Abstract: A new electroactive material of formula H4V3O8 obtainable from H2V3O8 is described as well as a method for its production, an electroactive cathode coating material comprising this electroactive material, a method for its production and cathodes as well as aqueous and non aqueous, rechargeable and non rechargeable batteries comprising such cathodes.

Abstract: Lithium-ion battery comprising: (a) a positive electrode comprising an amorphous chalcogenide which comprises lithium ions or which can conduct lithium ions; (b) a negative electrode; (c) a separator between the positive electrode and the negative electrode, wherein the separator comprises a non-woven material composed of fibres, preferably polymer fibres; (d) a non-aqueous electrolyte.

Abstract: According to one embodiment, a negative electrode active material includes a compound having a crystal structure of monoclinic titanium dioxide. The compound has a highest intensity peak detected by an X-ray powder diffractometry using a Cu-K? radiation source. The highest intensity peak is a peak of a (001) plane, (002) plane, or (003) plane. A half-width (2?) of the highest intensity peak falls within a range of 0.5 degree to 4 degrees.

Abstract: An anode active material for a lithium rechargeable battery, the anode active material including: a base material which is alloyable with lithium and a metal nitride disposed on the base material.

Abstract: [Objectives] The present invention provides a non-aqueous secondary battery in which a material containing Si and O as constituent elements is used in a negative electrode. The present invention provides a non-aqueous secondary battery having good charge discharge cycle characteristics, and suppressing the battery swelling associated with the charge and the discharge. Also, the present invention relates to a negative electrode that can provide the non-aqueous secondary battery. [Solution] The negative electrode includes a negative electrode active material, including a composite of a material containing Si and O as constitution elements (atom ratio x of O to Si is 0.5?x?1.5) in combination with a carbon material, and graphite. The graphite has an average particle diameter dg(?m) of 4 to 20 ?m. The material containing Si and O as constitution elements has an average particle diameter ds(?m) of 1 ?m or more. The ratio ds/dg (i.e., ds to dg) is 0.05 to 1.

Abstract: A secondary battery includes: a cathode; an anode; and an electrolytic solution. The cathode includes a lithium composite oxide, a first compound, and a second compound. The lithium composite oxide includes lithium (Li) and a transition metal element as constituent elements. The first compound includes a first metal element different from the transition metal element as a constituent element, the first compound existing on a surface and inside of the lithium composite oxide. The second compound includes a second metal element different from the first metal element as a constituent element, the second compound existing on the surface of the lithium composite oxide.

Abstract: Lithium ion batteries having an anode comprising at least one graphene layer in electrical communication with titania to form a nanocomposite material, a cathode comprising a lithium olivine structure, and an electrolyte. The graphene layer has a carbon to oxygen ratio of between 15 to 1 and 500 to 1 and a surface area of between 400 and 2630 m2/g. The nanocomposite material has a specific capacity at least twice that of a titania material without graphene material at a charge/discharge rate greater than about 10 C. The olivine structure of the cathode of the lithium ion battery of the present invention is LiMPO4 where M is selected from the group consisting of Fe, Mn, Co, Ni and combinations thereof.

Abstract: The present invention relates to nano structures of metal oxides having a nanostructured shell (or wall), and an internal space or void. Nanostructures may be nanoparticles, nanorod/belts/arrays, nanotubes, nanodisks, nanoboxes, hollow nanospheres, and mesoporous structures, among other nanostructures. The nanostructures are composed of polycrystalline metal, oxides such as SnO2. The nanostructures may have concentric walls which surround the internal space of cavity. There may be two or more concentric shells or walls. The internal space may contain a core such ferric oxides or other materials which have functional properties. The invention also provides for a novel, inexpensive, high-yield method for mass production of hollow metal oxide nanostructures. The method may be template free or contain a template such as silica. The nanostructures prepared by the methods of the invention provide for improved cycling performance when tested using rechargeable lithium-ion batteries.

Abstract: A negative electrode active material and a secondary battery are provided. The negative electrode active material can be useful in maintaining excellent cell efficiency and lifespan while showing high-capacity properties, and the secondary battery may be manufactured using the negative electrode active material.

Abstract: A cathode and a battery including a cathode active material including a layer-structured material having a composition of xLi2MO3-(1-x)LiMeO2; and a metal oxide having a perovskite structure. The cathode active material may have improved structural stability by intermixing a metal oxide having a similar crystalline structure with the layer-structured material, and thus, life and capacity characteristics of a cathode and a lithium battery including the metal oxide may be improved.

Abstract: The invention relates to positive electrode for lithium secondary battery which comprises an active material and a conductive material, wherein the active material comprises a lithium-transition metal compound which has a function of being capable of insertion and desorption of lithium ion, the lithium-transition metal compound gives a surface-enhanced Raman spectrum which has a peak at 800-1,000 cm?1, and the conductive material comprises carbon black which has a nitrogen adsorption specific surface area (N2SA) of 70-300 m2/g and an average particle diameter of 10-35 nm, and a lithium secondary battery which employs the same.

Abstract: The present invention provides a method of manufacturing an active material comprising both ?-LiVOPO4 and ?-LiVOPO4. The method of manufacturing an active material in accordance with the present invention comprises a hydrothermal synthesis step of heating a mixture containing a lithium source, a phosphate source, a vanadium source, and water and having a pH greater 7 but smaller than 12.7; and a firing step of firing the mixture after being heated under pressure in the hydrothermal synthesis step.

Abstract: A negative active material for a rechargeable lithium battery and a rechargeable lithium battery including the same. The negative active material includes a carbon-nanoparticle composite including a crystalline carbon material including pores, and amorphous nanoparticles dispersed either inside the pores, or on the surface of the crystalline carbon material, or both inside the pores and on the surface of the crystalline carbon material. At least one of the amorphous nanoparticles includes a metal oxide layer in a form of a film on the surface, and the amorphous nanoparticles have a full width at half maximum of about 0.35 degree (°) or greater at a crystal plane producing the highest peak as measured by X-ray diffraction analysis.

Abstract: An electrode active material includes a core capable of intercalating and deintercalating lithium; and a surface treatment layer disposed on at least a portion of a surface of the core, wherein the surface treatment layer includes a lithium-free oxide having a spinel structure, and an intensity of an X-ray diffraction peak corresponding to impurity phase of the lithium-free oxide, when measured using Cu—K? radiation, is at a noise level of an X-ray diffraction spectrum or less.

Abstract: A rechargeable lithium battery including: a positive electrode including a nickel-based positive active material; a negative electrode including a negative active material; and an electrolyte including a non-aqueous organic solvent, a lithium salt, a first fluoroethylene carbonate additive, a second vinylethylene carbonate additive, and a third alkane sultone additive, wherein when the battery is thicker than about 5mm, a mixing weight ratio of the first fluoroethylene carbonate additive to the second vinylethylene carbonate additive ranges from about 5:1 to about 10:1, or when the battery is thinner than about 5 mm, the mixing weight ratio of the first fluoroethylene carbonate additive to the second vinylethylene carbonate additive ranges from about 1:1 to about 4:1.

Abstract: Materials useful as electrodes for lithium batteries have very good electronic and ionic conductivities. They are fabricated from a starting mixture which includes a metal, a phosphate ion, and an additive which enhances the transport of lithium ions in the resultant material. The mixture is heated in a reducing environment to produce the material. The additive may comprise a pentavalent metal or a carbon. In certain embodiments the material is a two-phase material. Also disclosed are electrodes which incorporate the materials and lithium batteries which incorporate those electrodes.

Abstract: A lithium battery includes a cathode; an anode; and an organic electrolyte solution. The cathode includes cathode active materials that discharge oxygen during charging and discharging. The organic electrolyte solution includes: lithium salt; an organic solvent, and at least one selected from the group consisting of compounds represented by Formula 1 and Formula 2 below: P(R1)a(OR2)b??Formula 1 O?P(R1)a(OR2)b.??Formula 2 R1 is each independently a substituted or unsubstituted C1-C20 alkyl group or a substituted or unsubstituted C6-C30 aryl group. R2 is each independently a substituted or unsubstituted C1-C20 alkyl group or a substituted or unsubstituted C6-C30 aryl group. a and b are each independently in a range of about 0 to about 3 and a+b=3.

Abstract: A lithium ion battery anode for a lithium ion battery is provided. The lithium ion battery anode includes a number of anode material particles. The lithium ion battery anode also includes a number of carbon nanotubes. The carbon nanotubes are entangled with each other. The carbon nanotubes form a net structure.

Abstract: A lithium-titanium complex oxide, which exhibits high effective capacity and high rate characteristics, has a particle size distribution as measured by the laser diffraction method such that the maximum particle size (D100) is 20 ?m or less, average particle size D50 is 1.0 to 1.5 ?m, total frequency of particles whose particle size is greater than twice the average particle size D50 is 16 to 25%, and preferably the specific surface area as measured by the BET method is 6 to 14 m2/g, and preferably the angle of repose is 35 to 50°.

Abstract: A non-aqueous electrolyte battery includes an electrode group includes a positive electrode and a negative electrode disposed through a separator, and a non-aqueous electrolyte. The negative electrode comprises a current collector and a porous negative electrode layer formed on the current collector and containing a lithium compound. The porous negative electrode layer has a first peak at a pore diameter of 0.04 to 0.15 ?m and a second peak at a pore diameter of 0.8 to 6 ?m in the relation between the pore diameter and log differential intrusion obtained in the mercury press-in method.

Abstract: An active material including a metal oxide represented by the following formula (1): LixM1aM2bTiOz??(1) where M1 represents at least one element selected from the group consisting of Zr, Ge, Si and Al, M2 represents at least one element selected from the group consisting of Cr, Mn, Fe, Ni and Sn, Ti has an oxidation number of +4, and x, a, b and z satisfy the following requirements: 0.01?x?0.2, 0.005?a?0.1, 0.005?b?0.1 and 2?z?2.5.

Abstract: In one aspect, a lithium secondary battery that includes a positive electrode including a high-voltage positive active material; and a separator is provided. The high voltage positive active material can have a discharge plateau voltage of greater than or equal to about 4.6V with respect to a Li counter electrode, and the separator can include a porous substrate having a porosity of about 40% to about 60%.

Abstract: A composite electrode for an electricity storage device of the present invention includes: a substrate; a whisker or a fiber which is made of at least one of a metal and a metal compound and is formed on the substrate; and a coating layer which contains an active material and is formed on at least a part of a surface of the whisker or the fiber.

Abstract: An electrochemical cell including an anode comprising a carbonaceous material, where the carbonaceous material is capable of reversibly incorporating lithium ions therein and lithium metal on the surface thereof, a cathode capable of reversibly incorporating therein lithium ions, and a non-aqueous electrolyte in contact with the anode and the cathode, where the ratio of the capacity to reversibly incorporate lithium ions of the cathode to the capacity to reversibly incorporate lithium ions in the form of LiC6 of the carbonaceous material of the anode is equal to or larger than 4.5:1.

Abstract: Modifications to the surface of an electrode and/or the surfaces of the electrode material can improve battery performance. For example, the modifications can improve the capacity, rate capability and long cycle stability of the electrode and/or may minimize undesirable catalytic effects. In one instance, metal-ion batteries can have an anode that is coated, at least in part, with a metal fluoride protection layer. The protection layer is preferably less than 100 nm in thickness.

Abstract: A negative active material and a lithium battery including the negative active material. The negative active material includes primary particles, each including: a crystalline carbonaceous core having a surface on which silicon-based nanowires are disposed; and an amorphous carbonaceous coating layer that is coated on the crystalline carbonaceous core so as not to expose at least a portion of the silicon-based nanowires. Due to the inclusion of the primary particles, an expansion ratio is controlled and conductivity is provided and thus, a formed lithium battery including the negative active material may have improved charge-discharge efficiency and cycle lifespan characteristics.

Abstract: An electrochemical cell is described. The electrochemical cell includes an anode, a cathode, a separator between said anode and said cathode, and an electrolyte. The electrolyte includes a salt dissolved in an organic solvent. The separator in combination with the electrolyte has an area specific resistance less than 2 ohm-cm2. The electrochemical cell has an interfacial anode to cathode ratio of less than about 1.1.

Abstract: A nonaqueous electrolyte battery includes a positive electrode, a negative electrode and a nonaqueous electrolyte. At least one of the positive electrode and the negative electrode comprises a current collector made of aluminum or an aluminum alloy and an active material layer laminated on the current collector. The active material layer contains first active material particles having an average particle diameter of 1 ?m or less and a lithium diffusion coefficient of 1×10?9 cm2/sec or less at 20° C., and second active material particles having an average particle diameter of 2 to 50 ?m. A true density of the second active material particles is larger by 0.01 to 2.5 g/cm3 than a true density of the first active material particles.

Abstract: A unit for use within a furnace chamber having a gaseous environment of air, for carrying out a synthesizing process for synthesizing precursors to form a synthesized product at elevated temperatures. The materials of the synthesizing process are separated from the air of the furnace chamber by the vessel or the reductive material.

Abstract: A nonaqueous secondary battery having a positive electrode having a positive electrode mixture layer, a negative electrode, and a nonaqueous electrolyte, in which the positive electrode contains, as an active material, a lithium-containing transition metal oxide containing a metal element selected from the group consisting of Mg, Ti, Zr, Ge, Nb, Al and Sn, the positive electrode mixture layer has a density of 3.

Abstract: An active material for a battery includes an electrochemically reversibly oxidizable and reducible base material selected from the group consisting of a metal, a lithium-containing alloy, a sulfur-based compound, and a compound that can reversibly form a lithium-containing compound by a reaction with lithium ions and a surface-treatment layer formed on the base material and comprising a compound of the formula MXOk, wherein M is at least one element selected from the group consisting of an alkali metal, an alkaline earth metal, a group 13 element, a group 14 element, a transition metal, and a rare-earth element, X is an element that is capable of forming a double bond with oxygen, k is a numerical value in the range of 2 to 4.

Abstract: According to one embodiment, an active material for batteries includes monoclinic ?-type titanium composite oxide containing at least one element selected from the group consisting of V, Nb, Ta, Al, Ga, and In, the at least one element being contained in an amount of 0.03 wt % or more and 3 wt % or less.

Abstract: An electrode active material, an electrode including the electrode active material, a lithium battery including the electrode, and a method of preparing the electrode active material. The electrode active material includes a core having at least one of a metal or a metal oxide that enables intercalation and deintercalation of lithium ions and a crystalline carbon thin film that is formed on at least a portion of a surface of the core. The electrode active material has a nano-structure.

Abstract: According to one embodiment, there is provided an active material. The active material includes a titanate oxide compound. The active material has a peak appearing in a range of 1580 cm?1 to 1610 cm?1 in the infrared diffusion reflective spectrum when pyridine is absorbed onto the active material and released from it, after that, the active material is subjected to measurement of the infrared diffusion reflective spectrum. Further, a relationship represented by the following formula (I) is satisfied: S1/S2?2.4 (I). Wherein S1 indicates an area of a peak appearing in a range of 1430 cm?1 to 1460 cm?1 in the spectrum, and S2 indicates an area of a peak appearing in a range of 1520 cm?1 to 1560 cm?1 in the spectrum.

Abstract: There is provided is a lithium ion secondary battery. The lithium ion secondary battery includes: a positive electrode having a positive electrode active material layer containing a positive electrode active material containing a vanadium-based compound; and a negative electrode having a negative electrode active material layer containing a negative electrode active material into which lithium ions can be inserted/deinserted reversibly. A vanadium-based compound is dispersed in the negative electrode active material layer. As a result, a vanadium-based compound, corresponding to the vanadium-based compound contained in the positive electrode active material is dispersed in the negative electrode active material layer.

Abstract: The present invention relates to a process for producing lithium iron phosphate particles, wherein the process has a step of obtaining a melt containing, as represented by mol % based on oxides, from 1 to 50% of Li2O, from 20 to 50% of Fe2O3 and from 30 to 60% of P2O5; a step of cooling and solidifying the melt; a step of pulverizing the solidified product into a desired particle shape; and a step of heating the pulverized product in the air or under oxidizing conditions (0.21<oxygen partial pressure<1.0) at from 350 to 800° C. to precipitate crystals of LinFe2(PO4)3 (0<n<3), in this order.

Abstract: There is provided a positive electrode active material production method, a positive electrode, and a storage device. A production method of a positive electrode active material having a LiVPO4F-type crystal structure and containing carbon, includes: a step of synthesizing a precursor that has VPO4 containing carbon, from a starting material in the form of vanadium pentoxide and a phosphate compound, and from a carbon material as an additive; and a step of synthesizing LiVPO4F containing carbon, from the precursor and LiF. The carbon material as an additive is conductive carbon black having a specific surface area of 700 to 1500 m2/g, and in the step of synthesizing the precursor, an addition amount of the conductive carbon black is less than 2 moles per mole of vanadium pentoxide.

Abstract: The disclosure relates to positive electrode material used for Li-ion batteries, a precursor and process used for preparing such materials, and Li-ion battery using such material in its positive electrode. The disclosure describes a higher density LiCoO2 positive electrode material for lithium secondary batteries, with a specific surface area (BET) below 0.2 m2/g, and a volumetric median particle size (d50) of more than 15 ?m. This product has improved specific capacity and rate-capability. Other embodiments of the disclosure are an aggregated Co(OH)2, which is used as a precursor, the electrode mix and the battery manufactured using above-mentioned LiCoO2.

Abstract: An electrode active material, a method of manufacturing the same, and an electrode and a lithium battery utilizing the same. The electrode active material includes a core capable of intercalating and deintercalating lithium and a coating layer formed on at least a portion of a surface of the core, wherein the coating layer includes a composite metal halide having a spinel structure.

Abstract: This invention relates generally to electrode materials, electrochemical cells employing such materials, and methods of synthesizing such materials. The electrode materials have a crystal structure with a high ratio of Li to metal M, which is found to improve capacity by enabling the transfer of a greater amount of lithium per metal, and which is also found to improve stability by retaining a sufficient amount of lithium after charging. Furthermore, synthesis techniques are presented which result in improved charge and discharge capacities and reduced particle sizes of the electrode materials.

Abstract: A composition including a first material and a metal or a metal oxide component for use in an electrochemical redox reaction is described. The first material is represented by a general formula M1xM2yXO4, wherein M1 represents an alkali metal element; M2 represents an transition metal element; X represents phosphorus; O represents oxygen; x is from 0.6 to 1.4; and y is from 0.6 to 1.4. Further, the metal or the metal oxide component includes at least two materials selected from the group consisting of transition metal elements, semimetal elements, group IIA elements, group IIIA elements, group IVA elements, alloys thereof and oxides of the above metal elements and alloys, wherein the two materials include different metal elements. Moreover, the first material and the metal or the metal oxide component are co-crystallized or physically combined, and the metal or the metal oxide component takes less than about 30% of the composition.

Abstract: According to one embodiment, an active material includes a monoclinic system ?-type titanium composite oxide. The monoclinic system ?-type titanium composite oxide includes a first element including at least one of Mo and W and satisfies the following formula (1): B>A (1) In the formula, A is an intensity of a peak which is derived from (110) plane of the monoclinic system ?-type titanium composite oxide in a wide-angle X-ray diffraction pattern. B is an intensity of a peak which is derived from (002) plane of the monoclinic system ?-type titanium composite oxide in the wide-angle X-ray diffraction pattern.

Abstract: A cylindrical secondary battery including an electrode assembly including a positive electrode having a positive electrode active material layer containing lithium carbonate (Li2CO3), a negative electrode including a negative electrode active material layer, and a separator separating the positive electrode from the negative electrode, a can housing the electrode assembly, a cap assembly disposed on the can, and an electrolyte injected into the can. A content of the lithium carbonate (Li2CO3) is in the range of 1.0 to 1.5 wt % of the total weight of the positive electrode active material layer, a content of the electrolyte is in the range of 10.8 to 11.93 wt % of the total weight of a bare cell, and an operating pressure for interrupting current by the cap assembly is in the range of 7 to 9 kgf/cm2.

Abstract: An electrolyte for a rechargeable lithium battery that includes a non-aqueous organic solvent, a lithium salt, and an electrolyte additive. The electrolyte additive includes 2 to 6 wt % of succinonitrile, 2 to 6 wt % of alkane sultone, and 1 to 3 wt % of vinylethylene carbonate based on the total weight of the electrolyte.

Abstract: An electrode having an oriented array of multiple nanotubes is disclosed. Individual nanotubes have a lengthwise inner pore defined by interior tube walls which extends at least partially through the length of the nanotube. The nanotubes of the array may be oriented according to any identifiable pattern. Also disclosed is a device featuring an electrode and methods of fabrication.

Abstract: An active material for a battery contains a Y2Ti2O5S2 crystalline phase, and has an IB/IA value of 0.3 or smaller and an IC/IA value of 0.15 or smaller, wherein IA, IC and IC are the peak intensity of the Y2Ti2O5S2 crystalline phase at 2?=34.5°, the peak intensity of a Y2T2O7 crystalline phase at 2?35.6°, and the peak intensity of TiS2 at 2?=34.1°, respectively, that are measured by X-ray diffraction using CuK? radiation. The active material is synthesized by preparing a raw material composition containing TiS2, TiO2 and Y2O3 and having a molar ratio of TiS2 to Y2O3 of higher than 1 or containing TiS2, TiO2 and Y2O3 and having a molar ratio of TiO2 to Y2O3 of lower than 1, and heating the raw material composition. A positive or negative-electrode active material layer included in the battery may be contain the active material.

Abstract: An object of the present invention is to provide a cathode active material which contains small-particle sized and low-crystalline lithium transition metal silicate and which undergoes charge-discharge reaction at room temperature. The cathode active material for a non-aqueous electrolyte secondary battery is characterized by containing a lithium transition metal silicate and exhibits diffraction peaks having half widths of 0.175 to 0.6°, the peaks observed through powder X-ray diffractometry within a 2? range of 5 to 50°.

Abstract: A rechargeable lithium-ion battery includes a positive electrode having a first capacity and a negative electrode having a second capacity that is less than the first capacity such that the battery has a negative-limited design. The negative electrode includes a lithium titanate active material. A liquid electrolyte that includes a lithium salt dissolved in at least one non-aqueous solvent a porous polymeric separator are located between the positive electrode and negative electrode. The separator is configured to allow lithium ions to flow through the separator.

Abstract: A composite lithium ion battery electrode is formed from an active composite material dispersed in a conductive porous matrix formed over a current collector. The active composite material includes nano-clusters of an active material dispersed on a conductive skeleton structure. The active material is a metal-based material including one or more of Sn, Al, Si, Ti or a carbon-based material including one or more of graphite, carbon fibers, carbon nanotubes (CNT) or combinations thereof, having a particle size ranging from approximately 1 nanometers to approximately 10 microns. The conductive skeleton includes a conductive polymer or a conductive filament. The active material is dispersed on the conductive skeleton through an in situ polymerization process or a chemical grafting process. The conductive porous matrix includes a conductive polymeric binder and lithium ion diffusion channels created by a pore-forming agent. Conductive particles are further included in the conductive porous matrix.

Abstract: An negative active material for a rechargeable lithium battery includes a nano-composite including a Si phase, a SiO2 phase, and a metal oxide phase of formulation MyO, where M is a metal with an oxidation number x, a free energy of oxygen-bond formation ranging from ?900 kJ/mol to ?2000 kJ/mol, x, and x·y=2. The negative active material for a rechargeable lithium battery according to the present invention can improve initial capacity, initial efficiency, and cycle-life characteristics by suppressing its initial irreversible reaction.