Dye-fixing Agent In Ink Receptive Layer Patents (Class 428/32.3)
  • Patent number: 7014894
    Abstract: There is disclosed an ink jet recording sheet which comprises a substrate and an ink accepting layer composed of at least two layers on the substrate, characterized in that the ink accepting layer comprises at least one cracked layer having cracks in lower layers other than a surface layer (the layer farthest from the substrate) and a contact layer in contact with the cracked layer, wherein part of the contact layer cuts into the cracked layer, and the cracked layer contains a hydrophobic resin (e.g. styrene-acrylics copolymer resin) as a binder, or wherein the contact layer is formed by coating with a coating solution having viscosity of at most 3000 mPa.s and a proportion of solid content in the range of 10 to 30% by weight. The above ink accepting layer is excellent in water resistance and strength of adhesion among the interlayers, whereby the ink jet recording sheet as a whole becomes excellent in scratch-abrasion resistance under wet conditions as well as image density.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: March 21, 2006
    Assignee: Nisshinbo Industries, Inc.
    Inventor: Hirotaka Yamamoto
  • Patent number: 7008676
    Abstract: An ink jet recording element having a substrate having thereon: a) a subbing layer comprising an amine inactivated gelatin; and b) an image-receiving layer of a cross-linkable polymer containing hydroxyl groups and a polymeric mordant, the cross-linkable polymer being present at a thickness of from about 2 to about 40 ?m and the weight ratio of the cross-linkable polymer to the mordant being from about 30:70 to about 95:5.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: March 7, 2006
    Assignee: Eastman Kodak Company
    Inventors: Charles E. Romano, Jr., Richard J. Kapusniak
  • Patent number: 7005162
    Abstract: The invention provides methods for providing improved image quality and water resistance of dye based ink images on substrates using aqueous dispersed mordants and dispersed hydrophobic materials.
    Type: Grant
    Filed: June 10, 2004
    Date of Patent: February 28, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Lori P. Engle, David W. Tweeten
  • Patent number: 6994026
    Abstract: A method for the preparation of a flexographic printing plate is disclosed. In this method an ink jet image is used as mask for the exposure of a flexo plate precursor. The ink jet recording material is composed of several layers and comprises a binder, a cationic mordant and a spacing agent in its top layer.
    Type: Grant
    Filed: February 3, 2003
    Date of Patent: February 7, 2006
    Assignee: AGFA-Gevaert
    Inventors: Frank De Voeght, Peter Slabbinck, Huub Van Aert
  • Patent number: 6984423
    Abstract: The present invention provides less expensive ink jet recording papers having high glossiness and high durability and being capable of quickly absorbing inks without causing bleeding. Accordingly, the present invention provides an ink jet recording paper having an ink-receiving layer provided on a porous resin film, wherein the porous resin film has a liquid absorption capacity measured in accordance with “Japan TAPPI No.51-87” of 0.5 ml/m2 or above and the ink-receiving layer has a surface glossiness (JIS-Z8741: measuring method at 60°) of 40% or above. It is preferable that the ink jet recording paper contains at least one member selected from among alumina, alumina hydrate and amorphous silica in the ink-receiving layer.
    Type: Grant
    Filed: September 16, 2002
    Date of Patent: January 10, 2006
    Assignee: Yupo Corporation
    Inventors: Seiichiro Iida, Yasuo Iwasa
  • Patent number: 6969445
    Abstract: The object of the present invention is to provide an ink jet recording paper of so-called plain paper type having no coating of pigment on the recording surface which is excellent in image density and color reproducibility of the recorded image and besides has a water resistance of the printed portion. According to the present invention, there is provided an ink jet recording paper which comprises a neutral base paper comprising a wood pulp as a main starting material on which is coated a coating solution containing a fluorescent brightening agent, a water-soluble binder and a cationic polymer fixing agent and in which the coated paper has an ISO whiteness of not less than 95% and a fluorescence intensity of 7–15% measured by a method specified in JIS P-8148 using a xenon flash lamp as a light source.
    Type: Grant
    Filed: April 12, 1999
    Date of Patent: November 29, 2005
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Yoshihiko Hibino, Koji Idei
  • Patent number: 6962735
    Abstract: A textile substrate is treated with a composition having a dye fixing agent and an ink receiving agent, for the subsequent printing with an ink jet printer. The dye fixing agent includes a reactive amino compound, and the ink receiving agent comprises inorganic particles. A resin binder can also be used where the dye fixing agent does not provide an adequate bond to the textile substrate.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: November 8, 2005
    Assignee: Milliken & Company
    Inventors: Shulong Li, Anthony S Brandon
  • Patent number: 6951672
    Abstract: Ceramic pigment-based, chemically-modified porous coatings can be used for enhancing image permanence of ink-jet image printing. Specifically, a porous coated media sheet, comprising a media substrate, having a porous coating coated thereon comprising a modified ceramic pigment including a fixer group and a stabilizer group, each covalently attached to the ceramic pigment is disclosed. Additionally, a method and system for preparing permanent ink-jet images is also provided.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: October 4, 2005
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Kent D. Vincent, Sivapackia Ganapathiappan, Sean Xiao-An Zhang, Palitha Wickramanayake
  • Patent number: 6926936
    Abstract: An ink-jet recording material having a high ozone resistance comprises at least one ink-absorbing and at least one dye-fixing layer wherein on the top and/or bottom side of the dye-fixing layer, at least one water-soluble compound exhibiting ionic charge centres is arranged, which compound exhibits a dissociation constant in the region of 1×10?3 to 1×10?14 with a conductivity range ? of 6 to 25 ms at a temperature of 25° C.±1° C. in a 0.1 molar aqueous solution.
    Type: Grant
    Filed: May 20, 2003
    Date of Patent: August 9, 2005
    Assignee: Felix Schoeller Jr. Foto-und Spezialpapiere GmbH & Co. KG
    Inventors: Richard A. Barcock, Douglas J. Brownbridge, Natasha M. Dimbleby, Aidan Joseph Lavery, Robert M. Phillips
  • Patent number: 6919109
    Abstract: The present invention provides an ink-jet recording sheet having a coloring agent accepting layer which contains a dispersion containing a cationic polymer with an average molecular weight of 60,000 or lower and having a sulfate ion concentration of 1.5% by mass or lower to the cationic polymer together with a water-soluble resin; an particle dispersion obtained by further granulating a pre-dispersion obtained by pre-dispersing a solution containing at least fine particles and a cationic polymer and the pre-dispersion and/or the particle dispersion is heated at room temperature for 5 hours or longer after pre-dispersion and/or after granulating; and a coating solution for coloring agent accepting layer obtained by adding a water-soluble resin to the particle dispersion.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: July 19, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ryoichi Nakano, Shunsaku Higashi, Takashi Kobayashi
  • Patent number: 6908648
    Abstract: An ink-jet recording sheet containing a support having the following layers in the order: (a) a porous layer; and (b) a surface porous layer containing an organic particle A or an organic particle B, the organic particle A being insoluble in water and soluble in or swollen in a water soluble organic solvent having a SP value of 18.41 to 30.69 (MPa)1/2 and a boiling point of not less than 120° C.; the organic particle B comprising a copolymer having a specific recurring unit in an amount of not less than 5 weight % based on the total weight of the copolymer; the organic particle A and the organic particle B each having an average particle size of not more than 100 nm and a glass transition temperature of not less than 70° C., wherein the porous layer or the surface porous layer contains a compound having a polyvalent metal element.
    Type: Grant
    Filed: March 13, 2003
    Date of Patent: June 21, 2005
    Assignee: Konica Corporation
    Inventor: Kenzo Kasahara
  • Patent number: 6902781
    Abstract: An ink-jet recording medium is disclosed. The ink accepting layer of the recording medium contains silica dispersion containing silica particles having a ratio of a free silanol group of 1.0 to 4.5. Silica particles and silica particle dispersion are also disclosed.
    Type: Grant
    Filed: March 27, 2003
    Date of Patent: June 7, 2005
    Assignee: Konica Corporation
    Inventors: Kiyoshi Endo, Tomohiko Sakai, Masako Kikuchi
  • Patent number: 6893690
    Abstract: Provided is an ink jet recording sheet suitable for outdoor use, the recording sheet giving rise to no blurring of an image, being provided with an ink receiving layer and a print portion having high water-resistance and excellent abrasive resistance in a wet condition while maintaining color developing ability and ink-fixing ability and having excellent color reproducibility and light resistance.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: May 17, 2005
    Assignee: Nisshinbo Industries, Inc.
    Inventor: Hirotaka Yamamoto
  • Patent number: 6890610
    Abstract: A recording element comprising a support having thereon an image-receiving layer, said recording element containing core-shell particles wherein said core comprises an inorganic or organic particle and said shell comprises an organosilane or a hydrolyzed organosilane derived from a compound having the formula: Si(OR)aZb wherein R is hydrogen, or a substituted or unsubstituted alkyl group having from 1 to about 20 carbon atoms or a substituted or unsubstituted aryl group having from about 6 to about 20 carbon atoms; Z is an alkyl group having from 1 to about 20 carbon atoms or aryl group having from about 6 to about 20 carbon atoms, with at least one of said Z's having at least one primary, secondary, tertiary or quaternary nitrogen atom; a is an integer from 1 to 3; and b is an integer from 1 to 3; with the proviso that a+b=4; and with the further proviso that the amount of organosilane shell material is such that Ratio R, which is the number of micromoles of organosilane used to shell the core particle
    Type: Grant
    Filed: July 18, 2003
    Date of Patent: May 10, 2005
    Assignee: Eastman Kodak Company
    Inventors: Joseph F. Bringley, Krishnamohan Sharma, Gary N. Barber
  • Patent number: 6869648
    Abstract: The present invention relates to a print medium with improved resistance to airfade. The print medium is coated with a high molecular weight additive having low volatility. The high molecular weight additive is a monomeric or oligomeric compound that has a molecular weight of greater than approximately 1000. The high molecular weight additive is a hindered amine light stabilizer or a fixative. The present invention also relates to a method of producing a print medium with improved airfastness. The method comprises coating a print medium with a high molecular weight additive having low volatility. An image is then printed on the coated print medium and subjected to at least one atmospheric gas. The airfastness of the printed image is measured and compared to the airfastness of an image printed on an uncoated print medium.
    Type: Grant
    Filed: June 18, 2002
    Date of Patent: March 22, 2005
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Radha Sen
  • Patent number: 6869647
    Abstract: Ink-receiving print media products having multiple capabilities including (A) minimal drying time; (B) improved smear-fastness; (C) a high level of water-fastness; (D) the ability to generate high-definition images; and (E) excellent ink compatibility. The media products have at least one ink-receiving layer on a substrate (e.g. paper pre-coated with one or more binders and/or pigments). The ink-receiving layer includes a pigment (boehmite, pseudo-boehmite, or mixtures thereof) optimally combined with a special binder blend [polyvinyl alcohol, a poly(vinyl acetate-ethylene) copolymer, and a poly(vinyl pyrrolidone-vinyl acetate) copolymer]. Also included is a special dye fixative (namely, a cationic emulsion polymer) which provides enhanced water-fastness. This fixative is of a particular type (a quaternary amine) that also allows high pigment levels to be employed (at least about 65% by weight) which further promotes the foregoing benefits.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: March 22, 2005
    Assignee: Hewlett-Packard Development Company L.P.
    Inventors: Loretta Ann Grezzo Page, Richard J. McManus
  • Patent number: 6861111
    Abstract: An additive which can improve the water resistance of a water-soluble dye with which an article has been dyed; and an ink-jet recording medium which contains the additive, is exellent in the water resistance and resolution of characters or images recorded thereon, and is suitable for multicolor recordeng. The additive is obtained by reacting a secondary amine, ammonia, an epihalohydrin, and a crosslinking agent as essential ingredients. The recording medium is obtained by causing the additive to be present on a surface and/or inner part of a base.
    Type: Grant
    Filed: February 10, 2000
    Date of Patent: March 1, 2005
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Makoto Hasegawa, Noriko Kumazawa
  • Patent number: 6846526
    Abstract: An ink jet recording element comprising a support having thereon a porous image-receiving layer comprising particles, a poly(vinyl alcohol) binder and a crosslinking agent, the particles having a primary particle size of from about 7 to about 40 nm in diameter which may be aggregated up to about 300 nm, and the crosslinking agent being present in an amount of at least about 20 weight % of the poly(vinyl alcohol) binder.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: January 25, 2005
    Assignee: Eastman Kodak Company
    Inventors: Alexandra D. Bermel, Lori J. Shaw-Klein
  • Patent number: 6841204
    Abstract: In a recording medium for a printer having a dye fixation layer mainly composed of an interlayer compound for receiving and holding a water-soluble dye by an intercalation reaction, and a binder, the ink is to be improved in ink absorption, fixation, water-proofness and bleeding characteristics to enable image formation to a high resolution. A dye fixation layer, mainly composed of an interlayer compound for fixing and holding the water-soluble dye by the intercalation reaction derived from the ion exchange action and the binder is formed as an outermost layer on a substrate 2. The binder of the dye fixation layer contains an urethanated polyvinyl alcohol resin having an urethanation ratio of 1 to 20 mol %.
    Type: Grant
    Filed: September 12, 2002
    Date of Patent: January 11, 2005
    Assignee: Sony Corporation
    Inventors: Yoshinori Nakamura, Kengo Ito
  • Patent number: 6838134
    Abstract: A recording sheet adaptable to print an image using pigment ink, on which a smear is hardly generated, is provided. A recording sheet includes an ink permeable layer prepared by adding 3-30 parts by weight of a nonionic surfactant including an amine compound as a main component to 30 parts by weight of a water-insoluble component including an inorganic filler and a binder as main components. Ink applied on such an ink permeable layer is directly absorbed into the layer in a depth direction without dispersing in a lateral direction. Therefore, any smear (banding) is hardly generated on a printed image formed on the recording sheet using ink.
    Type: Grant
    Filed: June 14, 2001
    Date of Patent: January 4, 2005
    Assignee: Sony Chemicals Corp.
    Inventors: Jun Takahashi, Akio Ito, Yukiko Murasawa, Hideaki Takahashi
  • Patent number: 6827992
    Abstract: The present invention comprises an ink recording element comprising at least one solvent absorbing layer comprising an amine inactivated absorbing gelatin. In a preferred embodiment, the element includes a hydrophilic overcoat layer comprising cellulose ether. The recording element may further comprise at least one hydrophilic inner layer comprising poly(vinyl alcohol) and located between the hydrophilic absorbing layer and the hydrophilic overcoat layer.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: December 7, 2004
    Assignee: Eastman Kodak Company
    Inventors: Charles E. Romano, Jr., David M. Teegarden
  • Patent number: 6821584
    Abstract: An ink-jet recording sheet comprising a support having thereon in the following order: (i) a first ink absorbing layer comprising gelatin and a first cationic polymer; and (ii) a second ink absorbing layer comprising gelatin and a second cationic polymer, wherein the first cationic polymer has a larger ink absorption ratio Ai than the second cationic polymer, the ink absorption ratio Ai being defined by the following equation: Ai (%)=((an optical density of a print after immersion in water)/(an optical density of a print before immersion in water))×100.
    Type: Grant
    Filed: May 20, 2003
    Date of Patent: November 23, 2004
    Assignee: Konica Corporation
    Inventors: Kouji Tashiro, Toyoki Nishijima, Shinichi Suzuki, Kunimasa Hiyama, Junji Ito
  • Patent number: 6815018
    Abstract: An ink jet recording element having a support having thereon in order: a) at least one porous, ink-retaining layer; and b) a fusible, porous ink-transporting layer of a film-forming, hydrophobic binder and fusible, polymeric particles of a cellulose ester.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: November 9, 2004
    Assignee: Eastman Kodak Company
    Inventors: Allan Wexler, Kevin M. O'Connor, Kurt M. Schroeder
  • Patent number: 6815020
    Abstract: An ink jet recording element having a support having thereon a porous image-receiving layer having: (a) particles having a mean particle size of from greater than 0.04 &mgr;m to about 5 &mgr;m; and (b) water insoluble, cationic, polymeric particles having at least about 20 mole percent of a cationic mordant moiety.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: November 9, 2004
    Assignee: Eastman Kodak Company
    Inventors: Sridhar Sadasivan, Elizabeth A. Gallo, John M. Baier
  • Patent number: 6815021
    Abstract: The present invention provides a recording medium for ink jet printers in which superior image recording quality and color stability are exhibited. In a recording medium for ink jet printers in which an ink receiving layer contained at least pigment and binder resin is provided on a supporting material, partially saponified PVA having a degree of saponification of 85.0 to 73.0 mol % and a degree of polymerization of 300 to 1500, is contained in the ink receiving layer as a color stability improving component.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: November 9, 2004
    Assignees: Seiko Epson Corporation, Tomoegawa Paper Co., Ltd.
    Inventors: Takayuki Ishikawa, Nobuhiro Kubota, Minoru Tsuchida, Shigeki Asai, Takeshi Yoshimoto, Kiyoshi Iwamoto, Jun Sugiyama, Hiroyuki Onishi, Yukari Ishikawa
  • Patent number: 6811837
    Abstract: The invention provides a porous resin film having a good absorption of water content as a solvent for aqueous ink or aqueous paste and a recording medium comprising the porous resin film. The recording medium is characterized by the capability of absorbing an ink without density unevenness even during ink jet recording if the ejected amount of ink is great. The invention lies in a porous resin film comprising: a thermoplastic resin in an amount of 30 to 90% by weight; and an inorganic and/or organic finely divided powder in an amount of 10 to 70% by weight, wherein the inorganic and/or organic finely divided powder is surface-treated with a surface treating agent (A) made of a copolymer of diallylamine salt or alkyl diallylamine salt (a1) with a nonionic hydrophilic vinyl monomer (a2) and an anionic surface treating agent (B), and the porous resin film has a liquid absorption capacity of not smaller than 0.5 ml/m2 as measured by “Japan TAPPI No. 51-87”.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: November 2, 2004
    Assignee: Yupo Corporation
    Inventors: Yasuo Iwasa, Seiichiro Iida, Nobuhiro Shibuya
  • Patent number: 6811839
    Abstract: Disclosed herein is a recording medium comprising a base material, and at least one resin selected from a primary amine resin and a secondary amine resin and a hindered amine compound contained in the base material and/or on the surface of the base material.
    Type: Grant
    Filed: November 5, 2001
    Date of Patent: November 2, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masaaki Hiro, Kenji Shinjo, Katsutoshi Misuda
  • Patent number: 6811838
    Abstract: The present invention relates to an ink recording element comprising a hydrophilic absorbing layer and a hydrophilic overcoat polymer layer comprising cellulose ether and a vinyl latex polymer. An optional inner layer may be placed between the hydrophilic absorbing layer and the laminate adhesion promoting hydrophilic overcoat polymer. Another embodiment of the invention relates to an ink printing method comprising providing an ink recording element as described above, and applying liquid ink droplets thereon in an image-wise manner.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: November 2, 2004
    Assignee: Eastman Kodak Company
    Inventors: Charles E. Romano, Jr., David M. Teegarden
  • Patent number: 6808767
    Abstract: High gloss ink jet recording media are produced without need for calendering or supercalendering. The media are comprised of a substrate, such as paper, an ink carrier vehicle absorptive coating on the substrate and an ink-receptive coating overlying the absorptive coating. The absorptive coating is made up in major part of a pigment component that is comprised in major part, i.e., 60-100%, and preferably 100%, of calcined clay. The absorptive coating is applied to the substrate at a thickness sufficient to provide a smooth and level surface. The ink receptive coating is porous and made up of constituents that provide requisite ink holdout and print quality functions and that, when applied to the absorptive coating, also provide a high gloss print surface without calendering or supercalendering. The recording media have exceptionally quick ink drying times and provide excellent high-gloss print quality.
    Type: Grant
    Filed: April 19, 2001
    Date of Patent: October 26, 2004
    Assignee: Stora Enso North America Corporation
    Inventor: Leonard J. Schliesman
  • Patent number: 6800342
    Abstract: The present invention comprises an ink recording element comprising a support having thereon a hydrophilic absorbing layer, a laminate adhesion promoting polymer inner layer, and a hydrophilic overcoat polymer layer and a method therefor.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: October 5, 2004
    Assignee: Eastman Kodak Company
    Inventors: Charles E. Romano, Jr., David M. Teegarden
  • Patent number: 6797347
    Abstract: Paper coating compositions are provided for use with thermal ink-jet color printers, such as Hewlett-Packard Company's DeskJet® printer. The organic pigment present in the paper is modified by the addition of a metal-charge complex which causes anionic colorants in the ink to be precipitated on the surface of the paper. Printing any of the ink-jet ink sets onto the specially-prepared paper improves resolution, color retention, waterfastness, smear-fastness, image retention and image density while decreasing image bleed in ink-jet printing.
    Type: Grant
    Filed: September 5, 2002
    Date of Patent: September 28, 2004
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Joseph S. Chow
  • Patent number: 6777040
    Abstract: A recording sheet for an ink jet printer can improve both recording properties such as vividness of images, printing density, etc., and shelf life such as light resistance of images, ozone resistance, etc. The recording sheet for an ink jet printer comprises a base material and an ink receiving layer provided on at least one surface of the base material, in which the recording sheet contains oligosaccharide and divalent metallic salt.
    Type: Grant
    Filed: August 29, 2002
    Date of Patent: August 17, 2004
    Assignee: Tomoegawa Paper Co., LTD
    Inventors: Fumikazu Tatsuhashi, Nobuhiro Kubota, Shigeki Asai, Senichi Yoshizawa, Kazushige Katagiri, Minoru Tsuchida
  • Patent number: 6777039
    Abstract: An inkjet recording sheet comprising a support and, on a surface of the support, a colorant-receiving layer formed by applying a first coating liquid, adding a second coating liquid, after application of the first coating liquid and before the same shows a decreasing rate of drying, and thereafter hardening and drying the coat layer to form a porous structure. The first coating liquid has a pH value of 5 or lower, and is obtained by adding a solution which includes polyvinyl alcohol, a nonionic surfactant and/or amphoteric surfactant and a high boiling point organic solvent, to a dispersion including a cationic resin and vapor-phase-process silica having a specific surface area of at least 200 m2/g as measured by the BET method. The second coating liquid has a pH value of 8.5 or higher and includes a cross-linking agent capable of cross-linking the polyvinyl alcohol, an organic mordant and a nonionic surfactant.
    Type: Grant
    Filed: April 19, 2002
    Date of Patent: August 17, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuyuki Koike, Takashi Kobayashi, Katsuyoshi Suzuki, Ryoichi Nakano
  • Patent number: 6773770
    Abstract: An ink jet recording material appropriate to ink recording, preferably pigment ink recording, has an ink receiving layer formed on a support and including a pigment containing amorphous silica, alumina and/or alumino silicate, a binder, and a cationic resin having a cation equivalent of 1.5 to 6 milli equivalent/g, as determined by a colloid titration method.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: August 10, 2004
    Assignee: OJI Paper Co., Ltd.
    Inventors: Naonobu Sugiyama, Kazuo Totani, Hiromasa Kondo
  • Patent number: 6770336
    Abstract: An inkjet recording element having a support having thereon in order: (I) a base layer of at least about 50% by weight of inorganic particles; and (II) an image-receiving layer of: (a) colloidal, inorganic oxide particles having a mean particle size of from about 10 to about 500 nm; and (b) water-insoluble, cationic, polymeric particles having a benzyldimethyl benzylammonium moiety.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: August 3, 2004
    Assignee: Eastman Kodak Company
    Inventors: Yongcai Wang, Lori J. Shaw-Klein, Thomas P. Nicholas, Sridhar Sadasivan, Lixin Chu
  • Patent number: 6764725
    Abstract: The invention provides methods for providing improved image quality and water resistance of dye based ink images on substrates using aqueous dispersed mordants and dispersed hydrophobic materials.
    Type: Grant
    Filed: February 7, 2001
    Date of Patent: July 20, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Lori P. Engle, David W. Tweeten
  • Patent number: 6761941
    Abstract: Disclosed is an inkjet recording sheet having a colorant-receiving layer on the surface of its support, in which the colorant-receiving layer contains at least one of compounds represented by the following general formula (1) and compounds represented by the following general formula (2), and contains a vapor-phase-process silica, a polyvinyl alcohol, a boron compound, and a mordant. In the formulae, R represents a saturated hydrocarbon group having from 1 to 12 carbon atoms, an unsaturated hydrocarbon group having from 1 to 12 carbon atoms, a phenyl group, or an acyl group, and n indicates an integer of 1 to 3.
    Type: Grant
    Filed: April 4, 2002
    Date of Patent: July 13, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Kobayashi, Katsuyoshi Suzuki
  • Patent number: 6759105
    Abstract: Wood surfaces treated to be inkjet receptive media are disclosed, where the wood surface is treated in a manner that can control the spread of an ink droplet reaching the wood surface to provide a superior image graphic. The treatment uses an image fixing agent comprising an aqueous solution of containing an organo-metallic complex of a hydrophobic fatty acid coordinated with a halogenated trivalent chromium. Veneers, plywoods, and particle boards having faces of lesser value woods can be digitally imaged to give the appearance of higher value woods or other customized inkjet images. Environmental and economic considerations benefit from the use of commonly available wood surfaces to simulate exotic and threatened wood species.
    Type: Grant
    Filed: November 9, 2001
    Date of Patent: July 6, 2004
    Inventors: Dennis B. Brooker, George Cash
  • Patent number: 6759106
    Abstract: An ink jet recording element having a support having thereon a porous image-receiving layer with at least 30% by weight of particles and at least 30% by weight of a binder, the particles being a mixture of a) silica gel particles having an average particle size of greater than about 9 &mgr;m in diameter; and b) silica gel particles having an average particle size of between 1 and about 8 &mgr;m in diameter; wherein the ratio of the a) silica gel particles to the b) silica gel particles is from about 0.5 to about 5.
    Type: Grant
    Filed: December 4, 2002
    Date of Patent: July 6, 2004
    Assignee: Eastman Kodak Company
    Inventors: Lixin Chu, Lori J. Shaw-Klein, Kenneth J. Ruschak, Elizabeth A. Gallo, Christine M. Vargas, Charles R. Salerno
  • Patent number: 6723397
    Abstract: An ink jet recording element having a support having thereon in order: a) at least one porous, ink-retaining layer, and b) a fusible, porous ink-transporting layer of fusible, polymeric particles and a film-forming, hydrophobic binder.
    Type: Grant
    Filed: September 18, 2001
    Date of Patent: April 20, 2004
    Assignee: Eastman Kodak Company
    Inventor: Allan Wexler
  • Patent number: 6716494
    Abstract: A transfer sheet comprises a support, and a transfer layer separable from the support and receivable an ink, wherein the transfer layer contains a hot-melt adhesive particle. The hot-melt adhesive particle in the transfer sheet comprises a particle having a melting point of more than 80° C. (A) and a particle having a melting point of not more than 80° C. (B), and the particle (A) comprises a hot-melt adhesive particle having an oil absorption of not less than 50 ml/100 g (A1) and a hot-melt adhesive particle having an oil absorption of less than 50 ml/100 g (A2). Further, the transfer layer may comprise a film-formable resin component and a dye fixing agent. The transfer sheet is excellent in stability on delivery of a sheet, so prevents the inside of the printer from staining, and excels in ink-absorption to a degree that the stain transfer does not occur.
    Type: Grant
    Filed: August 9, 2002
    Date of Patent: April 6, 2004
    Assignees: Seiko Epson Corporation, Daicel Chemical Industries, Ltd.
    Inventors: Hideki Nakanishi, Noboru Yamada, Junichi Iida
  • Patent number: 6699538
    Abstract: An ink jet recording element having a support having thereon the following layers in order: a) a base layer having a polymeric binder and a polymeric mordant; and b) an overcoat layer having a polymeric UV-absorbing material.
    Type: Grant
    Filed: October 31, 2001
    Date of Patent: March 2, 2004
    Assignee: Eastman Kodak Company
    Inventors: Kristine B. Lawrence, Paul B. Merkel, Hwei-Ling Yau
  • Publication number: 20040028842
    Abstract: An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a substrate having thereon: I) a subbing layer of an amine inactivated gelatin; and II) an image-receiving layer of a cross-linkable polymer containing hydroxyl groups and a polymeric mordant, the cross-linkable polymer being present at a thickness of from about 5 to about 60 &mgr;m and the weight ratio of the cross-linkable polymer to the mordant being from about 30:70 to about 95:5; C) loading the printer with an ink jet ink; and D) printing on the image-receiving layer using the ink jet ink in response to the digital data signals.
    Type: Application
    Filed: August 7, 2002
    Publication date: February 12, 2004
    Applicant: Eastman Kodak Company
    Inventors: Charles E. Romano, Richard J. Kapusniak
  • Publication number: 20040028843
    Abstract: An ink jet recording element having a substrate having thereon: a) a subbing layer comprising an amine inactivated gelatin; and b) an image-receiving layer of a cross-linkable polymer containing hydroxyl groups and a polymeric mordant, the cross-linkable polymer being present at a thickness of from about 2 to about 40 &mgr;m and the weight ratio of the cross-linkable polymer to the mordant being from about 30:70 to about 95:5.
    Type: Application
    Filed: August 7, 2002
    Publication date: February 12, 2004
    Applicant: Eestman Kodak Company
    Inventors: Charles E. Romano, Richard J. Kapusniak
  • Patent number: 6689430
    Abstract: An ink jet recording element comprising a support having thereon an image-receiving layer having: (a) inorganic particles having a primary particle size of from about 7 to about 40 nm in diameter which may be aggregated up to about 500 nm; (b) colloidal particles having a mean particle size of from about 20 to about 500 nm; and (c) water-insoluble, cationic, polymeric particles having at least about 20 mole percent of a cationic mordant moiety.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: February 10, 2004
    Assignee: Eastman Kodak Company
    Inventors: Sridhar Sadasivan, Lixin Chu, John M. Baier, Yongcai Wang, Lori J. Shaw-Klein, Elizabeth A. Gallo
  • Publication number: 20040009312
    Abstract: Waterfast coating compositions which are comprised of a blend of a dye fixative and a dispersion of metal oxide particles to form a water-insoluble complex. The ink recording sheets comprise a composition that is absorbed into the surface of the substrate as a sizing material, or alternatively, forms a continuous layer on the substrate. The present invention also encompasses methods for making the ink jet receiving sheets.
    Type: Application
    Filed: June 6, 2003
    Publication date: January 15, 2004
    Inventor: Michael F. Koenig
  • Patent number: 6677006
    Abstract: An ink-jet recording material having on a support at least an ink-receiving layer, with the ink-receiving layer being comprised of a light resistance-imparting layer as a lower layer and a coloration layer as an upper layer. Herein, the light resistance-imparting layer comprises a light-resistance imparting chemical constituted of 1 to 10 parts by weight of a benzotriazole compound as ultraviolet absorbent, 1 to 8 parts by weight of magnesium sulfate and 1 to 10 parts by weight of zinc oxide in combination with 100 parts by weight of an ink absorbing pigment, and besides, the coloration layer contains no light resistance-imparting chemicals.
    Type: Grant
    Filed: July 19, 2001
    Date of Patent: January 13, 2004
    Assignees: Nippon Paper Industries Co., Ltd., Seiko Epson Cororaton
    Inventors: Teiichi Otani, Atsushi Ono, Noboru Kondo, Hiroyuki Onishi, Shinya Yamagata, Masaya Shibatani, Jun Sugiyama
  • Patent number: 6670001
    Abstract: A sufficiently flame-retardant fabric for ink-jet recording with an ink accepting layer on its one side at least, the ink acceptability (ink holding capability) of which is the same as that of its non-flame-retardant counterpart, allowing the fabric to render highly deep/brilliant shade and sharp color images. The flame-retardant fabric for ink-jet recording includes a flame retarded fiber substrate with an ink accepting layer on its one side at least, which is made up of a 3-12 &mgr;m-thick top sub-layer and a bottom sib-layer with a flame retarding agent contained only in the bottom sub-layer wherein the flame retarding agent has its active ingredient applied to the substrate in an aqueous dispersion, accounting for 4 to 30% of the entire ink accepting layer by weight.
    Type: Grant
    Filed: February 25, 2002
    Date of Patent: December 30, 2003
    Assignee: Seiren Co., Ltd.
    Inventor: Takahiro Kohsaka
  • Patent number: 6656545
    Abstract: A coating composition for an ink jet recording medium comprises an aqueous suspension of absorptive silica pigment, a polyvinyl alcohol binder, and a cationic fixing agent. The composition is dispersed at pH values in the range of 4.0 to 7.0. The pigment is preferably a mixture of 75% or more silica gel having a pore volume of 0.5-1.5 cc/g, and 10% or more alumina or alumina hydrate. A method for making down the coating composition and applying it to a substrate is also disclosed.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: December 2, 2003
    Assignee: Stora Enso North America Corporation
    Inventors: Leonard J. Schliesman, Leland O. Tritz, Karen K. Spreda
  • Patent number: 6652931
    Abstract: A recording material for ink-jet recording, having on a support a light resistance-imparting layer containing a light resistance-imparting chemical and an image-forming layer free of a light resistance-imparting chemical, which are provided in the order described.
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: November 25, 2003
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Teiichi Otani, Atsushi Ono, Noboru Kondo