High Energy Electromagnetic Radiation Or High Energy Particles Utilized (e.g., Gamma Rays, X-rays, Atomic Particles, I.e., Alpha Rays, Beta Rays, Electrons, Etc.) Patents (Class 427/496)
  • Patent number: 6210977
    Abstract: A measuring device for measuring or examining physiological parameters on biocomponents includes an FET sensor 5 whose electrical protective layer 12 is roughened or has a structured coating 15. The structuring of the active sensor contact surface 12 is adapted to the outer contour and topography of the biocomponent in question, so that a better possibility is available for anchoring the biocomponents to the contact surface 24 forming the FET protective layer of the sensor 5.
    Type: Grant
    Filed: December 21, 1999
    Date of Patent: April 3, 2001
    Assignee: Micronas Intermetall GmbH
    Inventors: Ulrich Sieben, Bernhard Wolf, Hellmut Haberland, Christoph Cremer
  • Patent number: 6187070
    Abstract: Production of a finished fabric backing for use in the production of a coated abrasive is performed using a dual cure system comprising a radiation curable binder and a thermal initiator in which polymerization is initiated by the use of radiation until the exotherm produced raises the temperature of the formulation to the activation temperature of the thermal initiator. Thereafter the polymerization continues under the influence of the thermal initiator alone.
    Type: Grant
    Filed: January 6, 2000
    Date of Patent: February 13, 2001
    Assignee: Norton Company
    Inventors: Anthony C. Gaeta, Gwo Shin Swei
  • Patent number: 6187389
    Abstract: This invention relates to an economical coating composition for porous substrates that provides extremely glossy surfaces, is capable of supporting holographic images, provides good oxygen barrier properties as well as good oil, grease, solvent and water resistance. Said coatings on paper substrates are printable, biodegradable, recyclable, and repulpable. They are also suitable for use in conjunction with food products. This invention also relates to a process for applying said coatings onto porous substrates as well as a process for the economical production of inexpensive holographic images on substrates such as paper and cardboard containers.
    Type: Grant
    Filed: May 3, 2000
    Date of Patent: February 13, 2001
    Assignee: A*Ware Technologies, L.C.
    Inventors: Derric T. Overcash, Richard C. Wallace
  • Patent number: 6162493
    Abstract: A process is disclosed for the preparation of a heat mode recording element of the DRAW type (Direct Read After Write), said process comprising the following steps:(A) providing a material having following layer arrangement, in order:(1) a transparent support optionally subbed,(2) a thin metal layer coated from an aqueous medium containing metal particles,(3) a coated single top layer curable by radiation,(B) radiation curing said coated single top layer (3).In the preferred embodiment of the present invention the metal layer is a bismuth layer.
    Type: Grant
    Filed: November 23, 1998
    Date of Patent: December 19, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Luc Leenders, Eddie Daems, Hieronymus Andriessen
  • Patent number: 6146712
    Abstract: The present invention provides an ink-jet recording sheet which is excellent in water resistance, capable of providing excellent ink-drying property and image quality, substantially free from blurring, and suitable for use as OHP sheets of which a high transparency is necessitated. The present process for producing an ink-jet recording sheet comprises applying to a base sheet, an aqueous solution of a water-soluble resin having no radically polymerizable double bond in the molecule and selected from the group consisting of polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylamide, polyacryloyl morpholine, water-soluble polyvinyl acetal, poly-N-vinyl acetamide, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose, gelatin, casein and derivatives of them, irradiating the resultant coating layer with electron beam before the coating layer is dried, to form a hydrogel, and drying the hydrogel.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: November 14, 2000
    Assignee: OJI Paper Co., Ltd.
    Inventors: Masayo Maeda, Kozo Tajiri
  • Patent number: 6096384
    Abstract: This invention relates to paperboard lids having a radiation cured overprint varnish. Such structures of this type, generally, protect the graphics which are printed upon the paperboard lid such that the graphics are not distorted and/or marred during the platen sealing process.
    Type: Grant
    Filed: July 17, 1998
    Date of Patent: August 1, 2000
    Assignee: Westvaco Corporation
    Inventor: Barry Gene Calvert
  • Patent number: 6093257
    Abstract: A method of cleaning a substrate by covering the substrate with a composition in a sufficient amount to clean the substrate. The composition includes a substantial amount of at least one low viscosity organic compound which includes a radiation curable group. The compound is reclaimed for further use. The reclaimed compound may be used as a reactive diluent in a radiation curable coating composition.
    Type: Grant
    Filed: March 16, 1998
    Date of Patent: July 25, 2000
    Assignee: DSM N.V.
    Inventor: George Pasternack
  • Patent number: 6071618
    Abstract: A polymeric film includes at least one irradiated water soluble layer. A process for making a water soluble film includes the steps of extruding a water soluble film; and irradiating the water soluble film. Using electron beam irradiation, a water soluble film's solubility rate can be increased.
    Type: Grant
    Filed: October 11, 1996
    Date of Patent: June 6, 2000
    Assignee: Cryovac, Inc.
    Inventors: Philip H. Cook, Jr., Tina V. Lorenzo Moore
  • Patent number: 6054502
    Abstract: A radiation curable coating composition comprising: (A) an unsaturated polyester component; and (B) a non-polymerized, cocurable vinyl ether component. Component (B) may be separate from or structurally incorporated in the unsaturated polyester component. The vinyl ether component contains an average of at least two vinyl ether groups per molecule of the vinyl ether component.
    Type: Grant
    Filed: March 23, 1998
    Date of Patent: April 25, 2000
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Charles B. Friedlander, David A. Diehl
  • Patent number: 6048587
    Abstract: Radiation-curable resins as well as thermal and electron-beam-curable resins are provided comprising a polymeric backbone having acrylate or vinyl ether substituents and an ionically bonded neutralizing agent such as an aminoacrylate. These resins are hydrophilic and water-dispersible before curing, but resistant to most solvents including water after curing while preserving a hard, strong, adhesive character which makes them suitable for use as coatings and fabrication of three-dimensional structures in a wide variety of applications.
    Type: Grant
    Filed: October 1, 1998
    Date of Patent: April 11, 2000
    Assignee: Ricon Resins, Inc.
    Inventor: Tanya Estrin
  • Patent number: 6040017
    Abstract: The fabrication of linear and non-linear optical materials including photoconductive, photorefractive, and optical limiting polymer composite films from radiation curable homogeneous solutions or heterogeneous slurries via vacuum flash evaporation techniques is disclosed.
    Type: Grant
    Filed: October 2, 1998
    Date of Patent: March 21, 2000
    Assignee: Sigma Laboratories, Inc.
    Inventors: Michael G. Mikhael, Ali Boufelfel, Angelo Yializis
  • Patent number: 6033916
    Abstract: A measuring device for measuring or examining physiological parameters on biocomponents includes an FET sensor 5 whose electrical protective layer 12 is roughened or has a structured coating 15. The structuring of the active sensor contact surface 12 is adapted to the outer contour and topography of the biocomponent in question, so that a better possibility is available for anchoring the biocomponents to the contact surface 24 forming the FET protective layer of the sensor 5.
    Type: Grant
    Filed: January 17, 1997
    Date of Patent: March 7, 2000
    Assignee: Micronas Intermetall GmbH
    Inventors: Ulrich Sieben, Bernhard Wolf, Hellmut Haberland, Christoph Cremer
  • Patent number: 6004629
    Abstract: A process for coating sheet metal is disclosed that comprises the steps of 1) cleaning the sheet metal to remove surface contaminants that may interfere with the coating adhering to the sheet metal; 2) pretreating the sheet metal to promote adhesion of the coating to the sheet metal; 3) applying an electron beam curable coating to the sheet metal that when curing is complete, adheres to the sheet metal; and, 4) exposing the coating on the sheet metal to an electron beam to cure the coating, the cleaning, pretreating and curing resulting in no emission of pollutants that need to be removed before the emission is released into the atmosphere.
    Type: Grant
    Filed: July 2, 1997
    Date of Patent: December 21, 1999
    Inventor: William Vincent Madigan
  • Patent number: 5976706
    Abstract: Polyesterdiols having low viscosities of less than 3500 cps, high content of non-volatile matter in excess of 96 wt %, and narrow molecular weight distribution of less than about 1.4 are prepared by esterification of one or more aliphatic dicarboxylic acids or ester derivatives thereof using at least a 1.5 molar excess of one or more aliphatic diols until an acid number of less than 20 is achieved, and stripping excess diol from the polyesterdiol reaction product. Where esterification catalyst is used, catalyst is substantially removed prior to stripping excess unreacted diol from polyesterdiol reaction product. The polyesterdiols so produced are useful as (i) curable components in thermosettable resin compositions, particularly compositions essentially free of volatile organic solvent and also containing a crosslinking agent and a reactive hardening agent: and/or (ii) useful as coatings, paints and adhesives, providing coatings with very low content of volatile organic compounds.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: November 2, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Albert Ilya Yezrielev, Konstantinos R. Rigopoulos, Richard William Ryan, Karen K. Kuo, George Andrew Knudsen
  • Patent number: 5939150
    Abstract: The present invention relates to a method for treating a substrate surface. The substrate surface is coated with a thin film of a treating agent, which is capable of enhancing or reducing its affinity towards a metal precursor by exposure to an arbitrary kind of radiation beam. In a subsequent metal deposition step utilizing the metal precursor, the metal is selectively deposited on the exposed or unexposed areas, depending on the kind of treating agent. (FIG.
    Type: Grant
    Filed: April 25, 1997
    Date of Patent: August 17, 1999
    Assignees: Max-Planck-Gesellschaft Zur Forderung Der Wissenschaften E.V., CNRS-Service De La Valorisation
    Inventors: Martin Stelzle, Pascal Doppelt
  • Patent number: 5932298
    Abstract: Methods for preparing viscoelastic compositions (e.g., adhesives such as hot melt adhesives) in which a pre-viscoelastic composition (e.g., a pre-adhesive composition) is combined with a packaging material and then polymerized.
    Type: Grant
    Filed: August 17, 1998
    Date of Patent: August 3, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: John D. Moon
  • Patent number: 5925420
    Abstract: Amorphously crosslinked aromatic polymeric low .kappa. materials and methods for their fabrication are provided. The subject materials are prepared by a modified transport polymerization process, in which aromatic precursors are pyrolyzed to produce radical comprising aromatic monomeric precursors which are then allowed to polymerize by deposition onto a substrate surface, where during and/or after deposition the growing polymer chain is exposed to a high energy crosslinking agent, such as high energy photons or plasma. The subject crosslinked materials find use in a variety of applications, particularly as low .kappa. dielectrics in the manufacture of integrated circuits.
    Type: Grant
    Filed: July 16, 1996
    Date of Patent: July 20, 1999
    Assignee: WJ Semiconductor Equipment Group, Inc.
    Inventor: Chung Lee
  • Patent number: 5922481
    Abstract: An electroluminescent arrangement contains one or more organic layers, at least one of which is obtained by thermal or radiation-induced crosslinking and contains at least one charge-transporting compound which can carry crosslinkable groups per layer, one of the layers being completely or partially composed of a crosslinkable fluorescent compound which emits fluorescent light in the wavelength range from 400 to 800 nm.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: July 13, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Frank Meyer, Wolfgang Paulus, Hans-Werner Schmidt
  • Patent number: 5922416
    Abstract: A method of forming a fuser roll by disposing a substantially uncured fluoroelastomer composition which is substantially free of metal containing material on a substrate, and curing the fluoroelastomer material. The fluoroelastomer has at least about 23.4 mole percent hexafluoropropylene and can be cured by electron beam treatment, fugitive base treatment or by the use of blocked/hindered bases.
    Type: Grant
    Filed: December 12, 1995
    Date of Patent: July 13, 1999
    Assignee: Ames Rubber Corporation
    Inventors: Chris F. DelRosario, James A. Lentz
  • Patent number: 5922473
    Abstract: Opaquely pigmented or thick filmed powder coatings for heat sensitive substrates, such as wood, wood composites, for example, medium density fiber board, and plastics, that can be fully cured, especially near the substrate, through the incorporation of a dual cure system in the powder comprising a thermal initiator, such as a peroxide, along with a UV initiator. The UV initiator cures the surface, while the thermal initiator cures at the substrate. Surprisingly, virtually no pregelation occurs during the heated melt and flow out step prior to UV curing. Consequently, the hardened film finish formed on the surface exhibits exceptional smoothness which is comparable to that of traditional UV curable powders. The hardened film finish is also fully cured throughout and exhibits exceptional adhesion to the substrate which cannot be achieved with traditional UV curable powders that have been pigmented.
    Type: Grant
    Filed: December 26, 1996
    Date of Patent: July 13, 1999
    Assignee: Morton International, Inc.
    Inventors: Jeno Muthiah, Andrew T. Daly, Richard P. Haley, Joseph J. Kozlowski
  • Patent number: 5916641
    Abstract: The present invention provides for a number of interrelated methods for the production of random and ordered arrays of particles as well as films containing the same. In another aspect, the present invention relates to the random and ordered arrays of particles and films prepared therefrom. The ordered arrays are obtained by the use of ferrofluid compositions which may be curable, solidifiable or non-curing/non-solidifiable. Especially preferred arrays and films contain electrically conductive particles for use in electronic applications for effecting contact between leads or pads.
    Type: Grant
    Filed: August 1, 1996
    Date of Patent: June 29, 1999
    Assignees: Loctite (Ireland) Limited, Loctite Corporation
    Inventors: Ciaran B. McArdle, Joseph Burke, Edward K. Welch, II
  • Patent number: 5914157
    Abstract: The incorporation of a non-thermosettable phenolic tackifying resin surprisingly provides improved solvent free, hot melt processing of hydrocarbon elastomers with crosslinking promoters to form pressure sensitive adhesive tapes. The tapes advantageously have a desirable balance of the properties of resistance to slow rate peel and fast rate peel adhesion.
    Type: Grant
    Filed: August 31, 1995
    Date of Patent: June 22, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Daniel C. Munson, Andrew C. Lottes, Angelo Psellas, Denis A. Brisson
  • Patent number: 5894042
    Abstract: A conduit coating which is made by covering a surface thereof with a polymeric material which may include an additive made of bacteriostatic, bacteriocidal, fungicidal, fungistatic or mildew-suppressing material. The coating material may be cross-linked using radiation exposure to improve the high temperature characteristics of the conduit.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: April 13, 1999
    Assignee: Technology Licensing Company
    Inventor: Michael W. Ferralli
  • Patent number: 5888617
    Abstract: An object with a homogeneous matted surface is provided which can be carried out in a simple manner and at low cost. The surface of the object has a thin skin layer produced by UV polymerization at a wavelength of at most 200 nm, and a core or carrier layer, beneath the skin layer, is produced by polymerization with UV radiation of a wavelength of at least 220 nm or by electron beams. A method for producing the matted surface is also provided, wherein a film made of an organic material that can be polymerized by UV radiation or electron beams is applied to a substrate; the film is irradiated with UV radiation of a wavelength of at most 200 nm, with the production of the skin layer at the surface, in which the organic material is at least partially polymerized; and the core area of the film, beneath the skin layer, is irradiated with UV radiation having a wavelength above 220 nm or by electron beams.
    Type: Grant
    Filed: September 12, 1996
    Date of Patent: March 30, 1999
    Assignee: Heraeus Noblelight GmbH
    Inventor: Angelika Roth
  • Patent number: 5879600
    Abstract: A method of preparing particles of an exfoliated vermiculite for the manufacture of a finished product, such as a particle board, includes the steps of, if necessary, chemically modifying the vermiculite by impregnating the vermiculite with a suitable anhydride in a non-aqueous solvent; if necessary, applying to the particles of vermiculite an adhesion promoter to promote the adherence of a resin to the surfaces of the particles of vermiculite; and resinating the particles of vermiculite either with a thermoplastic resin which has been surface modified by irradiation or by fluorination, or by an isocyanate thermosetting resin, or by a dry powder novolac thermosetting resin; and if necessary removing any solvent present.
    Type: Grant
    Filed: July 28, 1997
    Date of Patent: March 9, 1999
    Assignee: Tower Technologies Proprietary Limited
    Inventor: Michael Windsor Symons
  • Patent number: 5834274
    Abstract: Water soluble macromers are modified by addition of free radical polymerizable groups, such as those containing a carbon-carbon double or triple bond, which can be polymerized under mild conditions to encapsulate tissues, cells, or biologically active materials. The polymeric materials are particularly useful as tissue adhesives, coatings for tissue lumens including blood vessels, coatings for cells such as islets of Langerhans, coatings, plugs, supports or substrates for contact with biological materials such as the body, and as drug delivery devices for biologically active molecules.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: November 10, 1998
    Assignee: Board of Regents, The University of Texas System
    Inventors: Jeffrey A. Hubbell, Chandrashekhar P. Pathak, Amarpreet S. Sawhney, Neil P. Desai, Jennifer L. Hill, Syed F. A. Hossainy
  • Patent number: 5804263
    Abstract: A material consisting of a hydrophobic material having a metallic, ceramic or glass surface which has been modified by exposing the surface to a glow discharge plasma to activate the surface, followed by exposing the activated surface to one or more ethylenically unsaturated monomers and irradiating the surface with gamma or electron beam radiation to induce polymerization thereon of the monomer(s) so as to form a hydrophilic polymeric coating on the surface of an article.
    Type: Grant
    Filed: December 23, 1994
    Date of Patent: September 8, 1998
    Assignee: University of Florida Research Foundation, Inc.
    Inventors: Eugene P. Goldberg, Ali Yahiaoui, James Burns
  • Patent number: 5783251
    Abstract: An antistatic agent comprising a water-soluble electroconductive polymer comprising at least a repeating unit having a sulfo group-containing isothianaphthenylene structure; a method for suppressing electrification of an article during the production or use of the article by forming an electroconductive film comprising the water-soluble electroconductive polymer on the article; an article of which electrification is suppressed by having an electroconductive film comprising the water-soluble conductive polymer on the article; and a method for observing or inspecting an article with suppressing electrification thereof during irradiation with charged particle beams by forming an electroconductive film comprising the water-soluble electroconductive polymer on the article. The electroconductive film retains the electrification-suppressing effect and removability stably even when subjected to a heat treatment or left to stand for a long period of time.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: July 21, 1998
    Assignee: Showa Denko K.K.
    Inventors: Hideki Tomozawa, Yoshihiro Saida, Junya Kato, Yukie Akakabe, Yoshiaki Ikenoue, Reiko Ichikawa
  • Patent number: 5712327
    Abstract: A hydrophilic soft gas permeable contact lens having substantially improved clinical performance by the provision of a sufficient higher proportion of hydroxy acrylic units to silicon units in the lens surface layer, as compared to that existing in the lens core, by the surface treatment of the lens, such as by reacting of the lens surface with polyols and base or acid or by radiation treatment of the base lens to graft, deposit or coat thereon hydroxy acrylic units.
    Type: Grant
    Filed: June 16, 1992
    Date of Patent: January 27, 1998
    Inventors: Sing-Hsiung Chang, Mei-Zyh Chang
  • Patent number: 5698192
    Abstract: A method for modifying an ocular implant polymer surface by the gamma-irradiation induced polymerization thereon of N-vinylpyrrolidone, 2-hydroxyethylmethacrylate or a mixture thereof while maintaining the following conditions:(a) monomer concentration in the range of from about 0.1% to about 50%, by weight;(b) total gamma dose in the range of from about 0.001 to less than about 0.50 Mrad; and(c) gamma dose rate in the range of from above about 2,500 to about 10.sup.8 rads/minute.
    Type: Grant
    Filed: September 25, 1996
    Date of Patent: December 16, 1997
    Assignee: University of Florida
    Inventor: Eugene P. Goldberg
  • Patent number: 5693745
    Abstract: The present method provides a method for preparing the PI varnish which has the steps of: 1) preparing a mixed solution of 60-100% by weight aprotic solvent, and 0-40% by weight aromatic solvent; 2) adding into the mixed solution in a mole ratio of 1:9 two aromatic diamines; and 3) further adding in the mixed solution in a mole ratio of 1:5 two aromatic dianhydrides. Such PI has a suitable thermal expansion coefficient and characteristics different form those of the PI currently in use.
    Type: Grant
    Filed: February 8, 1996
    Date of Patent: December 2, 1997
    Assignee: Industrial Technology Research Institute
    Inventors: Lee-Ching Kuo, Jinn-Shing King, Wen-Yueh Hsu, Yu-Tai Tsai
  • Patent number: 5693373
    Abstract: A method of improving heat-seals for polyolefin polymers which are coated onto a paperboard substrate. The method obviates the need for use of a curable bonding agent. The materials are exposed to high energy radiation prior to formation of the heat seal to induce crosslinking of the poller and thereby increase the average molecular weight of same.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: December 2, 1997
    Assignee: International Paper Company
    Inventor: Joe L. Kinsey, Jr.
  • Patent number: 5683741
    Abstract: Method for the quality-controlled treatment of surfaces with a radiation-cured surface treatment, in which a finishing formulation is applied to the surface and is polymerically crosslinked under the effect of radiation. To enable the quality control to be conducted non-destructively and at reduced cost, it is proposed that the finishing formulation contains a proton-affinitive indicator substance analyzable by ion mobility spectroscopy and that the indicator substance escaping from the printed or coated surface after the radiation curing is analyzed by means of ion mobility spectroscopy.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: November 4, 1997
    Assignees: Druckfarbenfabrik Gebr.Schmidt GmbH, Brucker-Saxonia Analytik GmbH
    Inventors: Hans-Peter Seng, Reiner Mehnert, Hans-Rudiger Doring
  • Patent number: 5662834
    Abstract: An alloy of formula:Ti.sub.30+x Ru.sub.15+y Fe.sub.25+z O.sub.30+t M.sub.uwherein M represent at least one metal selected from the group consisting of chromium, manganese, vanadium, tungsten, antimony, platinum and lead; x is an integer ranging between -30 and +50; y is an integer ranging between -10 and +35; z is an integer ranging between -25 and +70; t is an integer ranging between -28 and +10; and u is an integer ranging between 0 and +50; x, y, z, t and u being selected so that: x+y+z+t+u=0. This alloy, especially when it has a nanocrystalline structure, is useful for the manufacture cathodes for the electro-chemical synthesis of sodium chlorate. These cathodes have an over-potential of hydrogen lower than the one of the soft-steel cathodes presently in use.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: September 2, 1997
    Assignee: Hydro-Quebec
    Inventors: Robert Schulz, Andre Van Neste, Sabin Boily, Shize Jin
  • Patent number: 5648011
    Abstract: The structurally stable gelled electrolyte of the present invention includes a base electrolyte, a three-dimensional polymer precursor that is radiation curable and an electrically non-conducting solvent gelling agent. The base electrolytes of this invention are comprised of an aprotic liquid and a dissolved ionizable alkaline metal salt. The preferred radiation curable polymer pre-cursors of this invention include trimethylol propane ethoxy triacrylate (TMPEOTA) and poly(ethylene glycol) diacrylate (PEGDA). The solvent gelling agent should be a solid powder or polymer with high surface area to adsorb the liquid electrolyte. Solid powders that can be used in the gelling agent include inorganic oxygen compounds such as silica (SiO.sub.2), titania (TiO.sub.2), alumina (Al.sub.2 O.sub.3), magnesium oxide (MgO), barium oxide (B.sub.2 O.sub.3) and the like. Other compounds that can be used in the gelling agent include super absorbent polymers, clays, zeolite and such.
    Type: Grant
    Filed: March 15, 1995
    Date of Patent: July 15, 1997
    Assignee: Micron Communications, Inc.
    Inventor: Peter Miller Blonsky
  • Patent number: 5633049
    Abstract: The present invention provides an acid-resistant protective coating, preferably an acid- and abrasion-resistant protective coating, for thermoplastic transparencies, particularly aircraft transparencies. The coating is prepared from a silica-free protective coating precursor composition comprising a multifunctional ethylenically unsaturated ester of acrylic acid, a multifunctional ethylenically unsaturated ester of methacrylic acid, or a combination thereof; and an acrylamide.
    Type: Grant
    Filed: September 8, 1995
    Date of Patent: May 27, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Zayn Bilkadi, Thomas W. Rambosek
  • Patent number: 5589270
    Abstract: Electrification is suppressed with a water-soluble electrification-suppressing film having an electron conductivity and comprising a polymer resin. A high electrification-suppressing effect which is also high in vacuum can be easily obtained by using the electrification-suppressing film with less contamination.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: December 31, 1996
    Assignees: Hitachi, Ltd., Showa Denko K.K.
    Inventors: Fumio Murai, Yasunori Suzuki, Hideki Tomozawa, Ryuma Takashi, Yoshihiro Saida, Yoshiaki Ikenoue
  • Patent number: 5529812
    Abstract: The present invention concerns a method of manufacturing decorative board meeting exceptionally high standard concerning abrasion resistance, scratch resistance and impact resistance and which for this pruposes is varnished, electron-beam cured to 60-9.5%, is subjected to a pressing treatment and finally it is electron-beam cured to 100% to provide the disired abrasion resistance, gloss, and surface finish.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: June 25, 1996
    Inventor: Djorn Keding
  • Patent number: 5525392
    Abstract: The present invention relates to a process for coating a magnetic recording device with a lubricating polymeric film using an ion beam generator.
    Type: Grant
    Filed: August 11, 1995
    Date of Patent: June 11, 1996
    Assignee: International Business Machines Corporation
    Inventors: Thomas H. Baum, Paul B. Comita, Mark S. Crowder, George W. Tyndall, III
  • Patent number: 5523115
    Abstract: The present invention provides magnetic recording media comprising a magnetizable layer and optionally a backside coating provided on a nonmagnetizable substrate. At least one of the magnetizable layer and the optional backside coating comprises a polymeric binder, wherein the polymeric binder is obtained from reactants comprising a free radical generator and a radiation curable polymer. The radiation curable polymer comprises a plurality of radiation curable, .alpha.
    Type: Grant
    Filed: December 12, 1994
    Date of Patent: June 4, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: John C. Haidos, Ravindra L. Arudi, Nelson T. Rotto
  • Patent number: 5501882
    Abstract: A method of making a heat-resistant coated electrically conductive wire is provided. The method involves forming an insulating coating of one or more thermoplastic resins containing aromatic rings or complex rings which are not cross-linkable alone by electron beams. Exemplary resins are polyetheretherketone, polyamide, polyetherimide, polyallylate, polycarbonate and polysulfone. The method then involves subjecting the insulating coating to irradiation with an accelerated ion beam, which cross-links the resin or resins. The energy of the accelerated ion beam is in a range of 0.1 MeV to 50 MeV, and the dose of the accelerated ion beam is in a range of 1.times.10.sup.11 ions/cm.sup.2 to 1.times.10.sup.15 ions/cm.sup.2.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: March 26, 1996
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventor: Satoshi Shukushima
  • Patent number: 5501745
    Abstract: The present invention relates to a low temperature method for making a photovoltaic material. In particular, the present invention describes a low temperature method for the deposition in vacuo of successive layers of materials required for a photovoltaic device. The present invention uses ion beam assisted processes in which a selected silicon containing precursor film is controllably converted to an amorphous silicon and carbon mixture. Ion beams are used to control the hydrogen content and thereby control the electrical conductivity of the material. The present invention further comprises the addition of a dopant and the deposition of the electrical contacts, both by thermal evaporation.
    Type: Grant
    Filed: May 31, 1994
    Date of Patent: March 26, 1996
    Assignee: Southwest Research Institute
    Inventor: Geoffrey Dearnaley
  • Patent number: 5480682
    Abstract: The present invention discloses an improved method of producing a low-cost, nitrogen-based inert atmosphere suitable for radiation curing of resins, coatings, etc. from non-cryogenically generated nitrogen. According to the disclosed method, residual oxygen present in non-cryogenically generated nitrogen is converted to either moisture or a mixture of moisture and carbon dioxide by reaction with a reducing gas in a catalytic reactor prior to using the nitrogen-based atmosphere for radiation curing of moisture insensitive materials such as resins and coatings.
    Type: Grant
    Filed: August 25, 1994
    Date of Patent: January 2, 1996
    Assignee: Air Products and Chemicals, Inc.
    Inventors: John J. Kaiser, Diwakar Garg
  • Patent number: 5470652
    Abstract: The support sheet for photographic printing paper of the present invention includes a substrate paper sheet, a front surface composite resin coating layer formed on the front surface of the substrate paper sheet and including an inside cured resin layer and outermost cured resin layer including, as a main component, an electron beam-curing product of electron beam-curable unsaturated organic compound, and a back surface resin coating layer formed on the back surface of the substrate paper sheet and including a film-forming synthetic resin, and is produced by a process including the steps of forming at least one inside coating liquid layer including an electron beam-curable unsaturated organic compound on the front surface of the substrate paper sheet;separately forming an outermost coating liquid layer containing an electron beam-curable unsaturated organic compound on a shaping surface and applying thereto a first electron beam irradiation to provide an outermost cured resin layer;superimposing the outermost
    Type: Grant
    Filed: June 2, 1993
    Date of Patent: November 28, 1995
    Assignee: Oji Paper Co., Ltd
    Inventors: Takaharu Miura, Hiroyuki Nemoto, Masataka Ito, Masafumi Kobayashi, Chieko Tanaka
  • Patent number: 5453449
    Abstract: Coating composition suitable for use in the production of coatings with a rapidly curable surface containingA) 10-80 wt. % of one or more compounds with on average at least two CH-acid hydrogen atoms,B) 10-80 wt. % of one or more .alpha.,.beta.-unsaturated compounds with at least two identical or different groups of the general formula R.sub.1 R.sub.2 C.dbd.CR.sub.3 --CO-- which are linked together by the residue of a di-or polyhydric alcohol, a di- or polyamine or aminoalcohol, in which R.sub.1, R.sub.2 and R.sub.3 are mutually independently a hydrogen atom or a straight or branched alkyl residue with 1 to 10 carbon atoms, which residue may be olefinically mono- or polyunsaturated and/or may have one or more hydroxyl groups,C) 0-50 wt. % of one or more radically or ionically polymerisable compounds,D) 5-50 wt.
    Type: Grant
    Filed: July 20, 1993
    Date of Patent: September 26, 1995
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Drueke: Stefan, Carmen Flosbach, Walter Schubert
  • Patent number: 5441775
    Abstract: Aqueous dispersions containA) from 20 to 90% by weight of a dispersed polymer having a glass transition temperature above 30.degree. C. andB) from 10 to 80% by weight of a tri-, tetra-, penta-or hexa(meth)acrylate of an alkoxylated, trivalent to hexavalent alcohol having a mean degree of alkoxylation of the hydroxyl groups of the alcohol, defined as the quotient of the number of alkoxy groups to the number of hydroxyl groups, ie. the functionality of the alcohol prior to the alkoxylation, of at least 0.5,the stated weights being based on the sum of A) and B).
    Type: Grant
    Filed: May 6, 1994
    Date of Patent: August 15, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Erich Beck, Gregor Ley, Erich Gulbins, Bernhard Schlarb, Edmund Keil, Matthias Lokai
  • Patent number: 5436033
    Abstract: The invention concerns an ultra thin polymer film electret comprising a polymer and a substrate having a surface electric charge, wherein a side chain of the polymer and the substrate are physically or chemically bonded. A method of manufacturing an ultra thin polymer film electret comprising: adsorbing a monomolecular film comprising a unsaturated group or a laminated film comprising the monomolecular film on to a substrate surface, irradiating the monomolecular film or the laminated film with an energy beam to polymerize the unsaturated groups and applying a high voltage to the film is also disclosed. Further, a method of manufacturing an ultra thin polymer film electret comprising: physically bonding a side chain of the polymer to a substrate surface to form a thin film and applying a high voltage to the thin film is also disclosed.
    Type: Grant
    Filed: August 1, 1994
    Date of Patent: July 25, 1995
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Norihisa Mino, Yoshikazu Yamagata, Kazufumi Ogawa
  • Patent number: 5433979
    Abstract: Non-slip laminatable materials are provided by coating a polymer sheet backing with mineral particles adhered to the backing by a radiation curable adhesive.
    Type: Grant
    Filed: August 18, 1994
    Date of Patent: July 18, 1995
    Assignee: Norton Company
    Inventor: David E. Williams
  • Patent number: 5405657
    Abstract: A process for the production of flexible impregnated protective, auxiliary and insulating materials on a fibre basis for electrical purposes by the application of an impregnating agent to the material to be impregnated, followed by curing, characterised in that a solvent-free impregnating mass containing one or more olefinically unsaturated, radically polymerisable polyesters, which contain one or more radically polymerisable monomers as reactive diluents, one or more plasticizing agents and optionally one or more peroxide-free radical initiators is applied to the material to be impregnated and curing is then carried out with high energy radiation and optionally by further heating.
    Type: Grant
    Filed: November 2, 1993
    Date of Patent: April 11, 1995
    Assignee: Herberts G.m.b.H.
    Inventors: Udo Bastian, Rainer Krause, Gerhard Kiessling
  • Patent number: 5387622
    Abstract: Perfume compositions are formed by hydrolyzing an aqueous mixture of an alkoxide, a silane coupling agent, and a perfume substance using an acid catalyst, then condensing the resulting hydrolysate using a base catalyst, to form a conjugated polymer matrix encapsulating and/or clathrating the perfume substance.
    Type: Grant
    Filed: June 28, 1991
    Date of Patent: February 7, 1995
    Inventor: Tohru Yamamoto