With Gas Diffusion Electrode Patents (Class 429/480)
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Patent number: 10511036Abstract: A channel forming body used in a fuel cell module has a gas channel, a water conduit, and a communication path that provides communication between the gas channel and the water conduit. When a ridge is seen in a cross-section perpendicular to a channel extension direction, one of both ends of an external shape of the ridge is shaped so as to be located closer to a center of the ridge than an imaginary surface of the channel assumed to extend in a straight line along the channel extension direction. Portions of the ridge located closer to the center of the ridge are formed opposite from each other at left and right ends of the external shape of the ridge with the communication path interposed therebetween.Type: GrantFiled: May 11, 2017Date of Patent: December 17, 2019Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, TOYOTA SHATAI KABUSHIKI KAISHAInventors: Hiroya Nakaji, Kazunori Shibata, Hiroki Okabe, Kousuke Kawajiri, Satoshi Futami, Keiji Hashimoto, Takamasa Kanie
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Patent number: 10497947Abstract: A seal (34) for a fuel cell (10), which includes multiple bipolar plates (13) and at least one membrane electrode assembly (12), the seal (34) having a seal body (40) surrounding a free inner chamber (42) is provided. It is provided that at least two flow barriers (46) pointing into the inner chamber (42) are formed as a single piece with the seal body (40), the flow barriers (46) being situated at a distance from the seal body (40) by at least one connecting element (48).Type: GrantFiled: January 22, 2016Date of Patent: December 3, 2019Assignees: Volkswagen AG, Audi AGInventors: Ian Stewart, Darcy McGowan
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Patent number: 10476086Abstract: A resin-framed stepped membrane electrode assembly for a fuel cell, includes a stepped membrane electrode assembly and a resin frame member. The resin frame member surrounds a membrane outer periphery end of a solid polymer electrolyte membrane and includes an inner protruding portion protruding from the membrane outer periphery end toward a second electrode and is joined to the stepped membrane electrode assembly with an adhesive. The inner protruding portion includes a bank portion, a groove portion, and a ledge portion. The roughness of the bank surface is smaller than a roughness of the groove surface.Type: GrantFiled: March 8, 2017Date of Patent: November 12, 2019Assignee: HONDA MOTOR CO., LTD.Inventors: Eri Terada, Kazuo Nunokawa, Satoru Terada, Masaki Tani, Shintaro Tanaka, Seiji Sugiura
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Patent number: 10439227Abstract: An air battery cathode including an organic-inorganic composite material including lyophobic nanopores, the organic-inorganic composite material including a porous metal oxide, and a lyophobic layer on a surface of a pore of the porous metal oxide and having a contact angle of greater than about 90°; and a binder. Also a lithium air battery including the cathode, and a method of manufacture the cathode.Type: GrantFiled: March 8, 2018Date of Patent: October 8, 2019Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Victor Roev, Dong-min Im, Sang-bok Ma, Won-sung Choi, Min-sik Park, Dong-joon Lee
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Patent number: 10411269Abstract: A gas diffusion electrode substrate that is used in a fuel cell and is constituted by an electrode substrate and microporous parts, in which a microporous part (A) is formed on one surface of the electrode substrate, and a microporous part (B) is formed in a part of the inside of the electrode substrate, the gas diffusion electrode substrate having a part in which the microporous part (B) is continuously present from the electrode substrate surface on the side on which the microporous part (A) is formed to a position near the electrode substrate surface on the opposite side, and a part in which pores are continuously distributed from the electrode substrate surface on the side on which the microporous part A is formed to the electrode substrate surface on the opposite side.Type: GrantFiled: February 17, 2015Date of Patent: September 10, 2019Assignee: TORAY INDUSTRIES, INC.Inventors: Yasuaki Tanimura, Masamichi Utsunomiya, Toshiya Kamae
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Patent number: 10403910Abstract: Disclosed herein is a fuel cell stack with improved manufacturing performance. The fuel cell stack includes: a separator that comprises a diffusion part, as being provided with a diffusion channel, configured to distribute reaction gas and cooling water and a reaction part, as being continuously formed from the diffusion part and provided with a reaction channel that has a height greater than that of the diffusion channel, configured to move reaction gas distributed from the diffusion part and generate electrons by a chemical reaction; and a gas diffusion layer configured to contact the separator at the diffusion part and the reaction part.Type: GrantFiled: November 17, 2015Date of Patent: September 3, 2019Assignees: Hyundai Motor Company, Kia Motors CorporationInventors: Sang Mun Jin, Yoo Chang Yang
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Patent number: 10388968Abstract: An illustrative example fuel cell component assembly includes a gas diffusion layer having a gas diffusion layer surface on one side. A microporous layer adjacent the gas diffusion layer includes a first portion having a first density and a second portion having a second density that is lower than the first density. The first portion and the second portion are arranged in a preselected pattern along the microporous layer. The first portion contacts a first section of the gas diffusion layer surface and the second portion contacts a second section of the gas diffusion layer surface.Type: GrantFiled: January 16, 2014Date of Patent: August 20, 2019Assignee: AUDI AGInventors: Siddique Ali Khateeb Razack, Robert Mason Darling
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Patent number: 10374243Abstract: Provided is a porous current collector which is used for a fuel electrode and has a high gas reforming function and high durability. A porous current collector 9 is provided adjacent to a fuel electrode 4 of a fuel cell 101 that includes a solid electrolyte layer 2, the fuel electrode 4 disposed on one side of the solid electrolyte layer, and an air electrode 3 disposed on the other side. The porous current collector includes a porous metal body 1 and a first catalyst 20. The porous metal body has an alloy layer 12a at least on a surface thereof, the alloy layer containing nickel (Ni) and tin (Sn). The first catalyst, which is in the form of particles, is supported on a surface of the alloy layer, the surface facing pores of the porous metal body, and is capable of processing a carbon component contained in a fuel gas that flows inside the pores.Type: GrantFiled: February 23, 2015Date of Patent: August 6, 2019Assignee: SUMITOMO ELECTRIC INDUSTRIES, LTD.Inventors: Takahiro Higashino, Masatoshi Majima, Hiromasa Tawarayama, Naho Mizuhara, Kazuki Okuno, Chihiro Hiraiwa, Yohei Noda, Masahiro Kato
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Patent number: 10361445Abstract: A microporous layer sheet for a fuel cell according to the present invention includes at least two microporous layers, which are stacked on a gas diffusion layer substrate, and contain a carbon material and a binder. Then, the microporous layer sheet for a fuel cell is characterized in that a content of the binder in the microporous layer as a first layer located on the gas diffusion layer substrate side is smaller than contents of the binder in the microporous layers other than the first layer. The microporous layer sheet for a fuel cell, which is as described above, can ensure gas permeability and drainage performance without lowering strength. Hence, the microporous layer sheet for a fuel cell, which is as described above, can contribute to performance enhancement of a polymer electrolyte fuel cell by application thereof to a gas diffusion layer.Type: GrantFiled: May 31, 2012Date of Patent: July 23, 2019Assignee: NISSAN MOTOR CO., LTD.Inventors: Shigemasa Kuwata, Yozo Okuyama, Kazufumi Kodama
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Patent number: 10347929Abstract: Realized are a high-performance electrochemical element and solid oxide fuel cell in which the contact properties between a dense and highly-gastight electrolyte layer and an electrode layer are improved while the treatment temperature during formation of the electrolyte layer is suppressed to a low temperature, and methods for producing the same. An electrochemical element includes an electrode layer 3, and an electrolyte layer 4 arranged on the electrode layer 3, wherein the electrode layer 3 has a plurality of pores that are open on a face thereof in contact with the electrolyte layer 4, and the pores are filled with fine particles made of the same components as the electrolyte layer 4.Type: GrantFiled: September 18, 2015Date of Patent: July 9, 2019Assignees: Osaka Gas Co., Ltd., National Institute of Advanced Industrial Science and TechnologyInventors: Mitsuaki Echigo, Hisao Ohnishi, Kyohei Manabe, Osamu Yamazaki, Kazuyuki Minami, Jun Akedo, Toshio Suzuki
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Patent number: 10333166Abstract: Provided is a catalyst for fuel cell which has a high catalytic activity and enables maintaining the high catalytic activity. Disclosed is an electrode catalyst for fuel cell comprising a catalyst carrier containing carbon as a main component and a catalytic metal supported on the catalyst carrier, wherein the catalyst has the R? (D?/G intensity ratio) of 0.6 or less, which is the ratio of D? band peak intensity (D? intensity) measured in the vicinity of 1620 cm?1 relative to G band peak intensity (G intensity) measured in the vicinity of 1580 cm?1 by Raman spectroscopy, and the volume ratio of a water vapor adsorption amount relative to a nitrogen adsorption amount at a relative pressure of 0.5 in adsorption isotherm is 0.15 or more and 0.30 or less.Type: GrantFiled: October 8, 2015Date of Patent: June 25, 2019Assignees: NISSAN MOTOR CO., LTD., NIPPON STEEL CHEMICAL & MATERIAL CO., LTD.Inventors: Shinichi Takahashi, Tetsuya Mashio
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Patent number: 10305115Abstract: A method of preparing a nitrogen containing electrode catalyst by converting a high surface area metal-organic framework (MOF) material free of platinum group metals that includes a transition metal, an organic ligand, and an organic solvent via a high temperature thermal treatment to form catalytic active sites in the MOF. At least a portion of the contained organic solvent may be replaced with a nitrogen containing organic solvent or an organometallic compound or a transition metal salt to enhance catalytic performance. The electrode catalysts may be used in various electrochemical systems, including an alkaline fuel cell.Type: GrantFiled: February 27, 2015Date of Patent: May 28, 2019Assignee: UChicago Argonne, LLCInventors: Di-Jia Liu, Shengqian Ma, Gabriel A. Goenaga, Dan Zhao
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Patent number: 10305114Abstract: A method of preparing a nitrogen containing electrode catalyst by converting a high surface area metal-organic framework (MOF) material free of platinum group metals that includes a transition metal, an organic ligand, and an organic solvent via a high temperature thermal treatment to form catalytic active sites in the MOF. At least a portion of the contained organic solvent may be replaced with a nitrogen containing organic solvent or an organometallic compound or a transition metal salt to enhance catalytic performance. The electrode catalysts may be used in various electrochemical systems, including a proton exchange membrane fuel cell.Type: GrantFiled: September 8, 2014Date of Patent: May 28, 2019Assignee: UChicago Argonne, LLCInventors: Di-Jia Liu, Shengqian Ma, Gabriel A. Goenaga
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Patent number: 10256480Abstract: In order to provide a flow element by means of which a fluid can be guided and/or distributed over a surface as uniformly as possible, it is proposed that the flow element comprises a plate-like main body, which has a channel structure, wherein the channel structure comprises two or more paths, which connect an inlet side of the channel structure to an outlet side of the channel structure, wherein the two or more channel paths each have one or more meandering segments, wherein meandering segments of channel paths different from each other are nested in each other.Type: GrantFiled: February 26, 2017Date of Patent: April 9, 2019Assignee: ElringKlinger AGInventors: Juergen Kraft, Michael Goetz, Manuel Morcos
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Patent number: 10249900Abstract: A method for making a composite membrane includes the steps of coating a first layer of ionomer on an intermediate support, laminating a dry porous support into the wet first layer of ionomer, impregnating the porous support with ionomer from the coated ionomer layer, optionally drying the impregnated porous support and the first layer of ionomer, coating a second layer of ionomer on the impregnated porous support, drying the second layer of ionomer until most of the solvent is evaporated, and delaminating the composite membrane from the intermediate support. The composite membrane thus obtained includes a porous support impregnated with the ionomer and on each side of the impregnated support a dense ionomer layer.Type: GrantFiled: August 25, 2014Date of Patent: April 2, 2019Assignee: AGFA-GEVAERTInventors: Guido Desie, Willem Mues, Patrick Wouters, Roger Hendriks
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Patent number: 10249886Abstract: A fuel cell gas diffusion layer includes: a porous carbon fiber base substrate containing discontinuous carbon fibers bonded to each other with carbide, and a porous layer containing at least carbonaceous particles, the porous carbon fiber base substrate having a porous layer (A) with a mean thickness t1 of 10 to 55 ?m deposited on one surface A thereof, the porous carbon fiber base substrate being impregnated with porous layer (J) at least part of which is exposed at an opposite surface B, the porous carbon fiber base substrate having internal pores with a cross-sectional area accounting for 5% to 40% of the total cross section in a through-plane direction, at least porous layer (A) and porous layer (J) both having a void percentage of 50% to 85%, the porous carbon fiber base substrate having a thickness of 60 to 300 ?m, and the porous carbon fiber base substrate having a bulk density of 0.20 to 0.45 g/cm3.Type: GrantFiled: February 7, 2014Date of Patent: April 2, 2019Assignee: Toray Industries, Inc.Inventors: Yasutaka Okano, Koichi Antoku, Eisuke Wadahara
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Patent number: 10205178Abstract: A fuel cell includes a membrane electrode assembly having a substantially rectangular shape having a first side and a second side opposite to the first side in a side direction. The substantially rectangular shape includes a first portion and a second portion. The first portion is closer to the first side than to the second side in the side direction. At least one of a cathode electrode and an anode electrode has a smaller amount of cracks in an electrode catalyst layer in the first portion than in the second portion. A fuel gas outlet manifold and an oxidant gas inlet manifold are closer to the first side than to the second side in the side direction. A fuel gas inlet manifold and an oxidant gas outlet manifold are closer to the second side than to the first side in the side direction.Type: GrantFiled: October 21, 2016Date of Patent: February 12, 2019Assignee: HONDA MOTOR CO., LTD.Inventors: Yukihito Tanaka, Suguru Ohmori, Eri Terada
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Patent number: 10157714Abstract: Provided is a process for producing a supercapacitor electrode, comprising: (a) preparing a deformable mass of multiple flakes of exfoliated graphite worms or expanded graphite dispersed in or impregnated by a liquid or gel electrolyte; and (b) subjecting the deformable mass to a forced assembling and orientating procedure, forcing the deformable mass to form the electrode, wherein these fakes are spaced by thin electrolyte layers, having an electrolyte layer thickness from 0.4 nm to 10 nm, and the flakes are substantially aligned along a desired direction, and wherein the electrode has a physical density from 0.5 to 1.7 g/cm3 and a specific surface area from 50 to 3,300 m2/g, when measured in a dried state of the flakes without the electrolyte. This process leads to a supercapacitor having a large electrode thickness, high active mass loading, high tap density, and exceptional energy density.Type: GrantFiled: August 7, 2017Date of Patent: December 18, 2018Assignee: Nanotek Instruments, Inc.Inventors: Aruna Zhamu, Bor Z. Jang
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Patent number: 10141583Abstract: A bipolar plate for a fuel cell, including a profiled anode plate and a profiled cathode plate, each having an active region and two distribution regions for feeding and discharging operating media to and from the active region, and each distribution region having a main anode-gas port for supplying and evacuating fuel, a main cathode-gas port for supplying and evacuating oxidant and a main coolant port for supplying and evacuating coolant, the ports being arranged along a lateral edge of the bipolar plate. The plates are stacked so that the bipolar plate has channels interconnecting the main operating media ports of both distribution regions, and the distribution regions have at least one overlapping section, in which the channels overlap such that they do not form fluidic connections. A fuel cell is also provided.Type: GrantFiled: April 2, 2015Date of Patent: November 27, 2018Assignee: Volkswagen AGInventors: Benno Andreas-Schott, Markus Ritter, Christian Martin Zillich
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Patent number: 10135078Abstract: In order to reduce corrosion of metal plates of a current collector which is comprised of the stacked metal plates made of different materials, a current collector for a fuel cell is provided, which includes a first metal plate that has a terminal portion and is conductive, and a second metal plate and a third metal plate that are metal plates having a higher corrosion resistance than the first metal plate and pinch the first metal plate therebetween. The current collector includes a first through-hole penetrating the first metal plate, the second metal plate, and the third metal plate, wherein fluid exists in at least either one of between the first metal plate and the second metal plate, and between the first metal plate and the third metal plate, and the first through-hole guides the fluid outside the current collector, and a first seal member blocking an end face of a perimeter of the current collector. A hole wall surface of the first through-hole is not blocked.Type: GrantFiled: October 5, 2015Date of Patent: November 20, 2018Assignee: Toyota Jidosha Kabushiki KaishaInventor: Fumishige Shizuku
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Patent number: 10135074Abstract: The present invention is to provide a carbon powder that can provide a catalyst having excellent durability and a catalyst. A carbon powder for catalyst of the present invention is a carbon powder containing as a main component carbon, which has a BET specific surface area per unit weight of 900 m2/g or greater, and a ratio R? (D?/G intensity ratio) of peak intensity for a D?-band (D? intensity) measured in the vicinity of 1620 cm?1 to peak intensity for a G-band (G intensity) measured in the vicinity of 1580 cm?1 by Raman spectroscopy of 0.6 or less.Type: GrantFiled: September 9, 2014Date of Patent: November 20, 2018Assignees: NISSAN MOTOR CO., LTD., NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD.Inventors: Shinichi Takahashi, Atsushi Ohma, Tetsuya Mashio, Ken Akizuki
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Patent number: 10115972Abstract: An embodiment of the invention is an air cathode having a porous membrane with at least one hydrophobic surface that contacts a conductive catalytic film that comprises single walled carbon nanotubes (SWNTs) where the nanotubes are in intimate electrical contact. The conductive film can include fullerenes, metals, metal alloys, metal oxides, or electroactive polymers in addition to the SWNTs. In other embodiments of the invention the air cathode is a component of a metal-air battery or a fuel cell.Type: GrantFiled: April 22, 2010Date of Patent: October 30, 2018Assignee: University of Florida Research Foundation, IncorporatedInventors: Andrew Gabriel Rinzler, Rajib Kumar Das, John R. Reynolds, Ryan M. Walczak
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Patent number: 10062911Abstract: Fuel cell devices and systems are provided. In certain embodiments, the devices include a ceramic support structure having a length, a width, and a thickness with the length direction being the dominant direction of thermal expansion. A reaction zone having at least one active layer therein is spaced from the first end and includes first and second opposing electrodes, associated active first and second gas passages, and electrolyte. The active first gas passage includes sub-passages extending in the y direction and spaced apart in the x direction. An artery flow passage extends from the first end along the length and into the reaction zone and is fluidicly coupled to the sub-passages of the active first gas passage. The thickness of the artery flow passage is greater than the thickness of the sub-passages.Type: GrantFiled: June 16, 2015Date of Patent: August 28, 2018Inventors: Alan Devoe, Lambert Devoe
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Patent number: 10049784Abstract: Nanocomposite films comprising conductive nanofiller dispersed throughout a polymer matrix and further comprising at least two surfaces with differing amounts of filler and differing electrical resistivity values are provided. In particular, nanocomposites comprising polyvinyl alcohol as the polymer matrix and nanosheets and/or nanoplatelets of graphene as the conductive filler are provided. In addition, a process for forming the nanocomposites, methods for characterizing the nanocomposites as well as applications in or on electrical and/or electronic devices are provided.Type: GrantFiled: October 7, 2015Date of Patent: August 14, 2018Assignee: King Fahd University of Petroleum and MineralsInventors: Mamdouh Ahmed Al-Harthi, Osamah Awadh Bin-Dahman, Mostafizur Rahaman
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Patent number: 9985297Abstract: A durability test device that examines durability of a membrane electrode assembly used for a polymer electrolyte fuel cell includes: a voltage application device that applies a voltage from one surface of the membrane electrode assembly to the other surface thereof; a current measurement device that measures a current flowing from the one surface to the other surface by the application of the voltage; and a control section that controls the voltage application device to apply the voltage to the membrane electrode assembly while sweeping the voltage over a plurality of consecutive voltage regions in such a manner that a first sweep rate of the voltage to be applied in the first voltage region in which a measured current value includes a peak caused due to carbon oxidation is set lower than that in the second voltage region that does not include the first voltage region.Type: GrantFiled: October 20, 2014Date of Patent: May 29, 2018Assignee: Toyota Jidosha Kabushiki KaishaInventors: Tohru Oda, Katsuhiko Kinoshita, Tatsuya Kawahara
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Patent number: 9966611Abstract: A bipolar plate for fuel cells includes a flow plate having a first surface for the introduction of hydrogen fuel gas and water vapor and a second surface for the introduction of an oxygen containing gas, wherein at least a portion of the first and/or second surface comprises a nanostructured carbon material (NCM) coating deposited thereon, said coating having a thickness of 1 nm to 5 ?m.Type: GrantFiled: June 8, 2010Date of Patent: May 8, 2018Inventor: Ramesh Sivarajan
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Patent number: 9954243Abstract: A fuel cell comprising at least two stacked fuel cell boards (22) which each comprise a membrane of substantially gas impervious electrolyte material and at least two electrode pairs wherein the anode and cathode of each said electrode pair are arranged on respective faces of said membrane. An electrode of each pair of electrodes is connected to an electrode of an adjacent pair of electrodes by a through-membrane connection (13) or by an external connection on a Printed Circuit Board, comprising an electrically conductive region of said electrolyte material. A method for forming the through-membrane electrical connections in the electrolyte membrane is also disclosed.Type: GrantFiled: February 29, 2012Date of Patent: April 24, 2018Assignees: Imperial Innovations Limited, UCL Business PLCInventors: Daniel John Leslie Brett, Anthony Robert John Kucernak
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Patent number: 9911981Abstract: An air-cathode battery includes a porous cathode current collector with an air interface, an ionic liquid electrolyte disposed in pores of the porous cathode current collector; a metal anode, and a separator in contact with the ionic liquid electrolyte and coupled between the porous cathode current collector and the metal anode. The porous cathode current collector is an ionogel formed from a silica sol-gel or a carbonized resorcinol-formaldehyde aerogel and the pores are functionalized with a thiol group-containing species that is functionalized with one or more catalytic nanoparticles or the pores are electroplated with catalytic metal.Type: GrantFiled: April 10, 2015Date of Patent: March 6, 2018Assignee: National Technology & Engineering Solutions of Sandia, LLCInventor: Marie C. Kane
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Patent number: 9912002Abstract: The present invention relates to: an ion exchange membrane containing, in a channel, an inorganic particle, substituted with an organic compound including SO4? group; and a method for manufacturing the ion exchange membrane. The ion exchange membrane according to the present invention can provide excellent physical properties while also maintaining ion conductivity.Type: GrantFiled: October 28, 2014Date of Patent: March 6, 2018Assignee: Hyundai Electric & Energy Systems Co., Ltd.Inventor: Ji Hyun Kong
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Patent number: 9905858Abstract: An improved platinum and method for manufacturing the improved platinum wherein the platinum having a fractal surface coating of platinum, platinum gray, with a increase in surface area of at least 5 times when compared to shiny platinum of the same geometry and also having improved resistance to physical stress when compared to platinum black having the same surface area. The process of electroplating the surface coating of platinum gray comprising plating at a moderate rate, for example at a rate that is faster than the rate necessary to produce shiny platinum and that is less than the rate necessary to produce platinum black. Platinum gray is applied to manufacture a fuel cell and a catalyst.Type: GrantFiled: January 29, 2013Date of Patent: February 27, 2018Assignee: Second Sight Medical Products, Inc.Inventors: David Daomin Zhou, Robert J. Greenberg
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Patent number: 9865883Abstract: Methods of preparing fuel cell electrodes having catalyst with high density catalyst support are provided. One method of fabricating a fuel cell electrode comprises adjusting an active catalyst particle loading to increase catalyst layer thickness to within a desired range.Type: GrantFiled: February 14, 2014Date of Patent: January 9, 2018Assignee: NISSAN NORTH AMERICA, INC.Inventors: Taehee Han, Ellazar Niangar
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Patent number: 9859573Abstract: Disclosed is a membrane electrode assembly provided with a polymer electrolyte membrane; a catalyst layer (A) which is laminated onto one surface of the polymer electrolyte membrane; a gas diffusion layer (A) which is laminated onto the catalyst layer (A); a catalyst layer (B); and a gas diffusion layer (B). The outer circumferential section of the catalyst layer (A) is the membrane electrode assembly with an integrated frame which comprises a membrane electrode assembly that protrudes from the gas diffusion layer (A) and a frame adhered to the outer circumferential section of the catalyst layer (A), whereby said frame surrounds the edge of the membrane electrode assembly. The surface that is adhered to the frame in the outer circumferential section of the catalyst layer (A) comprises a plurality of cracks.Type: GrantFiled: March 4, 2011Date of Patent: January 2, 2018Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Takashi Morimoto, Yoichiro Tsuji, Masaki Yamauchi, Atushi Murata, Mitsuo Yoshimura
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Patent number: 9853255Abstract: Embodiments of the disclosure relate to membrane electrode assemblies. The membrane electrode assembly may include at least one gas-diffusion layer having a first side and a second side, and particle cores adhered to at least one of the first and second sides of the at least one gas-diffusion layer. The particle cores includes surfaces adhered to the at least one of the first and second sides of the at least one gas-diffusion layer and surfaces not in contact with the at least one gas-diffusion layer. Furthermore, a thin layer of catalytically atoms may be adhered to the surfaces of the particle cores not in contact with the at least one gas-diffusion layer.Type: GrantFiled: June 20, 2017Date of Patent: December 26, 2017Assignee: Brookhaven Science Associates, LLCInventors: Radoslav Adzic, Stoyan Bliznakov, Miomir Vukmirovic
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Patent number: 9843063Abstract: A fuel cell includes: a membrane electrode assembly including an electrolyte membrane, catalyst layers stacked on both sides of the electrolyte membrane, and two or more porous bodies having different moduli of elasticity and provided on a surface of one of the catalyst layers; a separator defining a gas flow passage between the separator and the membrane electrode assembly; and a frame body surrounding an outer periphery of the electrolyte membrane. A porous body adjacent to the separator out of the two or more porous bodies includes an outer edge portion including an outer extending portion extending to overlap with the frame body. An elastic body is provided between the outer extending portion and the frame body.Type: GrantFiled: March 14, 2013Date of Patent: December 12, 2017Assignee: NISSAN MOTOR CO., LTD.Inventors: Motoki Yaginuma, Toshikazu Kotaka
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Patent number: 9809890Abstract: The present disclosure is directed towards flow structures in electrochemical cells for use in high differential pressure operations. The flow structure on the low pressure-side of the cell has a larger surface area than the flow structure on the high-pressure side of the cell at the flow structure—MEA interface. The boundary of the high pressure flow structure is entirely within the boundary of the low pressure flow structure. A seal around the high pressure flow structure is also contained within the boundary of the low pressure flow structure. In such an arrangement, high fluid pressures acting on the electrolyte membrane from the high-pressure side of the cell is fully and continuously balanced by the flow structure on the low pressure-side of the membrane. Use of the low pressure flow structure as a membrane support prevents the rupture or deformation of the membrane under high stresses.Type: GrantFiled: July 22, 2013Date of Patent: November 7, 2017Assignee: Nuvera Fuel Cells, LLC.Inventors: Scott Blanchet, Benjamin Lunt
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Patent number: 9793567Abstract: An ion exchange membrane for a redox flow battery, the anion exchange membrane including a porous substrate; and a polymer disposed in the porous substrate, wherein the polymer is a polymerization product of a composition for forming the ion exchange membrane, wherein the composition includes a first monomer and a second monomer, wherein the first monomer is substituted with a group including an ethylenic unsaturated double bond and includes a cationic heterocyclic compound including a nitrogen heteroatom and a counter anion thereof, and wherein the second monomer is polymerizable with the first monomer and is at least one selected from a (meth)acrylamide compound and a (meth)acrylate compound.Type: GrantFiled: October 31, 2014Date of Patent: October 17, 2017Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Myungjin Lee, Moonsung Kang, Dooyeon Lee, Dohyeong Kim
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Patent number: 9761898Abstract: There is provided a technique of preventing degradation of an electrolyte membrane included in a fuel cell. A fuel cell includes a membrane electrode assembly. The membrane electrode assembly is provided as a power generation device where electrodes are arranged on both sides of an electrolyte membrane having proton conductivity. Each of the electrodes has a layered structure of stacking a catalyst layer arranged to support a catalyst and a gas diffusion layer arranged to spread a reactive gas over the entire electrode plane. The outer peripheral edge of the gas diffusion layer is located inward of the outer peripheral edge of the catalyst layer.Type: GrantFiled: November 4, 2010Date of Patent: September 12, 2017Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Kenji Tsubosaka, Hiroo Yoshikawa, Junji Nakanishi
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Patent number: 9755259Abstract: There is provided a power generation body used for a fuel cell. The power generation body comprising a membrane electrode and gas diffusion layer assembly comprising an electrolyte membrane, a first catalyst layer placed on one surface of the electrolyte membrane, a second catalyst layer placed on the other surface of the electrolyte membrane, a first gas diffusion layer placed outside of the first catalyst layer and a second gas diffusion layer placed outside of the second catalyst layer; a frame placed around a circumference of the membrane electrode and gas diffusion layer assembly; and an adhesive provided to bond the membrane electrode and gas diffusion layer assembly to the frame. The first gas diffusion layer is formed to have an identical size with that of the electrolyte membrane, and the second gas diffusion layer is formed smaller than the electrolyte membrane. The frame has a stepped portion corresponding to a stepped shape formed by the electrolyte membrane and the second gas diffusion layer.Type: GrantFiled: October 23, 2014Date of Patent: September 5, 2017Assignee: Toyota Jidosha Kabushiki KaishaInventor: Tomokazu Hayashi
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Patent number: 9748579Abstract: The present invention provides a fused product comprising LTM perovskite, L designating lanthanum, T being an element selected from strontium, calcium, magnesium, barium, yttrium, ytterbium, cerium, and mixtures of these elements, and M designating manganese.Type: GrantFiled: April 28, 2014Date of Patent: August 29, 2017Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Samuel Marlin, Caroline Levy
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Patent number: 9742012Abstract: A fuel cell having a membrane electrode assembly (MEA) comprising an electrolyte membrane, an anode and a cathode; and a gas diffusion layer (GDL) combined with both surfaces of the MEA is provided. In particular, the GDL includes a first layer having a first surface that comes in contact with a reaction region of the MEA, a second layer formed on a second surface of the first layer, and a third layer formed along a peripheral portion between a first region in which both the first layer and the second layer are formed and a second region in which only the second layer is formed. The first layer may be a first microporous layer, the third layer may be a second microporous layer having a viscosity lower than that of the first microporous layer, and the second layer is not the first microporous layer and the second microporous layer.Type: GrantFiled: August 7, 2014Date of Patent: August 22, 2017Assignee: Hyundai Motor CompanyInventor: Byeong-Heon Jeong
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Patent number: 9692072Abstract: Disclosed is an anion exchange electrolyte membrane including: a base polymer having a polar group; and a graft chain having a specific structural unit. The graft chain is, for example, a polymer chain that is formed from diallyldimethylammonium chloride as a monomer.Type: GrantFiled: June 3, 2015Date of Patent: June 27, 2017Assignee: NITTO DENKO CORPORATIONInventors: Takashi Suzuki, Mizuki Yamamoto, Hiroyuki Nishii
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Patent number: 9620803Abstract: A solid oxide fuel cell has a reinforced membrane-electrode assembly. The solid oxide fuel cell includes a first electrode layer, a second electrode layer, and an electrolyte membrane disposed between the first and second electrode layers. The solid oxide fuel cell further includes a gas-permeable structure adjacent to one or both of the electrode layers, for mechanical stabilization.Type: GrantFiled: March 11, 2015Date of Patent: April 11, 2017Assignee: PRESIDENT AND FELLOWS OF HARVARD COLLEGEInventors: Shriram Ramanathan, Alexander C. Johnson
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Patent number: 9559376Abstract: Disclosed is a fuel cell in which an electrolyte membrane-electrode structure is held between the first separator and a second separator. The electrolyte membrane-electrode structure comprises a solid polymer electrolyte membrane, a cathode-side electrode and an anode-side electrode. An end portion of the solid polymer electrolyte membrane projects outwardly beyond end portions of gas diffusion layers, and the both surfaces of the end portion of the solid polymer electrolyte membrane are held between the first protective film and a second protective film. The thickness of the first protective film is set to be thinner than the thickness of the second protective film.Type: GrantFiled: January 12, 2011Date of Patent: January 31, 2017Assignee: Honda Motor Co., Ltd.Inventors: Masaru Oda, Teruyuki Ohtani, Seiji Sugiura, Kenichi Tanaka, Hiroshi Sohma
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Patent number: 9553324Abstract: A resin frame member of a resin frame equipped membrane electrode assembly includes a recess where adhesive is provided. An inner protrusion on an inner side of the recess abuts against an electrode catalyst layer protruding outward beyond a gas diffusion layer of a membrane electrode assembly. An outer protrusion on an outer side of the recess abuts against the outermost portion of a gas diffusion layer of the membrane electrode assembly such that a solid polymer electrolyte membrane is interposed between the outer protrusion and the gas diffusion layer.Type: GrantFiled: March 18, 2014Date of Patent: January 24, 2017Assignee: Honda Motor Co., Ltd.Inventors: Yukihito Tanaka, Naoki Mitsuta, Seiji Sugiura
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Patent number: 9537168Abstract: The present invention relates to improved membrane electrode assemblies, having two electrochemically active electrodes separated by a polymer electrolyte membrane. The membrane electrode assemblies according to the instant invention contains at least one phosphoric acid-containing polymer electrolyte membrane and two gas diffusion electrodes one of each located at both sides of said membrane, each of the gas diffusion electrodes having at least one catalyst layer facing towards the membrane. At least one of the gas diffusion electrodes contains a gas diffusion medium comprising an electrically conductive macroporous layer in which the pores have a mean pore diameter in the range from 10 ?m to 30 ?m and at least one micro porous layer arranged between said gas diffusion medium and said catalyst layer facing towards the membrane having a defined pore void volume and pore hydrophobicity measured by the Cobb Titration.Type: GrantFiled: October 28, 2014Date of Patent: January 3, 2017Assignee: BASF SEInventors: Zhenyu Liu, Yu-Min Tsou, Emory De Castro
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Patent number: 9490487Abstract: A fuel cell includes a membrane electrode assembly, separators, and a second separator among the separators. The membrane electrode assembly includes an electrolyte membrane, a first electrode and a second electrode, and a resin frame member. A first separator among the separators facing the first electrode includes a fuel gas channel, a fuel gas manifold, and a fuel gas buffer. The second separator among the separators facing the second electrode includes an oxidant gas channel, an oxidant gas manifold, and an oxidant gas buffer. The fuel gas buffer includes a first fuel gas buffer region and a second fuel gas buffer region. The second fuel gas buffer region is more deeply grooved than the first fuel gas buffer region in a stacking direction. The oxidant gas buffer includes a first oxidant gas buffer region and a second oxidant gas buffer region.Type: GrantFiled: October 9, 2014Date of Patent: November 8, 2016Assignee: HONDA MOTOR CO., LTD.Inventors: Kentaro Ishida, Seiji Sugiura
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Patent number: 9461311Abstract: In at least one embodiment, a fuel cell is provided comprising a positive electrode including a first gas diffusion layer and a first catalyst layer, a negative electrode including a second gas diffusion layer and a second catalyst layer, a proton exchange membrane (PEM) disposed between the positive and negative electrodes, and a microporous layer of carbon and binder disposed between at least one of the first gas diffusion layer and the first catalyst layer and the second gas diffusion layer and the second catalyst layer. The microporous layer may have defined therein a plurality of pores with a diameter of 0.05 to 2.0 ?m and a plurality of bores having a diameter of 1 to 100 ?m. The bores may be laser perforated and comprise from 0.1 to 5 percent of a total porosity of the microporous layer.Type: GrantFiled: March 15, 2013Date of Patent: October 4, 2016Assignee: Ford Global Technologies, LLCInventors: Zijie Lu, James Waldecker, Michael Allen Debolt, Donald Paul Alessi
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Patent number: 9397358Abstract: Disclosed herein are a membrane electrode assembly (MEA) for fuel cells, wherein the membrane electrode assembly has a porous membrane (a catalyst trapping layer) disposed at the opposite surface of a catalyst layer facing a polymer electrolyte membrane for preventing the loss of a catalyst, and a fuel cell including the same. The membrane electrode assembly has the effect of restraining the loss of the catalyst due to a liquid component, such as methanol, thereby improving the operating efficiency of the fuel cell. Especially, the membrane electrode assembly has the effect of minimizing the reduction in performance of the fuel cell due to the loss of the catalyst during the long-term operation.Type: GrantFiled: December 23, 2006Date of Patent: July 19, 2016Assignee: LG CHEM, LTD.Inventors: Yu Jin Oh, Hyuk Kim, Goyoung Moon
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Patent number: 9382620Abstract: An electrically conductive fluid distribution element for use in a fuel cell includes a conductive metal substrate and a layer of conductive non-metallic porous media. The conductive non-metallic porous media has an electrically conductive material deposited along a surface in one or more metallized regions and having an average thickness less than about 40 nm. The metallized regions improve electrical conductance at contact regions between the metal substrate and the fluid distribution media.Type: GrantFiled: July 30, 2010Date of Patent: July 5, 2016Assignee: GM Global Technology Operations LLCInventors: Gayatri Vyas Dadheech, Mahmoud H. Abd Elhamid, Youssef M. Mikhail
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Patent number: 9368823Abstract: A solid oxide fuel cell (SOFC) article including a SOFC unit cell having a functional layer of an average thickness of not greater than about 100 ?m, wherein the functional layer has a first type of porosity having a vertical orientation, and the first type of porosity has an aspect ratio of length:width, the width substantially aligned with a dimension of thickness of the functional layer.Type: GrantFiled: December 7, 2012Date of Patent: June 14, 2016Assignee: SAINT-GOBAIN CERAMICS & PLASTICS, INC.Inventor: Aravind Mohanram