Next To Fe-base Component (e.g., Galvanized) Patents (Class 428/659)
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Publication number: 20140302343Abstract: Steel strip provided with a hot dip galvanized zinc alloy coating layer, in which the coating of the steel strip is carried out in a bath of molten zinc alloy, the zinc alloy in the coating of: 0.3-2.3 weight % magnesium; 0.6-2.3 weight % aluminium; optional <0.2 weight % of one or more additional elements; unavoidable impurities; the remainder being zinc in which the zinc alloy coating layer has a thickness of 3-12 ?m.Type: ApplicationFiled: June 18, 2014Publication date: October 9, 2014Inventors: Theodorus Franciscus Jozef MAALMAN, Robert BLEEKER, Margot Julia VLOT
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Patent number: 8852753Abstract: The present invention provides a galvanized steel sheet including: a steel sheet; and a galvanizing layer provided on a surface of the steel sheet; wherein the galvanizing layer includes an amorphous coating layer having an inorganic oxoacid salt and metallic oxide on a surface layer of the galvanizing layer; the galvanizing layer includes a ? phase and a ?1 phase; the galvanizing layer includes, by mass, 8 to 13% of Fe; Zn in the metallic oxide exists up to an outermost surface layer of the amorphous layer; and an X-ray diffraction intensity ratio I, which is obtained by dividing an X-ray diffraction intensity of the ? phase at d=0.126, after removing background intensity, by an X-ray diffraction intensity of the ?1 phase at d=0.126, after removing background intensity, is 0.06 to 0.35.Type: GrantFiled: July 9, 2010Date of Patent: October 7, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Kenichiroh Matsumura, Makoto Nakazawa, Masahiro Yui, Takehiro Takahashi
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Publication number: 20140295210Abstract: A hot rolled steel sheet includes a composition including: C: 0.03% to less than 0.07%; Si: 0.3% or less; Mn: 0.5% to 2.0%; P: 0.025% or less; S: 0.005% or less; N: 0.0060% or less; Al: 0.1% or less; Ti: 0.07% to 0.11%; and V: 0.08% to less than 0.15% on a mass percent basis, such that Ti and V contents satisfy: 0.18?Ti+V?0.24 (where Ti and V are contents of the elements (by mass %)), the balance including Fe and inevitable impurities, a matrix having a ferrite phase with an area ratio of 95% or more; and a structure where fine carbide is dispersedly precipitated in the matrix, the fine carbide containing Ti and V has an average particle size of less than 10 nm, and a volume fraction of the fine carbide is 0.0020 or more, wherein the steel sheet has a tensile strength of 780 MPa or more.Type: ApplicationFiled: November 6, 2012Publication date: October 2, 2014Inventors: Tamako Ariga, Yoshimasa Funakawa, Noriaki Moriyasu
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Publication number: 20140287263Abstract: There is provided a high-strength hot-dip galvanized steel sheet and the like excellent in mechanical cutting property, which are capable of obtaining high ductility while ensuring high strength with maximum tensile strength of 900 MPa or more. The high-strength hot-dip galvanized steel sheet has a sheet thickness of 0.6 to 5.0 mm and has a plating layer on a surface of a steel sheet with component compositions being set in appropriate ranges, in which the steel sheet structure contains a 40 to 90% ferrite phase and a 3% or more retained austenite phase by volume fraction. In the retained austenite phase, a solid solution carbon amount is 0.70 to 1.00%, an average grain diameter is 2.0 ?m or less, an average distance between grains is 0.1 to 5.0 ?m, a thickness of a decarburized layer in a steel sheet surface layer portion is 0.01 to 10.0 ?m, an average grain diameter of oxides contained in the steel, sheet surface layer portion is 30 to 120 nm and an average density thereof is 1.Type: ApplicationFiled: September 28, 2012Publication date: September 25, 2014Inventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Takeshi Yasui, Takuya Kuwayama, Hiroyuki Ban, Kaoru Hiramatsu
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Publication number: 20140255724Abstract: A high-strength hot-dip galvanized steel sheet which includes a steel sheet that comprises major components and that contains at least 40 vol. % the sum of bainite and martensite, 8-60 vol. % retained austenite, and less than 40 vol. % ferrite, with the remainder comprising an incidental structure. The hot-dip galvanized steel sheet has, at the interface between the deposit layer formed by hot-dip galvanization and the base steel sheet, an intermetallic compound constituted of Fe, Al, Zn, and incidental impurities and having an average thickness of 0.1-2 ?m, the intermetallic compound having a crystal grain diameter of 0.01-1 ?m. After the deposit layer formed by hot-dip galvanization was removed, the surface of the base steel sheet has an arithmetic average roughness Ra of 0.1-2.0 ?m and gives a roughness curve in which the contour elements have an average length RSm of 5-300 ?m.Type: ApplicationFiled: September 28, 2012Publication date: September 11, 2014Inventors: Shintaro Yamanaka, Soshi Fujita, Koichi Sato
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Publication number: 20140255723Abstract: Hard beads can be formed in a single piece of sheet steel to enhance its strength before or after stamping. The hard beads are formed by melting and re-solidifying it in small discrete volumes. The melting can be performed by applying heat from a heat source; for example, a laser beam, an electron beam, a high temperature flame etc. The re-solidified volume of steel is the hard bead which is stronger than the remaining base steel. Preferably, the hard bead can be formed to have an elongated shape; and the tensile strength of the single piece of sheet steel is enhanced in the direction the bead is elongated. Hard beads thus formed can be arranged in a suitable pattern to meet a strength requirement of a part.Type: ApplicationFiled: March 10, 2013Publication date: September 11, 2014Inventor: Mohammad Nasim Uddin
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Publication number: 20140255725Abstract: A high-strength alloyed hot-dip galvanized steel sheet obtained by subjecting the surface of a high-strength steel sheet to alloyed hot-dip galvanization, and formed from a steel sheet containing, in mass %, main components, and containing at least 40 vol % bainite and/or martensite, 8-60 vol % retained austenite, and less than 40 vol % ferrite, with the remainder comprising unavoidable structures. In the alloyed hot-dip galvanized steel sheet, the total thickness of the Gamma1 layer and the Gamma layer (Tgamma1+Tgamma) is 2 ?m or less in the alloy layers formed by hot-dip galvanization, and the Gamma1 phase/Gamma phase thickness ratio (Tgamma1/Tgamma) is 1 or less. A tensile strength of 980 MPa or above can be easily imparted to the alloyed hot-dip galvanized steel sheet. The alloyed hot-dip galvanized steel sheet has excellent coating adherence, and coating separation during machining can be suppressed.Type: ApplicationFiled: September 28, 2012Publication date: September 11, 2014Inventors: Shintaro Yamanaka, Soshi Fujita, Koichi Sato
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Patent number: 8828557Abstract: A high strength galvanized steel sheet including all in mass %, C: 0.05% to <0.12%, Si: 0.35% to <0.80%, Mn: 2.0 to 3.5%, P: 0.001 to 0.040%, S: 0.0001 to 0.0050%, Al: 0.005 to 0.1%, N: 0.0001 to 0.0060%, Cr: 0.01% to 0.5%, Ti: 0.010 to 0.080%, Nb: 0.010 to 0.080%, and B: 0.0001 to 0.0030%, optionally one or more of Mo: 0.01 to 0.15%, Ca: 0.0001 to 0.0050%, REM: 0.0001 to 0.1%, and Sb: 0.0001 to 0.1%, and Fe and unavoidable impurities as the balance, has a microstructure containing a ferrite phase with a volume fraction in a range of 20 to 70% and an average grain diameter equal to or smaller than 5 ?m, and has a galvanized layer on a surface thereof at a coating weight (per side) of 20 to 150 g/m2.Type: GrantFiled: April 27, 2010Date of Patent: September 9, 2014Assignee: JFE Steel CorporationInventors: Shusaku Takagi, Kohei Hasegawa
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Patent number: 8828556Abstract: Disclosed is a pipe made of an iron-base material, having a corrosion prevention layer formed on the surface thereof. The corrosion prevention layer includes a Zn—Sn sprayed coating including Sn in a content of more than 1% by mass and less than 50% by mass and the balance composed of Zn. Alternatively, the corrosion prevention layer includes a Zn—Sn—Mg sprayed coating including Sn in a content of more than 1% by mass and less than 50% by mass, Mg in a content of more than 0.01% by mass and less than 5% by mass and the balance composed of Zn. Preferably, the sprayed coating of the corrosion prevention layer includes at least any one of Ti, Co, Ni and P, and the content of each of these elements is more than 0.001% by mass and less than 3% by mass.Type: GrantFiled: March 18, 2009Date of Patent: September 9, 2014Assignee: Kuboto CorporationInventors: Hiroaki Shimizu, Goro Funahashi, Hiroaki Fujii
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Publication number: 20140242415Abstract: Provided is a high-strength hot-dip galvanized steel sheet having small material anisotropy and excellent formability with an ultimate tensile strength of 980 MPa or more. The hot-dip galvanized steel sheet includes a hot-dip galvanized layer formed on a surface of a base steel plate. The base steel plate contains, by mass %, C: 0.1 to less than 0.40%, Si: 0.5 to 3.0%, Mn: 1.5 to 3.0%, O: limited to 0.006% or less, P: limited to 0.04% or less, S: limited to 0.01% or less, Al: limited to 2.0% or less, N: limited to 0.01% or less, and a balance including Fe and inevitable impurities. A microstructure of the base steel sheet contains ferrite of 40% or more, residual austenite of 8 to less than 60%, by volume fraction, and a balance being bainite or martensite. In a sheet thickness range of ? to ? from the surface of the base steel sheet, a pole density of specific crystal orientation is within a predetermined range.Type: ApplicationFiled: September 28, 2012Publication date: August 28, 2014Inventors: Masafumi Azuma, Chisato Wakabayashi, Takayuki Nozaki, Nobuhiro Fujita, Manabu Takahashi
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Publication number: 20140242416Abstract: A high strength pressed member has excellent ductility and stretch flangeability and tensile strength of 780-1400 MPa, with a predetermined steel composition and steel microstructure relative to the entire microstructure of steel sheet, where area ratio of martensite 5-70%, area ratio of retained austenite 5-40%, area ratio of bainitic ferrite in upper bainite 5% or more, and total thereof is 40% or more, 25% or more of martensite is tempered martensite, polygonal ferrite area ratio is above 10% and below 50% to the entire microstructure of steel sheet, and average grain size is 8 ?m or less, average diameter of a group of polygonal ferrite grains is 15 ?m or less, the group of polygonal ferrite grains represented by a group of ferrite grains of adjacent polygonal ferrite grains, and average carbon content in retained austenite is 0.70 mass % or more and tensile strength is 780 MPa or more.Type: ApplicationFiled: October 2, 2012Publication date: August 28, 2014Inventors: Hiroshi Matsuda, Yoshimasa Funakawa, Kaneharu Okuda, Kazuhiro Seto
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Publication number: 20140242414Abstract: The present invention provides a high-strength steel sheet excellent in shape fixability. The high-strength steel sheet contains C, Si, Mn, P, S, Al, N, and O with predetermined contents, in which a retained austenite phase of 5 to 20% in volume fraction is contained, an amount of solid-solution C contained in the retained austenite phase is 0.80 to 1.00% in mass %, WSi? is 1.10 times or more WSi*, WMn? is 1.10 times or more WMn*, and when a frequency distribution is measured with respect to a sum of a ratio between WSi and WSi* and a ratio between WAl and WAl*, a mode value of the frequency distribution is 1.95 to 2.05, and a kurtosis is 2.00 or more.Type: ApplicationFiled: July 27, 2012Publication date: August 28, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Akinobu Minami, Hiroyuki Kawata, Akinobu Murasato, Yuji Yamaguchi, Natsuko Sugiura, Takuya Kuwayama, Naoki Maruyama, Takamasa Suzuki
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Patent number: 8815026Abstract: A high strength galvanized steel sheet having a TS of 780 MPa or more and exhibiting excellent stretch frangeability and bendability and a method for manufacturing the same are provided. The component composition contains C: 0.05% to 0.15%, Si: 0.8% to 2.5%, Mn: 1.5% to 3.0%, P: 0.001% to 0.05%, S: 0.0001% to 0.01%, Al: 0.001% to 0.1%, N: 0.0005% to 0.01%, Cr: 0.1% to 1.0%, Ti: 0.0005% to 0.1%, B: 0.0003% to 0.003%, and the remainder composed of iron and incidental impurities, on a percent by mass basis. The microstructure includes 30% or more of ferrite phase and 30% or more, and 70% or less of martensite phase on an areal fraction basis, wherein regarding the above-described martensite phase, the proportion of a tempered martensite phase is 20% or more relative to the whole martensite phase and the proportion of a martensite phase having a grain diameter of 1 ?m or less is 10% or less relative to the whole martensite phase.Type: GrantFiled: December 12, 2008Date of Patent: August 26, 2014Assignee: JFE Steel CorporationInventors: Shinjiro Kaneko, Yoshiyasu Kawasaki, Saiji Matsuoka, Yoshitsugu Suzuki, Koji Maitake
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Publication number: 20140234659Abstract: A hot-dip galvanizing layer or an alloyed hot dip galvanizing layer is formed on the surface of a base steel sheet in which in volume fraction, 40 to 90% of a ferrite phase and 5% or less of a retained austenite phase are contained, and a ratio of non-recrystallized ferrite to the entire ferrite phase is 50% or less in volume fraction, and further a grain diameter ratio being a value of, of crystal grains in the ferrite phase, an average grain diameter in the rolling direction divided by an average grain diameter in the sheet width direction is 0.75 to 1.33, a length ratio being a value of, of hard structures dispersed in island shapes, an average length in the rolling direction divided by an average length in the sheet width direction is 0.75 to 1.33, and an average aspect ratio of inclusions is 5.0 or less.Type: ApplicationFiled: September 28, 2012Publication date: August 21, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Takeshi Yasui, Takuya Kuwayama, Hiroyuki Ban, Kaoru Hiramatsu
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Publication number: 20140234657Abstract: A hot-dip galvanized steel sheet includes: a steel sheet; and a plated layer on a surface of the steel sheet, a microstructure contains, by volume fraction, equal to or more than 20% and equal to or less than 99% in total of one or two of martensite and bainite, a residual structure contains one or two of ferrite, residual austenite of less than 8% by volume fraction, and pearlite of equal to or less than 10% by volume fraction, tensile strength is equal to or greater than 980 MPa, the plated layer is a hot-dip galvanized layer which contains oxides including one or two or more of Si, Mn, and Al, contains equal to or less than 15 mass % of Fe, and a remainder including Zn, Al, and unavoidable impurities, and when a cross section including the steel sheet and the hot-dip galvanized layer is seen in a sheet thickness direction, a projected area ratio is equal to or more than 10% and equal to or less than 90%.Type: ApplicationFiled: September 28, 2012Publication date: August 21, 2014Inventors: Masafumi Azuma, Chisato Wakabayashi, Takayuki Nozaki, Manabu Takahashi, Nobuhiro Fujita
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Publication number: 20140234656Abstract: A steel sheet which uses steel sheet which contains the easily oxidizable elements Si and Mn as a base material and which is provided with a hot dip galvanized layer which is excellent in plating wettability and plating adhesion and a method of production of the same are provided. A hot dip galvanized steel sheet which is comprised of a steel sheet having a hot dip galvanized layer A on the surface of the steel sheet, characterized by having the following B layer right under the steel sheet surface and in the steel sheet: B layer: Layer which has thickness of 0.001 ?m to 0.5 ?m, which contains, based on mass of the B layer, one or more of Fe, Si, Mn, P, S, and Al oxides in a total of less than 50 mass %, which contains C, Si, Mn, P, S, and Al not in oxides in C: less than 0.05 mass %, Si: less than 0.1 mass %, Mn: less than 0.5 mass %, P: less than 0.001 mass %, S: less than 0.001 mass %, and Al: less than 0.005 mass % and which contains Fe not in oxides in 50 mass % or more.Type: ApplicationFiled: September 28, 2012Publication date: August 21, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Soshi Fujita, Shintaro Yamanaka, Koichi Sato
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Publication number: 20140234655Abstract: A high-strength hot-dip galvanized steel sheet has excellent workability, namely, excellent ductility and hole expansion formability, and high yield ratio. The steel sheet has a chemical composition containing by mass %: C: 0.05-0.15%; Si: 0.10-0.90%; Mn: 1.0-1.9%; P: 0.005-0.10%; S: 0.0050% or less; Al: 0.01-0.10%; N: 0.0050% or less; Nb: 0.010-0.100%; and the balance being Fe and incidental impurities, in which: the steel sheet has a complex phase that includes: ferrite having an average crystal grain size of 15 ?m or less to at least 90% in volume fraction; martensite having an average crystal grain size of 3.0 ?m or less to 0.5% or more and less than 5.0% in volume fraction; pearlite to 5.0% or less in volume fraction; and the balance being a phase generated at low temperature.Type: ApplicationFiled: September 27, 2012Publication date: August 21, 2014Inventors: Katsutoshi Takashima, Yuki Toji, Nobusuke Kariya, Kohei Hasegawa
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Publication number: 20140234658Abstract: A galvanized steel sheet includes a steel sheet and a plating layer on the surface of the steel sheet, in which the steel sheet includes, as a steel chemical composition, by mass %, C: 0.05 to 0.40%, Si: 0.5 to 3.0% and Mn: 1.5 to 3.0%, a microstructure of the steel sheet includes ferrite, bainite, by volume fraction, 30% or more of a tempered martensite, and 8% or more of an austenite, and tensile strength of the steel sheet is 980 MPa or more, and the plating layer includes an oxide including at least one chemical element selected from Si, Mn and Al, and when seen at a cross section including the steel sheet and the plating layer in a plate thickness direction, a projection area fraction of the oxide is 10% or more.Type: ApplicationFiled: September 28, 2012Publication date: August 21, 2014Inventors: Takayuki Nozaki, Manabu Takahashi, Nobuhiro Fujita, Masafumi Azuma, Chisato Wakabayashi
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Publication number: 20140234660Abstract: Steel contains each of C, Si, Mn, P, S, Al, N, O, at a range from ? thickness centered around a ¼ sheet thickness from a surface to ? thickness centered around the ¼ sheet thickness from the surface at a base steel sheet, a structure of the base steel sheet contains, in volume fraction, 3% or more of a retained austenite phase, 50% or less of a ferrite phase, and 40% or more of a hard phase, average dislocation density is 5×1013/m2 or more, solid-solution C amount contained in the retained austenite phase is in mass % 0.70 to 1.00%, X-ray random intensity ratio of FCC iron in an texture of the retained austenite phase is 3.0 or less, ratio between a grain diameter relative to a rolling direction and a grain diameter relative to a sheet width direction of the retained austenite phase is 0.75 to 1.33.Type: ApplicationFiled: September 28, 2012Publication date: August 21, 2014Inventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Takeshi Yasui, Takuya Kuwayama, Hiroyuki Ban, Kaoru Hiramatsu
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Publication number: 20140234654Abstract: The invention relates to a thermal spraying material (5) for the coating of a surface of a workpiece by means of a thermal spraying method, wherein the spraying material (5) contains zinc. The invention further relates to a thermal spraying method and to a thermally sprayed coating sprayed with the material (5).Type: ApplicationFiled: January 13, 2014Publication date: August 21, 2014Applicant: Sulzer Metco AGInventors: Arno Refke, Gerard Barbezat, Jacobus Cornelis Doesburg
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Publication number: 20140227555Abstract: A base steel sheet has a hot-dip galvanized layer formed on a surface thereof, in which, in a steel sheet structure in a range of ? thickness to ? thickness centered around ¼ thickness of a sheet thickness from a surface, a volume fraction of a retained austenite phase is 5% or less, and a total volume fraction of phases of bainite, bainitic ferrite, fresh martensite, and tempered martensite is 40% or more, an average effective crystal grain diameter is 5.0 ?m or less, a maximum effective crystal grain diameter is 20 ?m or less, and a decarburized layer with a thickness of 0.01 ?m to 10.0 ?m is formed on a surface layer portion, in which a density of oxides dispersed in the decarburized layer is 1.0×1012 to 1.0×1016 oxides/m2, and an average grain diameter of the oxides is 500 nm or less.Type: ApplicationFiled: September 28, 2012Publication date: August 14, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Takeshi Yasui, Takuya Kuwayama, Hiroyuki Ban, Kaoru Hiramatsu
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Publication number: 20140227556Abstract: A high-strength hot-dip galvanized steel sheet containing a main component, the steel sheet having at least 40 wt. % of ferrite as a main phase in terms of the volumetric ratio, and 8-60% inclusive of residual austenite, the remaining structure comprising one or more of bainite, martensite, or pearlite. Austenite particles within a range where the average residual stress (sigmaR) thereof satisfies the expression ?400 MPa<=sigmaR<=200 MPa (formula (1)) are present in an amount of 50% or more in the hot-dip galvanized steel sheet. The surface of the steel sheet has a hot-dip galvanized layer containing less than 7 wt. % of Fe, the remainder comprising Zn, Al and inevitable impurities.Type: ApplicationFiled: September 28, 2012Publication date: August 14, 2014Inventors: Koichi Sato, Shintaro Yamanaka, Soshi Fujita
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Publication number: 20140227553Abstract: Disclosed are a preparation method of a steel product capable of local reinforcement using laser heat treatment, and a heat hardened steel used in the method. According to the present invention, the preparation method of a steel part comprises the following steps: (a) preparing a material comprising 0.1-0.5 wt % of C, 0.1-0.5 wt % of Si, 0.5-3.0 wt % of Mn, 0.1 wt % or less of P, 0.05 wt % or less of S, 0.01-1.0 wt % of Cr, 0.1 wt % or less of Al, 0.2 wt % or less of Ti, 0.0005-0.08 wt % of B, and the balance of Fe and inevitable impurities; (b) preparing a formed product by forming the material into a predetermined shape; and (c) locally reinforcing the high strength portion by carrying out laser heat treatment on a portion requiring high strength at the formed product.Type: ApplicationFiled: October 17, 2011Publication date: August 14, 2014Applicant: HYUNDAI HYSCOInventors: Hee-Joong Im, Seung-Man Nam, Bo-Ryong Lee, Kyung-Bo Kim, Youn-Il Jung
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Publication number: 20140227554Abstract: A galvannealed steel sheet having high corrosion resistance after painting includes, on a mass percent basis, C: 0.05% to 0.15%, Si: 0.1% to 1.0%, Mn: 0.5% to 2.7%, Al: 1.00% or less, P: 0.025% or less, S: 0.025% or less, and Cr: 0% to 0.8% or less as chemical components, the remainder being Fe and incidental impurities, wherein the galvannealed steel sheet includes a galvannealed layer on at least one surface of a steel sheet in an amount of 20 to 120 g/m2 per side, a percentage of exposed zinc metal of the galvannealed layer surface being 20% or more and less than 80%, and an amount of internal oxidation in a region disposed not more than 5 ?m from the surface of the steel sheet is 0.02 g/m2 or more and 0.1 g/m2 or less: Si?0.68%, Cr??1.25Si+0.85, and Si>0.68%, Cr=0, wherein Si and Cr denote respective contents (mass %) of Si and Cr.Type: ApplicationFiled: September 20, 2012Publication date: August 14, 2014Applicant: JFE Steel CorporationInventors: Yoshitsugu Suzuki, Mai Miyata, Yoichi Makimizu
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Patent number: 8802241Abstract: In an embodiment of a steel sheet having high Young's modulus, the steel can include in terms of mass %, e.g., C: 0.0005 to 0.30%, Si: 2.3% or less, Mn: 2.7 to 5.0%, P: 0.15% or less, 0.015% or less, Mo: 0.15 to 1.5%, B: 0.0006 to 0.01%, and Al: 0.15% or less, with the remainder being Fe and unavoidable impurities. One or both of {110}<223> pole density and {110}<111> pole density in the ? sheet thickness layer can be 10 or more, and a Young's modulus in a rolling direction can be more than 230 GPa. Other embodiments can include, e.g., Mn: 0.1 to 5.0%, N: 0.01% or less, and one or more of Mo: 0.005 to 1.5%, Nb: 0.005 to 0.20%, Ti: at least 48/14×N (mass %) and 0.2% or less, and B: 0.0001 to 0.01%, at a total content of 0.015 to 1.91 mass %.Type: GrantFiled: September 26, 2011Date of Patent: August 12, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Natsuko Sugiura, Naoki Yoshinaga, Shunji Hiwatashi, Manabu Takahashi, Koji Hanya, Nobuyoshi Uno, Ryoichi Kanno, Akihiro Miyasaka, Takehide Senuma
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Publication number: 20140220383Abstract: Provided are a high-strength hot-dip galvanized steel sheet having excellent formability and a tensile strength of 440 MPa or more and a method for manufacturing the same. A steel sheet has a microstructure containing a ferrite phase having an area fraction of 60% or more, a pearlite phase having an area fraction of 20% to 30%, and a bainite phase having an area fraction of 1% to 5%, the area fraction of a cementite phase present in a grain of the ferrite phase being 5% or less. Upon manufacture, a hot-rolled sheet or a cold-rolled sheet is heated to a temperature of 650° C. or higher at an average heating rate of 10° C./s or more, is held at a temperature of 700° C. to (Ac3-5)° C. for ten seconds or more, is cooled to a temperature of 300° C. to 500° C. at an average cooling rate of 10° C./s to 200° C./s, is held at a temperature of 300° C. to 500° C. for 30 seconds to 300 seconds, and is then hot-dip galvanized.Type: ApplicationFiled: August 1, 2012Publication date: August 7, 2014Applicant: JFE STEEL CORPORATIONInventors: Nobusuke Kariya, Shinjiro Kaneko, Yasunobu Nagataki
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Publication number: 20140220382Abstract: A high strength galvanized steel sheet excellent in coating adhesiveness is made from a base material that is a high strength steel sheet containing Si, Mn, and Cr. A method includes performing an oxidation treatment on steel containing Si, Mn, and Cr in an oxidation furnace under the condition that a selected exit temperature T, reduction annealing and a galvanizing treatment, or optionally, further an alloying treatment under conditions that heating is performed at a temperature of 460° C. or higher and 600° C. or lower for an alloying treatment time of 10 seconds or more and 60 seconds or less.Type: ApplicationFiled: June 6, 2012Publication date: August 7, 2014Applicant: JFE Steel CorporationInventors: Yoichi Makimizu, Yoshitsugu Suzuki, Hideki Nagano, Shinjiro Kaneko
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Publication number: 20140212684Abstract: The present invention provides a high-strength galvanized steel sheet with maximum tensile strength of 900 MPa or more. The high-strength galvanized steel sheet has an alloyed galvanized layer formed on a surface of a base steel sheet containing predetermined amounts of C, Si, Mn, P, S, Al, N, O with a balance being constituted of iron and inevitable impurities, in which in a structure of the base steel sheet, retained austenite is limited to 8% or less in volume fraction, kurtosis K* of the hardness distribution between 2% hardness and 98% hardness is ?0.30 or less, a ratio between Vickers hardness of surface layer of the base steel sheet and Vickers hardness of ¼ thickness of the base steel sheet is 0.35 to 0.70, and a content of iron in the alloyed galvanized layer is 8 to 12% in mass %.Type: ApplicationFiled: July 27, 2012Publication date: July 31, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Takeshi Yasui, Takuya Kuwayama, Shigeru Yonemura
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Publication number: 20140212687Abstract: A method of thermomechanical shaping a final product with very high strength including the steps of: providing a coated hot-rolled and/or cold-rolled steel strip or sheet including (all percentages in wt. %): 0.04%<carbon<0.5%, 0.5%<manganese<3.5%, silicon<1.0%, 0.01%<chromium<1%, titanium<0.2%, aluminium<0.2%, phosphorus<0.1%, nitrogen<0.015% N, sulphur<0.05%, boron<0.015%, unavoidable impurities, balance iron, the steel being coated with a zinc alloy coating layer, wherein the zinc alloy includes 0.3-4.0% Mg and 0.05-6.0% Al; optionally at most 0.2% of one or more additional elements; unavoidable impurities; the remainder being zinc; cutting the steel sheet to obtain a steel sheet blank; thermomechanical shaping of the steel sheet blank to a final product with its final properties.Type: ApplicationFiled: March 31, 2014Publication date: July 31, 2014Applicant: TATA STEEL IJMUIDEN B.V.Inventors: Margot Julia VLOT, Ronald Theodoor VAN TOL
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Publication number: 20140212686Abstract: A hot-dip galvanized cold-rolled steel sheet has a tensile strength of 750 MPa or higher, a composition consisting, in mass percent, of C: more than 0.10% and less than 0.25%, Si: more than 0.50% and less than 2.0%, Mn: more than 1.50% and 3.0% or less, and optionally containing one or more types of Ti, Nb, V, Cr, Mo, B, Ca, Mg, REM, and Bi, P: less than 0.050%, S: 0.010% or less, sol. Al: 0.50% or less, and N: 0.010% or less, and a main phase as a low-temperature transformation product and a second phase as retained austenite. The retained austenite volume fraction is more than 4.0% and less than 25.0% of the whole structure, and has an average grain size of less than 0.80 ?m. A number density of retained austenite grains having a grain size of 1.2 ?m or more is 3.0?10?2/?m2 or less.Type: ApplicationFiled: June 29, 2012Publication date: July 31, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Norio Imai, Masayuki Wakita, Takuya Nishio, Jun Haga, Kengo Hata, Yasuaki Tanaka, Mitsuru Yoshida, Hiroshi Takebayashi, Suguhiro Fukushima, Toshiro Tomida
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Publication number: 20140205858Abstract: A high strength hot dip galvanised steel strip having, in mass percent, the following elements: 0.13-0.19% C; 1.70-2.50% Mn; max 0.15% Si; 0.40-1.00% Al; 0.05-0.25% Cr; 0.01-0.05% Nb; max 0.10% P; max 0.004% Ca; max 0.05% S; max 0.007% N; and optionally at least one of the following elements: max 0.50% Ti, max 0.40% V, max 0.50% Mo, max 0.50% Ni, max 0.50% Cu, max 0.005% B, the balance being Fe and inevitable impurities; wherein 0.40%<Al+Si<1.05% and Mn+Cr>1.90%. This steel offers improved formability at a high strength, has a good weldability, and surface quality together with a good producability and coatability.Type: ApplicationFiled: September 12, 2012Publication date: July 24, 2014Applicant: TATA STEEL IJMUIDEN B.V.Inventor: Bernard Leo Ennis
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Publication number: 20140205855Abstract: [Summary] The present invention provides a high-strength steel sheet excellent in impact resistance. The high-strength steel sheet contains predetermined contents of C, Si, Mn, P, S, Al, Ti, N, and O, with the balance being iron and inevitable impurities, and has a steel sheet structure in which, in a ? thickness to ? thickness region across ¼ of a sheet thickness, 1 to 8% retained austenite is contained in volume fraction, an average aspect ratio of the retained austenite is 2.0 or less, an amount of solid-solution Mn in the retained austenite is 1.1 times an average amount of Mn or more, and TiN grains having a 0.5 ?m average grain diameter or less are contained, and a density of AlN grains with a 1 ?m grain diameter or more is 1.0 pieces/mm2 or less, wherein a maximum tensile strength is 900 MPa or more.Type: ApplicationFiled: July 27, 2012Publication date: July 24, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Hajime Hasegawa, Chisato Wakabayashi, Tsuyoshi Oki
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Patent number: 8785000Abstract: Steel strip provided with a hot dip galvanized zinc alloy coating layer, in which the coating of the steel strip is carried out in a bath of molten zinc alloy, the zinc alloy in the coating consisting of: 0.3-2.3 weight % magnesium; 0.6-2.3 weight % aluminum; optional <0.2 weight % of one or more additional elements; unavoidable impurities; the remainder being zinc in which the zinc alloy coating layer has a thickness of 3-12 ?m.Type: GrantFiled: June 23, 2005Date of Patent: July 22, 2014Assignee: Tata Steel Ijmuiden B.V.Inventors: Theodorus Franciscus Jozef Maalman, Robert Bleeker, Margot Julia Vlot
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Publication number: 20140193665Abstract: Provided are: a galvannealed steel sheet, reliably and sufficiently improved in the adhesiveness of a plated layer with a base steel sheet, as a galvannealed steel sheet, prepared by using a high-strength steel sheet as a base material; and a method for producing the galvannealed steel sheet. The galvannealed steel sheet wherein a galvannealed layer is formed on a base steel sheet including a high-strength steel having predetermined component composition; the average amount of Fe in the galvannealed layer is in a range of 8.0 to 12.0%; and the absolute value ?Fe of a difference between the amount of Fe in the vicinity of an interface with the base steel sheet (the amount of Fe in the vicinity of an internal side) and the amount of Fe in the vicinity of the external surface of the plated layer (the amount of Fe in the vicinity of an external side) in the plated layer is in a range of 0.0 to 3.0%.Type: ApplicationFiled: July 27, 2012Publication date: July 10, 2014Inventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Takeshi Yasui
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Publication number: 20140193667Abstract: A high-strength cold-rolled steel sheet having excellent stretch flangeability and precision punchability containing predetermined components and a balance being composed of iron and inevitable impurities, in which in a range of ? to ? in sheet thickness from the surface of the steel sheet, an average value of pole densities of the {100}<011> to {223}<110> orientation group represented by respective crystal orientations of {100}<011>, {116}<110>, {114}<110>, {113}<110>, {112}<110>, {335}<110>, and {223}<110> is 6.5 or less, and a pole density of the {332}<113> crystal orientation is 5.0 or less, and a metal structure contains, in terms of an area ratio, greater than 5% of pearlite, the sum of bainite and martensite limited to less than 5%, and a balance composed of ferrite.Type: ApplicationFiled: July 27, 2012Publication date: July 10, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Hiroshi Shuto, Nobuhiro Fujita, Tatsuo Yokoi, Riki Okamoto, Kazuaki Nakano, Shinichiro Watanabe
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Publication number: 20140186655Abstract: The present invention is to produce press hardened parts having excellent properties while avoiding a peeling of a plated layer or an intergranular cracking of a base material during a press forming, in such a manner that when a surface-treated steel sheet in which a Zn—Fe-based plated layer is formed on a surface of a base steel sheet is manufactured by a press hardening process, the forming is started after the surface-treated steel sheet is heated to a temperature that is not lower than an Ac1 transformation point of the base steel sheet and 950° C. or lower and the surface-treated steel sheet is then cooled to a temperature that is not higher than a solidifying point of the plated layer depending on the content of Fe in the plated layer.Type: ApplicationFiled: August 31, 2012Publication date: July 3, 2014Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Keisuke Okita, Shushi Ikeda, Junya Naitou
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Publication number: 20140170439Abstract: The present invention provides a cold rolled steel sheet. The steel sheet has a strength greater than 1000 MPa, a uniform elongation greater than 12% and a V-bendability greater than 90°. The composition of the steel sheet includes, expressed in per cent by weight, 0.15%?C?0.25%, 1.8%?Mn?3.0%, 1.2%?Si?2%, 0%?Al?0.10%, 0%?Cr?0.50%, 0%?Cu?1%, 0%?Ni?1%, 0%?S?0.005%, 0%?P?0.020%, Nb?0.015%, Ti?0.020%, V?0.015%, Co?1%, N?0.008%, B?0.001% whereby Mn+Ni+Cu?3%. The remainder of the composition consists of iron and inevitable impurities resulting from processing. The microstructure includes, in area percentage, 5 to 20% polygonal ferrite, 10 to 15% residual austenite, 5 to 15% martensite and a balance of bainite. The bainite is in the form of laths and includes carbides between the laths. A number N of inter-lath carbides larger than 0.1 micrometers per unit of surface area is less than or equal to 50000/mm2. A fabrication method and a motor vehicle are also provided.Type: ApplicationFiled: May 3, 2012Publication date: June 19, 2014Inventors: Sebastien Allain, Jan Mahieu, Mickael Denis Crouvizier, Thierry Mastrorillo, Arnaud Hennion
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Publication number: 20140170440Abstract: High strength steel sheet which secures tensile maximum strength 900 MPa or more high strength while having excellent shapeability, which high strength steel sheet which is excellent in shapeability characterized by having a predetermined composition of ingredients, by the steel sheet structure including a ferrite phase and martensite phase, by the ratio of Cu particles incoherent with the bcc iron being 15% or more with respect to the Cu particles as a whole, by a density of Cu particles in the ferrite phase being 1.0×1018/m3 or more, and by an average particle size of Cu particles in the ferrite phase being 2.0 nm or more.Type: ApplicationFiled: July 27, 2012Publication date: June 19, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Masafumi Azuma, Takuya Kuwayama, Shigeru Yonemura
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Publication number: 20140170438Abstract: A steel sheet, in one example, a press-hardening steel sheet is provided. The steel sheet includes a substrate layer of steel and a corrosion protection layer. The corrosion protection layer is electrogalvanically applied to the substrate layer, which contains zinc and manganese with a component of at least 5% by weight.Type: ApplicationFiled: December 17, 2013Publication date: June 19, 2014Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Hartmut BAUMGART, Ronald SANDERS
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Publication number: 20140162088Abstract: High strength steel sheet and high strength galvanized steel sheet which are excellent in shapeability which secure a tensile maximum strength 900 MPa or more high strength while obtaining excellent ductility and stretch flangeability, which sheets have predetermined compositions of ingredients, have steel sheet structures which contain volume fraction 1 to 20% of residual austenite phases, and which have martensite transformation points of the residual austenite phases of ?60° C. or less.Type: ApplicationFiled: July 27, 2012Publication date: June 12, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Takeshi Yasui, Yuji Yamaguchi, Natsuko Sugiura
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Publication number: 20140162087Abstract: The invention relates to a method for enhancing a metallic coating on a steel strip or steel plate, the coating being melted by heating to a temperature above the melting temperature of the material of the coating, the heating taking place by irradiation of the surface of the coating with electromagnetic radiation having a high power density over a limited irradiation time of not more than 10 ?s, and the mandated irradiation time and the energy density introduced into the coating by the electromagnetic radiation being selected such that the coating melts completely over its entire thickness down to the boundary layer with the steel strip, thereby forming a thin alloy layer at the boundary layer between the coating and the steel strip.Type: ApplicationFiled: January 2, 2012Publication date: June 12, 2014Applicant: THYSSENKRUPP RASSELSTEIN GMBHInventors: Winfried Hoehn, Helmut Oberhoffer, Benjamin Johannes Liebscher, Reiner Sauer
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Publication number: 20140150930Abstract: The present invention relates to a hot press forming steel plate made of a composition comprising: 0.3-1.0 wt % of C; 0.0-4.0 wt % of Mn; 1.0-2.0 wt % of Si; 0.01-2.0 wt % of Al; 0.015 wt % or less of S; 0.01 wt % or less of N; and the remainder being Fe and unavoidable impurities. Further, the present. invention relates to a method for manufacturing the hot press forming steel plate, characterized by comprising the steps of: heating, to between 1100 and 1300° C., a steel slab having the composition; performing hot rolling finishing between. an Ar3 transformation point and 950° C.; and performing winding between MS and 720° C. Further, the present invention. relates to a hot press formed member characterized by having the composition, and having a dual phase microstructure made of bainite and residual austenite.Type: ApplicationFiled: July 15, 2011Publication date: June 5, 2014Inventors: Kyoo-Young Lee, Jin-Keun Oh, Jong-Sang Kim, Tae-Kyo Han
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Patent number: 8741078Abstract: The present invention relates to a hot dip galvanized steel sheet and a manufacturing method thereof. The hot dip galvanize steel sheet includes a steel sheet including a martensitic structure as a matrix, and a hot dip galvanized layer formed on the steel sheet. The steel sheet includes C of 0.05 wt % to 0.30 wt %, Mn of 0.5 wt % to 3.5 wt %, Si of 0.1 wt % to 0.8 wt %, Al of 0.01 wt % to 1.5 wt %, Cr of 0.01 wt % to 1.5 wt %, Mo of 0.01 wt % to 1.5 wt %, Ti of 0.001 wt % to 0.10 wt %, N of 5 ppm to 120 ppm, B of 3 ppm to 80 ppm, an impurity, and the remainder of Fe.Type: GrantFiled: September 23, 2009Date of Patent: June 3, 2014Assignee: Postech Academy-Industry FoundationInventors: Tae-Jin Song, Han-Soo Kim, Jai-Hyun Kwak, Bruno C. De Cooman
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Publication number: 20140147697Abstract: An apparatus for producing annealed steels and annealed steels produced thereby.Type: ApplicationFiled: July 15, 2012Publication date: May 29, 2014Applicants: TATA STEEL NEDERLAND TECHNOLOGY BV, TATA STEEL IJMUIDEN BVInventors: Basjan Berkhout, David Neal Hanlon, Steven Celotto, Gerardus Jacobus Paulussen, Jacques Pierre Jean Verberne
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Publication number: 20140141280Abstract: Provided is a high-strength steel sheet having good warm press formability and excellent strength and ductility after warm press forming, and a method for manufacturing such. The high-strength steel sheet has a tensile strength at room temperature not less than 780 MPa, a yield stress at a heating temperature range of 400° C. to 700° C. not more than 80% of the yield stress at room temperature, total elongation at the heating temperature range not less than 1.1 times the total elongation at room temperature, yield stress and total elongation after the steel sheet is heated to the heating temperature range, subjected to a strain of not more than 20%, and cooled from the heating temperature to room temperature, not less than 70% of the yield stress and total elongation, respectively, at room temperature before the heating.Type: ApplicationFiled: July 11, 2012Publication date: May 22, 2014Applicant: JFE Steel CorporationInventors: Noriaki Kosaka, Yoshimasa Funakawa, Masato Shigemi, Hidekazu Okubo
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Publication number: 20140141279Abstract: A coated dual-phase steel and process for producing the coated dual-phase steel is provided. The process includes providing a steel slab with a desired chemistry, soaking the slab at an elevated temperature and then hot rolling the slab to produce hot-rolled strip. The hot-rolled strip is coiled and has a ferrite-pearlite microstructure. The coiled hot-rolled strip is cold-rolled into cold-rolled sheet with at least a 60% reduction in thickness compared to the thickness of the coiled hot-rolled strip. The cold-rolled sheet is subjected to an intercritical anneal followed by rapid cooling with the absence of an isothermal heat treatment or hold after rapid cooling near the molten metal pot temperature—during which, before or after which the steel is coated. The coated steel sheet has a dual-phase ferrite-martensite microstructure, a yield strength of at least 310 MPa, a tensile strength of at least 580 MPa and a total elongation to failure of at least 18%.Type: ApplicationFiled: November 20, 2013Publication date: May 22, 2014Applicant: THYSSENKRUPP STEEL USA, LLCInventors: Ranbir Jamwal, Joseph Frimpong, Bertram Wilhelm Ehrhardt, Harald Van Bracht, Roger Dale Boggs, Stanley Wayne Bevans
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Patent number: 8721809Abstract: A method of thermomechanical shaping a final product with very high strength including the steps of: providing a coated hot-rolled and/or cold-rolled steel strip or sheet including (all percentages in wt. %): 0.04%<carbon<0.5%, 0.5%<manganese<3.5%, silicon<1.0%, 0.01%<chromium<1%, titanium<0.2%, aluminum<0.2%, phosphorus<0.1%, nitrogen<0.015% N, sulphur<0.05%, boron<0.015%, unavoidable impurities, balance iron, the steel being coated with a zinc alloy coating layer, wherein the zinc alloy consists of 0.3-4.0% Mg and 0.05-6.0% Al; optionally at most 0.2% of one or more additional elements; unavoidable impurities; the remainder being zinc; cutting the steel sheet to obtain a steel sheet blank; thermomechanical shaping of the steel sheet blank to a final product with its final properties.Type: GrantFiled: February 22, 2008Date of Patent: May 13, 2014Assignee: Tata Steel Ijmuiden B.V.Inventors: Margot Julia Vlot, Ronald Theodoor Van Tol
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Patent number: 8722203Abstract: The invention relates to a steel part, the composition of the steel of which comprises, the contents being expressed by weight: 0.040%?C?0.100%; 0.80%?Mn?2.00%; Si?0.30%; S?0.005%; P?0.030%; 0.010% S?Al?0.070%; 0.015%?Nb?0.100%; 0.030% Ti?0.080%; N?0.009%; Cu?0.100%; Ni?0.100%; Cr?0.100%; Mo?0.100%; and Ca?0.006%, the balance of the composition consisting of iron and inevitable impurities resulting from the smelting, the microstructure of the steel consisting of at least 75% equiaxed ferrite, martensite in an amount not less than 5% but not exceeding 20%, and bainite in an amount not exceeding 10%.Type: GrantFiled: March 3, 2008Date of Patent: May 13, 2014Assignee: ArcelorMittal FranceInventors: Jean-Pierre Laurent, Thierry Malot
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Publication number: 20140127531Abstract: The present invention provides a high-corrosion-resistance hot-dip galvanized steel sheet having excellent appearance uniformity. The steel sheet includes: a coating layer containing Al: 4 to 22 mass %, Mg: 1 to 6 mass %, and Si: 0.001 to 1 mass %, and a balance being composed of Zn and inevitable impurities formed on a surface, in which at an interface between the coating layer and a base steel sheet, Mg2Si phases and Ca phases each mainly composed of Ca or a Ca compound exist, and at least part of the Mg2Si phases precipitate by using the Ca phases as a nucleus.Type: ApplicationFiled: June 29, 2012Publication date: May 8, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Takeshi Yasui, Tooru Oohashi, Nayuta Kamazu, Satoru Tanaka, Akio Saito
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Patent number: 8715837Abstract: A black-coated steel sheet exhibits good bendability and a good appearance after press working is provided. Zinc based plating layers, a chromium-free chemical conversion coating disposed on the zinc based plating layer, and a colored single organic coating which is disposed on the chemical conversion coating and which contains a polyester resin having a hydroxyl value of 10 KOHmg/g or more, an imino-containing melamine resin, and 5 to 15 percent by mass of carbon black are included, wherein the glass transition temperature (Tg) of the organic coating is 40° C. or higher, the film thickness is 10 ?m or less, and the hardness is 200 N/mm2 or more.Type: GrantFiled: September 8, 2009Date of Patent: May 6, 2014Assignee: JFE Steel CorporationInventors: Chiyoko Tada, Hiroyuki Ogata