By Coalescing Or Aggregating Patents (Class 430/137.14)
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Publication number: 20140370430Abstract: A toner particle includes a core containing a styrene-based resin; a low melting point wax; optionally an additive package; and optionally a colorant, wherein the low melting point wax has a melting point of less than about 80° C. A method of making a toner particle includes forming a slimy by mixing together an emulsion containing a resin, a low melting point wax, optionally a colorant, optionally a surfactant, optionally a coagulant, and one or more additional optional additives; and heating the slurry to form aggregated particles in the slurry, wherein the aggregated particles form a core of the toner particles; and the low melting point wax has a melting point of less than about 80° C.Type: ApplicationFiled: June 13, 2013Publication date: December 18, 2014Inventors: Grazyna E. KMIECIK-LAWRYNOWICZ, Samir KUMAR, Robert D. BAYLEY, Maura A. SWEENEY
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Publication number: 20140370428Abstract: Incorporation of organic amines as neutralization agents in based phase inversion emulsification (PIE) processes to provide emulsification of high molecular amorphous and high molecular branch amorphous polyester resins, which are traditionally difficult to emulsify. The organic amines facilitate emulsification of these resins to achieve desired particle size with a narrow size distribution.Type: ApplicationFiled: June 13, 2013Publication date: December 18, 2014Inventors: Yulin Wang, Shigang Steven Qiu, Ke Zhou, Karen Moffat, Edward G. Zwartz, Michael Hawkins, Paul Gerroir
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Patent number: 8911924Abstract: A toner including base particles each containing a crystalline polyester and a non-crystalline polyester, wherein the toner has a glass transition temperature of 45° C. or higher where the glass transition temperature is determined from a DSC curve of the toner obtained in the first elevation of temperature thereof, and wherein the toner has a temperature width of 8° C. or lower where the temperature width is a temperature width at ? the height of an endothermic peak attributed to the crystalline polyester in the DSC curve.Type: GrantFiled: October 13, 2011Date of Patent: December 16, 2014Assignee: Ricoh Company, Ltd.Inventors: Tomoyuki Sato, Naohiro Watanabe, Tsuyoshi Sugimoto, Shinya Hanatani, Mamoru Hozumi
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Publication number: 20140356780Abstract: Provided is a toner for electrostatic image development that has low-temperature fixability and long-term stable electrification performance, also has heat-resistant storage stability, and can suppress the occurrence of unevenness in gloss. Also provided is a production process of the toner. The toner for electrostatic image development includes toner particles having a domain-matrix structure. In the toner particles, a crystalline polyester resin and an amorphous resin including an amorphous polyester segment and a polymerized vinyl segment that are chemically bonded are dispersed as domain phases in a matrix phase formed of a vinyl resin.Type: ApplicationFiled: May 28, 2014Publication date: December 4, 2014Applicant: Konica Minolta, Inc.Inventors: Takaki Kawamura, Kaori Matsushima, Aya Shirai, Taiki Amemiya
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Publication number: 20140356778Abstract: A toner including a resin; an optional wax; and a colorant; wherein the colorant has disposed thereon a reactive component having at least one cross-linkable carbon-carbon double bond and wherein the tribo electric charge of the toner is adjusted through surface treatment of the colorant with the reactive component. Also a colorant having disposed thereon a reactive component having at least one cross-linkable carbon-carbon double bond, wherein the reactive component disposed on the colorant is selected from the group consisting of methyl acrylate, ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, methyl methacrylate, ethyl methacrylate, butyl methacrylate, cyclohexyl methacrylate, stearyl methacrylate, acrylic acid, methacrylic acid, maleic acid, hydroxyethyl methacrylate, hydroxypropyl acrylate, glycidyl acrylate, alkoxymethylol acrylamide, styrene, vinyl toluene, methylstyrene, acrylonitrile, methacrylonitrile, bisphenol A glycerolate diacrylate, and mixtures and combinations thereof.Type: ApplicationFiled: May 29, 2013Publication date: December 4, 2014Applicant: Xerox CorporationInventors: Christopher Wolfe, Jay L. Schneider, Randy Pheav Tin, Chieh-Min Cheng
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Publication number: 20140349232Abstract: A method for producing a toner that comprises toner particles, each of which comprises a binder resin, which comprises a resin (A) capable of forming a crystalline structure, and a colorant, the method including: a pressure holding step of, after preparing toner particles, holding the toner particles for 5 minutes or more at a pressure of 2.0 MPa or more under conditions of a temperature T1 (° C.) represented by formula (1): 20?T1?Tp2??(1) (wherein, Tp2 represents the onset temperature of the maximum endothermic peak derived from the resin (A)), wherein a peak temperature Tp1 of the maximum endothermic peak derived from the resin (A) during the first temperature rise of the toner particles as determined by differential scanning calorimetric measurement is 50° C. to 90° C.Type: ApplicationFiled: May 21, 2014Publication date: November 27, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Tetsuya Kinumatsu, Shuntaro Watanabe, Kenji Aoki, Atsushi Tani, Yoshihiro Nakagawa, Takaaki Kaya, Toshifumi Mori, Yusuke Kosaki, Takashige Kasuya
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Patent number: 8895220Abstract: An emulsion aggregation toner formulation for electrophotography and a method for preparation thereof. The emulsion aggregation toner formulation includes a polyester resin emulsion formed using an extruded polyester binder resin having a broad molecular weight distribution. The extruded polyester binder resin is formed using a plurality of polyester binder resins. Further, the emulsion aggregation toner formulation comprises at least one colorant dispersion and a wax dispersion.Type: GrantFiled: August 29, 2013Date of Patent: November 25, 2014Assignee: Lexmark International, Inc.Inventors: Michael James Bensing, Craig Michael Bartelsen, John Joseph Kraseski, Bryan Patrick Livengood, Jing X. Sun, Vincent Wen-Hwa Ting
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Patent number: 8889331Abstract: The disclosure relates to a process for making a latex emulsion suitable for use in a toner comprising at least one amorphous polyester resin and a solvent to form a resin mixture, including that the process is carried out at room temperature using acoustic mixing.Type: GrantFiled: March 1, 2013Date of Patent: November 18, 2014Assignee: Xerox CorporationInventors: Shigang Qiu, Santiago Faucher
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Patent number: 8883387Abstract: An electrostatic image developing toner of the exemplary embodiment of the invention contains an amorphous first polyester resin of a polycondenzation product of at least a carboxylic acid component and an alcohol component containing rosin, and a second polyester resin having the difference (absolute value) in parameter of solubility relative to the first polyester resin of from about 0.3 (cal/cm3)1/2 to about 3 (cal/cm3)1/2.Type: GrantFiled: September 25, 2012Date of Patent: November 11, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Emi Miyata, Sumiaki Yamasaki, Satoshi Hiraoka, Yuki Sasaki, Susumu Yoshino, Hirotaka Matsuoka
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Patent number: 8877414Abstract: An electrostatic image developing toner including: a toner matrix particle having an adhering particle adhered onto the surface of a central particle, wherein a volume average value of a ratio X of a peripheral length PM to a circle-corresponding diameter D is from 3.6 to 5.0.Type: GrantFiled: February 22, 2011Date of Patent: November 4, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Atsushi Sugawara, Shinpei Takagi, Atsushi Sugitate, Daisuke Noguchi
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Patent number: 8871419Abstract: The toner for electrostatic image development has excellent charge properties, by which excellent toner particle size-controlling ability is achieved, and moreover the sharpening of a particle size distribution is achieved. The toner is composed of toner particles containing a binder resin. The process has an aggregating step of adding an aggregating agent containing a transition element into an aqueous medium of dispersed fine binder resin particles to aggregate the fine binder resin particles, and an aggregation-stopping step of adding an aggregation stopper composed on a sulfur atom-containing compound exhibiting a reducing action on the aggregating agent. The aggregating agent is a salt of a bivalent or higher metal selected from Sr, Ti, V, Cr, Mn, Fe, Co, Ni and Cu.Type: GrantFiled: June 18, 2012Date of Patent: October 28, 2014Assignee: Konica Minolta Business Technologies, Inc.Inventors: Saburou Hiraoka, Tomomi Oshiba, Mikihiko Sukeno, Tomoko Mine, Hitomi Motani, Tatsuya Nagase, Ken Ohmura
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Patent number: 8865387Abstract: The present invention relates to, in the toner including toner particles having a biding agent resin, colorings and a release agent, an electrostatic image developing toner, its composition, and a preparation method thereof. The electrostatic image developing toner is prepared by the method comprising: (1) preparing an inorganic dispersion medium; (2) dispersing/dissolving a polymerizable monomer mixture; (3) micronizing the liquid obtained in step (2) in the liquid obtained in step (1) with high shear force in order to create droplets; (4) performing radical polymerization of the micronized droplets obtained in step (3); (5) aggregating particles obtained in step (4); (6) fusing the aggregate obtained in step (5); (7) cleaning and drying the toner obtained by step (6); and (8) adding additives to impart electrification and fluidity to a toner obtained by step (7).Type: GrantFiled: March 12, 2009Date of Patent: October 21, 2014Assignee: Park & OPC Co., LtdInventors: Jae-Goang Yu, Ho-Geun Jo
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Publication number: 20140308612Abstract: A method and system for magnetic actuated mixing which use magnetic particles and magnetic field to facilitate the mixing for preparing latex emulsion. In embodiments, a suitable process includes dissolving a resin in an organic solvent, optionally adding a surfactant, adding a neutralization agent and water, adding magnetic particles, and subjecting the mixture to a magnetic actuated mixing to form a latex emulsion. In embodiments, the latex emulsion thus produced may be utilized to form a toner.Type: ApplicationFiled: April 10, 2013Publication date: October 16, 2014Applicant: XEROX CORPORATIONInventors: Yu Liu, Ke Zhou, Yulin Wang, Frank Ping-Hay Lee
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Publication number: 20140302432Abstract: Processes for continuously coalescing particles from an aggregated particle slurry are disclosed. The aggregated particle slurry is heated, then coalesced by raising the pH. The coalesced particles are homogenized and exit as a coalesced particle slurry. A multi-screw extruder is used for the coalescing. These processes are useful for providing coalesced particles such as toner compositions.Type: ApplicationFiled: April 4, 2013Publication date: October 9, 2014Applicant: XEROX CORPORATIONInventors: Joo T. Chung, Chieh-Min Cheng, Steven M. Malachowski, Eric Joseph Young, Eric David Godshall, Brian Joseph Marion
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Publication number: 20140302436Abstract: Processes for continuously producing a wax dispersion are disclosed. A multi-screw extruder is used for the processes. A wax and a surfactant are fed into the extruder and melted together. Water is then added to form a dispersion. The wax particles are homogenized and exit the extruder to be passed through a quenching unit. The wax dispersion can be used to make toner compositions.Type: ApplicationFiled: April 4, 2013Publication date: October 9, 2014Applicant: Xerox CorporationInventors: Joo T. Chung, Chieh-Min Cheng, Steven M. Malachowski, Eric David Godshall, Ronald Dean Werner
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Patent number: 8852842Abstract: A production process of a toner, wherein wet colored resin particles are poured into a rotary vane type agitating device having a structure that an agitating vane fixed to a rotating drive shaft extending through a bottom wall of an agitation vessel is arranged at a bottom of the agitation vessel, and at least one gas inlet port and at least one gas outlet port are arranged at a lower portion of the agitation vessel and an upper portion of the agitation vessel, respectively, the wet colored resin particles are dried by a method, in which the wet colored resin particles are agitated by the rotary vane within the agitation vessel while supplying a heated gas, thereby forming a fluidized bed, and a mixed gas containing water is discharged from the gas outlet port to the outside, and at that time, drying conditions are controlled in such a manner that the temperature of the gas discharged falls within a range from 20 to 60° C.Type: GrantFiled: February 18, 2009Date of Patent: October 7, 2014Assignee: Zeon CorporationInventors: Takashi Iga, Hisashi Kurokawa
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Publication number: 20140295346Abstract: The method of manufacturing toners disclosed herein includes a continuous temperature ramp and coalescence process that involves continuously passing toner slurry, such as an aggregated toner slurry, through at least one heat exchanger before being subjected to a cooling step. The heat exchanger is pressurized, so the temperature of the slurry may be increased above the atmospheric boiling point of water without boiling the water component of the slurry. Because of these higher temperatures, the coalescence step can be completed more quickly than in conventional batch processes. More than two heat exchangers may be connected in the coalescence step, yielding multiple ramping/cooling temperature steps, ability to inject components, or recycling heat from the process to reduce energy consumption.Type: ApplicationFiled: March 26, 2013Publication date: October 2, 2014Applicant: XEROX CORPORATIONInventors: David John William LAWTON, David R. KURCEBA, Frank Ping-Hay LEE, Daniel McDougall MCNEIL, Santiago FAUCHER
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Patent number: 8846289Abstract: A method of manufacturing toner including melting, mixing, and kneading a releasing agent and a coloring agent with at least part of a polyester binder resin, and suspending and granulating an oil phase comprising the binder resin, the coloring agent, and the releasing agent in an aqueous medium.Type: GrantFiled: September 24, 2010Date of Patent: September 30, 2014Assignee: Ricoh Company, Ltd.Inventors: Satoshi Ogawa, Tsuyoshi Sugimoto, Naohito Shimota, Hiroshi Yamashita, Masana Shiba, Junichi Awamura
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Publication number: 20140287358Abstract: In producing an electrostatic latent image developing toner, fine particle aggregates are formed by aggregating fine particles containing a binder resin and fine particles containing a release agent in an aqueous medium in the presence of an aggregating agent containing an alkali metal sulfate, and toner particles are formed by coalescing components contained in the fine particle aggregates in an aqueous medium in the presence of hydroxypropyl methyl cellulose.Type: ApplicationFiled: March 19, 2014Publication date: September 25, 2014Applicant: KYOCERA DOCUMENT SOLUTIONS INC.Inventor: Hidetoshi MIYAMOTO
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Publication number: 20140272702Abstract: A method of making toner particles that includes forming a pre-shell aggregate mixture by adding to a reactor pre-shell aggregate ingredients, the includes a latex resin, the reactor having a mixing impeller and a heating jacket; performing pre-shell aggregation while homogenizing the pre-shell aggregate mixture with the impeller at an initial tip speed to form pre-shell aggregates; decreasing the tip speed to a second tip speed when the pre-shell aggregates reach a target intermediate average particle diameter; and then decreasing the tip speed at one or more intervals between when the pre-shell aggregates reach the target intermediate average particle diameter and when the pre-shell aggregates reach a target final average particle diameter so that the tip speed meets the following formula: tip speed=1644ft/min?204.9(ft/(min*?m))*average particle diameter(?m).Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: XEROX CORPORATIONInventors: Juan A. MORALES-TIRADO, Mark A. JACKSON
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Publication number: 20140255842Abstract: A method for preparing a latex or dispersion, the method comprising contacting at least one resin with an organic solvent to form a resin mixture; neutralizing the resin mixture with a neutralizing agent; and subjecting the resin mixture flow to steam flow in a continuous manner to form a dispersion. A method for forming toner, the method comprising: contacting a resin to an organic solvent and a neutralizing agent to form a resin mixture; subjecting the resin mixture flow to a steam flow in a continuous manner to form a dispersion; aggregating particles from a pre-toner mixture, the pre-toner mixture comprising the dispersion, an optional colorant, and an optional wax; and coalescing the aggregated particles to form toner particles. An apparatus that can perform the methods.Type: ApplicationFiled: March 8, 2013Publication date: September 11, 2014Applicant: XEROX CORPORATIONInventors: Yu LIU, Yulin WANG, Frank Ping-Hay LEE, Ke ZHOU
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Patent number: 8829149Abstract: Processes for preparing polyester resins as toner production components. The processes include reacting an organic diol and a cyclic alkylene carbonate to produce carbon dioxide (CO2) and a polyalkoxy diol. The carbon dioxide is reacted with an alkylene glycol or alkylene oxide to produce additional cyclic alkylene carbonate having the same chemical structure as the cyclic alkylene carbonate used to produce the polyalkoxy diol. The additional cyclic alkylene carbonate is added with the cyclic alkylene carbonate used to produce the polyalkoxy diol. The polyalkoxy diol can be reacted with an organic diacid or diester in preparing a polyester resin. To prepare a toner, the polyester resin can be contacted with at least one toner production component.Type: GrantFiled: September 12, 2012Date of Patent: September 9, 2014Assignee: Xerox CorporationInventor: Guerino G. Sacripante
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Publication number: 20140248560Abstract: A process for preparing a particulate solid is described, which comprises the steps of a) aggregating a dispersion comprising the particles i) and ii) and a liquid medium, wherein i) is 25 to 50 parts by weight of non-polymeric particles having an average particle size of from 1 to 10 microns and having a density of no more than 4 g/cm3; and ii) is 50 to 75 parts by weight of polymer particles having an average particle size of from 50 to 150 nm; b) optionally stabilising the aggregated particles; and c) heating the aggregated particles so as to cause particle coalescence.Type: ApplicationFiled: September 25, 2012Publication date: September 4, 2014Applicant: FUJIFILM IMAGING COLORANTS LIMITEDInventors: Martin Edwards, Daniel Morris, Miguel Rodriguez-Vazquez
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Patent number: 8815487Abstract: A process for forming toner using an emulsion/aggregation scheme wherein particle aggregation occurs in a batch reactor and coalescence occurs in a continuous reactor, with a space time yield of at least 200 g/L/hr.Type: GrantFiled: December 17, 2012Date of Patent: August 26, 2014Assignee: Xerox CorporationInventors: Santiago Faucher, Kimberly D Nosella, Matthew A Woods
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Publication number: 20140234768Abstract: Provided is a method for producing a toner including: aggregating colorant particles and release agent particles, thereby forming aggregates containing the colorant particles and the release agent particles; aggregating binder resin particles and the obtained aggregates containing the colorant particles and the release agent particles, thereby forming toner particle precursors; and aggregating and fusing the obtained toner particle precursors, thereby forming toner particles, wherein when the average circularity of the toner particles is represented by Rt, Rt satisfies the following formula (1): 0.85?Rt?0.92 (1).Type: ApplicationFiled: March 13, 2014Publication date: August 21, 2014Applicant: TOSHIBA TEC KABUSHIKI KAISHAInventors: Takafumi Hara, Masahiro Ikuta, Tsuyoshi Itou, Motonari Udo, Kazuhisa Takeda
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Patent number: 8802344Abstract: A process for making toner particles is provided. In embodiments, a suitable process includes adding a washing aid agent to toner particles at the time of washing the toner particles prior to their drying and recover. The washing aid agent assist in the removal of ionic species, including surfactants and ions that are part of the emulsion aggregation process, from the resulting toner particles. Utilization of the washing aid agent produces toner particles having improved charging characteristics.Type: GrantFiled: December 13, 2010Date of Patent: August 12, 2014Assignee: Xerox CorporationInventors: Zhen Lai, Chieh-Min Cheng, Zhaoyang Ou, Christopher D. Blair
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Patent number: 8785098Abstract: The invention provides a transparent toner for electrostatic latent image development, containing a polyester resin and a release agent, the difference between an endothermic peak Tm of the release agent in a temperature increasing process and an exothermic peak Tc of the release agent in a temperature decreasing process when measured by an ASTM method with a differential scanning calorimeter (DSC) is from about 40° C. to about 50° C., and the degree of exposure of the release agent at the surface of the toner as determined quantitatively by X-ray photoelectron spectroscopy (XPS) is about 10% or less.Type: GrantFiled: October 20, 2009Date of Patent: July 22, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Masaru Takahashi, Atsushi Sugawara, Yasuo Kadokura, Masanobu Ninomiya
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Patent number: 8785102Abstract: A toner having charge control agents which impart excellent triboelectric charging characteristics. In embodiments, the toner particles are made by a process in which charge control agent is added and adhered to the particle surface through washing steps and is maintained through the drying steps. The process of the present embodiments impart desirable charging characteristics to the toner particles.Type: GrantFiled: April 23, 2012Date of Patent: July 22, 2014Assignee: Xerox CorporationInventors: Robert D. Bayley, Maura A. Sweeney, Grazyna E. Kmiecik-Lawrynowicz, Daniel W. Asarese
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Publication number: 20140199625Abstract: A process for making a latex emulsion including contacting at least one amorphous polyester resin with at least two organic solvents to form a resin mixture, adding a neutralizing agent, and deionized water to the resin mixture, removing the solvent from the formed latex, and separating the solvent from water. Further, the process is carried out above the resin Tg for making the latex, which drives the latex particle size under 100 nm, where toners made from the latex show improved charging performance.Type: ApplicationFiled: January 15, 2013Publication date: July 17, 2014Applicant: XEROX CORPORATIONInventors: Shigang Qiu, Richard PN Veregin, Kimberly D. Nosella, Santiago Faucher, Cuong Vong, Enno E. Agur
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Publication number: 20140199623Abstract: The disclosure describes a process to produce toner with tunable gloss levels comprising a stabilizer to freeze particle growth following aggregation, where the stabilizer does not chelate metal ions.Type: ApplicationFiled: January 15, 2013Publication date: July 17, 2014Applicant: XEROX CORPORATIONInventors: Yulin Wang, Ke Zhou, Tie Hwee Ng, Edward Graham Zwartz, Cuong Vong, Shigang Qiu
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Publication number: 20140199624Abstract: A method of preparing a toner. A toner having a low residual VOC content, a narrow particle size distribution, excellent fixing properties at low temperature, and high image quality may be prepared using the method by which a polyester resin dispersion is prepared by adding ingredients to a single reactor in a predetermined order.Type: ApplicationFiled: April 1, 2011Publication date: July 17, 2014Inventors: Eui Hyun Ryu, Il Sun Hwang, Il Hyuk Kim, Sung Yul Kim
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Patent number: 8778584Abstract: The present disclosure provides toners and methods for their production. In embodiments, the amount of coagulant utilized in producing those toners may be less than amounts currently in use, which may have a beneficial effect by reducing the time for coalescence. Modified waxes may also be utilized which provide excellent gloss and charging characteristics.Type: GrantFiled: October 15, 2009Date of Patent: July 15, 2014Assignee: Xerox CorporationInventors: Mark E. Mang, Grazyna Kmiecik-Lawrynowicz, Maura A. Sweeney, Timothy L. Lincoln
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Patent number: 8778582Abstract: A toner having charge control agents which impart excellent triboelectric charging characteristics. In embodiments, the toner particles are made by a process in which the toner particles are made without a shell which provides homogenous distribution of the charge control agents, providing a toner with higher charge and better environmental stability.Type: GrantFiled: November 1, 2012Date of Patent: July 15, 2014Assignee: Xerox CorporationInventors: Maura A. Sweeney, Robert D. Bayley, Grazyna E. Kmiecik-Lawrynowicz, Brian S. Wang
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Publication number: 20140170558Abstract: A process for forming toner using an emulsion/aggregation scheme wherein particle aggregation occurs in a batch reactor and coalescence occurs in a continuous reactor. In embodiments, a continuous reactor comprises four sections joined in series.Type: ApplicationFiled: December 17, 2012Publication date: June 19, 2014Applicant: XEROX CORPORATIONInventors: Kimberly D. Nosella, Santiago Faucher
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Publication number: 20140170559Abstract: Regarding a method for manufacturing an electrostatic latent image developing toner, which includes a process for aggregating particulates of components such as a binder resin, a colorant, and a releasing agent, a dispersion solution of binder resin particulates obtained by a specific method is used. The dispersion solution of the binder resin particulates are prepared as an oil-in-water emulsion containing particulates including the binder resin by mixing the binder resin, which is polyester resin, in a molten state with an organic base in a liquid state so as to neutralize the binder resin and subsequently mixing a resin molten solution with water. The amount of use of the organic base is 6 parts by mass or more with respect to 100 parts by mass of the binder resin. The degree of neutralization of the binder resin neutralized by the organic base is 100% or more.Type: ApplicationFiled: December 10, 2013Publication date: June 19, 2014Applicant: KYOCERA DOCUMENT SOLUTIONS INC.Inventor: Ryotaro KOMADA
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Publication number: 20140170557Abstract: A process for forming toner using an emulsion/aggregation scheme wherein particle aggregation occurs in a batch reactor and coalescence occurs in a continuous reactor, with a space time yield of at least 200 g/L/hr.Type: ApplicationFiled: December 17, 2012Publication date: June 19, 2014Applicant: XEROX CORPORATIONInventors: Santiago Faucher, Kimberly D. Nosella, Matthew A. Woods
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Publication number: 20140170547Abstract: The present disclosure provides a bio-based polyester resin comprising a polyacidic furan, including the manufacture of such polyester resin, which resin may be used in manufacturing toner for imaging devices.Type: ApplicationFiled: December 18, 2012Publication date: June 19, 2014Applicant: Xerox CorporationInventors: Valerie M. Farrugia, Guerino G. Sacripante, Ke Zhou, Sonja Hadzidedic
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Publication number: 20140170548Abstract: Continuous and semi-continuous emulsion aggregation processes for the production of toner particles are presented.Type: ApplicationFiled: December 17, 2012Publication date: June 19, 2014Applicant: Xerox CorporationInventors: Santiago Faucher, Kimberly D. Nosella, Melanie Davis, Edward Graham Zwartz
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Publication number: 20140162186Abstract: A method of manufacturing a liquid electrophotographic ink includes: mixing a pigment with a resin powder; and microfluidizing the mixture together with a carrier fluid in a microfluidizer in a number of passes to form a concentrated ink containing composite particles.Type: ApplicationFiled: February 11, 2014Publication date: June 12, 2014Applicant: HEWLETT-PACKARD DEVELOPMENT COMPANY, L.P.Inventors: Sivapackia GANAPATHIAPPAN, Hou T. Ng, Albert Teishev
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Patent number: 8748073Abstract: A toner comprising a modified polyester resin containing a structure represented by Formula (1a) or (1b), wherein, in Formula (1a) and (1b), R1 represents a hydrogen atom, a methyl group, or an ethyl group, R2 represents an aliphatic hydrocarbon which may be branched, or an aromatic hydrocarbon, and R3 represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or a phenyl group.Type: GrantFiled: August 9, 2013Date of Patent: June 10, 2014Assignee: Konica Minolta Business Technologies, Inc.Inventors: Hiroshi Nagasawa, Ken Ohmura
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Patent number: 8741533Abstract: A method of manufacturing toner is provided. The method includes preparing a first liquid by dissolving or dispersing toner components in an organic solvent, preparing a second liquid by emulsifying the first liquid in an aqueous medium, and evaporating the organic solvent from the second liquid. The toner components include a colorant, a release agent, and one or both of a binder resin and a precursor thereof. The evaporating includes flowing down the second liquid as a liquid film in substantially a vertical direction along an inner wall surface of a pipe that is depressurized, heating the liquid film at a temperature not higher than a glass transition temperature of the binder resin, and supplying the pipe with a depressurized water vapor from a supply opening disposed on an upper part of the pipe.Type: GrantFiled: November 6, 2012Date of Patent: June 3, 2014Assignee: Ricoh Company, Ltd.Inventor: Hiroshi Yamada
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Patent number: 8741532Abstract: The disclosure describes a toner process in which portion-wise addition of colorant(s) during particle formation is used to control the distribution of colorant within the toner particle, thereby enhancing A zone charge.Type: GrantFiled: September 30, 2011Date of Patent: June 3, 2014Assignee: Xerox CorporationInventors: Ke Zhou, Shigang Qiu, Kimberly Nosella, Cuong Vong
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Publication number: 20140147780Abstract: A toner is prepared by wet granulation methods, including a monoester wax having carbon atoms of from 36 to 46 on average as a release agent. The toner has a DSC endothermic energy amount (?H1) originating from the wax of from 10 to 12 mJ/mg and a DSC endothermic energy amount (?H2) originating from the wax of from 0.6 to 0.9 times as much as ?H1 after a part of the wax is separated by hexane extraction from the toner. The hexane extraction includes mixing 1 g of the toner in 7 ml of n-hexane to prepare a mixture; stirring the mixture at 120 rpm for 1 min by a pot mill to prepare a dispersion; and subjecting the dispersion to suction filtration.Type: ApplicationFiled: October 23, 2013Publication date: May 29, 2014Inventors: Tsuyoshi NOZAKI, Takuya Kadota, Yoshihiro Mikuriya, Yoshimichi Ishikawa, Kazuoki Fuwa, Tomohiro Fukao, Tomoharu Miki
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Publication number: 20140147786Abstract: A method for preparing latex emulsion compositions uses a steam-driven emulsification process, and a method for preparing a toner using the latex emulsion compositions. The method includes contacting a resin with an organic solvent and optionally a neutralization agent; and applying steam or heated water vapor to contact the resin to prepare a latex emulsion. An apparatus can perform the method.Type: ApplicationFiled: November 27, 2012Publication date: May 29, 2014Applicant: XEROX CORPORATIONInventors: Yu LIU, Yulin WANG, Ke ZHOU, Frank Ping-Hay LEE, Yiliang WU, Shigang S. QIU
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Patent number: 8735037Abstract: A toner obtained by a method for producing a toner, which includes dissolving or dispersing in an organic solvent a toner material containing at least a binder resin, and a dispersion liquid of a crystalline polyester resin, so as to prepare a solution or dispersion liquid of the toner material, emulsifying or dispersing the solution or dispersion liquid of the toner material in an aqueous medium, so as to prepare an emulsion or dispersion liquid, and removing the organic solvent from the emulsion or dispersion liquid, wherein the crystalline polyester resin is localized near a surface of the toner.Type: GrantFiled: March 16, 2011Date of Patent: May 27, 2014Assignee: Ricoh Company, Ltd.Inventors: Hiroshi Yamashita, Masaki Watanabe, Tomoki Murayama
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Patent number: 8728703Abstract: An electrophotographic toner obtained from a dispersion or emulsion liquid of an oil phase containing a toner material in an aqueous medium, the toner including: a binder resin, wherein the toner material includes: (A) an epoxy resin prepolymer; (B) an adduct of a dihydric phenol with a polyalkylene oxide; (C) a phenolic compound, or an alcohol compound, or both thereof; and (D) a carboxylic acid compound, and wherein the binder resin includes a resin obtained by allowing the (A), the (B), the (C) and the (D) to react with each other.Type: GrantFiled: July 2, 2012Date of Patent: May 20, 2014Assignee: Ricoh Company, Ltd.Inventors: Hiroshi Yamashita, Satoyuki Sekiguchi, Daisuke Asahina, Tsuyoshi Sugimoto, Masaki Watanabe, Rintaro Takahashi
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Patent number: 8728701Abstract: The production process is a production process of a toner for electrostatic image development, which is composed of toner particles containing at least a binder resin. The process has an aggregating and fusion-bonding step of adding a aggregating agent containing polysilicato-iron into an aqueous medium in which fine binder resin particles formed of the binder resin have been dispersed, thereby aggregating the fine binder resin particles, and an aggregation stopper-adding step of adding an aggregation stopper composed of a polyvalent organic acid or a salt thereof. In the production process of the toner for electrostatic image development, the polyvalent organic acid or the salt thereof is preferably an amino acid or a salt thereof.Type: GrantFiled: April 18, 2012Date of Patent: May 20, 2014Assignee: Konica Minolta Business Technologies, Inc.Inventors: Tomoko Mine, Saburou Hiraoka, Tomomi Oshiba, Tatsuya Nagase
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Publication number: 20140134531Abstract: A yellow toner is provided which is much more improved in color development and chroma, and much more improved in light resistance. The yellow toner contains, at least, a binder resin, a wax, and a coloring agent. The coloring agent is a compound represented by the following general formula (1).Type: ApplicationFiled: January 23, 2014Publication date: May 15, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Shosei Mori, Takeshi Sekiguchi, Taichi Shintou, Takeshi Miyazaki
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Patent number: 8722297Abstract: The present invention relates to a resin binder for toners which contains a crystalline polyester which is produced by polycondensing at least an alcohol component containing an aliphatic diol having 2 to 12 carbon atoms and a carboxylic acid component containing an aliphatic dicarboxylic acid compound having 8 to 12 carbon atoms in an amount of from 70 to 100 mol %, wherein a content of a methyl ethyl ketone soluble component (at 20° C.) in the crystalline polyester is from 0.5 to 7% by weight on the basis of a weight of the crystalline polyester, and a difference between a melting point of the crystalline polyester and a peak top temperature observed in DSC measurement of the methyl ethyl ketone soluble component (“melting point of the crystalline polyester”?“peak top temperature observed in DSC measurement of the methyl ethyl ketone soluble component”) is within the range of from 1 to 15° C.Type: GrantFiled: March 8, 2011Date of Patent: May 13, 2014Assignee: Kao CorporationInventors: Eiji Shirai, Hiroki Kakiuchi
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Patent number: 8722300Abstract: Disclosed are an electrophotographic toner and a method of preparing the same. The electrophotographic toner includes latex; a colorant; and a releasing agent. The absolute value of a differential value of complex viscosity with respect to temperature, ( ? ? ? ? T ? ) ? ? ? ( log 10 ? ? ) / ? T ? of the electrophotographic toner in a temperature range of 100° C.-160° C. is in a range of about 0.03 to about 0.06, and complex viscosity (?) of the electrophotographic toner at 140° C. is in a range of about 1.0×102 Pa·s to about 6.0×102 Pa·s.Type: GrantFiled: June 22, 2009Date of Patent: May 13, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Hae-Ree Joo, Jae-Hyeuk Jeong, Kyeong Pang