Abstract: Known protective layers with a high Cr content and additionally silicon form brittle phases which additionally embrittle during use under the influence of carbon. A protective layer including the composition of from 24% to 26% cobalt, from 10% to 12% aluminium, from 0.2% to 0.5T yttrium, from 12% to 14% chromium, remainder nickel is provided.

Abstract: Provided is a rolled copper foil or electrolytic copper foil for an electronic circuit to be used for forming a circuit by etching, wherein the copper foil comprises a heat resistance layer composed of zinc or zinc alloy or its oxide formed on an etching side of the rolled copper foil or electrolytic copper foil, and a layer of nickel or nickel alloy, which is a metal or alloy with a lower etching rate than copper, formed on the heat resistance layer.

Abstract: A clad material 1A for insulating substrates is provided with a Ni layer 4 made of Ni or a Ni alloy, a Ti layer 6 made of Ti or a Ti alloy and arranged on one side of the Ni layer, and a first Al layer 7 made of Al or an Al alloy and arranged on one side of the Ti layer 6 that is opposite to a side of the Ti layer 6 on which the Ni layer 4 is arranged. The Ni layer 4 and the Ti layer 6 are joined by clad rolling. A Ni—Ti series superelastic alloy layer 5 formed by alloying at least Ni of constituent elements of the Ni layer 4 and at least Ti of constituent elements of the Ti layer 6 is interposed between the Ni layer 4 and the Ti layer 6. The Ti layer 6 and the first Al layer 7 are joined by clad rolling in an adjoining manner.

Abstract: An object with an internal cavity may serve as a cooling structure for a semiconductor package. The object includes a stack of form fitting bodies. The stack has a first form fitting body shaped according to the cavity with a first layer forming a partially form fitting surface, the first layer including a mixture of a first metal and an oxide of the first metal, and a second layer adjacent to the first layer. The second layer includes the first metal but less oxide of the first metal than the first layer. The stack has a second form fitting body shaped according to the cavity with a first layer forming a partially form fitting surface configured to conform to the partially form fitting surface of the first form fitting body.

Abstract: An alloy to a protective layer for protecting a component against corrosion and/or oxidation, in particular at high temperatures is proposed. Known protective layers with a high Cr content and in addition silicon form brittle phases which additionally embrittle during use under the influence of carbon. The proposed protective layer has the composition of from 24% to 26% cobalt, from 10% to 12% aluminum, from 0.2% to 0.5% yttrium, from 12% to 14% chromium, from 0.3% to 5.0% tantalum, nickel.

Abstract: A grain oriented electrical steel sheet has grooves on one surface of the steel sheet formed for magnetic domain refining, the steel sheet including a forsterite film and a tension coating on front and back surfaces of the steel sheet, wherein the tension coating is applied on a surface with the grooves in a coating amount A (g/m2) and is applied on a surface with no grooves in a coating amount B (g/m2), the coating amounts A and B satisfying (1) and (2): 3?A?8??(1); and 1.0<B/A?1.8??(2).

Abstract: A dual brazing alloy element for a materially integral connection of a ceramic surface to a metallic surface includes a first layer having a Ni-based brazing alloy with a Ni content of at least 50% by weight and having at least one component configured to lower a melting point of the Ni-based brazing alloy selected from the group consisting of Si, B, Mn, Sn and Ge. A second layer includes an active brazing alloy material having a total content of 1-15% by weight of at least one active element selected from the group consisting of Ti, Hf, Zr and V.

Abstract: An erosion sensor that can separately monitor erosion and corrosion of a substrate, such as a wind turbine blade or a turbine blade used in devices such as gas turbines, aircraft engines, microturbines, steam turbines, and the like is disclosed. The sensor can include a first element or “erosion part” that is made of a corrosion resistant material. The first element of the sensor has similar erosion properties to the substrate being monitored. The sensor can further include a second element or a “corrosion part” that is made of a material having similar erosion and corrosion properties to the substrate. The sensor can provide an erosion indicator based on the erosion of the first element and a corrosion indicator based on the erosion and corrosion of the second element.

Abstract: An article has a metallic substrate. The substrate has a first surface region and a plurality of blind recesses along the first surface region. The substrate has perimeter lips at the openings of the plurality of recesses and extending partially over the respective associated recesses. A ceramic coating is along the first surface region.

Abstract: It is possible to obtain a laminate having high adhesion strength between ceramic and a metal coating by providing the following: an insulating ceramic substrate; an intermediate layer formed on the surface of the ceramic substrate and having a metal-containing principal component metal layer and an active ingredient layer including metal, a metal oxide, or a metal hydride; and a metal coating formed on the surface of the intermediate layer by accelerating a metal-containing powder with gas, and depositing the same on the surface thereof by spraying while in a solid state.

Abstract: An integrated composite structure with a graded coefficient of thermal expansion (CTE) is formed by selecting a plurality of layers of materials with a graded CTE and using build-up (bottom-up) fabrication approaches such as metal deposition or powder metallurgy to produce a CTE-graded layered composite preform, which is then consolidated and heat treated to create the CTE graded integrated composite billet or near net shape. The integrated composite billet or near net shape is then processed to produce a first surface for attachment of a first structural member having a first CTE and to produce a second surface of for attachment of a second structural member having a second CTE.

Abstract: A coating and process for depositing the coating on a substrate. The coating is a nickel aluminide overlay coating of predominantly the beta (NiAl) and gamma-prime (Ni3Al) intermetallic phases, and is suitable for use as an environmental coating and as a bond coat for a thermal barrier coating (TBC). The coating can be formed by depositing nickel and aluminum in appropriate amounts to yield the desired beta+gamma prime phase content. Alternatively, nickel and aluminum can be deposited so that the aluminum content of the coating exceeds the appropriate amount to yield the desired beta+gamma prime phase content, after which the coating is heat treated to diffuse the excess aluminum from the coating into the substrate to yield the desired beta+gamma prime phase content.

Abstract: A housing includes a substrate and a nano-composite layer deposited on the substrate. The nano-composite layer includes a number of metal oxide nitride layers and a number of Ce layers. Each metal oxide nitride layer alternates with a Ce layer, and the outermost nano-composite layer is a metal oxide nitride layer. The metal in the metal oxide nitride layer aluminum, titanium, silicon, chromium, or zirconium.

Abstract: A method of improving corrosion resistance of a metal substrate comprising a zinc surface coated with zirconium oxide conversion coating by, prior to conversion coating, contacting the zinc surface with a composition comprising: a) iron(III) ions, b) a source of hydroxide ion; c) at least one complexing agent selected from organic compounds which have at least one functional group —COOX, wherein X represents either a H or an alkali and/or alkaline earth metal; d) 0.0 to about 4 g/l cobalt (II) ions; and optionally e) a source of silicate: wherein the composition has a pH of at least 10.

Abstract: A coating system for a turbine engine component having a substrate includes a multi-layer bond coat applied to the substrate. The multi-layer bond coat has an oxidation resistant layer and a spallation resistant layer deposited over the oxidation resistant layer. Processes for forming the coating system are described.

Abstract: A high-temperature resistant component for, e.g., a gas turbine hot part, includes an alloy substrate containing Ni, Co, or Fe as the principal component, and a thermal barrier coating formed over the surface of the substrate via a bond coat. The thermal barrier coating includes a porous thermal-barrier layer made of ceramic and an environmental barrier layer with corrosion resistance. An impregnated layer is provided between the environmental barrier layer and the thermal barrier layer. In the impregnated layer, the thermal barrier layer is impregnated with a part of the environmental barrier layer. The thermal barrier layer is made of a porous zirconia layer, and the environmental barrier layer includes silica as the principal component. The porous zirconia layer has pores impregnated with the part of the environmental barrier layer. As a result, the high-temperature resistant component has excellent corrosion resistance and excellent heat resistance.

Abstract: The present invention provides a steel sheet for a can exhibiting excellent corrosion resistance, adhesive properties, and weldability, including a steel sheet, an Ni—Cu alloy plating layer formed on at least one surface of the steel sheet; and a chromate film layer formed on a surface of the Ni—Cu alloy plating layer, in which the Ni—Cu alloy plating layer has Ni attached thereto in an amount of from 0.30 g/m2 to 3.0 g/m2, and Cu contained therein in an amount of from 0.5 mass % to 20 mass %; and the chromate film layer has Cr attached thereto in an amount of from 1.0 mg/m2 to 40 mg/m2 in equivalent units of Cr.

Abstract: An article includes a substrate; and a color layer deposited on the substrate, wherein the color layer has an L* value between about 28 to about 32, an a* value between about ?1 to about 1, and a b* value between about ?1 to about 1 in the CIE L*a*b* color space.

Abstract: A spark plug superior in salt corrosion resistance and stress corrosion cracking resistance is provided. The park plug includes a metallic shell coated with a composite layer which includes a nickel plating layer and a chromate layer formed on the nickel plating layer. The spark plug is characterized in that the nickel plating layer has a thickness A which satisfies a relational expression 3 ?m?A?15 ?m and that the chromate layer has a thickness B which satisfies a relational expression 2 nm?B?45 nm.

Abstract: A seed film and methods incorporating the seed film in semiconductor applications is provided. The seed film includes one or more noble metal layers, where each layer of the one or more noble metal layers is no greater than a monolayer. The seed film also includes either one or more conductive metal oxide layers or one or more silicon oxide layers, where either layer is no greater than a monolayer. The seed film can be used in plating, including electroplating, conductive layers, over at least a portion of the seed film. Conductive layers formed with the seed film can be used in fabricating an integrated circuit, including fabricating capacitor structures in the integrated circuit.

Abstract: The present invention provides a display device which is provided with a Cu alloy film having high adhesion to an oxygen-containing insulator layer and a low electrical resistivity. The present invention relates to a Cu alloy film for a display device, said film having a stacked structure including a first layer (Y) composed of a Cu alloy containing, in total, 1.2-20 atm % of at least one element selected from among a group composed of Zn, Ni, Ti, Al, Mg, Ca, W, Nb and Mn, and a second layer (X) composed of pure Cu or a Cu alloy having Cu as a main component and an electrical resistivity lower than that of the first layer (Y). A part of or the whole first layer (Y) is directly in contact with an oxygen-containing insulator layer (27), and in the case where the first layer (Y) contains Zn or Ni, the thickness of the first layer (Y) is 10-100 nm, and in the case where the first layer (Y) does not contain Zn and Ni, the thickness of the first layer (Y) is 5-100 nm.

Abstract: A article made by vacuum deposition, includes a substrate; and a color layer deposited on the substrate, wherein the color layer has an L* value between about 75 to about 80, an a* value between about ?5 to about ?10, and a b* value between about 15 to about 20 in the CIE LAB color space.

Abstract: A method for applying a protective coating to gas turbine engine components using a saturated solution of nickel acetate tetrahydrate, applying a uniform thickness of the coating onto the thermal barrier coating of selected components, and heat treating the coated component in air at a temperature sufficient to form a protective layer of NiO. The saturated NiO solution has sufficient solubility to penetrate into the microscopic cracks of the thermal barrier coating to form a “sacrificial mitigation layer” of NiO that substantially inhibits the reaction between vanadium pentoxide and yttria-stabilized compounds present in the thermal barrier coating.

Abstract: A process is disclosed for applying a heat shielding coating system on a metallic substrate. The coating system comprises at least three individual layers selected from the group of barrier layer, hot gas corrosion protection layer, protection layer, heat barrier layer, and smoothing layer. The coating system is applied to the metallic substrate by low pressure plasma spraying in a single operation cycle. This process enables the layers to be applied in an arbitrary sequence. The process is preferably used in applying a coating system to a turbine blade, particularly a stator or a rotor blade of a stationary gas turbine or of an aircraft engine, or to another component in a stationary or aircraft turbine that is subjected to hot gas.

Abstract: A coated article is described. The coated article includes a substrate, a combining layer formed on the substrate, a plurality of titanium dioxide layers and a plurality of copper-zinc alloy layers formed on the combining layer. The combining layer is a titanium layer. Each titanium dioxide layer interleaves with one copper-zinc alloy layer. A method for making the coated article is also described.

Abstract: A coated article includes a substrate, an anti-corrosion layer formed on the substrate, and a decorative layer formed on the anti-corrosion layer. The anti-corrosion layer is an amorphous alloy layer containing elements of iron, chromium, boron and M, wherein M is one or more selected from the group consisting of phosphorus, carbon and silicon. A method for making the coated article is also described.

Abstract: Disclosed is a method for the cathodic electrocoating of a tin-coated steel sheet in a treatment solution that does not contain any Cr compound, F or nitrite nitrogen. In the method, a tin oxide layer that is not subjected to a cathodic electrocoating treatment yet and is arranged on a tin-coated steel sheet is thinned to a specified thickness or less by a cathodic electrocoating treatment in an aqueous solution containing sodium carbonate or sodium hydrogen carbonate or a aqueous sulfuric acid solution immersion treatment, and the tin oxide layer is subjected to a cathodic electrocoating treatment in an aqueous solution of an alkaline metal sulfate containing a zirconium compound having a specified composition. In this manner, a coating film is formed on the tin oxide layer at a specific adhered amount in terms of Zr content.

Abstract: An article of manufacture and a process for making the article by the anodization of aluminum and aluminum alloy workpieces to provide corrosion-, heat- and abrasion-resistant ceramic coatings comprising titanium and/or zirconium oxides, and the subsequent coating of the anodized workpiece with polytetrafluoroethylene (“PTFE”) or silicone containing coatings. The invention is especially useful for forming longer life PTFE coatings on aluminum substrates by pre-coating the substrate with an anodized layer of titanium and/or zirconium oxide that provides excellent corrosion-, heat- and abrasion-resistance in a hard yet flexible film.

Abstract: Provided is a spark plug that is excellent not only in salt resistance but also in stress corrosion cracking resistance. The spark plug includes a metal shell covered by a composite layer including a nickel plating layer and a chromate layer formed on the nickel plating layer. The chromate layer has a film thickness of 2 to 45 nm and Cr element concentration of not more than 60 at % and contains Ni in addition to Cr.

Abstract: [Problem to be Solved] There is provided a highly wear-resistant and durable sliding contact material applicable to a commutator of a motor used for high-capacity applications in which the initial starting current (IS) is 1 ampere or higher. [Solution] The present invention provides a sliding contact material in which metal oxide particles are dispersed in an Ag alloy matrix, wherein the Ag alloy matrix is an Ag alloy containing 0.01 to 10.0 wt % of at least one kind of Fe, Co, Ni and Cu in Ag, and 0.1 to 3.0 wt % of a Ta oxide is dispersed as the metal oxide. In the present invention, 0.1 to 10.0 wt % of metal oxide particles of one kind or two or more kinds of Mg, Fe, Co, Ni and Zn may further be dispersed. The sliding contact material is used in a mode of clad composite material formed by embedding the sliding contact material in a part of a base material consisting of Cu or Cu alloy.

Abstract: A component assembly for use in living tissue comprises: a ceramic part; a metal part, e.g., a titanium metal; and a palladium (Pd) interlayer for bonding said ceramic part to the metal part. By applying sufficient heat to liquify a palladium-titanium interface, the Pd interlayer is used to braze the ceramic part to the titanium part to yield a hermetic seal.

Abstract: An insulating metal substrate is used for a semiconductor device such as a solar cell. The substrate includes a metal base made of steel, iron-based alloy steel or titanium, an aluminum layer and an insulating layer obtained by anodizing aluminum. An alloy layer primarily made of an alloy of a composition expressed by Al3X (where X is at least one kind of element selected from Fe, Cr, and Ti) exists in an interface between the metal base and the aluminum layer, and has a thickness of 0.01 to 10 micrometers. The aluminum layer has a thickness of 1 micrometer or more and equal to or less than a thickness of the metal base.

Abstract: Coatings suitable for use as protective oxide-forming coatings on Nb-based substrates exposed to high temperatures and oxidative environments. The coatings contain chromium and/or molybdenum, preferably contains silicon, and optionally contains niobium, titanium, hafnium, iron, rhenium, tantalum, and/or tungsten, which in combination form multiple intermetallic phases, which in combination form one or more intermetallic phases that promote the formation of a slow-growing oxide scale. Depending on the particular coating composition, the intermetallic phases maybe: a silicon-modified Cr2Nb Laves phase and optionally a chromium solid solution phase, a CrNbSi intermetallic phase, and/or an M3Si intermetallic phase where M is niobium, titanium, and/or chromium; or M5Si3, MSi2 and/or M3Si2 where M is molybdenum, niobium, titanium, chromium, hafnium, iron, rhenium, tantalum, and/or tungsten.

Abstract: A formed component of an automobile and a method for its manufacture are disclosed. The formed component has a base body made of a metal sheet and a smaller, locally arranged reinforcement sheet. The gap between the base body and the reinforcement sheet is sealed in certain areas with a sealing mass made of enamel on an alkali-vanadium-silicate basis. The sealing mass may be applied by screen printing. The sealing mass is dried on the base sheet and/or on the reinforcement sheet, whereafter the reinforcement sheet is attached by welding in a region that is not covered by the sealing mass. The composite sheet formed from the base sheet and the reinforcement sheet is then heated to a forming temperature and hot-formed in a forming tool to the formed component and at least partially hardened.

Abstract: A housing having a coating is disclosed. The housing comprises a base substrate made of metallic material; a micro-arc oxide layer formed on the base substrate; and a protection outer film formed on the micro-arc oxide layer and comprising a coating layer and a metallic layer, wherein the metallic layer is formed on the micro-arc oxide layer and covers a portion of the micro-arc oxide layer; and the coating layer is formed on a remaining portion of the micro-arc oxide layer so that the micro-arc oxide layer is covered by the metallic layer and the coating layer.

Abstract: A device housing is provided. The device housing includes a substrate, a barrier layer formed on the substrate, an illuminating layer formed on the barrier layer, and a protective layer formed on the illuminating layer. The barrier layer is made of titanium. The illuminating layer is made of rare-earth aluminates. The protective layer is made of silica dioxide. A method for making the device housing is also described there.

Abstract: A coating system on a superalloy or silicon-containing substrate of an article exposed to high temperatures. The coating system includes a coating layer that overlies the substrate and is susceptible to hot corrosion promoted by molten salt impurities. A corrosion barrier coating overlies the coating layer and contains at least one rare-earth oxide-containing compound that reacts with the molten salt impurities to form a dense, protective byproduct barrier layer.

Abstract: A housing is provided which includes an aluminum or aluminum alloy substrate, an aluminum layer and a corrosion resistant layer formed on the aluminum or aluminum alloy substrate in that order. The corrosion resistant layer is an Al—O—N layer. Then, Nd ions is implanted in the Al—O—N layer by ion implantation process. The atomic percentages of N and O in the Al—O—N gradient layer gradually increase from nearing the aluminum or aluminum alloy substrate to far away from it. The housing has a higher corrosion resistant. A method for making the housing is also provided.

Abstract: A process for joining a stainless steel part and a zirconia ceramic part comprising: providing a SUS part, a ZrO2 ceramic part, a Mo foil and a Cu foil; depositing a nickel coating on a surface of the ZrO2 ceramic part; placing the ZrO2 ceramic part, the Mo foil, the Cu foil, and the SUS part into a mold, the Mo foil and the Cu foil located between the ZrO2 ceramic part and the SUS part; placing the mold into a chamber of a hot press sintering device, heating the chamber and pressing the SUS part with the nickel coating, the ZrO2 ceramic part, the Mo foil, and the Cu foil at least until the SUS part, the ZrO2 ceramic part, the Mo foil and the Cu foil form a integral composite article.

Abstract: A housing is provided which includes an aluminum or aluminum alloys substrate, an aluminum layer and a corrosion resistant layer formed on the aluminum or aluminum alloys substrate in that order. The corrosion resistant layer is an Al—O—N layer. Then, La ions is implanted in the Al—O—N layer by ion implantation process. The atomic percentages of N and O in the Al—O—N gradient layer gradually increase from the bottom of the layer near the aluminum or aluminum alloys substrate to the top of the layer away from aluminum or aluminum alloys substrate by physical vapor deposition. The housing has a higher corrosion resistance. A method for making the housing is also provided.

Abstract: A process for joining a stainless steel part and a zirconia ceramic part comprising: providing a SUS part, a ZrO ceramic part, a Mo foil and a Ni foil; placing the ZrO ceramic part, the Mo foil, the Ni foil, and the SUS part into a mold, the Mo foil and the Ni foil located between the ZrO ceramic part and the SUS part, the Mo foil abutting against the ZrO ceramic part, the Ni foil abutting against the SUS part and the Mo foil; placing the mold into a chamber of an hot press sintering device, heating the chamber and pressing the SUS part, the ZrO ceramic part, the Mo foil, and the Ni foil at least until the SUS part, the ZrO ceramic part, the Mo foil and the Ni foil form a integral composite article.

Abstract: A coated article includes a substrate and a color layer formed on the substrate. The substrate is made of aluminum or aluminum alloy. The color layer includes an aluminum layer formed on the substrate and an aluminum oxide layer formed on the aluminum layer. In the CIE LAB color system, L* coordinate of the color layer is between 75 and 100, a* coordinate of the color layer is between ?1 and 1, b* coordinate of the color layer is between ?1 and 1. The coated article has a white color.

Abstract: A double-sided substrate includes a ceramic substrate, a first metal layer formed on one surface of the ceramic substrate and having a plurality of subsidiary metal layers which are laminated on the surface of the ceramic substrate and whose purities differ from each other and a second metal layer formed on the other surface of the ceramic substrate, wherein the closer to the ceramic substrate any subsidiary metal layer is located, the lower purity the subsidiary metal layer has. Additionally, a semiconductor includes the above double-sided substrate, a power element and a heat sink.

Abstract: A zinc-based metal plated steel sheet is excellent in tribological properties during press forming. An oxide layer containing crystalline 3Zn(OH)2·ZnSO4·xH2O is formed on a plated surface. The oxide layer has a thickness of 10 nm or more. The crystalline oxide layer is composed of 3Zn(OH)2·ZnSO4·3-5H2O.

Abstract: A coating composition for zinc- and zinc alloy-coated steel sheets includes: 1 to 30% by weight of hypophosphorous acid, 0.1 to 10% by weight of manganese, 0.01 to 5% by weight of a polyvinyl compound, zinc oxide and the balance of water, and further comprises 20% by weight or less of alcohol, when necessary, wherein the zinc oxide is included in such a content that, when 50 Ml (milliliters) of the coating composition is neutralized and titrated with 0.1N NaOH, the NaOH used for the neutralization titration is present in an amount of 10.0 Ml (milliliters) or less, and a content of free acid in the coating composition is adjusted to such an amount that, when 50 Ml (milliliters) of the coating composition is neutralized and titrated with 0.1N NaOH, the NaOH used for the neutralization titration is present in an amount of 10.0 Ml (milliliters) or less.

Abstract: A process is described for coating parts (1) made of an aluminium alloy, in particular made of a die-cast aluminium alloy, comprising the steps of; pre-treating the parts (1); washing the pre-treated parts (1); and depositing the parts on at least one first layer (3) and at least one second layer (5), each one of the first and the second layer (3, 5) being composed of a mixture of two constituents with variable relative molar fractions: 1) a metallic material, and 2) an oxide-based material of an element of Group IVA of the Periodic Table. A part (1) made of an aluminium alloy is further described, made through the above process.

Abstract: Coated products are described comprising a metallic substrate, an aluminium-rich layer, a chromia-forming layer and a thermally insulating top coat. The chromia-forming layer is located between the substrate and the thermally-insulating top coat. The aluminium-rich layer is located between the substrate and the chromia-forming layer. The coating may be used to provide protection of parts exposed to conditions of relatively high temperatures, heat flux, and/or corrosive environments, such as the conditions in industrial gas turbines using poorer-quality fuels (such as bio-fuels).

Abstract: A process for joining a stainless steel part and a zirconia ceramic part comprising: providing a SUS part, a ZrO ceramic part, a Mo foil and a Ni foil; placing the ZrO ceramic part, the Mo foil, the Ni foil, and the SUS part into a mold, the Mo foil and the Ni foil located between the ZrO ceramic part and the SUS part, the Mo foil abutting against the ZrO ceramic part, the Ni foil abutting against the SUS part and the Mo foil; placing the mold into a chamber of an hot press sintering device, heating the chamber and pressing the SUS part, the ZrO ceramic part, the Mo foil, and the Ni foil at least until the SUS part, the ZrO ceramic part, the Mo foil and the Ni foil form a integral composite article.

Abstract: A film structure includes a metal substrate, a metal film formed on the metal substrate, an insulating transparent optical film formed on the metal film. The metal film eliminates an interference color of the optical film so that the color of the film structure is substantially the same as the metal substrate.

Abstract: The invention is directed to a material and method for obtaining a ceramic abradable system for high temperature applications. High purity partially stabilized zirconia and/or hafnia base material has higher sintering resistance compared to conventional 6-9 weight percent yttria stabilized zirconia systems. The benefits of these systems are higher service lifetime and low thermal conductivity to achieve high operating temperatures. System includes a superalloy substrate, oxidation resistant bond coat and a thick ceramic abradable top coat. Total coating thickness is about 0.5-5 mm. In some applications an intermediate layer of high purity partially stabilized zirconia or a partially stabilized YSZ/MCrAlY cermet is applied over the oxidation resistant bond coat. In other applications an abradable system is applied on top of a grid. Additional benefits should be reduced blade wear at high operating conditions.