Acyclic Carbonate Solvent Patents (Class 429/342)
  • Publication number: 20140342246
    Abstract: A rechargeable lithium battery includes a positive electrode including a positive active material, a negative electrode including a negative active material and an electrolyte including a lithium salt and a non-aqueous organic solvent, wherein the positive active material includes a nickel-based composite oxide represented by the following Chemical Formula 1, the non-aqueous organic solvent includes ethylene carbonate, and the ethylene carbonate is included in an amount of 7.5 to 27.5 volume % based on the total amount of the non-aqueous organic solvent. LiNixCoyMnzO2??[Chemical Formula 1] (In the above Chemical Formula 1, each x, y and z is the same as defined in the specification.
    Type: Application
    Filed: September 24, 2013
    Publication date: November 20, 2014
    Applicant: Samsung SDI Co., Ltd.
    Inventor: Seung-Mo Kim
  • Publication number: 20140342240
    Abstract: An electrolyte solution for use in a battery includes at least: an ionizable salt; at least one organic solvent; and at least one cyclic phosphazene compound.
    Type: Application
    Filed: May 14, 2014
    Publication date: November 20, 2014
    Inventors: Mason Kurt Harrup, Harry Whittier Rollins, Kevin Leslie Gering, Michael Timothy Benson
  • Patent number: 8889291
    Abstract: A battery realizing the superior cycle characteristics is provided. An electrode includes a current collector including an active-material-layer-formation region and a flat and smooth region having a surface roughness smaller than that of the active-material-layer-formation region, and an active material layer provided in the active-material-layer-formation region of the current collector. An electrode lead is connected to the flat and smooth region.
    Type: Grant
    Filed: November 28, 2007
    Date of Patent: November 18, 2014
    Assignee: Sony Corporation
    Inventors: Masayuki Iwama, Kenichi Kawase, Yoshikazu Kato, Nozomu Morita
  • Publication number: 20140335428
    Abstract: A graphite material having pores which, when 200 rectangular regions of 6 ?m×8 ?m are randomly selected in a surface image of the graphite material observed by a scanning electron microscope, in the surface of the graphite material appearing in the regions, a pore appearing on the surface and having an aperture in a shape having a diameter of 15 nm to 200 nm, a circularity degree of 0.75 to 1.0 and a major axis/minor axis ratio of 1.0 to 1.5 is visible in two regions or more. Also disclosed is a carbon material for battery electrodes, a paste for electrodes, an electrode and a lithium ion secondary battery including the graphite material.
    Type: Application
    Filed: October 19, 2012
    Publication date: November 13, 2014
    Applicant: SHOWA DENKO K.K.
    Inventors: Yasuaki Wakizaka, Yuuichi Kamijou, Masataka Takeuchi, Takayuki Fukai, Chiaki Sotowa, Akinori Sudoh, Masako Tanaka
  • Publication number: 20140335427
    Abstract: An electrolyte for a lithium secondary battery and a lithium secondary battery including the electrolyte are provided. The electrolyte includes a compound represented by Formula 1 below; a nonaqueous organic solvent; and a lithium salt: wherein, in Formula 1, R1, R2, R3, and R4 are each independently a unsubstituted or substituted C1-C20 alkoxy group, a unsubstituted or substituted C1-C20 alkoxyalkyleneoxy group, a unsubstituted or substituted C6-C20 aryloxy group, or R—O—C(?O)— where R is a C1-C20 alkyl group, a C6-C20 aryl group, or a C1-C20 fluoroalkyl group.
    Type: Application
    Filed: September 13, 2013
    Publication date: November 13, 2014
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Makhmut Khasanov, Vladimir Egorov, Pavel Alexandrovich Shatunov, Alexey Tereshchenko, Denis Chernyshov, Jung-Yi Yu, SANG-IL HAN, Sang-Hoon Kim, Duck-Hyun Kim, Myung-Hwan Jeong, Seung-Tae Lee, Tae-Hyun Bae, Mi-Hyun Lee, Eon-Mi Lee, Ha-Rim Lee, Moon-Sung Kim, In-Haeng Cho, E-Rang Cho, Dong-Myung Choi, Woo-Cheol Shin
  • Patent number: 8877390
    Abstract: Compounds may have general Formula IVA or IVB. where, R8, R9, R10, and R11 are each independently selected from H, F, Cl, Br, CN, NO2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z? is a linkage between X and Y. Such compounds may be used as redox shuttles in electrolytes for use in electrochemical cells, batteries and electronic devices.
    Type: Grant
    Filed: May 23, 2011
    Date of Patent: November 4, 2014
    Assignee: UChicago Argonne, LLC
    Inventors: Wei Weng, Zhengcheng Zhang, Khalil Amine
  • Publication number: 20140322616
    Abstract: A non-aqueous electrolyte solution for secondary batteries, comprising a lithium salt (total number of moles of lithium atoms: NLi) and a liquid composition, wherein the liquid composition comprises a specific fluorinated solvent (?) and a cyclic carboxylic acid ester compound (total number of moles: NA), and may contain a specific compound (?) (total number of moles: NB), the content of the fluorinated solvent (?) is from 40 to 80 mass %, NA/NLi is from 1.5 to 7.0, and (NA+NB)/NLi is from 3 to 7.0; and, a lithium ion secondary battery employing such a non-aqueous electrolyte solution for secondary batteries.
    Type: Application
    Filed: March 27, 2014
    Publication date: October 30, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Yu ONOZAKI, Toyokazu ENTA, Masao IWAYA
  • Publication number: 20140315104
    Abstract: Cathodes for lithium batteries contain a lithium-manganese cathodic material and from 0.5 to 20% by weight of lithium oxalate. Batteries containing the electrodes tend to exhibit high cycling capacities.
    Type: Application
    Filed: November 30, 2012
    Publication date: October 23, 2014
    Inventors: Wenjuan Liu, Murali G. Theivanayagam, Koichi Numata, Ing-Feng Hu, David R. Wilson, Yiyong He
  • Publication number: 20140315066
    Abstract: The invention relates to an electrolyte battery electrode component having a layer having a surface adjoined by electrolyte in the battery and provided with a fluid-conducting channel structure. In this context, it is envisaged that through the fluid-conducting structure has channels having channel depths in the range from 10 to 200 ?m and/or at least 50% of the thickness of the active layer.
    Type: Application
    Filed: April 12, 2012
    Publication date: October 23, 2014
    Applicant: KARLSRUHER INSTITUT FUR TECHNOLOGIE
    Inventors: Wilhelm Pfleging, Robert Kohler, Johannes Proll
  • Patent number: 8859143
    Abstract: A surface-enabled, metal ion-exchanging battery device comprising a cathode, an anode, a porous separator, and a metal ion-containing electrolyte, wherein the metal ion is selected from (A) non-Li alkali metals; (B) alkaline-earth metals; (C) transition metals; (D) other metals such as aluminum (Al); or (E) a combination thereof; and wherein at least one of the electrodes contains therein a metal ion source prior to the first charge or discharge cycle of the device and at least the cathode comprises a functional material or nano-structured material having a metal ion-capturing functional group or metal ion-storing surface in direct contact with said electrolyte, and wherein the operation of the battery device does not involve the introduction of oxygen from outside the device and does not involve the formation of a metal oxide, metal sulfide, metal selenide, metal telluride, metal hydroxide, or metal-halogen compound.
    Type: Grant
    Filed: January 3, 2011
    Date of Patent: October 14, 2014
    Assignee: Nanotek Instruments, Inc.
    Inventors: Aruna Zhamu, ChenGuang Liu, David Neff, Bor Z. Jang, Zhenning Yu
  • Publication number: 20140295290
    Abstract: Electrodes and methods of forming electrodes are described herein. The electrode can be an electrode of an electrochemical cell or battery. The electrode includes a current collector and a film in electrical communication with the current collector. The film may include a carbon phase that holds the film together. The electrode further includes an electrode attachment substance that adheres the film to the current collector.
    Type: Application
    Filed: June 11, 2014
    Publication date: October 2, 2014
    Inventors: Benjamin Yong Park, Ian R. Browne, Stephen W. Schank, Steve Pierce
  • Publication number: 20140295298
    Abstract: Some batteries can exhibit greatly improved performance by utilizing electrodes having randomly arranged graphene nanosheets forming a network of channels defining continuous flow paths through the electrode. The network of channels can provide a diffusion pathway for the liquid electrolyte and/or for reactant gases. Metal-air batteries can benefit from such electrodes. In particular Li-air batteries show extremely high capacities, wherein the network of channels allow oxygen to diffuse through the electrode and mesopores in the electrode can store discharge products.
    Type: Application
    Filed: May 6, 2014
    Publication date: October 2, 2014
    Applicant: BATTELLE MEMORIAL INSTITUTE
    Inventors: Jiguang Zhang, Jie Xiao, Jun Liu, Wu Xu, Xiaolin Li, Deyu Wang
  • Publication number: 20140295221
    Abstract: Disclosed are an electrolyte for a secondary battery, and a secondary battery including the same, the electrolyte including an electrolyte salt; an electrolyte solvent; and a compound generating heat through oxidation at voltages higher than drive voltage of a cathode, wherein the compound can decompose or evaporate electrolyte components by oxidation heat, thereby causing gas generation. Also, the compound is included in an internal pressure increase accelerant for a battery. Upon overcharge, since a compound subjected to oxidation at voltages higher than normal drive voltage of a cathode generates heat, electrolyte components can be decomposed or evaporated, thereby generating gas by the oxidation heat. Accordingly, it is possible to operate a safety means of a battery, without using an internal pressure increasing material directly generating gas through oxidation at overcharge voltage as the electrolyte additive, and thus to improve the overcharge safety of a secondary battery.
    Type: Application
    Filed: May 16, 2014
    Publication date: October 2, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Miyoung Son, Jeong-Ju Cho, Hochun Lee, Joomi Jeon, Sunghoon Yu
  • Publication number: 20140287327
    Abstract: The present invention provides a method of coating a substrate for a lithium secondary battery with inorganic particles, comprising charging the inorganic particles to form charged inorganic particles; transferring the charged inorganic particles on the substrate for a lithium secondary battery to form a coating layer; and fixing the coating layer with heat and pressure. Such a coating method according to one embodiment of the present invention uses electrostatic force without the addition of a solvent, and therefore, non use of a solvent can result in cost-reducing effects since there is no burden on the handling and storing of the solvent, and since a drying procedure after slurry coating is not needed, it allows for the preparation of a lithium secondary battery in a highly effective and rapid manner.
    Type: Application
    Filed: June 9, 2014
    Publication date: September 25, 2014
    Inventors: Joo-Sung Lee, Jong-Hun Kim, Jeong-Min Ha, Bo-Kyung Ryu, Jin-Woo Kim
  • Patent number: 8841034
    Abstract: An electrolyte for an electrochemical device according to the present invention has a chemical structure formula represented by a general formula (1): where M is a group 13 or 15 element of the periodic table; A+ is an alkali metal ion or an onium ion; m is a number of 1-4 when M is a group 13 element, and is a number of 1-6 when M is a group 15 element; n is a number of 0-3 when M is a group 13 element, and is a number of 0-5 when M is a group 15 element; R is a halogen atom, a C1-C10 halogenated alkyl group, a C6-C20 aryl group, or a C6-C20 halogenated aryl group; a hydrogen atom in R may be replaced with a specific substituent; and a carbon atom in R may be replaced by a nitrogen atom, a sulfur atom or an oxygen atom.
    Type: Grant
    Filed: March 23, 2010
    Date of Patent: September 23, 2014
    Assignee: Central Glass Company, Limited
    Inventors: Shoichi Tsujioka, Toshinori Mitsui, Yuki Kondo, Aiichiro Fujiwara
  • Publication number: 20140272604
    Abstract: Provided is an electrolyte solution additive including lithium difluorophosphate (LiDFP), a vinylene carbonate-based compound, and a sultone-based compound. Also, a non-aqueous electrolyte solution including the electrolyte solution additive and a lithium secondary battery including the non-aqueous electrolyte solution are provided. The lithium secondary battery including the electrolyte solution additive of the present invention may improve low-temperature output characteristics, high-temperature cycle characteristics, output characteristics after high-temperature storage, and swelling characteristics.
    Type: Application
    Filed: May 29, 2014
    Publication date: September 18, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Young Min Lim, Chul Haeng Lee, Doo Kyung Yang, Yu Ha An
  • Publication number: 20140272601
    Abstract: Salts with formula X?M+ wherein M+ is Li, Na, K, an ammonium, a phosphonium, an imidazolium, a pyridinium, or a pyrazolium and X? is an anion formed from covalent linking of two negative moieties to a positive onium-type core are provided. Also provided are electrolytes and batteries produced from these salts.
    Type: Application
    Filed: November 16, 2012
    Publication date: September 18, 2014
    Inventors: Erlendur Jónsson, Michel Bernard Armand, Jens Patrik Johansson
  • Publication number: 20140272605
    Abstract: Provided are a non-aqueous electrolyte solution which includes a lithium salt including lithium bis(fluorosulfonyl)imide (LiFSI) and an additive including a vinylene carbonate-based compound and a sultone-based compound, and a lithium secondary battery including the non-aqueous electrolyte solution. The lithium secondary battery including the non-aqueous electrolyte solution of the present invention may improve low-temperature output characteristics, high-temperature cycle characteristics, output characteristics after high-temperature storage, and capacity characteristics.
    Type: Application
    Filed: June 2, 2014
    Publication date: September 18, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Young Min Lim, Chul Haeng Lee, Doo Kyung Yang, Kyoung Ho Ahn, Gwang Yeon Kim
  • Publication number: 20140272607
    Abstract: A substantially non-aqueous electrolyte solution includes an alkali metal salt, a polar aprotic solvent, and an organophosphorus compound of Formula IA, IB, or IC: where R1, R2, R3 and R4 are each independently hydrogen, halogen, alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heterocyclyl, heteroaryl, alkoxy, alkenoxy, alkynoxy, cycloalkoxy, aryloxy, heterocyclyloxy, heteroaryloxy, siloxyl, silyl, or organophosphatyl; R5 and R6 are each independently alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heterocyclyl, or heteroaryl; R7 is and R8, R9 and R10 are each independently alkyl, cycloalkyl, aryl, heterocyclyl, or heteroaryl; provided that if the organophosphorus compound is of Formula IB, then at least one of R5, and R6 are other than hydrogen, alkyl, or alkenyl; and if the organophosphorus compound is of Formula IC, then the electrolyte solution does not include 4-methylene-1,3-dioxolan-2-one or 4,5-dimethylene-1,3-dioxolan-2-one.
    Type: Application
    Filed: March 14, 2013
    Publication date: September 18, 2014
    Applicant: UCHICAGO ARGONNE LLC
    Inventors: Khalil Amine, Lu Zhang, Zhengcheng Zhang
  • Publication number: 20140255794
    Abstract: A composite material includes a porous organic polymer and an electrochemically active material, wherein the porous organic polymer contains a plurality of pores having a diameter of from about 0.1 nm to about 100 nm, and the electrochemically active material is disposed within the pores.
    Type: Application
    Filed: March 7, 2013
    Publication date: September 11, 2014
    Applicant: UCHICAGO ARGONNE LLC
    Inventors: Zhengcheng Zhang, Wei Weng, Shengwen Yuan, Khalil Amine
  • Publication number: 20140248543
    Abstract: The present invention relates to nanostructured materials for use in rechargeable energy storage devices such as lithium batteries, particularly rechargeable secondary lithium batteries, or lithium-ion batteries (LIBs). The present invention includes materials, components, and devices, including nanostructured materials for use as battery active materials, and lithium ion battery (LIB) electrodes comprising such nanostructured materials, as well as manufacturing methods related thereto. Exemplary nanostructured materials include silicon-based nanostructures such as silicon nanowires and coated silicon nanowires, nanostructures disposed on substrates comprising active materials or current collectors such as silicon nanowires disposed on graphite particles or copper electrode plates, and LIB anode composites comprising high-capacity active material nanostructures formed on a porous copper and/or graphite powder substrate.
    Type: Application
    Filed: October 2, 2012
    Publication date: September 4, 2014
    Applicant: OneD Material LLC
    Inventors: Yimin Zhu, Chunsheng Du, Joon Shin
  • Publication number: 20140242472
    Abstract: The present invention relates to a non-aqueous electrolyte solution for a lithium secondary battery, comprising a sulfolane-based additive; and a lithium secondary battery using the same. The non-aqueous electrolyte solution for a lithium secondary battery according to the present invention comprises an ionizable lithium salt; an organic solvent; and a sulfolane compound of formula (I), the sulfolane compound being present in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of the total weight of the lithium salt and the organic solvent. The non-aqueous electrolyte solution for a lithium secondary battery according to the present invention can exhibit superior storage characteristic and life cycle at a high temperature, with maintaining good output characteristic at a low temperature.
    Type: Application
    Filed: May 14, 2014
    Publication date: August 28, 2014
    Applicant: LG Chem, Ltd.
    Inventors: Yu-Ha An, Doo Kyung Yang, Chul-Haeng Lee, Young-Min Lim, Jong-Ho Jeon
  • Publication number: 20140242475
    Abstract: An object of the present invention is to provide a battery having excellent durability at high temperature and high voltage. The present invention is a battery including a positive electrode, a negative electrode and a non-aqueous electrolyte, wherein the non-aqueous electrolyte contains (i) a compound represented by the general formula (1): Rf—SO2F??(1) (where Rf is a C1-13 linear or branched fluorine-containing alkyl group optionally containing an ether bond and optionally containing a double bond).
    Type: Application
    Filed: October 3, 2012
    Publication date: August 28, 2014
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Meiten Koh, Aoi Nakazono, Hitomi Miyawaki, Hideo Sakata
  • Publication number: 20140242474
    Abstract: Disclosed is a high-capacity electrochemical energy storage device in which a conversion reaction proceeds as the oxidation-reduction reaction, and the separation (hysteresis) between the electrode potentials for oxidation and reduction is small. The electrochemical energy storage device includes a first electrode including a first active material, a second electrode including a second active material, and a non-aqueous electrolyte interposed between the first and second electrodes. At least one of the first and second active materials is a metal salt having a polyatomic anion and a metal ion, and the metal salt is capable of oxidation-reduction reaction involving reversible release and acceptance of the polyatomic anion.
    Type: Application
    Filed: March 11, 2013
    Publication date: August 28, 2014
    Applicant: PANASONIC CORPORATION
    Inventors: Tooru Matsui, Zempachi Ogumi, Toshiro Hirai, Akiyoshi Nakata
  • Publication number: 20140234696
    Abstract: A non-aqueous secondary battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution includes a non-aqueous solvent, an electrolyte salt, and one or both of a disulfonyl compound represented by a following Formula (1) and a disulfinyl compound represented by a following Formula (2), where R1 is one of a hydrocarbon group, a halogenated hydrocarbon group, an oxygen-containing hydrocarbon group, a halogenated oxygen-containing hydrocarbon group, and a group obtained by bonding two or more thereof to one another; and X1 is a halogen group, where R2 is one of a hydrocarbon group, a halogenated hydrocarbon group, an oxygen-containing hydrocarbon group, a halogenated oxygen-containing hydrocarbon group, and a group obtained by bonding two or more thereof to one another; and X2 is a halogen group.
    Type: Application
    Filed: February 7, 2014
    Publication date: August 21, 2014
    Applicant: SONY CORPORATION
    Inventors: Tomomi Sakuma, Midori Sugawara, Toru Odani
  • Publication number: 20140234729
    Abstract: A non-aqueous liquid electrolyte for a secondary battery, containing an electrolyte, and at least one or more cyclopropane compound selected from the group consisting of a compound represented by the following formula (I-1), a compound represented by the following formula (II-1), and a compound represented by the following formula (III-1) in an organic solvent, wherein R11 to R15, R21 to R24 and R31 to R34 represent a hydrogen or a specific substituent; L11, L21, L31 and L32 represent a specific linking group; X represents an electron-withdrawing group; and n and m each independently represent 1 or 2.
    Type: Application
    Filed: April 25, 2014
    Publication date: August 21, 2014
    Applicant: FUJIFILM Corporation
    Inventors: Yoshinori KANAZAWA, Tatsuya IGARASHI
  • Patent number: 8808915
    Abstract: The rechargeable lithium battery includes a positive electrode which includes a positive active material, a negative electrode, and an electrolyte which includes a non-aqueous organic solvent and a lithium salt. The positive active material includes a core including at least one of a compound represented by Formula 1 and a compound represented by Formula 2, and a surface-treatment layer which is formed on the core and includes a compound represented by Formula 3. The lithium salt includes LiPF6 and a lithium imide-based compound. LiaNibCocMndMeO2??(1) LihMn2MiO4??(2) M?xPyOz??(3) wherein each of M and M? is independently selected from the group consisting of an alkali metal, an alkaline-earth metal, a Group 13 element, a Group 14 element, a transition element, a rare earth element, and combinations thereof, 0.95?a?1.1, 0?b?0.999, 0?c?0.999, 0?d?0.999, 0.001?e?0.2, 0.95?h?1.1, 0.001?i?0.2, 1?y?4, 0?y?7, and 2?z?30.
    Type: Grant
    Filed: August 10, 2007
    Date of Patent: August 19, 2014
    Assignee: Samsung SDI Co., Ltd.
    Inventors: So-Hyun Hur, Euy-Young Jung, Duck-Chul Hwang, Yong-Chul Park, Jong-Hwa Lee, Jeom-Soo Kim, Jae-Yul Ryu, Jin-Bum Kim
  • Patent number: 8808918
    Abstract: The rechargeable lithium battery of the present invention includes a positive electrode including a positive active material, a negative electrode including a negative active material, and a non-aqueous electrolyte. The positive active material includes a core and a coating layer formed on the core. The core is made of a material such as LiCo0.98M?0.02O2, and the coating layer is made of a material such as MxPyOz. The electrolyte solution includes a nitrile-based additive. The rechargeable lithium battery of the present invention shows higher cycle-life characteristics and longer continuous charging time at high temperature.
    Type: Grant
    Filed: June 12, 2007
    Date of Patent: August 19, 2014
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Euy-Young Jung, Duck-Chul Hwang, Jeom-Soo Kim, Jong-Hwa Lee, Yong-Chul Park, Jae-Yul Ryu, So-Hyun Hur
  • Publication number: 20140220455
    Abstract: A rechargeable lithium battery including a negative electrode including a silicon-based negative active material; a positive electrode including a positive active material including a sacrificial positive active material selected from lithium nickel oxides, lithium molybdenum oxides, and combinations thereof; and a non-aqueous electrolyte, is disclosed.
    Type: Application
    Filed: July 23, 2013
    Publication date: August 7, 2014
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Soon-Rewl Lee, Ick-Kyu Choi, Young-Ki Kim, Young-Hun Lee, Na-Leum Yoo, Na-Ri Park, Yong-Chul Park
  • Publication number: 20140220456
    Abstract: The present application is generally directed to energy storage materials such as activated carbon comprising enhanced particle packing properties and devices containing the same. The energy storage materials find utility in any number of devices, for example, in electric double layer capacitance devices and batteries. Methods for making the energy storage materials are also disclosed.
    Type: Application
    Filed: January 8, 2014
    Publication date: August 7, 2014
    Applicant: EnerG2 Technologies, Inc.
    Inventors: Henry R. Costantino, Chad Goodwin, William D. Scott, Aaron M. Feaver
  • Publication number: 20140212771
    Abstract: The present invention relates to an electrode material for an electrical cell comprising activated carbon fibers as component (A) which have been impregnated with elemental sulfur as component (B). The present invention further relates to rechargeable electrical cells comprising at least one electrode which has been produced from or using the inventive electrode material and to a process for producing said inventive electrode material.
    Type: Application
    Filed: August 14, 2012
    Publication date: July 31, 2014
    Applicant: BASF SE
    Inventors: Arnd Garsuch, Alexander Panchenko, Doron Aurbach, Ran Elazari, Gregory Salitra
  • Publication number: 20140212770
    Abstract: Disclosed are a non-aqueous electrolytic solution that exhibits excellent electrochemical characteristics over a wide temperature range, and an electrochemical device using the non-aqueous electrolytic solution. The non-aqueous electrolytic solution includes a non-aqueous solvent and an electrolyte salt dissolved in the non-aqueous solvent, wherein the non-aqueous electrolytic solution further comprises one compound represented by general formula (I): wherein R1 represents alkyl having 1 to 6 carbon atoms, cycloalkyl having 3 to 6 carbon atoms, alkenyl having 2 to 6 carbon atoms, alkynyl having 3 to 6 carbon atoms, or aryl having 6 to 12 carbon atoms; X represents a divalent linking group that has 1 to 6 carbon atoms and is optionally substituted by a halogen atom; and Y1 represents a specific substituent, for example, alkylcarbonyl.
    Type: Application
    Filed: August 3, 2012
    Publication date: July 31, 2014
    Applicant: Ulbe industries, Ltd.
    Inventors: Koji Abe, Kei Shimamoto
  • Publication number: 20140199601
    Abstract: The present invention aims to provide an additive for a non-aqueous electrolyte solution with excellent storage stability capable of forming a stable SEI on the surface of an electrode to improve cell performance such as a cycle performance, a discharge/charge capacity, and internal resistance, when the additive is used for electrical storage devices such as non-aqueous electrolyte solution secondary cells and electric double layer capacitors. The present invention also aims to provide a non-aqueous electrolyte solution containing the additive for a non-aqueous electrolyte solution and to provide an electrical storage device using the non-aqueous electrolyte solution.
    Type: Application
    Filed: July 6, 2012
    Publication date: July 17, 2014
    Applicant: SUMITOMO SEIKA CHEMICALS CO., LTD.
    Inventors: Tomohiro Onozuka, Shohei Fujimoto, Koji Fujita
  • Patent number: 8771882
    Abstract: There is provided a method for producing an electrolyte solution for lithium ion batteries, in which lithium hexafluorophosphate is used as an electrolyte, comprising the steps of (a) reacting phosphorus trichloride, chlorine and lithium chloride in a nonaqueous organic solvent; and (b) reacting a reaction product of the step (a) formed in the solvent, with hydrogen fluoride.
    Type: Grant
    Filed: November 7, 2006
    Date of Patent: July 8, 2014
    Assignee: Central Glass Company, Limited
    Inventors: Keiji Sato, Meguru Oe
  • Patent number: 8771879
    Abstract: A lithium-sulfur battery is disclosed in one embodiment of the invention as including an anode containing lithium and a cathode comprising elemental sulfur. The cathode may include at least one solvent selected to at least partially dissolve the elemental sulfur and Li2Sx. A substantially non-porous lithium-ion-conductive membrane is provided between the anode and the cathode to keep sulfur or other reactive species from migrating therebetween. In certain embodiments, the lithium-sulfur battery may include a separator between the anode and the non-porous lithium-ion-conductive membrane. This separator may prevent the lithium in the anode from reacting with the non-porous lithium-ion-conductive membrane. In certain embodiments, the separator is a porous separator infiltrated with a lithium-ion-conductive electrolyte.
    Type: Grant
    Filed: September 5, 2008
    Date of Patent: July 8, 2014
    Assignee: Ceramatec, Inc.
    Inventors: John Howard Gordon, John Joseph Watkins
  • Publication number: 20140186721
    Abstract: An electrolyte including an alkali metal salt; a polar aprotic solvent; and a triazinane trione; wherein the electrolyte is substantially non-aqueous.
    Type: Application
    Filed: March 4, 2014
    Publication date: July 3, 2014
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Lu Zhang, Zhengcheng Zhang, Khalil Amine
  • Publication number: 20140178770
    Abstract: The Coulombic efficiency of lithium deposition/stripping can be improved while also substantially preventing lithium dendrite formation and growth using particular electrolyte compositions. Embodiments of the electrolytes include organic solvents and their mixtures to form high-quality SEI layers on the lithium anode surface and to prevent further reactions between lithium and electrolyte components. Embodiments of the disclosed electrolytes further include additives to suppress dendrite growth during charge/discharge processes. The solvent and additive can significantly improve both the Coulombic efficiency and smoothness of lithium deposition. By optimizing the electrolyte formulations, practical rechargeable lithium energy storage devices with significantly improved safety and long-term cycle life are achieved. The electrolyte can also be applied to other kinds of energy storage devices.
    Type: Application
    Filed: February 27, 2014
    Publication date: June 26, 2014
    Inventors: Wu Xu, Ji-Guang Zhang, Yaohui Zhang, Xilin Chen
  • Publication number: 20140178771
    Abstract: The present invention discloses a new metal cyano-substituted benzimidazolide salt having formula (I) and its preparation. This new cyano-substituted benzimidazole derivatives exhibited excellent thermal stability. The organic salt of the present invention were soluble in an alkyl carbonate solvent, such as propylene carbonate (PC), dimethyl carbonate (DMC) and ethylene carbonate (EC)/DMC cosolvent. The non-aqueous electrolyte prepared by mixing the organic metal salt of the present invention with the alkyl carbonate solvent shows high conductivity and excellent electrochemical stability. The non-aqueous electrolyte is suitable for use in primary or secondary rechargeable batteries.
    Type: Application
    Filed: December 23, 2013
    Publication date: June 26, 2014
    Applicant: NATIONAL TAIWAN UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventors: Yaw-Terng Chern, Jyh-Long Jeng, Szu-Yuan Chen, An-Shing Wei, Bing-Joe Hwang
  • Publication number: 20140170507
    Abstract: The present invention provides: a non-aqueous electrolyte for an electrochemical device, having ion conductivity sufficient for practical use and capable of improving energy density; a method for producing the same; and an electrochemical device using the same. The non-aqueous electrolyte for an electrochemical device includes a non-aqueous solvent and an alkaline earth metal chloride. The alkaline earth metal chloride is dissolved in an amount of 0.015 mol or more relative to 1 mol of the non-aqueous solvent. The total content of the non-aqueous solvent and the alkaline earth metal chloride is 70 mass % or more in the non-aqueous electrolyte.
    Type: Application
    Filed: March 11, 2013
    Publication date: June 19, 2014
    Applicant: PANASONIC CORPORATION
    Inventors: Tooru Matsui, Zempachi Ogumi, Toshiro Hirai, Akiyoshi Nakata
  • Publication number: 20140162144
    Abstract: Disclosed is a production method of a lithium tetrafluoroborate solution for use as a lithium battery electrolytic solution, including: a reaction step of forming lithium tetrafluoroborate by reaction of lithium fluoride and boron trifluoride in a chain carbonate ester solvent and thereby obtaining a reaction solution of the lithium tetrafluoroborate dissolved in the chain carbonate ester solvent; a water removal step of adding a water removing agent to the reaction solution; an acidic impurity removal step of removing an acidic impurity component from the reaction solution by concentrating the reaction solution after the water removal step; and a dilution step of diluting the concentrated solution after the acidic impurity removal step. It is possible by this method to obtain the lithium tetrafluoroborate solution whose acidic impurity content and water content are reduced to be 50 mass ppm or lower and 15 mass ppm or lower, respectively.
    Type: Application
    Filed: July 31, 2012
    Publication date: June 12, 2014
    Applicant: Central Glass Company ,Limited
    Inventors: Masutaka Shinmen, Shoichi Tsujioka, Tetsu Taroura, Keiji Sato, Takayoshi Morinaka
  • Publication number: 20140141342
    Abstract: The present invention relates to an electrolyte for a lithium secondary battery and a lithium secondary battery including the same, wherein the electrolyte comprises an organic solvent and an electrolyte additive, represented by chemical formula 1 and mixed lithium salts in the organic solvent so that room and high temperature life-time properties of the battery can be improved. Said chemical 1 is defined in the specification.
    Type: Application
    Filed: July 12, 2012
    Publication date: May 22, 2014
    Inventors: Hyeong Kyu Lim, Hong Hie Lee, Eun Gi Shim, Jong Su Kim, Chang Sin Lee, Kyung Il Park, Hahn Mok Song
  • Publication number: 20140127556
    Abstract: A lithium salt is disclosed. The lithium salt includes a lithium ion and an anion represented by formula (I), wherein R1 to R5 are independently selected from hydrogen atom, cyano group, fluorine atom, and C1-C5 alkyl group, in which the C1-C5 alkyl group is substituted with at least one fluorine atom. The present invention further provides an electrolyte solution and a lithium battery containing the lithium salt to enable a high conductivity of the battery at a high temperature.
    Type: Application
    Filed: October 30, 2013
    Publication date: May 8, 2014
    Applicant: China Petrochemical Development Corporation, Taipei (Taiwan)
    Inventor: Fu-Ming Wang
  • Publication number: 20140127590
    Abstract: A nonaqueous electrolytic solution effective in improving cycle characteristics and used for a nonaqueous electrolyte secondary battery including a positive electrode having a positive-electrode active material capable of storing and releasing metal ions and a negative electrode having a negative-electrode active material containing at least one atom selected from the group consisting of Si, Sn, and Pb includes an electrolyte, a nonaqueous solvent, and an isocyanate compound having at least one aromatic ring in its molecule.
    Type: Application
    Filed: January 13, 2014
    Publication date: May 8, 2014
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Youichi OHASHI, Takashi Fujii, Shinichi Kinoshita, Martin Winter, Michael Sternad
  • Publication number: 20140127589
    Abstract: The invention relates to a method for preparing a polyacrylonitrile-sulfur composite material, in which, polyacrylonitrile is converted to cyclized polyacrylonitrile, and the cyclized polyacrylonitrile is reacted with sulfur to form a polyacrylonitrile-sulfur composite material. By a separation of the preparation method into two partial reactions, the reaction conditions are advantageously able to be optimized for the respective reactions and a cathode material is able to be provided for alkali-sulfur cells with improved electrochemical properties. In addition, the invention relates to a polyacrylonitrile-sulfur composite material, a cathode material, an alkali-sulfur cell or an alkali-sulfur battery as well as to an energy store.
    Type: Application
    Filed: March 7, 2012
    Publication date: May 8, 2014
    Inventors: Marcus Wegner, Jens Grimminger, Martin Tenzer, Jens Fanous
  • Patent number: 8715863
    Abstract: The battery includes an electrolyte activating one or more cathodes and one or more anodes. The electrolyte includes one or more salts in a solvent. The solvent includes one or more organic solvents and one or more silanes and/or one or more siloxanes.
    Type: Grant
    Filed: March 22, 2007
    Date of Patent: May 6, 2014
    Assignee: Quallion LLC
    Inventors: Zhengcheng Zhang, Phuong-Nghi Karen Lam, Mikito Nagata, Hisashi Tsukamoto
  • Publication number: 20140113175
    Abstract: A lithium ion battery containing conducting materials comprises a positive electrode, a negative electrode, a separator, an electrolyte, adhesives and sealing materials. The conducting materials in the positive electrode comprise metal carbides, metal borides or metal nitrides. The conducting materials in the negative electrode comprise metal carbides, metal borides or metal nitrides. The metal carbide is titanium carbonitride, tungsten carbide or titanium carbide, vanadium carbide, tantalum carbide, and eutectic of tungsten carbide and titanium carbide. The metal boride is molybdenum boride, tungsten boride or vanadium boride. The metal nitride is titanium nitride, tungsten nitride or tantalum nitride. The conducting materials in the positive electrode may also comprise powdered metals. The conducting materials in the negative electrode comprise powdered metals. The powdered metal is nickel powder, copper powder or chromium powder.
    Type: Application
    Filed: June 2, 2011
    Publication date: April 24, 2014
    Inventor: Panyi ZHANG
  • Publication number: 20140106239
    Abstract: The invention relates to a lithium/sulphur accumulator including at least one unit cell including: a negative electrode; an electrode separator comprising a material soaked with electrolyte, said material comprising at least one nonwoven and having a porosity in the range from 50 to 96%, and a thickness in the range from 50 to 200 micrometers; a positive electrode; and wherein said electrolyte is introduced by an excess quantity, and comprises at least one lithium salt, and the excess quantity of electrolyte amounting to from 20 to 200% of the quantity of electrolyte ensuring the wetting of the electrodes and of the separator.
    Type: Application
    Filed: December 13, 2013
    Publication date: April 17, 2014
    Applicant: Commissariat A L'Energie Atomique Et Aux Energies Alternatives
    Inventors: Céline Barchasz, Sébastien PATOUX, Grégory SI LARBI
  • Publication number: 20140080008
    Abstract: Use of an electrolyte for an electrochemical cell and a method for manufacturing an electrochemical cell comprising such an electrolyte. The electrolyte comprises at least one conductive salt comprising lithium ions, at least one solvent and at least one wetting agent. The electrochemical cell comprises at least one anode, at least one cathode and at least one separator arranged between the at least one anode and the at least one cathode. The electrolyte may be filled between the at least one anode and the at least one cathode.
    Type: Application
    Filed: November 24, 2013
    Publication date: March 20, 2014
    Applicant: Leclanche' SA
    Inventors: Pierre Blanc, Hilmi Buqa, Karl Heinz Pettinger
  • Patent number: 8673504
    Abstract: The objective of the present invention is to prevent deterioration and expanding of anode active material and to improve charge-discharge cycle characteristics in a non-aqueous electrolyte secondary battery comprising an anode of which current collector has thereon a thin layer of an anode active material containing a metal. To solve this problem, in a non-aqueous electrolyte secondary battery wherein a thin layer of anode active material containing a metal which absorbs and discharges lithium is formed on a current collector and the thin layer of the anode active material is divided into columns by a gap formed along the thickness thereof, a compound represented by the following formula is contained in the non-aqueous electrolyte. A-N?C?O In the above formula, A represents an element or a group other than hydrogen.
    Type: Grant
    Filed: May 3, 2012
    Date of Patent: March 18, 2014
    Assignees: SANYO Electric Co., Ltd., Mitsubishi Chemical Corporation
    Inventors: Keiji Saisho, Hidekazu Yamamoto, Masahiro Takehara
  • Publication number: 20140065491
    Abstract: A secondary battery which includes a positive electrode and a negative electrode, wherein the negative electrode has a negative electrode collector and a negative electrode active material layer, and the negative electrode collector has a base material which is formed of aluminum foil and an resin film which has a thickness of 0.01 to 5 ?m and does not allow a nonaqueous electrolyte to permeate therethrough.
    Type: Application
    Filed: April 25, 2012
    Publication date: March 6, 2014
    Applicant: SHOWA DENKO K.K.
    Inventors: Hitoshi Yokouchi, Masahiro Ohmori, Masatoshi Kunisawa