Zinc Patents (Class 423/622)
  • Patent number: 7235224
    Abstract: Disclosed is a process for preparing fine metal oxide particles, comprising the following steps of reacting a reactant mixture comprising i) water, ii) at least one water-soluble metal nitrate and iii) ammonia or ammonium salt at 250–700° C. under 180–550 bar for 0.01 sec to 10 min in a reaction zone to synthesize the metal oxide particles, the metal nitrate being contained at an amount of 0.01–20 wt % in the reactant mixture; and separating and recovering the metal oxide particles from the resulting reaction products. According to the present invention, nano-sized metal oxide particles are synthesized, while the harmful by-products generated concurrently therewith are effectively decomposed in the same reactor.
    Type: Grant
    Filed: July 8, 2003
    Date of Patent: June 26, 2007
    Assignee: Han-Wha Chemical Corporation
    Inventors: Wan-Jae Myeong, Jin-Soo Baik, Se-Woong Park, Chang-Mo Chung, Kyu-Ho Song
  • Patent number: 7223377
    Abstract: The present invention is the method for preparation of transition metal oxide having micro-mesoporous structure whose average fine pores size is not less than 1 nm and not more than 2 nm comprising, adding and dissolving transition metal salt which is a precursor of transition metal oxide and/or metal alkoxide in the solution prepared by dissolving polymer surfactant in organic solvent, hydrolyzing said transition metal salt and/or metal alkoxide and preparing sol solution which is polymerized and self organized, then obtaining gel whose organization is stabilized from said sol solution and removing said polymer surfactant by using water of room temperature or water to which alkali metal or alkaline earth metal ion is added.
    Type: Grant
    Filed: October 2, 2002
    Date of Patent: May 29, 2007
    Assignee: Japan Science and Technology Agency
    Inventors: Kazunari Domen, Junko Nomura, Byonjin Ri
  • Patent number: 7211230
    Abstract: The present invention discloses a process for producing nanometer powders, comprising the following steps: (a) providing reactant solution A and reactant solution B that can rapidly react to form precipitate; (b) continuously adding said solution A and solution B into a mixing and reacting precipitator with a stator and a rotor in operation, respectively; and (c) post-treating the precipitate-containing slurry discharged continuously from the mixing and reacting precipitator. The present process could produce nanometer powders with adjustable particle size, good homogeneity in size and good dispersity. The method also has the characteristics of high production yield, simplicity in process and low consumption of energy. It could be applied to produce various nanometer powders of metals, oxides, hydroxides, salts, phosphides and sulfides as well as organic compounds.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: May 1, 2007
    Assignee: Anshan University of Science and Technology
    Inventors: Yingyan Zhou, Shoushan Gao, Hongxia Li, Kaiming Wang, Xiaoqi Li, Lixiang Li, Chuangeng Wen
  • Patent number: 7198773
    Abstract: Disclosed are a method of fabricating ZnO nanostructures and its apparatus, and more particularly, to a method of fabricating ZnO nanostructures from Zn gas, which is produced by a reduction process between ZnO powder and graphite, on a silicon substrate, wherein various types of nanostructures are reproducibly generated by adjusting the processing temperature and the mixed ratio between oxygen and argon gases, which are introduced into the interior of a reaction tube as carrier gases, and its apparatus.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: April 3, 2007
    Assignee: Korea Institute of Science and Technology
    Inventors: Jae-Hwan Park, Heon-Jin Choi, Jae-Gwan Park
  • Patent number: 7182929
    Abstract: A method for producing nanostructured multi-component or doped oxide particles and the particles produced therein. The process includes the steps of (i) dissolving salts of cations, which are either dopants or components of the final oxide, in an organic solvent; (ii) adding a dispersion of nanoparticles of a single component oxide to the liquid solution; (iii) heating the liquid solution to facilitate diffusion of cations into the nanoparticles; (iv) separating the solids from the liquid solution; and (v) heat treating the solids either to form the desired crystal structure in case of multi-component oxide or to render the homogeneous distribution of dopant cation in the host oxide structure. The process produces nanocrystalline multi-component or doped oxide nanoparticles with a particle size of 5–500 nm, more preferably 20–100 nm; the collection of particles have an average secondary (or aggregate) particle size is in the range of 25–2000 nm, preferably of less than 500 nm.
    Type: Grant
    Filed: August 18, 2004
    Date of Patent: February 27, 2007
    Assignee: NEI, Inc.
    Inventors: Amit Singhal, Ganesh Skandan, Mohit Jain
  • Patent number: 7138098
    Abstract: A method of manufacturing a nanocrystallite from a M-containing salt forms a nanocrystallite. The nanocrystallite can be a member of a population of nanocrystallites having a narrow size distribution and can include one or more semiconductor materials. Semiconducting nanocrystallites can photoluminesce and can have high emission quantum efficiencies.
    Type: Grant
    Filed: October 8, 2004
    Date of Patent: November 21, 2006
    Assignee: Massachusetts Institute of Technology
    Inventors: Moungi Bawendi, Nathan E. Stott
  • Patent number: 7135161
    Abstract: A method of forming metal oxide powders includes the steps of solid state mixing of at least one metal nitrate salt, such as Fe(NO3)3 or a combination of metal nitrate salts such as Zn(NO3)3,6H2O and Ga(NO3)3, xH2O, and at least one reducing organic acid, such as tartaric or citric acid. The mixture is heated to form a metal oxide powder, such as alpha-iron oxide (?-Fe2O3) or a mixed metal powder such as zinc gallate phosphor (ZnGa2O4). A metal oxide precursor intermediate can be formed and then heated to form the metal oxide powder.
    Type: Grant
    Filed: September 4, 2003
    Date of Patent: November 14, 2006
    Assignee: University of Florida Research Foundation, Inc.
    Inventors: Paul H. Holloway, Mostafa Abboudi
  • Patent number: 7118727
    Abstract: The present invention provides a process for producing particles, such as oxide nanoparticles, in a substantially water-free environment. The process involves mixing at least one metal compound of the formula MX(m?n) with at least one surfactant and at least one solvent, wherein M is an electropositive element of Groups 1–15; each X is independently selected from the group consisting of O1/2, F, Cl, Br, I, OR, O2CR, NR2, and R; each R is independently a hydrocarbyl group; n is equal to ½ the oxidation state of the metal M in the product particle; and m is equal to the oxidation state of the element M. The components are typically combined to form a mixture which is thermally treated for a time period sufficient to convert the metal compound into particles of the corresponding oxide, having sizes in a range between about 0.5 nanometer and about 1000 nanometers.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: October 10, 2006
    Assignee: General Electric Company
    Inventor: Darryl Stephen Williams
  • Patent number: 7118726
    Abstract: A method of making an oxide compound, comprising subjecting a base material to a source of heat that produces a localized temperature in the range of 2,000 to 5,500 degrees Celsius that vaporizes the base material which is drawn upward above the surface of the base material where it oxidizes, after which the resulting oxide compound is collected. A method of making bismuth trioxide, comprising providing an electric arc between electrodes, wherein elemental bismuth is in touching proximity to one of the electrodes. The bismuth is evaporated, drawn upward off the surface of the molten metal, forms the bismuth oxide on contact with oxygen, and the particles of bismuth oxide are collected. A method of making an oxide using an electric arc to evaporate a base material which then reacts with oxygen, and collecting the resulting oxides of base material.
    Type: Grant
    Filed: April 4, 2003
    Date of Patent: October 10, 2006
    Assignee: Clark Manufacturing, LLC
    Inventors: Jeffrey W. Clark, Larry B. Hunnel
  • Patent number: 7090821
    Abstract: The present invention relates to a metal oxide powder for high precision polishing and prepartion thereof, comprising aggregates formed by cohesion of primary particles, which has a cohesive degree (?) of 1.1 to 2.0 and a cohesive scale (?) of 3 to 10, the cohesive degree (?) and the cohesive scale (?) being defined by formula (I) and formula (II), respectively: ?=6/(S×?×d(XRD)) ??(I) ?=weight average particle diameter/d(XRD) ??(II) wherein, S is the specific surface area of the powder; ?, the density; and d(XRD), the particle diameter of the powder determined by X-ray diffraction analysis. In accordance with the present invention, it is possible to provide a high polishing speed and reduce scratches.
    Type: Grant
    Filed: June 5, 2003
    Date of Patent: August 15, 2006
    Assignee: Samsung Corning Co., Ltd.
    Inventors: Hyukjin Kwon, Myungho Ahn, Youngkwon Joung, Inyeon Lee
  • Patent number: 7081234
    Abstract: A process of treating metal oxide nanoparticles that includes mixing metal oxide nanoparticles, a solvent, and a surface treatment agent that is preferably a silane or siloxane is described. The treated metal oxide nanoparticles are rendered hydrophobic by the surface treatment agent being surface attached thereto, and are preferably dispersed in a hydrophobic aromatic polymer binder of a charge transport layer of a photoreceptor, whereby ?—? interactions can be formed between the organic moieties on the surface of the nanoparticles and the aromatic components of the binder polymer to achieve a stable dispersion of the nanoparticles in the polymer that is substantially free of large sized agglomerations.
    Type: Grant
    Filed: April 5, 2004
    Date of Patent: July 25, 2006
    Assignee: Xerox Corporation
    Inventors: Yu Qi, Nan-Xing Hu, Ah-Mee Hor, Cheng-Kuo Hsiao, Yvan Gagnon, John F. Graham
  • Patent number: 7022303
    Abstract: Polycrystalline materials of macroscopic size exhibiting Single-Crystal-Like properties are formed from a plurality of Single-Crystal Particles, having Self-Aligning morphologies and optionally ling morphology, bonded together and aligned along at least one, and up to three, crystallographic directions.
    Type: Grant
    Filed: May 13, 2002
    Date of Patent: April 4, 2006
    Assignee: Rutgers, The State University
    Inventors: Richard E. Riman, Larry E. McCandlish
  • Patent number: 6992038
    Abstract: The present invention is to solve the problems caused by a conventional method for producing a zinc chloride-loaded support wherein zinc chloride is adsorbed on a solid support in an aqueous solution of zinc chloride. The problems include environmental destruction caused by the treatment of a used aqueous solution of zinc chloride, corrosion to a reactor, a threat to health for workers, deterioration of zinc chloride due to deliquescence thereof, and reduction of specific surface area.
    Type: Grant
    Filed: November 18, 2003
    Date of Patent: January 31, 2006
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mitsuo Narita, Masaki Tabata, Kazuhisa Hayakawa
  • Patent number: 6984369
    Abstract: Disclosed is a process for making surfactant capped nanocrystals of metal oxides which are dispersable in organic solvents. The process comprises decomposing a metal cupferron complex of the formula MXCupX, wherein M is a metal, and Cup is a N-substituted N-Nitroso hydroxylamine, in the presence of a coordinating surfactant, the reaction being conducted at a temperature ranging from about 150 to about 400° C., for a period of time sufficient to complete the reaction. Also disclosed are compounds made by the process.
    Type: Grant
    Filed: November 22, 2000
    Date of Patent: January 10, 2006
    Assignee: The Regents of the University of California
    Inventors: A. Paul Alivisatos, Joerg Rockenberger
  • Patent number: 6942728
    Abstract: The present invention is embodied in high performance p-type thermoelectric materials having enhanced thermoelectric properties and the methods of preparing such materials. In one aspect of the invention, p-type semiconductors of formula Zn4?xAxSb3?yBy wherein 0?x?4, A is a transition metal, B is a pnicogen, and 0?y?3 are formed for use in manufacturing thermoelectric devices with substantially enhanced operating characteristics and improved efficiency. Two methods of preparing p-type Zn4Sb3 and related alloys of the present invention include a crystal growth method and a powder metallurgy method.
    Type: Grant
    Filed: October 1, 2002
    Date of Patent: September 13, 2005
    Assignee: California Institute of Technology
    Inventors: Thierry Caillat, Alexander Borshchevsky, Jean-Pierre Fleurial
  • Patent number: 6936188
    Abstract: A zinc oxide semiconductor material comprising at least zinc and oxygen as constituent elements, which can be deterred with respect to the deterioration of doping characteristic, luminous characteristic and the like, compared with a conventional c-axial oriented one by orienting the crystal orientation plane to a-axis of the wurtzite structure.
    Type: Grant
    Filed: March 27, 2000
    Date of Patent: August 30, 2005
    Assignees: Tohoku Techno Arch Co., Ltd., Sumitomo Electric Industries, Ltd.
    Inventor: Koichi Haga
  • Patent number: 6869596
    Abstract: A UV screening composition comprising particles which are capable of absorbing UV light so that electrons and positively charged holes are formed within the particles, characterised in that the particles are adapted to minimise migration to the surface of the particles of the electrons and/or the positively charged holes when said particles are exposed to UV light in an aqueous environment.
    Type: Grant
    Filed: May 27, 1999
    Date of Patent: March 22, 2005
    Assignee: ISIS Innovation Limited
    Inventors: John Sebastian Knowland, Peter James Dobson, Gareth Wakefield
  • Patent number: 6863873
    Abstract: A hydrometallurgical process utilizing an atmospheric calcium chloride leach to selectively recover from various metal feed stocks (consisting of elemental metals, metal oxides, metal ferrite, metal hydroxide, metal carbonates, metal sulfate/sulfur compounds, and their hydrates, specifically including but not limited to EAF Dust K061) zinc, lead, cadmium, silver, copper and other valuable metals to the exclusion of iron, magnesium, halogen salts and other unwanted elements. The process solves the problem of iron and magnesium leach solution contamination because iron is unexpectedly converted to magnetite. The heavy metals are cemented out of solution using zinc or other selected dust at a pH of 6 or greater under unique and unexpected conditions, which do not require acid.
    Type: Grant
    Filed: September 23, 2003
    Date of Patent: March 8, 2005
    Inventors: Loren P. Hoboy, Nick A. Wolf, Tonya F. Yoder
  • Patent number: 6843976
    Abstract: An apparatus and a process for producing zinc oxide from a zinc-bearing material are provided. The process comprises the steps of leaching the complex sulfide material with hydrochloric acid, ferric chloride, and oxygen; precipitating iron from the leach solution using lime and oxygen; removing copper, silver, cadmium, cobalt and lead from the leach solution by cementation with zinc dust; precipitating zinc oxide from the leach solution using lime; and regenerating HCl from a calcium chloride leach filtrate solution to regenerate hydrochloric acid and precipitate gypsum. Related processes for recovering copper, silver, lead, and iron from complex sulfide materials and for recovering lead from residue by solubilizing lead chloride and precipitating it with lime are also provided.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: January 18, 2005
    Assignee: Noranda Inc.
    Inventors: Carole Allen, Serge Payant, Peter Kondos, Gezinus Van Weert
  • Patent number: 6841143
    Abstract: This invention provides mesostructured oxide ceramics and a synthesizing method thereof, the synthesizing method employs a water-based solvent containing a metallic salt or metal complex as the ceramics precursor, template formed from an organic compound or the association thereof, and a precipitant, wherein mesostructured oxide ceramics are obtained from self-assembled oxide ceramics and organic substance by directly extracting oxide ceramics at a low temperature of 200° C. or less by utilizing a homogenous precipitation reaction from said ceramics precursor under the coexistence of a nanometer-sized template in the solvent, and separating and collecting the obtained precipitation, and mesostructured oxide ceramics is prepared by employing the synthesizing method described above.
    Type: Grant
    Filed: September 6, 2001
    Date of Patent: January 11, 2005
    Assignee: National Institute of Advanced Industrial Science and Technology
    Inventors: Masahiko Inagaki, Atsushi Hozumi, Kei Teraoka, Kaori Nishizawa, Fukue Nagata, Yoshiyuki Yokogawa, Tetsuya Kameyama
  • Patent number: 6841000
    Abstract: Aqueous mineralizer solutions having retrograde solubility for ZnO contain a mineral acid in which ZnO is soluble and at least one compound of a coordinating ligand for Zn2+ ions wherein the coordinating ligand compound is present in an amount that is effective to inhibit Zn(OH)+ ion formation as ZnO is dissolved in the solution. Reduced temperature methods using the mineralizer solutions to grow pure or doped ZnO crystals, pure or doped ZnO thick or thin films, and pure or doped ZnO crystalline powders are also disclosed. Cation doped ZnOs prepared by the inventive methods are also disclosed.
    Type: Grant
    Filed: October 1, 2002
    Date of Patent: January 11, 2005
    Assignee: Ceramare Corporation
    Inventors: Larry Eugene McCandlish, Robert Uhrin
  • Publication number: 20040241085
    Abstract: The present invention provides a process for preparing ball-shaped zinc oxide particles and their use.
    Type: Application
    Filed: May 28, 2004
    Publication date: December 2, 2004
    Inventors: Thiemo Marx, Bernd Hynek, Volker Wege
  • Patent number: 6800135
    Abstract: A ZnO/sapphire substrate includes an R-plane sapphire substrate whose (0 1-1 2) planes are parallel to the surface thereof and a ZnO epitaxial film formed on the R-plane sapphire substrate. The (1 1-2 0) planes of the ZnO epitaxial film are disposed with an interplanar spacing in the range of about 1.623 to 1.627 Å parallel to the (0 1-1 2) planes of the R-plane sapphire substrate.
    Type: Grant
    Filed: June 17, 2002
    Date of Patent: October 5, 2004
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Jun Koike, Hideharu Ieki
  • Patent number: 6783744
    Abstract: A method for the recovery of high purity zinc oxide products, and optionally iron-carbon feedstocks, from industrial waste streams containing zinc oxide and/or iron. The waste streams preliminary can be treated by adding carbon and an ammonium chloride solution, separating any undissolved components from the solution, displacing undesired metal ions from the solution using zinc metal, treating the solution to remove therefrom zinc compounds, and further treating the zinc compounds and the undissolved components, as necessary, resulting in the zinc products and the optional iron-carbon feedbacks. Once the zinc oxide has been recovered, the purification process is used to further purify the zinc oxide to obtain zinc oxide which is at least 99.8% pure and which has predeterminable purity and particle characteristics. Various zinc compounds may then be quickly, easily, and economically produced from this recovered zinc oxide.
    Type: Grant
    Filed: August 27, 2003
    Date of Patent: August 31, 2004
    Inventors: Allan S Myerson, Peter Robinson, Stephan Tabah
  • Patent number: 6780393
    Abstract: A method of producing fine particles of an oxide of a metal, comprising the steps of: preparing an acidic solution which contains ions of the metal; precipitating fine particles of a hydroxide of the metal by adding an alkaline solution to the acidic solution; collecting the fine particles of the hydroxide of the metal precipitated in a mixed solution of the acidic solution and the alkaline solution; mixing fine particles of a carbon with the collected fine particles of the hydroxide of the metal; and heat-treating a mixture of the fine particles of the hydroxide of the metal and the fine particles of the carbon at a predetermined temperature in a non-reducing atmosphere, whereby the fine particles of the oxide of the metal are produced.
    Type: Grant
    Filed: December 14, 2001
    Date of Patent: August 24, 2004
    Assignees: National Institute of Advanced Industrial Science and Technology, Noritake Co., Limited
    Inventors: Norimitsu Murayama, Woosuck Shin, Sumihito Sago, Makiko Hayashi
  • Publication number: 20040115533
    Abstract: A zinc electrode for use in alkaline batteries comprises a mixture of 0.425 to 1.55 volume parts of zinc oxide with a volume part of a metallic oxide chosen from the group consisting of: calcium oxide, barium oxide, and mixtures thereof, together with hydroxy-ethyl cellulose, an oxide dispersant chosen from the group consisting of: soap derivatives, anionic polyelectrolytes, anionic surfactants, and mixtures thereof, and a binder. The electrode is prepared by mixing zinc oxide with the chosen metallic oxide in an aqueous medium such as water or potassium hydroxide, stirring overnight, filtering and drying the mixture, optionally adding a further small amount of zinc oxide, optionally adding other metallic oxides, and adding hydroxy-ethyl cellulose, an oxide dispersant, and a binder. The aqueous paste os slurry thus formed is placed on a conductive substrate, drawn through a sizing gap, cut and dried, to form low cost pasted zinc oxide electrodes.
    Type: Application
    Filed: January 20, 2004
    Publication date: June 17, 2004
    Inventor: Jeffrey Phillips
  • Publication number: 20040115123
    Abstract: The present invention discloses a process for producing nanometer powders, comprising the following steps: (a) providing reactant solution A and reactant solution B that can rapidly react to form precipitate; (b) continuously adding said solution A and solution B into a mixing and reacting precipitator with a stator and a rotor in operation, respectively; and (c) post-treating the precipitate-containing slurry discharged continuously from the mixing and reacting precipitator. The present process could produce nanometer powders with adjustable particle size, good homogeneity in size and good dispersity. The method also has the characteristics of high production yield, simplicity in process and low consumption of energy. It could be applied to produce various nanometer powders of metals, oxides, hydroxides, salts, phosphides and sulfides as well as organic compounds.
    Type: Application
    Filed: February 6, 2004
    Publication date: June 17, 2004
    Inventors: Yingyan Zhou, Shoushan Gao, Hongxia Li, Kaiming Wang, Xiaoqi Li, Lixiang Li, Chuangeng Wen
  • Patent number: 6730518
    Abstract: Disclosed is a method of reducing photooxidation or air oxidation in susceptible materials such as food, plastics or pharmaceuticals comprising mixing the material with an antioxidation composition comprising at least one amino acid, at least one metal ion, and at least one carboxylic acid in an amount effective to reduce photooxidation in the material.
    Type: Grant
    Filed: September 25, 2000
    Date of Patent: May 4, 2004
    Assignee: Natura, Inc.
    Inventors: Joel I. Dulebohn, Ronald J. Carlotti
  • Patent number: 6719821
    Abstract: The production and selection of precursor mixtures used to produce fine powders and methods for making fine powders using the selected precursor. The precursor mixture comprises at least one metal containing precursor, the metal containing precursor has an average molecular weight of less than 2000 grams per unit mol of the metal, the metal containing precursor has a normal boiling point greater than 350K, and the viscosity of the precursor mixture is between 0.1 to 250 cP. The precursor mixture is processed under conditions that produce a fine powder from the precursor mixture. Fine powders produced are of size less than 100 microns, preferably less than 10 micron, more preferably less than 1 micron, and most preferably less than 100 nanometers.
    Type: Grant
    Filed: February 8, 2002
    Date of Patent: April 13, 2004
    Assignee: NanoProducts Corporation
    Inventors: Tapesh Yadav, Elena Mardilovich
  • Patent number: 6710091
    Abstract: A method for the preparation of nano size zinc oxide particles having an average primary particle diameter of less than or equal to 15 nm, which are redispersible in organic solvents and/or water, by basic hydrolysis of at least one zinc compound in alcohol or an alcohol/water mixture. The hydrolysis is carried out with substoichiometric amounts of base, based on the zinc compound. The precipitate which originally forms during hydrolysis is left to mature until the zinc oxide has completely flocculated. This precipitate is then thickened to give a gel and separated off from the supernatant phase.
    Type: Grant
    Filed: August 21, 2001
    Date of Patent: March 23, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hermann-Jens Womelsdorf, Werner Hoheisel, Gerd Passing
  • Patent number: 6706220
    Abstract: In the mixture of metal and/or alloy particles and a liquid electrolytic medium, the metal and/or alloy particles are irregularly shaped, have a non-uniform surface and a bulk density of below 33% by weight of the specific density of the compact metal and/or the compact alloy, and the volume of the medium is larger than that which corresponds to the spaces between the particles in a dry packing.
    Type: Grant
    Filed: March 11, 2002
    Date of Patent: March 16, 2004
    Assignee: Grillo-Werke AG
    Inventor: Wolfgang Glaeser
  • Patent number: 6703006
    Abstract: A deodorant composition for topical application, which comprises a plurality of particles dispersed and a carrier, each particle comprising a glass microsphere at least partially coated with zinc oxide, a zinc salt, or any mixture of two or more thereof.
    Type: Grant
    Filed: August 23, 2001
    Date of Patent: March 9, 2004
    Assignee: The Gillette Company
    Inventors: Brian Edward Causton, Sydney Christopher Tavern
  • Patent number: 6696029
    Abstract: A method for the recovery of high purity zinc oxide products, and optionally iron-carbon feedstocks, from industrial waste streams containing zinc oxide and/or iron. The waste streams preliminary can be treated by adding carbon and an ammonium chloride solution, separating any undissolved components from the solution, displacing undesired metal ions from the solution using zinc metal, treating the solution to remove therefrom zinc compounds, and further treating the zinc compounds and the undissolved components, as necessary, resulting in the zinc products and the optional iron-carbon feedbacks. Once the zinc oxide has been recovered, the purification process is used to further purify the zinc oxide to obtain zinc oxide which is at least 99.8% pure and which has predeterminable purity and particle characteristics. Various zinc compounds may then be quickly, easily, and economically produced from this recovered zinc oxide.
    Type: Grant
    Filed: January 29, 1996
    Date of Patent: February 24, 2004
    Inventors: Allan S Myerson, Peter Robinson, Stephan Tabah
  • Patent number: 6627100
    Abstract: A current/voltage non-linear resistor comprises a sintered body having a main component of ZnO, an electrode applied to a surface of the sintered body and an insulation material applied to another surface of the sintered body. The main component containing, as auxiliary components, Bi, Co, Mn, Sb, Ni and Al, and the contents of the auxiliary components are respectively expressed as Bi2O3, Co2O3, MnO, Sb2O3, NiO and Al3+, of Bi2O3: 0.3 to 2 mol %, Co2O3: 0.3 to 1.5 mol %, MnO: 0.4 to 6 mol %, Sb2O3: 0.8 to 7 mol %, NiO: 0.5 to 5 mol % and Al3+: 0.001 to 0.02 mol %; a Bi2O3 crystalline phase in the sintered body including an &agr;-Bi2O3 phase representing at least 80% of the total Bi2O3 phase.
    Type: Grant
    Filed: April 25, 2001
    Date of Patent: September 30, 2003
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hideyasu Ando, Takeshi Udagawa, Yoshiyasu Ito, Hironori Suzuki, Hiroyoshi Narita, Koji Higashibata, Toshiya Imai, Kiyokazu Umehara, Yoshikazu Tanno
  • Patent number: 6627173
    Abstract: A process for the preparation of doped, pyrogenically prepared titanium dioxide is described. The titanium dioxide is doped with zinc oxide, platinum oxide, magnesium oxide, or aluminium oxide, by injecting an aerosol of the oxide into the production stream. The doped titanium dioxide may be used as a photocatalyst or UV absorber.
    Type: Grant
    Filed: March 27, 2001
    Date of Patent: September 30, 2003
    Assignee: Degussa AG
    Inventors: Ina Hemme, Helmut Mangold, Sven-Uwe Geissen, Anna Moiseev
  • Publication number: 20030114296
    Abstract: During regeneration of a sulfurized sorbent, the oxygen partial pressure in the regeneration zone is controlled to minimize sulfation of the sorbent.
    Type: Application
    Filed: December 19, 2001
    Publication date: June 19, 2003
    Inventors: Jason J. Gislason, Ronald E. Brown, Robert W. Morton, Glenn W. Dodwell
  • Patent number: 6555075
    Abstract: A method for preparing basic zinc carbonate from die casting ash, zinc skimming or zinc ash includes heating urea or a mixture of urea and ammonia and carbon dioxide with water in a closed vessel with zinc ash. After zinc is dissolved in sufficient quantities, the solution is cooled and filtered. The filtered solution is cemented with zinc dust to precipitate heavy metals and the filtered. The solution is preferably heated a second time to remove an iron precipitate. The solution is then heated a third time to precipitate the dissolved zinc as basic zinc carbonate, which is washed and dried. The filtrate and gases recovered from the heating steps are reused in the process.
    Type: Grant
    Filed: May 23, 2001
    Date of Patent: April 29, 2003
    Inventor: Raymond Lee Nip
  • Publication number: 20030057105
    Abstract: The present invention provides a composition comprising a saturated solution of zinc oxide in an aqueous sodium or potassium hydroxide solution wherein the concentrations of the zinc oxide and the sodium hydroxide in said solution are as set forth in FIG. 1, and the concentrations of the zinc oxide and potassium hydroxide are as set forth in FIG. 2.
    Type: Application
    Filed: September 27, 2001
    Publication date: March 27, 2003
    Applicant: Clariant International Ltd.
    Inventors: Baldev K. Bandlish, Vincent Wise Martin
  • Patent number: 6517789
    Abstract: An industrial waste stream recycling method for recovery of high purity zinc oxide products and other chemical and metal values from industrial waste streams containing zinc compounds by leaching the waste stream with a solution of 30% or greater by weight ammonium chloride, resulting in a first product solution and undissolved materials; adding zinc metal to the first product solution, whereby zinc-displaceable metal ions contained in the first product solution are displaced by the zinc metal and precipitate out of the first product solution as metals, leaving a second product solution; and diluting the second product solution with water, resulting in the precipitation of zinc oxide.
    Type: Grant
    Filed: April 30, 2001
    Date of Patent: February 11, 2003
    Inventors: Allan S. Myerson, Peter Robinson
  • Patent number: 6517802
    Abstract: A chemical synthetic route for nanostructured materials that is scalable to large volume production, comprising spray atomization of a reactant solution into a precursor solution to form a nanostructured oxide or hydroxide precipitate. The precipitate is then heat-treated followed by sonication, or sonicated followed by heat treatment. This route yields nanostructured doped and undoped nickel hydroxide, manganese dioxide, and ytrria-stabilized zirconia. Unusual morphological superstructures may be obtained, including well-defined cylinders or nanorods, as well as a novel structure in nickel hydroxide and manganese dioxide, comprising assemblies of nanostructured fibers, assemblies of nanostructured fibers and agglomerates of nanostructured particles, and assemblies of nanostructured fibers and nanostructured particles. These novel structures have high percolation rates and high densities of active sites, rendering them particularly suitable for catalytic applications.
    Type: Grant
    Filed: September 15, 2000
    Date of Patent: February 11, 2003
    Assignees: The University of Connecticut, Rutgers, The State University of New Jersey
    Inventors: Tongsan D. Xiao, Peter R. Strutt, Bernard H. Kear, Huimin Chen, Donald M. Wang
  • Patent number: 6497830
    Abstract: An ultraviolet light absorber containing, as an active ingredient, a zinc oxide type solid solution which is represented by the formula (1), (Zn)1−xM3+x−&dgr;O   (1) wherein M3+ is a trivalent metal such as Al, Fe, Ce or Ti, x is a number in the range of 0<x<=0.2, and &dgr; is a cationic lattice defect, and has an average secondary particle diameter of from 0.1 to 1.5 &mgr;m in a plate form and a BET specific surface area of at least 5 m2/g, an ultraviolet light resistant resin composition containing a resin and the above zinc oxide type solid solution and a sun block cosmetic material containing the above zinc oxide type solid solution.
    Type: Grant
    Filed: March 14, 2001
    Date of Patent: December 24, 2002
    Assignee: Kabushiki Kaisha Kaisui Kagaku Kenkyujo
    Inventor: Shigeo Miyata
  • Patent number: 6468498
    Abstract: A composite metal material of formula (I) are stable and not deteriorated for a long time and have excellent activities in photolyzing water with visible light: x(A)y(B)z(C)-p(P)n(N)  (I) wherein, (A) is Pb(Mg1/3Nb2/3)O3 or Pb(Zn1/3Nb2/3)O3, (B) is PbTiO3, (C) is LiTaO3, (P) is a metal selected from the group consisting of Pt, Au, Ag, Pd and Rh, (N) is an oxide of a metal selected from the group consisting of Ni, Co, Fe, Sr, Sc, Ru, Cu and Cd, x is a number in the range of 0.65 to 0.98, y is a number in the range of 0.01 to 0.34, z is a number in the range of 0.01 to 0.1, and p and n are each independently a number in the range of 0.01 to 5.
    Type: Grant
    Filed: May 25, 2001
    Date of Patent: October 22, 2002
    Assignee: Idbule Photonics Co., Ltd.
    Inventors: Sang-Goo Lee, Min-Chan Kim, Gil-Seon Kang, Wha-Young Lee, In-Kyu Song, Young-Gwan Ko
  • Publication number: 20020139688
    Abstract: A process for producing a zinc oxide acicular structure by growing an acicular zinc oxide on a substrate, the process comprising the steps of holding the substrate in an electrolytic solution in which at least zinc ions are present, and forming zinc oxide on the substrate by electrodeposition. The electrolytic solution contains at least one cosolute. Also disclosed is a photoelectric conversion device comprising a charge transport layer having the zinc oxide acicular structure.
    Type: Application
    Filed: March 20, 2002
    Publication date: October 3, 2002
    Inventors: Hiroshi Okura, Tohru Den, Kaoru Konakahara
  • Patent number: 6458319
    Abstract: The present invention is embodied in high performance p-type thermoelectric materials having enhanced thermoelectric properties and the methods of preparing such materials. In one aspect of the invention, p-type semiconductors of formula Zn4−xAxSb3−yBy wherein 0≦x≦4, A is a transition metal, B is a pnicogen, and 0≦y≦3 are formed for use in manufacturing thermoelectric devices with substantially enhanced operating characteristics and improved efficiency. Two methods of preparing p-type Zn4Sb3 and related alloys of the present invention include a crystal growth method and a powder metallurgy method.
    Type: Grant
    Filed: March 18, 1997
    Date of Patent: October 1, 2002
    Assignee: California Institute of Technology
    Inventors: Thierry Caillat, Alexander Borshchevsky, Jean-Pierre Fleurial
  • Patent number: 6365555
    Abstract: A process for the preparation of nanostructured materials in high phase purities using cavitation is disclosed. The method comprises mixing a metal containing solution with a precipitating agent and passing the mixture into a cavitation chamber. The chamber consists of a first element to produce cavitation bubbles, and a second element that creates a pressure zone sufficient to collapse the bubbles. The process is useful for the preparation of mixed metal oxide catalysts and materials for piezoelectrics and superconductors.
    Type: Grant
    Filed: October 25, 1999
    Date of Patent: April 2, 2002
    Assignee: Worcester Polytechnic Institute
    Inventors: William R. Moser, Oleg V. Kozyuk, Josef Find, Sean Christian Emerson, Ivo M. Krausz
  • Patent number: 6350946
    Abstract: A photoelectric conversion device having a photosensitive layer comprising semiconductor particles is disclosed, in which the semiconductor particles are obtained from a metal hydroxide gel or a precursor thereof present in a hydrophilic solvent. Also disclosed in a photoelectric cell including the photoelectric conversion device.
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: February 26, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyoteru Miyake, Tadao Sugimoto
  • Publication number: 20010013362
    Abstract: Provided are a zinc oxide thin film having an X-ray diffraction peak of the plane of zinc oxide crystal, a photoelectric conversion element having the zinc oxide thin film, and production processes thereof. By these, the texture level of the zinc oxide thin film is increased and the photoelectric conversion element is provided with excellent short circuit current density (Jsc).
    Type: Application
    Filed: April 6, 2001
    Publication date: August 16, 2001
    Inventor: Takaharu Kondo
  • Patent number: 6267949
    Abstract: The invention provides a sunscreen formulation including conventional UVB sunscreening agents and zinc oxide having an average particle size in the order of 150 to 800 nm. Preferably the zinc oxide used is pigment grade. Most preferably, zinc oxide prepared by the French process is used, although that produced by the American process is also suitable. The average particle size of the zinc oxide is most preferably in the order of 200-400 nm. Throughout this specification, the term “pigment grade” is used to define zinc oxide that has been produced by the French or American process. A further embodiment of the invention is a method of reducing or preventing the harmful effects of solar radiation on skin by applying inventive sunscreen formulation. A further embodiment of the invention relates to a sunscreen composition having a sun protection factor greater than 30 including zinc oxide having an average particle size of 150 to 800 nm.
    Type: Grant
    Filed: November 15, 1999
    Date of Patent: July 31, 2001
    Assignee: Soltec Research PTY Ltd.
    Inventor: Neil Graham Halls
  • Patent number: 6264903
    Abstract: An industrial waste stream recycling method for recovery of high purity zinc oxide products and other chemical and metal values from industrial waste streams containing zinc compounds by leaching the waste stream with a solution of 30% or greater by weight ammonium chloride, resulting in a first product solution and undissolved materials; adding zinc metal to the first product solution, whereby zinc-displaceable metal ions contained in the first product solution are displaced by the zinc metal and precipitate out of the first product solution as metals, leaving a second product solution; and diluting the second product solution with water, resulting in the precipitation of zinc oxide.
    Type: Grant
    Filed: June 22, 1999
    Date of Patent: July 24, 2001
    Inventors: Allan S. Myerson, Peter Robinson
  • Patent number: 6254940
    Abstract: The present invention related to methods of manufacturing oxide, nitride, carbide, and boride powders and other ceramic, organic, metallic, carbon and alloy powders and films and their mixtures having well-controlled size and crystallinity characteristics. This invention relates, more particularly, to a development in the synthesis of the ceramic, metallic, composite, carbon and alloy nanometer-sized particles with precisely controlled specific surface area, or primary particle size, crystallinity and composition. The product made using the process of the present invention and the use of that product are also claimed herein.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: July 3, 2001
    Assignee: University of Cincinnati
    Inventors: Sotiris E. Pratsinis, Srinivas Vemury