Identified Physical Parameter Of Carrier Particle Or Dry Toner Particle, Etc. (tg, Mw, Coercivity, Density, Etc.) Patents (Class 430/111.4)
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Patent number: 8778585Abstract: A toner with good low-temperature fixability even in light-pressure type fixing units, which causes no contamination of fixing films and provides images having stable image densities and excellent image quality after long-term use. The toner includes a toner particle containing a binder resin, a coloring agent, a release agents (a) and (b) The release agent (a) is a monofunctional or bifunctional ester wax; the release agent (b) is a hydrocarbon wax; a solubility of the release agent (a) into the binder resin is higher than that of the release agent (b). When tetrahydrofuran-soluble components of the toner are subjected to GPC, a proportion of components having a molecular weight of 500 or less is 2.5 area % or less. When the tetrahydrofuran-soluble components at 25° C. are subjected to SEC-MALLS, a weight-average molecular weight Mw thereof is 5,000-100,000, and the Mw and the radius of gyration Rw thereof satisfy 5.0×10?4?Rw/Mw?1.0×10?2.Type: GrantFiled: September 12, 2011Date of Patent: July 15, 2014Assignee: Canon Kabushiki KaishaInventors: Takashi Matsui, Michihisa Magome, Tomohisa Sano, Shuichi Hiroko, Yoshitaka Suzumura, Shotaro Nomura
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Patent number: 8758969Abstract: A method for producing an antenna structure for an RFID device, a dry toner for use in producing an antenna for an RFID device and a RFID device comprising an antenna structure made of fused toner are disclosed. In a method for producing an antenna structure for an RFID device, a dry toner comprising a polymeric binder and metallic particles is provided. The toner comprises particles having a resistance allowing triboelectric charging or a resistance allowing inductive charging, wherein said metallic particles are nanoparticles having a mean particle size below approximately 500 nm in at least one direction. In the method, a continuous layer of the dry toner is applied to a substrate in a desired shape of an antenna via an electrophotographic printing process, and subsequently the toner is fused to the substrate by heating the toner above its glass transformation temperature.Type: GrantFiled: December 22, 2007Date of Patent: June 24, 2014Assignee: Eastman Kodak CompanyInventors: Detlef Schulze-Hagenest, Dinesh Tyagi
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Patent number: 8741521Abstract: A toner containing toner particles, each toner particle containing: a releasing agent; a colorant; and a binder resin containing at least a crystalline polyester resin and a non-crystalline polyester resin, wherein in the case where a volume average particle diameter of the toner is defined as Dv, the toner contains a group of the toner particles having 4/5 Dv, and a group of the toner particles having 6/5 Dv, and wherein an endothermic value A of the crystalline polyester resin at a first temperature increase in DSC of the toner, an endothermic value B of the crystalline polyester resin at a first temperature increase in DSC of the group of the toner particle having 4/5 Dv, and an endothermic value C of the crystalline polyester resin at a first temperature increase in DSC of the group of the toner particles having 6/5 Dv satisfy the relation represented by the following formulas: 50<(B/A)×100<90, and 110<(C/A)×100<150.Type: GrantFiled: September 14, 2011Date of Patent: June 3, 2014Assignee: Ricoh Company, Ltd.Inventors: Mamoru Hozumi, Tsuyoshi Sugimoto, Naohiro Watanabe, Tomoyuki Satoh, Shinya Hanatani, Osamu Uchinokura, Kiwako Hirohara
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Patent number: 8741525Abstract: The resin coated carrier is used with a toner in which an external additive having an average primary particle size of 50 nm or more is added to a toner particle, and has a carrier core and a resin coating layer on the surface of the carrier core. In the resin coated carrier, the following expression (1) is satisfied: 0.5??log {(A/C)/(B/C)}?2.5??(1) wherein A represents a volume resistance value (?/cm) of the resin coated carrier in an electric field of 1000 V/cm that is obtained by conducting a stirring test, B represents a volume resistance value (?/cm) of the resin coated carrier in an electric field of 1000 V/cm before the stirring test, and C represents a volume resistance value (?/cm) of the carrier core in an electric field of 1000 V/cm.Type: GrantFiled: July 1, 2009Date of Patent: June 3, 2014Assignee: Sharp Kabushiki KaishaInventors: Osamu Wada, Takanori Kamoto, Tadashi Iwamatsu, Nobuyuki Yoshioka, Hiroyuki Hirakawa, Yoshinori Mutoh, Takashi Hara, Hirofumi Kanda, Yoshio Ichii
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Publication number: 20140147779Abstract: A toner is provided. The toner includes a crystalline resin and a non-crystalline resin, and has a thermal property such that when the toner is heated after being firstly heated to 60° C. followed by cooling in differential scanning calorimetry (DSC), the toner has a clear peak specific to melting of the crystalline resin at a temperature T1, and when the toner is heated after being firstly heated to 80° C. followed by cooling in the differential scanning calorimetry (DSC), the toner does not have a clear peak specific to melting of the crystalline resin at a temperature not higher than the temperature T1.Type: ApplicationFiled: October 1, 2013Publication date: May 29, 2014Inventors: Kazuoki FUWA, Takuya KADOTA, Yoshihiro MIKURIYA, Tsuyoshi NOZAKI, Yoshimichi ISHIKAWA, Yuta TAKEUCHI, Tomohiro FUKAO, Tomoharu MIKI, Takayuki NAKAMURA
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Publication number: 20140141370Abstract: Provided is a suitable toner external additive which has an excellent spacer effect, without causing image defects in repeated image formation and which is suitable in preparing a toner with stable printing properties and to provide a fine spherical silica powder suitable for adding to the toner additive. A fine spherical silica power having an average particle size measured by a laser diffraction/scattering distribution measuring apparatus of 0.090 ?m or more and 0.140 ?m or less, a particle content ratio of 5.0% by mass or more and 25.0% by mass or less when the particle diameter is 0.150 ?m or more, and a particle content ratio of 1.0% by mass or less when the particle diameter is 0.300 ?m or more.Type: ApplicationFiled: January 28, 2014Publication date: May 22, 2014Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHAInventors: Shuji SASAKI, Masaaki HIDESHIMA, Hideaki SONODA, Takahisa MIZUMOTO
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Patent number: 8728698Abstract: The present invention is to provide a carrier and a developer, which have fewer occurrences of carrier adhesion and background smear, excellent granularity and longer durability. The carrier comprises the core material particles having magnetism and resin coating layer covering the core material particles, and wherein the weight average particle diameters is in the range of 22 m to 32 m, the proportion of the weight average particle diameters relative to the number average particle diameter is in the range of 1.00 to 1.20, the content of particles having a diameter of 20 m or smaller is 7% by mass, the content of carrier particles having a diameter of 36 m or smaller is in the range of 90% by mass to 100% by mass, and the proportion of the particle density of the core material particles is in the range of 85% to 100% of the true density of the core material particles.Type: GrantFiled: March 6, 2007Date of Patent: May 20, 2014Assignee: Ricoh Company, Ltd.Inventors: Masashi Nagayama, Kimitoshi Yamaguchi, Naoki Imahashi
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Patent number: 8728699Abstract: A porous ferrite core material for an electrophotographic developer, the porous ferrite core material including Mg in a content of 0.3 to 3% by weight, Ti in a content of 0.4 to 3% by weight and Fe in a content of 60 to 70% by weight, and the porous ferrite core material having a pore volume of 0.04 to 0.16 ml/g, a peak pore size of 0.4 to 1.6 ?m, a saturation magnetization of 40 to 80 Am2/kg, a remanent magnetization of less than 7 Am2/kg and a coercive force of less than 43 A/m; a resin-filled ferrite carrier for an electrophotographic developer obtained by filling a resin in the voids of the porous ferrite core material; and an electrophotographic developer using the ferrite carrier.Type: GrantFiled: October 19, 2010Date of Patent: May 20, 2014Assignee: Powedertech Co., Ltd.Inventors: Toru Iwata, Koji Aga
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Patent number: 8728689Abstract: Provided are a toner containing at least a binder resin and a colorant, the toner having a specific hue angle and an absorbance at a specific wavelength in reflectance spectrophotometry, and a full-color image-forming method involving the use of the toner, the method including the steps of: forming an electrostatic image on a charged electrostatic image bearing member; developing the formed electrostatic image with the toner to form a toner image; transferring the formed toner image onto a transfer material; and fixing the transferred toner image to the transfer material to form a fixed image.Type: GrantFiled: December 17, 2010Date of Patent: May 20, 2014Assignee: Canon Kabushiki KaishaInventors: Yasukazu Ayaki, Shigeto Tamura
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Patent number: 8715898Abstract: An electrostatic charge image developer includes a toner for developing an electrostatic charge image, containing toner particles including a polyester resin having a rosin skeleton and an external additive, and a carrier having core material particles and a coating resin layer which coats the surface of the core material particles, in which the hardness of the coating resin layer is from 1.2 times to 2.0 times that of the toner particles.Type: GrantFiled: June 27, 2012Date of Patent: May 6, 2014Assignee: Fuji Xerox Co., Ltd.Inventor: Kazuhiko Yanagida
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Patent number: 8703378Abstract: A method of manufacturing toner including mixing mother toner particles containing a binder resin and a coloring agent and first particles having an average primary particle diameter of from 100 nm to 1 ?m to using a mixer including a rotary shaft member, multiple stirring members provided to the surface of the shaft member, and a casing to cover the multiple stirring members, wherein the cross section of the inner periphery of the casing relative to a direction perpendicular to the rotation axis of the shaft member is circular around the rotation axis with a substantially constant distance between the inner periphery and the rotation axis. The casing covers the multiple stirring members and a cooling jacket is provided to at least part of the outer periphery of the casing. The weight ratio of the particles to the mother toner particles is from 1.5% to 10%.Type: GrantFiled: September 16, 2011Date of Patent: April 22, 2014Assignee: Ricoh Company, Ltd.Inventors: Kohsuke Satoh, Tetsuya Tanaka, Masahiro Kawamoto, Natsuko Matsushita
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Patent number: 8691484Abstract: Disclosed is a non-magnetic toner for use in developing electrostatic toner image, wherein the toner is produced by a toner production method that includes: dispersing in an aqueous medium an organic dispersion liquid that comprises in an organic solvent a pigment, a binder resin and/or a binder resin precursor, and a releasing agent; removing the organic solvent to prepare a dispersion slurry in which toner particles are dispersed in the aqueous medium; heating the dispersion slurry to a temperature equal to or higher than the melting point of the releasing agent; and washing the toner particles.Type: GrantFiled: March 12, 2008Date of Patent: April 8, 2014Assignee: Ricoh Company, Ltd.Inventors: Tsuyoshi Nozaki, Chiyoshi Nozaki, Atsushi Yamamoto, Mitsuyo Matsumoto, Takuya Kadota, Katsunori Kurose, Yoshimichi Ishikawa
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Patent number: 8685602Abstract: There is provided a toner for electrophotography containing at least a binder resin, a colorant and a barium compound, and having a relaxation modulus G(t) of from about 2.0×102 Pa to about 3.0×103 Pa in a relaxation time of t=10×Dt (wherein Dt is the heating time taken during fixing) as determined by the measurement of dynamic viscoelasticity, and a barium content of from about 0.1% to about 0.5% with respect to the total amount of constituent atoms in the toner as determined by X-ray fluorescence.Type: GrantFiled: August 16, 2011Date of Patent: April 1, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Yuka Ishihara, Emi Takahashi, Masahiro Okita
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Patent number: 8685613Abstract: A method of producing an electrostatic latent image developing toner that includes the steps of producing a resin particle dispersion by polymerizing, in a water-based solvent, a polymerizable monomer that includes a polymerizable monomer having a vinyl-based double bond, and washing the resin particle dispersion through contact with an organic solvent, wherein the washed resin particle dispersion, a colorant particle dispersion produced by dispersing a colorant, and a release agent particle dispersion produced by dispersing a release agent are mixed together, and following formation of aggregate particles by aggregation of the resin particles, the colorant particles and the release agent particles, heating is conducted to fuse the aggregate particles and produce the electrostatic latent image developing toner.Type: GrantFiled: June 24, 2013Date of Patent: April 1, 2014Assignee: Fuji Xerox Co., Ltd.Inventor: Masaaki Suwabe
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Patent number: 8685612Abstract: A continuous emulsion aggregation process for the production of particles is presented including a plurality of continuous stirred-tank reactors (CSTR). The plurality of continuous stirred-tank reactors includes a first reactor and a second reactor for facilitating an aggregation process; a third reactor for facilitating a shell addition process; a fourth reactor for facilitating a freeze process; a fifth reactor for facilitating a chelating process; a sixth reactor for facilitating a ramp-up process; and a seventh reactor for facilitating a coalescence process. The reactors are sequentially assembled in a series configuration, each of the reactors cooperating with an overhead stirrer. In other embodiments, a CSTR system of the present disclosure possesses five reactors sequentially assembled in a series configuration to form toner particles.Type: GrantFiled: January 18, 2011Date of Patent: April 1, 2014Assignee: Xerox CorporationInventors: Santiago Faucher, Kimberly D. Nosella, Lai Chi So
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Patent number: 8679714Abstract: A toner including: a first binder resin; a colorant; a releasing agent; and a crystalline organic compound, wherein the first binder resin contains an amorphous polyester resin (a) having a polyhydroxycarboxylic acid skeleton derived from optically active monomers in a part of a main chain of the amorphous polyester resin, and the polyhydroxycarboxylic acid skeleton has an optical purity X, calculated on the monomer basis, of 80% or less, and the optical purity X is determined from the equation, Optical Purity X (%)=|X(L-form)?X(D-form)| wherein the crystalline organic compound is any one of a crystalline polyester resin (b) and a crystalline low molecular compound having a melting point of 60° C. to 100° C., and being selected from a group consisting of fatty acid having 16 to 24 carbon atoms, alcohol having 16 to 24 carbon atoms, a fatty acid ester compound, and aliphatic carboxylic acid amide.Type: GrantFiled: September 9, 2010Date of Patent: March 25, 2014Assignee: Ricoh Company, Ltd.Inventors: Ryota Inoue, Akihiro Kotsugai, Yoshihiro Moriya, Akiyoshi Sabu, Shingo Sakashita, Keiko Osaka, Yukiko Nakajima, Yoshitaka Yamauchi, Daiki Yamashita
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Publication number: 20140080047Abstract: To provide an electrophotographic toner, which contains a crystalline resin, a non-crystalline resin, a colorant, and a releasing agent, wherein the toner has a storage elastic modulus of 5.0×104 Pa to 5.0×106 Pa at 80° C., and a storage elastic modulus of 2.0×102 Pa to 2.0×103 Pa at 140° C., and wherein the toner has a ratio (C)/((C)+(A)) of 0.10 or greater, where (C) is an integrated intensity of a diffraction spectrum derived from a crystalline structure, (A) is an integrated intensity of a diffraction spectrum derived from a non-crystalline structure, and the diffraction spectrum is a diffraction spectrum of the toner as measured by an X-ray diffraction spectrometer.Type: ApplicationFiled: September 17, 2013Publication date: March 20, 2014Inventors: Rintaro TAKAHASHI, Kazumi SUZUKI, Masana SHIBA, Tatsuya MORITA, Yoshitaka YAMAUCHI, Azumi MIYAAKE
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Patent number: 8673529Abstract: The present invention relates to a magnetic carrier for an electrophotographic developer comprising spherical composite particles comprising spherical composite core particles comprising at least ferromagnetic iron oxide fine particles and a cured phenol resin and having an average particle diameter of 1 to 100 ?m, and a melamine resin coating layer formed on the respective core particles, wherein a ratio of R100 to R300 (R100/R300) in which R100 is an electric resistance value as measured when applying a voltage of 100 V to the magnetic carrier; and R300 is an electric resistance value as measured when applying a voltage of 300 V to the magnetic carrier, is controlled to lie within the range of 1 to 50.Type: GrantFiled: June 15, 2010Date of Patent: March 18, 2014Assignee: Toda Kogyo CorporationInventors: Kaori Kinoshita, Shinji Uemoto, Eiichi Kurita
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Patent number: 8673530Abstract: The present disclosure describes toner compositions comprising an alkyl surface-treated silica, which toners exhibit improved tribo-charging, second transfer efficiency and IQ without impacting color.Type: GrantFiled: November 9, 2011Date of Patent: March 18, 2014Assignee: Xerox CorporationInventors: Suxia Yang, Richard P N Veregin, Magid Kamel, Cuong Vong, Kimberly Nosella, Eric Rotberg
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Patent number: 8663892Abstract: A latent electrostatic image developing carrier including: core particles each having magnetism; and a coating layer covering each of the core particles, wherein the latent electrostatic image developing carrier has a shape factor SF-2 of 115 to 150 and has a bulk density of 1.8 g/cm3 to 2.4 g/cm3, wherein the core particles have a shape factor SF-2 of 120 to 160 and have an arithmetic mean surface roughness Ra of 0.5 ?m to 1.0 ?m, and wherein the coating layer contains a resin and a filler and an amount of the filler contained in the coating layer is 50 parts by mass to 500 parts by mass per 100 parts by mass of the resin contained in the coating layer.Type: GrantFiled: August 23, 2012Date of Patent: March 4, 2014Assignee: Ricoh Company, Ltd.Inventors: Shigenori Yaguchi, Kimitoshi Yamaguchi, Toyoshi Sawada, Hitoshi Iwatsuki, Toyoaki Tano, Hiroshi Tohmatsu
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Patent number: 8658340Abstract: A toner containing a binder resin comprising a first binder resin A and a second binder resin B, a coloring agent, and a releasing agent, wherein the first binder resin A is formed by reacting a compound A1 having an active hydrogen group with a resin A2 having a portion reactive with the compound A1 in an organic solvent and the resin A2 is formed by reacting a non-crystalline polyester resin “a” having a polyhydroxy carboxylic acid skeleton in the main chain with a compound having the portion reactive with the compound A1 having an active hydrogen group.Type: GrantFiled: May 9, 2011Date of Patent: February 25, 2014Assignee: Ricoh Company, Ltd.Inventors: Shingo Sakashita, Shinya Nakayama, Ryota Inoue, Yoshihiro Moriya, Akiyoshi Sabu, Yukiko Nakajima, Daiki Yamashita
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Patent number: 8652736Abstract: The present invention provides a carrier core material for use in the production of an electrophotographic developer which, even when applied, for example, to MFPs (multifunction printers), can realize stable, high-quality and high-speed development, and has a prolonged replacing life of magnetic carriers, and a method of manufacturing the same, a magnetic carrier including the carrier core material, and an electrophotographic developer manufactured from the magnetic carrier. An electrophotographic development carrier is prepared by adding resin particles, a binder, a dispersant, a wetting agent, and water to a raw material powder, wet pulverizing the mixture, drying the pulverized product to give granulated powder, calcinatng the granulated powder, and then sintering the granulated powder to prepare a carrier core material having an internally hollow structure, and coating the carrier core material with a resin.Type: GrantFiled: September 25, 2006Date of Patent: February 18, 2014Assignees: Dowa IP Creation Co., Ltd., Dowa Electronics Materials Co., Ltd.Inventors: Ryusuke Nakao, Takeshi Kawauchi
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Patent number: 8642240Abstract: A decolorable electrophotographic toner, containing a color former compound, a color developing agent, a binder resin, and a release agent, wherein the toner has a pH of from 6 to 9 when dispersed in water with a pH of from 5.5 to 7 at a mass ratio of toner/water of 1/10.Type: GrantFiled: February 26, 2013Date of Patent: February 4, 2014Assignee: Toshiba Tec Kabushiki KaishaInventor: Satoshi Araki
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Patent number: 8642237Abstract: In differential scanning calorimetry of a toner, regarding a binder resin in the toner, (i) the peak temperature T10 of a maximum endothermic peak (temperature raising rate 10.0° C./min; P10) is 50° C. to 80° C. and the half-width W10 is 2.0° C. to 3.5° C. and (ii) W1, W10, and W20 satisfy that W1/W10 is 0.20 to 1.00 and W20/W10 is 1.00 to 1.50, where the half-width of a maximum endothermic peak (temperature raising rate of 1.0° C./min; P1) is represented by W1 (° C.) and the half-width of a maximum endothermic peak (temperature raising rate of 20.0° C./min; P20) is represented by W20 (° C.).Type: GrantFiled: July 20, 2011Date of Patent: February 4, 2014Assignee: Canon Kabushiki KaishaInventors: Atsushi Tani, Tetsuya Kinumatsu, Ayako Okamoto, Kenji Aoki, Shuntaro Watanabe, Takaaki Kaya, Takashige Kasuya
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Patent number: 8628905Abstract: A ferrite core material for a resin-filled type carrier, and a resin-filled type carrier which is used as an electrophotographic developer by mixing a toner, sufficiently secure the image density, have no carrier adhesion and can maintain high-quality images over a long period, and an electrophotographic developer using the carrier, are provided. A ferrite core material for a resin-filled type carrier characterized in a void fraction of 10 to 60%, a resin-filled type carrier filled in the carrier core material with a resin, and an electrophotographic developer composed of the resin-filled type carrier and a toner, are provided.Type: GrantFiled: May 31, 2006Date of Patent: January 14, 2014Assignee: Powdertech Co. Ltd.Inventors: Hiromichi Kobayashi, Tsuyoshi Itagoshi, Tomoyuki Suwa, Toshio Honjo
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Patent number: 8628904Abstract: The present invention provides a carrier for replenishment including an associated particle in which single particles each having a core material and a resin layer covering the core material, are bound via the resin layer, the carrier being used in a developer for replenishment of a trickle development system, and the system including performing development while the developer for replenishment is replenished, upon development of a latent image on a latent image holding member using a development unit.Type: GrantFiled: July 24, 2009Date of Patent: January 14, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Moegi Iguchi, Satoshi Inoue, Koutarou Yoshihara, Masahiro Takagi
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Patent number: 8614044Abstract: To provide a toner which can achieve both low-temperature fixing performance and dot reproducibility and further can obtain images on which any density non-uniformity has been kept from coming about, the toner has toner particles, each of the toner particles has a toner base particle containing a binder resin, a colorant and a release agent, and an inorganic fine powder; the toner having: (1) an average circularity of 0.960 or more; (2) a number-average molecular weight Mn(25° C.) of from 500 or more to 3,000 or less in measuring a tetrahydrofuran-soluble matter at 25° C. of the toner by SEC-MALLS; and (3) a value of Mn(135° C.)/Mn(25° C.) of from 25 or more to 50 or less which is the ratio of number-average molecular weight Mn(135° C.) in measuring an o-dichlorobenzene-soluble matter at 135° C. of the toner by SEC-MALLS to number-average molecular weight Mn(25° C.) in measuring a tetrahydrofuran-soluble matter at 25° C. of the toner by SEC-MALLS.Type: GrantFiled: June 13, 2011Date of Patent: December 24, 2013Assignee: Canon Kabushiki KaishaInventors: Takashi Matsui, Michihisa Magome, Yusuke Hasegawa, Tomohisa Sano, Shuichi Hiroko, Yoshitaka Suzumura, Shotaro Nomura, Atsuhiko Ohmori
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Patent number: 8603716Abstract: An electrostatic image developing carrier includes a ferrite particle and a resin layer that coats the ferrite particle, wherein a magnesium element content of the ferrite particle is from about 3.0% by weight to about 20.0% by weight; wherein a manganese element content of the ferrite particle is from about 0.2% by weight to about 0.8% by weight; and wherein a content of toluene is more than about 100 ppm and not more than about 2,000 ppm.Type: GrantFiled: April 7, 2010Date of Patent: December 10, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Takeshi Shoji, Akihiro Iizuka, Yosuke Tsurumi, Fusako Kiyono
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Patent number: 8603718Abstract: An anisotropic magnetic material-dispersed resin carrier including: fine magnetic particles; and a binder resin in which at least the fine magnetic particles are dispersed, wherein the anisotropic magnetic material-dispersed resin carrier has a magnetic anisotropy where magnetic fields of the fine magnetic particles are orientated in the same direction, and wherein the anisotropic magnetic material-dispersed resin carrier has a saturation magnetization of 16 emu/g to 30 emu/g, a coercive force of 15 kA/m to 40 kA/m, and a number average particle diameter of 15 ?m or more but less than 100 ?m.Type: GrantFiled: January 31, 2012Date of Patent: December 10, 2013Assignee: Ricoh Company, Ltd.Inventors: Kazumi Suzuki, Masaki Yoshino, Hisao Kurosu, Tatsuya Morita, Tomoko Kino, Shingo Sakashita
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Patent number: 8603717Abstract: Provided are a toner and a method of preparing the same. The toner includes a binder resin, a coloring agent, and at least one additive, and a storage modulus curve of the toner with respect to temperature has multiple inflection points. The toner may be used in an electrophotographic image forming apparatus.Type: GrantFiled: July 22, 2009Date of Patent: December 10, 2013Assignee: Samsung Fine Chemicals Co., Ltd.Inventors: Jae Bum Park, Woo Young Yang, Keon Il Kim, Dae Il Hwang, Il Hyuk Kim, Il Sun Hwang, Jae Kwang Hwang, Dae Woong Choi, Dong Won Kim, Duck Kyun Ahn
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Publication number: 20130323636Abstract: The present disclosure is drawn to an electrostatic ink composition comprising: (a) a carrier liquid; (b) particles comprising: (i) a polymer having a melt flow rate of less than 60 g/10 minutes, (ii) a colorant, (c) a charge director, wherein the electrostatic ink composition excludes a positively charged organic molecule or an organic molecule capable of becoming a positively charged organic molecule during an electrostatic printing process. Also disclosed herein is a method of producing a electrostatic ink composition and a method of electrophotographic printing an electrostatic ink composition.Type: ApplicationFiled: March 30, 2011Publication date: December 5, 2013Applicant: Hewlett-Packard Indigo B.V.Inventors: Gil Bar-Haim, Eyal Bodinger, Albert Teishev, Marc Klein, Alexey Kabalnov, Guang Jin Li
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Patent number: 8592124Abstract: A toner having: a peak temperature before fixation T1a of about 40° C. or more; and a peak temperature after fixation T1b that is lower than T1a by from about 10° C. to about 35° C.: T1a being a peak temperature of an endothermic peak occurring at the lowest temperature in a range of from 0° C. to 100° C. and obtained at a first warming-up step of a differential scanning calorimetry measurement that uses a toner before fixation as a sample; T1b being a peak temperature of an endothermic peak occurring at the lowest temperature within a range of from 0° C. to 100° C. and obtained at a first warming-up step of a differential scanning calorimetry measurement that uses a toner after fixation as a sample; and the toner after fixation being contained in a fixed image transferred from a transferring member and fixed on a recording medium, a maximum width of an image defect formed after conducting a folding test of the fixed image being 0.30 mm or less.Type: GrantFiled: July 7, 2008Date of Patent: November 26, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Yasuhiro Oya, Atsuhiko Eguchi
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Patent number: 8592116Abstract: A toner to develop an electrostatic charge image, a method of preparing the toner, a toner supply device employing the toner, an apparatus to form an image employing the toner, and a method of forming an image using the toner are provided. The toner includes a binder resin including a first type of binder resin having a first weight-average molecular weight and a second type of binder resin having a second weight-average molecular weight different than the first weight-average molecular weight, a colorant, and a releasing agent.Type: GrantFiled: February 17, 2012Date of Patent: November 26, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: Kyeong Pang, Tae-hoe Koo, Su-bum Park, Ju-yeon Lee, Jun-young Lee
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Patent number: 8586274Abstract: A toner for developing an electrostatic charge image, which satisfies both low temperature fixing property and blocking resistance and which is excellent in the fixed image strength and further excellent in the production stability and is capable of presenting a constant quality, and a process for its production, which toner comprises a binder resin containing a crystalline resin, and wax, and which has, in its DSC curve measured by a differential scanning calorimeter, an endothermic peak of from 0.01 to 10 mJ/mg at a temperature of at most 45° C. during its temperature rise.Type: GrantFiled: May 27, 2011Date of Patent: November 19, 2013Assignee: Mitsubishi Chemical CorporationInventors: Tetsuharu Yuge, Yuqing Xu
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Patent number: 8586276Abstract: A carrier for developing an electrostatic latent image includes carrier particles, and the carrier particles include magnetic particles and a coating layer coating the surfaces of the magnetic particles. The BET specific surface area of the magnetic particles is 0.1300 m2/g to 0.2500 m2/g, and the difference in BET specific surface areas obtained by subtracting the BET specific surface area of the magnetic particles from the BET specific surface area of the carrier particles is 0.0300 m2/g to 0.400 m2/g.Type: GrantFiled: March 27, 2008Date of Patent: November 19, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Akira Matsumoto, Taichi Yamada, Yosuke Tsurumi, Fusako Kiyono, Akihiro Iizuka, Fumiaki Mera, Hirotaka Matsuoka
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Publication number: 20130295500Abstract: A fluorescing dry toner particle comprises a polymeric binder phase comprising a non-fluorescing binder polymer and a polymeric fluorescing colorant dispersed within the non-fluorescing binder polymer. The polymeric fluorescing colorant comprises a fluorescing moiety that is covalently attached to a colorant polymer that is the same or different than the non-fluorescing binder polymer, but the polymeric fluorescing colorant is blendable with the non-fluorescing binder polymer to form a homogeneous polymeric binder matrix, and is present in an amount of at least 1 weight % and up to and including 40 weight %, based on the total fluorescing dry toner particle weight. These fluorescing dry toner particles can be used in various dry developers to provide fluorescing toner images with or without non-fluorescing color toner images.Type: ApplicationFiled: March 15, 2013Publication date: November 7, 2013Inventors: Dinesh Tyagi, Louise Granica
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Patent number: 8574805Abstract: An object of the present invention is to provide a toner in which the problems in the techniques described are solved. That is, the object is to provide a toner which has an excellent charging characteristic regardless of the environment and which achieves high image quality over a long period of time. A toner includes toner particles including at least a binder resin, a colorant, and a wax, and at least one inorganic fine powder, the toner being characterized in that, in a thermally stimulated current spectrum of the toner measured with a thermally stimulated current measurement apparatus, the thermally stimulated current spectrum of the toner has a specific shape.Type: GrantFiled: October 21, 2010Date of Patent: November 5, 2013Assignee: Canon Kabushiki KaishaInventors: Yuhei Terui, Katsuyuki Nonaka, Koji Abe, Yasuhiro Hashimoto, Naoya Isono, Akira Sugiyama
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Patent number: 8563208Abstract: A toner for developing an electrostatic charge image includes: an amorphous polyester resin; a crystalline polyester resin; and a releasing agent, an amount of the releasing agent in the toner being from 5 to 15% by weight; an amount of the releasing agent present at a surface of the toner being from 10 to 35% by weight; and the toner showing at least one endothermic peak in each of a temperature range from 45 to 60° C., a temperature range from 65 to 80° C., and a temperature range from 85 to 100° C. in a temperature-rise process of differential scanning calorimetry of the toner.Type: GrantFiled: July 2, 2012Date of Patent: October 22, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Hiroshi Nakazawa, Masanobu Ninomiya, Hirokazu Hamano
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Patent number: 8563207Abstract: Disclosed is a toner binder which has high storage stability and can achieve both of good low-temperature fixability and good hot offset resistance (a broadened fixing temperature range). Specifically disclosed is a toner binder comprising, as constituting units, a carboxylic acid component (x) and a polyol component (y), wherein the component (x) comprises two or more kinds of dicarboxylic acids (X1), selected from among aromatic dicarboxylic acids and ester-forming derivatives of the same, in a total amount of 80 mol % or more and a trivalent or higher polycarboxylic acid (x2); the component (y) comprises a polyester resin (P) which is constituted by a polyester resin (A) comprising 80 mol % or more of an aliphatic diol (y1) having 2 to 10 carbon atoms optionally together with a linear polyester resin (B); and the storage modulus at 150° C. [G?150] of resin (A) is 20000 dyn/cm2 or more and the ratio of [G?150] to the storage modulus as 180° C. [G?180] thereof, i.e., [G?150]/[G?180], is 15 of less.Type: GrantFiled: March 31, 2010Date of Patent: October 22, 2013Assignee: Sanyo Chemical Industries, Ltd.Inventors: Masashi Minaki, Shinichi Maeda, Mitsumasa Kamura, Shuichi Shinohara, Yuya Iwagoe
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Patent number: 8546054Abstract: An electrophotographic toner includes a binder resin, a colorant, and a releasing agent, wherein the electrophotographic toner has a complex viscosity (?) of 4e2 Pa·s to 8e3 Pa·s at a temperature range of 120 to 160° C. and an angular velocity range of 1.6 to 10 rad/s, a rate of change of the complex viscosity of 165 to 185 Pa·s/° C. at 1.6 rad/s, and 70 to 80 Pa·s/° C. at 10 rad/s within the temperature range, a stress relaxation of 1.0 e3 to 4.5 e4 Pa at a relaxation time of 0.05 to 0.3 seconds under a temperature range of 120 to 160° C., and a rate of change of the stress relaxation (?G/?T) of 785 to 1000 Pa/° C. at 0.05 seconds and 190 to 215 Pa/° C. at 0.3 seconds within the temperature range above.Type: GrantFiled: September 29, 2008Date of Patent: October 1, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: Jae-hyeuk Jeong, Duck-hee Lee, Deuck-woo Jang, Jung-ik Choi, Soon-cheol Jeong, Hae-ree Joo
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Patent number: 8524436Abstract: In the image forming method, a color toner image and a transparent toner image are formed using a first developing device containing a first developer including color toner and carrier, and a second developing device containing a second developer including transparent toner and carrier. At least the second developing device includes a developer bearing member bearing the second developer for developing an electrostatic image; a developer supplying passage supplying the developer to the developer bearing member while feeding the developer in a first direction; and a developer feeding passage separated from the developer supplying passage at a central portion thereof and feeding the developer used for development in a direction parallel to the first direction. The transparent toner includes a resin and a lubricant and has viscoelastic property such that loss tangent has a peak with height of not less than 3 at a temperature of from 80° C. to 160° C.Type: GrantFiled: June 24, 2011Date of Patent: September 3, 2013Assignee: Ricoh Company, Ltd.Inventors: Masashi Nagayama, Mitsuo Aoki, Hideyuki Santo, Shigenori Yaguchi
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Patent number: 8518621Abstract: A toner for electrostatic image development containing a resin binder, a negatively chargeable charge control agent, and a positively chargeable charge control agent, wherein the resin binder contains at least one polyester, wherein a carboxylic acid component of the polyester contains isophthalic acid and/or an ester thereof and fumaric acid and/or an ester thereof, provided that if two or more polyesters are used, the carboxylic acid component is taken as an overall component, and wherein the negatively chargeable charge control agent contains a metal-containing azo dye and/or a metal complex of salicylic acid, and wherein the toner has a softening point of from 90° to 120° C. The toner for electrostatic image development of the present invention can be suitably used in developing latent images formed in, for example, electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.Type: GrantFiled: January 19, 2010Date of Patent: August 27, 2013Assignee: Kao CorporationInventors: Satoshi Kunii, Masahito Yamazaki, Yoshihiro Fukushima
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Patent number: 8512929Abstract: A latent electrostatic image developing carrier including a carrier core material, and a coating layer containing a resin and provided on a surface of the carrier core material, wherein the coating layer includes a particulate material containing at least first fine conductive particles and second fine conductive particles, and wherein the first fine conductive particles and the second fine conductive particles satisfy the relationships expressed by Expressions 1 and 2, 3?D1/D2?15 . . . Expression 1, where D1 denotes a dispersed particle diameter of the first fine conductive particles and D2 denotes a dispersed particle diameter of the second fine conductive particles, and ?7E?R1×R2?8E . . . Expression 2, where R1 denotes a powder specific resistance of the first fine conductive particles and R2 denotes a powder specific resistance of the second fine conductive particles.Type: GrantFiled: September 10, 2010Date of Patent: August 20, 2013Assignee: Ricoh Company, Ltd.Inventors: Hitoshi Iwatsuki, Kimitoshi Yamaguchi, Minoru Masuda, Yutaka Takahashi, Koichi Sakata, Toyoaki Tano
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Patent number: 8501055Abstract: A toner manufacturing method, a toner manufacturing apparatus, and a toner are disclosed. The toner manufacturing apparatus includes a droplet generating unit that includes a thin film in which plural nozzles are formed, and an annular vibrating unit that is arranged at a perimeter of a deformable domain of the thin film for vibrating the thin film; a storage unit for storing a toner-containing liquid that includes at least a resin and a colorant, and for supplying the toner-containing liquid 10 to the droplet generating unit; and a granulating unit for solidifying droplets that are periodically breathed out from the nozzles of the droplet generating unit to form toner particles.Type: GrantFiled: March 5, 2008Date of Patent: August 6, 2013Assignee: Ricoh Company, Ltd.Inventors: Shinji Ohtani, Yoshihiro Norikane, Seichin Kinuta
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Patent number: 8465900Abstract: The present invention provides an electrophotographic toner comprising a polyester resin as binder resin and a colorant, said polyester resin being the condensation product of at least one polyhydric alcohol with at least one polybasic acid, wherein said at least one polyhydric alcohol comprises cyclohexanedimethanol, said toner having a loss modulus of from 2×103 Pa to 3×104 Pa at 110° C. and being irradiated with only laser light for fixing. According to toner of the invention, high quality toner images can be fixed with desired fastness and without white spots.Type: GrantFiled: October 26, 2010Date of Patent: June 18, 2013Assignee: Sharp Kabushiki KaishaInventor: Masahiko Kubo
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Patent number: 8465896Abstract: A black toner has a toner particle including at least a resin (a) having a polyester as a main component, carbon black, and a wax, and a fine inorganic particle. When the Tgs of the black toner measured by DSC at temperature rise rate of 0.5° C./min and 4.0° C./min are defined as Tg(0.5) and Tg(4.0) respectively, Tg(0.5) is 35.0 to 60.0° C. and the difference between Tg(4.0) and Tg(0.5) is 2.0 to 10.0° C. When preparing a solution of which the black toner is dissolved in ethyl acetate and defined the concentration thereof as Cb1 (mg/mL) and the light absorbance thereof at 600 nm wavelength as A600, A600/Cb1 is less than 0.15. When preparing a solution of which the black toner is dissolved in chloroform and defined the concentration thereof as Cb2 (mg/mL) and the light absorbance thereof at 600 nm wavelength as A600, A600/Cb2 is 2.00 to 6.55.Type: GrantFiled: February 19, 2010Date of Patent: June 18, 2013Assignee: Canon Kabushiki KaishaInventors: Ayako Sekikawa, Atsushi Tani, Takaaki Kaya, Shigeto Tamura, Makoto Kambayashi
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Patent number: 8455169Abstract: The toner includes a binder resin; a colorant; and a release agent. The first inter-particle force Fp(A) of the toner, which is measured under an environmental condition of 23° C. and 60% RH after the toner is pressed for 1 minute at 25° C. under a compression stress of 15 kg/cm2, is from 1.0×10?9 (N) to 1.0×10?6 (N). The difference (Fp(B)?Fp(A)) between the second inter-particle force Fp(B) of the toner, which is measured under the environmental condition of 23° C. and 60% RH after the toner is pressed for 1 minute at 50° C. under a compression stress of 15 kg/cm2, and the first inter-particle force Fp(A) is 0 (N) to 1.0×10?7 (N).Type: GrantFiled: June 23, 2010Date of Patent: June 4, 2013Assignee: Ricoh Company, LimitedInventors: Daisuke Inoue, Fumihiro Sasaki, Osamu Uchinokura, Satoshi Kojima, Hideki Sugiura, Naoko Morisawa
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Patent number: 8455168Abstract: An electrophotographic developer is provided which includes: a toner that includes toner base particles and an external additive attached to a surface of the toner base particles and has an amount of Al on the surface of the toner base particles of from about 0.002 to about 0.02 atm %; and a carrier that includes magnetic particles and a coating resin layer that coats the magnetic particles, the coating resin layer including particles with a volume-average particle diameter of from about 80 to about 800 nm, such as organic particles or inorganic particles having an organic layer on a surface of the inorganic particles, the carrier satisfying any one of the following formulas, where SP1, SP2 and SP3 represent a solubility parameter of resin of the coating resin layer, the organic particles, and the organic layer respectively: about 10>|SP1?SP2|>about 4??(1); and about 10>|SP1?SP3|>about 4??(2).Type: GrantFiled: August 24, 2010Date of Patent: June 4, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Fusako Kiyono, Sakon Takahashi, Toshiaki Hasegawa, Takeshi Shoji
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Publication number: 20130115551Abstract: The invention relates to a toner for developing a toner image, the toner comprising a binder resin, a colorant, a first wax and a compatibilizer. The wax is finely dispersed within the toner. The compatibilizer has a melting transition, wherein the lower temperature limit of the melting transition is between 110° C. and 140° C. at the time of temperature rise in the DSC curve measured using a differential scanning calorimeter. The invention further relates to a printing system for applying the toner according to the present invention on an image receiving medium. The invention further relates to a method for preparing the toner according to the present invention.Type: ApplicationFiled: October 25, 2012Publication date: May 9, 2013Applicant: OCE TECHNOLOGIES B.V.Inventor: OCE TECHNOLOGIES B.V.
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Patent number: 8435711Abstract: A toner comprising toner particles which comprise binder resin and colorant, wherein the binder resin is made from latexes which comprise a low molecular weight (LMW) latex of resin particles having a weight average molecular weight (Mw) less than 50,000 and a medium molecular weight (MMW) latex of resin particles having a Mw from 50,000 to 500,000, wherein the glass transition temperature (Tg) of the resin particles of the LMW latex is not greater than 52° C.Type: GrantFiled: October 21, 2008Date of Patent: May 7, 2013Assignee: Fujifilm Imaging Colorants LimitedInventors: Daniel Patrick Morris, John Dylan Morgan, Martin Russell Edwards