Next To An Aldehyde Or Ketone Condensation Product Patents (Class 428/501)
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Patent number: 5413863Abstract: Holographic films are disclosed that contain a binder having the following formula:(M).sub.w (VAc).sub.x (VOH).sub.y (VOS).sub.zwherein M is a fluoromonomer; VAc is vinyl acetate; VOH is vinyl alcohol; and VOS is vinyl trimethylsilyl ether; and wherein w, x, y, and z are percentages by weight; w is 5 to 30, x is 40 to 80, y is 0 to 20, and z is 2 to 30; said copolymers containing 3 to 23% by weight fluorine. These imaged films are particularly suited for lamination to glass in head-up display applications.Type: GrantFiled: November 4, 1993Date of Patent: May 9, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Andrew M. Weber, Aleksander Beresniewicz
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Patent number: 5378542Abstract: Process for the simultaneous application of at least two molten, thermoreversible organogel layers to a substrate. The organogel layers can optionally contain dispersed additive ingredients, such as pigments. The organogel layers are coated onto a suitable substrate and then rapidly cooled or chilled to form a gel. Residual solvent is then removed. Multilayer coated films are thus formed with minimal interlayer mixing or interlayer diffusion of the additive ingredients.Type: GrantFiled: June 6, 1994Date of Patent: January 3, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kenneth L. Hanzalik, George H. Crawford, Jr., Sharon M. Rozzi, David J. Scanlan
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Patent number: 5318856Abstract: Dyes having the specific structural formula (1) set out below, their copper salt dyes, water-soluble azo dyes containing the dyes or the copper salt dyes, and polarizing films containing the water-soluble azo dyes: ##STR1## wherein A means a benzene or naphthalene ring having a sulfone group or a base thereof, Y and Z individually denote a group of the following formula (a): ##STR2## wherein R.sup.2 is a hydrogen atom, a methyl group, a methoxyl group or an ethoxyl group and R.sup.3 is a methyl, methoxyl or ethoxyl group, R.sup.1 represents an amino, C.sub.1-4 alkylamino, C.sub.2-4 alkylcarboxyamino, benzoylamino or phenylamino group bonded to the 6 or 7 position of the naphthalene ring, and X denotes a hydrogen, sodium, potassium or lithium atom, with the proviso that Y and Z are different but, when both R.sup.2 s are hydrogen atoms and both R.sup.3 s are methoxyl groups, Y and Z may be the same.Type: GrantFiled: December 24, 1992Date of Patent: June 7, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Tsutami Misawa, Akira Ogiso, Rihoko Imai, Hisato Itoh
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Patent number: 5302439Abstract: Disclosed is a recording sheet which comprises (a) a substrate; (b) a coating on the substrate which comprises a binder and a material having a melting point of less than about 65.degree. C. and a boiling point of greater than 150.degree. C. and selected from the group consisting of alkyl phenones, alkyl ketones, halogenated alkanes, alkyl amines, alkyl anilines, alkyl diamines, alkyl alcohols, alkyl diols, halogenated alkyl alcohols, alkane alkyl esters, saturated fatty acids, unsaturated fatty acids, alkyl aldehydes, alkyl anhydrides, alkanes, and mixtures thereof; (c) an optional traction agent; and (d) an optional antistatic agent.Type: GrantFiled: March 19, 1993Date of Patent: April 12, 1994Assignee: Xerox CorporationInventors: Shadi L. Malhotra, Brent S. Bryant
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Patent number: 5300338Abstract: A coextruded laminate may be formed by coextruding a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon (a polyketone polymer) with an other thermoplastic polymer, without the use of an adhesive or tie layer, wherein the other thermoplastic polymer is polyvinylidene fluoride, nylon-6,6, or phenoxy resin.Type: GrantFiled: May 8, 1992Date of Patent: April 5, 1994Assignee: Shell Oil CompanyInventors: Paul S. Byrd, Jr., Dixie G. Waters
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Patent number: 5262219Abstract: A composite film is disclosed which includes (a) a synthetic resin substrate film having a roughened surface, and (b) a thin, slippery, electrically conducting layer coated over the roughened surface. The conducting layer contains 2-10% by weight of carbon black, 10-40% by weight of a fluorine resin, 25-78% by weight of a hardened binder resin selected from hardened amino resins, hardened phenol resins and mixtures thereof, and 7-25% by weight of a modifying resin selected from polyurethane resins, acrylic resins, polyester resins and mixtures thereof, the total amount of the hardened binder resin and the modifying resin being 50-85% by weight.Type: GrantFiled: November 15, 1990Date of Patent: November 16, 1993Assignee: Somar CorporationInventors: Shinichi Yamamoto, Masatoshi Tomiki, Haruo Hatakeyama
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Patent number: 5248550Abstract: Gel coating of thermoplastic particles, such as polyimide particles, with a polyketone or polyvinyl alcohol gel, and applying the gel coated particles to reinforcement, e.g. carbon, fibers to form a pre-preg. Such gel coated thermoplastic particles can be mixed with a thermosetting resin to form a pre-preg, which can be cured at elevated temperatures to form a composite having damage tolerance characteristics. The gel coating is applied to the thermoplastic particles by contacting such particles with a polymerizable material such as acetone in a weakly acidic solution to cause the acetone to undergo tautomerism, and in the presence of a polymerization promoter or catalyst, preferably certain anionic surfactants such as sulfated ammonium salts, to convert the tautomer to polyacetone gel of low molecular weight, which coats or encapsulates the thermoplastic particles.Type: GrantFiled: March 12, 1991Date of Patent: September 28, 1993Assignee: Lockheed CorporationInventors: Russell L. Turpin, Anthony L. Green
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Patent number: 5234761Abstract: Barriers against atomic oxygen attack, e.g. on substrates such as parts of space vehicles in low earth orbit, consist of layer minerals, especially vermiculite and selected smectites.Type: GrantFiled: July 31, 1990Date of Patent: August 10, 1993Assignee: Imperial Chemical Industries, PLCInventors: John A. Barnes, William J. Brennan, William N. E. Meredith, Florence H. G. Cowan
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Patent number: 5227241Abstract: The present invention relates to a laminated glass, more specifically to an airplane windshield. The present laminated glass offers excellent resistance to breakage, and particularly, to cleavage of the sheets of glass from plastic layer(s) laminated therewith.Type: GrantFiled: April 9, 1992Date of Patent: July 13, 1993Assignee: Saint-Gobain Vitrage InternationalInventors: Pierre Chaussade, Yves Naoumenko
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Patent number: 5190825Abstract: The invention relates to an adhesive plastic layer used in laminated glazings, in particular as an intermediate layer. The plastic layer contains, radiochemically grafted onto at least one of its surfaces, monomer and/or oligomers of an unsaturated monomer, such as acrylic acid or salts of said monomer.Type: GrantFiled: October 25, 1991Date of Patent: March 2, 1993Assignee: Saint-Gobain VitrageInventors: Herve Arribart, Pascal Chartier
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Patent number: 5102695Abstract: Clear, abrasion resistant, tintable coating compositions which are based on siloxane/silica hybrid coating resins and which also contain at least about 3 weight percent and up to about 30 weight percent of a tintability enhancing compound comprising at least one alkylated amine formadehyde compound. These coating compositions are especially useful for providing both abrasion resistance and high levels of tinting.Type: GrantFiled: November 14, 1990Date of Patent: April 7, 1992Assignee: Swedlow, Inc.Inventors: Allen M. Guest, Martin W. Preus, William Lewis
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Patent number: 5079069Abstract: A capacitor laminate is described either as an intermediate product for use in a capacitive printed circuit board or as part of the assembled printed circuit board in order to provide a bypass capacitive function for large numbers of devices mounted or formed on the printed circuit board, the capacitor laminate being formed from sheets of conductive material and an intermediate sheet of dielectric material forming the laminated capacitor as a structurally rigid assembly and facilitating its inclusion within the PCB, components of the capacitor laminate having selected characteristics whereby each individual device is provided with capacitance by a proportional portion of the capacitor laminate and by borrowed capacitance from other portions of the capacitor laminate, the capacitive function of the capacitor laminate being dependent upon random firing or operation of the devices. Methods of manufacture for the capacitor laminate as well as the capacitive PCB are also described.Type: GrantFiled: August 23, 1989Date of Patent: January 7, 1992Assignee: Zycon CorporationInventors: James R. Howard, Gregory L. Lucas
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Patent number: 5066525Abstract: The invention relates to a laminated glass panel incorporating therein a hologram sheet. For example, the laminated glass panel is a vehicle windshield in which the hologram sheet is used as a combiner of a head-up display. As adhesive means, the laminated glass panel uses either one sheet or two sheets of polyvinyl butyral resin (PVB) film. In the former case the hologram sheet is interposed between the PVB film and one of the glass plate and shielded from the PVB film by a transparent resin or glass film which prevents the plasticizer contained in the PVB film from transferring to the hologram sheet. In the latter case the hologram sheet is interposed between the two sheets of PBB film and shielded from each PVB film by a transparent resin or glass film having the aforementioned property. By virtue of the shielding of the hologram sheet from the PVB film, the diffraction wavelength of the hologram sheet does not significantly shift from the aimed wavelength.Type: GrantFiled: January 18, 1990Date of Patent: November 19, 1991Assignee: Central Glass Company, LimitedInventors: Fumihiko Nakamachi, Masanori Umebayashi
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Patent number: 5064724Abstract: A laminate, a method for making the laminate and articles formed from the laminate are disclosed. The laminate comprises an outer layer, an optional adhesive layer, an inner layer, an intermediate regrind layer formed of a blend of the materials from which the other layers are formed, and, interposed between the outer layer and the intermediate regrind layer, there is a buffer layer which is formed from a blend of the materials from which the outer layer and the intermediate regrind layer are formed and which comprises at least about 5% of the material of the intermediate regrind layer. The outer layer is preferably polypropylene and the inner layer is preferably a polyketone.Type: GrantFiled: October 9, 1990Date of Patent: November 12, 1991Assignee: Shell Oil CompanyInventor: David E. Ofstein
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Patent number: 5055444Abstract: An intermediate dye image-receiving element for thermal dye transfer comprising a support having thereon a separable polyolefin layer, a dye image-receiving layer, and a subbing layer between the polyolefin layer and the dye image-receiving layer, wherein the subbing layer comprises a crosslinked poly(vinyl acetal-co-vinyl alcohol).Type: GrantFiled: May 4, 1990Date of Patent: October 8, 1991Assignee: Eastman Kodak CompanyInventor: Linda A. Kaszczuk
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Patent number: 5032462Abstract: Coating compositions comprise a thixotropic resin dispersion in which the resin particles are a vinyl polymer, a cross-linked unsaturated carboxylic acid polymer which is neutralized with a salt of a low valence metal, and an adhesion promoter.Type: GrantFiled: July 18, 1989Date of Patent: July 16, 1991Assignee: The B. F. Goodrich CompanyInventor: Jongshun S. Kim
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Patent number: 5024871Abstract: A composite material is presented comprised of a ceramic filled fluoropolymer wherein the ceramic is coated with a zirconate coupling agent and/or a titanate coupling agent.Type: GrantFiled: February 21, 1990Date of Patent: June 18, 1991Assignee: Rogers CorporationInventors: David J. Arthur, Gwo S. Swei
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Patent number: 5021291Abstract: A multiple-time ink-bearing medium containing a thermally-transferable ink for thermal printing, produced in a process comprising: preparing a resin solution of a water-soluble resin comprising polyvinyl alcohol as a major constituent; preparing a fusible ink material consisting of a mixture which includes a solid fatty acid as a major constituent, a coloring agent, and a fusible agent having a low melting point; finely dispersing the ink material in the resin solution, so as to provide an ink-layer composition; applying the ink-layer composition to one surface of a substrate; and drying the applied ink-layer composition to form an ink layer on the substrate.Type: GrantFiled: June 12, 1989Date of Patent: June 4, 1991Assignee: Brother Kogyo Kabushiki KaishaInventors: Tetuo Kobayashi, Mikio Imaeda
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Patent number: 5015529Abstract: Phenolic molding compositions, particularly useful as sheet molding compositions comprise: (1) a resole phenolic resin, (2) a thickening agent selected from the group consisting of alkaline earth metal oxides or hydroxides and silanes, (3) a filler selected from the group consisting of clay, talc, and mixtures thereof, and (4) an epoxy resin.Type: GrantFiled: September 14, 1988Date of Patent: May 14, 1991Assignee: Occidental Chemical CorporationInventor: Manoj K. Gupta
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Patent number: 5013608Abstract: Abrasion resistant, tintable coating compositions which are based on siloxane/silica hybrid coating resins and which also contain at least about 3 percent but less than about 20 percent of a tintability enhancing compound selected from the group consisting of polyhydroxyl-functional compounds and butylated urea formaldehyde compounds. These coating compositions are especially useful for providing both abrasion resistance and high levels of tinting and, optionally, absorbance of ultraviolet radiation. Tetrahydroxybenzophenone is a preferred tintability enhancing compound that also absorbs UV light.Type: GrantFiled: July 7, 1989Date of Patent: May 7, 1991Assignee: Swedlow, Inc.Inventors: Allen M. Guest, Martin W. Preus, William Lewis
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Patent number: 4960631Abstract: A laminated transparency includes a flexible epoxy moisture seal about the periphery of the transparency. The edge of the transparency may be cleaned and primed with a silane surface treatment.Type: GrantFiled: December 30, 1988Date of Patent: October 2, 1990Assignee: PPG Industries, Inc.Inventors: Patricia B. Walters, David C. Allen
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Patent number: 4954390Abstract: A thermal transfer recording medium is disclosed which is improved not only in the print quality on a transferee medium of poor smoothness, but also in character quality in a high speed printing operation. The recording medium comprises a support and at least two heat softening layers provided on the support in the order of a first heat softening layer and a second heat softening layer. At least one of said first and second heat softening layers contain a colorant, and said second heat softening layer contains a heat fusible substance in an amount of from 15% to 50% by weight; a thermo-plastic resin in an amount of from 20% to 80% by weight; and a tackifier in an amount of from 5% to 35% by weight.Type: GrantFiled: October 3, 1988Date of Patent: September 4, 1990Assignee: Konica CorporationInventors: Kunihiro Koshizuka, Takao Abe
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Patent number: 4935297Abstract: Rubber-reinforcing fibrous materials are disclosed, which each comprise fibers and a coat formed on the fibers. The coat is formed by applying a rubbery adhesive composition on the fibers and then thermally treating the rubbery adhesive composition-applied fibers. The rubbery adhesive composition is mainly composed of rubber latex and mixed with a bismaleimide compound at a mixing ratio of 0.25 to 5 relative to 100 of the rubber latex in terms of weight.Type: GrantFiled: April 22, 1988Date of Patent: June 19, 1990Assignee: Bridgestone CorporationInventor: Toshihiro Yotsumoto
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Patent number: 4904525Abstract: An anti-reflection optical article which has an excellent anti-reflection properties, scratch resistance, impact resistance, flexibility, anti-static properties and weatherability, and which is easy to dye, is disclosed. The anti-reflection optical article of the present invention includes a transparent plastic substrate; a hard coat film formed on a surface of the substrate, the film having an index of refraction of not less than 1.52; and a fluorine-containing organopolysiloxane-based film with a thickness of 10 nm to 500 nm, which has an index of refraction lower than that of the hard coat film by not less than 0.02, and which is formed on the hard coat film.Type: GrantFiled: October 29, 1987Date of Patent: February 27, 1990Assignee: Toray Industries, Inc.Inventors: Takashi Taniguchi, Tetsuya Seki
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Patent number: 4889770Abstract: A composition for the surface treatment of rubber is disclosed which comprises (A) a diorganopolysiloxane capped with a triorganosiloxy group at one end and a hydroxyl or alkoxy group at the other end; (B) at least one compound selected from organotrialkoxysilanes, organotriacyloxysilanes, organotrioximesilanes or tetraalkyl silicates; and (C) a condensation-reaction catalyst. The composition imparts durable release and lubrication properties to rubber bladders used in the manufacture of tires.Type: GrantFiled: September 29, 1988Date of Patent: December 26, 1989Assignee: Toray Silicone Company LimitedInventors: Isao Ona, Tsutomu Naganawa, Toshio Suzuki, Tadashi Okawa
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Patent number: 4861675Abstract: A coated object is produced by flame spraying the object with a substantially molten polymeric material which comprises a linear alternating polymer of ethylene and at least one ethylenically unsaturated hydrocarbon optionally blended with a copolymer of ethylene and .alpha.,.beta.-ethylenically unsaturated carboxylic acid.Type: GrantFiled: April 25, 1988Date of Patent: August 29, 1989Assignee: Shell Oil CompanyInventor: Eric R. George
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Patent number: 4756952Abstract: The inventive water-swellable caulking material for water-leakage prevention is of the type formed of a composition comprising a rubbery polymer and a highly water-absorptive resin and useful in the caulking works of a construction joint of concrete. Different from the conventional caulking materials of the type, the inventive caulking material is provided on the surface of a shaped body of the water-swellable composition with a coating film which is impervious to neutral water but exhibits water-permeability when contacted with an alkaline water of an alkalinity such as in an uncured concrete mixture so that the caulking material is prevented from premature or untimely expansion by swelling even when inadvertently contacted with water prior to application to the working site but capable of promptly expanding when contacted with an uncured concrete mixture with alkalinity.Type: GrantFiled: April 8, 1985Date of Patent: July 12, 1988Assignee: C.I. Kasei Co., Ltd.Inventors: Hiroharu Sasayama, Yuji Ishihara
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Patent number: 4740404Abstract: The waterstop used to prevent passage or leakage of water through a construction joint of concrete is shaped of a plastic or rubber in the form of a continuous-length belt-like form and provided with a water-swellable rubbery layer on at least a portion, or, for example, along the peripheries of the belt-like form, side-by-side coming into contact with the concrete bodies to serve as a water-tight filling of the joint by being swollen with water. The water-swellable rubbery layer is protected temporarily prior to use with a coating film of an alkali-soluble polymeric material which can at least partially be dissolved away by the alkalinity of the water in the concrete joint. The peripheries of the plastic- or rubber-made belt-like form are preferably in a length-wise bulged form having a bore running therethrough to serve as a stress absorber when the water-swellable rubbery layer is swollen with water.Type: GrantFiled: October 6, 1986Date of Patent: April 26, 1988Assignee: C. I. Kasei, Co. Ltd.Inventors: Shozo Otsugu, Michiyoshi Terauchi, Hiroharu Sasayama, Yuji Ishihara, Takashi Kushida
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Patent number: 4606972Abstract: An improved polyamide yarn for tire and industrial applications is prepared by applying to the yarn a finish composition comprising a diarylamine-ketone condensation product such as the low temperature reaction product of diphenylamine and acetone, and a compound selected from the group consisting of 1,3,5 tris(4t-butyl-3-hydroxy-2,6 dimethylbenzyl)-1,3,5 triazine-2,4,6(1H, 3H, 5H) trione and 1,3,5 tris(2 hydroxy ethyl)-s-triazine-2,4,6(1H, 3H, 5H) trione in effective amounts to provide improved adhesion of the fiber to rubber after aging the yarn.Type: GrantFiled: September 9, 1985Date of Patent: August 19, 1986Assignee: Allied CorporationInventor: Robert M. Marshall
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Patent number: 4590111Abstract: A fragrance releasing sheet article comprising a resin member with patterns and/or colors thereon and a fragrance releasing member comprising a resin and perfume, the pattern member and the fragrance releasing member being integrally constituted; and a method of making such sheet article.Type: GrantFiled: October 17, 1983Date of Patent: May 20, 1986Assignee: Hakugen, Ltd.Inventor: Keinosuke Takeuchi
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Patent number: 4502263Abstract: A sealable, transparent, polyolefinic multilayer film comprises a base layer formed of a polypropylene polymer and at least one sealable layer, which contains a propylene copolymer, a low-molecular weight resin, a polypropylene homopolymer and a polydiorganosiloxane. The sealing layer is comprised of a combination of(a) from about 68.5 to 89.7% by weight, based on the weight of the sealable layer, of an olefin resin composition, comprising an ethylene-propylene-butylene terpolymer and a propylene-butylene copolymer, corresponding to a content of from about 0.1 to 7% by weight of ethylene, 53 to 89.9% by weight of propylene and 10 to 40% by weight of butylene, based on the weight of the olefin resin composition,(b) from about 5 to 15% by weight, based on the weight of the sealable layer, of a low-molecular weight resin, which compatible with the olefin resin composition,(c) from about 5 to 15% by weight, based on the weight of the sealable layer, of a propylene homopolymer, and(d) from about 0.3 to 1.Type: GrantFiled: December 16, 1983Date of Patent: March 5, 1985Assignee: Hoechst AktiengesellschaftInventors: G/u/ nther Crass, Siegfried Janocha, Wolfgang Dietz, Lothar Bothe
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Patent number: 4477536Abstract: Multilayer coatings having at least one base coating containing pigments and at least one transparent top coating are applied from coating compositions on the substrates and cured together. The coating composition contains:(a) a film-forming synthetic resin;(b) an organic solvent in which the synthetic resin is soluble; and(c) polymer microparticles having polar and/or ionic groups on their surfaces and a diameter of about 0.01 to 5 microns obtained by emulsion polymerization of ethylene unsaturated monomers, these monomers having a portion comprising 2 or more double bonds per molecule and the microparticles are insoluble in the solution of (a) and (b).The base coat(s) have (d) pigments and the top coats are free of pigments.Type: GrantFiled: May 11, 1983Date of Patent: October 16, 1984Assignee: Glasurit America, Inc.Inventors: Howard J. Wright, David P. Leonard, Roger A. Etzell
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Composite polymeric film and method for its use in installing a very thin polymeric film in a device
Patent number: 4448622Abstract: A composite polymeric film and a method for its use in forming and installing a very thin (<10 .mu.m) polymeric film are disclosed. The composite film consists of a thin film layer and a backing layer. The backing layer is soluble in a solvent in which the thin film layer is not soluble. In accordance with the method, the composite film is installed in a device in the same position in which it is sought to finally emplace the thin film. The backing layer is then selectively dissolved in the solvent to leave the insoluble thin film layer as an unbacked film. The method permits a very thin film to be successfully installed in devices where the fragility of the film would preclude handling and installation by conventional methods.Type: GrantFiled: April 26, 1982Date of Patent: May 15, 1984Assignee: The United States of America as represented by the United States Department of EnergyInventors: David V. Duchane, Barry L. Barthell -
Patent number: 4442177Abstract: A coating composition comprises(A) an alkyl ether methylolmelamine in which a part or whole of methylol groups of methylolmelamine are converted into alkyl ether methylol groups;(B) a polyhydric alcohol having 2 or more hydroxyl groups; and(C) a dispersion of colloidal silica which can be condensed each other for the two or three components; and(D) a solvent.Type: GrantFiled: April 1, 1981Date of Patent: April 10, 1984Assignee: Asahi Glass Company, Ltd.Inventors: Akinori Noda, Seiichi Miyasaka, Hiroshi Kawahara
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Patent number: 4414275Abstract: A flexible adhesive tape comprising a thermoplastic support film etched on one side with a suitable etchant or etching method, said etched side being coated with a polyvinylformal pre-coat, and further coated with a photo-sensitive adhesive composition comprising,(i) at least one polymerizable acrylate ester monomer;(ii) a photo-initiator;(iii) optionally a film former;and the other side of said thermoplastic support film being coated with a release agent.These tape are useful as protective coatings, and adhere to a variety of surfaces, particularly high surface energy materials.Type: GrantFiled: July 13, 1981Date of Patent: November 8, 1983Assignee: Loctite (Ireland) LimitedInventor: John Woods
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Patent number: 4388374Abstract: Water reducible compositions useful as coating compositions for flexible substrates are prepard by reacting a glycidyl polyether of a dihydric phenol with a polyethylene glycol and ortho phosphoric acid.Type: GrantFiled: August 30, 1982Date of Patent: June 14, 1983Assignee: Celanese CorporationInventor: David A. Shimp
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Patent number: 4361625Abstract: A plasticizer-containing film of a partially acetalized polyvinyl alcohol resin contains as the plasticizer a mixture of an ester of an organic cyclic acid and/or a conventional acetal plasticizer for said resin, and an ester of an oxygen acid of phosphorus.Type: GrantFiled: May 10, 1979Date of Patent: November 30, 1982Assignee: Dynamit Nobel AktiengesellschaftInventors: Rolf Beckmann, Wilhelm Knackstedt
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Patent number: 4294738Abstract: Oligomer solution, process of increasing the water-miscibility of the oligomer solution, one- and two-part coating solutions containing the oligomer solution, and substrates coated with the coating solution, said oligomer solution being miscible with at least 12 wt % of water, based on non-volatile ingredients, and consisting essentially of:(a) about 50 to about 94 wt % of an oligomer having a degree of polymerization (DP) of about 10 to about 50, for example, an oligomer of vinyl acetate, hydroxyethyl acrylate, and a C.sub.1-8 alkyl acrylate;(b) 0 to about 30 wt % of a polyalkylene ether glycol having a molecular weight of about 400 to about 1300; and(c) 0 to about 20 wt % of a water-miscible solvent,with the sum of the weight percentages being 100%.Type: GrantFiled: October 28, 1980Date of Patent: October 13, 1981Assignee: E. I. Du Pont de Nemours and CompanyInventor: Aleksander Beresniewicz
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Patent number: 4293615Abstract: Laminates of glazing material and polyvinyl butyral plasticized with propylene oxide oligomers.Type: GrantFiled: May 30, 1980Date of Patent: October 6, 1981Assignee: E. I. Du Pont de Nemours and CompanyInventors: Griffith Bowen, Peter A. Fowell
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Patent number: 4289675Abstract: An air drying latex coating composition, curable under ambient conditions, is described having copolymer particles consisting essentially of copolymerized monoethylenically unsaturated monomers dispersed in an aqueous emulsion. The copolymer particles have 0.5-30% by weight of ethylenically unsaturated monomers bonded thereto through reacted C.sub.1 -C.sub.6 N-alkylol functionalities. Curing agents or curing catalysts are also present to cure the deposited composition. The coating compositions are provided by forming an aqueous dispersion of the copolymer particles, bonding an ethylenically unsaturated monomer thereto through a C.sub.1 -C.sub.6 N-alkylol functionality, and admixing therein a curing catalyst or curing agent.Type: GrantFiled: December 3, 1979Date of Patent: September 15, 1981Assignee: DeSoto, Inc.Inventor: John J. Krajewski
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Patent number: 4288477Abstract: Films consisting essentially of alpha-olefin polymers, such as normally solid polypropylene consisting essentially of recurring propylene units and having a substantial crystalline polypropylene content, and in particular isotactic polypropylene, are coated with a ketonic resin resulting from the polycondensation of aldehydes with ketones, which coating renders the films readily thermoweldable and/or impervious to gases, vapors and the like. The coated films are useful for the manufacture of containers, covers, small bags, vessels and in general for the manufacture of articles useful in the packaging industry.Type: GrantFiled: October 23, 1978Date of Patent: September 8, 1981Assignee: Moplefan S.p.A.Inventors: Fosco Bordini, Luigi Mauri
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Patent number: 4284677Abstract: An electrically heated laminated aircraft glazing including at least two sheets of glass and an interposed non-brittle thermoplastic interlayer. A bus bar and an electrically conducting film are located on the inwardly disposed surface of one of the sheets and the bus bar covered with a thin layer of polyisobutylene resin. Additional layers of polyisobutylene resin are provided between the interlayer material and selected glass areas to prevent delamination and cold chipping of the glazing with subsequent moisture ingress and bus bar failure.Type: GrantFiled: April 24, 1979Date of Patent: August 18, 1981Assignee: Libbey-Owens-Ford CompanyInventor: Siegfried H. Herliczek
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Patent number: 4277533Abstract: A waterproofing sheet material useful for example as a free floating membrane or flashing material in roofing applications, a pond liner, or a gasketing material, composed of from about 15 wt. % to about 80 wt. % of an ingredient selected from the group consisting of:(a) homopolymers of alkadienes and substituted alkadienes(b) addition copolymers of alkadienes with unsaturated monomers(c) homopolymers of alkenes and substituted alkenes selected from the group consisting of polyethylene, chlorosulfonated polyethylene and polyisobutylene(d) resin acids and resin acid derivatives(e) highly aromatic bituminous materials, and(f) pine oiland from about 85 wt. % to about 20 wt. % of a plasticized polyvinyl butyral resin. Minor amounts of fatty acids and paraffin wax may be added to improve low temperature properties and to facilitate processing a hot melt admixture of the ingredients into a sheet.Type: GrantFiled: October 26, 1979Date of Patent: July 7, 1981Assignee: Tremco, Inc.Inventors: Charles A. Kumins, Milan L. Warford
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Patent number: 4269321Abstract: A peelable bonded structure having a peel strength of 0.05 to 5 kg/cm comprises a plurality of articles, at least one of which is made of metal, bonded together through a composite coating layer. The composite coating layer is composed of adjacent first and second coating layers at least one of which comprises (A) a modified olefin resin having a carbonyl group concentration of 0.01 to 200 milliequivalents per 100 g of the olefin resin and (B) a coating film-forming base resin at an (A)/(B) weight ratio of from 0.2/99.8 to 40/60 and has a multi-layer distribution structure having resin concentration gradients in the thickness direction such that the modified olefin resin (A) is distributed predominantly in the portion contiguous to the interface between the two coating layers and the base resin (B) is distributed predominantly in the opposite portion.Type: GrantFiled: November 28, 1978Date of Patent: May 26, 1981Assignee: Toyo Seikan Kaisha, Ltd.Inventors: Isao Ichinose, Fumio Mori, Noboru Suzuki
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Patent number: 4264674Abstract: A waterproofing sheet material useful for example as a free floating membrane or flashing material in roofing applications, a pond liner, or a gasketing material, composed of from about 15 wt. % to about 80 wt. % of an ingredient selected from the group consisting of:(a) homopolymers of alkaldienes and substituted alkadienes(b) addition copolymers of alkadienes with unsaturated monomers(c) homopolymers of alkenes and substituted alkenes selected from the group consisting of polyethylene, chlorosulfonated polyethylene and polyisobutylene(d) resin acids and resin acid derivatives(e) highly aromatic bituminous materials, and(f) pine oiland from about 85 wt. % to about 20 wt. % of a plasticized polyvinyl butyral resin. Minor amounts of fatty acids and paraffin wax may be added to improve low temperature properties and to facilitate processing a hot melt admixture of the ingredients into a sheet.Type: GrantFiled: October 26, 1979Date of Patent: April 28, 1981Assignee: Tremco, IncorporatedInventors: Charles A. Kumins, Milan L. Warford
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Patent number: 4261473Abstract: A molded container having a wall composed of a thermoplastic resin oriented in at least one direction on the wall face, wherein the container wall has a layer of a blend composed mainly of a plurality of melt-extrudable thermoplastic resins, each of which has a solubility parameter (Sp) of at least 9.5, at least one of said thermoplastic resins has an oxygen permeability lower than 5.times.10.sup.-11 cc.multidot.cm/cm.sup.2 .multidot.sec.multidot.cmHg, said thermoplastic resins are chosen so that the difference (.DELTA.Sp) of the solubility parameter in said thermoplastic resins is not greater than 4.5, the elongation of said resin blend is higher than the arithmetic mean (.epsilon.) of elongations of the respective thermoplastic resins, and wherein the container has a thermal shrinkability (.delta.) of at least 5% in the orientation direction of said container wall.Type: GrantFiled: December 14, 1976Date of Patent: April 14, 1981Assignee: Toyo Seikan Kaisha LimitedInventors: Muneki Yamada, Sadao Hirata, Shunsaku Hirata, Akira Kishimoto, Fumio Kano, Jinichi Yazaki, Toru Suzuki
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Patent number: 4250661Abstract: A covering multilayer film or sheet structure for agricultural application, which consists essentially of:(1) a film or sheet of a resin composition comprising (A) 100 parts by weight of a thermoplastic resin selected from the group consisting of olefinic resins and vinyl chloride resins and (B) about 1 to about 40 parts by weight of an acetal resin, and(2) a layer of the thermoplastic resin (A) laminated to at least one surface of the film or sheet (1); and a method for maintaining an agricultural locus at temperatures suitable for the growth of plants, using aforesaid covering multilayer film or sheet.Type: GrantFiled: August 23, 1979Date of Patent: February 17, 1981Assignee: Sekisui Kagaku Kogyo K.K.Inventors: Yoshiaki Kodera, Kiyoyuki Watanabe, Tetsuo Kadoya, Tadashi Taguchi
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Patent number: 4251591Abstract: Laminates of a polyvinyl butyral sheet with a sheet comprising a copolymer of a vinylaromatic monomer with an unsaturated dicarboxylic acid anhydride have high strength and can be made optically clear. The laminates can be in part foamed to provide insulation materials or metalplated to provide tough materials that could be used for example in automotive applications.Type: GrantFiled: October 1, 1979Date of Patent: February 17, 1981Assignee: Monsanto CompanyInventor: Henry K. Chi
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Patent number: 4243719Abstract: The present invention provides a reinforced glass laminate, comprising a non-hydrophilic synthetic resin, at least one surface of which has been rendered hydrophilic by bonding thereon a layer of a hydrophilic material, a layer of hydrophilic synthetic resin being bonded to said layer of hydrophilic material and a layer of glass being bonded to said layer of hydrophilic synthetic resin.The present invention also provides a process for producing a reinforced glass laminate, wherein a non-hydrophilic synthetic resin is coated with a solution capable of forming a layer of a hydrophilic material thereon, the solvent medium is then removed, a hydrophilic synthetic resin is placed on the layer of hydrophilic material and glass is then placed on the hydrophilic synthetic resin, whereafter bonding together of the layers is achieved either by applying an increased pressure at an elevated temperature or by heating under reduced pressure.Type: GrantFiled: January 29, 1979Date of Patent: January 6, 1981Assignee: Romag Holdings Ltd.Inventor: Alan Holmes
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Patent number: RE30573Abstract: A crown closure having a polyolefin liner that can be readily removed, said crown closure comprising a crown shell having a primer layer on its inner surface and a polyolefin liner applied to the inside of said crown shell, characterized in that said primer layer is a two-component priming consisting of an undercoat layer containing .[.a polyethylene oxide.]. .Iadd.an oxidized polyethylene .Iaddend.and a topcoat layer containing .[.a polyethylene oxide.]. .Iadd.an oxidized polyethylene .Iaddend.and at least one other compatible resin, with the provision of a printing layer of indicia at the interface between said undercoat and topcoat layers or atop said topcoat layer. Aforesaid crown closure can be prepared by providing at one face of a metal stock sheet a primer undercoat layer containing .[.a polyethylene oxide.]. .Iadd.an oxidized polyethylene.Iaddend., printing indicia thereon, providing atop said undercoat layer a primer topcoat layer containing .[.a polyethylene oxide.]. .Iadd.Type: GrantFiled: September 18, 1979Date of Patent: April 14, 1981Assignee: Japan Crown Cork Co., Ltd.Inventors: Isao Ichinose, Mitsuhiro Sakemoto, Noboru Suzuki