Abstract: A heat resistant precoated steel sheet suitable for use in the manufacture of a muffler of an automobile exhaust gas system comprising:a hot dip aluminized steel sheet,a chromate pretreatment layer formed on at least one surface of said hot dip aluminized steel sheet and having a chromium pickup of 10 to 50 mg/m.sup.2,a primer coat formed on said pretreatment layer and comprising a cured polyamide imide resin and 8 to 52 parts by weight, based on 100 parts by weight of said resin, of strontium chromate intimately admixed with said resin, anda top coat formed on said primer coat and comprising a cured silicone-modified polyester resin with a modification degree of from 30 to 50% and 8 to 32 parts by weight, based on 100 parts by weight of said resin, of aluminum scale intimately admixed with said resin.

Abstract: A heat resistant precoated steel sheet suitable for use in the manufacture of a muffler of an automobile exhaust gas system comprising:a hot dip aluminized steel sheet,a chromate pretreatment layer formed on at least one surface of said hot dip aluminized steel sheet and having a chromium pick-up of 10 to 50 mg/m.sup.2,a primer coat formed on said pretreatment layer and comprising a cured polyamide imide resin and 8 to 52 parts by weight, based on 100 parts by weight of said resin, of strontium chromate intimately admixed with said resin, anda top coat formed on said primer coat and comprising a cured polyamide imide resin and 8 to 32 parts by weight, based on 100 parts by weight of said resin, of aluminum scale intimately admixed with said resin.

Abstract: An antenna reflector comprising a face skin of graphite fiber reinforced epoxy (GFRE) material is coated with a layer of chromium. The chromium is then coated with aluminum and a protective coating of silicon dioxide is then deposited over the aluminum. The chromium has a thickness sufficiently thin to provide good coverage of the pores of the GFRE material and to minimize distortion causing poor bond due to differences in the coefficient of thermal expansion of the different materials in the presence of temperature cycles. The aluminum is sufficiently thick to provide good reflecting characteristics to minimize the polarizing effects of the graphite face skins.

Abstract: The present invention provides an aqueous composition and process for the electrodeposition of a layer of zinc containing silicon and phosphorus on a metal substrate. The electrodeposition composition is prepared by reacting metallic silicon and zinc with phosphoric acid and an alkali metal hydroxide in the ratio of between 0.4 and 1.3 moles of alkali metal hydroxide per mole of phosphoric acid, and adjusting the solution to a pH of 2 or higher after completion of the reaction. The coating is deposited on the metal substrate by electrodeposition and comprises about 70% to about 99.5% by weight of zinc, and about 0.10% to about 10% by weight of silicon, and about 0.5% to about 20% by weight of phosphorus.The resultant zinc/silicon/phosphorus coating improves the resistance of the metal substrate to corrosion, wear, galling and stress corrosion cracking.

Abstract: Disclosed herein is a radiant energy reflector comprising a laminated article mounted on a contoured support. The article includes a specularly reflective layer of silver protected on one side thereof from deterioration-inducing agents by a transparent cover sheet of polymeric material, and on the opposite side thereof by a non-polymeric protective layer of substantially inert and corrosion-resistant material. Also disclosed is a method for producing the article which yields an intimate and tenacious bond between the cover sheet, reflective layer and protective layer, thus reducing the likelihood of delamination.

Abstract: This invention is directed to an improved electroplated and painted product that is resistant to corrosive damage as measured on painted and scribed panels subjected to salt spray and cyclic humidity exposure, such as used to judge corrosion behavior of an automotive body panel. The electroplate layer, underlying a paint layer, is characterized by a two-phase structure and is composed of an alloy of 6.5 to 9.5%, by weight nickel, balance essentially zinc.

Abstract: A corrosion resistant duplex plated sheet steel is disclosed, which comprises a sheet steel having on at least one surface thereof a lower layer of Zn base alloy plating and an upper layer thereon selected from a zinc plating having a coating weight of 0.1-5 g/m.sup.2 and a zinc alloy or zinc composite plating having a coating weight of 0.1-10 g/m.sup.2. The ratio of the coating weight of the lower layer to that of the upper layer is at least 1:1 and in the case of upper layer of zinc alloy or zinc composite plating, it comprises, on a weight basis as metal, at least 80% Zn, and one or more additives as Zn corrosion inhibitors selected from Ni, Co, Mn, Sn, Ti, Al, Mg and Si. The duplex plated sheet steel is suitable for coating thereon with an electrophoretic coating composition and exhibits excellent cratering resistance in cathodic electrophoretic coating and excellent cosmetic resistance after painting.

Abstract: A material for forming contacts for use in connectors, switches and the like for electronic appliances. The material comprises a first metal layer having a conductivity, a second metal layer having a springiness and a plastic layer interposed between these metal layers. With this arrangement, the contacts according to the invention can be miniaturized to a far greater extent and far more inexpensively in comparison with prior art contacts made of copper alloys while maintaining the same current capacity and contact pressure. Moreover, the contacts according to the invention can eliminate disadvantages of prior art contacts made of two directly contacted metals, such as separation between them and elongation due to difference in coefficient of thermal expansion, deterioration of the contacts due to diffusion therebetween, and disintegration of the contacts due to electrochemical corrosion resulting from difference in electric potential between two metals.

Abstract: A composition for rust prevention of metals consisting essentially of (a) an organic silicon compound having an aminoalkyl group and at least one alkoxy group and (b) a compound having at least one oxirane ring. Said composition exhibits its effects particularly when applied on threaded metal elements.

Abstract: In a magnetic recording medium particularly for perpendicular magnetization comprising a non-magnetic substrate and a magnetic thin film formed on the surface thereof and including at least two layers, a lower layer with low coercive force and high permeability, for example, of permalloy is sputtered on the substrate and an upper layer for perpendicular recording, for example, of cobalt-chromium alloy is sputtered on the lower layer, and the average grain diameter of the lower layer is less than one half of that of the upper layer.

Abstract: To a sheet of oriented polyethylene terephthalate a layer of nickel chrome alloy with an optical density of approximately 60% is applied by conventional vacuum deposition. To this sheet a subsequent stripe layer of stainless steel at 35% is applied by vacuum deposition down the center portion of the web which yields a combined optical density of approximately 21% over the center area. This first sheet is then laminated with a suitable optically clear adhesive to a second sheet of oriented polyethylene terephthalate incorporating a center portion which includes a nickel chrome stripe with an optical density of approximately 35% applied by conventional vacuum deposition. The resulting composite exhibits a vignette pattern of dark (optical density 7 to 12%) to light optical density 50 to 70% (from center to edge). A suitable optically clear mounting adhesive is then applied. When desired, the finished laminate contains a layer of clear PET which has been coated with a hard coat, i.e.

Abstract: A wire electrode for a spark-eroding system for erosion cutting of workpieces using intermittent electrical charges includes a core of a current-conducting material and a wire coating of a material with a lower evaporation temperature, for example zinc. The core consists of one of the following alloys according to DIN (German Industrial Standard) 17666:(a) Cu Mg 0.4;(b) Cu Fe 2P;(c) Cu Cr Zr;(d) Cu Zr.

Abstract: A perpendicular magnetic recording medium composed of a base material, a 1st magnetic thin layer formed on the base material, and a perpendicularly magnetizable 2nd magnetic thin layer formed on the 1st magnetic thin layer, wherein the 1st magnetic thin layer is composed of a Co-base ternary amorphous alloy containing small amounts of Hf and Ta.

Abstract: A novel method is provided for producing high technology decorative materials that incorporates both computer-aided design and semiconductor processing. The high technology decorative materials thereby produced also make use of microscopic diffraction gratings for generating a dynamic spectral pattern of changing colors when exposed to ambient light such as sunlight, incandescent light, and the like. The decorative materials comprise a semiconductor substrate (10), at least one patterned coating (14) formed on one major surface (12) of the substrate and a transparent layer (28) formed thereover. The patterned coating comprises a material that is capable of being patterned to the dimensions required to diffract incident visible light and includes a series of lines (26) having an arrangement, spacing and width such that incident light will be diffracted in a pleasing pattern. A suitable jewelry mount (44) is attached to individual pieces formed from the substrate.

Abstract: Method and apparatus for the coating of a substrate wherein the following chronologically takes place under vacuum conditions: (i) non-oxidized plating material is deposited on the substrate via ion vapor deposition; and (ii) a coating material is chemically bonded with the non-oxidized plating material. The coating material may comprise a primer, which chemically bonds with the non-oxidized plating material, and a polymer, which impregnates the primer-prepared plating material. Said polymer may also chemically bond with the primer. Alternatively, the coating material may comprise an epoxy which forms an organo-metallic bond with the plating material. In another embodiment of the invention, the coating material may comprise boron trifluoride, which chemically bonds with the non-oxidized plating material, and a polymer, which impregnates the boron trifluoride-prepared plating material.

Abstract: A magnetic recording medium comprising a support, a first layer formed on the support by evaporating cobalt or its alloy by an oblique-incidence vacuum evaporation technique, and a second plated layer made of cobalt or its alloy and formed by a wet plating. The cobalt alloy for the first layer substantially consists of, aside from cobalt, up to 30 wt % of Ni, Fe, Cu, W, Cr, Ru or a mixture thereof. On the other hand, the cobalt alloy for the second layer substantially consists of up to 40 wt % of Ni, up to 8 wt % of P and the balance of Co.

Abstract: The invention relates to molded pieces of plastic having at least a partial metal coating of their surfaces. The surfaces to be coated are roughened up by means of suitable pretreatment so that a good adhesion of the metal coating on the molded pieces is provided. For the support of this metal coating additionally a cover layer is applied. The molded pieces can also consist of shrinkable material which e.g. are also designed in the form of enveloping objects such as cable fittings.

Abstract: A weldable paint-coated steel sheet having improved corrosion resistance, weldability and workability, comprising a zinc alloy coated steel substrate and a paint coating applied thereon, said paint coating containing zinc alloy powder and at least one of the groups consisting of zinc powder and hard electric conductive powder.

Abstract: A composite structure of thin films including alternating layers of relatively high conductivity metals and low conductivity metals to combine the effects of reflection and absorption and thereby maximize the attenuation of the structure. Additionally, a similar structure of layers of materials with differing magnetic permeabilities may be used for the same purpose.

Abstract: A support for lithographic printing plate having provided on an iron material (i) a layer substantially consisting of chromium and/or chromium oxide and (ii) a layer consisting essentially of a water soluble polymeric compound and at least one selected from water soluble salts of calcium, magnesium, zinc, barium, strontium, cobalt, manganese, nickel and silicon, in this order.

Abstract: A multilayer metal/organic polymer composite which has a formable thermoplastic polymer layer, a first metal layer adhered to the polymer layer and a second metal layer adhered to the first metal layer. The first metal layer is formed either from one metal or from an alloy of two or more metals. Suitable alloys are those which begin melting at a temperature within a range of from about 85 to 150 percent of the forming temperatures in degrees Kelvin of the polymer layer. If the first meal layer is formed from one metal, the metal is suitably, copper, silver, nickel or manganese. The second metal layer is a metal or an alloy of two or more metals that melts at a temperature which is less than that at which the first metal layer melts.

Abstract: A product useful in the manufacture of printed circuits includes a carrier layer of copper having a thickness on the order of about 10-15 microns. A thin layer of copper having a thickness in the range of 1-12 microns, and which will provide the conductive path for the printed circuit, is secured to the copper carrier by an intermediate metallic layer positioned therebetween and secured to both layers of copper. The intermediate layer has a thickness in the range of 0.1-2.0 microns and is selected from the group consisting of nickel, a nickel-tin alloy, a nickel-iron alloy, lead and a tin-lead alloy. The intermediate layer adheres sufficiently to the thin layer of copper to prevent removal thereof during the etching process which removes the carrier layer of copper. The described thin metallic foil is bonded upon opposite sides of a suitable dielectric which may be a reinforced or non-reinforced epoxy or any one of a number of other suitable materials for forming the core of a printed circuit board.

Abstract: A coating composite provides extended corrosion resistance for substrate metals. The thin metallic undercoat of the composite contains combined metals. The heat curable and substantially resin free topcoat is established from composition containing chromium in non-elemental form, which topcoat composition may further contain particulate metal, all in liquid medium. In addition to outstanding corrosion resistance, the composite can retain substrate weldability and formability, while further enhancing paintability and weatherability.

Abstract: A particular plastic material is formed into the desired component shape and then is plated by a process comprising; a particular surface preparation step, electroless deposition and electrolytic deposition which results in excellent plating adhesion. The plated component is then assembled with other components manufactured in the same manner or with compatible metal components such as aluminum and soldered together in a disclosed hot oil dip soldering process. In the soldering process, the plated plastic substrate is completely immersed in a hot oil medium at a temperature of approximately 243.degree. C. (470.degree. F.) for a time of approximately 60 seconds for solder reflow.

Abstract: A metal composite is provided extended corrosion resistance. Prior to joining the metals of the composite, at least one of the metals is provided with a metallic undercoat. This undercoat is then coated with a metallic zinc layer. Lastly, a heat curable and substantially resin free topcoat is established on the zinc layer and cured. The topcoat composition contains chromium in non-elemental form and may further contain particulate metal, all in liquid medium. The metal composite is then formed by contacting metals including the thus coated metal. In addition to outstanding corrosion resistance, the composite can retain substrate weldability while further enhancing weatherability.

Abstract: A particular plastic material is formed into the desired component shape and then is plated by a process comprising; a particular surface preparation step, electroless deposition and electrolytic deposition which results in excellent plating adhesion. The plated component is then assembled with other components manufactured in the same manner or with compatible metal components such as aluminum and soldered together in a disclosed hot oil dip soldering process. In the soldering process, the plated plastic substrate is completely immersed in a hot oil medium at a temperature of approximately 243.degree. C. (470.degree. F.) for a time of approximately 60 seconds for solder reflow.

Abstract: A novel method is provided for producing jewelry that incorporates both computer-aided design and semiconductor processing. The high technology jewelry produced also makes use of microscopic diffraction gratings for generating a dynamic spectral pattern of changing colors when exposed to ambient light such as sunlight, incandescent light, moonlight and the like. The jewelry comprises a semiconductor substrate (10), at least one patterned coating (14) formed on one major surface (12) of the substrate and a transparent layer (28) formed thereover. The patterned coating comprises a material that is capable of being patterned to the dimensions required to diffract incident visible light and includes a series of lines (26) having an arrangement, spacing and width such that incident light will be diffracted in a pleasing pattern. A suitable jewelry mount (44) is attached to the substrate.

Abstract: A reflector includes a base body exhibiting dielectric property at least at its surface. A reflecting layer made of aluminum is formed on one surface of the base body by vacuum deposition. A light-transmitting water-insoluble inorganic oxide layer is formed on the aluminum reflecting layer. The light-transmitting inorganic oxide layer has its micropores sealed by sealing agent comprising H.sub.2 O or a carboxylate of an iron family element having a low valence.

Abstract: A reflector includes a base body made of a metallic material having substantially the same ionization potential as that of aluminum. A reflecting layer made of aluminum is formed over one surface of the base body by vacuum deposition. A light-transmitting water-insoluble inorganic oxide layer is formed on the aluminum reflecting layer. The light-transmitting inorganic oxide layer has its micropores sealed by H.sub.2 O a carboxylate of an iron family element having a low valence.

Abstract: A method of forming adherent metallized coatings on a substrate which is useful for the manufacture of printed circuit boards as well as other metal coated articles involves providing the substrate with a rubber-modified epoxy surface or coating, sputter etching at least 50 A. from the surface followed by vacuum depositing an adherent thin metal film of Cr, Ni, Ni-V alloy, Pt, Pd or Ti onto the substrate. Another metal layer is then provided over the adherent thin film.

Abstract: Pyrophorically activated surfaces of metal foil or screen, prepared by diffusing into surface a selectably removable second metal that is then selectively removed as by leaching, can be covered with reactive or inert materials. Reactive materials such as easily ignited metals or carbon or decomposable chemicals increase the heat generated by pyrophoric action. Inert materials slow down or prevent pyrophoric action. Pressure-sensitive adhesive tape in which the adhesive is of the non-transfer or transfer types can be adhered to pyrophorically activated surfaces to slow down action or to adhere material that reduces or increases severity of pyrophoric action. Pyrophoric Ni can be preserved for many months in alkaline solutions such as aqueous KOH, NaOH and triethanolamine. Pyrophoric Fe is prepared and preserved in aqueous alkaline stannite. Even better preservation is obtained for Ni and Fe with glycerine, ethylene glycol, triethanolamine and propylene oxide.

Abstract: A product useful in the manufacture of printed circuits includes a carrier layer of copper having a thickness on the order of about 10-15 microns. A thin layer of copper having a thickness in the range of 1-12 microns, and which will provide the conductive path for the printed circuit, is secured to the copper carrier by an intermediate metallic layer positioned therebetween and secured to both layers of copper. The intermediate layer has a thickness in the range of 0.1-2.0 microns and is selected from the group consisting of nickel, a nickel-tin alloy, a nickel-iron alloy, lead and a tin-lead alloy. The intermediate layer adheres sufficiently to the thin layer of copper to prevent removal thereof during the etching process which removes the carrier layer of copper. The described thin metallic foil is bonded upon opposite sides of a suitable dielectric which may be a reinforced or non-reinforced epoxy or any one of a number of other suitable materials for forming the core of a printed circuit board.

Abstract: A composite comprising a steel cords-covering rubber composition and a rubber composition which is contiguous thereto and contains a thiazole type vulcanization accelerator, at least one of these rubber compositions containing a m-cresol resin whereby they can be cured without decreasing the resulting strength of bond therebetween even after they have been left uncured in contact with each other for a considerable time.

Abstract: A copper-clad laminate having special utility in the production of high resolution printed circuit patterns by either subtractive or semi-additive processing is made by vapor depositing a film of zinc on a copper film on a silica-coated aluminum carrier sheet, vapor depositing a silica film on the resulting zinc-copper foil, bonding the resulting body to a substrate and then stripping the silica-coated aluminum carrier sheet from the copper-clad laminate.

Abstract: A metal web having a pyrophoric surface is coated by a solid or liquid that does not block the pyrophoric property and undergoes a pyrophoricity-intensifying exothermic change when subjected to the pyrophoricity of that surface.

Abstract: A method of metallizing materials by coating a substrate material with a hydrophilic composite material; electrolessly metal plating the hydrophilic composite material with a metal to render the surface conductive; followed by electroplating a metal onto the conductive surface. The method can, for example, be utilized to produce metallized foams, embossing plates for reproduction of grains and textures, and decorative coatings for substrate materials.

Abstract: Manganese coated steel materials having a compact film of hydrated manganese oxide formed on the manganese coating by heating and drying. Manganese coated steel materials of the present invention show very excellent corrosion resistance in ordinary corrosive environments as well as special corrosive environments such as marine environments and young plant cultivation in mountaineous forests. For further improvement of corrosion resistance, organic coating and metal coatings are applied.

Abstract: A method of applying solder to gold by applying a gold-tin intermediate layer to the gold and applying the solder over at least a portion of the intermediate layer. The method can be employed to produce a printed circuit unit composed of a printed circuit board, at least one gold member mounted on the board, a gold-tin intermediate layer bonded to at least a portion of the gold member, and solder bonded onto the intermediate layer.

Abstract: An improved plastic camera housing having an exterior decorative metallic coating and method of producing the same is disclosed. The camera housing assembly can comprise a polycarbonate glass fiber filled molded part that has been plasma etched in an inert argon gas filled pressure vessel. The camera part is plasma etched for a brief period of time to deteriorate the cross linkage of plastic bonding of the surface polymers without causing any outgassing of the elements of the plastic. A layer of copper is deposited to an approximate thickness of 1 to 3 microns in the inert subatmospheric environment. A second exterior layer of chromium approximately 0.2 to 0.5 microns is subsequently deposited to provide a hard abrasion resistant surface. Alternatively, a lacquer subsurface layer can be sprayed onto the camera part before the initial plasma etching.

Abstract: The decorative coating of metal, such as chrome plated cold rolled steel, is accomplished through use of a layout fluid which presents a highly desirable colored finish without any loss of the shine normally associated with chrome plating. The resulting colored metal part is achieved at a modest cost when compared to brass or other colored plating.

Abstract: A magnetic record member for use in magnetic recording devices is disclosed. The record member comprises a non-magnetic alloy disk polished to a mirror surface, a non-magnetic alloy layer formed on the disk, a magnetic thin film medium formed on the surface of the alloy layer, and a protective polysilicate film layer formed on the alloy layer. In certain embodiments, an oriented lubricant layer is formed on the polysilicate film layer.

Abstract: A desoldering wick formed of tin-coated copper strands braided together. The wick is coated with a flux solution which includes a coloring agent such as a dye. In use, the extent to which molten solder has traveled along the wick is visually indicated by a color demarcation line between the portion of the wick still having colored flux thereon and the portion of the wick from which the colored flux has been discharged. The latter portion can then be cut off and discarded.

Abstract: Addition compounds of sulfur dioxide and Schiff bases from primary aliphatic or araliphatic amines and aromatic aldehydes can be used for the sealing of the surface of phosphated mild steel. As a result of this the corrosion resistance of the steel and the adhesion of paint coatings on the treated steel are increased substantially. The addition compounds may have three different structures depending on the components used. They can be prepared easily by passing a stream of SO.sub.2 through the solution of the Schiff base.

Abstract: A white rust inhibited composition is comprised of a zinc containing substrate. A white rust inhibiting composition contacts the substrate and is comprised of a vapor corrosion inhibitor and a pH adjusting compound to adjust and maintain the pH of the white rust inhibiting composition between 8 and 12.5.