Park, Sarah Lipscomb, Edward Holland
  • Patent number: 7297321
    Abstract: A new class of supermicroporous mixed oxides, with pore sizes in the 10-20 ? range has been prepared utilizing basic metal acetates. The reactions are carried out in non-aqueous solvent media to which an excess of amine is added. Hydrolysis of the reagents is effected by addition of a water-propanol mixture and refluxing. The amine and solvent are removed by thorough washing and/or calcining at temperatures as low as 200° C. Mixtures of transition metal oxides with either ZrO2, TiO2, La2O3, SiO2, Al2O3 or mixtures thereof were prepared. The surface area curves of the pure oxides are Type I with surface areas of 400-600 m2/g and up to 1100 m2/g for the mixed oxides.
    Type: Grant
    Filed: January 11, 2005
    Date of Patent: November 20, 2007
    Assignee: The Texas A&M University System
    Inventors: Boris G. Shpeizer, Abraham Clearfield
  • Patent number: 7238331
    Abstract: The present invention discloses a process for producing nano-powders and powders of nano-particle loose aggregate, which includes: (a) providing at least two reactant solutions A and B capable of rapidly reacting to form deposits; (b) supplying the at least two reactant solutions A and B at least at the reaction temperature into a mixing and reaction precipitator respectively, in which mixing reaction and precipitation are continuously carried out in sequence, the mixing and reaction precipitator being selected from at least one of a tubular ejection mixing reactor, a tubular static mixing reactor and an atomization mixing reactor; and (c) treating the deposit-containing slurry continuously discharged from the mixing reaction precipitator.
    Type: Grant
    Filed: July 26, 2002
    Date of Patent: July 3, 2007
    Assignee: Anshan University of Science and Technology
    Inventors: Yingyan Zhou, Shoushan Gao, Kaiming Wang, Chuangeng Wen, Xiaoqi Li