Abstract: This invention relates to compositions suitable for the formation of an adhesive layer used for in-mold decoration. This invention also relates to in-mold decoration tape or strip, comprising: a carrier layer; a release layer; a durable layer; and an adhesive layer which comprises an adhesive binder, a polymeric particulate material and an inorganic particulate material.

Abstract: Disclosed is a co-extruded water-proof and moisture-permeable film structure, including a top skin layer, a core layer, and a bottom skin layer. The top and bottom skin layers include polyolefin or polyurethane and the core layer comprise polyurethane. The core layer is disposed between the top and bottom skin layers. If polyurethane is adopted in top and/or bottom skin layers, the polyurethane of the skin layers has lower moisture and vapor permeability than the polyurethane of the core layer. The described film can be manufactured by co-extruded bubble blown or co-extruded casting. In addition, the film can be laminated to a fabric to form a water-proof and moisture-permeable textile.

Abstract: The present invention provides a polyol component for polyurethane formation comprising an anionic diol (A1); and an anionic diol composition comprising said diol (A1), another active hydrogen atom-containing compound (A2), and/or a compounding ingredient (A3) selected from the group consisting of inert solvents (A31) and additives (A32), with the content of (A2) being not higher than 85 mole % based on the total number of moles of (A1) and (A2).

Abstract: A laminate film has a clear layer (B) comprising an acrylic-based polymer (B1) having at least one longer unsaturated double bond group and at least one shorter unsaturated double bond group as side chains, and having a weight-average molecular weight not less than 50,000 but not more than 500,000, the longer unsaturated double bond group introduced in the acrylic-based polymer (B1) by a long-chain unsaturated carboxylic acid having a molecular weight of 150 or more, and the shorter unsaturated double bond group introduced in the acrylic-based polymer (B1) by a short-chain unsaturated carboxylic acid having a molecular weight of less than 150. Compared with laminate films prepared by spray coating, dip coating, or other coating methods, this laminate film is excellent in processability, coating film properties, and ornamental properties. Thus, an article can be excellently decorated with the laminate film provided by the present invention.

Abstract: The invention encompasses compositions with improved adhesive properties and methods of use and manufacture thereof. In particular, the addition of one or more triols to adhesive compositions improved the tensile properties over straight, commercial available pMDI, while also improving cure kinetics.

Abstract: Novel, poison-blocking compositions and methods of using those compositions to form poison-blocking layers are provided. The compositions comprise a typical composition used in microlithographic processes, but with a poison-blocking additive included in that composition. The preferred additive is a compound comprising one or more blocked isocyanates. Upon heating to certain temperatures, the blocking group is released from the isocyanate, leaving behind a moiety that is highly reactive with the poisonous amines generated by typical dielectric layers.

Abstract: A glass fiber reinforced article can be manufactured by: applying a mixture of glass fiber and binder over a mold surface of a first mold section to form a glass fiber matrix, wherein the binder comprises an organic solvent based binder capable of holding the glass fiber in place at room temperature; closing a second mold section over the first mold section to form a plenum between the first mold section and the second mold section, wherein the glass fiber matrix is provided in the plenum between the first mold section and the second mold section; injecting a reactive polymer forming composition into the plenum; and allowing the reactive polymer forming composition to react and form a thermoset resin. A glass fiber reinforced article is provided according to the invention.

Abstract: Describes an optical article, e.g., an ophthalmic photochromic article, such as a lens, in which the article includes: (1) a transparent substrate, such as a thermoset or thermoplastic plastic substrate, (2) a multiply laminate adjacent to at least one surface of the substrate, the laminate comprising (i) a transparent, thermoplastic polyurethane film, the thermoplastic, polyurethane film providing a desirable light filtering property, e.g., photochromism, and being juxtaposed to the surface of the substrate, the polyurethane being formed from a material comprising polyether-based polyurethane or polycarbonate-based polyurethane, and (ii) a transparent protective film of polymeric material, e.g., polycarbonate film, adjacent to the thermoplastic polyurethane film. Describes also the aforedescribed optical article having an abrasion-resistant coating affixed to the protective film, e.g.

Abstract: The present invention includes an image transfer sheet. The image transfer sheet comprises a release layer and a polymer layer. One or more of the release layer and the polymer layer comprise titanium oxide or other white pigment.

Abstract: A multilayer protective film comprising a first layer, a second layer and a PSA layer. The first layer at least comprises a polyester-based polyurethane, a polycarbonate-based polyurethane or a combination or blend of both. The second layer at least comprises a polycaprolactone-based thermoplastic polyurethane. The PSA layer comprises a pressure sensitive adhesive. One major surface of the first layer is bonded to one major surface of the second layer, and the PSA layer is bonded to an opposite major surface of the second layer such that the second layer is sandwiched between the first layer and the PSA layer.

Abstract: The present invention relates to a rear-illuminable aircraft interior component consisting of a transparent or translucent thermoplastic, a translucent varnish layer disposed on the latter and a decorative varnish layer disposed on the translucent varnish layer, as well as the use of a rear-illuminable aircraft interior component of this kind as a rear-illuminable aircraft window ring.

Abstract: The object of the present invention is to provide a golf ball having a paint film which is obtained from an environment-friendly aqueous paint and is excellent in the durable adhesion. The present invention provides a golf ball comprising a golf ball body, and a paint film covering said golf ball body, wherein the paint film has a resin component which is a reaction product obtainable by reacting an aqueous polyurethane having a carboxyl group with an aqueous polycarbodiimide and the blending ratio of the aqueous polycarbodiimide to the aqueous polyurethane having the carboxyl group is ranging from 0.9 to 1.5 at a molar ratio of a carbodiimide group to a carboxyl group(carbodiimide group/carboxyl group).

Abstract: A light management film includes a first layer with a thermoplastic resin and a particular phosphonium sulfonate salt, and a second layer formed from a curable composition and having a refractive index of at least 1.5. The light management film exhibits reduced static electricity build-up and reduced dust attraction, making it easier to handle during fabrication of display devices such as the flat panel displays of laptop computers.

Abstract: A polarizing plate of the present invention comprising a polarizer and a protective film provided on at least one surface thereof with an adhesive layer, wherein the protective film comprises (A) a thermoplastic resin having a substituted and/or non-substituted imide group in a side chain and (B) a thermoplastic resin having a substituted and/or non-substituted phenyl group, and nitrile group in a side chain, and the adhesive layer comprises a polyurethane adhesive containing a urethane polyol and an isocyanate crosslinking agent. The polarizing plate exhibits good resistance moisture.

Abstract: A coating composition comprising a binder of a. polyisocyanate crosslinking agent; b. an isocyanate-reactive component having at least one compound having the following formula: wherein X is an aliphatic or cycloaliphatic group, R1 and R2 are the same or different organic groups that are inert to isocyanate groups, and n is 2 to 4, and c. optionally, a polymeric component having a number average molecular weight of 5,000 to 50,000 having reactive groups that crosslink with an isocyanate, where the reactive groups are hydroxyl, carboxyl, glycidyl, amine and any mixtures thereof; and d.

Abstract: An article including a panel structure mountable in an automobile vehicle to form a part of the vehicle interior thereof, and a process for making the same are disclosed. According to this process, an outer layer defining at least a portion of the exposed exterior surface of the structure is prepared by applying a first composition containing a thermoplastic polyurethane and a heat-activated crosslinking agent onto a mold surface and thereafter drying the composition. Next, a second composition comprising (i) a poly(vinyl chloride) resin and at least one plasticizer and/or (ii) a thermoplastic polyurethane resin material is gelled onto an inner surface of the outer layer while on the outer layer is retained on the mold surface. The gelled composition is then fused to form an inner layer interfacially chemically bonded to the outer layer. The layered composite structure is united with the reinforcing substrate so that the reinforcing substrate serves to reinforce the outer layer.

Abstract: The invention relates to a liquid curable resin composition capable of forming a ribbon matrix material which can be completely removed from a coloring layer when separating the optical fiber ribbon. A liquid curable resin composition comprising: (1) 30–80 wt. % of a urethane (meth)acrylate produced by reacting (A) a polyol compound, (B) a polyisocyanate compound, and (C) a (meth)acrylate compound containing a hydroxyl group, (2) 0.01–10 wt % of 2-methly-1-[4-(methylthio)phenyl]-2-morpholino-propan-1-one, and (3) 10–70 wt. % of a polymerizable diluent comprising a polymerizable monofunctional vinyl monomer which is copolymerizable with the component (1), wherein a two-layer film, which is obtained by applying the composition to a cured film of a UV-curable resin comprising the compound shown by the above formula (1) and curing the composition, has a T-peel strength of about 1.8 g/cm or less.

Abstract: A composite of a resin member bonded to a vulcanized rubber member is obtained with using a rubber member vulcanized with a radical-generating agent (e.g., an organic peroxide) and a thermoplastic resin having at least 2 atoms, on average, selected from H and S atom per molecule, each atom having not less than 0.006 of an orbital interaction energy coefficient S represented by the following formula (1): S=(CHOMO,n)2/|Ec?EHOMO,n|+(CLUMO,n)2/|Ec?ELUMO,n| ??(1) wherein Ec: an orbital energy (eV) of a radical, CHOMO,n: a molecular-orbital coefficient of a highest occupied molecular orbital (HOMO) of an n-th H or S atom constituting a basic unit of the resin, EHOMO,n: an orbital energy (eV) of the HOMO, CLUMO,n: a molecular-orbital coefficient of a lowest unoccupied molecular orbital (LUMO) of the n-th H or S atom constituting the basic unit of the resin, ELUMO,n: an orbital energy (eV) of the LUMO, and above all represent a value calculated by a semiempirical molecular orbital method MOPACPM3.

Abstract: A method of producing polyurethane pads and other articles has the steps of providing at least one polyurethane layer having a first curing agent, providing a second polymer layer having a second curing agent, providing a connecting layer between the first and second layers with the first curing agent as in the first polyurethane layer, and subjected the layers to a thermal treatment so that the same first curing agent migrates from the connecting layer to the first polyurethane layer and vice versa. Also, an article produced by the method is proposed.

Abstract: A coating composition comprising a film forming binder of a. an acrylic polymer having pendant groups that are reactive with isocyanate moieties and having a glass transition temperature (Tg) of 10 to 80° C.; b. a polytrimethylene ether diol having a Mn (number average molecular weight) of 500 to 5,000; and c. an organic polyisocyanate crosslinking agent; ?wherein the coating composition contains pigments and cures at ambient temperatures or elevated temperatures and forms a coating that is sandable and when used in combination with a top coat, for example, a colored base coat and clear coat or a pigmented mono-coat forms a chip resistant multi-layer coating useful for refinishing or repairing automotive and truck bodies and parts the coating composition can be used as an exterior clear coating composition primarily for automobiles, trucks and parts thereof.

Abstract: A flexible window is formed by a multi-layer sheet having a transparent flexible base layer and one or more transparent flexible protective layers, wherein the protective layers have a greater abrasion resistance than the base layer. The base layer and the protective layers are formed of substantially plasticizer-free polymeric materials.

Abstract: A composition, which is particularly useful as an adhesive, as well as a method of making an adhesive composition, and a method of using an adhesive composition are disclosed.

Abstract: A self-adhesive surface protective film, particularly for automobile paint surfaces, having a backing layer and a self-adhesive layer based on a crosslinked polyurethane, characterized in that the loss angle tan ? of the polyurethane at room temperature in the frequency interval from 10?1 to 102 rad/sec rises or remains at the same level.

Abstract: The disclosure describes vapor permeable retroreflective material for use on protective garments. The material may be formed in a non-continuous pattern that provides a high-level of retroreflective brightness, yet also provides adequate permeability to prevent exposure to trapped thermal energy and heated moisture. The non-continuous retroreflective pattern may include retroreflective regions and non-retroreflective regions arranged such that thermal decay through the protective garment is not substantially decreased in the regions corresponding to the retroreflective material. Rather, vapor permeation and thermal decay through the garment may be substantially the same as if the retroreflective material was not present.

Abstract: A laminate film includes a guard film layer (A), a clear coating layer (B), and a color coating layer (C). A color coating material, from which the color coating layer (C) is made, contains a shining material (C3) containing at least an aluminum flake. If necessary, the color coating layer further contains an orientation control material (C4).

Abstract: An aqueous polyurethane dispersion and thermosetting compositions containing them. The aqueous polyurethane dispersion includes an aqueous medium with dispersed polyurethane-acrylate particles, which include the reaction product obtained by polymerizing a pre-emulsion formed from hydrophobic polymerizable ethylenically unsaturated monomers, a crosslinking monomer, and an active hydrogen-containing polyurethane acrylate prepolymer, which is a reaction product obtained by reacting a polyol, a polymerizable, ethylenically unsaturated monomer containing at least one hydroxyl group, a compound that includes an alkyl group having at least one hydroxyl group and optionally a carboxylic acid group, and a polyisocyanate.

Abstract: In a laminated composite comprising a support made of a thermoplastic polymer, an intermediate layer located thereon which is likewise made of a thermoplastic polymer and a heat-cured layer applied to the intermediate layer, a resin layer (a) having a degree of curing of at least 20% is additionally inserted between the support and the intermediate layer and a resin layer (c) having a degree of curing of at least 60% is inserted between the intermediate layer and the heat-cured layer.

Abstract: An article including a panel structure mountable in an automobile vehicle to form a part of the vehicle interior thereof, and a process for making the same are disclosed. According to this process, an outer layer defining at least a portion of the exposed exterior surface of the structure is prepared by applying a water-dispersed composition containing a thermoplastic polyurethane and a heat-activated crosslinking agent onto a mold surface and thereafter drying the composition. Next, a composition comprising (i) a poly(vinyl chloride) resin and at least one plasticizer and/or (ii) a thermoplastic polyurethane resin material is gelled onto an inner surface of the outer layer while on the outer layer is retained on the mold surface. The gelled composition is then fused to form an inner layer interfacially chemically bonded to the outer layer. The layered composite structure is united with the reinforcing substrate so that the reinforcing substrate serves to reinforce the outer layer.

Abstract: A multi-layer application film formed by laminating at least two resin films, a top layer film (I) being formed from a crosslinkable resin coating composition (A), an under layer film (II) being formed from a thermoplastic resin (B), showing practically no stickiness per se, and having a tensile elongation at breakage in the range of 50 to 1000%, said multi-layer application film being applied onto a plastic substrate.

Abstract: The disclosure describes vapor permeable retroreflective material for use on protective garments. The material may be formed in a non-continuous pattern that provides a high-level of retroreflective brightness, yet also provides adequate permeability to prevent exposure to trapped thermal energy and heated moisture. The non-continuous retroreflective pattern may include retroreflective regions and non-retroreflective regions arranged such that thermal decay through the protective garment is not substantially decreased in the regions corresponding to the retroreflective material. Rather, vapor permeation and thermal decay through the garment may be substantially the same as if the retroreflective material was not present.

Abstract: This invention provides encapsulated type fluorescent retroreflective sheeting which is excellent in appearance and weatherability, and which comprises a surface-protective layer disposed on the side on which light is to strike, a binder layer connected to the surface-protective layer through network bonding parts, an air layer which is sealed-up by the network bonding parts between the surface-protective layer and the binder layer, and a retroreflective element layer disposed between the surface-protective layer and the air layer, or between the binder layer and the air layer, wherein at least one layer located on the light-incident side of sealed-up air layer contains at least one fluorescent dye selected from the group consisting of benzimidazole coumarin type-fluorescent dyes of formula (1) as follows: and benzopyran type-fluorescent dyes of formula (2) as follows:

Abstract: A process for preparing a multicomponent system curable thermally and with actinic radiation (dual cure), where (A) at least one component comprising at least one constituent (A1) containing per molecule at least two isocyanate-reactive functional groups, and (B) one component containing one polyisocyanate (B1), are mixed with one another, which comprises mixing component (A) and/or component (B), shortly before their mixing, with one further liquid component (C) comprising (C1) one constituent which is curable with actinic radiation and contains per molecule at least two functional groups which contain bond which can be activated with actinic radiation, and/or (C2) one constituent which is curable thermally and with actinic radiation and contains per molecule at least one functional group which contains at least one bond which can be activated with actinic radiation, and containing per molecule at least one isocyanate-reactive functional group or containing at least one isocyanate group, and subsequently mi

Abstract: A process for painting integrated automobile and commercial vehicle bodies or cabins which comprise plastic parts. The metal parts of the body/cabin are provided with an electrocoat and are integrated with the plastic parts. These plastic parts either already have an electrically conductive aqueous primer coat or an uncured electrically conductive aqueous primer film or are unpainted. Primers are applied to the metal and plastic parts. Atop the primers, a basecoat and a clearcoat are applied.

Abstract: A headliner assembly, for use with a vehicle having a roof, includes a headliner body that is positionable proximate the roof, and a support frame attached to the headliner body. The support frame cooperates with the headliner body to provide a sufficient structural characteristic such that the headliner assembly is self-supporting.

Abstract: A coating composition comprising a film forming binder of a. an acrylic polymer having pendant groups that are reactive with isocyanate moieties and having a glass transition temperature (Tg) of 10 to 80°C.; b. a polytrimethylene ether diol having a Mn (number average molecular weight) of 500 to 5,000; and c. an organic polyisocyanate crosslinking agent; wherein the coating composition contains pigments and cures at ambient temperatures or elevated temperatures and forms a coating that is sandable and when used in combination with a top coat, for example, a colored base coat and clear coat or a pigmented mono-coat forms a chip resistant multi-layer coating useful for refinishing or repairing automotive and truck bodies and parts.

Abstract: A method for preparing multi-layer protective coatings having enhanced durability with easy removability under conventional stripping conditions is disclosed. The invention is based on applying to a substrate, a first-coating composition that is removable, followed by application of a second-coating composition that is highly durable but not readily removable. Preferred second-coating compositions are based on polymers that provide highly crosslinked ‘non-removable’ (under conventional stripping conditions) coatings if used alone. The resultant multi-layer coating compositions provide enhanced detergent resistance while retaining easy overall removability properties.

Abstract: A composite structure is disclosed. The structure includes one or several polyurethane layers, a support layer, in particular a textile support layer, as well as an optional adhesive layer placed between these layers. The composite structure is characterized in that at least one of the polyurethane layers contains a polyurethane having the formula (I) wherein O—R1—O— is the radical of a polyole with primary and/or secondary hydroxyl functional end groups, R1 and R2 independently represent an organic radical which includes aliphatic, cyclo-aliphatic, aromatic and/or heterocyclic groups, and n is an integer number between 1 and 50,000. Also disclosed is a method of manufacturing the composite structure and its use as imitation leather.

Abstract: Described is a membrane comprising a microlayer polymeric composite having at least about 10 microlayers. The microlayers are each individually up to about 100 microns thick and alternate between at least one gas barrier material and at least one elastomeric material. The membrane can be formed into a pressurized bladder or cushioning device for many applications, including footwear and hydropneumatic accumulators.

Abstract: A method of making a polyurea—polyurethane composite structure that is substantially free from emission of volatile organic compounds is disclosed. The composite structure produced according to the method of the subject invention has a flexural modulus of at least 200,000 lb/in2. The composite structure includes first and second layers. A mold substrate is provided and a first-layer polyisocyanate component and a first-layer resin component are reacted and sprayed onto the mold substrate to form the first-layer. The first-layer polyisocyanate component includes an aliphatic polyisocyanate, and the first-layer resin component includes a polyamine thereby forming a polyurea show surface having a Shore D hardness of at least 65. After application of the first-layer, a second-layer polyisocyanate component and a second-layer resin component are reacted and sprayed behind the first-layer to form the second-layer of the composite structure.

Abstract: A molding method and a metal-covered plastic component such as partial or entire fascia, body side moldings, and the like, which have bright surface requirements and which includes a film sheet and a one-piece thermoplastic elastomeric structural carrier are provided. The film sheet includes a decorative layer of metal such as chrome. A plastic layer of the film sheet on which the layer of metal is formed is selected from a group consisting of polyester, polyurethane and polycarbonate. A bottom contact surface of the film sheet bonds with a front contact surface of the structural carrier by diffusion between the contact surfaces thereof within a mold cavity of an injection mold separate from the step of forming a preform which is securely positioned within the injection mold during injection molding to form the plastic part.

Abstract: The present invention relates to membranes including an urethane including a polyester polyol, wherein the membrane has a gas transmission rate of 15.0 or less for nitrogen gas wherein the membrane has an average thickness of approximately 20.0 mils. Under certain embodiments, the membranes include blends of one or more polyester polyol based thermoplastic urethanes and one or more barrier materials. The membranes can be employed in a variety of applications and can be used as either monolayers or multi-layered laminates.

Abstract: A technique and device for rehabilitating or repairing waste water system components or the like, comprising a spray-applied, multi-layer liner which seals the components and imparts structural integrity. The liner comprises a primer layer, a first moisture barrier layer, a foam layer and a second moisture barrier layer. The first and second moisture barrier layers are preferably made of the same material and form a skin on both sides of the internal foam layer. The combination of the foam layer and the two moisture barrier layers imparts structural strength and rigidity to the cured liner.

Abstract: Disclosed is a floor-covering material, in which a phenol composite resin comprising phenol resin of resorcinol-formaline and polyurethane resin is incorporated with paper and dried, to form a prepreg, which is then thermally compressed to the upper side of a PVC base or a waterproof plywood layer, yielding a transparent protective layer and a shaping layer. In the flooring material, the transparent layer and the shaping layer are made of phenol composite resin, and thus low in heat- and moisture-distortion, with no curling. Further, since a surface layer of the floor-covering material is hardly distorted by heat, a balance layer for the suppression of such distortion is not additionally required.

Abstract: Described is an article of a non-elastomeric poly(urea-urethane) substrate having free isocyanato surface groups and at least a partial coating of a photochromic polymeric coating on at least one surface of the substrate.

Abstract: In order to create a full grain napa cowhide which exhibits the characteristics with respect to grain pipeyness and water vapor permeability that are required by the automotive and upholstery industries, a finish is applied to the grain side of the full grain leather. The finish includes a pigmented layer with a thickness of between 0.015 mm and 0.04 mm and is formed of a stabilized polyurethane and/or polyacrylate dispersion. The dispersion contains microspheres with a diameter of less than 45 &mgr;m, which form primarily closed cells, and at least 10% open cells by volume. The top side of the layer is provided with a napa embossing. A second layer, placed on the first layer, is formed from a cross-linked polyurethane-based varnish application containing a dulling agent. The leather undergoes a milling treatment.

Abstract: A hydrophilic coating having a covalently cross-linked hydrophilic polymer suitable for coating medical devices or instruments for introduction into human cavities, the coating further having a water soluble compound, the water soluble compound being glucose, sorbitol a halide, nitrate, acetate, citrate or benzoate of an alkali metal or alkaline earth metal or silver; acetic acid, glycine or urea. A medical device or instrument for introduction into human cavities having a hydrophilic coating and a method of producing such a medical device or instrument.

Abstract: Flame retardant, clear pressure-sensitive adhesive tape comprises clear polyether-based polyurethane backing film and clear, polyether-based polyurethane pressure sensitive adhesive coated on one side of the backing film. Flame retardant is incorporated into the polyurethane backing film and the polyurethane adhesive to render the tape substantially flame retardant without causing a loss of the substantial transparency of the tape. The tape meets the following flame retardancy requirements: maximum average burn extinguishing time of 15 seconds, maximum average burn length of 8 inches and maximum average drip extinguishing time of 5 seconds, measured in accordance with defined test methods.

Abstract: This invention relates to low-tack thin-walled articles comprising a polyurethane elastomer, for example surgical gloves, clean-room gloves, condoms, and the like. More particularly, the invention relates to such elastomeric articles containing specific amounts of molecular sieve.

Abstract: Provided is a treated substrate comprising a backing material coated with a resin derived from a curable precursor resin, which comprises an energy-curable component comprising a cyanate ester resin and a curing agent. Also provided is an abrasive article comprising a plurality of abrasive particles incorporated into a bond system, wherein the bond system comprises a make resin derived from a first curable precursor resin, which comprises a first curable component comprising a cyanate ester resin and a first curing agent, and wherein the bond system additionally comprises a size resin derived from a second curable precursor resin, which comprises a second curable component comprising a cyanate ester resin and a second curing agent. Also provided are methods of making a treated substrate and an abrasive article.

Abstract: The invention provides composite components constructed of a layer i) comprising short fiber reinforced PU and having a paintable surface, and a layer ii) comprising long fiber reinforced polyurethane, and also provides a process for producing them, and provides for their use as exterior bodywork parts.