The Electrolyte Is Solid Patents (Class 429/304)
  • Patent number: 10763542
    Abstract: Provided are an all solid-state secondary battery capable of exhibiting an improved ion-conducting property regardless of troublesome manufacturing steps or special materials, inorganic solid electrolyte particles, a solid electrolyte composition, an electrode sheet for a battery, and a method for manufacturing an all solid-state secondary battery.
    Type: Grant
    Filed: January 11, 2017
    Date of Patent: September 1, 2020
    Assignee: FUJIFILM Corporation
    Inventors: Katsuhiko Meguro, Hiroaki Mochizuki, Masaomi Makino, Tomonori Mimura
  • Patent number: 10658691
    Abstract: Disclosed are a method of manufacturing an inorganic electrolyte membrane and a composition for manufacturing an inorganic electrolyte membrane, the method including: (a) mixing primary inorganic particles (<50 nm), a dispersant, and a solvent and dispersing the primary inorganic particles, thus preparing a dispersion of secondary inorganic particles having a hydrodynamic diameter of 120 to 230 nm, determined using DLS (Dynamic Light Scattering), (b) adding and mixing the dispersion of secondary inorganic particles with a binder, (c) applying a mixed solution composed of the dispersion of inorganic particles and the binder and drying the mixed solution, thus forming a green sheet, and (d) firing the green sheet, thus forming an electrolyte membrane.
    Type: Grant
    Filed: July 30, 2015
    Date of Patent: May 19, 2020
    Assignee: LG CHEM, LTD.
    Inventors: Ki-Youl Yoon, Dong-Oh Shin, Kwang-Wook Choi, Hyeon Choi
  • Patent number: 10622194
    Abstract: A bulk, sintered solid solution-comprising ceramic article useful in semiconductor processing, which is resistant to erosion by halogen-containing plasmas and provides advantageous mechanical properties. The solid solution-comprising ceramic article is formed from a combination of yttrium oxide and zirconium oxide. The bulk, sintered solid solution-comprising article is formed from zirconium oxide at a molar concentration ranging from about 96 mole % to about 94 mole %, and yttrium oxide at a molar concentration ranging from about 4 mole % to about 6 mole %.
    Type: Grant
    Filed: October 20, 2015
    Date of Patent: April 14, 2020
    Assignee: Applied Materials, Inc.
    Inventors: Jennifer Y. Sun, Ren-Guan Duan, Jie Yuan, Li Xu, Kenneth S. Collins
  • Patent number: 10608239
    Abstract: A method for producing an electrode body, suppressing a decrease in capacity of an oxide active material while improving the Li-ion conductance of a sulfide solid electrolyte material. The method producing an electrode body, including a heating step of heating an oxide active material and amorphous sulfide solid electrolyte material in state where the oxide active material and amorphous sulfide solid electrolyte material are in contact with each other, in which the oxide active material is a rock salt bed type active material, the sulfide solid electrolyte material contains a Li element, P element, and S element, and includes an ion conductor containing PS43—as main component of an anion structure, LiI, and LiBr, and heating temperature in the step is equal to or higher than the crystallization onset temperature of the sulfide solid electrolyte material and equal to or lower than the sulfide solid electrolyte material crystallization peak temperature.
    Type: Grant
    Filed: March 2, 2016
    Date of Patent: March 31, 2020
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Tomoya Suzuki
  • Patent number: 10587005
    Abstract: A battery having an anode, a soft-solid electrolyte, and a cathode. The soft-solid electrolyte includes a polymer soft-solid material formed from polymer combined with a solvent such as butylene carbonate, butyl sulfoxide, n-methyl-2-pyrrolidone, or ?-caprolactone.
    Type: Grant
    Filed: March 30, 2016
    Date of Patent: March 10, 2020
    Assignee: Wildcat Discovery Technologies, Inc.
    Inventors: Bin Li, Marissa Caldwell, Prabhakar Tamirisa, Hui Ye
  • Patent number: 10566653
    Abstract: Provided is a lithium-conductive solid-state electrolyte material that comprises a sulfide compound of a composition that does not deviate substantially from a formula of Li9S3N. The compound's conductivity is greater than about 1×10?7 S/cm at about 25° C. and is in contact with a negative electroactive material. Also provided is an electrochemical cell that includes an anode layer, a cathode layer, and the electrolyte layer between the anode and cathode layers. In an example, the material's activation energy can be no greater than about 0.52 eV at about 25° C.
    Type: Grant
    Filed: April 29, 2016
    Date of Patent: February 18, 2020
    Assignees: SAMSUNG ELECTRONICS CO., LTD., MASSACHUSETTS INSTITUTE OF TECHNOLOGY
    Inventors: Lincoln J. Miara, Naoki Suzuki, William D. Richards, Yan E. Wang, Jae Chul Kim, Gerbrand Ceder
  • Patent number: 10541443
    Abstract: (Problem to be Solved) A solid electrolyte material with favorable ion conductivity is demanded from the viewpoint of the higher output of a battery. The present invention was made in view of the above-described problems, with an object of providing a sulfide solid electrolyte material with favorable Li ion conductivity and providing a lithium battery including the sulfide solid electrolyte material. (Solution) There are provided: a solid electrolyte including a sulfide-based solid electrolyte represented by a composition formula: (Li2S)x(MS2)y(P2S5)z, in which M is at least one selected from the group consisting of Ge, Sb, Si, Sn, B, Al, Ga, In, Zr, V, and Nb, and 0.53?x?0.74, 0.13?y?0.37, 0.04?z?0.15, and x+y+z=1 are satisfied; and a lithium battery including the solid electrolyte.
    Type: Grant
    Filed: July 8, 2016
    Date of Patent: January 21, 2020
    Assignees: Tokyo Institute of Technology, Tokyo Jidosha Kabushiki Kaisha
    Inventors: Ryoji Kanno, Yuki Inoue
  • Patent number: 10514581
    Abstract: An electrochromic device comprising a counter electrode layer comprised of lithium metal oxide which provides a high transmission in the fully intercalated state and which is capable of long-term stability, is disclosed. Methods of making an electrochromic device comprising such a counter electrode are also disclosed.
    Type: Grant
    Filed: April 5, 2017
    Date of Patent: December 24, 2019
    Assignees: SAGE ELECTROCHROMICS, INC, ALLIANCE FOR SUSTAINABLE ENERGY, LLC
    Inventors: Dane T. Gillaspie, Douglas G. Weir
  • Patent number: 10501317
    Abstract: The present invention discloses high aspect ratio multifunctional nanocomposite of CNF/polymer comprising of functionalized CNF incorporated with metal nanoparticles and phosphoric acid doped polybenzimidazole (PBI) along the inner and outer surfaces of hollow carbon nanofiber and to a process for fabrication of the same thereof.
    Type: Grant
    Filed: March 24, 2011
    Date of Patent: December 10, 2019
    Assignee: Council of Scientific & Industrial Research
    Inventors: Sreekumar Kurungot, Beena Kalasaparambil Balan, Ulhas Kanhaiyalal Kharul, Vijayamohanan Kunjuukrishna Pillai
  • Patent number: 10461103
    Abstract: Disclosed is a power storage element including a positive electrode current collector layer and a negative electrode current collector layer which are arranged on the same plane and can be formed through a simple process. The power storage element further includes a positive electrode active material layer on the positive electrode current collector layer; a negative electrode active material layer on the negative electrode current collector layer; and a solid electrolyte layer in contact with at least the positive electrode active material layer and the negative electrode active material layer. The positive electrode active material layer and the negative electrode active material layer are formed by oxidation treatment.
    Type: Grant
    Filed: August 15, 2017
    Date of Patent: October 29, 2019
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Kazutaka Kuriki, Ryota Tajima, Tamae Moriwaka
  • Patent number: 10431808
    Abstract: Electrodes and methods of forming electrodes are described herein. The electrode can be an electrode of an electrochemical cell or battery. The electrode includes a current collector and a film in electrical communication with the current collector. The film may include a carbon phase that holds the film together. The electrode further includes an electrode attachment substance that adheres the film to the current collector.
    Type: Grant
    Filed: March 27, 2018
    Date of Patent: October 1, 2019
    Assignee: ENEVATE CORPORATION
    Inventors: Benjamin Yong Park, Ian R. Browne, Stephen W. Schank, Steve Pierce
  • Patent number: 10424778
    Abstract: A material for a positive electrode containing: a positive electrode active material, an inorganic solid electrolyte having conductivity of ions of metals belonging to Group I or II of the periodic table; an auxiliary conductive agent; and a dispersant including a compound having at least one selected from a group of functional groups (I), an electrode sheet for an all-solid state secondary battery and an all-solid state secondary battery for which the material for a positive electrode is used, and methods for manufacturing an electrode sheet for an all-solid state secondary battery and an all-solid state secondary battery. Group of functional groups (I): acidic groups, (meth)acryloyl groups, (meth)acryloyloxy groups, (meth)acrylamide groups, alkoxysilyl groups, epoxy groups, oxetanyl groups, isocyanate groups, cyano groups, and mercapto groups.
    Type: Grant
    Filed: December 1, 2017
    Date of Patent: September 24, 2019
    Assignee: FUJIFILM Corporation
    Inventors: Hiroaki Mochizuki, Tomonori Mimura, Masaomi Makino, Katsuhiko Meguro
  • Patent number: 10411247
    Abstract: A fabrication method of an electrode for an all solid cell includes: providing a sulfide-based solid electrolyte; forming a coating layer on a surface of the sulfide-based solid electrolyte by heating a nonmetallic oxide at 300 to 700° C.; forming electrode slurry by mixing an electrode active material, the sulfide-based solid electrolyte formed with the coating layer, and a conductive material with a polar solvent; casting the electrode slurry on at least one surface of an electrode current collector; removing the polar solvent by heating the cast electrode slurry at 100 to 300° C.; and removing the coating layer by heating the electrode slurry from which the polar solvent is removed at 300 to 700° C.
    Type: Grant
    Filed: December 18, 2017
    Date of Patent: September 10, 2019
    Assignees: Hyundai Motor Company, Kia Motors Corporation, IUCF-HYU (Industry-University Cooperation Foundation Hanyang University)
    Inventors: Oh Min Kwon, Yong Sub Yoon, Sung Woo Noh, Sun Ho Choi, Jin Oh Son, Dong Wook Shin, Chan Hwi Park
  • Patent number: 10354810
    Abstract: The cycle performance of a lithium-ion secondary battery or a lithium-ion capacitor can be obtained by minimizing the decomposition reaction of an electrolytic solution, etc. in the repeated charge and discharge cycles of the lithium-ion secondary battery or the lithium-ion capacitor. An electrode includes a current collector and an active material layer over the current collector. The active material layer includes active material particles, a conductive additive, a binder, and a film containing silicon oxide as its main component. The surface of one of the active material particles includes at least one of a region in contact with the surface of another active material particle, a region in contact with the conductive additive, and a region in contact with the binder. The surface of the active material particle except these regions is at least partly in contact with the film containing silicon oxide as its main component.
    Type: Grant
    Filed: March 11, 2015
    Date of Patent: July 16, 2019
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Tatsuya Ikenuma, Kazutaka Kuriki, Ai Nakagawa
  • Patent number: 10312509
    Abstract: An electrode additive comprising an electrochemically active material in a form of one-dimensional molecular chain is disclosed wherein the electrochemically active material is contained inside a nanotube-formed conductive shell material. An electrode comprising said electrode additive, and the uses of said electrode additive and said electrode are also disclosed.
    Type: Grant
    Filed: November 10, 2014
    Date of Patent: June 4, 2019
    Assignees: Robert Bosch GmbH, Institute of Chemistry, Chinese Academy of Sciences
    Inventors: Chunpeng Yang, NaHong Zhao, Yuguo Guo, Yunhua Chen, Eric Zhang, Yaxia Yin
  • Patent number: 10295881
    Abstract: A synaptic electronic device includes a substrate including a one or more of a semiconductor and an insulator; a photosensitive layer disposed on a surface of the substrate; an electrochromic stack disposed on the photosensitive layer, the electrochromic stack including a first transparent electrode layer, a cathodic electrochromic layer, a solid electrolyte layer, an anodic electrochromic layer, and a second transparent electrode layer; and a pair of electrodes disposed on the photosensitive layer and on opposing sides of the electrochromic stack.
    Type: Grant
    Filed: December 10, 2015
    Date of Patent: May 21, 2019
    Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventor: Shu-Jen Han
  • Patent number: 10288970
    Abstract: The present invention provides a nano smart glass system, including nano smart glass, DC power supply, sensor, and control unit. Wherein, the nano smart glass includes glass and the electrochromic thin-film device; The anode of the DC power supply connects to the at least one conductive anode layer of the electrochromic thin-film device; the cathode of the DC power supply connects to the at least one conductive cathode layer of the electrochromic thin-film device; the DC power supply is used to provide 1V-50V DC voltage to the electrochromic thin-film device; the electrochromic thin-film device adheres to the inside surface of the glass through the at least one conductive cathode layer or the at least one conductive anode layer; The sensor measures outdoor or indoor conditions and send the real-time measurement data to the control unit. The control unit connects to the DC power supply, and it can control the output voltage of the DC power supply to the electrochromic thin-film device.
    Type: Grant
    Filed: May 25, 2012
    Date of Patent: May 14, 2019
    Inventor: Qi Wang
  • Patent number: 10263275
    Abstract: The present invention relates to an all-solid rechargeable battery, a method for manufacturing the same, and an electronic apparatus, makes the annealing step for crystallization unnecessary in the all-solid rechargeable battery. The present invention includes a substrate, a negative electrode, a solid electrolyte, and a positive electrode, wherein LiFePO4 in an amorphous state is used as the positive electrode.
    Type: Grant
    Filed: February 24, 2016
    Date of Patent: April 16, 2019
    Assignee: FUJITSU LIMITED
    Inventors: Satoru Watanabe, Tomochika Kurita
  • Patent number: 10249403
    Abstract: A lithiated carbon phosphonitride material is made by, for example, reacting P(CN)3 with LiN(CN)2 in solution (for example, dimethoxyethane or pyridine), then drying the solution to obtain the product. The material is a thermoset that is stable to over 400° C. and exhibits up to 10?3 S·cm2 of Li+ conductivity.
    Type: Grant
    Filed: June 22, 2017
    Date of Patent: April 2, 2019
    Assignee: The United States of America, as represented by the Secretary of the Navy
    Inventors: Albert Epshteyn, Andrew P. Purdy, Brian L. Chaloux
  • Patent number: 10242888
    Abstract: A solid solution-comprising ceramic article useful in semiconductor processing, which article may be in the form of a solid, bulk ceramic, or may be in the form of a substrate having a ceramic coating of the same composition as the bulk ceramic material on at least one outer surface. The ceramic article is resistant to erosion by halogen-containing plasmas and provides advantageous mechanical properties. The solid solution-comprising ceramic article is formed from a combination of yttrium oxide and zirconium oxide. The ceramic-comprising article includes ceramic which is formed from zirconium oxide at a molar concentration ranging from about 96 mole % to about 91 mole %, and yttrium oxide at a molar concentration ranging from about 4 mole % to about 9 mole %.
    Type: Grant
    Filed: November 26, 2013
    Date of Patent: March 26, 2019
    Assignee: APPLIED MATERIALS, INC.
    Inventors: Jennifer Y. Sun, Ren-Guan Duan, Jie Yuan, Li Xu, Kenneth S. Collins
  • Patent number: 10147944
    Abstract: A cathode includes a cathode collector layer, and a cathode active material layer on a surface of the cathode collector layer. The cathode active material layer includes a sintered polycrystalline material having a plurality of crystal grains of a lithium-based oxide, and each of the plurality of crystal grains includes a seed template, and a matrix crystal around the seed template, where the seed template is a single crystal and having a shape of a plate.
    Type: Grant
    Filed: February 19, 2016
    Date of Patent: December 4, 2018
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Kyunghoon Cho, Seunghoon Nam, Hwiyeol Park, Hojung Yang, Huisu Jeong, Jin S. Heo
  • Patent number: 10128499
    Abstract: A positive electrode active material includes a lithium composite oxide and a zirconium oxide coating layer and a lithium zirconium oxide coating layer that are in a form of sequential layers on the lithium composite oxide.
    Type: Grant
    Filed: November 3, 2016
    Date of Patent: November 13, 2018
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Yumi Song, Mingzi Hong, Gyuran Jeon, Dohyung Park, Minhan Kim, Joongho Moon
  • Patent number: 10090557
    Abstract: An electrochemical cell including a multi-layer solid-state electrolyte, a battery including the cell, and a method of forming the battery and cell are disclosed. The electrolyte includes a first layer that is compatible with the anode of the cell and a second layer that is compatible with the cathode of the cell. The cell exhibits improved performance compared to cells including a single-layer electrolyte.
    Type: Grant
    Filed: March 9, 2016
    Date of Patent: October 2, 2018
    Assignee: The Regents of the University of Colorado, a body corporate
    Inventors: James Trevey, Se-hee Lee, Jae-Ha Woo
  • Patent number: 10056645
    Abstract: An electrolyte including a block copolymer having a first domain and a second domain covalently linked to the first domain, an ionic liquid, an oligomer, an inorganic particle, and a lithium salt, wherein the first domain includes an ion conductive polymer block, and the second domain includes a non-conducting polymer block.
    Type: Grant
    Filed: July 14, 2015
    Date of Patent: August 21, 2018
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Yonggun Lee, Yooseong Yang, Jenam Lee, Hongsoo Choi
  • Patent number: 10056593
    Abstract: An anode structure of a lithium sulfur battery includes a sulfur anode laminated on an aluminum foil, and a carbon coating layer disposed between the sulfur anode and a carbon structure layer in which sulfur is immersed. The sulfur anode includes the sulfur, a conductor, and a binder. The carbon structure layer in which sulfur is immersed is a polyester (PE) separation membrane separated from a counter electrode. A loaded amount of sulfur within the anode structure is dispersed to the sulfur anode and the carbon structure layer in which the sulfur is immersed.
    Type: Grant
    Filed: December 12, 2014
    Date of Patent: August 21, 2018
    Assignee: HYUNDAI MOTOR COMPANY
    Inventors: Sang Jin Park, Hee Yeon Ryu, Yoon Ji Lee, Hee Jin Woo
  • Patent number: 10020536
    Abstract: A method for preparing a sulfide-based solid electrolyte which is stable upon exposure to the air is provided. Specifically, a stabilization layer is formed on the surface of a sulfide-based solid electrolyte particle through treatment with a reactive gas. The sulfide-based solid electrolyte with superior air stability can be obtained because oxidation or reduction reactions with water, etc. in the air occur on the stabilization layer rather than on the sulfide-based solid electrolyte particle.
    Type: Grant
    Filed: January 12, 2017
    Date of Patent: July 10, 2018
    Assignee: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Hyoung Chul Kim, Sung Jun Choi, Jeong Hun Kim, Wo Dum Jung, Hun Gi Jung, Ji Won Son, Jong Ho Lee, Byung Kook Kim, Hae Weon Lee
  • Patent number: 9997765
    Abstract: Electrodes and methods of forming electrodes are described herein. The electrode can be an electrode of an electrochemical cell or battery. The electrode includes a current collector and a film in electrical communication with the current collector. The film may include a carbon phase that holds the film together. The electrode further includes an electrode attachment substance that adheres the film to the current collector.
    Type: Grant
    Filed: October 19, 2017
    Date of Patent: June 12, 2018
    Assignee: Enevate Corporation
    Inventors: Benjamin Yong Park, Ian Russell Browne, Stephen W. Schank, Steve Pierce
  • Patent number: 9991540
    Abstract: A solid oxide fuel cell (SOFC) that includes an anode electrode, a cathode electrode and a solid oxide electrolyte having a fuel inlet riser opening and a fuel outlet riser opening. The electrolyte is located between the anode electrode and the cathode electrode. The SOFC also includes a ceramic support layer on the electrolyte. The ceramic support is layer located around the at least one of a periphery of the electrolyte or at least partially around perimeters of the fuel inlet and fuel outlet riser openings. The ceramic support layer comprises a multi-component material comprising yttria stabilized zirconia (YSZ) and alpha alumina.
    Type: Grant
    Filed: December 15, 2015
    Date of Patent: June 5, 2018
    Assignee: BLOOM ENERGY CORPORATION
    Inventors: Emad El Batawi, Eric Petersen, Richard Stephenson
  • Patent number: 9929433
    Abstract: The problem is to provide a sulfide solid electrolyte material with favorable Li ion conductivity in a low-temperature environment. The problem is overcome by providing a sulfide solid electrolyte material comprising an M1 element (such as an Li element and an Mg element), an M2 element (such as a Ge element and a P element) and a S element, wherein the sulfide solid electrolyte material has a peak at a position of 2?=29.58°±0.50° in X-ray diffraction measurement using a CuK? ray, does not have a peak at a position of 2?=27.33°±0.50° or slightly having the peak, and a substituted amount ?(%) of the divalent element in the M1 element is in such a range that the sulfide solid electrolyte material exhibits higher Li ion conductance at 0° C. than the case of ?=0.
    Type: Grant
    Filed: December 18, 2013
    Date of Patent: March 27, 2018
    Assignees: TOKYO INSTITUTE OF TECHNOLOGY, TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Ryoji Kanno, Masaaki Hirayama, Yuki Kato, Hisatsugu Yamasaki
  • Patent number: 9929404
    Abstract: A non-aqueous electrolyte secondary battery includes: a positive electrode containing a positive active material; a negative electrode; and a non-aqueous electrolyte. The positive active material contains composite oxide particles having a spinel structure including Ni and Mn. The composite oxide particles contain at least one of a crystal phase of LiNbO3 and a crystal phase of LiMg1-xNbxO3. The “x” is higher than 0 and lower than 1. The crystal phase is segregated and located in a surface layer portion of the composite oxide particles.
    Type: Grant
    Filed: August 31, 2015
    Date of Patent: March 27, 2018
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Hikaru Aso
  • Patent number: 9812726
    Abstract: A solid oxide fuel cell includes a solid electrolyte layer, a fuel electrode layer that is disposed on one surface of the solid electrolyte layer, an oxygen electrode layer that is disposed on the other surface of the solid electrolyte layer, and an intermediate layer that is disposed between the solid electrolyte layer and the oxygen electrode layer and that includes ceria-based particles containing rare earth elements other than cerium and ceramic particles consisting of oxide of a metallic element different from that of the ceria-based particles. The ceramic particles having a smaller average particle diameter than that of the ceria-based particles exist in grain boundaries of the ceria-based particles of the intermediate layer.
    Type: Grant
    Filed: January 30, 2013
    Date of Patent: November 7, 2017
    Assignee: KYOCERA Corporation
    Inventor: Shushin Inoue
  • Patent number: 9761908
    Abstract: A sulfide solid electrolyte material with favorable reduction-resistance has a second structural part formed to cover a plurality of first structural parts, a first ion conductor composing the first structural part has a specific crystal phase with favorable ion conductivity, and a weight ratio ? of an Me element to a P element in the second structural part is less than 0.72.
    Type: Grant
    Filed: September 10, 2014
    Date of Patent: September 12, 2017
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Yuki Kato
  • Patent number: 9728808
    Abstract: The main object of the present invention is to provide an all solid state battery in which compatibility between battery performance and safety is intended. The present invention attains the object by providing an all solid state battery comprising a cathode layer containing a cathode active material, an anode layer containing an anode active material, and a solid electrolyte layer formed between the cathode layer and the anode layer, containing a first sulfide solid electrolyte material, characterized in that a ratio of ion resistance of the whole all solid state battery to ion resistance of the solid electrolyte layer is 3.8 or less, and the ion resistance of the solid electrolyte layer is 7.6 ?·cm2 or more and 16 ?·cm2 or less.
    Type: Grant
    Filed: January 29, 2016
    Date of Patent: August 8, 2017
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Koichi Sugiura, Satoshi Yoshida, Hisataka Fujimaki, Yuki Matsushita
  • Patent number: 9722271
    Abstract: A polymer electrolyte membrane includes a fluorinated polymer membrane and a coating layer including a hydrocarbon-based ionomer on at least one surface of the fluorinated polymer membrane. The polymer electrolyte membrane maintains high hydrogen ion conductivity and has improved performance under high temperature and low humidity conditions. A membrane electrode assembly and a fuel cell including the polymer electrolyte membrane are also disclosed.
    Type: Grant
    Filed: June 30, 2014
    Date of Patent: August 1, 2017
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jun-Young Kim, Yeon-Su Kim, Tae-Yoon Kim, Hee-Tak Kim, Jin-Hwa Lee, Bok-Chun Yun
  • Patent number: 9651845
    Abstract: An electrochromic device comprising a counter electrode layer comprised of lithium metal oxide which provides a high transmission in the fully intercalated state and which is capable of long-term stability, is disclosed. Methods of making an electrochromic device comprising such a counter electrode are also disclosed.
    Type: Grant
    Filed: September 19, 2013
    Date of Patent: May 16, 2017
    Assignees: SAGE ELECTROCHROMICS, INC., ALLIANCE FOR SUSTAINABLE ENERGY, LLC
    Inventors: Dane T. Gillaspie, Douglas Glenn John Weir
  • Patent number: 9653758
    Abstract: Provided are a solid electrolyte for a sodium secondary battery, and a surface treatment method thereof, and more specifically, a solid electrolyte for a sodium secondary battery capable of having excellent electrochemical performance by improving wettability with respect to molten sodium, even under a low temperature operation environment of 250° C. or less, and a surface treatment method thereof.
    Type: Grant
    Filed: August 14, 2015
    Date of Patent: May 16, 2017
    Assignee: SK INNOVATION CO., LTD.
    Inventors: Young Shol Kim, Ku Bong Chung, Seung Hwan Jo, Jeong Soo Kim
  • Patent number: 9620772
    Abstract: A lithium-ion battery cathode material includes a composite of sulfur and porous carbon, and glass particles and/or glass ceramic particles that satisfy a composition represented by the following formula (1), LiaMbPcSd??(1) wherein M is B, Zn, Si, Cu, Ga, or Ge, and a to d are the compositional ratio of each element, and satisfy a:b:c:d=1 to 12:0 to 0.2:1:2 to 9.
    Type: Grant
    Filed: December 21, 2011
    Date of Patent: April 11, 2017
    Assignee: IDEMITSU KOSAN CO., LTD.
    Inventors: Hiromichi Koshika, Hiroyuki Higuchi, Atsushi Sato
  • Patent number: 9618473
    Abstract: A gas sensor has a cylindrical housing case, a gas sensor element as a sensor component, and a filler portion. The filler portion is formed between the inner surface of the cylindrical housing case and the outer surface of the gas sensor element. The filler portion is filled with filler powder composed of talc as a layered compound. Talc is a principal ingredient of the filler powder. The space formed between the cylindrical housing case and the gas sensor element is sealed with the filler powder in the filler portion. The filler powder in the filler portion has a degree of c-axis orientation within a range of 60% to 85%, The filler powder in the filler portion has a porosity of not more than 10%.
    Type: Grant
    Filed: June 7, 2012
    Date of Patent: April 11, 2017
    Assignee: DENSO CORPORATION
    Inventor: Kiyomi Kobayashi
  • Patent number: 9620774
    Abstract: A method of manufacturing an electrode, including: a) depositing catalytic growth seeds on an electrically conducting support by aerosol spraying, b) growth of oriented carbon nanotubes on the basis of the deposition of the catalytic growth seeds, c) a deposition of sulphur on the oriented carbon nanotubes formed in b), and d) a deposition of a layer of carbon on the sulphur. An electrode, as well as to a battery including such an electrode, includes an electrically conducting support and oriented carbon nanotubes disposed on the surface of the electrically conducting support and covered at least partly by sulphur, the oriented carbon nanotubes exhibiting a length of greater than 20 ?m, or greater than 50 ?m.
    Type: Grant
    Filed: May 24, 2013
    Date of Patent: April 11, 2017
    Assignee: RENAULT s.a.s.
    Inventor: Aurelien Gohier
  • Patent number: 9601759
    Abstract: To provide: a cathode for secondary batteries, which has a high capacity retention rate; a method for producing a cathode for secondary batteries; and an all-solid-state secondary battery comprising the cathode. This object has been achieved providing by a cathode for secondary batteries, which is characterized by comprising a cathode active material layer containing at least a cathode active material and a solid electrolyte, wherein the cathode active material has an oil absorption amount of 35 to 50 ml per 100 g; wherein the solid electrolyte has an average particle diameter of 1.5 to 2.5 ?m; and wherein the cathode active material layer is formed by mixing the cathode active material and the solid electrolyte in the absence of solvent and pressure-forming the resulting mixture.
    Type: Grant
    Filed: January 14, 2014
    Date of Patent: March 21, 2017
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Toshihiko Inoue
  • Patent number: 9548512
    Abstract: A solid electrolyte for a lithium-sulfur battery includes particles of a lithium ion conducting oxide composition embedded within a lithium ion conducting sulfide composition. The lithium ion conducting oxide composition can be Li7La3Zr2O12 (LLZO). The lithium ion conducting sulfide composition can be ?-Li3PS4 (LPS). A lithium ion battery and a method of making a solid electrolyte for a lithium ion battery are also disclosed.
    Type: Grant
    Filed: December 12, 2013
    Date of Patent: January 17, 2017
    Assignee: UT-Battelle, LLC
    Inventors: Chengdu Liang, Ezhiylmurugan Rangasamy, Nancy J. Dudney, Jong Kahk Keum, Adam Justin Rondinone
  • Patent number: 9543607
    Abstract: A process for producing an ion exchange membrane involves melt-processing a mixture of a perfluorosulfonic acid ionomer in its acid form and a specific azole additive. The additive may be a triazole, alkyl triazole, vinyl triazole, fluoro-alkyl triazole, fluoro-vinyl triazole, pyrazole, alkyl pyrazole, vinyl pyrazole, fluoro-alkyl pyrazole, fluoro-vinyl pyrazole, benzimidazole, alkyl benzimidazole, vinyl benzimidazole, fluoro-alkyl benzimidazole, fluoro-vinyl benzimidazole or any mixture thereof to form a film having a thickness of from 3 to 200 microns. Ion exchange membranes so produced have reduced in-plane-swelling, improved dimensional stability and mechanical properties, and are useful as electrolytes in proton exchange membrane fuel cells.
    Type: Grant
    Filed: February 24, 2014
    Date of Patent: January 10, 2017
    Assignee: National Research Council of Canada
    Inventor: Asmae Mokrini
  • Patent number: 9531010
    Abstract: A flexible paper based battery system with a first a least partially electrically conductive nanomaterial infused paper sheet combined with a first lithium metal oxide electrode sheet disposed in an interference fit between the first infused paper sheet and a dielectric sheet, and a second at least partially electrically conductive nanomaterial infused paper sheet combined with a second lithium metal oxide electrode sheet disposed in an interference fit between the second infused paper sheet and the dielectric sheet. Where the first lithium metal oxide electrode sheet and the second lithium metal oxide sheet are different compositions.
    Type: Grant
    Filed: December 14, 2013
    Date of Patent: December 27, 2016
    Assignee: INDIANA UNIVERSITY RESEARCH AND TECHNOLOGY CORPORATION
    Inventors: Mangilal Agarwal, Khodadad Varahramyan, Sudhir Shrestha, Nojan Aliahmad
  • Patent number: 9502729
    Abstract: An ion-conducting composite electrolyte is provided comprising path-engineered ion-conducting ceramic electrolyte particles and a solid polymeric matrix. The path-engineered particles are characterized by an anisotropic crystalline structure and the ionic conductivity of the crystalline structure in a preferred conductivity direction H associated with one of the crystal planes of the path-engineered particle is larger than the ionic conductivity of the crystalline structure in a reduced conductivity direction L associated with another of the crystal planes of the path-engineered particle. The path-engineered particles are sized and positioned in the polymeric matrix such that a majority of the path-engineered particles breach both of the opposite major faces of the matrix body and are oriented in the polymeric matrix such that the preferred conductivity direction H is more closely aligned with a minimum path length spanning a thickness of the matrix body than is the reduced conductivity direction L.
    Type: Grant
    Filed: August 29, 2012
    Date of Patent: November 22, 2016
    Assignee: Corning Incorporated
    Inventors: Michael Edward Badding, Jacqueline Leslie Brown, Katherine A. Fink, Atanas Valentinov Gagov, Cameron Wayne Tanner
  • Patent number: 9431658
    Abstract: A positive electrode for a lithium battery including a protected negative electrode containing a lithium metal or a lithium alloy, wherein the positive electrode contains a positive electrode active material, a polyoxometalate compound, and a conductive material. Also provided is a lithium battery including the positive electrode.
    Type: Grant
    Filed: April 9, 2014
    Date of Patent: August 30, 2016
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Won-sung Choi, Dong-min Im, Victor Roev, Young-gyoon Ryu, Dong-joon Lee, Seung-sik Hwang
  • Patent number: 9431683
    Abstract: A hermetically sealed lithium secondary battery is provided which has an excellent battery performance and in which a current-interrupt mechanism operates accurately when overcharging occurs. This battery comprising an electrode assembly 80 that has a positive electrode 10. The positive electrode 10 has a positive electrode current collector 12, a positive electrode mixture layer 14 formed on the current collector, and a positive electrode assist layer 16 formed on the current collector and adjacent to the positive electrode mixture layer 14.
    Type: Grant
    Filed: October 2, 2012
    Date of Patent: August 30, 2016
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Koji Takahata
  • Patent number: 9425486
    Abstract: An additive is for extending the useful life-span of the lead acid batteries. The additive is a safe and environmentally harmless material in the form of an aqueous liquid or an easy-to-use capsule. A method refurbishes lead acid batteries and extends their life-span.
    Type: Grant
    Filed: August 26, 2013
    Date of Patent: August 23, 2016
    Assignee: BATTERY SOLUTION INTERNATIONAL LTD.
    Inventor: Emilia Larin
  • Patent number: 9368820
    Abstract: A solid oxide fuel cell has anode, cathode and electrolyte layers each formed essentially of a multi-oxide ceramic material and having a far-from-equilibrium, metastable structure selected from the group consisting of nanocrystalline, nanocomposite and amorphous. The electrolyte layer has a matrix of the ceramic material, and is impervious and serves as a fast oxygen ion conductor. The electrolyte layer has a matrix of the ceramic material and a dopant dispersed therein in an amount substantially greater than its equilibrium solubility in the ceramic matrix. The anode layer includes a continuous surface area metallic phase in which electron conduction is provided by the metallic phase and the multi-oxide ceramic matrix provides ionic conduction.
    Type: Grant
    Filed: November 16, 2012
    Date of Patent: June 14, 2016
    Assignee: NANO CELL SYSTEMS, INC.
    Inventors: Peter R. Strutt, Bernard H. Kear
  • Patent number: 9306240
    Abstract: A solid polymeric electrolyte having a pattern, and a lithium battery including the same, includes a polymer matrix having a mesh structure and being formed of a cured photo-crosslinking agent; inorganic particles substantially uniformly distributed in the polymer matrix; and a liquid electrolyte comprised of a lithium salt and an organic solvent impregnated between the polymer matrix and the inorganic particles. The liquid electrolyte and the cured photo-crosslinking agent are present in a weight ratio ranging from 50:50 to 99:1. The liquid electrolyte containing the cured photo-crosslinking agent and the inorganic particle are present in a weight ratio ranging from 10:90 to 90:10. The solid polymeric electrolyte has properties suitable for a printing process to provide the pattern including a thickness ranging from about 10 nm to about 500 ?m and, prior to curing the photo-crosslinking agent, a viscosity ranging from 100-10,000 poise under a shear rate condition of 1 sec?1.
    Type: Grant
    Filed: April 17, 2015
    Date of Patent: April 5, 2016
    Assignee: ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTE
    Inventors: Young-Gi Lee, Kwang Man Kim, Dong Ok Shin, Kunyoung Kang, Sang-Young Lee, Eun-Hye Kil, Keunho Choi
  • Patent number: 9276265
    Abstract: A lithium-ion cell includes outgoing conductor foils and collectors. The outgoing conductor foil of a negative electrode of the lithium-ion cell consists of an aluminum foil which is covered on both sides with a metal layer. The collector for the negative electrode has an aluminum workpiece, which is at least partially covered with a metal layer. The metal layers of the outgoing conductor foil and of the collector consist of copper or nickel.
    Type: Grant
    Filed: November 22, 2011
    Date of Patent: March 1, 2016
    Assignee: Robert Bosch GmbH
    Inventors: Stephan Leuthner, Thomas Woehrle, Holger Fink, Joachim Fetzer