Abstract: An improved bipolar separator for electrochemical cells comprising a molded aggregate of an electrically conductive powdered material and a powdered thermosetting resin in a weight ratio of 1:1 to 9:1 and having a resistivity coefficient, in the direction perpendicular to the major surfaces of the separator, of less than 0.3.OMEGA. cm and having the entire surface exposed to the anolyte, except the area of electrical contact with the anode, coated with a layer of a chemically resistant and electrically non-conductive thermosetting resin and electrochemical cells containing the said bipolar separator and method of producing the said bipolar separator.
Abstract: A battery containing an alkaline electrolyte, having within a container, said electrolyte and two electrodes separated by a separator; said separator being made of a partially reticulated polyvinyl acetal produced by the action of at least one aldehyde on polyvinyl alcohol; preferably an aromatic aldehyde, which may also have at least one hydroxyl radical, being used together with formaldehyde.
Abstract: A battery separator is produced from a polyvinyl alcohol sheet structure which is subjected to an in situ, self cross-linking process by selective oxidation of the 1,2 diol units present in the polyvinyl alcohol sheet structure. The 1,2 diol units are cleaved to form aldehyde end groups which subsequently cross-link through acetalization of the 1,3 diol units of the polyvinyl alcohol. Selective oxidation is achieved using a solution of a suitable oxidizing agent such as periodic acid or lead tetraacetate.
Type:
Grant
Filed:
April 19, 1978
Date of Patent:
May 15, 1979
Assignee:
The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
Inventors:
Warren H. Philipp, Li-Chen Hsu, Dean W. Sheibley
Abstract: A battery containing an alkaline electrolyte, having within a container, said electrolyte and two electrodes separated by a separator; said separator being made of a partially reticulated polyvinyl acetal produced by the action of at least one aldehyde on polyvinyl alcohol; preferably an aromatic aldehyde, which may also have at least one hydroxyl radical, being used together with formaldehyde.
Abstract: The invention relates to an improved phenol-aldehyde resole resin composition for battery separators and a fibrous battery separator impregnated with the composition. Said composition comprising a resole resin with particular soluble hydroxy organic salts that do not salt out and improve the oxidation resistance of the battery separators.
Type:
Grant
Filed:
January 21, 1977
Date of Patent:
February 21, 1978
Assignee:
Monsanto Company
Inventors:
William D. Burke, Harold P. Higginbottom, John R. Le Blanc