Solid State Alloying (e.g., Diffusion, To Disappearance Of An Original Layer) Patents (Class 428/941)
  • Patent number: 11761478
    Abstract: A contact layer is formed by a deposition method on an inner surface of a first metal element by a centrifuging process, and preferably includes an inner layer of copper alloy and an outer layer of tin alloy. Such a contact layer is used in an articulation joint including a first metal element having a surface provided with the contact layer, and a second metal element with a second surface. The first and second elements are relatively movable such that first and second surfaces slide against each other.
    Type: Grant
    Filed: June 18, 2020
    Date of Patent: September 19, 2023
    Assignees: AKTIEBOLAGET SKF, SKF AEROSPACE FRANCE S.A.S
    Inventors: Azeez Abdul, Camille Dayot, Christine Matta, Pei Rose Yan, Xiaobo Zhou
  • Patent number: 8940404
    Abstract: Tin-plated copper-alloy material for terminal having: a substrate made of Cu or Cu alloy; an Sn-based surface layer formed on a surface of the substrate; and a Cu—Ni—Sn alloy layer including Ni formed between the Sn-based surface layer and the substrate, in which the Cu—Ni—Sn alloy layer is made of: fine Cu—Ni—Sn alloy particles; and coarse Cu—Ni—Sn alloy particles, an average thickness of the Sn-based surface layer is not less than 0.2 ?m and not more than 0.6 ?m, an area ratio of the Cu—Ni—Sn alloy layer exposed at a surface of the Sn-based surface layer is not less than 10% and not more than 40%, and a coefficient of kinetic friction of the tin-plated copper-alloy material for terminal is not more than 0.3.
    Type: Grant
    Filed: January 22, 2013
    Date of Patent: January 27, 2015
    Assignee: Mitsubishi Materials Corporation
    Inventors: Yuki Taninouchi, Naoki Kato, Kenji Kubota
  • Patent number: 8632890
    Abstract: A method for forming a nickel aluminide based coating on a metallic substrate includes providing a first source for providing a significant portion of the aluminum content for a coating precursor and a separate nickel alloy source for providing substantially all the nickel and additional alloying elements for the coating precursor. Cathodic arc (ion plasma) deposition techniques may be utilized to provide the coating precursor on a metallic substrate. The coating precursor may be provided in discrete layers, or from a co-deposition process. Subsequent processing or heat treatment forms the nickel aluminide based coating from the coating precursor.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: January 21, 2014
    Assignee: General Electric Company
    Inventors: Brian Thomas Hazel, Don Mark Lipkin, Michael Howard Rucker, Rudolfo Viguie
  • Patent number: 8628861
    Abstract: Herein are disclosed steel forms having stainless steel exteriors that pass a 0T-bend Advanced T-bend Test. One steel form has a stainless steel exterior; the steel form includes a core region that comprises at least 55 wt. % iron which is metallurgically bonded to a stainless steel coating that consists of a stainless steel region and a bonding region. The stainless steel region can have a thickness of about 1 ?m to about 250 ?m, and a stainless steel composition that is approximately consistent across the thickness of the stainless steel region. The stainless steel composition can include an admixture of iron and about 10 wt. % to about 30 wt. % chromium. The bonding region is positioned between the stainless steel region and the core region, has a thickness that is greater than 1 ?m and less than the thickness of the stainless steel region, and has a bonding composition.
    Type: Grant
    Filed: March 13, 2013
    Date of Patent: January 14, 2014
    Assignee: Arcanum Alloy Design Inc.
    Inventors: Daniel E. Bullard, Joseph E. McDermott
  • Patent number: 8574722
    Abstract: An electrical conductor has a metal substrate. A seal plating layer is provided on and exterior of the metal substrate. A nickel plating layer is provided on and exterior of the seal plating layer. A gold plating layer is provided on and exterior of the nickel plating layer. The seal plating layer is a non-nickel based metal. Optionally, the seal plating layer may be tin based. Optionally, the seal plating layer may create intermetallic interface layers with the nickel plating layer and the metal substrate. Optionally, the electrical conductor may constitute a contact configured for mating with at least one of a printed circuit board or another mating contact.
    Type: Grant
    Filed: May 9, 2011
    Date of Patent: November 5, 2013
    Assignee: Tyco Electronics Corporation
    Inventors: George Jyh-Shann Chou, Robert Daniel Hilty
  • Patent number: 8557397
    Abstract: A steel form having a stainless steel exterior; the steel form includes a core region that comprises at least 55 wt. % iron which is metallurgically bonded to a stainless steel coating that consists of a stainless steel region and a bonding region. The stainless steel region can have a thickness of about 1 ?m to about 250 ?m, and a stainless steel composition that is approximately consistent across the thickness of the stainless steel region. The stainless steel composition includes an admixture of iron and about 10 wt. % to about 30 wt. % chromium. The bonding region is positioned between the stainless steel region and the core region, has a thickness that is greater than 1 ?m and less than the thickness of the stainless steel region, and has a bonding composition.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: October 15, 2013
    Assignee: Arcanum Alloy Design Inc.
    Inventors: Daniel E. Bullard, Joseph E. McDermott
  • Patent number: 8389126
    Abstract: A structural component suitable for use as refinery and/or petrochemical process equipment and piping is provided. The structural component has improved corrosion, abrasion, environmental degradation resistance, and fire resistant properties with a substrate coated with a surface-treated amorphous metal layer. The surface of the structural component is surface treated with an energy source to cause a diffusion of at least a portion of the amorphous metal layer and at least a portion of the substrate, forming a diffusion layer disposed on a substrate. The diffusion layer has a negative hardness profile with the hardness increasing from the diffusion surface in contact with the substrate to the surface away from the substrate.
    Type: Grant
    Filed: April 28, 2010
    Date of Patent: March 5, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: Grzegorz Jan Kusinski, Jan H. Kusinski
  • Patent number: 8013428
    Abstract: A method of fabricating an interconnection between a region of copper material and a conducting region is disclosed. The method includes a step of forming a region of tin material and a step of forming a region of nickel material. The method also includes a step of melting the tin material to induce formation of a nickel/tin/copper intermetallic composition at an interface between the region of copper material and the conducting region. The region of tin material and the region of nickel material define the interface between the region of copper material and the conducting region.
    Type: Grant
    Filed: July 28, 2009
    Date of Patent: September 6, 2011
    Assignee: LSI Corporation
    Inventors: Kultaransingh N. Hooghan, John W. Osenbach, Brian Dale Potteiger, Poopa Ruengsinsub, Richard L. Shook, Prakash Suratkar, Brian T. Vaccaro
  • Patent number: 7645522
    Abstract: A bonding or superfine wire is provided made of copper, with a gold enrichment on the surface thereof, in particular in an amount corresponding to a coating of at most 50 nm. The wire may be bonded by the ball/wedge method, has a copper-colored appearance, and the ball thereof after flame-off has a hardness of less than 95 according to HV0.002. In order to produce the bonding or superfine wire, a copper wire is coated with gold or a copper-gold alloy or gold is introduced into the surface of the copper wire. The wires are bonded to a semiconductor silicon chip.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: January 12, 2010
    Assignee: W.C. Heraeus GmbH
    Inventors: Albrecht Bischoff, Heinz Förderer, Lutz Schräpler, Frank Krüger
  • Patent number: 7510779
    Abstract: A coated article is prepared by furnishing a nickel-base article substrate having a free sulfur content of more than 0 but less than about 1 part per million by weight. A protective layer is formed at a surface of the article substrate. The protective layer includes a platinum aluminide diffusion coating. The protective layer may be substantially yttrium-free, or have a controlled amount of yttrium. A ceramic layer may overlie the protective layer.
    Type: Grant
    Filed: September 17, 2004
    Date of Patent: March 31, 2009
    Assignee: General Electric Company
    Inventors: William Scott Walston, Jon Conrad Schaeffer, Wendy Howard Murphy
  • Patent number: 7494719
    Abstract: A component having a platinum-aluminum substrate surface region which is formed in the area of the substrate surface of the component by diffusion of platinum and aluminum into the substrate surface and which contains platinum and aluminum as well as the constituents of the substrate composition. The integrated aluminum content and/or the integrated platinum content in the substrate area is less than 18 wt %.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: February 24, 2009
    Assignee: MTU Aero Engines GmbH
    Inventors: Ernst Affeldt, Anja Kliewe, Lothar Peichl, Heinrich Walter
  • Publication number: 20070141374
    Abstract: An environmentally resistant gas turbine engine disk is disclosed. The disk includes a substrate metal having locally enriched surface regions, the locally enriched surface regions comprising alloying elements present in a higher percentage than found in the substrate metal. A method for making the disk and other articles is also disclosed. The method includes furnishing a plurality of powder particle substrates made of a substrate metal, providing a nonmetallic precursor of a metallic coating material, wherein the metallic coating material includes an alloying element that is thermophysically melt incompatible with the substrate metal, contacting the powder particle substrates with the nonmetallic precursor, and chemically reducing the nonmetallic precursor to form coated powder particles comprising the powder particle substrates having a surface-enriched layer of the metallic coating material thereon, wherein the step of chemically reducing is performed without melting the powder particle substrates.
    Type: Application
    Filed: December 19, 2005
    Publication date: June 21, 2007
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: David P. Mourer, Kenneth R. Bain
  • Patent number: 7041384
    Abstract: A method for producing a coated carbon composite material is provided. The resulting coated composite is useful for applications such as rocket nozzles and valve bodies that encounter the high temperature and high flow rates in rocket propulsion and control. A carbon substrate such as graphite is first coated with rhenium. A layer of ruthenium is then deposited on the rhenium. The materials are heated at high temperature so as to melt the ruthenium. The ruthenium melts and penetrates through the rhenium layer and into pores of the carbon substrate. The rhenium and ruthenium are mutually soluble and further form a rhenium/ruthenium alloy. Upon solidification of the rhenium/ruthenium alloy interlayer, a further rhenium coating may be deposited thereon. The rhenium/ruthenium interlayer provides a high strength bond between the carbon substrate and the rhenium coating.
    Type: Grant
    Filed: March 10, 2004
    Date of Patent: May 9, 2006
    Assignee: Honeywell International, Inc.
    Inventor: Donald L. Mittendorf
  • Patent number: 7029760
    Abstract: A plated material reduces insertion and withdrawal forces when used in a connector. A terminal member for a connector and a connector therewith are also provided. The plated material comprises a substrate 3 made of Cu or a Cu alloy and a metal plating layer 6 formed on the surface of the substrate 3. A soft region 6A spreading in a network-shape and a hard region 6B surrounded by the network of the soft region 6A coexists in the metal plating layer 6. The soft region 6A has a Vickers hardness of 20 to 250, while the hard region 6B has a Vickers hardness of 60 to 700, which is at least 30 higher than that of the soft region 6A. An average size of the network of the soft region 6A is from 5 to 500 ?m.
    Type: Grant
    Filed: July 10, 2003
    Date of Patent: April 18, 2006
    Assignee: Mitsubishi Shindoh Co., Ltd.
    Inventors: Akihito Mori, Takeshi Suzuki, Tadao Sakakibara, Shuzo Umezu, Masahiko Ishida
  • Patent number: 6991855
    Abstract: Reactive foils and their uses are provided as localized heat sources useful, for example, in ignition, joining and propulsion. An improved reactive foil is preferably a freestanding multilayered foil structure made up of alternating layers selected from materials that will react with one another in an exothermic and self-propagating reaction. Upon reacting, this foil supplies highly localized heat energy that may be applied, for example, to joining layers, or directly to bulk materials that are to be joined. This foil heat-source allows rapid bonding to occur at room temperature in virtually any environment (e.g., air, vacuum, water, etc.). If a joining material is used, the foil reaction will supply enough heat to melt the joining materials, which upon cooling will form a strong bond, joining two or more bulk materials.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: January 31, 2006
    Assignee: Johns Hopkins University
    Inventors: Timothy P. Weihs, Omar Knio, Michael Reiss, David van Heerden
  • Patent number: 6969558
    Abstract: A coated article is prepared by furnishing an nickel-base article substrate having a free sulfur content of more than 0 but less than about 1 part per million by weight. A protective layer is formed at a surface of the article substrate. The protective layer includes a platinum aluminide diffusion coating. The protective layer may be substantially yttrium-free, or have a controlled amount of yttrium. A ceramic layer may overlie the protective layer.
    Type: Grant
    Filed: November 18, 2003
    Date of Patent: November 29, 2005
    Assignee: General Electric Company
    Inventors: William S. Walston, Jon C. Schaeffer, Wendy H. Murphy
  • Patent number: 6869690
    Abstract: The present invention relates to a zinc-diffused nickel alloy coating for corrosion and heat protection and to a method for forming such a coating. The coating method broadly comprises the steps of forming a plain nickel or nickel alloy coating layer on a substrate, applying a layer of zinc over the nickel or nickel alloy coating layer, and thermally diffusing the zinc into the nickel alloy coating layer. The coating method may further comprise immersing the coated substrate in a phosphated trivalent chromium conversion solution either before or after the diffusing step. The substrate may be a component used in a gas turbine engine, which component is formed from a steel material.
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: March 22, 2005
    Assignee: United Technologies Corporation
    Inventors: Henry M. Hodgens, Thomas R. Hanlon
  • Patent number: 6863992
    Abstract: Reactive foils and their uses are provided as localized heat sources useful, for example, in ignition, joining and propulsion. An improved reactive foil is preferably a freestanding multilayered foil structure made up of alternating layers selected from materials that will react with one another in an exothermic and self-propagating reaction. Upon reacting, this foil supplies highly localized heat energy that may be applied, for example, to joining layers, or directly to bulk materials that are to be joined. This foil heat-source allows rapid bonding to occur at room temperature in virtually any environment (e.g., air, vacuum, water, etc.). If a joining material is used, the foil reaction will supply enough heat to melt the joining materials, which upon cooling will form a strong bond, joining two or more bulk materials.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: March 8, 2005
    Assignee: Johns Hopkins University
    Inventors: Timothy P. Weihs, Omar Knio, Michael Reiss, David van Heerden
  • Patent number: 6797408
    Abstract: A coated article is prepared by furnishing an nickel-base article substrate having a free sulfur content of more than 0 but less than about 1 part per million by weight. A protective layer is formed at a surface of the article substrate. The protective layer includes a platinum aluminide diffusion coating. The protective layer may be substantially yttrium-free, or have a controlled amount of yttrium. A ceramic layer may overlie the protective layer.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: September 28, 2004
    Assignee: General Electric Company
    Inventors: William S. Walston, Jon C. Schaeffer, Wendy H. Murphy
  • Patent number: 6756134
    Abstract: The present invention relates to a zinc-diffused nickel alloy coating for corrosion and heat protection and to a method for forming such a coating. The coating method broadly comprises the steps of forming a plain nickel or nickel alloy coating layer on a substrate, applying a layer of zinc over the nickel or nickel alloy coating layer, and thermally diffusing the zinc into the nickel alloy coating layer. The coating method may further comprise immersing the coated substrate in a phosphated trivalent chromium conversion solution either before or after the diffusing step. The substrate may be a component used in a gas turbine engine, which component is formed from a steel material.
    Type: Grant
    Filed: September 23, 2002
    Date of Patent: June 29, 2004
    Assignee: United Technologies Corporation
    Inventors: Henry M. Hodgens, Thomas R. Hanlon, Promila Bhatia
  • Patent number: 6720088
    Abstract: A group of alloys suitable for use in a high-temperature, oxidative environment, a protective coating system comprising a diffusion barrier that comprises an alloy selected from the group, an article comprising the diffusion barrier layer, and a method for protecting an article from a high-temperature oxidative environment comprising disposing the diffusion barrier layer onto a substrate are presented.
    Type: Grant
    Filed: February 5, 2002
    Date of Patent: April 13, 2004
    Assignee: General Electric Company
    Inventors: Ji-Cheng Zhao, Melvin Robert Jackson, Richard John Grylls, Ramgopal Darolia
  • Publication number: 20040058189
    Abstract: The present invention relates to a zinc-diffused nickel alloy coating for corrosion and heat protection and to a method for forming such a coating. The coating method broadly comprises the steps of forming a plain nickel or nickel alloy coating layer on a substrate, applying a layer of zinc over the nickel or nickel alloy coating layer, and thermally diffusing the zinc into the nickel alloy coating layer. The coating method may further comprise immersing the coated substrate in a phosphated trivalent chromium conversion solution either before or after the diffusing step. The substrate may be a component used in a gas turbine engine, which component is formed from a steel material.
    Type: Application
    Filed: September 23, 2002
    Publication date: March 25, 2004
    Inventors: Henry M. Hodgens, Thomas R. Hanlon
  • Patent number: 6613445
    Abstract: A method for forming a metal-containing layer on a substrate is disclosed. A slurry of the metal is first deposited on the substrate; followed by heating to remove volatile material from the slurry, and to form a layer of the metal. In another embodiment, a slurry of aluminum is deposited over the slurry of the metal, before or after the metal has been heat-treated to some degree. A diffusion heat treatment results in a coating which includes the noble-metal aluminide compound. Related articles are also disclosed.
    Type: Grant
    Filed: January 16, 2002
    Date of Patent: September 2, 2003
    Assignee: General Electric Company
    Inventors: D. Sangeeta, Howard John Farr
  • Patent number: 6610416
    Abstract: The present invention provides for a method to reduce the strength of the honeycomb of a jet turbine stator, increasing its machinability, with a resultant reduction in measured peak tooth temperature, while maintaining or even improving its high temperature capability, so as not to limit its operating environment. The air seal functionality is unaffected, and even improved in some instances. The machinability of the honeycomb is increased by using a light element diffused into the honeycomb ribbon to produce the effect of reducing its strength and ductility while maintaining the environmental resistance needed. The present invention also includes the stator honeycomb produced by the foregoing method.
    Type: Grant
    Filed: April 26, 2001
    Date of Patent: August 26, 2003
    Assignee: General Electric Company
    Inventors: Thomas Tracy Wallace, Brent Ross Tholke
  • Publication number: 20030113577
    Abstract: An electrically conductive metal element comprises an electrically conductive metal substrate having a layer of Ni—Sn alloy overlying an electrically conductive surface of the substrate and at least one layer of Ag or of Ag containing Sn overlying the Ni—Sn alloy layer. The Ni—Sn alloy(s) has a Sn-content not greater than for Ni3Sn2 for high temperature uses. In a convenient method of forming the element the Sn is applied to one or more layers of Ni in a Ag+Sn mixture and diffused into the Ni layer(s) to form the Ni—Sn alloy layer and at least one layer of Ag or of Ag containing Sn. The element may have a surface layer of SnO2 which can be formed by oxidising residual Sn which migrates to the outer surface of the at least one layer of Ag containing Sn.
    Type: Application
    Filed: December 31, 2002
    Publication date: June 19, 2003
    Inventor: Xiao Guang Zheng
  • Patent number: 6565990
    Abstract: An airfoil having a melting temperature of at least about 1500° C. and comprising a first piece and a second piece joined at a bonded region to the first piece by a diffusion bond. The first piece comprises one of a first niobium-based refractory metal intermetallic composite and a first molybdenum-based refractory metal intermetallic composite. The second piece comprises one of a second niobium-based refractory metal intermetallic composite and a second molybdenum-based refractory metal intermetallic composite. The diffusion bond is formed from a first metallic element disposed on a first surface of the first piece and a second metallic element disposed on at least one of the first surface and a second surface of the second piece, the second surface contacting the first surface, wherein the first and second metal form a composition having a melting temperature less than about 1400° C. This abstract is submitted in compliance with 37 C.F.R. 1.
    Type: Grant
    Filed: May 30, 2001
    Date of Patent: May 20, 2003
    Assignee: General Electric Company
    Inventors: Bernard Patrick Bewlay, Melvin Robert Jackson, Ji-Cheng Zhao
  • Patent number: 6528181
    Abstract: A plated steel sheet and a connection terminal material using the plated steel sheet have low contact resistance and excellent corrosion resistance. The coated film, which has excellent adhesion, is formed by coating a stainless steel base sheet which is coated with a nickel-tin alloy with a solution/suspension of carbon black or graphite, carboxymethyl cellulose, and a water-borne organic resin which is acrylic resin, polyester resin, urethane resin, or phenol resin.
    Type: Grant
    Filed: July 31, 2000
    Date of Patent: March 4, 2003
    Assignee: Toyo Kohan Co., Ltd.
    Inventors: Keiji Yamane, Hitoshi Ohmura, Tatsuo Tomomori, Hideo Ohmura, Yuji Yamazaki
  • Patent number: 6514629
    Abstract: An article such as a gas turbine blade or vane has a superalloy substrate, and a coating system deposited on the substrate. The coating system includes a protective layer overlying the substrate, and, optionally, a ceramic thermal barrier coating layer overlying the bond coat. The protective layer has an uppermost layer with a composition including platinum, aluminum, and, in atom percent, from about 0.14 to about 2.8 percent hafnium and from about 2.7 to about 7.0 percent silicon, with the atomic ratio of silicon:hafnium being from about 1.7:1 to about 5.6:1.
    Type: Grant
    Filed: December 15, 1998
    Date of Patent: February 4, 2003
    Assignee: General Electric Company
    Inventors: Joseph D. Rigney, Ramgopal Darolia, William S. Walston
  • Patent number: 6514631
    Abstract: A heating furnace tube, a method of using the same and a method of manufacturing the same which have been developed with a view to eliminating inconveniences occurring when a carbon-containing fluid is made to flow in the heating furnace tube. The heating furnace tube which comprises a rare earth oxide particle distributed iron alloy containing 17-26 wt. % of Cr and 2-6 wt. % of Al. The method of manufacturing this heating furnace tube which comprises the steps of forming or inserting an insert metal on or into at least one of a joint end portion of one heating furnace tube element and that of the other heating furnace tube element, bringing these two joint end portions into pressure contact with each other directly or via an intermediate member, and diffusion welding the two heating furnace tube elements to each other by heating the insert metal.
    Type: Grant
    Filed: May 1, 2000
    Date of Patent: February 4, 2003
    Assignee: JGC Corporation
    Inventors: Katsumi Yamamoto, Takeo Murata, Rin Sasano, Kenji Sato, Toshikazu Nakamura, Muneyasu Ichimura, Kunio Ishii, Keizo Hosoya
  • Patent number: 6489043
    Abstract: An iron aluminide fuel injector component such as a nozzle, plunger or other part is manufactured from iron aluminide or includes an iron aluminide coating on at least a portion of a surface in contact with the fuel which passes through the fuel injector. The iron aluminide alloy can include 8 to 32 wt. % Al, up to 5 wt. % refractory metal, B and/or C in amounts sufficient to form borides and/or carbides. The fuel injector component can be formed from powders of the iron aluminide alloy by powder metallurgy techniques and the coating can be formed by a diffusional reaction process, cathodic plasma process, chemical vapor deposition or physical vapor deposition. The fuel injector component is corrosion, carburization, sulfidation and/or coking resistant.
    Type: Grant
    Filed: November 9, 2001
    Date of Patent: December 3, 2002
    Assignee: Chrysalis Technologies Incorporated
    Inventors: Seetharama C. Deevi, Shalva Gedevanishvili, Sohini Paldey
  • Patent number: 6475647
    Abstract: A method for protecting high temperature stainless steel from coking and corrosion at elevated temperatures in corrosive environments, such as during ethylene production by pyrolysis of hydrocarbons or the reduction of oxide ores, by coating the stainless steel with a coating of MCrAlX in which M is nickel, cobalt, iron or a mixture thereof and X is yttrium, hafnium, zirconium, lanthanum or combination thereof deposited onto and metallurgically bonded to the stainless steel by plasma transferred arc deposition of atomized powder of MCrAlX. The coating has a thick, dense, continuous and smooth transition region providing an effective metallurgically bond of the coating with the stainless steel. The coating retains a relatively high aluminum content which permits generation of an adherent alumina layer on the surface, providing good resistance to high temperature oxidation together with good anti-coking and hot erosion resistance properties.
    Type: Grant
    Filed: October 18, 2000
    Date of Patent: November 5, 2002
    Assignee: Surface Engineered Products Corporation
    Inventors: Juan Manuel Mendez Acevedo, Chinnia Gounder Subramanian
  • Patent number: 6468679
    Abstract: This invention is related to a metal-based gradient composite material having good lubrication and wear-resistance properties. The composite material comprises a metal (M) matrix and a gradient composite layer of metal sulfide (M[S]) and metal oxide,(M[O]) on the surface of said metal matrix. In the gradient composite layer,, the sum (Ds+Do) of the concentration of metal sulfide (Ds) and the concentration of metal oxide (Do) decreases gradually from the surface to the interior, and the concentration of metal (DM) increases from the surface to the interior. The invention is also related to a process for producing the gradient composite material and the use of the same.
    Type: Grant
    Filed: June 20, 2000
    Date of Patent: October 22, 2002
    Inventors: Xinhui Zhang, Yifei Zhang
  • Patent number: 6436556
    Abstract: The invention relates to a method and a device for the production of a strip-like metallic composite material by the high-temperature dip coating of a metallic carrier strip, consisting of a metallurgic vessel for receiving the liquid depositing material, through which the carrier strip is capable of being led in a preferably vertical run-through direction by means of pairs of rollers arranged on the entry and the exit side, and of a preheating device for the carrier strip, said preheating device being located upstream of the metallurgic vessel. At the same time, the preheating device (41) is arranged in a housing (61) which is arranged in the entry region upstream of the metallurgic vessel (11) and surrounds the carrier strip (21) and into which the medium coming from a media supply (52) is capable of being introduced via at least one feed (51) led into the housing.
    Type: Grant
    Filed: August 11, 2000
    Date of Patent: August 20, 2002
    Assignees: SMS Demag AG, Thyssen Krupp Stahl AG
    Inventors: Wolfgang Bleck, Rolf Bünten, Frank Friedel, Oliver Picht, Wolfgang Reichelt, Wilhelm Schmitz, Dieter Senk, Paul Splinter, Ulrich Urlau
  • Patent number: 6413649
    Abstract: The present invention is directed to brazing filler metals that can be used in the infiltration brazing of porous matrix materials without the need for a flux. The brazing filler metals contain two different Group II metals and a third metal of Group 9 and 10. A particular brazing filler metal of the invention contains silver, copper, and nickel. The invention is also directed to composite materials formed by infiltration of the brazing material into a porous matrix, and to methods for preparing the composite materials. The invention is further directed to composite articles fabricated from composite materials, including steel bearings or bushings, and to methods of preparing the composite articles.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: July 2, 2002
    Assignee: The Morgan Crucible Company plc
    Inventors: David J. Kepniss, Toshimasa Oyama
  • Publication number: 20020048683
    Abstract: A coated article is prepared by furnishing an nickel-base article substrate having a free sulfur content of more than 0 but less than about 1 part per million by weight. A protective layer is formed at a surface of the article substrate. The protective layer includes a platinum aluminide diffusion coating. The protective layer may be substantially yttrium-free, or have a controlled amount of yttrium. A ceramic layer may overlie the protective layer.
    Type: Application
    Filed: December 10, 2001
    Publication date: April 25, 2002
    Inventors: William S. Walston, Jon C. Schaeffer, Wendy H. Murphy
  • Patent number: 6348114
    Abstract: A sliding bearing having improved seizure resistance has the following structure: (a) A bearing layer (2). It comprises a copper alloy containing in a Cu matrix Ag, Sn, Sb, In, Mn, Fe, Bi, Zn, Ni and/or Cr. (b) A first sub-layer (3) of the bearing layer (2). First sub-layer (3) contains concentrated element, hexagonal compound or eutectic of said element(s). (c) A second sub-layer (2a) in which said element in essential solid-solution state. (d) Metal backing (1).
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: February 19, 2002
    Assignee: Taiho Kogyo Co., Ltd.
    Inventors: Haruyuki Oshiro, Takashi Tomikawa, Soji Kamiya, Katuyuki Hashizume
  • Patent number: 6344282
    Abstract: A diffusion aluminide coating having a graded structure is applied over a nickel base superalloy substrate. The coating has an inner region of a diffusion aluminide adjacent to the substrate rich in a reactive element, typically Hf, Si or combinations of the two. The near surface region is a diffusion aluminide which is substantially free of reactive elements. Such coatings when used as bond coats in thermal barrier coating systems exhibit improved spallation performance.
    Type: Grant
    Filed: December 30, 1998
    Date of Patent: February 5, 2002
    Assignee: General Electric Company
    Inventors: Ramgopal Darolia, Joseph D. Rigney, Joshua L. Miller
  • Patent number: 6340535
    Abstract: This invention relates to a method for the heat treatment of a ZnSe crystal substrate to dope it with Al as a donor impurity, a ZnSe crystal substrate prepared by this heat treatment and a light-emitting device using the ZnSe crystal substrate, in particular, the method for the heat treatment of a ZnSe crystal substrate comprising previously forming an Al film on the substrate, first subjecting the substrate to a heat treatment in a Se atmosphere and then subjecting to a heat treatment in a Zn atmosphere.
    Type: Grant
    Filed: May 18, 2001
    Date of Patent: January 22, 2002
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Yasuo Namikawa, Shinsuke Fujiwara
  • Patent number: 6336979
    Abstract: Wear resistant copper or a wear resistant copper base alloy having formed on the outermost surface thereof an oxide layer having a thickness of 10-1000 nm and a layer of an intermetallic compound primarily comprising Cu—Sn having a thickness of 0.1-10 &mgr;m under the oxide film layer is provided; a method of preparing the above-described wear resistant copper or copper base alloy by coating base material copper or a copper base alloy with Sn, preferably performing reflow treatment and then conducting heat treatment is provided; and an electrical part comprising the above-described wear resistant copper or copper base alloy is provided. A terminal made of the alloy according to the present invention which has an appropriate oxide film layer by performing heat treatment can greatly decrease a terminal-insertion force compared with that made of an ordinary copper base alloy which is not subjected to the heat treatment.
    Type: Grant
    Filed: January 27, 2000
    Date of Patent: January 8, 2002
    Assignees: Dowa Mining Co., Ltd., Yazaki Corporation
    Inventors: Akira Sugawara, Yoshitake Hana, Takayoshi Endo
  • Patent number: 6333121
    Abstract: A coated article is prepared by furnishing an nickel-base article substrate having a free sulfur content of more than 0 but less than about 1 part per million by weight. A protective layer is formed at a surface of the article substrate. The protective layer includes a platinum aluminide diffusion coating. The protective layer may be substantially yttrium-free, or have a controlled amount of yttrium. A ceramic layer may overlie the protective layer.
    Type: Grant
    Filed: June 9, 1999
    Date of Patent: December 25, 2001
    Assignee: General Electric Company
    Inventors: William S. Walston, Jon C. Schaeffer, Wendy H. Murphy
  • Publication number: 20010053456
    Abstract: The present invention is directed to brazing filler metals that can be used in the infiltration brazing of porous matrix materials without the need for a flux. The brazing filler metals contain two different Group II metals and a third metal of Group 9 and 10. A particular brazing filler metal of the invention contains silver, copper, and nickel. The invention is also directed to composite materials formed by infiltration of the brazing material into a porous matrix, and to methods for preparing the composite materials. The invention is further directed to composite articles fabricated from composite materials, including steel bearings or bushings, and to methods of preparing the composite articles.
    Type: Application
    Filed: March 6, 1998
    Publication date: December 20, 2001
    Inventors: DAVID J. KEPNISS, TOSHIMASA OYAMA
  • Patent number: 6329079
    Abstract: A tube for a cracker unit in which ethylene is produced withstands, without oxidizing or losing its strength, the elevated temperatures required to effect cracking, yet retards coking. The tube has a shell formed from stainless steel or high nickel alloy and a liner formed from an iron-aluminum alloy. The liner retards the deposit of carbon and its build up known as coking. To form the tube, a high alloy ingot is bored to provide a bore that extends through its center. Then a weld overlay is applied to surface of the bore, with the overlay being derived from a weld metal containing at least 16% aluminum and the balance essentially iron. Thereafter, the ingot is heated to its hot working temperature and extruded through sets of opposed rollers, with the direction of advance being in the direction of the bore. The extruding transforms the ingot into a lined tube.
    Type: Grant
    Filed: October 27, 1999
    Date of Patent: December 11, 2001
    Assignee: Nooter Corporation
    Inventor: John J. Meyer
  • Patent number: 6231996
    Abstract: A part or jig of a metal for a gas carburizing furnace has an Al diffusion layer which has an Al content of 10 to 50 wt % in the surface portion of the part or jig, the Al diffusion layer being formed by carrying out the calorizing treatment.
    Type: Grant
    Filed: December 8, 1997
    Date of Patent: May 15, 2001
    Assignee: Shinto Kogyo Kabushiki Kaisha
    Inventors: Kenji Umeno, Tatsuya Oishi
  • Patent number: 6228513
    Abstract: A method of improving the oxidation and corrosion resistance of a superalloy article comprises providing a superalloy substrate having a sulphur content which is less than 0.8 ppm by weight, and depositing on the substrate a protective antioxidation coating having a sulphur content also less than 0.8 ppm by weight. A heat barrier layer may also be provided by depositing on the protective anti-oxidation coating a ceramic coating of columnar structure.
    Type: Grant
    Filed: September 22, 1998
    Date of Patent: May 8, 2001
    Assignee: Societe Nationale d'Etude et de Construction de Moteurs d'Aviation “SNECMA”
    Inventors: Yann Jaslier, Serge Alexandre Alperine, Jacques Louis Leger
  • Patent number: 6194088
    Abstract: An intermetallic-compound coated stainless steel having excellent rigidity, toughness, wear resistance and corrosion resistance comprises a substrate of a martensite stainless steel having a Vickers hardness of 400 or more, and a hard film having a bottom surface adhered to the substrate and an exposed top surface. The hard film has an outermost layer made of a compound selected from the group consisting of a Ti—Ni intermetallic compound, Ti—Fe intermetallic compound, and a mixture of the Ti—Ni intermetallic compound and a Ti—Cu intermetallic compound. The coated stainless steel can be produced by cladding an outer sheet made of Ti or a Ti alloy to a martensite stainless steel sheet directly or through an intermediate sheet made of Ni, Fe or a Ni—Cu alloy, heating the laminate at a temperature of 900° C. to 1150° C. for 30 seconds to 5 minutes, and then cooling the heated laminate at a cooling rate of 1° C./sec or more.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: February 27, 2001
    Assignees: Daido Steel Co., Ltd., Matsushita Electric Works, Ltd.
    Inventors: Hiroaki Yoshida, Hiroshi Yamada, Fumio Iwane, Junji Imai, Tadashi Hamada, Shinji Fujimoto, Shuji Yamada, Shigetoshi Sakon
  • Patent number: 6139976
    Abstract: The invention relates to an article of manufacture comprising: a substrate composed of a superalloy containing chromium and a base element selected from the group consisting of iron, cobalt, and nickel; and an enrichment layer containing chromium and placed on the substrate. Therein, the enrichment layer comprises a continuous matrix composed of a gamma-phase solid solution of chromium in the base element. The invention also relates to the manufacture of such an article. The article may in particular be a gas turbine component.
    Type: Grant
    Filed: June 7, 1999
    Date of Patent: October 31, 2000
    Assignee: Siemens Aktiengesellschaft
    Inventors: Norbert Czech, Knut Halberstadt, John Smith, Adrian Kempster
  • Patent number: 6136451
    Abstract: A method of improving oxidation resistance of a platinum modified aluminide diffusion coating on a substrate involves electroplating the substrate with a platinum layer from an aqueous hydroxide based electroplating solution and aluminizing the substrate to grow the platinum modified aluminide diffusion coating on said layer. The electroplating solution preferably includes an alkali element and/or alkaline earth element that is incorporated in the platinum layer and in the aluminide diffusion coating formed thereon to significantly improve oxidation resistance of the coating.
    Type: Grant
    Filed: February 3, 1998
    Date of Patent: October 24, 2000
    Assignee: Howmet Research Corporation
    Inventors: Bruce M. Warnes, Thomas A. Legard, Nick S. DuShane, Jack E. Cockerill, Robert W. Beck
  • Patent number: 6129991
    Abstract: High temperature oxidation resistance of an aluminide diffusion overcoated MCrAlY coating system is substantially improved by CVD over-aluminizing the MCrAlY type overlay coating under CVD conditions that result in reduced concentrations of such tramp impurities as S and P in the aluminized MCrAlY overlay coating region of the coating system. The CVD aluminizing conditions yield an outwardly grown aluminide over-coat on the underlying MCrAlY type coating.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: October 10, 2000
    Assignee: Howmet Research Corporation
    Inventors: Bruce M. Warnes, William J. Shriver, Ronald J. Honick, Jr., Nick S. DuShane
  • Patent number: 6060179
    Abstract: Disclosed is a Cu--Pb alloy bearing and a producing method thereof. The Cu--Pb alloy bearing consists of a backing metal layer and a Cu--Pb bearing alloy layer which is bonded to the backing metal layer and whose matrix contains dispersed Pb-phase grains. Within an at least 30 .mu.m thick surface region of the Cu--Pb bearing alloy layer, the Pb-phase grains comprise at least one of In and Sn in an amount or a total amount of not less than 2 wt %, respectively, which are elements added into the Pb-phase grains by migration.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: May 9, 2000
    Assignee: Daido Metal Company Ltd.
    Inventors: Hideo Tsuji, Tatsuo Yamada, Hideo Ishikawa, Takayuki Shibayama
  • Patent number: 6020075
    Abstract: A thermal barrier coating system and a method for forming the coating system on an article designed for use in a hostile thermal environment, such as superalloy turbine, combustor and augmentor components of a gas turbine engine. The method is particularly directed to a coating system comprising an APS bond coat on which a thermal-insulating APS ceramic layer is deposited, wherein the oxidation resistance of the bond coat and the spallation resistance of the ceramic layer are increased by diffusing platinum, palladium, hafnium, rhenium and/or rhodium into the bond coat. The diffusion process is performed so as not to alter the surface roughness of the bond coat, which is maintained in a range of about 200 to about 500.mu. inch Ra.
    Type: Grant
    Filed: September 2, 1998
    Date of Patent: February 1, 2000
    Assignee: General Electric Company
    Inventors: Bhupendra K. Gupta, Thomas E. Mantkowski