Toner Having Identified External Additive On Outside Of Toner Particle (e.g., External Fluidity Agent, External Charge Control Agent, Etc.) Patents (Class 430/123.51)
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Patent number: 7803508Abstract: A toner which combines excellent cleaning ability, image quality and durability, as well as a developer and an image forming method using the toner are provided. A toner comprising a toner base particle which comprises at least a binding resin and a colorant, and an external additive, wherein an external additive is a non-spherical amorphous silica particle and a major axis of the silica particle is 40 nm to 180 nm. An aspect wherein the non-spherical amorphous silica particle has a true specific gravity of 1.8 to 2.3 and the silica particle is hydrophobilized and a hydrophobilization degree is 40 or more, and an aspect wherein the non-spherical amorphous silica particle is produced by a dry system and a mass reduction rate is 5% by mass or less when the silica particle is heated from 30° C. up to 250° C. are preferable.Type: GrantFiled: March 16, 2007Date of Patent: September 28, 2010Assignee: Ricoh Company, Ltd.Inventors: Masayuki Ishii, Tsuneyasu Nagatomo
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Patent number: 7754405Abstract: Toners having toner matrix particles having conductive fine particles, a heat decomposable binder resin and glass frit, and heat decomposable organic resin fine particles attached on the surface of the toner matrix particles. The heat decomposition temperature of the organic resin in the heat decomposable organic resin fine particles is lower than the heat decomposition temperature of the heat decomposable binder resin.Type: GrantFiled: December 28, 2006Date of Patent: July 13, 2010Assignee: Asahi Glass Company, LimitedInventors: Satoshi Kashiwabara, Kazuo Sunahara, Naoki Okahata
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Patent number: 7745084Abstract: A toner including a binder resin and a colorant, wherein a pellet of the toner which is prepared by applying a pressure of 15 kg/cm2 to the toner has a tensile strength of from 900 Pa to 10,000 Pa, and wherein the toner has a methanol wettability of from 25 to 65% by volume, wherein the methanol wettability is measured by a method in which the toner is dispersed in a mixture solvent of water and methanol, and methanol is added to the toner dispersion while checking the transparency of the dispersion to determine a transparency fall starting point, wherein the methanol wettability is defined as {Vm/(Vm+Vw)}×100, wherein Vm represents a total volume (ml) of methanol in the dispersion at the transparency dropping point, and Vw represents the total volume of the pure water added.Type: GrantFiled: July 21, 2005Date of Patent: June 29, 2010Assignee: Ricoh Company LimitedInventors: Hideki Sugiura, Hitoshi Iwatsuki
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Patent number: 7666564Abstract: Disclosed is an image forming method employing an apparatus comprising a plurality of toner image forming units, which forms a plurality of toner images and transfer them onto an intermediate transferring member in sequence, and the transferred images is transferred onto a recording sheet. The developer is a non-magnetic single component toner and turbidity of toners of each color is less than 60; and the maximum turbidity difference among the toners is 5-45.Type: GrantFiled: October 19, 2004Date of Patent: February 23, 2010Assignee: Konica Minolta Business Technologies, Inc.Inventors: Masao Asano, Tomoe Kitani
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Publication number: 20100015543Abstract: A black toner includes: toner mother particles containing carbon black as a colorant and a binder resin, the toner mother particles being surface-modified with a polyalkyleneimine.Type: ApplicationFiled: June 30, 2009Publication date: January 21, 2010Applicant: SEIKO EPSON CORPORATIONInventors: Masahiro Oki, Yoshihiro Ueno
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Patent number: 7611815Abstract: An external additive for a toner for electrophotography which contains oxide fine particles which contain silicon, in which the oxide fine particles have a primary particle diameter of 30 nm to 300 nm in number average, a standard deviation ? of a particle size distribution of the primary particle diameter satisfies a relation of: R/4???R, in which the R expresses the primary particle diameter, the oxide fine particles are substantially spherical having a circularity SF1 defined as equation (1) of 100 to 130 and a circularity SF2 defined as equation (2) of 100 to 125; SF1=(L2/A)×(?/4)×100??equation (1) SF2=(P2/A)×(1/4?)×100??equation (2), in the equations, “L” expresses the absolute maximum length of the oxide fine particles; “A” expresses a projected area of the oxide fine particles; and “P” expresses a maximum perimeter of the oxide fine particles.Type: GrantFiled: July 15, 2003Date of Patent: November 3, 2009Assignee: Ricoh Company, Ltd.Inventors: Hideki Sugiura, Satoshi Mochizuki, Kazuhiko Umemura, Shinya Nakayama, Yasuo Asahina
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Patent number: 7596345Abstract: An image forming apparatus includes a developing apparatus for developing an electrostatic image with a developer comprising at least a toner and a first external additive, the developing apparatus including a plurality of developing devices, containing toners different in color or lightness from each other, in which at least two developing devices contain a dark color toner and a light color toner which have an identical hue and different lightnesses and the developing device containing the light color toner is subjected to a developing operation prior to another developing device; a first transfer apparatus for sequentially transferring toner images, which have been developed by the plurality of developing devices, onto an intermediary transfer member; and a second transfer apparatus for transferring the toner images from the intermediary transfer member all together onto a transfer medium The first external additive includes particles having an aspect ratio of not less than 1.0 and not more than 1.Type: GrantFiled: August 23, 2006Date of Patent: September 29, 2009Assignee: Canon Kabushiki KaishaInventors: Fumitake Hirobe, Yuichiro Toyohara, Tatsuomi Murayama, Akihiro Noguchi
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Patent number: 7588875Abstract: A toner having at least one binder, at least one colorant and external additives. The external additives include at least one fluoropolymer. An electrophotographic image forming machine and method includes the toner with at least one fluoropolymer.Type: GrantFiled: September 2, 2008Date of Patent: September 15, 2009Assignee: Xerox CorporationInventors: Nan-Xing Hu, Cuong Vong, John F. Graham, Richard P. N. Veregin
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Publication number: 20090208862Abstract: Provided is a method for forming an image containing the steps of: (a) forming an electrostatic latent image on an electrostatic latent image carrier; and (b) developing the electrostatic latent image by a two component developer comprising a toner and a carrier, wherein the two component developer is continually replenished in the developing step. (b); and the toner includes: colored particles.; and external additive particles comprising a complex oxide incorporating silicon atoms and at least one of titanium atoms and aluminum atoms, and a surface existing ratio of the silicon atoms (R2) in a surface of the external additive particles being larger than an average existing ratio of the silicon atoms (R1) in an entirety of the external additive particles.Type: ApplicationFiled: February 17, 2009Publication date: August 20, 2009Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Masahiro ANNO, Masahiko NAKAMURA, Tsuyoshi UCHIDA, Kenichi ONAKA, Junya ONISHI, Naoya TONEGAWA
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Patent number: 7553595Abstract: A toner composition includes toner particles including a polymeric resin, a colorant, a wax, and an optional coagulant, and a coagulant applied as a surface additive to a surface of the toner particles to alter a triboelectric charge of the toner particles.Type: GrantFiled: April 26, 2006Date of Patent: June 30, 2009Assignee: Xerox CorporationInventors: Valerie M. Farrugia, Raj D. Patel, Michael S. Hawkins
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Patent number: 7541128Abstract: A toner composition including toner particles including a binder resin including a modified polyester resin, and a second resin having a weight average molecular weight of from 2,000 to 10,000; a colorant; a release agent; and a particulate material which is present at least a surface portion of the toner particles while embedded into the surface portion, wherein the binder resin has a glass transition temperature not lower than 35° C. and lower than 55° C., and wherein the particulate material has an average particle diameter of from 0.002 to 0.2 times that of the toner particles. A developer including the toner composition and a carrier having a layer thereon which includes at least an acrylic resin and a silicone resin, and a method for fixing an image of the toner composition are also provided.Type: GrantFiled: September 26, 2003Date of Patent: June 2, 2009Assignee: Ricoh Company LimitedInventors: Yohichiroh Watanabe, Masanori Suzuki, Tsunemi Sugiyama, Hiroshi Yamashita, Takuya Saito, Naohiro Watanabe, Masami Tomita, Shigeru Emoto, Shinichiro Yagi, Hiroshi Yamada, Toshiki Nanya, Tadao Takigawa
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Patent number: 7488563Abstract: The present invention is a method of forming a toner image on a receiving sheet. The method includes forming an electrostatic image on a primary image member and toning the image with a dry toner to form a toner image. The toner includes toner particles having a diameter of between 4 and 10 microns and transfer assisting particles appended to the toner particles surface. The transfer assisting particles have a diameter of between 20 and 100 nm. The toner image is transferred from the primary image member to an intermediate image member having an overcoat layer, the overcoat layer having a Young's modulus of from 250 to 500 MPa. The toner image is transferred from the intermediate image member to a receiving sheet wherein the intermediate image member drives the primary image member or the receiving sheet.Type: GrantFiled: October 14, 2005Date of Patent: February 10, 2009Assignee: Eastman Kodak CompanyInventors: Donald S. Rimai, Biao Tan, Craig M. Cody, Rodney R. Bucks, Charles E. Hewitt, M. Cristina B. Dejesus, Paul L. Nielsen, Diane M. Herrick
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Patent number: 7435521Abstract: A toner for developing an electrostatic image which has a small particle size essential for attaining a high-quality image, and can output a high-quality image excellent in frictional charging property and free from scumming. The toner for developing an electrostatic image has the volume average particle diameter of 2.0 ?m to 7.1 ?m and the surface condition of the toner is in scab form.Type: GrantFiled: December 28, 2004Date of Patent: October 14, 2008Assignee: Ricoh Company, Ltd.Inventors: Shinichiro Yagi, Hiroshi Yamada, Hiroshi Yamashita, Naohiro Watanabe, Tsunemi Sugiyama, Shigeru Emoto, Masami Tomita, Toshiki Nanya, Tadao Takikawa
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Publication number: 20080247783Abstract: In an image forming apparatus containing a developing device containing a toner housed therein and feeding the toner onto a photoreceptor to form a toner image, and a cleaning blade removing the toner remaining on the photoreceptor after transferring the toner image formed on the photoreceptor to a transfer medium, a toner having a particle diameter of from 5 to 8 ?m and a degree of circularity of from 0.925 to 0.965 and having a lubricant added to a surface thereof in an amount of from 0.01 to 0.125 wt % is used, and the cleaning blade has a hardness of from 60 to 80, a 300% modulus of from 100 to 420 kg/cm2, a tear strength of from 35 to 120 kg/cm, a repulsive elasticity at 10° C. of from 10 to 50%, and a repulsive elasticity at 40° C. of from 40 to 80%.Type: ApplicationFiled: April 4, 2007Publication date: October 9, 2008Applicants: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHAInventors: Yousuke Imamura, Hiroshi Kawaguchi
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Patent number: 7396630Abstract: A toner composition including toner particles including a binder resin including a modified polyester resin, and a second resin having a weight average molecular weight of from 2,000 to 10,000; a colorant; a release agent; and a particulate material which is present at least a surface portion of the toner particles while embedded into the surface portion, wherein the binder resin has a glass transition temperature not lower than 35° C. and lower than 55° C., and wherein the particulate material has an average particle diameter of from 0.002 to 0.2 times that of the toner particles. A developer including the toner composition and a carrier having a layer thereon which includes at least an acrylic resin and a silicone resin, and a method for fixing an image of the toner composition are also provided.Type: GrantFiled: October 11, 2006Date of Patent: July 8, 2008Assignee: Ricoh Company LimitedInventors: Yohichiroh Watanabe, Masanori Suzuki, Tsunemi Sugiyama, Hiroshi Yamashita, Takuya Saito, Naohiro Watanabe, Masami Tomita, Shigeru Emoto, Shinichiro Yagi, Hiroshi Yamada, Toshiki Nanya, Tadao Takigawa
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Patent number: 7312010Abstract: A toner having at least one binder, at least one colorant and external additives. The external additives include at least one of silica and titania, and at least two metal stearates. A developer may be produced including the toner having at least two metal stearates and a carrier. An electrophotographic machine includes the toner with two metal stearates.Type: GrantFiled: March 31, 2005Date of Patent: December 25, 2007Assignee: Xerox CorporationInventors: Richard P. Veregin, Maria N. McDougall, Eric Strohm, Dwight J. Tshudy, Thomas R. Pickering
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Publication number: 20070238041Abstract: A method to form an image using a trickle developing system, wherein (a) the toner comprises colorant particles with a volume median diameter of 3 to 8 ?m having first inorganic particles on surfaces of the colorant particles to form toner particles; (b) the carrier comprises magnetic particles with a weight average particle diameter (D4) of 20 to 40 ?m having second inorganic particles on surfaces of the magnetic particles to form carrier particles; and (c) an area ratio of element (A) based on a total area of surfaces of the carrier particles is 0.5 to 3.0 area % determined by using an X-ray analysis, provided that element (A) represents one or more elements commonly contained in the first inorganic particles and in the second inorganic particles.Type: ApplicationFiled: April 3, 2007Publication date: October 11, 2007Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Makoto KOBAYASHI, Yoshiyasu MATSUMOTO
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Publication number: 20070238042Abstract: An oilless-fixing toner is provided for use in a vertical image developer including a toner feeder feeding the oilless-fixing toner vertically below; a developing roller located vertically below the toner feeder; and a screw blade agitating the oilless-fixing toner, wherein the oilless-fixing toner contains: a resin including a wax; a colorant; and an external additive, wherein a total energy determined from a torque and a load of the screw blade is from 450 to 530 mJ when rotating in the oilless-fixing toner at 100 mm/s, and a ratio of total energy at 10 mm/s to total energy at 100 mm/s is from 2.0 to 3.0.Type: ApplicationFiled: April 5, 2007Publication date: October 11, 2007Inventors: Hideaki Yasunaga, Hiroaki Katoh, Masayuki Hagi, Takuya Kadota, Yoshimichi Ishikawa, Hiroyuki Murakami, Katsunori Kurose, Yoshihiro Mikuriya
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Publication number: 20070212122Abstract: The purpose is to be provide, in a development apparatus using a two-component developer, a compact development apparatus, image forming apparatus and development method that prevents carrier deterioration and that can carry out good image formation over a long time period. In a development apparatus using a developer in which are mixed a toner, a carrier, and opposite polarity particles that are charged to a polarity opposite to the charging polarity of the toner, the surface charge density of the opposite polarity particles should be in the range of 0.5 to 3.0 times the surface charge density of the carrier.Type: ApplicationFiled: February 28, 2007Publication date: September 13, 2007Inventors: Takeshi Maeyama, Toshiya Natsuhara, Junya Hirayama, Masahiko Matsuura, Shigeo Uetake
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Publication number: 20070190443Abstract: A toner including toner particles including a binder resin, a colorant and a release agent, and an external additive including a first particulate inorganic material having a formula of MgxSiyOx+2y where each of x and y is an integer, and a number average secondary particle diameter of from 0.02 ?m to 2 ?m, wherein the first atomic ratio (Mg/Si) s in a surface portion of the first particulate inorganic material is not greater than (preferably less than) the second atomic ratio (Mg/Si)e in the entire first particulate inorganic material. Alternatively, a toner including toner particles including a binder resin and a colorant, and an external additive which includes a particulate inorganic material having a formula of MgxSiyOx+2y where each of x and y is an integer and which has a surface treated with a fatty acid.Type: ApplicationFiled: February 1, 2007Publication date: August 16, 2007Inventors: Masayuki Hagi, Takuya Kadota, Hiroaki Katoh, Atsushi Yamamoto, Katsunori Kurose, Yoshihiro Mikuriya, Masahide Inoue, Hideaki Yasunaga, Minoru Nakamura, Yoshimichi Ishikawa, Hiroyuki Murakami