Entirely Inorganic Patents (Class 428/552)
  • Patent number: 5682595
    Abstract: The ceramic/metal composite material is comprised of a ceramic phase with particles of alumina or of a solid solution based on alumina and a refractory phase including titanium nitride and/or carbonitride and a metallic matrix based on Ni, Co, Fe. The interface between the particles of alumina or the solid solution of alumina and the metallic matrix is rich in nitrogen and in titanium or in compounds thereof.
    Type: Grant
    Filed: November 1, 1994
    Date of Patent: October 28, 1997
    Assignee: UFEC- Universal Fusion Energie Company SA
    Inventors: Denis Gonseth, Daniele Mari, Paul Bowen, Claude Paul Carry, Pascal Streit, Roberto Mulone
  • Patent number: 5679469
    Abstract: A metallized ceramic substrate having a smooth plating layer comprises a ceramic substrate containing aluminum nitride as a main component; a tungsten- and/or molybdenum-based metallized layer formed on at least one face of the ceramic substrate; and a nickel-based plating layer formed on the metallized layer wherein the plating layer has a thickness of not greater than 2 .mu.m and a surface roughness (Ra) of not greater than 2 .mu.m. Alternatively, the plating layer on the ceramic substrate may comprise a first nickel-based plating layer having a thickness of not greater than 2 .mu.m and a second gold-based plating layer having a thickness of not greater than 1 .mu.m wherein the gold-based plating layer has a surface roughness (Ra) of 2 .mu.m or less.
    Type: Grant
    Filed: July 26, 1995
    Date of Patent: October 21, 1997
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Kouhei Shimoda, Hirohiko Nakata
  • Patent number: 5672435
    Abstract: Hard disk drive components, such as, sliders, load beams, support arms, actuators, actuator bearings, spacers, clamps, spindles, ball bearings, thrust bearings, journal bearings, base plates, housings, and covers, formed of a multi-phase ceramic-based material. One method of making the hard disk drive components includes (a) forming a porous body of ceramic; (b) infiltrating a liquid into the pores of the ceramic body; (c) solidifying the infiltrated liquid; and (d) machining the metal-infiltrated ceramic body to form the hard disk drive component.
    Type: Grant
    Filed: June 29, 1995
    Date of Patent: September 30, 1997
    Assignee: The Dow Chemical Company
    Inventors: David W. Born, Uday V. Deshmukh, Timothy G. Fawcett, Richard T. Fox, Kevin J. Nilsen, Aleksander J. Pyzik
  • Patent number: 5666643
    Abstract: A braze material is provided for repairing an article, and particularly components formed from cobalt and nickel-base superalloys, such as gas turbine engine components. The braze material is composed of high melt particles distributed within a braze alloy. The braze alloy can be any suitable bonding material of the type used to repair components that must operate at high temperatures. The particles are single crystal, directionally solidified or equiaxed particles formed from a superalloy or ceramic material, or mixtures thereof. Importantly, the particles have an aspect ratio (length to width) of at least 4:1. The braze material can be provided and used in the form of a slurry, a presintered preform, a plasticized tape, or in a powdered form.
    Type: Grant
    Filed: May 15, 1996
    Date of Patent: September 9, 1997
    Assignee: General Electric Company
    Inventors: Richard P. Chesnes, Stephen J. Ferrigno, David E. Budinger, Melvin R. Jackson
  • Patent number: 5658678
    Abstract: A corrosion resistant cermet comprises a ceramic component (e.g., WC) and a binder alloy comprised of a major component (e.g., one or more of iron, nickel, cobalt, their mixtures, and their alloys) and at least one additive component (e.g., one or more of ruthenium, rhodium, palladium, osmium, iridium, and platinum). Plungers for hyper compressors used in the corrosive environments generated during the manufacture of low density polyethylene (LDPE) or ethylene copolymers are an example of the use of the corrosion resistant cermet.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: August 19, 1997
    Assignee: Kennametal Inc.
    Inventors: William M. Stoll, James P. Materkowski, Ted R. Massa
  • Patent number: 5655211
    Abstract: A honeycomb structure includes a honeycomb body of electrically conductive material. The honeycomb body has regions of different material with different specific electrical resistance. The honeycomb body is electrically divided by slots and/or electrically insulating layers for causing an electric current to flow along a winding path through the honeycomb body. A method for producing a honeycomb body having regions of different specific electrical resistances includes supplying two different compositions of metal powder or a mixture of metal and ceramic powder to an extruder, while guiding one of the compositions to an inner region and the other of the compositions to an outer region of the extruder surrounding the inner region. The different compositions are co-extruded to make a monolithic honeycomb body. The honeycomb body is fired, sintered or physically-chemically treating differently from one region to another. Offset slots are formed in the extruded honeycomb body.
    Type: Grant
    Filed: September 17, 1996
    Date of Patent: August 5, 1997
    Assignee: Emitec Gesellschaft fuer Emissionstechnologie
    Inventor: Wolfgang Maus
  • Patent number: 5655212
    Abstract: A modular membrane filter for gases liquid and particulate matter is disclosed, the filter comprising at least two porous ceramic or ceramic modules. A regenerative filter is also disclosed comprising a means for filtering; and a means for regenerating said means for filtering, said means for regenerating being integral with said filtering means.
    Type: Grant
    Filed: February 28, 1995
    Date of Patent: August 5, 1997
    Assignee: Micropyretics Heaters International, Inc.
    Inventors: Jainagesh A. Sekhar, Vikas Gupta, Srinivas Penumella
  • Patent number: 5649282
    Abstract: An element for thermally protecting a substrate is deposited on the substrate and comprises a quasicrystalline aluminium alloy having a thermal diffusivity lower than 2.5.times.10.sup.-6 m.sup.2 /s at room temperature and a thermal diffusivity, within the temperature range 650.degree.-750.degree. C., which does not exceed its thermal diffusivity at room temperature by a factor greater than 3. The element may be used to provide heat barriers or bonding layers for substrates. The heat protection element, used in the form of a heat barrier or in the form of a bond coat for heat barriers, exhibits good thermal insulation properties, good mechanical properties, a low specific mass, good resistance to corrosion, and great ease of processing. Further, the invention is useful in limiting heat transfer towards or from parts and components of fittings in many household and industrial devices, for example, heating or cooking devices, smoothing irons, automobile components, and in aeronautic components.
    Type: Grant
    Filed: September 26, 1995
    Date of Patent: July 15, 1997
    Assignee: Centre National de la Recherche Scientifique
    Inventors: Jean-Marie Dubois, Pierre Archambault, Bernard Colleret
  • Patent number: 5640669
    Abstract: A process for preparing a metallic porous body, comprising: forming a layer comprising Cu, a Cu alloy, or a precursor thereof onto a skeleton composed of a porous resin body having a three-dimensional network, heat-treating the resin body with the layer formed thereon to remove a heat-decomposable organic component, thereby forming a porous metallic skeleton of Cu or a Cu alloy; and plating the surface of the Cu or Cu alloy skeleton with Ni or an Ni alloy. The heat treating may be carried out by direct induction heating. The metallic porous body is useful as electrodes for batteries, various filters, carriers for catalysts, etc. When the porous body is cut and used as the electrode substrate, the coating of an area, where Cu or its alloy has been exposed by cutting or the like, with a third metal having a lower ionization tendency than Cu or its alloy can provide an electrode substrate having better corrosion resistance and battery service life.
    Type: Grant
    Filed: December 4, 1995
    Date of Patent: June 17, 1997
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Keizo Harada, Masayuki Ishii, Kenichi Watanabe, Shosaku Yamanaka
  • Patent number: 5634189
    Abstract: A structural component is formed with an outer shell of sintered, solid, powder particles, and a porous core of sintered, hollow, bodies arranged in layers. The hollow bodies are of increased diameter in the layers in a direction from the outer periphery of the core towards the center of the core. The material of the outer shell and of the core is a metal or ceramic.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: May 27, 1997
    Assignee: Mtu Motoren-Und Turbinen Union Munchen GmbH
    Inventors: Axel Rossmann, Wilfried Smarsly
  • Patent number: 5624766
    Abstract: A coated cemented carbide comprising: a substrate comprising a WC-based cemented carbide containing 4 to 10 wt. % of Co as a binder phase; based on a ratio in a mirror-polished texture of a cross section of the cemented carbide, 70% or more of WC crystals as a hard phase being classified into either of a group of fine particles A having a particle size of from 0.1 to 1 .mu.m and a group of coarse particles B having a particle size of from 3 to 10 .mu.m, the area ratio S.sub.A /S.sub.B of the fine particles A to the coarse particles B being in a range of from 0.22 to 0.45; and a coating layer disposed on a surface of the cemented carbide and having a total thickness in a range of from 5 to 100 .mu.m. The coating layer comprises at least one layer comprising at least one selected from the group consisting of: carbides, nitrides, carbonitrides, oxycarbides, and boronitrides of Ti, Zr, and/or Hf; and at least one layer comprising at least one selected from the group consisting of: Al.sub.2 O.sub.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: April 29, 1997
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Hideki Moriguchi, Nobuyuki Kitagawa, Toshio Nomura, Mitsunori Kobayashi, Katsuya Uchino, Kazuo Yamagata
  • Patent number: 5613187
    Abstract: A rotationally symmetrical preform (1) is made by atomizing molten metal by means of a gas jet in a nozzle and by deposition of the droplets on a suitable substrate, wherein at least two independent nozzles (2,3) are arranged so that their droplet streams (4,5) overlap and are directed onto a substrate (6) of circular cross-section, and wherein insoluble particles are injected either into the first or into the second droplet stream (4 or 5) or wherein different types of particles are injected into the first and the second droplet stream (4,5).
    Type: Grant
    Filed: August 1, 1995
    Date of Patent: March 18, 1997
    Assignee: Wieland-Werke AG Metallwerke
    Inventors: Dieter Stock, W. Gary Watson
  • Patent number: 5605558
    Abstract: A nitrogenous Al--Si powder metallurgical alloy contains at least 4 wt % and at most 15 wt % of nitrogen, with the remaining part consisting essentially of Al, Si and an unavoidable component. Consequently, a highly safe material which is lightweight and has a density of at most 3.0 g/cm.sup.3, a thermal expansion coefficient in the range of 5 to 10.times.10.sup.-6 /.degree.C., and a thermal conductivity coefficient of at least 0.2 cal/cm.multidot.sec.multidot..degree.C. has been obtained.
    Type: Grant
    Filed: November 4, 1994
    Date of Patent: February 25, 1997
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Shin-ichi Yamagata, Yoshishige Takano, Tetsuya Hayashi, Yugaku Abe
  • Patent number: 5603075
    Abstract: A corrosion resistant cermet comprises a ceramic component (e.g., WC) and a binder alloy comprised of a major component (e.g., one or more of iron, nickel, cobalt, their mixtures, and their alloys) and at least one additive component (e.g., one or more of ruthenium, rhodium, palladium, osmium, iridium, and platinum).Plungers for hyper compressors used in the corrosive environments generated during the manufacture of low density polyethylene (LDPE) or ethylene copolymers are an example of the use of the corrosion resistant cermet.
    Type: Grant
    Filed: March 3, 1995
    Date of Patent: February 11, 1997
    Assignee: Kennametal Inc.
    Inventors: William M. Stoll, James P. Materkowski, Ted R. Massa
  • Patent number: 5590393
    Abstract: The invention relates to a neutron-absorbing material and to its production process.This material comprises a homogeneous, boron carbide matrix 1 in which are dispersed e.g. pseudospherical, 150 to 500 .mu.m , calibrated clusters 3 of boride such as HfB.sub.2, in order to prevent the propagation of cracks F in the material and improve its thermal shock resistance.
    Type: Grant
    Filed: February 7, 1995
    Date of Patent: December 31, 1996
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Guy M. Decroix, Dominique Gosset, Bernard Kryger
  • Patent number: 5590392
    Abstract: A corrosion-resistant material for the construction of a member destined to contact molten metal comprises a matrix of a refractory metal and a powder of the oxide of at least one metallic element selected from the group consisting of the same metallic element as the molten metal and metallic elements having lower levels of free energy for the formation of an oxide than the molten metal, the powder of the oxide being dispersed and disposed in the matrix. The refractory metal is W, Mo, Ta, Nb, or Re. The metal oxide is selected from the rare earth metal oxides, namely the oxides of the same metallic elements as the molten metals, and the oxides of Ti, Cr, and Zr.
    Type: Grant
    Filed: February 22, 1995
    Date of Patent: December 31, 1996
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Yutaka Ishiwata, Yoshiyasu Itoh
  • Patent number: 5590383
    Abstract: A porous membrane produced by preparing a slurry made from at least one micropyretic substance and at least one liquid carrier. The slurry is dried into a green form having a desired geometric configuration. Combustion of the green form produces the porous membrane.
    Type: Grant
    Filed: August 29, 1994
    Date of Patent: December 31, 1996
    Assignee: Micropyretics Heaters International, Inc.
    Inventors: Jainagesh A. Sekhar, James J. Liu, Naiping Zhu
  • Patent number: 5584045
    Abstract: Polycrystalline diamond has non-uniform impurity concentration along the direction of thickness. The diamond near the rake surface has a lower impurity concentration. The diamond near the fixation surface has a higher impurity concentration. The diamond with the higher impurity concentration near the fixation surface alleviates strong stress or absorbs external shock. Owing to the higher impurity concentration of diamond near the fixation surface, the diamond tool excels in chip resistance or toughness. The diamond with a lower impurity concentration near the rake surface heightens abrasion resistance, adhesion resistance and strength.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: December 10, 1996
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Keiichiro Tanabe, Naoji Fujimori
  • Patent number: 5580666
    Abstract: A multi-phase cemented ceramic article, method of making same, and the material thereof is disclosed which is useful for machining and forming of metals, including ferrous metals, titanium, aluminum and other metals. The article and its material preferably includes novel microstructures including platelets, a range of grain sizes which yields superior hardness and other characteristics, and a lower tungsten concentration within the binder phase than has been seen in the prior art. The preferred composition includes ultrafine WC, an ultrafine solid solution of (Ti, Ta, W)C, and a cobalt binder. Platelets are formed in-situ, eliminating the need to add them during manufacture for improving toughness.
    Type: Grant
    Filed: January 20, 1995
    Date of Patent: December 3, 1996
    Assignee: The Dow Chemical Company
    Inventors: Ellen M. Dubensky, Stephen D. Dunmead, Daniel F. Carroll
  • Patent number: 5579534
    Abstract: A heat-resistant member is constructed by having a ceramic coating layer deposited on the surface of a metallic substrate through the medium of a metallic bonding layer. The metallic bonding layer is composed of at least two layers, i.e. a layer of an aggregate of minute particles disposed on the metallic substrate side and a layer of an aggregate of coarse particles disposed on the ceramic coating layer side. Otherwise, the metallic bonding layer is composed of at least three layers, i.e. two layers of an aggregate of coarse particles disposed one each on the metallic substrate side and the ceramic coating layer side and one layer of an aggregate of minute particles interposed between these two layers of an aggregate of coarse particles. These layers are obtained by the low pressure ambient plasma thermal spraying using a fine powder or a coarse powder of an alloy resistant to corrosion and oxidation.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: November 26, 1996
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Masayuki Itoh, Kazuhiro Yasuda, Kunihiko Wada, Seiichi Suenaga, Shinji Arai
  • Patent number: 5577263
    Abstract: A method for producing a composite element by causing a stream of gaseous rhenium hexafluoride to flow onto a carbon substrate in a chemical vapor deposition reaction. A flow of hydrogen gas causes a reduction of the rhenium hexafluoride to rhenium metal to thereby deposit a uniform layer of rhenium metal onto the surface of the carbon substrate. A fine grain rhenium coating on carbon is produced having an average particle diameter of from about 0.1 to about 25 micrometers. The elements may be used alone or several of them may be bonded together into various articles. Such elements and articles are useful as light weight, high temperature strength, corrosive gas resistant structural elements.
    Type: Grant
    Filed: March 22, 1995
    Date of Patent: November 19, 1996
    Assignee: AlliedSignal Inc.
    Inventor: Gary A. West
  • Patent number: 5574961
    Abstract: A material for disposition on a surface comprising Fe, Co, or FeCo in the form of small single magnetic domain metallic clusters disposed in an insulating matrix of BN. The material may be utilized as a new absorbing material for radar microwave signals. Additionally, the material may be utilized on a magnetic storage substrate to form a new magnetic recording medium.
    Type: Grant
    Filed: January 16, 1985
    Date of Patent: November 12, 1996
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Alan S. Edelstein, Stuart A. Wolf, Kenneth E. Kihlstrom
  • Patent number: 5572725
    Abstract: Reinforcement fibers are formed from a single crystal garnet body--suitably an aluminum garnet, desirably a rare earth aluminum garnet--having an epitaxial surface layer of a second garnet having a lattice constant larger than that of the body garnet so as to provide a compressive strain, to thereby strengthen the fiber.
    Type: Grant
    Filed: October 29, 1993
    Date of Patent: November 5, 1996
    Assignee: AlliedSignal, Inc.
    Inventors: Robert C. Morris, Devlin M. Gualtieri, Dave Narasimhan, Philip J. Whalen
  • Patent number: 5569543
    Abstract: A method and composition for coating an automotive brake rotor to render it corrosion resistant without impeding the braking function of the rotor, includes cleaning the rotor and thereafter applying a coating composition thereto which composition includes an inorganic alkali metal-silicate binder and a finely divided metal admixed therewith.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: October 29, 1996
    Assignees: Inorganic Coatings, Inc., Ford Motor Company
    Inventors: Parke Schaffer, Jr., Thomas Laughin, David M. Mann
  • Patent number: 5552107
    Abstract: Disclosed is an aluminum nitride body having graded metallurgy and a method for making such a body. The aluminum nitride body has at least one via and includes a first layer in direct contact with the aluminum nitride body and a second layer in direct contact with, and that completely encapsulates, the first layer. The first layer includes 30 to 60 volume percent aluminum nitride and 40 to 70 volume percent tungsten and/or molybdenum while the second layer includes 90 to 100 volume percent of tungsten and/or molybdenum and 0 to 10 volume percent of aluminum nitride.
    Type: Grant
    Filed: May 9, 1995
    Date of Patent: September 3, 1996
    Inventors: Jon A. Casey, Carla N. Cordero, Benjamin V. Fasano, David B. Goland, Robert Hannon, Jonathan H. Harris, Lester W. Herron, Gregory M. Johnson, Niranjan M. Patel, Andrew M. Reitter, Subhash L. Shinde, Rao V. Vallabhaneni, Robert A. Youngman
  • Patent number: 5552232
    Abstract: Disclosed is an aluminum nitride body having graded metallurgy and a method for making such a body. The aluminum nitride body has at least one via and includes a first layer in direct contact with the aluminum nitride body and a second layer in direct contact with, and that completely encapsulates, the first layer. The first layer includes 30 to 60 volume percent aluminum nitride and 40 to 70 volume percent tungsten and/or molybdenum while the second layer includes 90 to 100 volume percent of tungsten and/or molybdenum and 0 to 10 volume percent of aluminum nitride.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: September 3, 1996
    Assignees: International Business Machines Corporation, The Carborundum Company
    Inventors: Jon A. Casey, Carla N. Cordero, Benjamin V. Fasano, David B. Goland, Robert Hannon, Jonathan H. Harris, Lester W. Herron, Gregory M. Johnson, Niranjan M. Patel, Andrew M. Reitter, Subhash L. Shinde, Rao V. Vallabhaneni, Robert A. Youngman
  • Patent number: 5549975
    Abstract: A coated tool consisting of a cermet body and a refining layer thereon. The refining layer is a wear resistant layer of (Ti, Me) N, wherein Me is at least one metal which forms a stable oxide at a temperature above 700.degree. C.
    Type: Grant
    Filed: July 20, 1994
    Date of Patent: August 27, 1996
    Assignee: Balzers Aktiengesellschaft
    Inventors: Hans Schulz, Josef Maushart
  • Patent number: 5549951
    Abstract: Ultrafine whiskery or columnar ceramic particles, a method for producing the ultrafine particles, and a sintered article obtained by sintering the ultrafine ceramic particles are disclosed. The ultrafine ceramic particles are produced by thermally melting a matrix alloy of a composition of Al--M.sup.1, wherein M.sup.1 stands for at least one metallic element selected from the group consisting of Cr, Co, and Fe, or Al--M.sup.1 --M.sup.2, wherein M.sup.2 stands for at least one metallic element selected from the group consisting of Au, Cu, Dy, Er, Ga, Ge, Gd, Hf, Ho, Lu, Mn, Mo, Nb, Nd, Ni, Pr, Re, Sb, Sc, Si, Sn, Ta, Tb, Ti, Tm, V, W, Y, Zn, or Zr, in a nitriding atmosphere containing nitrogen and causing the vaporized raw material to react with the nitrogen in the atmosphere.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: August 27, 1996
    Assignees: YKK Corporation, Tsuyoshi Masumoto, Akihisa Inoue, Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Tadashi Yamaguchi, Katsutoshi Nosaki, Inoue Akihisa, Tsuyoshi Masumoto
  • Patent number: 5545249
    Abstract: A sintered bearing alloy for high-temperature application containing from more than 5 to 10 weight percent h-BN particles having a size of 100 to 500 .mu.m, which are dispersed in the matrix of stainless steel. Granulated h-BN powder is mixed with austenitic stainless steel powder and the resultant blended powder is formed into a green compact by compression, after which the green compact is sintered.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: August 13, 1996
    Assignee: Daido Metal Company Ltd.
    Inventors: Tadashi Tanaka, Masaaki Sakamoto, Koichi Yamamoto, Kouki Ozaki
  • Patent number: 5545487
    Abstract: The Al-Si sintered alloy having good mechanical strength and elongation and is especially excellent in wear resistance, and a method for producing the same. The sintered alloy consists of 2.4-23.5% Si, 2-5% Cu, 0.2-1.5% Mg, 0.01-1% of transition metals and the balance of aluminum and unavoidable impurities, and has a dapple grain structure of an Al-solid solution phase and an Al-Si alloy phase containing dispersed pro-eutectic Si crystals having a maximum diameter of 5-60 .mu.m either in the whole body or in the surface contact portion, and the area ratio of the Al-solid solution phase in the grain structure is in the range of 20-80%.
    Type: Grant
    Filed: February 9, 1995
    Date of Patent: August 13, 1996
    Assignees: Hitachi Powdered Metals Co., Ltd., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Zenzo Ishijima, Jun-ichi Ichikawa, Shuji Sasaki, Hideo Shikata, Hideo Urata, Shoji Kawase, Jun-ichi Ueda
  • Patent number: 5543235
    Abstract: The present invention provides multiple grade, composite cemented carbide articles and a method of making such articles. The cemented carbide articles comprise carbides of different grades (or different compositions and/or microstructures) and, therefore, correspondingly different properties at different locations in the same article. The method of the present invention comprises filling different areas or portions of a die with metallurgical powders having different compositions and/or microstructures. The powder is then compressed as a single compact in the die cavity. The compressed compact is subsequently sintered to produce a multigrade cemented carbide article having composition and/or microstructural variations within the volume of the article.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: August 6, 1996
    Assignee: SinterMet
    Inventors: Prakash K. Mirchandani, Robert E. Thomas, Mark Cippel
  • Patent number: 5541006
    Abstract: Methods for making, methods for using and articles comprising ferromagnetic cermets, preferably cemented carbides and more preferably tungsten carbide, having at least two regions exhibiting at least one property that differs are discussed. The multiple-region cermets are particularly useful in wear applications. The cermets are manufactured by juxtaposing and densifying at least two powder blends having different properties (e.g., differential carbide grain size or differential carbide chemistry or differential binder content or differential binder chemistry or differential magnetic saturation or any combination of the preceding). Preferably, a first region of the cermet comprises a first hard component having a prescribed binder content and a first magnetic saturation and a second region, juxtaposing or adjoining the first region, comprising a second binder content different than the binder content of the first region and a second magnetic saturation different than that of the first region.
    Type: Grant
    Filed: December 23, 1994
    Date of Patent: July 30, 1996
    Assignee: Kennametal Inc.
    Inventor: Edward V. Conley
  • Patent number: 5534353
    Abstract: A composite sintered material of a mixed-phase structure comprising fine particles of hard compound compactly and uniformly dispersed in grains of matrix of titanium or titanium alloy. The material is outstanding in abrasion resistance, strength, toughness, etc., and also has high resistance to corrosion by molten nonferrous metals and is therefore reduced in the likelihood of dissolving out into the melt.The sintered material is produced by uniformly mixing together a metal powder for forming the matrix of the desired sintered material and a powder for forming particles of hard compound to be dispersed, molding the powder mixture into a block under pressure, atomizing the block while melting the block and sintering the resulting powder.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: July 9, 1996
    Assignee: Kubota Corporation
    Inventors: Takahiro Kaba, Takashi Nishi, Tsuyoshi Mitsuhashi
  • Patent number: 5532069
    Abstract: A dispersion-strengthened aluminum alloy having a composite structure containing a matrix of .alpha.-aluminum and a precipitation deposited phase of an intermetallic compound with the intermetallic compound in a volume ratio of not more than 35 vol. %, has both high strength and high toughness. The precipitation phase of the intermetallic compound has an aspect ratio of not more than 3.0, the .alpha.-aluminum has a crystal grain size which is at least twice the grain size of the precipitation phase of the intermetallic compound, and the crystal grain size of the .alpha.-aluminum is not more than 200 nm. It is possible to obtain an aluminum alloy having the aforementioned limited structure by carrying out first and second heat treatments on gas-atomized powder containing at least 10 vol. % of an amorphous phase or a green compact thereof and thereafter carrying out hot plastic working.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: July 2, 1996
    Assignees: Tsuyoshi Masumoto, Akihisa Inoue
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Toshihiko Kaji, Junji Iihara, Yoshishige Takano
  • Patent number: 5529851
    Abstract: The present invention generally relates to mechanisms for preventing undesirable oxidation (i.e., oxidation protection mechanisms) of reinforcement materials in composite bodies. The oxidation protection mechanisms include getterer materials which are added to the composite body which gather or scavenge undesirable oxidants which may enter the composite body. The getterer materials may be placed into at least a portion of the matrix such that any desirable oxidant approaching, for example, a fiber reinforcement, would be scavenged by (e.g., reacted with) the getterer. Ceramic filler materials which serve as reinforcements may have a plurality of super-imposed coatings thereon, at least one of which coatings may function as a getterer. The coated materials may be useful as reinforcing materials in ceramic matrix composites to provide improved mechanical properties such as fracture toughness.
    Type: Grant
    Filed: July 18, 1994
    Date of Patent: June 25, 1996
    Assignee: Lanxide Technology Company
    Inventors: Christopher R. Kennedy, Birol Sonuparlak, Ali S. Fareed, John E. Garnier, Gerhard H. Schiroky
  • Patent number: 5525428
    Abstract: This invention relates to a substrate for semiconductor apparatus loading a semiconductor chip in an integrated circuit apparatus and is characterized in that a sintered compact containing copper of 2 to 30 wt. % in tungsten and/or molybdenum is used as the substrate having the heat radiation capable of efficiently radiating heat developed from the loaded semiconductor chip and thermal expansion coefficient similar to those of semiconductor chip and other enclosure material except for the substrate.
    Type: Grant
    Filed: January 4, 1995
    Date of Patent: June 11, 1996
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Mituo Osada, Yoshinari Amano, Nobuo Ogasa, Akira Ohtsuka
  • Patent number: 5523132
    Abstract: Solar energy absorptive coatings that comprise single cermet layers with a homogeneous metal volume fraction exhibit an absorptance of about 0.8, which is not high enough for practical solar applications. To achieve absorptance greater than 0.9, graded composite films have been developed, but they give rise to higher thermal emittance due to the absorption edge not being sharp enough. This leads to increased thermal emittance at high operating temperatures, in the range of 300.degree. C. to 500.degree. C. There is now disclosed a novel solar selective surface coating which is composed of two cermet layers, with different metal volume fractions in each layer. The two cermet layers have different thicknesses, and the layers have thicknesses and volume fractions such that solar radiation is absorbed by internal absorbing and phase cancellation interference, but the cermet layers are substantially transparent in the thermal infrared region.
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: June 4, 1996
    Assignee: The University of Sydney
    Inventors: Qi-Chu Zhang, David Mills, Anthony Monger
  • Patent number: 5523170
    Abstract: An article with a high temperature superalloy body having a directionally oriented microsuucture and a structural discontinuity, such as a crack, or surface erosion or wear portion, is repaired, to provide a repaired article, using a mixture of Ni base ahoy powders. One powder includes a careful balance of the temperature depressants Si and B. In the one powder, Si is included in the range of about 0.05-2.2 wt. % to provide about 0.02-1.3 wt. % Si in a repaired portion as bonded with the article. In that same powder, B is include in the range of about 0.2-1.2 wt. % to provide about 0.08-0.7 wt. % in that repaired portion. In the repair method, the repaired portion can be provided, when shorter brazing times are used, with improved mechanical properties by diffusing the brazed alloy and aging the repaired structure in the range of about 1600.degree.-1700.degree. F. for a time in the range of about 1-16 hours.
    Type: Grant
    Filed: December 28, 1994
    Date of Patent: June 4, 1996
    Assignee: General Electric Company
    Inventors: David E. Budinger, Jim D. Reeves, Robert A. Anderson
  • Patent number: 5521016
    Abstract: Subject boron carbide to a passivation treatment at a temperature within a range of 1350.degree. C. to less than 1800.degree. C. prior to infiltration with a molten metal such as aluminum. This method allows control of kinetics of metal infiltration and chemical reactions, size of reaction products and connectivity of B.sub.4 C grains and results in cermets having desired mechanical properties.
    Type: Grant
    Filed: January 24, 1995
    Date of Patent: May 28, 1996
    Assignee: The Dow Chemical Company
    Inventors: Aleksander J. Pyzik, Uday V. Deshmukh, Stephen D. Dunmead, Jack J. Ott, Timothy L. Allen, Harold E. Rossow
  • Patent number: 5521015
    Abstract: A metal matrix composite component e.g. a brake disc, is provided with a protective coating to prevent displacement of the reinforcing filler in the matrix when the component is placed under load. Preferably the protective coating is metal, alloy, composite, refractory or ceramic applied e.g. by electro-plating.
    Type: Grant
    Filed: December 5, 1994
    Date of Patent: May 28, 1996
    Inventor: Martin J. M. Murphy
  • Patent number: 5518822
    Abstract: A TiCN-based cermet cutting insert superior in toughness with improved wear resistance includes a binding phase and at least two hard dispersion phases. One of the hard dispersion phases includes one of a duplex and triplex structure having a core structure containing at least one of titanium carbonitride and a carbonitride solid solution of Ti and one of a V, Cr, Ti, Nb, Zr, W and Mo (hereinafter referred to as a (Ti,M)CN. The other hard dispersion phase includes a single structure wherein the core structure is composed of at least one of (Ti,M)CN or (Ti,M)CN and TiCN.
    Type: Grant
    Filed: October 12, 1994
    Date of Patent: May 21, 1996
    Assignee: Mitsubishi Materials Corporation
    Inventors: Kiyohiro Teruuchi, Katsuhiko Yano, Niro Odani
  • Patent number: 5514480
    Abstract: A metal-based composite includes a metal matrix including aluminum as a major component, discontinuous alumina fibers buried in the metal matrix, mullite particles buried therein, and solid lubricant particles buried therein. The solid lubricant particles can be either graphite particles with a nickel layer formed on a surface thereof, or boron nitride cermet particles. By thus including the specific solid lubricant particles, the wear resistance of the metal-based composite can be improved, the wear of its mating parts can be reduced, and the friction coefficient between the metal-based composite and the mating parts can be inhibited from fluctuating. Hence, the metal-based composite can appropriately make aluminum-based internal combustion engines.
    Type: Grant
    Filed: August 5, 1994
    Date of Patent: May 7, 1996
    Assignee: Aisin Seiki Kabushiki Kaisha
    Inventors: Katumi Takagi, Shuji Inoue
  • Patent number: 5512235
    Abstract: Supported polycrystalline compacts having improved shear strength, impact, and fracture toughness properties, and methods for making the same under high temperature/high pressure (HT/HP) processing conditions. The method involves a HT/HP apparatus formed of a generally cylindrical reaction cell assembly having an inner chamber of predefined axial and radial extents and containing pressure transmitting medium, and a charge assembly having axial and radial surfaces and formed of at least one sub-assembly comprising a mass of crystalline particles adjacent a metal carbide support layer. The charge assembly is disposed within the chamber of the reaction cell assembly, with the pressure transmitting medium being interposed between the axial and radial surfaces of the charge assembly and the extents of the reaction cell chamber to define an axial pressure transmitting medium thickness, L.sub.h, and a radial pressure transmitting medium thickness, L.sub.r, the ratio of which, L.sub.h /L.sub.
    Type: Grant
    Filed: May 6, 1994
    Date of Patent: April 30, 1996
    Assignee: General Electric Company
    Inventors: David B. Cerutti, Henry S. Marek
  • Patent number: 5510193
    Abstract: Metal carbide supported polycrystalline diamond (PCD) compacts having improved shear strength and impact resistance properties, and a method for making the same under high temperature/high pressure (HT/HP) processing conditions. A sintered polycrystalline cubic boron nitrite (PCBN) compact interlayer is provided to be bonded at a first interface to a sintered PCD compact layer, and at a second interface to a cemented metal carbide support layer comprising particles of a metal carbide in a binder metal. The supported compact is characterized as having a substantially uniform sweep through of the binder metal from the cemented metal carbide support layer, which sweep through bonds the sintered PCD compact layer to the sintered PCBN interlayer, and the sintered PCBN interlayer to the cemented metal carbide support layer.
    Type: Grant
    Filed: October 13, 1994
    Date of Patent: April 23, 1996
    Assignee: General Electric Company
    Inventors: David B. Cerutti, Henry S. Marek
  • Patent number: 5508114
    Abstract: A method of manufacturing a lead-provided porous metal sheet comprises the steps of: forming a porous metal material having a metal layer on a surface of a framework of a porous base material comprising a foamed sheet and the like, by plating the porous base material and/or applying fine metal powders thereto; passing the porous metal material through a pair of rolls having a plurality of projections formed thereon to compress the porous metal material against the projections and reduce or eliminate pores so as to form one or more recesses extending; and forming solid metal portions by applying fine metal powders to the entire recesses.
    Type: Grant
    Filed: December 9, 1994
    Date of Patent: April 16, 1996
    Assignee: Katayama Special Industries, Inc.
    Inventor: Hirofumi Sugikawa
  • Patent number: 5508115
    Abstract: A titanium alloy matrix fiber reinforced composite made from titanium alloy sheet processed to have ductility up to about 35%. Of particular usefulness is the composite having a Ti.sub.3 Al titanium aluminide having this level of ductility. The composites have good resistance to thermal cyclic fatigue.
    Type: Grant
    Filed: April 1, 1993
    Date of Patent: April 16, 1996
    Assignee: United Technologies Corporation
    Inventors: Gary D. Linsey, Otis X. Chen, Martin J. Blackburn
  • Patent number: 5500289
    Abstract: A sinterable powder mix for the production of a tungsten-based cemented carbide material, said powder mix comprising at least 70% by weight of WC, from about 2 to about 15% by weight of an iron group metal binder, and optionally up to about 15% by weight of one or more carbides, nitrides and carbonitrides of metals of the groups IVb, Vb and VIb of the periodic table; characterized in thatsaid powder mix comprises from about 1 to about 8% by weight of Ta(Nb) oxide and powdered elemental carbon in about the stoichiometric amount required for the reaction:Ta(Nb).sub.2 O.sub.5 +7C.fwdarw.
    Type: Grant
    Filed: June 20, 1995
    Date of Patent: March 19, 1996
    Assignee: ISCAR Ltd.
    Inventor: Ilan Gavish
  • Patent number: 5498483
    Abstract: A wear-resistant sintered ferrous alloy for use as a valve seat, the alloy comprising an iron-based matrix having a sorbite or pearlite structure consisting of 0.5 to 1.5% by weight of C, 0.5 to 3% by weight of Ni, 0.5 to 2% by weight of Mo, 0.1 to 8% by weight of Co, 0.05 to 1% by weight of Mn, and the balance of Fe, with unavoidable impurities, and having a Vickers hardness of from 300 to 450; hard particles A consisting of 1.5 to 2.5% by weight of C, 38 to 45% by weight of Cr, 18 to 30% by weight of W, 5 to 15% by weight of Co, 0.5 to 3% by weight of Mo, 0.03 to 0.5% by weight of Ti, and the balance of Fe, with unavoidable impurities, and having an average particle diameter of from 30 to 80.mu.m; and hard particles B consisting of 60 to 70% by weight of Mo, 0.5 to 2% by weight of Si, and the balance of Fe, with unavoidable impurities, and having an average particle diameter of from 30 to 80 .mu.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: March 12, 1996
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Kozo Ito, Yoshishige Takano
  • Patent number: 5492771
    Abstract: An improved method of making a monolayer abrasive tool using a relatively low melting point, soft filler metal alloy braze which possesses sufficiently high yield strength combined with a relatively high ductility and low elastic modulus to produce an exceptional bond between a monolayer of superabrasive particles and the tool substrate. The steps of the brazing process include applying a layer of the filler metal alloy including a an active metal in either pre-alloyed or as a mixture with the metal alloy and a monolayer of superabrasive crystals over the filler metal layer. This assembly is heated in a mon-oxidizing atmosphere such as a vacuum to melt the alloy and braze bond the superabrasive particles to the tool substrate. The alloy bond formed possess the properties of a ductility of at least 20 percent elongation, an elastic modulus of less than 15.times.10.sup.6 or less, and a yield strength preferably at least about 45,000 to 50,000 psi.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: February 20, 1996
    Assignee: Abrasive Technology, Inc.
    Inventors: James T. Lowder, Roy F. Wielonski, Kosta L. George
  • Patent number: 5492769
    Abstract: A method is provided for improving the scratch or surface wear resistance of substrates by embedding discrete, hard particles within the surface layer of the substrate. Discrete, hard particles are applied to the substrate surface and then embedded within and bonded to the surface layer of the substrate by softening the substrate surface layer by either thermal or solvent means. Suitable substrate materials include thermoplastics, thermoset plastics, polymers, glass, soft metals, and composites. Suitable hard particles include diamond, silicon dioxide, aluminum oxide, cubic boron nitride, boron carbide, silicon carbide, silicon nitride, tantalum carbide, titanium carbide, titanium nitride, tungsten carbide, and zirconia alloys containing at least one phase stabilization additive selected from the group yttrium, hafnium, calcium, magnesium, and cesium. Scratch resistant substrates or articles having discrete, hard particles embedded within the surface layer of the substrate or article are also provided.
    Type: Grant
    Filed: September 17, 1992
    Date of Patent: February 20, 1996
    Assignee: Board of Governors of Wayne State University
    Inventors: Roger W. Pryor, Antony B. Brennan, James H. Adair, Rajiv K. Singh