Abstract: Blocked polyisocyanates and one-component stoving systems containing these blocked polyisocyanates, and the preparation thereof and their use for the preparation of lacquers, paints, adhesives and elastomers. The blocked polyisocyanates are derived from polyisocyanates reacted with secondary amines and cationic, anionic and/or nonionic hydrophilizing agents such that they are incorporated into the polyisocyanate at a ratio of from 20:1 to 1:1, wherein the blocking agents correspond to the formula R1–R4 can be identical or different and independently of one another denote hydrogen, C1–C6-alkyl or C3–C6-cycloalkyl, R5 denotes C1–C10-alkyl, C3–C10-cycloalkyl, and B represents ?wherein R6–R8 can be identical or different and independently of one another denote C1–C6-alkyl and/or C1–C6-cycloalkyl, R9 denotes hydrogen or C3–C6-alkyl or C3–C6-cycloalkyl.

Abstract: The present invention relates to a wood-polymer composite, particularly wood which has been impregnated with a mixture containing polymerizable organic compounds, and more particularly to a method for preparing a wood-polymer-composite by impregnating wood material and/or wood-based material with a mixture containing polymerizable organic compounds, and most particularly uses thereof.

Abstract: The invention relates to an improvement in a process for imparting barrier properties to porous substrates, such as, concrete, masonry products, and wood products. The process comprises the steps of: applying an aqueous based sealing composition comprising a polymeric resin to said porous substrate, evaporating the water and forming a water repellent coating of said polymeric resin on said porous substrate. The improvement comprises: deriving the polymeric resin from an aqueous based polymer emulsion comprising a polymer comprised of emulsion polymerized units of vinyl acetate and ethylene, preferably with a carboxylic acid monomer, the polymer containing amorphous and crystalline ethylene segments and having: (a) a crystalline melting point (Tm) ranging from 35 to 110° C., preferably 50 to 100° C.; measured at a heat rate of 20° C./minute; and, (b) a tensile storage modulus of at least 1×105 dynes/cm2 at 115° C. measured at 6.28 rad/sec.

Abstract: A method of making an absorbent structure having high integrity is provided. A first superabsorbent polymer precursor composition including a monomer, a crosslinking agent and a reducing agent, and a second superabsorbent polymer precursor composition including a monomer, a crosslinking agent and an oxidizing agent are combined at a plurality of discrete, spaced-apart locations on or in a substrate. The precursor compositions react with each other to form discrete, spaced-apart microdomains of superabsorbent polymer adhering to the substrate. The spacing is sufficient to avoid gel blocking when the microdomains swell due to liquid absorption. The adhesion to the substrate is sufficient to maintain spacings between the microdomains of superabsorbent polymer.

Abstract: A furan polymer impregnated wood which comprises wood impregnated with a polymerizable furfural alcohol monomer solution containing at least water, stabilizers, and furfuryl alcohol, and at least one further compound selected from the group consisting of anhydrides, acids and combinations thereof is described. A method for preparing a furan polymer impregnated wood and uses thereof is also described.

Abstract: A system and method for wood preservation comprises treating wood products via conventional pressure treating mechanics of sequential vacuum and pressure with a solution comprising an oligomeric, stoichiometrically balanced blend of primary and secondary diamines with modified diphenylmethane diisocyanates and a carrier solvent/reactant. Upon application, the carrier solvent/reactant evaporates, allowing polymerization of the remaining solution constituents to form a non-toxic, hydrophobic, elastomeric polyureathane linked copolymer that provides a long-term barrier against rot, environmental, termite and mold/fungus attack. Complete polymer impregnation of the wood's interstitial fiber space enables the hydrophobic property of the polymer to provide a long-time barrier to water penetration. Alternatively, the polymer may be surface applied to provide both protection and to prevent leaching out of CCA chemicals in the case of conventionally treated wood. The polymer is also an effective termiticide.

Abstract: Coating compositions comprising a polymer and an initiator are disclosed. The polymer comprises an alkyd, portion and a free radical curable portion that is pendant from the alkyd portion; the alkyd portion includes one or more fatty acid moieties that can be derived from one or more drying, semi-drying or nondrying oils. When drying or semi-drying oils are used, the molecules of the present invention exhibit a dual cure, both oxidative and free radical. The compositions are particularly suitable for coating substrates comprising wood. Methods for using the present compositions are also disclosed.

Abstract: The present invention relates to a method and a wood preserving composition which is free of poly-aspartic acid and its derivatives and comprises mixtures of a metal compound, complexing agents selected from ethanolamines, polyethylenimine, ammonia or a mixture of these compounds, and a vinyl based polymer selected from poly(vinyl alcohol) (PVA), poly(acrylamide) (PA), poly(N-vinyl pyrrolidone) (PVP) and poly(N-isopropyl acrylamide) (PNIPAM). The resulting metal amine solution can then be used to formulate a variety of metal-based cellulosic material preserving products.

Abstract: An aqueous coating composition having improved adhesion to friable surfaces including an emulsion polymer of certain compositions and certain acid numbers having a glass transition temperature of ?20 C to 100 C and an average particle diameter less than 120 nanometers; and 0.25-10%, by weight based on emulsion polymer weight, water-soluble alkoxylated amine is provided. In addition a method for for improving adhesion to friable surfaces by using the aqueous coating compositions of the invention is provided.

Abstract: A process for making an absorbent fibrous web composite including a stable, controllable dispersion of superabsorbent polymer is provided. A pre-formed web, desirably including cellulose fibers and, optionally, thermoplastic fibers is provided. First and second superabsorbent polymer precursor compositions are added to the fibrous web using separate streams. The first and second superabsorbent polymer precursor compositions combine with each other and chemically react on or in the fibrous web, to form a superabsorbent polymer which sticks to the surface of the fibrous web.

Abstract: Polyurethane powder coating compositions containing uretdione groups and curing at low temperatures are provided, along with processes for preparing such compositions, and their use as powder coatings, wherein the compositions generally contain: A) a uretdione-containing powder coating hardener derived from aliphatic, (cyclo)aliphatic, cycloaliphatic or aromatic polyisocyanates and hydroxyl-containing compounds, and having a melting point from 40 to 130° C., a free NCO content of less than 5% by weight, and a uretdione content of 6-18% by weight; B) a hydroxyl-containing polymer having a melting point from 40 to 130° C., and an OH number between 20 and 200 mg KOH/gram, and C) a catalyst of the formula [NR1R2R3R4]+[R5]?, in which R1-R4 simultaneously, or independently of one another, are alkyl, aryl, aralkyl, heteroaryl or alkoxyalkyl radicals, and each R1-R4 is aromatic, linear or branched, unbridged or bridged with other radicals, R1-R4.

Abstract: Wood cellulose is treated with a reactive silicate. The reaction is done to cellulose within the wood and may be catalyzed with acid or base catalysts or a carbon silicon halogen combination which produces in situ acid catalysts or a different combination to produce an in situ base catalyst which replaces some of the molecules or atoms within the cellulose structure with silicon, boron or other hydrophobic or anti-degrading agents. Preferably an organic solvent, such as alcohol is used to accelerate the reaction with the water in the wood. Here, the hydroxyl (OH) group on some or all of the cellulose molecules is partially replaced with silicon or an alternative atom or molecule to changes the character of the wood. The process may be modified to insert a preliminary step of adding a reactive agent to be locked into the wood. Manufacturing techniques to enhance the process using ultrasound or other wave generating techniques are also taught.

Abstract: The invention is directed to a protective barrier coating composition including a metal borate compound, a zinc compound, magnesium hydroxide, and a water based binder. The invention is also directed to a method of protecting building construction materials from termites and other insects, mold or mildew, and fire or water damage. The composition can be applied onto construction materials by a paint roller, spraying, or brushing, before, during, or after construction.

Abstract: A process for forming an absorbent fibrous web composite includes the initial step of forming a fibrous web from hydrophilic fibers and, optionally, thermoplastic fibers. Then, a superabsorbent polymer is completely formed in situ on or in the fibrous web by adding one or more superabsorbent polymer precursor compositions to the fibrous web using a non-contact process, and performing the polymerization reaction(s) completely on or in the web.

Abstract: The present invention relates to a process for the coating and water-repellent impregnation of mineral building materials, in which an architectural coating composition containing from 1 to 30 % by weight of C1-C20-alkyl-C1-C6-alkoxysilane as impregnating agent is applied to the building material. The principal architectural coating compositions are paints and plasters.

Abstract: The present invention relates to a method and a wood preserving composition which comprises mixtures of a metal compound, complexing agents selected from ethanolamines, polyethylenimine, ammonia or a mixture of these compounds, and a vinyl based polymer selected from poly(vinyl alcohol) (PVA), poly(acrylamide) (PA), poly(N-vinyl pyrrolidone) (PVP) and poly(N-isopropyl acrylamide) (PNIPAM). The resulting metal amine solution can then be used to formulate a variety of metal-based cellulosic material preserving products.

Abstract: Wood products, specifically wood commonly used in construction including dimension lumber, pressure treated pine, composite wood materials such as plywood, particle board, and wafer board, and samples of paper and fabric were variously treated with concentrations of sodium silicate (Na2O.SiO2) also known as water glass. Cellulosic materials including dimension lumber, plywood, particle board, wafer board, paper, and fabric were treated with sodium silicate (Na2O.SiO2) in concentrations ranging from 400-0.04 g Na2O.SiO2/kg water. To overcome the disadvantages of sodium silicate, sodium silicate treated samples were further treated to convert the water soluble sodium silicate to a water insoluble form, thereby overcoming the disadvantages of water solubility. and rendering the material effective for internal and external uses.

Abstract: The invention relates to a method of producing an interior fitment for motor vehicles, the interior fitment having on its facing side a wood molding which is provided with a coating. In order to impart a substantially natural impression to the interior fitment, the invention proposes applying to the wood molding a coating material based on vegetable-oil-modified resins and natural vegetable oils, with the addition to the coating material of ceramic microparticles. Likewise proposed is an interior fitment produced preferably by this method.

Abstract: The invention relates to a method for the protective treatment of wood, derived timber products and wood-type substrates by means of thermal treatment at 60-250° C. and additional treatment using an amine and/or amine derivative of general formula (Ia), (Ib) or (Ic) wherein R1 and R4 independently represent C6-24 alkyl; R2 and R3 independently represent C1-24 alkyl or (CH2)—NH2; R5, R6, R8 and R9 independently represent C1-24 Alkyl; R7 represents C6-24 alkyl or benzyl; R10 independently represents C1-24 alkyl or —[(CH2)2—O]nR11 where n=1-20; R11 represents hydrogen or optionally substituted phenyl; and X− represents a monovalent inorganic or organic anion or an equivalent of a polyvalent inorganic or organic anion. The additional treatment can also be carried out using a corresponding salt the wood treated according to said method has good resistance even to harmful organisms which cannot be reliably controlled by means of only a heat treatment.

Abstract: The invention provides a method for incorporating biocides into wood or a wood product. The method comprises incorporating an additive into a nanoparticle, applying the nanoparticle to wood or a wood particle and applying sufficient pressure to force the nanoparticle to penetrate the wood or wood particle.

Abstract: The present invention relates to a method of coating a wooden component, such as a slat. The method includes the following steps: applying a pigmented or sheen-enhanced lacquer coating onto a first surface of the component; drying the lacquer coating on the first surface; flipping the wooden component; applying a pigmented or sheen-enhanced lacquer coating onto a second surface of the wooden component; drying the lacquer coating on the second surface; applying a UV-cured polymer coating to one of the lacquer coated surfaces; flash curing the polymer and lacquer coated surface; flipping the wooden component; applying a UV-cured polymer coating to the other side of the lacquer coated surface; and flash curing the polymer and lacquer coated surface.

Abstract: There is provided a building board which is colored by mixture of a pigment(s) into the raw materials and exhibiting an excellent color development effect. A pigment and a resin(s) are incorporated into the raw materials of the front layer to form a resin film simultaneously with cement curing, thereby blocking the inflow or outflow of water through the surface of the substrate to provide a cement board with good waterproofness. The cement board obstructs the efflorescence generation and exhibits an excellent pigment color development effect.

Abstract: The invention provides cross-linkable polymer powder compositions containing a) at least one water-soluble polyhydroxy compound; b) at least one boric acid complex compound which is of limited solubility in water that is, it has a water solubility of less than 10 g per liter at normal conditions; and optionally c) a water-soluble film-forming polymer consisting of one or more free-radical polymerizable, ethylenically unsaturated monomers. The compositions are useful as a constituent in adhesives, plaster, jointing mortars, paints and binders for coating compositions, textiles, paper and the like.

Abstract: The invention relates to a decorative paper sheet, made impregnable by a thermosetting resin, characterized in that it comprises one or more polymers making the 60-second Cobb water absorption value of the sheet, determined according to the ISO 535 standard, at most 40% less than the grammage of the said sheet. It also relates to a decorative sheet impregnated with a thermosetting resin and the laminated decorative panels or moulded section which include it. The invention also relates to a process for manufacturing the sheets as well as to the decorative sheets impregnated with a thermosetting resin.

Abstract: A method and apparatus for applying a fluid preservative to wood or wood products has a work tank for maintaining a predetermined concentration of preservative in the fluid. The work tank is equipped with a heater to keep the temperature of the fluid and the preservative in the work tank at a predetermined level. Hot fluid and preservative is drawn under a vacuum, initially from the work tank. On filling a pressure vessel, a pressure pump then supplies the preservative and fluid mixture under pressure to the pressure vessel in which the wood or wood product is being treated. As the treatment process depletes the preservative in the fluid, through absorption in the wood, the depleted fluid is circulated back to the work tank where it is heated and more preservative is added to restore the concentration of preservative in the fluid to a desired level. The fluid, replenished with preservative, is then pumped into the pressure vessel.

Abstract: A furan polymer impregnated wood which is uniform in colour and density throughout the treated zone. In order to obtain the polymer impregnated wood, a parent wood has been impregnated with a mixture containing polymerizable organic compounds of at least furfuryl alcohol and one further compound. The invention also relates to a method for preparing a furan polymer impregnated wood and uses thereof.

Abstract: The present invention relates to a wood-polymer composite, particularly wood which has been impregnated with a mixture containing polymerizable organic compounds, and more particularly to a method for preparing a wood-polymer-composite by impregnating wood material and/or wood-based material with a mixture containing polymerizable organic compounds, and most particularly uses thereof.

Abstract: An aqueous composition is provided containing a first polymer including at least one C12 to C40 alkyl ester of (meth)acrylic acid, as polymerized units; at least one wax, at least one pigment, and optionally, at least one second polymer, wherein the sum of the first polymer and the second polymer is at least 10 weight %, based on weight of the aqueous composition; wherein the weight ratio of the first polymer to the second polymer is at least 1:4; and wherein the first polymer and the second polymer have a combined glass transition temperature in the range of −5 to 20° C. As provided is a method of treating a wood surface with the aqueous composition. The aqueous composition provides wood with resistance to water wetting and penetration of water and is suitable as a semi-transparent stain for wood.

Abstract: An aqueous coating composition having improved adhesion to friable surfaces is provided. The aqueous coating composition includes a plurality of polymeric particles having a particle size of less than 120 nanometers, and containing at least two polymers, one of which contains, as polymerized units, acid functional monomers, water soluble monomers, or both. Optionally, the aqueous coating composition includes a nonionic surfactant. In addition, a method for improving adhesion to friable surfaces by using the aqueous coating compositions of the invention is provided.

Abstract: A method for manufacturing a tire retardant cellulose insulation with reduced density and reduced settling. The method consists of adding a material, the fibers of which have a positive electrostatic charge, onto a shredded newspaper base either before or after the addition of a pre-coat, consisting of a mixture of limestone and an antistat. A fire retardant agent is then added and the materials are ground in a finish mill. The newspaper fibers become positioned at an angle to the paper pieces, increasing the distance between the paper pieces, thereby lowering the density of the cellulose. Fibers such as ground cardboard, wood mulch, sawdust, and fiberglass fibers are examples of materials with electrostatically positively charged fibers.

Abstract: The present invention relates to in situ polymerization of fluoropolymer into porous substrates, to improve resistance to degradation by wetting and staining, and wood, to improve resistance to degradation, staining and warping.

Abstract: The present invention provides a method of preparation for a degradable, water and oil resistant protective membrane. In the said method, carbon dioxide copolymer is dissolved in a low toxic or non-toxic solvent to form a solution of 3-6 wt % concentration. After standing and filtration to remove metal oxide, the solution is used to coat the surface of the fabricated starch, paper pulp, or straw tableware by spraying or dipping. The residual solvent is removed by drying process and a degradable, water and oil resistant and transparent protective membrane is obtained. The thickness of the protective membrane is in the range of 10-20 micrometer. Metal ion content is lower than 1 ppm. No leakage and deformation of the tableware are observed after the tableware is immerged in water or edible oil for 4 hours at 80° C. The decoloration test by cold edible oil and ethanol is negative. Fungus test gives grade V.

Abstract: A wood treatment composition for the preservation of wood comprises a mixture of creosote and a polymer which is miscible with the creosote at about 200° F. and does not substantially phase-separate when the wood treatment composition is under ambient conditions. The polymer may include, but is not limited to, ethylene vinyl acetate copolymers, ethylene methyl acrylate copolymers, ethylene ethyl acrylate copolymers, ethylene butyl acrylate copolymers, ethylene acrylic acid copolymers, ethylene methacrylic acid copolymers, ethylene methyl methacrylic acid copolymers, ethylene styrene interpolymers, styrene acrylic acid copolymers, styrene methacrylic acid copolymers, styrene methyl acrylate copolymers, styrene butadiene styrene block copolymers, styrene ethylene butylene styrene block copolymers, or a blend thereof. Preferably, the creosote is present in an amount of at least 50 percent by weight of the composition.

Abstract: The present invention relates to an aqueous coating composition having low volatile organic compounds (VOC) and producing a coating having excellent durability and resistance properties. The coating composition contains acetoacetate functional polymer and divalent metal ions. Coating compositions of the present invention are particularly useful in ink, polish and coating compositions where a tough, resistant coating is required. The coating composition can be used on various substrates such as floors, walls wood, metal, plastic, stone, paper, leather and concrete.

Abstract: Water resistant wood composition boards and methods of making the boards by coating or impregnating the panels with a solvent soluble, further curable, partial condensation product of a methyltrialkoxy silane or a phenyl trialkoxy silane or mixtures thereof or ladder-type organosilsesquioxane polymers.

Abstract: A method for manufacturing reinforced oriented strand boards includes steps of injecting melamine-formaldehyde resin or phenol-formaldehyde resin in finished oriented stand boards, of heating and pressing them to let the resin harden. As strands of woods of the originally oriented strand boards cannot completely closely bonded together, with many gaps remained, so injected resin can fill up those gaps and filtrate and wrap the strand woods to make the whole oriented strand boards having reinforced strength and fire-resistant property as well.

Abstract: A process for forming a polyurea coating on a wood composite substrate comprises the steps of applying an isocyanate to an edge of the wood substrate to form a pretreated edge and applying a polymer latex to the pretreated edge to form the polyurea coating. This polyurea coating provides excellent protection against the penetration of water through the edges and into the interior of the wood composite material and wood composite materials having this polyurea coating have significantly less edge swelling and adsorb considerably less water than wood composites that have no such protective coatings.

Abstract: The present invention relates to in situ polymerization of fluoropolymer into porous substrates, to improve resistance to degradation by wetting and staining, and wood, to improve resistance to degradation, staining and warping.

Abstract: The invention relates to a process for coating powders on wood substrate comprising pre-treating at least one surface of the substrate with a substantially solvent free treating composition, applying a powder coating composition on the pre-treated surface of the substrate; and curing the powder coating composition. The treating composition includes at least one thermoset material and has a viscosity that is sufficiently low to allow the treating composition to wet out the surface(s) of the substrate and to penetrate into the surface fiber structure of the substrate.

Abstract: A fire-retardant wood-based composite is formed by treating a green wood furnish with an amount of a phosphate/borate fire retardant treatment effective to increase the fire retardancy of the resulting wood-based composite, compared to the fire retardancy of the corresponding wood-based composite lacking the fire retardant. The fire retardant treated green wood furnish is blended with a binder and then bound, as by pressing the furnish, to form a non-leaching fire-retardant wood based composite. Another aspect of the invention is the product formed according to the preceding process. The fire retardant may also act as a catalyst to cure the binder and thus promote binding. Also, the addition of the fire retardant to green wood chips, without the need to dry them to a low moisture content, is believed to be novel.

Abstract: The treatment of the wood with a reactive silicate which is preferably a carbon silicon halogen combination which replaces some of the molecules or atoms within the cellulose structure with silicon. Here, the hydroxyl (OH) group on some or all of one or more of the cellulose molecules is partially replaced with silicon or an alternative atom or molecule to changes the character of the wood. The process may be modified to insert a preliminary step of adding a reactive agent to be locked into the wood.

Abstract: The invention provides a method for incorporating biocides into wood or a wood product. The method comprises incorporating an additive into a nanoparticle, applying the nanoparticle to wood or a wood particle and applying sufficient pressure to force the nanoparticle to penetrate the wood or wood particle.

Abstract: Disclosed are aqueous, storage-stable, crosslinkable polymer compositions comprising: (a) an aqueous dispersion of a an acrylic polymer component containing certain carbonyl-containing functional-groups; (b) a nitrogen-containing compound having at least two carbonyl-reactive nitrogen groups; and (c) optionally, co-solvents, pigments, fillers, dispersants, wetting agents, anti-foam agents, UV absorbers, antioxidants, biocides, and stabilizers. Such compositions are useful as coatings or binders in coating compositions, or as adhesives.

Abstract: An aqueous coating composition having improved adhesion to friable surfaces is provided. The aqueous coating composition includes a plurality of polymeric particles having a particle size of less than 120 nanometers, and containing at least two polymers, one of which contains, as polymerized units, acid functional monomers, water soluble monomers, or both. Optionally, the aqueous coating composition includes a nonionic surfactant. In addition, a method for improving adhesion to friable surfaces by using the aqueous coating compositions of the invention is provided.

Abstract: The invention relates to compositions for reducing the swelling of wood in the presence of water, comprising:

Abstract: Composition for impregnating porous materials, in which the composition contains at lease one component having preservative properties or which release a component having preservative properties on heating, the composition comprising an emulsion of water and oil containing a primary surfactant and an amphoteric additive, the pH of the emulsion being equal or approximately equal to the iso-electric point of the amphoteric additive. The compositions of the invention are particularly useful in the preservation of timber.

Abstract: The present invention provides a method of improving the adhesion of a copper layer to a barrier layer on a substrate. After deposition of a barrier layer, such as TiN, an amorphous silicon layer is deposited by striking a plasma over the substrate using a silicon source gas, such as silane, and an inert gas, such as argon (Ar). A Cu layer is deposited on the amorphous silicon. In another aspect of the invention, a TiSiN layer is deposited using a silicon source gas, such as silane, and a titanium source gas, such as TDMAT, during the deposition of the TiN barrier layer.

Abstract: The invention provides a method of treating of a substrate by contacting the substrate with a fluorochemical composition that comprises a condensation product of a di- or tri-isocyanate and at least one polyether, the polyether being obtained as the reaction product of a fluorochemical substituted epoxide. Substrates treated in accordance with the invention have good stain release properties, particularly to oil stains or tea stains, so stains can be more easily removed from the treated substrate in a laundering procedure.

Abstract: The object of the invention is a method for improving the impregnability of refractory wood species by pretreatment with fungi of the genera Trichoderma o Gliocladium or with weakly wood-degraging fungi. The pretreatment comprises a thermal treatment of the wood, the addition of a nutrient medium as well as an incubation phase to promote fungal growth. The incubation phase is stopped when the desired depth of penetration of the fungus is reached. The wood is subsequently impregnated with a wood impregnating agent. The typical result of the fungal pretreatment is an incarease in the depth of penetration of the impregnating agent to a depth of penetration of 5 mm to 30 mm required depending on the intended use.

Abstract: A finished product from lignocellulose, such as a length of wood or chipboard, is impregnated with a composition containing a thermosetting resin in a nonaqueous solvent, and a styrene polymer in a nonaqueous solvent. Excess impregnating composition is removed from the impregrnated material. The solvent or solvents are also removed. The thermosetting resin may thereafter be subjected to temperature conditions for polymerization to form a finished product.