Core-shell Structure Patents (Class 430/110.2)
  • Publication number: 20130273471
    Abstract: Toners containing encapsulated crystalline resin have lower minimum fix temperatures without charge degradation.
    Type: Application
    Filed: April 11, 2012
    Publication date: October 17, 2013
    Applicant: Xerox Corporation
    Inventors: Guerino Sacripante, Ke Zhou, Jordan Wosnick, Edward Zwartz, Michael Hawkins
  • Patent number: 8557493
    Abstract: Environmentally friendly toner particles are provided which may include a bio-based amorphous polyester resin, optionally in combination with another amorphous resin and/or a crystalline resin. Methods for providing these toners are also provided. In embodiments, the bio-based amorphous polyester resin is modified with a multi-functional bio-based acid, thereby providing acid-functionalized polyesters, which can be readily emulsified in emulsion aggregation processes for toner fabrication.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: October 15, 2013
    Assignee: Xerox Corporation
    Inventors: Valerie M. Farrugia, Guerino G. Sacripante, Sonja Hadzidedic
  • Patent number: 8557495
    Abstract: A method for producing a developing agent including preparing a dispersion liquid containing first fine particles containing a binder resin and second fine particles containing a color developable compound, a color coupler, and a color eraser, and aggregating the first and second fine particles in the dispersion liquid to form aggregated particles.
    Type: Grant
    Filed: July 19, 2012
    Date of Patent: October 15, 2013
    Assignee: Toshiba Tec Kabushiki Kaisha
    Inventors: Takahito Kabai, Tsuyoshi Itou
  • Patent number: 8551679
    Abstract: A toner including a plurality of fine particles includes a core including first latex particles, a wax and a pigment, or a first latex particle-wax complex and a pigment, and a first shell layer including second latex particles and covering at least a portion of the surface of the core, a method of preparing the toner, a method of forming images using the toner, and an image forming device including a toner transferring unit. The toner can have improved fixing and charging properties, preserving properties at a high temperature and high humidity, glossness and anti-offset properties by reducing a domain size of a wax dispersed in the toner and improving dispersibility of the wax.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: October 8, 2013
    Assignee: SAMSUNG Electronics Co., Ltd.
    Inventors: Kyeong Pang, Hong-chul Shin, Kyung-yoi Yon
  • Publication number: 20130260308
    Abstract: The present disclosure describes a toner produced using a coalescing temperature lower than the melting point of a wax in the toner, quench cooling or both. The resulting toners can exhibit reduced dielectric loss and improved tribo charging.
    Type: Application
    Filed: March 29, 2012
    Publication date: October 3, 2013
    Applicant: XEROX CORPORATION
    Inventors: Melanie Davis, Kimberly Nosella, Suxia Yang, Daryl Vanbesien, Richard P.N. Veregin
  • Patent number: 8546053
    Abstract: The present invention provides a method for producing a toner, the method including: preparing a wax dispersion liquid by cooling a wax solution, in which a wax is heated and dissolved or dispersed in an organic solvent, in a container so that a standard deviation ? of a temperature distribution between a center portion of the container and an inner wall of the container is 0.5 or less and the cooling rate is 2.0° C./min or more, to precipitate wax particles in the wax solution; forming toner base precursor particles by adding an aqueous phase containing resin fine particles into an oil phase containing at least the wax dispersion liquid, a colorant and a binder resin and mixing the oil phase and the aqueous phase with each other; and preparing toner base particles by removing the solvent from the toner base precursor particles.
    Type: Grant
    Filed: September 8, 2009
    Date of Patent: October 1, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Teruki Kusahara, Junichi Awamura, Tomomi Suzuki, Toshihiko Karato
  • Patent number: 8541154
    Abstract: A method for making toners to include at least one nanoscale fluorescent pigment particle composition and/or a fluorescent organic nanoparticle composition. The particles are incorporated into emulsion of toner and used in making toner via emulsion aggregation. Such toners may have a core and/or a shell and the clay composites may be included within the core, the shell or both. The fluorescent organic nanoparticle composition includes a polymeric matrix obtained by modified EA latex process and/or emulsion polymerization and one or more fluorescent dyes and the nanoscale fluorescent pigment particle composition includes pigment molecules with at least one functional moiety, and a sterically bulky stabilizer compound including at least one functional group, the functional moiety of the pigment associates non-covalently with the functional group of the stabilizer, and the presence of the associated stabilizer limits the extent of particle growth and aggregation, to afford nanoscale-sized pigment particles.
    Type: Grant
    Filed: October 6, 2008
    Date of Patent: September 24, 2013
    Assignee: Xerox Corporation
    Inventors: Gabriel Iftime, Daryl W. Vanbesien, Maria M. Birau, Jordan H. Wosnick, Peter M. Kazmaier
  • Publication number: 20130236825
    Abstract: Toner particles include a shell and a core, wherein the shell includes charge control agent-treated spacer particles that cause protrusions from the toner particle surface.
    Type: Application
    Filed: March 9, 2012
    Publication date: September 12, 2013
    Applicant: XEROX CORPORATION
    Inventors: Maura A. SWEENEY, Robert D. BAYLEY, Grazyna E. KMIECIK-LAWRYNOWICZ, Anne Marie SWEENEY-JONES
  • Publication number: 20130236829
    Abstract: A toner particle having a core and a shell, and a method for making the toner particle. The core includes a crystalline resin and the shell includes an amorphous resin. The shell is substantially to completely free of the crystalline resin. The toner particle permits inclusion of greater amounts of crystalline resin materials in the core, thereby lowering the minimum fusing temperature of the toner formed from the particles.
    Type: Application
    Filed: March 6, 2012
    Publication date: September 12, 2013
    Applicant: XEROX CORPORATION
    Inventors: Jordan H. Wosnick, Richard P. N. Veregin, Edward G. Zwartz, Michael S. Hawkins
  • Patent number: 8530131
    Abstract: Toner particles are provided which may, in embodiments, include a core and a shell, one or both of which may include a polyester gel. The gel in the shell and/or core may prevent a crystalline resin in the core from migrating to the toner surface.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: September 10, 2013
    Assignee: Xerox Corporation
    Inventors: Ke Zhou, Karen Ann Moffat, Maria N. V. McDougall, Edward G. Zwartz, Paul J. Gerroir
  • Patent number: 8524434
    Abstract: A toner having a toner particle including a core particle obtained by polymerizing a polymerizable monomer composition containing at least a polymerizable monomer, a colorant, a release agent, a polar resin, and a crystalline polyester in an aqueous medium and an outer shell formed by fixing resin fine particles to the surface of the core particle, wherein the resin constituting the resin fine particles is an amorphous resin and the acid value of the resin fine particles is 4.0 to 50.0 mgKOH/g.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: September 3, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tsuneyoshi Tominaga, Ryoichi Fujita, Tsutomu Shimano
  • Patent number: 8497056
    Abstract: A magenta toner characterized by satisfying, in DSC measurement, 40.0?Tg(0.5)?60.0 and 2.0?Tg(4.0)?Tg(0.5)?10.0, wherein when preparing a solution of which the magenta toner is dissolved in ethyl acetate, and defined the concentration of the thereof as Cm1 (mg/ml), and the light absorbance thereof at a wavelength of 538 nm as A(ethyl acetate)538, the ratio of A(ethyl acetate)538 to Cm1 satisfies the formula, A(ethyl acetate)538/Cm1<0.15, and, when preparing a solution of which the magenta toner is dissolved in chloroform, and defined the concentration of the thereof as Cm2 (mg/ml), and the light absorbance thereof at a wavelength of 538 nm as A(chloroform)538, the ratio of A(chloroform)538 to Cm2 satisfies the formula, 2.00<A(chloroform)538/Cm2<6.55.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: July 30, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Ayako Sekikawa, Takaaki Kaya, Atsushi Tani, Shigeto Tamura
  • Publication number: 20130189614
    Abstract: A carrier core particle for an electrophotographic developer including a core composition expressed by a general formula: (MnxMgyCaz) FeWO4+V (x+y+z+w=3, ?0.003<v) as a main ingredient, wherein 0.05?y?0.35 and 0.005?z?0.024.
    Type: Application
    Filed: July 26, 2011
    Publication date: July 25, 2013
    Applicants: DOWA IP CREATION CO., LTD., DOWA ELECTRONICS MATERIALS CO., LTD.
    Inventors: Takeshi Kawauchi, Yukihiro Matsuda
  • Publication number: 20130183618
    Abstract: Provided is an electrostatic charge image developing toner, each toner particle including a core portion, a first shell layer, and a second shell layer, wherein the core portion contains a first polyester resin, a colorant, and a release agent, the first shell layer contains a second polyester resin and covers the core portion, the second shell layer contains a polymer of an aromatic vinyl monomer and a third polyester resin having an ethylenic unsaturated double bond that is polymerizable with the aromatic vinyl monomer, and covers the first shell layer, and a total amount of the first shell layer and the second shell layer is within a range of from 16% by weight to 40% by weight of the toner particle.
    Type: Application
    Filed: July 3, 2012
    Publication date: July 18, 2013
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Shinpei TAKAGI, Soichiro KITAGAWA, Shinya SAKAMOTO, Tomohiro SHINYA
  • Patent number: 8486597
    Abstract: A toner including an amorphous resin (R), a crystalline material (A) which is compatible with the amorphous resin (R) and has a melting point of 80° C. or lower, a resin (I) which is different from the amorphous resin (R), and a colorant, wherein the crystalline material (A) is capsulated by the resin (I) and the capsulated crystalline material (A) is present in the amorphous resin (R).
    Type: Grant
    Filed: April 5, 2011
    Date of Patent: July 16, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Atsushi Yamamoto, Takuya Kadota, Masayuki Hagi
  • Publication number: 20130171558
    Abstract: It is an object of the present invention to provide a ferrite carrier core material and a ferrite carrier for an electrophotographic developer, which have an excellent charging property, hardly cause carrier scattering due to cracking and chipping of the core material, and have a prolonged life, and methods for manufacturing these, and an electrophotographic developer using the ferrite carrier. For this object, the ferrite carrier core material and a ferrite carrier for an electrophotographic developer, wherein (1) the ferrite composition contains 0.5 to 2.5% by weight of Sr, and the presence amount of Sr—Fe oxides satisfies a specific conditional expression, (2) the distribution in the number of the shape factor SF-2 is in a specific range, (3) the BET specific surface area is 0.15 to 0.30 m2/g, (4) the average particle diameter D50 is 20 to 35 ?m, and (5) the magnetization is 50 to 65 Am2/kg.
    Type: Application
    Filed: August 29, 2011
    Publication date: July 4, 2013
    Applicant: POWDERTECH CO., LTD.
    Inventors: Tomoyuki Suwa, Toru Iwata, Koji Aga
  • Patent number: 8475993
    Abstract: A method for producing a decolorable toner comprising: forming particles containing a color former compound, a color developing agent, and a binder resin; forming first aggregated particles by aggregating and fusing the particles containing the color former compound, the color developing agent, and the binder resin in a dispersion medium; and forming second aggregated particles by aggregating and fusing the first aggregated particles and a binder resin in a dispersion medium.
    Type: Grant
    Filed: November 19, 2010
    Date of Patent: July 2, 2013
    Assignee: Toshiba Tec Kabushiki Kaisha
    Inventor: Masahiro Ikuta
  • Patent number: 8475987
    Abstract: A yellow toner is provided which can form high-quality images and has high offset resistance and excellent charging performance while being a capsule-type toner having excellent low-temperature fixability. The yellow toner satisfies, in DSC measurement, 40.0?Tg(0.5)?60.0 and 2.0?Tg(4.0)?Tg(0.5)?10.0, wherein when the concentration of the yellow toner in an ethyl acetate dispersion is Cy1 (mg/ml) and the light absorbance at a wavelength of 422 nm of the dispersion is A(ethyl acetate)422, the relationship between Cy1 and A(ethyl acetate)422 satisfies A(ethyl acetate)422/Cy1<0.45, and when the concentration of the yellow toner in a chloroform solution is Cy2 (mg/ml) and the light absorbance at a wavelength of 422 nm of the solution is A(chloroform)422, the relationship between Cy2 and A(chloroform)422 satisfies 6.00<A(chloroform)422/Cy2<14.4.
    Type: Grant
    Filed: February 9, 2010
    Date of Patent: July 2, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takaaki Kaya, Ayako Sekikawa, Atsushi Tani, Shigeto Tamura
  • Patent number: 8465896
    Abstract: A black toner has a toner particle including at least a resin (a) having a polyester as a main component, carbon black, and a wax, and a fine inorganic particle. When the Tgs of the black toner measured by DSC at temperature rise rate of 0.5° C./min and 4.0° C./min are defined as Tg(0.5) and Tg(4.0) respectively, Tg(0.5) is 35.0 to 60.0° C. and the difference between Tg(4.0) and Tg(0.5) is 2.0 to 10.0° C. When preparing a solution of which the black toner is dissolved in ethyl acetate and defined the concentration thereof as Cb1 (mg/mL) and the light absorbance thereof at 600 nm wavelength as A600, A600/Cb1 is less than 0.15. When preparing a solution of which the black toner is dissolved in chloroform and defined the concentration thereof as Cb2 (mg/mL) and the light absorbance thereof at 600 nm wavelength as A600, A600/Cb2 is 2.00 to 6.55.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: June 18, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Ayako Sekikawa, Atsushi Tani, Takaaki Kaya, Shigeto Tamura, Makoto Kambayashi
  • Patent number: 8460847
    Abstract: The present invention relates to a toner for electrophotography including a polyester obtained by subjecting a crystalline polyester-containing aqueous dispersion and a non-crystalline polyester-containing aqueous dispersion to aggregation and coalescence, as a resin binder, wherein the crystalline polyester is produced by polycondensing an alcohol component containing 70 mol % or more of an aliphatic diol having 2 to 8 carbon atoms with a carboxylic acid component containing 50 mol % or more of terephthalic acid. The toner is excellent in low-temperature fusing ability and pressure storage stability.
    Type: Grant
    Filed: August 14, 2009
    Date of Patent: June 11, 2013
    Assignee: Kao Corporation
    Inventors: Eiji Shirai, Takashi Kubo, Hiroshi Mizuhata, Shoichi Murata
  • Publication number: 20130137028
    Abstract: A method of manufacturing toner carrier formed of a core and a cover thereon, including the steps of: coating the core with a liquid cover containing a solvent and a material for forming the cover on the core in a processing tank; heating the core and the cover by first microwave radiation to volatilize the solvent from the cover; and removing the solvent volatilized in the step of heating from the processing tank.
    Type: Application
    Filed: November 8, 2012
    Publication date: May 30, 2013
    Inventors: Yoshikatsu Matsuda, Kousuke Suzuki, Yuuki Mizutani
  • Publication number: 20130130171
    Abstract: A toner including a core particle, an inner shell layer covering the core, and an outer shell layer covering the inner shell layer is provided. The core particle includes a resin P. The inner shell layer includes fine particles of a resin A. The outer shell layer includes fine particles of a resin B. The toner satisfies the following formulae (1) to (3): 4.5?T½(P)?Tfb(P)?14??(1) 20?T½(A)?Tfb(A)?40??(2) 23.5?T½(B)?Tfb(B)?40??(3) wherein T½(P), T½(A), and T½(B) represent ½ method temperatures of the resins P, A, and B, respectively, and Tfb(P), Tfb(A), and Tfb(B) represent flow beginning temperatures of the resins P, A, and B, respectively, and wherein the ½ method temperatures and the flow beginning temperatures are measured by a flowtester.
    Type: Application
    Filed: November 1, 2012
    Publication date: May 23, 2013
    Inventors: Masaki Watanabe, Osamu Uchinokura, Junichi Awamura, Takahiro Honda, Satoshi Ogawa, Tsuneyasu Nagatomo, Hiroshi Yamashita
  • Patent number: 8440380
    Abstract: A toner containing core particles each containing at least a resin A having a polyester skeleton and a colorant; and vinyl resin fine particles each of which encapsulates a resin B having at least a polyester skeleton and an endothermic peak measured by differential scanning calorimeter (DSC) at 40° C. to 110° C., wherein the vinyl resin fine particles are attached onto each of the core particles.
    Type: Grant
    Filed: December 6, 2010
    Date of Patent: May 14, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Atsushi Yamamoto, Takuya Kadota, Yoshihiro Mikuriya, Tsuyoshi Nozaki, Yoshimichi Ishikawa, Kazuoki Fuwa, Tomohiro Fukao, Tomoharu Miki, Masayuki Hagi
  • Patent number: 8435715
    Abstract: Disclosed is a production method of a two-component developer for developing an electrostatic image comprising a toner and a resin coated carrier having a porous magnetic core particle and a resin coated layer, wherein the porous magnetic core particle are composed of a porous ferrite material and have pore apertures on a surface of the particle, and the method comprises steps of blocking the pore apertures of the porous magnetic core particle with rubber particles by dry mixing of the porous magnetic core particle and the rubber particles, forming the resin coated carrier by forming a resin layer on the porous magnetic core particle whose pore apertures have been blocked, and mixing the resin coated carrier and the toner.
    Type: Grant
    Filed: July 18, 2011
    Date of Patent: May 7, 2013
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Kosuke Nakamura, Hiroyuki Kozuru, Yoshiyasu Matsumoto, Takanari Kayamori, Junya Ueda
  • Patent number: 8431314
    Abstract: The present invention provides a method for producing a colored resin particle, the method including: preparing an oil phase in which at least a resin and a colorant are dissolved or dispersed in an organic solvent; preparing an aqueous phase containing at least a surfactant in an aqueous medium; dispersing the oil phase in the aqueous phase to prepare a colored particle dispersion liquid so as to form core particles; causing resin fine particles to adhere to surfaces of the core particles by adding at least the resin fine particles to the colored particle dispersion liquid, in which the core particles have been formed; removing the solvent from the colored particle dispersion liquid to obtain colored resin particles, washing the colored resin particles, and drying the colored resin particles, wherein an inorganic base is dissolved in the colored particle dispersion liquid.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: April 30, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Yoshihiro Mikuriya, Tomoharu Miki, Tomohiro Fukao, Kazuoki Fuwa, Takuya Kadota, Yoshimichi Ishikawa, Atsushi Yamamoto, Tsuyoshi Nozaki
  • Patent number: 8431306
    Abstract: Embodiments include a toner having a polyester resin derived from diacids and diesters, in combination with at least one diol, in embodiments a cycloaliphatic diol, an optional crystalline resin, an optional colorant, and an optional wax.
    Type: Grant
    Filed: March 9, 2010
    Date of Patent: April 30, 2013
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Daryl W. Vanbesien, Biritawit Asfaw, Rosa M. Duque, Sonja Hadzidedic
  • Patent number: 8431307
    Abstract: The disclosure provides an electrographic toner having a core layer, which includes a binder, a colorant and two or more types of releasing agents, and a shell layer covering the core layer, and a method of preparing the same.
    Type: Grant
    Filed: November 2, 2010
    Date of Patent: April 30, 2013
    Assignee: SAMSUNG Electronics Co., Ltd.
    Inventors: Jae-hwan Kim, Kyeong Pang, Jin-mo Hong, Su-bum Park, Jeong-hyun Lee, Mi-rim Cho
  • Patent number: 8431308
    Abstract: Toner for developing an electrostatic image, which satisfies charging stability, low-temperature fixability, high-temperature storage characteristics, and durability with respect to an environment up to a predetermined level or above, and a method of preparing the toner. The toner includes: a core layer including a first binder resin, a colorant, and a releasing agent; and a shell layer covering the core layer and including a second binder resin, wherein the first binder resin includes about 70 wt % or above of amorphous polyester resin and about 30 wt % or below of crystalline polyester resin, the second binder resin includes an amorphous polyester resin, and a melting temperature (Tm(C)) of the crystalline polyester resin, a melting temperature (Tm(W)) of the releasing agent, and a melting point (Tm(T)) of the toner satisfy the following conditions: ?20° C.?Tm(W)?Tm(C)?20° C.; and 0° C.<Tm(C)?Tm(T)?10° C.
    Type: Grant
    Filed: October 18, 2010
    Date of Patent: April 30, 2013
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Kyeong Pang, Jae-hwan Kim, Jin-mo Hong, Yo-da Shin, Su-bum Park, Jeong-hyun Lee, Mi-rim Cho
  • Patent number: 8431317
    Abstract: A method for manufacturing a capsule toner, capable of obtaining a capsule toner including a coating layer having uniform thickness at high yield is provided. The method for manufacturing a capsule toner includes a fine resin particle adhering step of adhering fine resin particles to surfaces of toner base particles, a spraying step of spraying a spray liquid for plasticizing the toner base particles and the fine resin particles, while fluidizing the toner base particles and the fine resin particles, and a film-forming step of fluidizing the toner base particles and the fine resin particles until the fine resin particles adhered to the surfaces of the toner base particles are softened to form a film. In the spraying step, ultrasonic vibration is applied to set a number average liquid-droplet diameter of the spray liquid to less than 10 ?m.
    Type: Grant
    Filed: January 19, 2011
    Date of Patent: April 30, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Yoritaka Tsubaki, Yoshitaka Kawase, Keiichi Kikawa, Yoshinori Mutoh, Takashi Hara, Yoshiaki Akazawa
  • Patent number: 8431296
    Abstract: Provided are an electrophotographic toner, a process for preparing the same, image forming method and an image forming apparatus using the toner. The electrophotographic toner may include a latex, colorant, wax, Si and Fe. A molar ratio of Si/Fe may be about 0.1 to about 5.
    Type: Grant
    Filed: July 10, 2009
    Date of Patent: April 30, 2013
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Kyeong Pang, Hae-ree Joo, Jeong-hyun Lee, Su-bum Park
  • Patent number: 8431309
    Abstract: Toner particles are provided which may, in embodiments, include a core and a shell formed in situ. The resins utilized to form the core, the shell, or both, may be contacted with a water soluble initiator. The resin, in embodiments present in the shell, cross-links at a temperature near the temperature for coalescence, and may prevent a crystalline resin in the core from migrating to the toner surface.
    Type: Grant
    Filed: January 6, 2012
    Date of Patent: April 30, 2013
    Assignee: Xerox Corporation
    Inventors: Ke Zhou, Edward G Zwartz, Karen A Moffat
  • Patent number: 8431305
    Abstract: A capsule toner capable of enhancing low temperature fixation property without impairing preservation property under a high temperature environment, a two-component developer, and an image forming apparatus are provided. The capsule toner is constituted of toner particles having toner base particles and a coating layer for coating the surface thereof. The toner base particle includes styrene-acrylic resin or polyester resin as a binder resin, and the coating layer includes styrene-acrylic resin or polyester resin. The capsule toner contains 0.05% by weight or more and 0.70% by weight or less of volatile plasticizer based on a total amount of the capsule toner.
    Type: Grant
    Filed: February 17, 2010
    Date of Patent: April 30, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Keiichi Kikawa, Yoshiaki Akazawa, Yoshitaka Kawase, Yoritaka Tsubaki, Yoshinori Mutoh, Takashi Hara
  • Publication number: 20130101935
    Abstract: A toner is described containing low melt wax and having a core and shell, which toner exhibits improved fusing performance as compared to a toner produced with a high melt wax in the core; having a core resin with a Tg equal to or lower than that of the shell resin; or both.
    Type: Application
    Filed: October 24, 2011
    Publication date: April 25, 2013
    Applicant: Xerox Corporation
    Inventors: Grazyna E. Kmiecik-Lawrynowicz, Daniel A. Asarese, Maura A. Sweeney, Robert D. Bayley, Mark Mang
  • Patent number: 8426096
    Abstract: A capsule toner in which fine solid particles constituting a shell layer are less likely to become detached from the surfaces of toner particles in spite of a long-term use within an image forming apparatus and which is capable of prevention of occurrence of filming on a photoreceptor drum, and a method of manufacturing the capsule toner are provided. The capsule toner includes core particle and shell layers for covering the surface of the core particle. The shell layer is formed of a plurality of fine polyester resin particles. The polyester resins contained in the fine polyester resin particles, respectively, are cross-linked to each other by a cross-linking agent.
    Type: Grant
    Filed: April 14, 2010
    Date of Patent: April 23, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Nobuhiro Maezawa
  • Patent number: 8426095
    Abstract: Disclosed is a decolorable toner containing a binder resin and a coloring agent which contains a color former compound and a color developing agent and has a capsule structure such that it is covered with an outer shell, and having a volume average particle diameter of from 5.0 to 15.0 ?m and a number-based particle size distribution CV of 35% or less.
    Type: Grant
    Filed: December 27, 2010
    Date of Patent: April 23, 2013
    Assignee: Toshiba Tec Kabushiki Kaisha
    Inventors: Takayasu Aoki, Junichi Ishikawa, Tsuyoshi Itou
  • Patent number: 8420286
    Abstract: The present disclosure provides processes for preparing toner particles, in which fewer coarse particles are generated. The process includes introducing a buffer solution during coalescence of the toner slurry. The amount of coarse particles in the resulting toner particles may, in embodiments, be reduced to less than about 5 percent by weight of the total toner particles generated.
    Type: Grant
    Filed: March 27, 2008
    Date of Patent: April 16, 2013
    Assignee: Xerox Corporation
    Inventors: Kimberly D. Nosella, Guerino G. Sacripante
  • Publication number: 20130084521
    Abstract: The carrier core particles for electrophotographic developer include a core composition expressed by a general formula Fe3O4 as a main ingredient and 30 ppm to 400 ppm Na. Such carrier core particles can reduce environmental dependency thereof, while optimizing the resistivity.
    Type: Application
    Filed: May 17, 2011
    Publication date: April 4, 2013
    Applicants: DOWA IP CREATION CO., LTD., DOWA ELECTRONICS MSTERIALS CO., LTD
    Inventor: Takeshi Kawauchi
  • Publication number: 20130078567
    Abstract: A method for regenerating a carrier core material for electrophotography, including: treating a carrier for electrophotography including a carrier core material for electrophotography and a coating layer on a surface of the carrier core material for electrophotography with an aqueous solution including an oxidant in a subcritical state or a supercritical state having a temperature of 280° C. or greater and a density of 0.20 g/cm3 or greater, wherein an amount of the oxidant in a total amount of the aqueous solution used in the treating is greater than 0.05 parts by mass with respect to 1 part by mass of the carrier for electrophotography to be treated in the treating.
    Type: Application
    Filed: September 24, 2012
    Publication date: March 28, 2013
    Inventors: Takayuki Shimizu, Kazumi Ohtaki, Shinichiro Yagi, Takeshi Sako, Idzumi Okajima
  • Patent number: 8399167
    Abstract: The present invention relates to a toner composition for forming a masking pattern for use e.g. in connection with a method of building up a three-dimensional body from a large number of mutually connected layers of powder particles that are bonded to each other using radiant heat. The toner composition consists of powder particles that arc able to withstand a temperature of at least 200° C. without sticking together. It also relates to a developer that comprises the toner composition and carrier particles and a method in connection with the production of a volume body by using a toner composition or a developer according to the invention.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: March 19, 2013
    Assignee: Sintermask GmbH
    Inventors: David Hermann, Ralf Larson
  • Publication number: 20130065175
    Abstract: A carrier for developing electrostatic latent image, including a core material; and a coated layer covering the core material, including a binder resin and a particulate material, wherein the core material is exposed on the surface of the carrier at an areal ratio of from 0.1 to 5.0% and has the largest exposed part having an areal ratio not greater than 0.03%, and wherein the coated layer comprises the particulate material in an amount of from 100 to 500 parts by weight per 100 parts by weight of the binder resin.
    Type: Application
    Filed: July 24, 2012
    Publication date: March 14, 2013
    Inventors: Koichi Sakata, Shigenori Yaguchi, Kimitoshi Yamaguchi, Toyoshi Sawada, Hiroshi Tohmatsu, Hiroyuki Kishida
  • Patent number: 8394562
    Abstract: Coated phosphorescent pigments are provided which may be utilized in toner compositions. In embodiments, the phosphorescent pigment may be coated by a powder coating process. The large pigment particles may be dry blended with dried resin latex particles, thereby coating the pigment surface, followed by heating and shearing in a rotary kiln or extruder to melt the toner resin and fuse it to the pigment surface. The resulting coated particles may be utilized with other toners, in embodiments color toners, to provide phosphorescent images.
    Type: Grant
    Filed: June 29, 2009
    Date of Patent: March 12, 2013
    Assignee: Xerox Corporation
    Inventors: Richard P. N. Veregin, Eric Rotberg, Michael S. Hawkins, Cuong Vong, Jordan H. Wosnick
  • Patent number: 8394564
    Abstract: A polymerized toner is provided. The polymerized toner has cores containing polyvinylidene fluoride particles. The polyvinylidene fluoride particles have an average particle diameter of 1.1 to 1.5 ?m and a melting temperature (Tm) of 140 to 160° C. The polyvinylidene fluoride particles are distributed at a higher concentration near the surface of the cores. This distribution improves the affinity of the cores for silica as an external additive to achieve an increased amount of surface charge and improved transfer efficiency of the polymerized toner. Further provided is a method of producing the polymerized toner.
    Type: Grant
    Filed: November 3, 2009
    Date of Patent: March 12, 2013
    Assignee: LG Chem, Ltd.
    Inventors: Wook Jang, Chang Soon Lee
  • Patent number: 8394565
    Abstract: A positively charged developer for development of electrostatic images, comprising positively charged toner particles and an external additive, wherein the positively charged toner particles are colored resin particles composed of aggregated and fusion-bonded particles of fine binder resin particles and fine colorant particles and having a shape factor SF-1 of 115 to 150 and a shape factor SF-2 of 110 to 140, and the external additive is an external additive containing positively charged inorganic particles subjected to a hydrophobization treatment with an amino group-containing compound, and a production process thereof.
    Type: Grant
    Filed: March 30, 2007
    Date of Patent: March 12, 2013
    Assignee: Zeon Corporation
    Inventor: Keita Sensui
  • Patent number: 8389194
    Abstract: A toner manufacturing method, a toner obtained by the method, a one-component developer, a two-component developer, a developing device and an image forming apparatus are provided. By using a toner manufacturing apparatus including a powder passage, a spraying section for spraying a predetermined substance in the powder passage and a rotary stirring section, provided in the powder passage, and stirring particles in the powder passage to apply impact force to the particles so that the particles are fluidized in the powder passage, performed are a stirring step S3 of fluidizing toner core particles with fine inorganic particles adhering to the surfaces thereof and fine resin particles in the powder passage as the powder by the rotary stirring section, and a spraying step S5 of spraying a volatile liquid which softens fine resin particles as a predetermined substance by the spraying section.
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: March 5, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Yoshiaki Akazawa, Yoshitaka Kawase, Yoritaka Tsubaki, Yoshinori Mutoh, Keiichi Kikawa, Takashi Hara
  • Patent number: 8389193
    Abstract: There are provided a toner manufacturing method of manufacturing a toner which has excellent characteristics such as fluidity and preservation stability and in which a resin layer having uniform thickness is formed on a surface of tone core particle, a toner obtained by a method thereof, a one-component developer, a two-component developer, a developing device, and an image forming apparatus. By using a toner manufacturing apparatus, a stirring step S3 is performed, and during rotation of a rotary shaft section, after a completion of inputting the fine resin particles into a powder passage, and within a period satisfying 1.7?(load F?load F0)/(load Fcore?load F0)?5.7, a spraying step S4 is started.
    Type: Grant
    Filed: March 24, 2010
    Date of Patent: March 5, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Takashi Hara, Yoshitaka Kawase, Yoshiaki Akazawa, Yoritaka Tsubaki, Keiichi Kikawa, Yoshinori Mutoh
  • Patent number: 8389189
    Abstract: The present invention relates to a resin binder for toners which includes core/shell particles each including a core portion containing a crystalline polyester obtained by polycondensing an alcohol component containing an aliphatic diol having 2-12 carbon atoms and a carboxylic acid component containing an aliphatic dicarboxylic acid compound having 8-12 carbon atoms in an amount of 70-100 mol %, and a non-crystalline resin (A) obtained by polycondensing an alcohol component and a carboxylic acid component containing at least one succinic acid compound selected from the group consisting of an alkyl (C9-C18) succinic acid and an alkenyl (C9-C18) succinic acid in an amount of 3-60 mol %; and a shell portion containing a non-crystalline resin (B) obtained by polycondensing a carboxylic acid component and an alcohol component containing an aliphatic dialcohol having 2-5 carbon atoms in an amount of 80 mol % or more.
    Type: Grant
    Filed: March 2, 2011
    Date of Patent: March 5, 2013
    Assignee: Kao Corporation
    Inventors: Eiji Shirai, Shoichi Murata
  • Patent number: 8383313
    Abstract: Provided is a toner including toner particles each containing a binder resin, a colorant, and a wax, and inorganic fine particles, the toner having such a characteristic that a temperature-storage elastic modulus curve at a high frequency shows a characteristic change in its behavior in a specific temperature region with respect to a temperature-storage elastic modulus curve at a low frequency.
    Type: Grant
    Filed: December 3, 2010
    Date of Patent: February 26, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasukazu Ayaki, Tsuneyoshi Tominaga
  • Publication number: 20130045442
    Abstract: A toner including a resin particle (C) is provided. The resin particle (C) includes a resin particle (B) and a resin particle (A). The resin particle (B) includes a resin (b). The resin particle (A) or covering layer (P) includes a resin (a). The resin particle (A) or covering layer (P) is adhered to a surface of the resin particle (B). The resin (a) is a polyester resin. The resin (a) has a total acid value of 15 to 36 mgKOH/g. The resin particle (A) or covering layer (P) has a surface acid value of 10 to 27 mgKOH/g.
    Type: Application
    Filed: August 2, 2012
    Publication date: February 21, 2013
    Inventors: Yoshihiro MORIYA, Shinya Nakayama, Atsushi Yamamoto, Hideyuki Santo, Akiyoshi Sabu, Yukiko Nakajima, Daiki Yamashita
  • Patent number: 8361690
    Abstract: A toner for developing electrostatic latent images, including a binder resin; a colorant; and a release agent, wherein the toner has a glass transition temperature (Tg) of from 55 to 75° C., a melting point (T1/2) of from 95 to 125° C. as measured by a flow tester in a ½ method, and ?Ts of from 1 to 5° C., and wherein ?Ts is defined by the following formula: ?Ts=Ts?T(Ls/2) wherein Ts is a softening point of the toner; T(Ls/2) is a temperature when a stroke is Ls/2; and Ls is a stroke (mm) at Ts.
    Type: Grant
    Filed: June 9, 2010
    Date of Patent: January 29, 2013
    Assignee: Ricoh Company, Limited
    Inventors: Yuka Sakaguchi, Hideki Sugiura
  • Publication number: 20120308923
    Abstract: A toner composition includes resin core particles having outer surfaces, and surface treatment, wherein the surface treatment includes at least first metal oxide particles having a surface area equivalent average particle diameter of greater than 25 nm and a surface energy of less than 28 erg/cm2, as determined by methanol wettability midpoint at 22° C., tacked to the outer surfaces of the resin core particles, at a concentration to provide a total projected area of the first metal oxide particles sufficient to cover at least 10% of the resin core particle outer surfaces area, and wherein the toner composition comprises less than 0.013 g non-tacked surface treatment per square meter of resin core particles outer surface. A developer for developing electrostatic images includes magnetic carrier particles and toner as described above, wherein the developer comprises less than 0.
    Type: Application
    Filed: June 30, 2011
    Publication date: December 6, 2012
    Inventors: Kevin D. Lofftus, Peter S. Alexandrovich