Aerosol Hair Preparation Patents (Class 424/DIG1)
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Patent number: 4196190Abstract: Acrylic polymer solutions having superior properties when used as hair setting or holding resins are disclosed. Specific polymers disclosed are derived from (1) alkyl acrylates with 2-8 carbon alkyl groups, (2) methyl methacrylate, (3) hydroxyethyl methacrylate, and (4) methacrylic acid in proportions yielding a film forming resin readily soluble in shampoo, with a Tg between about 40.degree. C. and 80.degree. C., a molecular weight between about 25,000 and 250,000 and not more than 50 ppm of unreacted alkyl acrylate monomer.Type: GrantFiled: January 9, 1978Date of Patent: April 1, 1980Assignee: Rohm and Haas CompanyInventors: David R. Gehman, William A. Kirn
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Patent number: 4192862Abstract: The invention relates to a hairspray product having improved hair-holding properties. The hairspray composition comprises, as is usual, a solution of a hairspray resin in a suitable solvent, but to improve the holding power there is also included a minor amount of a drag reducing agent which is soluble in the solvent for the hairspray resin. The drag reducing agent is present in an amount such that the weight ratio of the hairspray resin to the drag reducing agent is 10,000 to 2:1. The drag reducing agent amounts to less than 0.3% by weight of the composition.Type: GrantFiled: July 26, 1978Date of Patent: March 11, 1980Assignee: Lever Brothers CompanyInventor: Roger W. Pengilly
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Patent number: 4189468Abstract: A cosmetic composition for the hair comprises at least one water-soluble crosslinked polymer obtained by crosslinking a polyamino-polyamide with a crosslinking agent, said polyamino-polyamide being prepared by the polycondensation of (a) an acidic compound selected from the group consisting of (i) organic dicarboxylic acid, (ii) ethylenically unsaturated aliphatic mono- or di-carboxylic acid, (iii) ester of said acids of (i) and (ii), and (iv) mixtures of (i), (ii) and (iii) on (b) a polyamine selected from the group consisting of bis-primary and mono- or bis-secondary polyalkylene polyamines, said polyamine (b) being replaceable by a member selected from the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole percent bis-primary amine and (3) 0-40 mole percent bis-secondary amine, said crosslinking agent being selected from the group consisting of (a') simple bi-functional compounds selected from bis-halohydrins, bis-azetidinium, bis-haloacyl diamine and alkyl bis-halides, (b') oliType: GrantFiled: February 27, 1978Date of Patent: February 19, 1980Assignee: L'OrealInventors: Guy Vanlerberghe, Henri Sebag, Jean-Francois Grollier, Alexandre Zysman
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Patent number: 4180084Abstract: Hair-care compositions in the form of aqueous, alcoholic or aqueous alcoholic solutions, creams, gels, emulsions, or of aerosols which optionally contain a propellant are provided which contain at least one polymeric quaternary ammonium salt which contains cationic units of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and represent alkyl, cycloalkyl or alkenyl, aryl or aralkyl, or (R.sub.1 and R.sub.2) and/or (R.sub.3 and R.sub.4) together with the nitrogen atom to which they are bonded, form an unsubstituted or substituted heterocyclic ring containing 3 to 6 ring members,A.sub.1 represents an optionally substituted alkylene, cycloalkylene or aralkylene bridging group and A.sub.2 is a group of the formula ##STR2## The compositions are especially useful as shampoos.Type: GrantFiled: April 25, 1978Date of Patent: December 25, 1979Assignee: Ciba-Geigy CorporationInventors: Hans Wegmuller, Ulrich Horn, Walter Hungerbuhler, Jaroslav Haase
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Patent number: 4174295Abstract: The present invention concerns new propellant compositions for aerosols. More particularly, the present invention relates to propellant compositions for aerosols, characterized in that said compositions consist of a mixture of a chlorofluorocarbon or fluorocarbon (A) containing hydrogen and selected from the group consisting of CHClF.sub.2, CH.sub.2 F.sub.2 and CF.sub.3 --CH.sub.3, with a chlorofluorocarbon or fluorocarbon (B) containing hydrogen and selected from the group consisting of: CH.sub.2 ClF, CClF.sub.2 --CHClF, CF.sub.3 --CHClF, CHF.sub.2 --CClF.sub.2, CHClF--CHF.sub.2, CF.sub.3 --CH.sub.2 --Cl, CHF.sub.2 --CHF.sub.2, CF.sub.3 --CH.sub.2 F, CClF.sub.2 --CH.sub.3 and CHF.sub.2 --CH.sub.3. In addition to propellant A and propellant B, there may be included a hydrocarbon propellant so that a ternary propellant composition is provided.Type: GrantFiled: August 9, 1977Date of Patent: November 13, 1979Assignee: Montedison S.p.A.Inventors: Gianangelo Bargigia, Gerardo Caporiccio, Giuliano Carniselli
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Patent number: 4173627Abstract: Hair lacquer compositions in pressurized containers are rendered less inflammable consistently throughout the emptying of the container by incorporating bromotrifluoromethane therein in an amount from 5 to 30% by weight based on the weight of the composition and providing the container with a valve provided with an inlet for additional gas.Type: GrantFiled: April 17, 1978Date of Patent: November 6, 1979Assignee: L'OrealInventors: Annie Madrange nee Dermain, Henri M. de Montalembert, Pierre Meurice, Jean-Louis Refregier
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Patent number: 4165367Abstract: Hair preparations containing a copolymer of about 95 to 45 mole percent of vinyl pyrrolidone and about 5 to 50 mole percent of diloweralkylaminoalkyl acrylate or methacrylate, and method of setting and conditioning hair therewith.Type: GrantFiled: June 10, 1977Date of Patent: August 21, 1979Assignee: GAF CorporationInventor: Paritosh M. Chakrabarti
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Patent number: 4164562Abstract: A pressurized hair spray composition having reduced flammability, having from 20 to 35 percent aliphatic hydrocarbons and 2 to 12 percent water.Type: GrantFiled: October 21, 1977Date of Patent: August 14, 1979Assignee: American Cyanamid CompanyInventors: Arun Nandagiri, Uma Tripathi, LeRoy Hunter
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Patent number: 4150115Abstract: Quaternized polyamine polymers are employed in cosmetic compositions for application to the hair or skin. The polymer has recurring units of the formula: ##STR1## WHEREIN A is polymethylene having 2-10 carbon atoms, B is selected from polymethylene having 3-10 carbon atoms, xylylidenyl group --CH.sub.2 --C.sub.6 H.sub.4 --CH.sub.2 -- ortho, meta or para, --(CH.sub.2).sub.x --O--(CH.sub.2).sub.x -- wherein x is 2 or 3, or --CH.sub.2 --CHOH--CH.sub.2 --; R.sub.1 and R.sub.3 represent an aliphatic radical having 1-12 carbon atoms; R.sub.2 and R.sub.4 represent an aliphatic radical having 1-20 carbon atoms; R.sub.5 is hydrogen or an aliphatic, alicyclic, aryl or arylaliphatic radical containing 1-20 carbon atoms; R.sub.6 is an aliphatic or arylaliphatic radical containing 1-20 carbon atoms; X is a halide anion; Y is selected from a halide anion, SO.sub.4 H.sup..crclbar. or CH.sub.3 SO.sub.4.sup..crclbar. ; and n and p are whole numbers with p being able to be 0, such that the ratio p/n+p ranges from 0 to 0.95.Type: GrantFiled: November 15, 1976Date of Patent: April 17, 1979Assignee: L'OrealInventors: Bernard Jacquet, Gerard Lang
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Patent number: 4134968Abstract: An aerosol composition comprising a liquid mixture of hydrocarbon propellant, an alcoholic solvent and, to reduce flammability, water and methylene chloride and/or 1,1,1-trichloroethane, wherein the liquid mixture forms a single phase consisting essentially of 5-30% by weight of the hydrocarbon propellant, 5-30% by weight of water, 10-40% by weight of methylene chloride and/or 1,1,1-trichloroethane, and 37-80% by weight of ethanol, n-propanol or iso-propanol. The composition does not require to be shaken before use.Type: GrantFiled: February 10, 1977Date of Patent: January 16, 1979Assignee: Lever Brothers CompanyInventor: Malcolm R. D. Stebles
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Patent number: 4117853Abstract: An improvement in the process of setting hair comprising applying a film of a vinyl acetate copolymerizate consisting essentially of(a) from 65% to 80% by weight of vinyl acetate units,(b) from 10% to 20% by weight of units of a maleic acid diester with a straight-chained alkanol-1 having from about 8 to 10 carbon atoms,(c) from 5% to 20% by weight of units of a mono-olefinically unsaturated ester having from 6 to 8 carbon atoms and a hydrophilic group, and(d) from 3% to 10%, particularly 7%, by weight of crotonic acid and salts thereof,To the hair after setting the same; and hair setting agents in the form of hair sprays and setting lotions containing up to 10% by weight of said vinyl acetate copolymerizate and/or salts thereof.Type: GrantFiled: September 14, 1977Date of Patent: October 3, 1978Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Gunter Reese, Hermann Kroke, Fanny Scheuermann
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Patent number: 4118423Abstract: Aminated .gamma.-dialdehyde and the quaternary ammonium salts thereof are prepared by acid hydrolysis of their respective corresponding 2,5-dialkoxy 3-amino 4-hydroxy tetrahydrofurans or by acid hydrolysis of their respective corresponding tetraalkyl acetals. The aminated .gamma.-dialdehydes and the quaternary ammonium salts thereof are usefully employed in cosmetic compositions to tan the skin or to strengthen or restructure the hair.Type: GrantFiled: December 14, 1976Date of Patent: October 3, 1978Assignee: L'OrealInventors: Guy Vanlerberghe, Georges Rosenbaum
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Patent number: 4107289Abstract: Substituted pyran compounds as exemplified by 2,5-dimethyl-3,4-dihydro-2H-pyran-2-carbinol are used as chemically active deodorizing agents in admixture with substrates such as gelatinous substances, powders, sprays, soaps, etc.Type: GrantFiled: July 29, 1976Date of Patent: August 15, 1978Assignee: Naarden International Holland, B.V.Inventor: Jerome G. Kaufman
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Patent number: 4087550Abstract: A method and composition for combatting the greasy and unaesthetic appearance of the hair and to improve the appearance of the skin comprises in a carrier at least one active component of the formula ##STR1## wherein R.sub.1 and R.sub.2 are methyl, ethyl, isopropyl, cyclohexyl, benzyl or .beta.-hydroxyethyl, or R.sub.1 and R.sub.2 taken together form --(CH.sub.2).sub.2 --(CH.sub.2).sub.2 --, --(CH.sub.2).sub.2 --CH.sub.2 --(CH.sub.2).sub.2 --, --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --, ##STR2## and R is (i) linear or branched alkyl having 1-18 carbon atoms, (ii) alkenyl having 3-18 carbon atoms, (iii) alkyl having 2-3 carbon atoms and substituted by 1-2 alcohol functions, (iv) --(CH.sub.2).sub.m --CH(OR.sub.3).sub.2 wherein R.sub.3 is alkyl having 1-4 carbon atoms and m is 1-2, (v) --(CH.sub.2).sub.n R.sub.4 wherein n is 0, 1 or 2 and R.sub.4 is 2-pyridyl or phenyl, (vi) --(CH.sub.2).sub.q R'.sub.4 wherein q is 0 or 1 and R'.sub.Type: GrantFiled: April 15, 1976Date of Patent: May 2, 1978Assignee: L'OrealInventors: Claude Bouillon, Charles Vayssie
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Patent number: 4080465Abstract: A method for improving the appearance of the greasy skin of the face of a person having a skin so characterized, which comprises topically applying to the skin of the face an effective amount of a composition containing as an active ingredient a cis or trans 3,4-thiolannediol, its cis or trans S-oxide derivatives or its cis or trans S-dioxide derivatives.Type: GrantFiled: January 27, 1976Date of Patent: March 21, 1978Assignee: Societe Anonyme dite: L'OrealInventors: Claude Bouillon, Michel Colin
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Patent number: 4073898Abstract: A composition for treating oily hair or skin to reduce the oily appearance thereof comprises in an appropriate vehicle an active compound having the formula ##STR1## wherein R.sub.3 is lower alkyl containing 1-3 carbon atoms; n= 0 or 1 with the proviso that when n= 0, ##STR2## and when n= 1, R.sub.2 is hydrogen; and HX represents a mineral or organic acid. The composition can be applied topically or be orally administered to a person whose hair or skin has an oily appearance to reduce said oily appearance.Type: GrantFiled: December 31, 1975Date of Patent: February 14, 1978Assignee: L'OrealInventors: Claude Bouillon, Claudine Berrebi
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Patent number: 4059688Abstract: Hair fixation with fluorine containing acrylate or methacrylate terpolymers or with mixtures thereof with known non-fluorine containing hair fixing polymers.Type: GrantFiled: June 29, 1976Date of Patent: November 22, 1977Assignee: Clairol IncorporatedInventors: Ira E. Rosenberg, John A. Ferguson, Norman P. Loveless
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Patent number: 4054147Abstract: Diphenylamine of the formula ##STR1## wherein R.sub.1 and R.sub.4 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, amino, lower alkyl amino, acylamino, lower carbamylalkyl amino, lower hydroxyalkyl amino, lower carbalkoxy amino and ureido;R.sub.2 and R.sub.3 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, acylamino and ureido;R.sub.5 represents a member selected from the group consisting of hydrogen, halogen, lower alkyl and lower alkoxy;R.sub.6 represents a member selected from the group consisting of lower hydroxyalkyl, lower amino alkyl, lower acylamino alkyl, lower mesylamino alkyl, lower carbamylalkyl, lower sulfoalkyl, lower piperidinoalkyl, lower morpholinoalkyl, lower mono alkyl lower amino alkyl and lower dialkyl lower amino alkyl; andR.sub.Type: GrantFiled: February 21, 1975Date of Patent: October 18, 1977Assignee: L'OrealInventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
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Patent number: 4046786Abstract: Indoaniline of the formula ##STR1## wherein R.sub.1 represents hydrogen, halogen, alkyl or alkoxy;R.sub.2 represents alkyl, hydroxyalkyl, carbamylalkyl, piperidinoalkyl, morpholinoalkyl, sulfoalkyl, dialkylaminoalkyl, acylaminoalkyl, (preferably acetylaminoalkyl or benzoylaminoalkyl) and mesylaminoalkyl;R.sub.3 represents hydroxyalkyl, carbamylalkyl, piperidinoalkyl, morpholinoalkyl, sulfoalkyl, dialkylaminoalkyl, acylaminoalkyl, (preferably acetylaminoalkyl or benzoylaminoalkyl), mesylaminoalkyl; or R.sub.2 and R.sub.3 together form with the nitrogen atom to which they are attached a heterocycle selected from piperidino or morpholino;R.sub.4, r.sub.5 and R.sub.6 each independently represents hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino, and R.sub.5 can also represent amino, alkylamino, hydroxyalkylamino or carbamylalkylamino. The alkyl and alkoxy groups above can contain from 1 to 6 carbon atoms and the acyl group can contain from 2 to 7 carbon atoms.Type: GrantFiled: October 3, 1975Date of Patent: September 6, 1977Assignee: L'OrealInventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
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Patent number: 4044121Abstract: Hair spray compositions are disclosed comprising conventional film-forming resins in a solvent vehicle to which have been added fluorocarbon compounds formed by the reaction of an aromatic anhydride or dibasic acid and a fluorocarbon amine or alcohol.Type: GrantFiled: March 11, 1976Date of Patent: August 23, 1977Assignee: Minnesota Mining and Manufacturing CompanyInventor: Su Sen Ko
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Patent number: 4036241Abstract: A hair spray composition comprising an alcoholic medium having substantially uniformly dispersed therein a film forming carboxylic acid containing resin and a polyvalent metal alkyl carboxylic acid salt having from 5 to 20 carbon atoms, said composition having a pH from about 3.5 to 7.5.Type: GrantFiled: October 1, 1975Date of Patent: July 19, 1977Assignee: Avon Products, Inc.Inventors: Gerhart Karg, Christopher D. Vaughan
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Patent number: 4030512Abstract: A hair lacquer or hair setting lotion composition comprises in a cosmetic carrier or vehicle at least one bi- or tri-sequenced copolymer comprising at least one sequence (A) having the formula ##STR1## wherein Y is a saturated hydrocarbon chain containing 2-4 carbon atoms or a hydrocarbon chain containing 2-4 carbon atoms and interrupted by sulfur or oxygen, R.sub.1 and R.sub.2 are alkyl containing 1-4 carbon atoms, n is 0 or 1 and HX is hydrochloric, hydrobromic, lactic or acetic acid, and at least one sequence (B) resulting from the anionic polymerization of a polymerizable monomer.Type: GrantFiled: December 29, 1975Date of Patent: June 21, 1977Assignee: Societe Anonyme dite: L'OrealInventors: Christos Papantoniou, Quintino Gaetani
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Patent number: 4025301Abstract: A composition for dyeing hair comprises in a cosmetic vehicle at least one dye compound of the formula ##STR1## wherein B is selected from the group consisting of ##STR2## and ##STR3## wherein R is lower alkyl containing 1-4 carbon atoms, R.sub.1 is selected from the group consisting of hydrogen, lower alkyl containing 1-4 carbon atoms, lower alkoxy containing 1-4 carbon atoms and chlorine,R.sub.2 is selected from the group consisting of hydrogen, methyl and methoxy,R.sub.4 is selected from the group consisting of hydrogen, methyl, chlorine, nitro, amino and acetylamino,R.sub.3 is hydrogen or together with R.sub.4 forms an unsaturated 6 membered ring carrying a hydroxy substituent chelated with one of the nitrogen atoms of the azo link, and ##STR4## where R.sub.5 is selected from the group consisting of hydrogen, -CH.sub.3, -C.sub.2 H.sub.5 and .beta.-hydroxyethyl, and R.sub.6 is selected from the group consisting of hydrogen, --CH.sub.3, --C.sub.2 H.sub.5, .beta.-hydroxyethyl, phenyl and -CH.sub.2 SO.sub.Type: GrantFiled: September 26, 1975Date of Patent: May 24, 1977Assignee: Societe Anonyme dite: L'OrealInventor: Gerard Lang
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Patent number: 4023926Abstract: 2,5-Diamino-1,4-benzoquinones are used in hair dye compositions.Type: GrantFiled: July 31, 1975Date of Patent: May 17, 1977Assignee: Societe Anonyme dite: L'OrealInventors: Andree Bugaut, Monique Laudon
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Patent number: 4015612Abstract: Hair styling compositions which have excellent holding characteristics at elevated humidity and impart a soft hand and natural sheen to hair comprising a solution of a film-forming polymer modified with a fluoroaliphatic radical containing compound are disclosed.Type: GrantFiled: April 26, 1974Date of Patent: April 5, 1977Assignee: Minnesota Mining and Manufacturing CompanyInventors: Frank J. Pavlik, Robert L. Hansen
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Patent number: 4014990Abstract: Aminated .gamma.-dialdehyde and the quaternary ammonium salts thereof are prepared by acid hydrolysis of their respective corresponding 2.5-dialkoxy 3-amino 4-hydroxy tetrahydrofurans or by acid hydrolysis of their respective corresponding tetraalkyl acetals. The aminated .gamma.-dialdehydes and the quaternary ammonium salts thereof are usefully employed in cosmetic compositions to tan the skin or to strengthen or restructure the hair.Type: GrantFiled: April 24, 1974Date of Patent: March 29, 1977Assignee: Societe Anonyme dite: L'OrealInventors: Guy Vanlerberghe, Georges Rosenbaum
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Patent number: 4013787Abstract: Piperazine-based low molecular weight film-forming cationic polymer is employed in a cosmetic hair-conditioner composition comprising a solution of the polymer in amounts of about 0.1-5 weight percent of the composition in a solvent such as water, acidified water, or aqueous alcohol solution.Type: GrantFiled: July 29, 1975Date of Patent: March 22, 1977Assignee: Societe Anonyme dite: L'OrealInventors: Guy Varlerberghe, Henri Sebag
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Patent number: 4012501Abstract: The hair-care composition broadly comprises an ethanolic cosmetic vehicle and between about 1 and 20% by weight, based on the total weight of the composition, of film-forming thermoplastic resinous polymeric material which in dried condition is resistant to softening by humidity, insoluble in water alone but dispersible in water having a cosmetic pH, fully soluble in ethanol, and consists essentially of the addition free-radical polymerization product formed by polymerizing a monomeric mixture consisting essentially of, by weight percent: 1 to 20% of 1,1 dimethyl-1,(2-hydroxypropyl) amine methacrylimide; 8 to 45% of N-vinyl pyrrolidone; and 35 to 89% of vinyl acetate.Type: GrantFiled: May 8, 1975Date of Patent: March 15, 1977Assignee: La Maur Inc.Inventor: Elliott Farber
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Patent number: 4010872Abstract: Packages are described wherein two compositions are maintained isolated from each other within a container, the first composition comprising an oxidation hair dye and the other comprising hydrogen peroxide. The container is fitted with valve means which communicate with each composition, actuation of the valve means resulting in mixing of portions of each composition and dispensing of the mixture as a hair dye. Through the addition of a reducing agent or a hydrogen peroxide decomposition catalyst to the first composition, the hair dye can be dispensed in a warmed state. A process for packaging of plural fluids to insure uniform dispensing in which one is a foamable liquid is described wherein the foamable liquid is placed within an inner compartment within a container separated from the remainder of the container by a movable wall and a pressurized fluid is placed inside the container outside the inner compartment.Type: GrantFiled: March 13, 1972Date of Patent: March 8, 1977Assignee: Dart Industries Inc.Inventors: David S. Lozano, Samuel B. Prussin
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Patent number: 4007005Abstract: Aqueous solutions of water soluble, reactive polyamide-epichlorohydrin resins and vinylpyrrolidone polymers serve upon application to hair as a spray or lotion to markedly improve the resistance of set curls to relaxation under conditions of high humidity.Type: GrantFiled: June 19, 1975Date of Patent: February 8, 1977Assignee: Redken Laboratories, Inc.Inventor: Kanu I. Patel
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Patent number: 3993745Abstract: Hair setting lotions, gels, hair sprays and grooming aids, containing distinctly minor proportions of hydrophobiclipophobic perfluorinated compounds.Type: GrantFiled: May 31, 1974Date of Patent: November 23, 1976Assignee: Alberto Culver CompanyInventors: John A. Cella, Robert A. Lukey, August Emil Fiebig, Jr., Frank J. Pum
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Patent number: 3986825Abstract: A hair treating composition containing, in addition to a hair coloring agent, a water soluble secondary or tertiary amine polymer or a polymer of diallylamine or a quaternary polymer of diallyldialkylammonium salts which improves the surface characteristics of hair.Type: GrantFiled: May 14, 1975Date of Patent: October 19, 1976Assignee: The Gillette CompanyInventor: Phillip E. Sokol
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Patent number: 3984402Abstract: Indoaniline having the formula ##SPC1##Wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each independently represent a member selected from the group consisting of hydrogen, lower alkyl or halogen with 1 - 2 of these substituents being other than hydrogen; R.sub.5, R.sub.6 and R.sub.7 each independently represent a member selected from the group consisting of hydrogen, lower alkyl and lower alkoxy; R.sub.8 and R.sub.9 each independently represent a member selected from the group consisting of hydrogen, lower alkyl and lower alkyl substituted with a member selected from the group consisting of amino, hydroxy, carbamoyl, piperidinyl and acylamino, R.sub.8 and R.sub.5 or R.sub.9 and R.sub.Type: GrantFiled: December 24, 1974Date of Patent: October 5, 1976Assignee: L'OrealInventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
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Patent number: 3984536Abstract: A cosmetic composition for use as a hair lacquer or hair-setting lotion contains an essentially homogeneous vinyl acetate/crotonic acid copolymer, the macromolecular chains of which contain essentially the same content of each of vinyl acetate and crotonic acid along the entire length thereof. The content of each of vinyl acetate and crotonic acid does not vary more than 2.5% by weight relative to the average content of each in essentially all of the macromolecular chains, along essentially the entire length of each of said chains.Type: GrantFiled: February 19, 1975Date of Patent: October 5, 1976Assignee: L'OrealInventors: Andre Viout, Paul Roussopoulos, Christos Papantoniou
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Patent number: 3984443Abstract: Indamine having the formula ##SPC1##Wherein R and R' each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms, lower alkoxy having 1-4 carbon atoms, amino, acylamino wherein the acyl moiety has 1 to 4 carbon atoms and hydroxy, with the proviso that one, but not both of R and R' is said amino, acylamino or hydroxy; R.sub.1 and R.sub.2 each independently represent a member selected from the group consisting of lower alkyl having 1-4 carbon atoms and lower alkyl having 1-4 carbon atoms and substituted with a member selected from the group consisting of hydroxy, acylamino wherein the acyl moiety has 1 to 4 carbon atoms, carbamyl, piperidino, benzoylamino and alkylsulfonamido wherein the alkyl moiety has 1 to 4 carbon atoms; R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.Type: GrantFiled: February 25, 1975Date of Patent: October 5, 1976Assignee: L'OrealInventors: Gregoire Kalopissis, Andre Bugaut, Francoise Estradier
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Patent number: 3981987Abstract: Copolymers obtained by copolymerization of vinyl esters of aliphatic carboxylic acids and/or acrylic or methacrylic acid esters of aliphatic alcohols, with half-esters of ethylenically unsaturated dibasic carboxylic acids, followed by neutralization with bases, are used in hair setting compositions.Type: GrantFiled: January 8, 1975Date of Patent: September 21, 1976Assignee: BASF AktiengesellschaftInventors: Wolfgang Linke, Karl Herrle, Wolfgang Schwarz, Johannes Perner
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Patent number: 3980091Abstract: This invention is concerned with the pretreatment of hair on the human head, preceding shampooing the hair with anionic type hair shampoos, and with compositions for effecting such pretreatment, to obtain highly improved manageability of the hair after shampooing and with improved fullness, combability and other desired properties of the hair. The pretreatment compositions utilize readily water-soluble quaternary ammonium compounds, particularly in combination with certain agents, notably polyethylenimines and N-ethanolacetamide, and desirably together with various supplemental ingredients.Type: GrantFiled: January 6, 1975Date of Patent: September 14, 1976Assignee: Alberto Culver CompanyInventors: George F. Dasher, Kathleen A. O'Cull, Thomas J. Schamper
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Patent number: 3977825Abstract: Indoaniline of the formula ##SPC1## wherein R.sub.1 represents hydrogen, halogen, alkyl or alkoxy; R.sub.2 and R.sub.3 represent alkyl; R.sub.4, R.sub.5 and R.sub.6 each independently represent hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino and R.sub.5 can also represent amino, alkylamino, hydroxy alkylamino or carbamylalkylamino, the alkyl and alkoxy groups above being able to contain 1 to 6 carbon atoms and the acyl group from 2 to 7 carbon atoms with the condition that R.sub.5 does not represent hydrogen, chlorine, methyl or methoxy and when R.sub.5 represents acetylamino, R.sub.6 does not represent hydrogen; it being understood that the above compounds can be present in the tautomeric form of that represented by formula (I). The indoaniline is usefully employed in dye compositions for keratinic fibers, especially living human hair.Type: GrantFiled: June 24, 1974Date of Patent: August 31, 1976Assignee: L'OrealInventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
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Patent number: 3977826Abstract: Terpenes and their derivatives provide improved stability to aqueous solutions containing hydrogen peroxide as well as to aerosol co-dispensing hair coloring systems containing oxidation dye compositions.Type: GrantFiled: February 21, 1975Date of Patent: August 31, 1976Assignee: Clairol IncorporatedInventor: Sigmund Iscowitz
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Patent number: 3972336Abstract: A process for setting hair is disclosed comprising the steps of applying to the hair a solution of sulfonated polymer selected from the group consisting of sulfonated polystyrene, sulfonated interpolymers of styrene and ethylenically unsaturated comonomers, and soluble salts of said sulfonated polymers, setting the hair in the desired configuration, and allowing the hair to dry while it is retained in the desired configuration.Type: GrantFiled: April 18, 1975Date of Patent: August 3, 1976Assignee: National Starch and Chemical CorporationInventors: Frank A. Nowak, Jr., Frank Theodore Koehler, Jr.
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Patent number: 3972998Abstract: A hair cosmetic composition, for example a shampoo, for the treatment of wet hair on the head to reduce the time necessary for drying the hair, including a vinyl polymer containing monomers of the general formula ##EQU1## where Y is a partially or wholly fluorinated C.sub.1 -C.sub.11 alkyl group and Y' and Y" individually are either the same or different partially or wholly fluorinated C.sub.1 -C.sub.11 alkyl groups or hydrogen atoms and R.sup.2 is a hydrogen atom or a methyl group.Type: GrantFiled: November 15, 1974Date of Patent: August 3, 1976Assignee: Lever Brothers CompanyInventor: John Anthony Keiner
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Patent number: 3968218Abstract: A method and composition for combatting the greasy and unaesthetic appearance of the hair and to improve the appearance of the skin comprises in a carrier at least one active component of the formula ##EQU1## wherein R.sub.1 and R.sub.2 are methyl, ethyl, isopropyl, cyclohexyl, benzyl or .beta.-hydroxyethyl, or R.sub.1 and R.sub.2 taken together form --(CH.sub.2).sub.2 --(CH.sub.2).sub.2 --, --(CH.sub.2).sub.2 --CH.sub.2 --(CH.sub.2).sub.2 --, --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --, ##EQU2## or ##EQU3## ; and R is (1) linear or branched alkyl having 1-18 carbon atoms, (ii) alkenyl having 3-18 carbon atoms, (iii) alkyl having 2-3 carbon atoms and substituted by 1-2 alcohol functions, (iv) --(CH.sub.2).sub.m --CH(OR.sub.3).sub.2 wherein R.sub.3 is alkyl having 1-4 carbon atoms and m is 1-2, (v) --(CH.sub.2).sub.n R.sub.4 wherein n is 0, 1 or 2 and R.sub.4 is 2 -pyridyl or phenyl, (vi) --(CH.sub.2).sub.q R'.sub.4 wherein q is 0 or 1 and R'.sub.Type: GrantFiled: September 27, 1973Date of Patent: July 6, 1976Assignee: L'OrealInventors: Claude Bouillon, Charles Vayssie
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Patent number: 3966403Abstract: Copolymer of (a) an unsaturated acid having the formula R--CH = CH--(CH.sub.2 --O--CH.sub.2).sub.n --COOH wherein n = 0 or 1, and when n = O, R = CH.sub.3 and when n = 1, R = H, (b) a vinyl ester of the formula ##EQU1## wherein R is CH.sub.3 or C.sub.2 H.sub.5, (c) at least one branched allyl or methallyl ester of the formula ##EQU2## wherein R' represents hydrogen or CH.sub.3, R.sub.1 represents a saturated hydrocarbon chain, linear or branched, having 1-6 carbon atoms and R.sub.2 represents CH.sub.3 or CH(CH.sub.3).sub.2, with the proviso that the sum of the number of the carbon atoms in R.sub.1 +R.sub.2 is equal to or less than 7 and (d) a monomer selected from the group consisting of a vinyl ether of the formula CH.sub.2 = CH--O--R.sub.3 wherein R.sub.3 is linear or branched alkyl having 1-12 carbon atoms, a vinyl ester having a fatty chain and having the formula ##EQU3## wherein R.sub.Type: GrantFiled: March 31, 1975Date of Patent: June 29, 1976Assignee: L'OrealInventors: Christos Papantoniou, Jean-Claude Grognet
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Patent number: 3966404Abstract: Terpolymer of crotonic acid, vinyl acetate and an allyl or methallyl ester having the formula ##EQU1## wherein R' hydrogen or CH.sub.3, R.sub.1 is a saturated hydrocarbon chain containing 1-6 carbon atoms and R.sub.2 is -CH.sub.3 or -CH(CH.sub.3).sub.2, with the proviso that the sum of the number of carbon atoms in R.sub.1 + R.sub.2 is equal to or less than 7. The terpolymer is employed with a cosmetic carrier or vehicle to provide a cosmetic composition for the hair, such as a hair lacquer or hair setting lotion, generally in amounts of about 1-4 weight percent of the composition.Type: GrantFiled: March 31, 1975Date of Patent: June 29, 1976Assignee: L'OrealInventors: Christos Papantoniou, Jean-Claude Grognet
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Patent number: 3966087Abstract: An aerosol hairsetting preparation comprises a film-forming resin and a minor amount of a propellant dissolved in water and optionally a water-miscible organic solvent. The product is preferably dispensed from an aerosol can having two compartments connected by a gas valve, one compartment containing the product and the other containing propellant gas.Type: GrantFiled: March 29, 1974Date of Patent: June 29, 1976Assignee: Lever Brothers CompanyInventors: Kenneth Vasey Curry, Rustom Kooverji Gamadia, Barry Graham Pike
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Patent number: 3963764Abstract: Indoaniline having the formula ##SPC1##Wherein Z represents amino, acylamino or hydroxy; R.sub.5, R.sub.6 and R.sub.7 each independently represent hydrogen, lower alkyl or lower alkoxy; R.sub.8 and R.sub.9 each independently represent hydrogen, lower alkyl or lower alkyl substituted with hydroxy, carbamoyl, acylamino or piperidinyl, R.sub.8 and R.sub.5 or R.sub.9 and R.sub.6 being able to form with the adjacent nitrogen and carbon atoms a dihydrooxazine or pyrroline heterocycle; and the salts formed by these indoanilines with an organic or inorganic acid, and the double zinc salts of these indoanilines, and the tautomers thereof. These indoanilines are usefully employed for dyeing keratinous fibers, and in particular, human hair.Type: GrantFiled: May 27, 1975Date of Patent: June 15, 1976Assignee: L'OrealInventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
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Patent number: 3959463Abstract: A hair dressing composition comprising a hair substantive quaternary resin to impart hair-holding properties to hair when applied, and a grooming agent; the grooming agent preferably being incompatible with the quaternary resin.Type: GrantFiled: January 24, 1975Date of Patent: May 25, 1976Assignee: Bristol-Myers CompanyInventors: Ara Nersesian, Fred Hubner, Taras Durbak
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Patent number: 3958581Abstract: A cosmetic composition to strengthen the hair which comprises (a) a cosmetic vehicle containing a member selected from water, ethanol, isopropanol or mixtures thereof (b) 0.2 to 25 percent by weight of a cationic polymer and (c) 0.01 - 0.5 mole per gram of cationic polymer of a divalent metal salt selected from the carbonate, silicate, nitrate, acetate, gluconate, pantothenate and lactate of calcium, magnesium, manganese, iron, strontium, zinc and cadmium.Type: GrantFiled: October 15, 1974Date of Patent: May 25, 1976Assignee: L'OrealInventors: Jean-Louis Abegg, Jean-Pierre Boiteux, Colette Hourseau
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Patent number: 3959462Abstract: A process for keeping hair cleaner longer by applying to the hair a fluorine-containing polymer and products containing such polymers.Type: GrantFiled: August 26, 1974Date of Patent: May 25, 1976Assignee: The Procter & Gamble CompanyInventors: Lawrence Roy Parks, Stuart Elliot Builder
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Patent number: 3954725Abstract: An acyl amide product of reaction of polypeptides useful in cosmetics such as hair sprays because it is alcohol soluble and forms continuous films which are insoluble in water of neutral or acidic pH, is prepared by hydrolyzing proteins with either alkali metal hydroxides or calcium hodroxide mixture, bonding to the hydrolyzate an acyl radical selected from the group consisting of 12, 14, 16 and 18 carbon atoms through amide linkages to produce reaction products of for example, alkali metal hydrolyzates, the reaction products of the respective acyl radicals having an average total molecular weight in the ranges of 433 to 583; 386 to 486; 389 to 489; and 392 to 467.Type: GrantFiled: May 17, 1974Date of Patent: May 4, 1976Assignee: Wilson Pharmaceutical & Chemical CorporationInventors: Vernon L. Johnsen, Thomas M. Weisinger