Plural Organic Solvents (i.e., Solvent Mixture) Patents (Class 429/326)
  • Publication number: 20140342249
    Abstract: A rechargeable lithium metal or lithium-ion cell comprising a cathode having a cathode active material and/or a conductive supporting structure, an anode having an anode active material and/or a conductive supporting nano-structure, a porous separator electronically separating the anode and the cathode, a highly concentrated electrolyte in contact with the cathode active material and the anode active material, wherein the electrolyte contains a lithium salt dissolved in an ionic liquid solvent with a concentration greater than 3 M. The cell exhibits an exceptionally high specific energy, a relatively high power density, a long cycle life, and high safety with no flammability.
    Type: Application
    Filed: May 16, 2013
    Publication date: November 20, 2014
    Inventors: Hui He, Bor Z Jang, Yanbo Wang, Aruna Zhamu
  • Patent number: 8889302
    Abstract: Disclosed is a nonaqueous electrolytic solution which forms a nonaqueous-electrolyte battery having high capacity and excellent storage characteristics at high temperatures, while sufficiently enhancing safety at the time of overcharge, and a nonaqueous-electrolyte battery using the same. The nonaqueous electrolytic solution has an electrolyte and a nonaqueous solvent with (A) a compound of formula (2): wherein R7 is an optionally halogenated and/or phenylated alkyl group comprising 1-12 carbon atoms, R8 to R12 are independently a hydrogen atom, a halogen atom, an optionally halogenated ether or alkyl group comprising 1-12 carbon atoms, and at least one of R8 to R12 is an optionally halogenated alkyl group comprising 2-12 carbon atoms; and/or (B) a carboxylic acid ester with a phenyl group substituted by at least one alkyl group (having 4 or more carbon atoms) that is optionally substituted.
    Type: Grant
    Filed: August 16, 2012
    Date of Patent: November 18, 2014
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yumiko Nakagawa, Minoru Kotato, Daisuke Noda, Shinichi Kinoshita
  • Publication number: 20140335399
    Abstract: Disclosed is an additive for an electrochemical cell wherein the additive includes an N—O bond. The additive is most preferably included in a nonaqueous electrolyte of the cell. Also disclosed are cells and batteries including the additive, and methods of charging the batteries and cells. An electrochemical cell including the additive preferably has an anode that includes lithium and a cathode including an electroactive sulfur-containing material.
    Type: Application
    Filed: July 29, 2014
    Publication date: November 13, 2014
    Inventor: Yuriy V. Mikhaylik
  • Patent number: 8883344
    Abstract: An electrolyte for a lithium secondary battery having flame retardancy, low negative electrode interfacial resistance, and excellent high temperature properties and life characteristics, and a lithium secondary battery including the same. An electrolyte for a lithium secondary battery of the present invention may include a non-aqueous organic solvent, a lithium salt, fluorinated ether or phosphazene, and a resistance-improving additive represented as the following chemical formula (1): FSO2—R1—SO2F??[Chemical Formula 1] wherein R1 is a C1-C12 hydrocarbon unsubstituted or substituted with at least one fluorine.
    Type: Grant
    Filed: October 3, 2011
    Date of Patent: November 11, 2014
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Sinyoung Park, Yongbeom Lee, Sunyoung Kim, Bora Lee
  • Patent number: 8877389
    Abstract: There is provided a lithium secondary cell having specifically excellent discharge capacity, rate characteristics and further cycle characteristics and improved incombustibility (safety). The lithium secondary cell comprises a negative electrode, a non-aqueous electrolytic solution and a positive electrode, in which an active material for the negative electrode comprises lithium titanate and the non-aqueous electrolytic solution comprises a fluorine-containing solvent.
    Type: Grant
    Filed: June 29, 2009
    Date of Patent: November 4, 2014
    Assignee: Daikin Industries, Ltd.
    Inventors: Meiten Koh, Hideo Sakata, Hitomi Nakazawa, Hiroyuki Arima
  • Publication number: 20140322615
    Abstract: It is an object of this exemplary embodiment to provide a lithium ion secondary battery using a positive electrode active material having an operating potential of 4.5 V or more, the lithium ion secondary battery having excellent high temperature cycle characteristics. This exemplary embodiment is a lithium ion secondary battery comprising a positive electrode and a negative electrode capable of intercalating and deintercalating lithium, a separator between the positive electrode and the negative electrode, and an electrolytic solution containing a nonaqueous electrolytic solvent, wherein the positive electrode comprises a positive electrode active material operating at a potential of 4.5 V or more versus lithium, the separator comprises cellulose, a cellulose derivative, or a glass fiber, and the nonaqueous electrolytic solvent comprises a fluorinated solvent.
    Type: Application
    Filed: October 26, 2012
    Publication date: October 30, 2014
    Inventors: Makiko Uehara, Takehiro Noguchi
  • Patent number: 8871391
    Abstract: Method of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electrolytes are composed of ?-Li3PS4 or Li4P2S7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li2S), a first shell of ?-Li3PS4 or Li4P2S7, and a second shell including one of ?-Li3PS4 or Li4P2S7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.
    Type: Grant
    Filed: November 26, 2013
    Date of Patent: October 28, 2014
    Assignee: UT-Battelle, LLC
    Inventors: Chengdu Liang, Zengcai Liu, Wujun Fu, Zhan Lin, Nancy J. Dudney, Jane Y. Howe, Adam J. Rondinone
  • Publication number: 20140315066
    Abstract: The invention relates to an electrolyte battery electrode component having a layer having a surface adjoined by electrolyte in the battery and provided with a fluid-conducting channel structure. In this context, it is envisaged that through the fluid-conducting structure has channels having channel depths in the range from 10 to 200 ?m and/or at least 50% of the thickness of the active layer.
    Type: Application
    Filed: April 12, 2012
    Publication date: October 23, 2014
    Applicant: KARLSRUHER INSTITUT FUR TECHNOLOGIE
    Inventors: Wilhelm Pfleging, Robert Kohler, Johannes Proll
  • Publication number: 20140315104
    Abstract: Cathodes for lithium batteries contain a lithium-manganese cathodic material and from 0.5 to 20% by weight of lithium oxalate. Batteries containing the electrodes tend to exhibit high cycling capacities.
    Type: Application
    Filed: November 30, 2012
    Publication date: October 23, 2014
    Inventors: Wenjuan Liu, Murali G. Theivanayagam, Koichi Numata, Ing-Feng Hu, David R. Wilson, Yiyong He
  • Publication number: 20140315096
    Abstract: In some embodiments, the present disclosure pertains to energy storage compositions that comprise a clay and an ionic liquid. In some embodiments, the clay is a bentonite clay and the ionic liquid is a room temperature ionic liquid (RTIL). In some embodiments, the clay and the ionic liquid are present in the energy storage compositions of the present disclosure in a weight ratio of 1:1. In some embodiments, the ionic liquid further comprises a lithium-containing salt that is dissolved in the ionic liquid. In some embodiments, the energy storage compositions of the present disclosure further comprise a thermoplastic polymer, such as polyurethane. In some embodiments, the thermoplastic polymer constitutes about 10% by weight of the energy storage composition. In some embodiments, the energy storage compositions of the present disclosure are associated with components of energy storage devices, such as electrodes and separators.
    Type: Application
    Filed: February 26, 2014
    Publication date: October 23, 2014
    Applicants: Universidade Federal de Minas Gerais, William Marsh Rice University
    Inventors: Raquel Silveira Borges, Kaushik Kalaga, Marco Tulio Fonseca Rodrigues, Hemtej Gullapalli, Leela Mohana Reddy Arava, Kaushik Balakrishnan, Glaura Goulart Silva, Pulickel M. Ajayan
  • Publication number: 20140308544
    Abstract: A system and method for stabilizing electrodes against dissolution and/or hydrolysis including use of cosolvents in liquid electrolyte batteries for three purposes: the extension of the calendar and cycle life time of electrodes that are partially soluble in liquid electrolytes, the purpose of limiting the rate of electrolysis of water into hydrogen and oxygen as a side reaction during battery operation, and for the purpose of cost reduction.
    Type: Application
    Filed: March 31, 2014
    Publication date: October 16, 2014
    Applicant: Alveo Energy, Inc.
    Inventors: Colin Deane Wessells, Ali Firouzi, Shahrokh Motallebi, Sven Strohband
  • Patent number: 8859145
    Abstract: A primary cell having an anode comprising lithium or lithium alloy and a cathode comprising iron disulfide (FeS2) or a mixture of iron disulfide (FeS2) and iron sulfide (FeS) and conductive carbon particles. A cathode slurry is prepared comprising the FeS2 or FeS2 plus FeS powder, conductive carbon, binder, and a solvent. The binder is preferably a styrene-ethylene/butylene-styrene (SEBS) block copolymer. There is an advantage discovered in utilizing a hydronaphthalene solvent to form the cathode slurry. The preferred solvent is 1,2,3,4-tetrahydronaphthalene or decahydronaphthalene and mixtures thereof. The slurry mixture is coated onto a conductive substrate and the solvent evaporated leaving a dry cathode coating on the substrate. Higher drying temperature may be used resulting in a dry cathode coating which resists cracking. The anode and cathode can be spirally wound with separator therebetween and inserted into the cell casing with electrolyte then added.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: October 14, 2014
    Assignee: The Gillette Company
    Inventors: Maya Stevanovic, Michael Pozin, Yelena Kouznetsova, Steven J. Specht, Fred J. Berkowitz
  • Publication number: 20140302400
    Abstract: For a metal anode in a battery, the capacity fade is a significant consideration. In energy storage devices having an anode that includes Mg, the cycling stability can be improved by an electrolyte having a first salt, a second salt, and an organic solvent. Examples of the organic solvent include diglyme, triglyme, tetraglyme, or a combination thereof. The first salt can have a magnesium cation and be substantially soluble in the organic solvent. The second salt can enhance the solubility of the first salt and can have a magnesium cation or a lithium cation. The first salt, the second salt, or both have a BH4 anion.
    Type: Application
    Filed: April 8, 2013
    Publication date: October 9, 2014
    Applicant: BATTELLE MEMORIAL INSTITUTE
    Inventors: Yuyan Shao, Jun Liu
  • Publication number: 20140295289
    Abstract: According to one embodiment, a nonaqueous electrolyte battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes at least one oxide selected from the group consisting of a first oxide having a spinel structure and represented by LixNi0.5Mn1.5O4, a second metal phosphate having an olivine structure and represented by LixMn1-wFewPO4, and a third oxide having a layered structure and represented by LixNiyMnzCo1-y-zO2. The nonaqueous electrolyte includes a first solvent. The first solvent includes at least one compound selected from the group consisting of trimethyl phosphate, triethyl phosphate, tripropyl phosphate, tributyl phosphate, and fluorinated phosphate ester.
    Type: Application
    Filed: March 7, 2014
    Publication date: October 2, 2014
    Applicant: Kabushiki Kaisha Toshiba
    Inventors: Norio TAKAMI, Hiroki INAGAKI, Takashi KISHI
  • Patent number: 8846254
    Abstract: Disclosed is a nonaqueous electrolytic solution which enables formation of a nonaqueous-electrolyte battery having high capacity and excellent storage characteristics at high temperatures, while sufficiently enhancing safety at the time of overcharge. A nonaqueous-electrolyte battery produced by using the nonaqueous electrolytic solution is also disclosed. The nonaqueous electrolytic solution comprises an electrolyte and a nonaqueous solvent, and includes any of specific nonaqueous electrolytic solutions (A) to (D).
    Type: Grant
    Filed: May 8, 2012
    Date of Patent: September 30, 2014
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yumiko Nakagawa, Minoru Kotato, Daisuke Noda, Shinichi Kinoshita
  • Publication number: 20140272603
    Abstract: An electrolyte solution for a lithium sulfur battery contains a lithium oxalatoborate compound in a 0.05-2 M solution in conventional lithium sulfur battery electrolyte solvents, optionally with other lithium compounds. Examples of solvents include dimethoxyethane (DME), dioxolane, and triethyleneglycol dimethyl ether (TEGDME). Electrochemical cells contain a lithium anode, a sulfur-containing cathode, and a non-aqueous electrolyte containing the lithium oxalatoborate compound. Lithium sulfur batteries contain a casing enclosing a plurality of the cells.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 18, 2014
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Li Yang, Mei Cai, Minghong Liu
  • Publication number: 20140272605
    Abstract: Provided are a non-aqueous electrolyte solution which includes a lithium salt including lithium bis(fluorosulfonyl)imide (LiFSI) and an additive including a vinylene carbonate-based compound and a sultone-based compound, and a lithium secondary battery including the non-aqueous electrolyte solution. The lithium secondary battery including the non-aqueous electrolyte solution of the present invention may improve low-temperature output characteristics, high-temperature cycle characteristics, output characteristics after high-temperature storage, and capacity characteristics.
    Type: Application
    Filed: June 2, 2014
    Publication date: September 18, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Young Min Lim, Chul Haeng Lee, Doo Kyung Yang, Kyoung Ho Ahn, Gwang Yeon Kim
  • Publication number: 20140255793
    Abstract: Functional electrolyte solvents include compounds having at least one aromatic ring with 2, 3, 4 or 5 substituents, at least one of which is a substituted or unsubstituted methoxy group, at least one of which is a tert-butyl group and at least one of which is a substituted or unsubstituted polyether or poly(ethylene oxide) (PEO) group bonded through oxygen to the aromatic ring, are provided.
    Type: Application
    Filed: March 6, 2013
    Publication date: September 11, 2014
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Lu Zhang, Zhengcheng Zhang, Khalil Amine
  • Patent number: 8828610
    Abstract: Disclosed is an additive for an electrochemical cell wherein the additive includes an N—O bond. The additive is most preferably included in a nonaqueous electrolyte of the cell. Also disclosed are cells and batteries including the additive, and methods of charging the batteries and cells. An electrochemical cell including the additive preferably has an anode that includes lithium and a cathode including an electroactive sulfur-containing material.
    Type: Grant
    Filed: April 18, 2008
    Date of Patent: September 9, 2014
    Assignee: Sion Power Corporation
    Inventor: Yuriy V. Mikhaylik
  • Publication number: 20140248542
    Abstract: An electrolyte for a lithium ion secondary battery includes a non-aqueous organic solvent; a lithium salt; and a phosphonitrile fluoride trimer as an additive, and a lithium ion secondary battery comprising the same. The thickness increase rate of a lithium ion secondary battery including the electrolyte is reduced even when the battery is kept at a high temperature. Thus, the thermal stability and durability of the battery are prominently improved. The durability of the battery can be further improved by including a vinylene carbonate or ethylene carbonate group compound in the electrolyte.
    Type: Application
    Filed: May 9, 2014
    Publication date: September 4, 2014
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Jinsung KIM, Narae PARK, Jinhyunk LIM, Suhee HAN, Jinbum KIM, Jungkang OH
  • Patent number: 8822072
    Abstract: A nonaqueous electrolyte includes: a solvent, an electrolyte salt, and at least one of heteropolyacid salt compounds represented by the following formulae (I) and (II): HxAy[BD12O40].zH2O (I), HpAq[B5D30O110].rH2O (II). A represents Li, Na, K, Rb, Cs, Mg, Ca, Al, NH4, or an ammonium salt or phosphonium salt; B represents P, Si, As or Ge; D represents at least one element selected from Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Tc, Rh, Cd, In, Sn, Ta, W, Re and Tl; x, y and z are values falling within the ranges of (0?x?1), (2?y?4) and (0?z?5), respectively; and p, q and r are values falling within the ranges of (0?p?5), (10?q?15) and (0?r?15), respectively.
    Type: Grant
    Filed: February 23, 2011
    Date of Patent: September 2, 2014
    Assignee: Sony Corporation
    Inventors: Ichiro Yamada, Shunsuke Saito, Haruo Watanabe, Tadahiko Kubota
  • Publication number: 20140242472
    Abstract: The present invention relates to a non-aqueous electrolyte solution for a lithium secondary battery, comprising a sulfolane-based additive; and a lithium secondary battery using the same. The non-aqueous electrolyte solution for a lithium secondary battery according to the present invention comprises an ionizable lithium salt; an organic solvent; and a sulfolane compound of formula (I), the sulfolane compound being present in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of the total weight of the lithium salt and the organic solvent. The non-aqueous electrolyte solution for a lithium secondary battery according to the present invention can exhibit superior storage characteristic and life cycle at a high temperature, with maintaining good output characteristic at a low temperature.
    Type: Application
    Filed: May 14, 2014
    Publication date: August 28, 2014
    Applicant: LG Chem, Ltd.
    Inventors: Yu-Ha An, Doo Kyung Yang, Chul-Haeng Lee, Young-Min Lim, Jong-Ho Jeon
  • Patent number: 8815453
    Abstract: The battery has an electrode assembly that includes one or more anodes and one or more cathodes. A first liquid phase is positioned in an active region of the electrode assembly. The first phase includes a first fire retardant and an electrolyte. A second liquid phase is in contact with the first liquid phase. The second liquid phase includes a second fire retardant that is different from the first fire retardant.
    Type: Grant
    Filed: April 5, 2006
    Date of Patent: August 26, 2014
    Assignee: Quallion LLC
    Inventor: Hisashi Tsukamoto
  • Publication number: 20140227611
    Abstract: The object of the present exemplary embodiment is to provide a non-aqueous secondary battery effectively in which the decomposition of an electrolyte liquid is effectively reduced even under high-voltage and high-temperature condition, and which is excellent in the long-term cycle property. The present exemplary embodiment is a non-aqueous secondary battery including an electrolyte liquid including a supporting salt and a non-aqueous electrolyte solvent, wherein the non-aqueous electrolyte solvent includes a sulfone compound represented by a predetermined formula and a fluorine-containing ester compound represented by a predetermined formula; a content of the sulfone compound in the non-aqueous electrolyte solvent is 20 vol % or more and 70 vol % or less; and a content of the fluorine-containing ester compound in the non-aqueous electrolyte solvent is 20 vol % or more and 60 vol % or less.
    Type: Application
    Filed: August 22, 2012
    Publication date: August 14, 2014
    Applicant: NEC CORPORATION
    Inventor: Akinobu Nakamura
  • Publication number: 20140220455
    Abstract: A rechargeable lithium battery including a negative electrode including a silicon-based negative active material; a positive electrode including a positive active material including a sacrificial positive active material selected from lithium nickel oxides, lithium molybdenum oxides, and combinations thereof; and a non-aqueous electrolyte, is disclosed.
    Type: Application
    Filed: July 23, 2013
    Publication date: August 7, 2014
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Soon-Rewl Lee, Ick-Kyu Choi, Young-Ki Kim, Young-Hun Lee, Na-Leum Yoo, Na-Ri Park, Yong-Chul Park
  • Patent number: 8795904
    Abstract: A series of polar and aprotic organic molecules, which, when used as solvents or additives in nonaqueous electrolytes, afford improved performance for electrochemical cells that operate at high voltages. These polar and aprotic solvents or additives may contain at least one unsaturated functionality per molecule. The unsaturated functionality is conjugated with the polar functionality of the molecule. The unsaturated functionality that is either a double or triple bond could be between carbon-carbon, or between carbon-heteroatom, or between hetroatom-heteroatom. Nonaqueous electrolyte solutions are provided comprising one or more lithium salts dissolved in the mixture solvents, which comprises, in all possible ratios, at least one of the polar, aprotic and unsaturated solvent or additives, one or more cyclic carbonic diesters such as ethylene carbonate, and one or more acyclic carbonic diesters such as dimethyl carbonate, diethyl carbonate, and ethylmethyl carbonate.
    Type: Grant
    Filed: January 10, 2011
    Date of Patent: August 5, 2014
    Assignee: The United States of America as Represented by the Secretary of the Army
    Inventor: Kang Conrad Xu
  • Publication number: 20140212770
    Abstract: Disclosed are a non-aqueous electrolytic solution that exhibits excellent electrochemical characteristics over a wide temperature range, and an electrochemical device using the non-aqueous electrolytic solution. The non-aqueous electrolytic solution includes a non-aqueous solvent and an electrolyte salt dissolved in the non-aqueous solvent, wherein the non-aqueous electrolytic solution further comprises one compound represented by general formula (I): wherein R1 represents alkyl having 1 to 6 carbon atoms, cycloalkyl having 3 to 6 carbon atoms, alkenyl having 2 to 6 carbon atoms, alkynyl having 3 to 6 carbon atoms, or aryl having 6 to 12 carbon atoms; X represents a divalent linking group that has 1 to 6 carbon atoms and is optionally substituted by a halogen atom; and Y1 represents a specific substituent, for example, alkylcarbonyl.
    Type: Application
    Filed: August 3, 2012
    Publication date: July 31, 2014
    Applicant: Ulbe industries, Ltd.
    Inventors: Koji Abe, Kei Shimamoto
  • Publication number: 20140205915
    Abstract: An electrolyte for a lithium secondary battery and a lithium secondary battery including the same are provided. The electrolyte includes a non-aqueous organic solvent, lithium salt, and an additive that is either a dicarboxylic acid anhydride and a halogenated ethylene carbonate or a diglycolic acid anhydride and a halogenated ethylene carbonate.
    Type: Application
    Filed: March 19, 2014
    Publication date: July 24, 2014
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Jin Sung Kim, Ha Young Lee, Jinbum Kim, Yongshik Kim, Narae Park, Myungkuk Patk
  • Patent number: 8785015
    Abstract: Disclosed are an electrolyte for a secondary battery, and a secondary battery including the same, the electrolyte including an electrolyte salt; an electrolyte solvent; and a compound generating heat through oxidation at voltages higher than drive voltage of a cathode, wherein the compound can decompose or evaporate electrolyte components by oxidation heat, thereby causing gas generation. Also, the compound is included in an internal pressure increase accelerant for a battery. Upon overcharge, since a compound subjected to oxidation at voltages higher than normal drive voltage of a cathode generates heat, electrolyte components can be decomposed or evaporated, thereby generating gas by the oxidation heat. Accordingly, it is possible to operate a safety means of a battery, without using an internal pressure increasing material directly generating gas through oxidation at overcharge voltage as the electrolyte additive, and thus to improve the overcharge safety of a secondary battery.
    Type: Grant
    Filed: May 15, 2008
    Date of Patent: July 22, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Mi Young Son, Jeong-Ju Cho, Hochun Lee, Joomi Jeon, Sunghoon Yu
  • Publication number: 20140199600
    Abstract: The present invention provides a nonaqueous electrolyte solution, which can improve flame retardancy and ameliorate performances of a battery without deteriorating the basic battery performance as far as possible, and a secondary battery. The nonaqueous electrolyte solution is a nonaqueous electrolyte solution for a secondary battery that contains metal salts including ions of metals belonging to group 1 or 2 of the periodic table and a specific cyclic compound having phosphorus and nitrogen atoms in a non-protonic solvent. The non-protonic solvent is a solvent that contains at least one kind of carboxylic acid ester compound and carbonic acid ester compound, and a ratio (MPN/Ms) between a mass (Ms) of the non-protonic solvent containing the metal salts and a mass (MPN) of the cyclic compound is 0.01 to 1.
    Type: Application
    Filed: March 18, 2014
    Publication date: July 17, 2014
    Applicant: FUJIFILM CORPORATION
    Inventors: Toshihiko YAWATA, Ikuo KINOSHITA
  • Publication number: 20140199599
    Abstract: Disclosed is an electrolyte for a rechargeable lithium battery including an organic solvent; a lithium salt; a flame retardant; and at least one acrylate compound having a fluorinated alkyl group. The electrolyte for a rechargeable battery may provide a rechargeable lithium battery having flame-retardant characteristics without decrease of cycle-life and battery performance.
    Type: Application
    Filed: July 19, 2013
    Publication date: July 17, 2014
    Inventors: Jung-Yi YU, Woo-Cheol SHIN, Sang-IL HAN, Tae-Hyun BAE, Myung-Hwan JEONG, Sang-Geun KIM
  • Publication number: 20140186721
    Abstract: An electrolyte including an alkali metal salt; a polar aprotic solvent; and a triazinane trione; wherein the electrolyte is substantially non-aqueous.
    Type: Application
    Filed: March 4, 2014
    Publication date: July 3, 2014
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Lu Zhang, Zhengcheng Zhang, Khalil Amine
  • Patent number: 8758934
    Abstract: The present disclosure relates to an electrolyte for a lithium secondary battery, comprising a non-aqueous solvent, a lithium salt and an additive having a perfluoroalkyl group. By including the additive having a specific structure in the electrolyte, the output of the lithium secondary battery can be improved greatly.
    Type: Grant
    Filed: December 6, 2013
    Date of Patent: June 24, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Kyoung Ho Ahn, Chul Haeng Lee, Min Jung Kim, Doo Kyung Yang
  • Patent number: 8758946
    Abstract: Electrolyte suitable for use in a lithium ion cell or battery. According to one embodiment, the electrolyte includes a fluorinated lithium ion salt and a solvent system that solvates lithium ions and that yields a high dielectric constant, a low viscosity and a high flashpoint. In one embodiment, the solvent system includes a mixture of an aprotic lithium ion solvating solvent and an aprotic fluorinated solvent.
    Type: Grant
    Filed: October 4, 2007
    Date of Patent: June 24, 2014
    Assignee: Giner, Inc.
    Inventor: Robert C. McDonald
  • Patent number: 8748043
    Abstract: Disclosed is an electrochemical cell comprising a lithium anode and a sulfur-containing cathode and a non-aqueous electrolyte. The cell exhibits high utilization of the electroactive sulfur-containing material of the cathode and a high charge-discharge efficiency.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: June 10, 2014
    Assignee: Sion Power Corporation
    Inventor: Yuriy V. Mikhaylik
  • Patent number: 8748046
    Abstract: An embodiment lithium-ion battery comprising a lithium-ion electrolyte of ethylene carbonate; ethyl methyl carbonate; and at least one solvent selected from the group consisting of trifluoroethyl butyrate, ethyl trifluoroacetate, trifluoroethyl acetate, methyl pentafluoropropionate, and 2,2,2-trifluoroethyl propionate. Other embodiments are described and claimed.
    Type: Grant
    Filed: January 25, 2008
    Date of Patent: June 10, 2014
    Assignees: California Institute of Technology, University of Southern California
    Inventors: Marshall C. Smart, Ratnakumar V. Bugga, G. K. Surya Prakash, Kiah Smith, Pooja Bhalla
  • Publication number: 20140154588
    Abstract: A method for preparing an ionic liquid nanoscale ionic material, the ionic liquid nanoscale ionic material and a battery that includes a battery electrolyte that comprises the ionic liquid nanoscale ionic material each provide superior performance. The superior performance may be manifested within the context of inhibited lithium dendrite formation.
    Type: Application
    Filed: July 10, 2012
    Publication date: June 5, 2014
    Applicant: CORNELL UNIVERSITY
    Inventors: Lynden A. Archer, Surya S. Moganty, Yingying Lu
  • Patent number: 8741479
    Abstract: An electrolyte for a lithium secondary battery including a lithium salt, a nonaqueous organic solvent, and an additive, in which the additive is composed of one or more compounds including a purinone or a purinone derivative. The lithium secondary battery with improved life and high-temperature storage may be provided by using the electrolyte for a lithium secondary battery according to an embodiment of the present invention.
    Type: Grant
    Filed: March 28, 2012
    Date of Patent: June 3, 2014
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Yoon-sok Kang, Jun-young Mun, Min-sik Park, Jin-hwan Park, Mi-jeong Song
  • Patent number: 8741473
    Abstract: A pouch-type lithium secondary battery includes an electrode assembly having an anode made of carbon material capable of occluding or emitting lithium ions, a cathode made of lithium-containing oxide, and a separator interposed between the cathode and the anode for electrical insulation therebetween; a pouch-type case made of sheet to provide a space receiving the electrode assembly; and a non-aqueous electrolyte injected into the electrode assembly. The non-aqueous electrolyte is a non-linear carbonate-based non-aqueous electrolyte including a lithium salt, (a) a cyclic carbonate compound, and (b) a linear ester compound selected from propionate-based compound, methyl butyrate, and propyl acetate, or their mixtures. During LiPF6 IM dissolution, the non-aqueous electrolyte has an ion conductivity of 9 mS/cm or above at about 23° C.
    Type: Grant
    Filed: December 31, 2008
    Date of Patent: June 3, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Ho-Chun Lee, Jeong-Ju Cho, Jong-Ho Jeon
  • Publication number: 20140147754
    Abstract: A magnesium battery electrolyte with a wide electrochemical window was developed. The electrolyte includes an organic boron magnesium salt and an aprotic polar solvent. The organic boron magnesium salt is an organic boron magnesium salt complex formed by compounding a Lewis acid with a boron center and a magnesium-containing Lewis base R?2-nMgXn, wherein n is 0 or 1, R and R? respectively represent a fluoroaryl group, an alkylated aryl group, an aryl group, an alkyl group, or a pyrrolidinyl group, and X represents a halogen. The solvent is an aprotic polar solvent such as ether or a mixed solvent thereof. The concentration of the electrolyte is 0.25 to 1 mol/L, and the electric conductivity is 0.5 to 10 mS/cm. The electrolyte allows reversible deposition/dissolution of magnesium, features good cycling stability, and has a wide electrochemical window (>3.0V vs.Mg/Mg2+).
    Type: Application
    Filed: July 30, 2012
    Publication date: May 29, 2014
    Applicants: SHANGHAI JIAO TONG UNIVERSITY, TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Jun Yang, Yongsheng Guo, Fan Zhang, Feifei Wang
  • Publication number: 20140141342
    Abstract: The present invention relates to an electrolyte for a lithium secondary battery and a lithium secondary battery including the same, wherein the electrolyte comprises an organic solvent and an electrolyte additive, represented by chemical formula 1 and mixed lithium salts in the organic solvent so that room and high temperature life-time properties of the battery can be improved. Said chemical 1 is defined in the specification.
    Type: Application
    Filed: July 12, 2012
    Publication date: May 22, 2014
    Inventors: Hyeong Kyu Lim, Hong Hie Lee, Eun Gi Shim, Jong Su Kim, Chang Sin Lee, Kyung Il Park, Hahn Mok Song
  • Patent number: 8728670
    Abstract: The invention provides a nonaqueous-electrolyte battery which has a positive electrode 3 including a positive active material, a negative electrode 4 including a negative active material having a lithium insertion/release potential higher than 1.0 V (vs. Li/Li+), and a nonaqueous electrolyte, wherein an organic compound having one or more isocyanato groups has been added to the nonaqueous electrolyte.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: May 20, 2014
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hiroki Inagaki, Norio Takami
  • Patent number: 8722255
    Abstract: A non-aqueous electrolytic solution is advantageously used in preparation of a lithium secondary battery excellent in cycle characteristics. In the non-aqueous electrolytic solution for a lithium secondary battery, an electrolyte salt is dissolved in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a vinylene carbonate compound in an amount of 0.01 to 10 wt. %, and an alkyne compound in an amount of 0.01 to 10 wt. %.
    Type: Grant
    Filed: March 27, 2012
    Date of Patent: May 13, 2014
    Assignee: Ube Industries, Ltd.
    Inventors: Koji Abe, Kazuhiro Miyoshi, Takaaki Kuwata
  • Publication number: 20140127594
    Abstract: There is provided an electrolyte solution including a solvent formed from a sulfone, and a magnesium salt dissolved in the solvent.
    Type: Application
    Filed: September 23, 2013
    Publication date: May 8, 2014
    Applicant: Sony Corporation
    Inventors: Yuri Nakayama, Hideki Kawasaki, Hiroyuki Morioka
  • Patent number: 8715863
    Abstract: The battery includes an electrolyte activating one or more cathodes and one or more anodes. The electrolyte includes one or more salts in a solvent. The solvent includes one or more organic solvents and one or more silanes and/or one or more siloxanes.
    Type: Grant
    Filed: March 22, 2007
    Date of Patent: May 6, 2014
    Assignee: Quallion LLC
    Inventors: Zhengcheng Zhang, Phuong-Nghi Karen Lam, Mikito Nagata, Hisashi Tsukamoto
  • Patent number: 8703329
    Abstract: A redox shuttle is provided to prevent overcharge of batteries and/or shuttle current in batteries including high voltage batteries, such as high voltage lithium ion (Li-ion) batteries. An exemplary redox shuttle includes a methylated closo-monocarborate anion.
    Type: Grant
    Filed: March 26, 2012
    Date of Patent: April 22, 2014
    Assignee: Enerdel, Inc.
    Inventors: Thomas Barbarich, Mary Patterson
  • Patent number: 8703344
    Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.
    Type: Grant
    Filed: August 30, 2012
    Date of Patent: April 22, 2014
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Vinay V. Bhat, Gang Cheng, Steven S. Kaye, Bin Li, Risa Olugbile, Jen-Hsien Yang
  • Patent number: 8691449
    Abstract: A nonaqueous electrolyte and a lithium-ion secondary battery using the same, wherein a mixture of a cyclic carbonate, a chain carbonate, a first phosphoric acid ester wherein bonding between carbons is a single bond, and a second phosphoric acid ester wherein bonding between carbons contains a double bond is used as the nonaqueous electrolyte. It is desirable that the first phosphoric acid ester is a trimethyl phosphate. In addition, it is desirable that the second phosphoric acid ester is a dimethylisopropenyl phosphate.
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: April 8, 2014
    Assignee: Hitachi, Ltd.
    Inventors: Toshiyuki Kobayashi, Kazushige Kohno
  • Patent number: 8691448
    Abstract: Provided is a lithium secondary battery comprising an anode, a cathode and a non-aqueous electrolyte, wherein the anode includes an aqueous binder, and the non-aqueous electrolyte contains (a) a cyclic anhydride or a derivative thereof; and (b) any one anion receptor selected from the group consisting of a borane compound, a borate compound and mixtures thereof. According to the present invention, a stable SEI film is formed on the anode, and the life characteristics of the battery are improved by controlling the LiF content in the SEI film.
    Type: Grant
    Filed: February 26, 2010
    Date of Patent: April 8, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Su-Jin Yoon, Sung-Hoon Yu, Jong-Ho Jeon
  • Patent number: 8679683
    Abstract: An electrolytic solution capable of improving battery characteristics even at high temperature, and a battery using the electrolytic solution are provided. A separator is impregnated with an electrolytic solution. The electrolytic solution includes a cyclic imide salt such as 1,1,2,2,3,3-hexafluoropropane-1,3-disulfonimide lithium and a light metal salt such as difluoro[oxalato-O,O?] lithium borate or bis[oxalato-O,O?] lithium borate. Thereby, the decomposition reaction of the electrolytic solution can be prevented even at high temperature, and the battery characteristics can be improved.
    Type: Grant
    Filed: March 12, 2007
    Date of Patent: March 25, 2014
    Assignee: Sony Corporation
    Inventors: Akira Yamaguchi, Atsumichi Kawashima, Masayuki Ihara, Hiroshi Horiuchi, Hiroyuki Yamaguchi, Tadahiko Kubota, Kumiko Takagi