Alkaline Earth Metal Or Magnesium (mg) Component Is Active Material Patents (Class 429/231.6)
-
Patent number: 11489191Abstract: The present invention provides a manufacturing method of a lithium rechargeable battery, including (i) preparing a lithium metal electrode in which metal lithium (Li) is formed on one surface or both surfaces of a current collector; (ii) applying an electrolyte solution for coating including one or more lithium salts, one or more non-aqueous organic solvents, and one or more additives on a surface of the metal lithium to form a passive film which is a stable coat; (iii) manufacturing an electrode assembly including the lithium metal electrode as a negative electrode; and (iv) housing the electrode assembly in a rechargeable battery case and injecting an electrolyte solution for injection including one or more lithium salts, one or more non-aqueous organic solvents, and one or more additives to manufacture a rechargeable battery.Type: GrantFiled: December 14, 2018Date of Patent: November 1, 2022Assignee: LG Energy Solution, Ltd.Inventors: Jongpil Jegal, Hyunjun Choi
-
Patent number: 11271216Abstract: The invention relates to a method of producing electrode materials for solid oxide cells which comprises applying an electric potential to a metal oxide which has a perovskite crystal structure. The resultant electrode catalyst exhibits excellent electrochemical performance. The invention extends to the electrode catalyst itself, and to electrodes and solid oxide cells comprising the electrode catalyst.Type: GrantFiled: July 7, 2017Date of Patent: March 8, 2022Assignee: UNIVERSITY COURT OF THE UNIVERSITY OF ST ANDREWSInventors: John T. S. Irvine, Jae-Ha Myung, Dragos Neagu, David Miller
-
Patent number: 11158856Abstract: An electrode comprises an electrode core. A composite bilayer coating is conformally disposed on the electrode core. The composite bilayer coating comprises a first layer disposed on at least a portion of the electrode core. The first layer comprises a metal fluoride, a metal oxide or a metal sulfide. A second layer is disposed on the first layer and comprises a metal fluoride, a metal oxide or a metal sulfide.Type: GrantFiled: May 1, 2018Date of Patent: October 26, 2021Assignee: UChicago Argonne, LLCInventors: Anil U. Mane, Jason R. Croy, Jeffrey W. Elam, Mahalingam Balasubramanian
-
Patent number: 10886559Abstract: New poly(anhydride)-based polymers have been synthesized. When these polymers are combined with electrolyte salts, such polymer electrolytes have shown excellent electrochemical oxidation stability in lithium battery cells. Their stability along with their excellent ionic transport properties make them especially suitable as electrolytes in high energy density lithium battery cells.Type: GrantFiled: December 12, 2017Date of Patent: January 5, 2021Assignee: Robert Bosch GmbHInventors: Malar Azagarsamy, Kulandaivelu Sivanandan, Hany Basam Eitouni, Jonathan P. Mailoa, Georgy Samsonidze, Karim R. Gadelrab, Boris Kozinsky
-
Patent number: 10535864Abstract: A nonaqueous electrolyte primary battery with improved storage properties at high temperatures and excellent reliability, and a method for producing the battery are provided. The nonaqueous electrolyte primary battery includes a negative electrode containing metallic lithium or a lithium alloy, a positive electrode, a separator, and a nonaqueous electrolyte solution. The nonaqueous electrolyte solution contains at least LiClO4 as an electrolyte and 0.1 to 5% by mass of LiB(C2O4)2.Type: GrantFiled: June 3, 2016Date of Patent: January 14, 2020Assignee: Maxell Holdings, Ltd.Inventor: Yu Sugioka
-
Patent number: 10516160Abstract: An electrode for a lithium secondary battery includes a current collector, primer layer formed on a side of the current collector and includes a first conductive agent, a first binder and a first dispersant. Further, an active material layer is formed on a side of the primer layer disposed opposite to the current collector and includes an active material. Additionally, the lithium secondary battery includes a positive electrode, a negative electrode or both, a separator disposed between the positive electrode and the negative electrode and an electrolyte. The structural stability and adhesion of the electrode is improved, a ratio of a binder in the active material layer is reduced and the internal resistance is reduced.Type: GrantFiled: September 11, 2017Date of Patent: December 24, 2019Assignee: LG Chem, Ltd.Inventors: Seul Ki Kim, Jong Heon Seol, Hee Soo Na, Chan Sub Lee, Hyung Suk Cho, Jung Keun Yoo, Je Young Kim
-
Patent number: 9960467Abstract: A non-aqueous type magnesium oxygen battery including a negative electrode, a positive electrode, a non-aqueous magnesium ion conductor, and a promoter is described. The negative electrode is configured to absorb magnesium and release magnesium ion. The positive electrode is configured to produce a discharge product that includes magnesium and oxygen during a discharge process of the battery. The non-aqueous magnesium on conductor is between the negative electrode and the positive electrode. The promoter is included with the positive electrode. The promoter is configured to promote MgO2 (magnesium peroxide) production during the discharge process of the battery.Type: GrantFiled: December 1, 2015Date of Patent: May 1, 2018Assignees: DENSO CORPORATION, The Regents of The University of MichiganInventors: Junichi Naruse, Donald Siegel, Jeffrey Smith, Gulin Vardar, Charles Monroe
-
Patent number: 9502720Abstract: A seawater power generation system is installed beside an ocean and comprises a seawater processing apparatus, a precipitation apparatus, a separation apparatus and a power generation apparatus. The seawater processing apparatus obtains seawater from the ocean and concentrates the seawater into concentrated seawater. The precipitation apparatus heats the concentrated seawater to form a precipitate of a metal oxide. The separation apparatus heats the metal oxide and reduces the metal oxide into a metal. The power generation apparatus uses the metal as a first electrode and includes a second electrode and an electrolyte contacting the first electrode and the second electrode. Thereby, the seawater is continuously fabricated into the first electrode. The electrolyte respectively reacts with the first electrode and the second electrode in an electrochemical reaction fashion to form a potential difference between the first and second electrode and generate stable electric power.Type: GrantFiled: September 17, 2014Date of Patent: November 22, 2016Assignee: TAIWAN CARBON NANOTUBE TECHNOLOGY CORPORATIONInventors: Chun-Hsien Tsai, Kuang-Che Lee, Chun-Jung Tsai, Ting-Chuan Lee, Yuan-Shin Huang
-
Patent number: 9444094Abstract: An anode active material for a magnesium battery includes a Metal M which electrochemically alloys with magnesium, magnesium, and carbon that are ball milled forming an active material mixture. The mixture may be of the formula: MgaM1-a (0?a<1)+Carbon wherein the mixture is ball milled and has a stoichiometric amount of M and Mg and carbon of from 0.1-50 weight percent of the total mixture.Type: GrantFiled: April 25, 2013Date of Patent: September 13, 2016Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.Inventors: Ruigang Zhang, Fuminori Mizuno
-
Patent number: 9231244Abstract: Provided is a positive electrode active material for lithium ion batteries, which is capable of realizing stability and safety at a high voltage, a high energy density, high load characteristics, and long-term cycle characteristics by controlling a crystal shape of LiMnPO4 particles having a crystal structure very suitable for Li diffusion or controlling an average primary particle size, a production method thereof, an electrode for lithium ion batteries, and a lithium ion battery. The positive electrode active material for lithium ion batteries of the invention is a positive electrode active material for lithium ion batteries, which is formed from LiMnPO4. Values of lattice constants a, b, and c, which are calculated from an X-ray diffraction pattern, satisfy 10.41 ?<a?10.43 ?, 6.070 ?<b?6.095 ?, and 4.730 ?<C?4.745 ?, and an average particle size is 10 to 100 nm.Type: GrantFiled: March 16, 2012Date of Patent: January 5, 2016Assignee: SUMITOMO OSAKA CEMENT CO., LTD.Inventors: Kouji Oono, Satoru Oshitari
-
Publication number: 20150140387Abstract: A biodegradable battery is provided. The battery includes an anode comprising a material including an inner surface and an outer surface, wherein electrochemical oxidation of the anode material results in the formation of a reaction product that is substantially non-toxic and a cathode comprising a material including an inner surface and an outer surface, the inner surface of the cathode being in direct physical contact with the inner surface of the anode, wherein electrochemical reduction of the cathode material results in the formation of a reaction product that is substantially non-toxic, and wherein the cathode material presents a larger standard reduction potential than the anode material.Type: ApplicationFiled: January 23, 2015Publication date: May 21, 2015Inventors: GERALD HODGKINSON, WILLIAM O. POWERS, AHMAD ROBERT HADBA
-
Publication number: 20150140359Abstract: In an aspect, a negative active material, a negative electrode and a lithium battery including the negative active material, and a method of manufacturing the negative active material is provided. The negative active material includes a silicon-based active material substrate; a metal oxide nanoparticle disposed on a surface of the silicon-based active material substrate. An initial irreversible capacity of the lithium battery may be decreased and lifespan characteristics may be improved by using the negative active material.Type: ApplicationFiled: April 25, 2014Publication date: May 21, 2015Applicant: Samsung SDI Co., Ltd.Inventors: Sang-Eun Park, Young-Ugk Kim, Hyun-Ki Park, Chang-Su Shin, Ui-Song Do, Sung-Su Kim
-
Patent number: 9023537Abstract: A positive electrode includes: a positive electrode collector; and a positive electrode active material layer provided on the positive electrode collector and containing a positive electrode active material and an alkaline earth metal carbonate having a fixed form.Type: GrantFiled: April 6, 2011Date of Patent: May 5, 2015Assignee: Sony CorporationInventors: Kentaro Yoshimura, Toru Odani, Tadahiko Kubota
-
Patent number: 9023523Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bMb1Fe1-cMc2Pd-eMe3Ox, wherein Fe has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Al, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, F a: 0.8-1.9, b: 0-0.3, c: 0-0.9, d: 0.8-1.9, e: 0-0.5, x: 1.0-8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state 0, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500° C.Type: GrantFiled: March 16, 2010Date of Patent: May 5, 2015Assignee: BASF SEInventors: Kirill Bramnik, Hartmut Hibst, Jordan Keith Lampert
-
Publication number: 20150111105Abstract: To provide an active material with high capacity, high initial charge-discharge efficiency, and high average discharge voltage. An active material according to the present invention includes a first active material and a second active material, wherein the ratio (?) of the second active material (B) to the total amount by mole of the first active material (A) and the second active material (B) satisfies 0.4 mol %???18 mol % [where ?=(B/(A+B))×100].Type: ApplicationFiled: March 27, 2013Publication date: April 23, 2015Applicant: TDK CORPORATIONInventors: Tomohiko Kato, Atsushi Sano, Masaki Sobu, Akinobu Nojima
-
Patent number: 9012086Abstract: A magnesium ion battery includes a first electrode including a substrate and an active material deposited on the substrate. Also provided is a second electrode. An electrolyte is located between the first electrode and the second electrode. The electrolyte includes a magnesium compound. The active material includes indium and an intermetallic compound of magnesium and indium.Type: GrantFiled: March 5, 2013Date of Patent: April 21, 2015Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.Inventors: Nikhilendra Singh, Masaki Matsui
-
Publication number: 20150104707Abstract: The present disclosure refers to a cathode material composite having improved conductivity, and a cathode and electrochemical device having the cathode material composite. In accordance with one embodiment of the present disclosure, a conductive polymer is positioned on the surface of a shell present in the form of a tetragonal structure in the lithium manganese oxide, thereby enhancing electrical conductivity to be highly involved in reaction around 3V, and providing a conductive path to improve the capacity, life and rate characteristics of an electrochemical device.Type: ApplicationFiled: December 18, 2014Publication date: April 16, 2015Applicant: LG Chem, Ltd.Inventors: Ji-Hye Park, Song-Taek Oh, Hyeok-Moo Lee
-
Patent number: 9005813Abstract: A negative electrode active material, a method of preparing the negative electrode active material and a lithium secondary battery including the negative electrode active material are disclosed. A negative electrode active material includes a lithium titanate, wherein a portion of lithium of the lithium titanate is substituted by at least one selected from the group consisting of Sr, Ba, a mixture thereof and an alloy thereof, and thus a lithium secondary battery including the negative electrode active material may improve high-rate discharge characteristics.Type: GrantFiled: February 2, 2012Date of Patent: April 14, 2015Assignee: Samsung SDI Co., Ltd.Inventors: Jong-Hee Lee, Yong-Mi Yu, Joa-Young Jeong, Jae-Myung Kim
-
Publication number: 20150099175Abstract: The present invention provides an electrode material in which unevenness in a supporting amount of a carbonaceous film is less when using an electrode-active material having a carbonaceous film on a surface thereof as the electrode material, and which is capable of improving conductivity, and a method for producing the electrode material. The electrode material includes an aggregate formed by aggregating an electrode-active material in which a carbonaceous film is formed on a surface. In the electrode material, an average particle size of the aggregate is 0.5 to 100 ?m, a volume density of the aggregate is 50 to 80 vol % of a volume density in a case in which the aggregate is a solid, and 80% or more of the surface of the electrode-active material is covered with the carbonaceous film. Alternatively, the electrode material includes an aggregate formed by aggregating electrode-active material particles in which a carbonaceous film is formed on a surface.Type: ApplicationFiled: December 11, 2014Publication date: April 9, 2015Applicant: SUMITOMO OSAKA CEMENT CO., LTD.Inventors: Takao KITAGAWA, Hirofumi YASUMIISHI, Masaru UEHARA
-
Publication number: 20150099183Abstract: Electrodes employing as active material metal nanoparticles synthesized by a novel route are provided. The nanoparticle synthesis is facile and reproducible, and provides metal nanoparticles of very small dimension and high purity for a wide range of metals. The electrodes utilizing these nanoparticles thus may have superior capability. Electrochemical cells employing said electrodes are also provided.Type: ApplicationFiled: March 19, 2014Publication date: April 9, 2015Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.Inventors: Nikhilendra Singh, Michael Paul Rowe
-
Publication number: 20150099182Abstract: Methods for synthesizing metal nanoparticles and the nanoparticles so produced are provided. The methods include addition of surfactant to a novel reagent complex between zero-valent metal and a hydride. The nanoparticles produced by the method include oxide-free, zero-valent tin nanoparticles useful in fabricating a battery electrode.Type: ApplicationFiled: March 19, 2014Publication date: April 9, 2015Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.Inventors: Nikhilendra Singh, Michael Paul Rowe
-
Patent number: 8999583Abstract: A lithium-ion secondary battery allowed to improve cycle characteristics and initial charge-discharge characteristics is provided. The lithium-ion secondary battery includes a cathode; an anode; and an electrolytic solution. The anode includes an anode active material layer including a plurality of anode active material particles. The anode active material particles each include a core section and a coating section applied to a part or a whole of a surface of the core section, and the core section includes a silicon-based material (SiOx: 0?x<0.5) and the coating section includes an amorphous or low-crystalline silicon-based material (SiOy: 0.5?y?1.8).Type: GrantFiled: December 16, 2010Date of Patent: April 7, 2015Assignee: Sony CorporationInventors: Takakazu Hirose, Kenichi Kawase, Takashi Fujinaga, Masaharu Senoue, Motoki Endo, Masayuki Iwama
-
Patent number: 8999575Abstract: Disclosed is a positive electrode and a lithium battery including the positive electrode. The positive electrode includes a current collector, a first layer irreversibly deintercalating lithium ions, and a second layer allowing reversible intercalation and deintercalation of lithium ions. In one embodiment, the first layer further comprises a first sublayer and a second sublayer, in which the first sublayer is interposed between the current collector and the second sublayer. The first sublayer comprises a first active material represented by Formula 1 Li2Mo1-nR1nO3, and the second sublayer comprises a second active material represented by Formula 2 Li2Ni1-mR2mO2. In Formula 1, 0?n<1; and R1 is selected from the group consisting of manganese (Mn), iron (Fe), cobalt (Co), copper (Cu), zinc (Zn), magnesium (Mg), nickel (Ni), and combinations of at least two of the foregoing elements.Type: GrantFiled: May 5, 2011Date of Patent: April 7, 2015Assignee: Samsung SDI Co., Ltd.Inventors: Soon-Rewl Lee, Ick-Kyu Choi, Young-Ki Kim, Jay-Hyok Song, Young-Hun Lee, Yu-Mi Song, Yoon-Chang Kim
-
Publication number: 20150093641Abstract: Provided is a lithium metal compound oxide having a layered structure, which is very excellent as a positive electrode active material of a battery that is mounted on, particularly, an electric vehicle or a hybrid vehicle. Suggested is a lithium metal compound oxide having a layered structure which is expressed by general formula of Li1+xM1?xO2 (M represents metal elements including three elements of Mn, Co, and Ni). In the lithium metal compound oxide having a layered structure, D50 is more than 4 ?m and less than 20 ?m, a ratio of a primary particle area to a secondary particle area of secondary particles having a size corresponding to the D50 (“primary particle area/secondary particle area”) is 0.004 to 0.035, and the minimum value of powder crushing strength that is obtained by crushing a powder using a microcompression tester is more than 70 MPa.Type: ApplicationFiled: April 16, 2013Publication date: April 2, 2015Inventors: Tetsuya Mitsumoto, Hitohiko Ide, Shinya Kagei, Yoshimi Hata
-
Patent number: 8993163Abstract: A positive electrode active material provided by the present invention is formed of a lithium-nickel-containing metal phosphate compound represented by a general formula: LiNi(1-x)MxPO4(1) (in Formula (1), M is one or more metal elements selected from divalent and trivalent metal elements, and x is a number satisfying the condition 0<x<0.5). At least part of a surface of the lithium-nickel-containing metal phosphate compound is covered with carbon, and the lithium-nickel-containing metal phosphate compound covered with carbon has an olivine-type crystal structure confirmed by structure analysis by X-ray diffraction.Type: GrantFiled: July 31, 2009Date of Patent: March 31, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventor: Jun Yoshida
-
Patent number: 8993167Abstract: Provided is a cathode active material composed of lithium nickel oxide represented by Formula 1, wherein the lithium nickel oxide contains nickel in an amount of 40% or higher, based on the total weight of transition metals, and the cathode active material comprises a first coating layer provided on the surface thereof and a second coating layer provided on the surface of the first coating layer, wherein the first coating layer is composed of a non-reactive material selected from the group consisting of oxides, nitrides, sulfides and mixtures or complexes thereof and the second coating layer is composed of a carbon-based material.Type: GrantFiled: August 6, 2010Date of Patent: March 31, 2015Assignee: LG Chem, Ltd.Inventors: Sung kyun Chang, Hong-Kyu Park, Sinyoung Park
-
Publication number: 20150086859Abstract: A cathode active material for a magnesium secondary battery, the cathode active material including a composite transition metal oxide which is expressed by Chemical Formula 1 and intercalates and deintercalates magnesium: MgxMa1-yMbyO2+d??Chemical Formula 1 wherein 0?x?1, 0.05?y<0.5, and ?0.3?d<1, and Ma and Mb are each independently a metal selected from the group consisting of Groups 5 to 12 of the Periodic Table.Type: ApplicationFiled: January 8, 2014Publication date: March 26, 2015Applicant: Samsung Electronics Co., Ltd.Inventors: Won-seok CHANG, Seok-soo LEE, Ju-sik KIM, Jae-myung LEE, Dong-wook HAN
-
Patent number: 8986887Abstract: A magnesium secondary battery includes: a negative electrode for adsorbing and releasing a magnesium ion; a positive electrode for producing a magnesium oxide product in a discharging process; and a non-aqueous magnesium ion conductor disposed between the negative electrode and the positive electrode. The positive electrode includes an accelerator for promoting the magnesium oxide product, which is decomposed to a magnesium ion and an oxygen molecule easier than MgO. In this case, since the electrochemical reaction at the positive electrode in a charging process rapidly progresses, the magnesium secondary battery can charge and discharge repeatedly. Thus, the battery functions as a secondary battery sufficiently.Type: GrantFiled: August 6, 2013Date of Patent: March 24, 2015Assignee: Denso CorporationInventors: Nobuyoshi Sakakibara, Kenichirou Kami, Norikazu Adachi, Hidehiko Hiramatsu
-
Publication number: 20150079476Abstract: A seawater power generation system is installed beside an ocean and comprises a seawater processing apparatus, a precipitation apparatus, a separation apparatus and a power generation apparatus. The seawater processing apparatus obtains seawater from the ocean and concentrates the seawater into concentrated seawater. The precipitation apparatus heats the concentrated seawater to form a precipitate of a metal oxide. The separation apparatus heats the metal oxide and reduces the metal oxide into a metal. The power generation apparatus uses the metal as a first electrode and includes a second electrode and an electrolyte contacting the first electrode and the second electrode. Thereby, the seawater is continuously fabricated into the first electrode. The electrolyte respectively reacts with the first electrode and the second electrode in an electrochemical reaction fashion to form a potential difference between the first and second electrode and generate stable electric power.Type: ApplicationFiled: September 17, 2014Publication date: March 19, 2015Inventors: Chun-Hsien Tsai, Kuang-Che LEE, Chun-Jung Tsai, Ting-Chuan Lee, Yuan-Shin Huang
-
Publication number: 20150079472Abstract: A method for manufacturing silicon flakes includes steps as follows. A silicon material is contacted with a machining tool which includes at least one abrasive particle fixedly disposed thereon. The silicon material is scraped along a displacement path with respect to the machining tool to generate the silicon flakes having various particle sizes.Type: ApplicationFiled: June 13, 2014Publication date: March 19, 2015Inventors: Kun-Fung LIN, Rong-Ruey JENG, Han-Tu LIN, Chih-Hung CHAN
-
Publication number: 20150072236Abstract: Using metal foams for the electrode of secondary lithium battery, preparing method thereof, and secondary lithium battery including the metal foam. A metal foam is used in an electrode of secondary lithium battery where the surface and the inner pore walls are coated with the active materials, a method of manufacturing such metal foam, and secondary lithium battery including the metal foam.Type: ApplicationFiled: April 18, 2014Publication date: March 12, 2015Inventors: Ji Hyun Um, Hyeji Park, Myounggeun Choi, Hyelim Choi, Yong-Hun Cho, Yung-Eun Sung, Heeman Choe
-
Publication number: 20150064557Abstract: Provided are a cathode active material including lithium transition metal phosphate particles, wherein the lithium transition metal phosphate particles include a first secondary particle formed by agglomeration of two or more first primary particles, and a second secondary particle formed by agglomeration of two or more second primary particles in the first secondary particle, and a method of preparing the same. Since the cathode active material according to an embodiment of the present invention may include first primary particles and second primary particles having different average particle diameters, the exfoliation of the cathode active material from a cathode collector may be minimized and performance characteristics, such as high output characteristics and an increase in available capacity, of a secondary battery may be further improved. In addition, since the first secondary particles are porous, the secondary particles are collapsed and fractured due to rolling when used in a cathode.Type: ApplicationFiled: October 21, 2014Publication date: March 5, 2015Applicant: LG Chem, Ltd.Inventors: Ji Hye Kim, Wang Mo Jung, Sang Seung Oh, Byung Chun Park, Sung Bin Park
-
Publication number: 20150064556Abstract: An electrode for a rechargeable battery and a rechargeable battery, the electrode including a current collector; an electrode active material layer; and an electrolyte solution impregnation layer, wherein the electrolyte solution impregnation layer includes a metal oxide and a conductive material.Type: ApplicationFiled: January 17, 2014Publication date: March 5, 2015Applicant: SAMSUNG SDI CO., LTD.Inventors: Jin-Hyon LEE, Ju-Hee SOHN, Jung-Yeon WON, Eun-Young GOH, Jong-Ki LEE, Sang-In PARK
-
Patent number: 8968934Abstract: The present invention relates to an electrode for a secondary battery, comprising a collector and a porous electrode active material layer disposed on at least one surface of the collector by spraying metal oxide nanoparticle dispersion, wherein the porous electrode active material comprises one selected from the group consisting of aggregated metal oxide nanoparticles, metal oxide nanoparticles and a mixture thereof, which is capable of undergoing stable high speed charging/discharging cycles under a high-energy-density and high-current condition.Type: GrantFiled: October 13, 2009Date of Patent: March 3, 2015Assignee: Korea Institute of Science and TechnologyInventor: Il Doo Kim
-
Patent number: 8962189Abstract: A cathode includes a lithium transition metal complex compound including lithium, one, or two or more transition metals, magnesium, and oxygen as constituent elements. In a standardized X-ray absorption spectrum of the lithium transition metal complex compound measured by an X-ray absorption spectroscopic method, a first absorption edge having absorption edge energy E1 in X-ray absorption intensity of about 0.5 exits in a range where X-ray energy is from about 1303 eV to about 1313 eV both inclusive, in a discharged state in which a discharge voltage is about 3.0 V, and a second absorption edge having absorption edge energy E2 in X-ray absorption intensity of about 0.5 exits, in a charged state in which a charge voltage V is from about 4.3 V to about 4.5 V both inclusive. The absorption edge energies E1 and E2 and the charge voltage V satisfy a relation of E2?E1?(V?4.25)×4.Type: GrantFiled: August 13, 2012Date of Patent: February 24, 2015Assignee: Sony CorporationInventors: Satoshi Fujiki, Hirotaka Fukudome, Kazunari Motohashi, Yosuke Hosoya, Yoshihiro Kudo
-
Publication number: 20150037689Abstract: Provided is a lithium secondary battery with three-dimensional network porous bodies as current collectors in which the internal resistance does not increase even after repeated charging and discharging. A lithium secondary battery including a positive electrode and a negative electrode each having as a current collector a three-dimensional network porous body, the positive electrode and the negative electrode being formed by filling at least an active material into pores of the three-dimensional network porous bodies, wherein the three-dimensional network porous body for the positive electrode is a three-dimensional network aluminum porous body having a hardness of 1.2 GPa or less, and the three-dimensional network porous body for the negative electrode is a three-dimensional network copper porous body having a hardness of 2.6 GPa or less.Type: ApplicationFiled: February 22, 2013Publication date: February 5, 2015Inventors: Junichi Nishimura, Kazuhiro Gotou, Akihisa Hosoe, Kentarou Yoshida
-
Publication number: 20150024269Abstract: The invention relates to electrodes that contain active materials of the formula: AaMb(SO4)cXx wherein A is a single or mixed alkali metal phase comprising one or more of sodium, potassium, lithium mixed with sodium, lithium mixed with potassium or lithium mixed with sodium and potassium; M is selected from one or more transition metals and/or non-transition metals and/or metalloids; X is a moiety comprising one or more atoms selected from halogen and OH; and further wherein 1<a<3; b is in the range: 0<b?2; c is in the range: 2?c?3 and x is in the range 0?x?1. Such electrodes are useful in, for example, sodium ion battery applications.Type: ApplicationFiled: January 30, 2013Publication date: January 22, 2015Inventor: Jeremy Barker
-
Publication number: 20150024280Abstract: In a battery production process, a positive electrode active material having a reaction-suppressing layer that does not easily peel off formed on the surface thereof, and a positive electrode and an all-solid-state battery that use said material are provided. The present invention involves positive electrode active material particles for an all-solid-state battery containing sulfide-based solid electrolyte. The positive electrode active material particles are an aggregate containing two or more particles. The surface of the aggregate is coated with a reaction-suppressing layer for suppressing reactions with the sulfide-based solid electrolyte.Type: ApplicationFiled: May 23, 2011Publication date: January 22, 2015Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Takayuki Uchiyama
-
Publication number: 20150017500Abstract: The present disclosure provides a sheet-form electrode for a secondary battery, comprising a current collector; an electrode active material layer formed on one surface of the current collector; a conductive layer formed on the electrode active material layer and comprising a conductive material and a binder; and a first porous supporting layer formed on the conductive layer. The sheet-form electrode for a secondary battery according to the present disclosure has supporting layers on at least one surfaces thereof to exhibit surprisingly improved flexibility and prevent the release of the electrode active material layer from a current collector even if intense external forces are applied to the electrode, thereby preventing the decrease of battery capacity and improving the cycle life characteristic of the battery.Type: ApplicationFiled: September 4, 2014Publication date: January 15, 2015Applicant: LG Chem, Ltd.Inventors: Yo-Han Kwon, Hye-Ran Jung, Eun-Kyung Kim, Je-Young Kim, Hyo-Mi Kim
-
Publication number: 20150017550Abstract: Provided are a current collector, an electrode, and a nonaqueous electrolyte secondary battery, each of which capable of reducing internal resistance and producing cost. More specifically, provided are: a three-dimensional network metal porous body for a current collector, comprising a sheet-shaped three-dimensional network metal porous body, wherein a degree of porosity of the sheet-shaped three-dimensional network metal porous body is 90% or more and 98% or less, and a 30%-cumulative pore diameter (D30) of the sheet-shaped three-dimensional network metal porous body calculated from a fine pore diameter measurement conducted by a bubble point method is 20 ?m or more and 100 ?m or less; an electrode using the three-dimensional network metal porous body; and a nonaqueous electrolyte secondary battery including the electrode.Type: ApplicationFiled: February 22, 2013Publication date: January 15, 2015Inventors: Junichi Nishimura, Kazuhiro Gotou, Akihisa Hosoe, Kentarou Yoshida
-
Publication number: 20150017527Abstract: The present invention relates to a negative electrode active material for a rechargeable lithium battery, a method for preparing the same, and a rechargeable lithium battery using the same, and provides a negative electrode active material for a rechargeable lithium battery of a carbon-metal complex or a mixture type, containing a carbon-based active material including a first ceramic coating layer, a metal-based active material or a metal-base active material including a first ceramic coating layer, and a carbon-based active material.Type: ApplicationFiled: November 15, 2013Publication date: January 15, 2015Applicant: POSCO CHEMTECH CO., LTD.Inventors: Kyoung Muk LEE, Heon Young LEE, Mi Ryeong LEE, Eun Byeol HYEONG
-
Publication number: 20150017536Abstract: Provided is a non-aqueous electrolyte secondary battery excellent in durability, the non-aqueous electrolyte secondary battery including a positive electrode active material, the surface of which is coated with a film formed of an inorganic solid electrolyte, wherein a change in volume of the positive electrode active material during charge and discharge is reduced to prevent deterioration of the film with which the surface of the positive electrode active material is coated. In a non-aqueous electrolyte secondary battery including a positive electrode active material, the surface of which is coated with a film formed of an inorganic solid electrolyte, the positive electrode active material is a lithium-containing composite oxide having a spinel structure, and contains at least one of Ti and Mg as an additional element.Type: ApplicationFiled: March 9, 2012Publication date: January 15, 2015Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Takeshi Abe, Yoshitomo Takebayashi, Ippei Toyoshima
-
Publication number: 20150017549Abstract: Provided an all-solid lithium secondary battery hardly gives rise to internal resistance even if charging and discharging are repeated. The all-solid lithium secondary battery including a positive electrode and a negative electrode, each of electrodes being an electrode in which a three-dimensional network porous body is used as a current collector and pores of the three-dimensional network porous body are filled with at least an active material, wherein the three-dimensional network porous body of the positive electrode includes an aluminum alloy with a Young's modulus of 70 GPa or higher and the three-dimensional network porous body of the negative electrode includes a copper alloy with a Young's modulus of 120 GPa or higher.Type: ApplicationFiled: February 22, 2013Publication date: January 15, 2015Inventors: Junichi Nishimura, Kazuhiro Gotou, Akihisa Hosoe, Kentarou Yoshida
-
Publication number: 20150003033Abstract: An energy storage device includes an electrode made from an active material in which a plurality of channels have been etched. The channels are coated with an electrically functional substance selected from a conductor and an electrolyte.Type: ApplicationFiled: June 27, 2013Publication date: January 1, 2015Inventors: Yang Liu, Priyanka Pande, Bum Ki Moon, Michael C. Graf, Donald S. Gardner, Nicolas Cirigliano, Shanthi Murali, Zhaohui Chen
-
Publication number: 20150004471Abstract: Ultrafast battery devices having enhanced reliability and power density are provided. Such batteries can include a cathode including a first silicon substrate having a cathode structured surface, an anode including a second silicon substrate having an anode structured surface positioned adjacent to the cathode such that the cathode structured surface faces the anode structured surface, and an electrolyte disposed between the cathode and the anode. The anode structured surface can be coated with an anodic active material and the cathode structured surface can be coated with a cathodic active material.Type: ApplicationFiled: June 28, 2013Publication date: January 1, 2015Inventors: Zhaohui Chen, Yang Liu, Charles W. Holzwarth, Nicolas Cirigliano, Bum Ki Moon
-
Patent number: 8916294Abstract: Lithium rich metal oxyfluorides are described with high specific capacity and, good cycling properties. The materials have particularly good high rate capabilities. The fluorine dopant can be introduced in a low temperature process to yield the materials with desirable cycling properties. In some embodiments, the positive electrode active materials have a composition represented approximately by the formula Li1+xNi?Mn?Co?A?O2?zFz where: x is from about 0.02 to about 0.19, ? is from about 0.1 to about 0.4, ? is from about 0.35 to about 0.869, ? is from about 0.01 to about 0.2, ? is from 0.0 to about 0.1 and z is from about 0.01 to about 0.2, where A is Mg, Zn, Al, Ga, B, Zr, Ti, Ca, Ce, Y, Nb or combinations thereof.Type: GrantFiled: September 29, 2009Date of Patent: December 23, 2014Assignee: Envia Systems, Inc.Inventors: Sujeet Kumar, Herman Lopez, Subramanian Venkatachalam, Deepak Karthikeyan
-
Publication number: 20140370389Abstract: A positive electrode active material includes: center cores containing a composite oxide containing alkali metal or alkali earth metal; and eutectic layers containing a eutectic substance composed of at least two types of composite oxides containing the alkali metal or the alkali earth metal and configured to cover the center cores. Preferably, the eutectic layers have a thickness of 4 nm or larger and 800 nm or smaller. The composite oxides forming the eutectic substance include the composite oxide of the center cores.Type: ApplicationFiled: June 25, 2013Publication date: December 18, 2014Applicant: GREENFUL NEW ENERGY CO., LTD.Inventors: Si MENGQUN, Zhou YING
-
Publication number: 20140370359Abstract: A magnesium cell includes a positive electrode, a negative electrode including a magnesium alloy, and a separator disposed between the positive electrode and the negative electrode to hold an electrolytic solution, in which a contact area between the negative electrode and the separator is variable.Type: ApplicationFiled: June 11, 2014Publication date: December 18, 2014Inventors: Yuhei TATSUMOTO, Yasutaka Tanimura, Tomonobu Tamura, Hiroshi Hiraguchi
-
Publication number: 20140370349Abstract: The present disclosure provides a sheet-form electrode for a secondary battery, comprising a current collector; an electrode active material layer formed on one surface of the current collector; and a first porous supporting layer formed on the electrode active material layer. The sheet-form electrode for a secondary battery according to the present disclosure has supporting layers on at least one surface thereof to exhibit surprisingly improved flexibility and prevent the release of the electrode active material layer from a current collector even if intense external forces are applied to the electrode, thereby preventing the decrease of battery capacity and improving the cycle life characteristic of the battery.Type: ApplicationFiled: August 29, 2014Publication date: December 18, 2014Applicant: LG Chem, Ltd.Inventors: Yo-Han Kwon, Hye-Ran Jung, Eun-Kyung Kim, Je-Young Kim, Hyo-Mi Kim
-
Publication number: 20140370360Abstract: A secondary battery includes a first electrode, a second electrode, an ion transmission member in contact with the first electrode and the second electrode, and a hole transmission member in contact with the first electrode and the second electrode. Suitably, the first electrode contains a composite oxide. The composite oxide contains alkali metal or alkali earth metal. The composite oxide contains a p-type composite oxide as a p-type semiconductor.Type: ApplicationFiled: June 25, 2013Publication date: December 18, 2014Inventors: Si MENGQUN, Zhou YING