Abstract: A curable composition comprising: (i) 2.5 to 50 wt % crosslinker comprising at least two acrylamide groups; (ii)12 to 65 wt % curable ionic compound comprising an ethylenically unsaturated group and a cationic group; (iii) 10 to 70 wt % solvent; (iv) 0 to 10 wt % of free radical initiator; and (v) lithium and/or calcium salt. The compositions are useful for preparing ion exchange membranes.

Abstract: Provided is a method for simply producing a polymer sheet having a three-dimensional pattern on surface. The method produces such a polymer sheet having a three-dimensional pattern on surface by applying a polymerizable composition to one surface of a polymer sheet and allowing the surface to have a three-dimensionally altered shape; and thereafter performing polymerization/curing to form a three-dimensional pattern on the surface of the polymer sheet. The polymerizable composition includes a monomer mixture including at least one polymerizable monomer absorbable by the polymer sheet, or a partial polymer of the monomer mixture as an essential component.

Abstract: The present invention provides: a pigment dispersion composition including (A) an organic pigment, (B) a pigment derivative represented by Formula (I) below and (C) a polymer compound having a pigment-adsorptive functional group; a curable color composition including the pigment dispersion composition, a polymerizable compound and a polymerization initiator; and a color filter having a color region formed using the curable color composition and a method for producing the same. Q represents an organic colorant residue; A represents an ethylene group or the like; and R represents a hydroxyl group or a group represented by —NH-A-Z; Z represents —SO3H, —COOH or a salt thereof; and n represents an integer of from 1 to 4. When R represents —NH-A-Z, the structures represented by the two —NH-A-Zs bonded to the triazine ring contained in each of the n partial structures bonded to Q may be the same as each other or different from each other.

Abstract: Copper plating baths containing a leveling agent that is a reaction product of a certain benzimidazole with a certain epoxide-containing compound that deposit copper on the surface of a conductive layer are provided. Such plating baths deposit a copper layer that is substantially planar on a substrate surface across a range of electrolyte concentrations. Methods of depositing copper layers using such copper plating baths are also disclosed.

Abstract: A curable composition for imprints, containing (A1) a polymerizable compound having at least one of a fluorine atom and a silicon atom, (A2) a polymerizable compound having an aromatic group and (B) a photopolymerization initiator, exhibits good patternability in repeated pattern transferring and solvent resistance.

Abstract: The invention relates to coated products containing a substrate (S) provided with a coating consisting of a single high refractive index and scratch-resistant layer (A) or provided with a multilayer structure in which layers (A) alternate with lower refractive index layers (B), wherein the layers (A) are characterised in that they contain particularly finely divided TiO2 nanoparticles.

Abstract: According to a method for forming a UV patternable conductive polymer film, vapor-phase polymerization (VPP) may be employed to synthesize a conductive polymer, and a UV-curable polymer resin may be used as a binder to form a conductive polymer film, the method including coating a mixed solution of a binder and an oxidant on a transparent substrate, synthesizing a conductive polymer by vapor-phase polymerization (VPP) on the coating to form a conductive polymer film and patterning the conductive polymer film with UV light. The conductive polymer film may be patterned in a relatively simple manner while maintaining increased conductivity, improved transparency and improved flexibility. Therefore, the conductive polymer film may be used as a material for transparent electrodes of a variety of display devices, e.g., LCD and PDP devices, and electronic devices, e.g., ELs and TFTs.

Abstract: An isothermal, low pressure-based process of depositing material within a substrate has been developed, and is particularly useful in forming an optical fiber preform results in creating an extremely narrow reaction zone within which a more uniform and efficient deposition will occur. Sets of isothermal plasma operating conditions have been found that create a narrow deposition zone, assuring that the deposited material is clear glass rather than soot particles. The exhaust end of the tube is connected to a vacuum system which is in turn connected to a scrubber apparatus for removal and neutralization of reaction by-products. The operating conditions are selected such that the hot plasma does not transfer a substantial amount of heat to the substrate tube, where the presence of such heat has been found to result in vaporizing the reactant material (creating soot) and developing hot spots.

Abstract: A method of making a flexographic printing forme precursor for laser engraving including the steps of (i) providing at least one layer of a curable composition on a substrate; (ii) curing the at least one layer; wherein the curable composition defining an outermost layer includes at least 0.5% by weight relative to the total weight of the composition of an organo-silicon compound including at least one polymerizable group; and a urethane (meth)acrylate oligomer having three or less polymerizable groups.

Abstract: The photocuring efficiency of a photoinitiator is increased by mixing it with an organic phosphite and an aldehyde. This mixture or photoinitiator composition can be used to cure acrylates or other photocurable compounds, particularly in an oxygen-containing environment.

Abstract: A process for applying an energy-curable primer and a brilliant metallic ink to a paperboard or paper substrate is provided. The primer may be cured using an energy curing system such as a UV or EB curing system. The curable primer facilitates the orientation of the metallic pigment particles to provide a coherent reflectance of light and optimal reflectance. Advantageously, the primer-cured paper may be “spot-coated” with the metallic ink at pre-designated areas, which minimizes the amount of metallic ink used. In exemplary embodiments, the metallic paper is over-coated with one or more transparent or opaque inks Additionally, the cured, primer coated paper may be subjected to corona discharge to remove excess solvent and compounds in the liquid phase within the matrix of the cured primer and/or to increase the surface tension of the primer. In certain circumstances, the metallic paper and the end product are recyclable and repulpable.

Abstract: An ink composition for inkjet recording is provided. The ink composition contains (a) a monomer containing a fluorinated alkylene group and two or more polymerizable groups, (b) a photo initiator, and (c) a polymerizable monomer.

Abstract: In order to limit the negative effect of metal contamination on reflectivity within an EUV lithography device, a reflective optical element is proposed for the extreme ultraviolet and soft X-ray wavelength range with a reflective surface with an uppermost layer, in which the uppermost layer comprises one or more organic silicon compounds with a carbon-silicon and/or silicon-oxygen bond.

Abstract: An imprint lithography template having a photoactive coating adhered to a surface of the template. Irradiation of the photoactive coating promotes cleaning of the template by decomposition of organic material proximate the template (e.g., organic material adsorbed on the template). An imprint lithography system may be configured such that template cleaning is achieved during formation of a patterned layer on an imprint lithography substrate. Cleaning of the template during an imprint lithography process reduces down-time that may be associated with template maintenance.

Abstract: A process of readily producing a patterned birefringent product excellent in resolution and heat-resistance is provided. Said process comprises at least the following steps [1] to [3] in order: [1] preparing a birefringence pattern builder which comprises an optically anisotropic layer comprising a polymer, and said optically anisotropic layer has a retardation disappearance temperature in the range higher than 20° C., at said retardation disappearance temperature in-plane retardation becomes 30% or lower of the retardation at 20° C. of the same optically anisotropic layer, and said retardation disappearance temperature rises by light exposure; [2] subjecting the birefringence pattern builder to patterned light exposure; [3] heating the laminated structure obtained after the step [2] at 50° C. or higher and 400° C. or lower.

Abstract: Method for making a low cost, light weight impact deflecting material, comprising directionally aligned single walled carbon nanotubes in an epoxy resin composition, that is near impervious to bullets fired at close range at all angles of incidence, that does not deteriorate upon abrasion or when exposed to wide ranges of temperature and humidity, and that when used to construct a protective shield for a body armor vest protects the wearer from blunt trauma effects.

Abstract: A method for manufacturing a liquid discharge head includes the steps of: forming a solid layer for forming a flow path on a substrate on which an energy generating element is arranged to generate energy that is used to discharge liquid; forming, on the substrate where the solid layer is mounted, a coating layer for coating the solid layer; forming a discharge port used to discharge a liquid, through a photolithographic process, in the coating layer deposited on the solid layer; and removing the solid layer to form a flow path that communicates with the energy element and the discharge port. A material used for the coating layer contains a cationically polymerizable chemical compound, a cationic photopolymerization initiator and an inhibitor of cationic photopolymerization, and a material of the solid layer that forms a boundary with a portion where the discharge port of the coating layer is formed contains a copolymer of methacrylic acid and methacrylate ester.

Abstract: A solid electrolytic capacitor includes an anode body, a dielectric coating provided on a surface of the anode body, and a first conductive polymer layer provided on the anode body. The first conductive polymer layer includes a bis(perfluoroalkanesulfonyl)imide anion and an organic solvent having a boiling point of 240° C. or higher.

Abstract: The present invention provides an oxetane compound represented by the following formula (1), and a active energy ray-curable composition including the oxetane compound as a polymerizable monomer.

Abstract: An electromagnetic wave reflective member production method including a right-circularly-polarized-light selective reflective layer forming step, and a left-circularly-polarized-light selective reflective layer forming step, characterized in that a right-handed twisted coating film is formed in the right-circularly-polarized-light selective reflective layer forming step by applying a right-handed twisting coating liquid on a transparent substrate and forming a substantially fully cured right-circularly-polarized-light selective reflective layer by means of energy irradiation of the right-handed twisted coating film; and a left-handed twisted coating film is formed in the left-circularly-polarized-light selective reflective layer forming step by applying a left-handed twisting coating liquid on the right-circularly-polarized-light selective reflective layer and forming a left-circularly-polarized-light selective reflective layer by means of energy irradiation of the left-handed twisted coating film.

Abstract: Positive and negative stamp masters derived from UV curable ink molds comprising ultraviolet (UV) curable inks and methods for digitally preparing those stamp masters. In particular, the digitally prepared molds provide a method of printing micropatterns of fine variable features or images in a more efficient manner than the methods currently available.

Abstract: A substrate assembly containing a conductive film and a fabrication method thereof are provided. The substrate assembly includes a polymer substrate, a surface treatment layer formed on the polymer substrate and a conductive film formed on the surface treatment layer, wherein the conductive film is formed by sintering a metal conductive ink and the surface treatment layer is formed from a composite material of an auxiliary filler and a polymer. The auxiliary filler in the surface treatment layer can deliver energy into the metal conductive ink for sintering the conductive metal ink.

Abstract: A process for preparing a composite membrane comprising acidic and/or basic groups comprising the following steps: (i) applying a curable composition to a support; and (ii) curing the composition to form a membrane; wherein the curable composition comprises: (a) 18 to 78 wt % crosslinking agent(s) having at least two acrylic groups; (b) 20 to 80 wt % curable compound(s) having one or more acidic or basic groups or groups which are convertible to acidic or basic groups; (c) 2 to 30 wt % solvent(s); and (d) 0 to 10 wt % photoinitiator(s). The membranes are particularly useful for water purification or for the generation of electricity from two streams differing in salt concentration.

Abstract: Nano-composites include a graphite material such as nanotubes or graphene sheets and a partial or complete coating of a polymer including sufficient ?-conjugated moieties to interact with surfaces of the graphite material. The polymers may also include electropolymerizable or oxidatively polymerizable moieties so the films may be crosslinked. The films may be used to form layers on substrates or patterned layers on substrates.

Abstract: A method of manufacturing a nozzle plate including: a step for forming the nozzle hole on a plate to become the nozzle plate; a first photocurable resin injection step for (i) coating with a photocurable resin a first surface of the plate and (ii) injecting the photocurable resin into an area inside the nozzle hole; a first curing step for applying light to the plate, so as to form a first cured resin part including a columnar part and an annular part; a first uncured resin removing step for removing an uncured portion of the photocurable resin; a base film formation step for forming a base film on the first surface; a cured resin removing step for removing the first cured resin part; and a water-repellent film formation step for coating with a water-repellent film a surface of the base film and a portion of the first surface of the plate exposed from the base film.

Abstract: A micro structure which is preferred as an original plate of an antireflection, a mold of nano imprint or injection molding is obtained by a single particle film etching mask on which each particle is precisely aligned and closest packed in two dimensions. A single particle film etching mask is produced by a drip step wherein a dispersed liquid in which particles dispersed in a solvent are dripped onto a liquid surface of a water tank, a single particle film formation step in which a single particle film which consists of the particles by volatizing a solvent is formed, and a transfer step in which the single particle film is transferred to a substrate. The single particle film etching mask on which particles are closest packed in two dimensions, has a misalignment D(%) of an array of the particles that is defined by D(%)=|B?A|×100/A being less than or equal to 10%. However, A is the average diameter of the particles, and B is the average pitch between the particles in the single particle film.

Abstract: The invention provides methods for modifying one or more properties of porous thin films. In such methods, a formulation comprising a reactive species is applied to the porous thin film and allowed to crosslink. In some embodiments, the crosslinked network thus formed imparts increased mechanical strength and wear resistance to the porous thin films.

Abstract: This invention is a radiation curable resin composition for wire coatings that have excellent adhesion with the center conductor as well as having excellent manufacturing efficiency for the coating layer and sufficient strength. This radiation curable resin composition for wire coating comprising the following ingredients (A), (B) and (D): (A) a mixture of a urethane (meth)acrylate having a structure derived from an aliphatic polyol and a urethane (meth)acrylate not having a structure derived from a polyol, (B) a compound having a cyclic structure and one ethylenically unsaturated group, (D) a compound given by the following formula (4a) wherein, R8 is a monovalent organic group having an ethylenically unsaturated group, and R9 is a hydrogen atom or a monovalent organic group that may have an ethylenically unsaturated group.

Abstract: An object of complex three-dimensional configuration, such as an automotive vehicle body, is coated with a combination of a coating formulation and a photoactivated mixture containing active centers that have been produced prior to application. The two liquids can be intimately mixed prior to application to the object, or the coating formulation can be applied prior to the application of the photoactivated mixture. The coating formulation is cured by the active centers that have been produced prior to application.

Abstract: A process for producing an overprint is provided that includes a step of preparing a printed material printed on a printing substrate, a step of coating the printed material with a photocurable composition, and a step of photocuring the photocurable composition, the photocurable composition comprising (I) a fluorine-containing polymer having an ethylenically unsaturated group, (II) an ethylenically unsaturated compound, and (III) a photopolymerization initiator. There are also provided an overprint produced by the production process, and the photocurable composition.

Abstract: Methods of forming patterned coatings are disclosed. The methods include the steps of disposing a composition onto a substrate to form a liquid coating on the substrate and removing or providing energy through a first pattern of areas on the liquid coating to form a topographically patterned coating, the topographical pattern corresponding to the first pattern of areas.

Abstract: A method of making a 3-D object from a photocurable composition, including (a) a cationically curable monomer; (b) a radically curable monomer; (c) reactive particles comprising a crosslinked polysiloxane core and a shell of reactive groups on an outer surface of the core, wherein the reactive groups comprise epoxy groups, ethylenically unsaturated groups, or hydroxy groups; (d) a radical photoinitiator; and (e) a cationic photoinitiator; the method comprising (1) forming a first layer of the photocurable composition; (2) exposing the first layer to actinic radiation sufficient to harden the first layer; (3) forming a second layer of the photocurable composition above the hardened first layer; (4) exposing the second layer to actinic radiation sufficient to harden the second layer; and (5) repeating steps (3)-(4) as needed to form a 3-D object.

Abstract: Acrylate-containing compositions are photocured by mixing at least one N-oxyazinium salt photoinitiator, a photosensitizer for the N-oxyazinium salt, an N-oxyazinium salt efficiency amplifier, and one or more photocurable acrylates to form a photocurable composition. This photocurable composition is then irradiated to effect polymerization of the one or more acrylates. This method can be carried out in oxygen-containing environments.

Abstract: The present invention relates to a method for producing a superhydrophobic film composed of a polymer having surface microstructures (irregularities) and in particular to a method for producing a superhydrophobic film that utilizes a phase separation phenomenon caused by a polymerization reaction by energy ray irradiation and to a superhydrophobic film formed by this production method. The method includes a step of preparing a film-forming composition (X) by mixing a polymerizable compound (A) that can be polymerized by energy ray irradiation and a compound (B) that is compatible with the polymerizable compound (A) but incompatible with a polymer of the polymerizable compound (A), a step of forming a layer of the film-forming composition (X); and a step of removing the compound (B) after polymerizing the polymerizable compound (A), in which the compound (B) is liquid or solid, has a molecular weight of 500 or less, and has a saturation vapor pressure of 400 Pa or less at 25° C.

Abstract: The present invention relates to a method for producing a multi-layer product comprising a) a substrate containing at least one thermoplastic substrate layer and b) at least one protective layer made of a coating composition comprising compounds with at least two functional groups, characterized in that the protective layer(s) are/is applied inline after the production of the substrate containing the substrate layer.

Abstract: A method for forming a polymeric coating on a substrate surface, by plasma treating a mixture comprising a free-radical initiated polymerisable monomer having one or more free-radical polymerisable groups in the presence of a free radical initiator, wherein said plasma treatment is a soft ionisation plasma process (a process wherein precursor molecules are not fragmented during the plasma process and as a consequence, the resulting polymeric coating has the physical properties of the precursor or bulk polymer) aid depositing the resulting polymeric coating material onto a substrate surface.

Abstract: The present invention relates to a method for manufacturing a resin-impregnated decorative paper, which method comprises the following steps: i) providing a paper, ii) impregnating the paper obtained in step i) with a first, actinic radiation-curable resin, iii) subjecting the paper obtained after step ii) to a drying step, iv) applying a second, actinic radiation-curable resin to the dried paper obtained after step iii), and v) curing the paper obtained after step iv) to obtain the resin-impregnated decorative paper.

Abstract: Provided is a charging member having a rough surface, thereby suppressing adhesion of dirt on the surface. A charging member having a supporting member, an elastic layer and a surface layer, in which the surface layer contains a polymer compound, which has a Si—O-M bond and at least one structural unit selected from structural units represented by the following general formula (1) and the following general formula (2), and has a structural unit represented by the following general formula (3); the charging member has cracks developing from the surface thereof and reaching the elastic layer; and the cracks each have convexly raised edges, by which the surface thereof is roughened.

Abstract: The invention provides a cross-linkable elestomeric thermoplastic polyurethane that is urea free, isocyanutrate free, oxazolinyl free, functional radically-polymerizable pendant group free and having terminal functional radically-polymerizable groups at both ends, and thermoset polyurethanes obtained therefrom. The invention also provides applications of the compositions, and processes for manufacturing these compositions.

Abstract: A method of forming a water repelling film, includes: a thin film forming step of forming, on a base member, a thin film mainly having Si—O bonds and having hydrophobic substituent groups directly bonded to silicon, using a starting material which is a gas at normal temperature and atmospheric pressure; an irradiation step of irradiating the thin film obtained in the thin film forming step with excitation light in such a manner that the hydrophobic substituent groups are left and OH groups are present in the thin film; and an application step of applying a silane coupling agent onto the thin film obtained in the irradiation step.

Abstract: Process for obtaining a hard coated article having anti-fouling properties, including, for example, an optical article such as an ophthalmic lens, comprising a substrate coated with a hard coating providing abrasion resistance and hardness and adhesion to the anti-fouling coating, and the article obtained from such process.

Abstract: A concrete railroad-tie having a radiation-cured coating covering at least 5% of the exterior surface and a having a median thickness between 0.005 inches and 0.125 inches. The coating comprises the reaction product of radiation curable oligomers selected from the group consisting of epoxy acrylates, urethane acrylates, polyester acrylates, and combinations thereof. Method of providing the same.

Abstract: An aqueous polymerizable monomer composition including an ?,?-unsaturated carboxylic acid monomer and a polyvalent metal ion in an amount sufficient to neutralize 10 to 90% of a carboxyl group of the ?,?-unsaturated carboxylic acid monomer in the form of a solution or dispersion in water in an amount of 20 to 85% by weight based on the whole amount of the composition, a gas barrier film including an ionically crosslinked polycarboxylic acid polymer film formed by subjecting a coating film of the aqueous polymerizable monomer composition to a polymerization treatment and having an oxygen transmission rate of at most 50×10?4 cm3(STP)/(m2·s·MPa) as measured under conditions of a temperature of 30° C. and a high relative humidity of 80%, and a production process of the film.

Abstract: The invention relates to a method of sealing at least part of the surface of an article, comprising the steps of (a) applying a layer of a radiation-curable melt based on a moisture-crosslinking polyurethane to at least part of the surface of the article, and (b) irradiating the melt layer. The invention further relates to article surfaces sealed in this way, and also to the use of the abovementioned melt for surface sealing.

Abstract: A liquid resin, which is the Michael addition product of an amine-terminated aminoamide thermoplastic polymer with one or more polyol ester compounds having at least one (meth)acrylate group, wherein the amine-terminated aminoamide thermoplastic polymer contains a bisphenol or novolac segment to provide increased hardness and improved flow of radiation-curable compositions incorporating such resins, methods of printing using such compositions and articles printed with such compositions.

Abstract: A manufacturing method of a laminated body includes applying an energy ray curable resin composition on a base, and causing a rotation surface of a rotation stamper to come into close contact with the energy ray curable resin composition applied on the base during rotation, and irradiating the energy ray curable resin composition with energy rays emitted from one or a plurality of energy ray sources provided in the rotation stamper via the rotation surface so as to cure the energy ray curable resin composition, thereby forming a shape layer onto which concave and convex shapes of the rotation surface are transferred, on the base.

Abstract: A method of forming a three-dimensional microstructure on a flat surface of a support, comprising the application of a first flat and uniform layer of silicone on said surface of support and the application on the first layer of silicone of a second three dimensionally microstructured layer of silicone, said first layer and second layer of silicone become integrally connected to thus form a common three-dimensional microstructure ensuring anti-adhesive properties distributed regularly on the surface of the support, so that any flexible surface of substrate, in particular a surface of adhesive deposited on said layers of silicone will be microstructured by inverse replication of the three-dimensional microstructure formed by the two layers of silicone, where said layers of silicone are fixed by hardening by heating or by exposure to an ultraviolet or electronic radiation, or a combination thereof, applications thereof and films, notably self-adhesive films, such as those microstructured by said method.

Abstract: Provided a method for producing an oriented-porosity dielectric material on a substrate. The method includes depositing a vapor phase on a substrate of a composite layer comprising a material forming a matrix and a compound comprising chemical groups capable of being oriented under the effect of an electromagnetic field and/or photonic radiation; treating the composite layer to obtain the cross-linking of the material forming a matrix; and subjecting the substrate coated with the composite layer to an electromagnetic field and/or a photonic radiation.

Abstract: The present invention relates to the use of a R—N2+ diazonium salt carrying an aromatic group R, for grafting of the aromatic group onto insulating, semiconductor, binary or ternary compound or composite material surfaces, the diazonium salt being present at a concentration close to its solubility limit, notably at a concentration higher than 0.05 M, and preferably varying between approximately 0.5 M to approximately 4 M.

Abstract: A method of coating a surface with a polymer layer, which method comprises exposing said surface to a plasma comprising a monomeric unsaturated organic compound which comprises a chain of carbon atoms, which are optionally substituted by halogen; provided that where the compound is a perhalogenated alkene, it has a chain of at least 5 carbon atoms; so as to form an oil or water repellent coating on said substrate.