From Ethylenically Unsaturated Monomer Patents (Class 430/263)
  • Patent number: 5609985
    Abstract: Disclosed are a color image-formable material which comprises a support, a cushion layer provided on the support and a color light-sensitive layer containing a light-sensitive composition and a coloring agent provided on the cushion layer and gives a transferred image by forming a color image portion by imagewise exposure and developing treatment and then transferring the color image portion alone to an image-receiving material,wherein the surface at a color light-sensitive layer side of the cushion layer has an average gloss (GS (60.degree. )) of 30 or more and the color light-sensitive layer is provided on the cushion layer, a process for preparing the same.
    Type: Grant
    Filed: September 20, 1994
    Date of Patent: March 11, 1997
    Assignees: Konica Corporation, Mitsubishi Chemical Corporation
    Inventors: Tetsuya Taniguchi, Kiyoshi Goto, Takeo Akiyama, Miyuki Hosoi, Tetsuya Masuda, Hideaki Mochizuku
  • Patent number: 5609984
    Abstract: An element comprising, in order: (a) a removable substrate; (b) a transparent, nonphotosensitive, polymeric layer having a thickness of less than about 0.002 cm and a gloss of 45-70; said polymeric layer consisting essentially of at least one thermoplastic polymer having an elongation at break of greater than 30%, a glass transition temperature of 35.degree.-70.degree. C.; and (c) an elastomeric layer and optionally an additional, different removable substrate (d) adjacent to the elastomeric layer, wherein the polymeric layer exhibits improved adhesion to the removable substrate (a) when removable substrate (d) is removed is described.
    Type: Grant
    Filed: May 4, 1995
    Date of Patent: March 11, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Anchi Hou
  • Patent number: 5599648
    Abstract: Surface reforming of a polymeric article containing a polymerizable compound is effectively performed by polymerizing the polymeric article in contact with a surface reforming medium because the transfer of the material constituting the surface reforming medium to the polymeric article is enhanced by the polymerization. The surface reforming can be performed locally selectively, i.e., imagewise. The remaining un-polymerized part may be subjected to further surface reforming, e.g., by using another type of surface reforming medium or attachment of powder, to provide an enhanced contrast of surface property. Such an enhanced contrast of surface property can be effectively used, e.g., for production of a printing plate.
    Type: Grant
    Filed: November 26, 1993
    Date of Patent: February 4, 1997
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yuji Kondo, Masato Katayama, Akihiro Mouri
  • Patent number: 5597676
    Abstract: The present invention provides a method for obtaining an imaging element suitable for use in a silver salt diffusion transfer process by the steps of:preparing an image receiving element by coating the anodized surface of an aluminum foil with an image-receiving layer comprising physical development nuclei,preparing a photosensitive layer packet by coating a temporary base with at least one photosensitive silver halide emulsion layer,pressing the thus formed photosensitive layer packet with its photosensitive silver halide emulsion coated side against said image receiving layer, which has been wet with an aqueous moistening liquid, andoptionally removing said temporary base, characterized in that between said temporary base and said at least one photosensitive silver halide emulsion layer a barrier layer is present which is substantially free of developing agents, is substantially unhardened, comprises one or more hydrophilic binders in an amount of at least 0.25 g/m.sup.
    Type: Grant
    Filed: August 17, 1995
    Date of Patent: January 28, 1997
    Assignee: AGFA-Gevaert. N.V.
    Inventors: Ludo Van Rompuy, Paul Coppens
  • Patent number: 5593811
    Abstract: (A) being a photosensitive relief-forming layer in which imagewise exposure to actinic light results in different solubilities of the exposed and unexposed parts, and this layer consists of a mixture of:(a1)one or more polymeric binders,(a2)one or more photopolymerization initiators,(a3)one or more organic compounds which are compatible with the binder (a1) and contain photopolymerizable olefinically unsaturated groups and, if required,(a4)one or more assistants,(B) being a smooth or dull, nontacky release layer (B) which is transparent to light, soluble or swellable in the relevant liquid media and formed by a polymer forming strong films and additives contained therein, and(C) being a cover sheet which can be detached from the release layer (B), the release layer (B) containing a metal salt as an additive,is suitable for the production of printing plates.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: January 14, 1997
    Assignee: BASF Lacke+Farben Aktiengesellschaft
    Inventors: Thomas Loerzer, Stefan Wegener, Friedrich Goffing
  • Patent number: 5593809
    Abstract: There are described a diffusion transfer photographic film unit of the type wherein an image-receiving element is designed to be separated from a photosensitive element after photoexposure and processing and a photographic process which utilizes the film unit. The photographic film unit comprises a photosensitive element including a support carrying at least one silver halide emulsion, an image-receiving element comprising a support, an image-receiving layer and, optionally, an overcoat layer and/or a strip-coat layer. At least one of the image-receiving layer, overcoat layer or strip-coat layer includes a "crosslinkable material" which is crosslinked during processing. The film unit further includes means for providing an aqueous alkaline processing composition to the photosensitive element and the image-receiving element for developing an image. The aqueous alkaline processing composition includes a borate compound for crosslinking the crosslinkable material of the image-receiving element during processing.
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: January 14, 1997
    Assignee: Polaroid Corporation
    Inventors: Gia Y. Kim, Lloyd D. Taylor, Kenneth C. Waterman
  • Patent number: 5591560
    Abstract: An image-receiving element for use in photographic and photothermographic diffusion transfer film units of the type wherein the image-receiving element is designed to be removed or "peeled-apart" from a photosensitive element following exposure and processing. The present image-receiving element comprises in sequence, a support, an image-receiving layer, and a strip-coat layer. The strip-coat layer serves to facilitate separation of the image-receiving layer from a photosensitive element after processing. The strip-coat layer comprises a copolymer including: 1) at least about 50% by weight of monomer units, the same or different, derived from an ethylenically unsaturated carboxylic acid or salt thereof, 2) at least about 15% by weight of monomer units of vinyl pyrrolidone, and 3) at least about 5% by weight of monomer units, the same or different, represented by the formula: ##STR1## wherein R.sub.
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: January 7, 1997
    Inventors: Agota F. Fehervari, James A. Foley, Gia Y. Kim, Diana R. Koretsky, Lloyd D. Taylor, Kenneth C. Waterman
  • Patent number: 5587272
    Abstract: This invention makes available processes for preparing images, especially color proofs. A layer with imagewise tacky and nontacky areas is toned. Toner adhering to the tacky areas is transferred first onto a temporary support and from there onto an image receptor.
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: December 24, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Mario Grossa, Udo D. Bode, Manfred Sondergeld, Karl-Heinz Wiedenmann, Ronald J. Convers, Steven M. Kalo, Ashok K. Kudva
  • Patent number: 5578413
    Abstract: A photosensitive transfer material is disclosed including a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the transfer material having an interlaminar adhesion which is lowest between the thermoplastic resin layer and the temporary substrate, wherein the alkali-soluble thermoplastic resin layer contains (A) an alkali-soluble thermoplastic resin having a weight average molecular weight of from 50,000 to 500,000 and a glass transition temperature of from 0.degree. to 140.degree. C. and (B) an alkali-soluble thermoplastic resin layer having a weight average molecular weight of from 3,000 to 30,000 and a glass transition temperature of from 30.degree. to 170.degree. C. at an (A)/(B) weight ratio of from 5/95 to 95/5. The transfer material can be transferred to a permanent substrate at a high speed without entrapping air bubbles due to unevenness on the permanent substrate.
    Type: Grant
    Filed: March 15, 1996
    Date of Patent: November 26, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadao Fujikura, Minoru Wada
  • Patent number: 5576140
    Abstract: An image-receiving sheet material for forming a transfer image by heat-transferring an ink layer from a transfer material having a heat-transferable ink layer onto an image-receiving sheet material, and re-transferring the ink layer onto a permanent support. The image-receiving sheet material comprises a support having thereon at least two image-receiving layers, at least one of the image-receiving layers is transferred onto the permanent support, and at least the image-receiving layer onto which the ink layer is transferred contains a modified resin prepared from a polyvinyl acetal resin containing hydroxyl groups in which from 0.1 to 1 equivalent of the hydroxyl groups of the polyvinyl acetal resin have been converted to a group represented by formula (I). In a preferred embodiment, the image-receiving layer onto which the ink layer is transferred further contains a high molecular weight compound having at least a repeating unit represented by formula (II) and/or formula (III).
    Type: Grant
    Filed: March 7, 1996
    Date of Patent: November 19, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yuichi Wakata, Hideyuki Nakamura
  • Patent number: 5534384
    Abstract: A photosensitive material for the production of color proofing films for multicolor printing, having(A) a transparent, flexible film support of plastic,(B) a photopolymerizable layer which contains(B1) a polymeric binder,(B2) a free-radically polymerizable compound,(B3) a compound which is capable of initiating the polymerization of (B2) on exposure to actinic light, and(B4) a dye or a colored pigment in a primary color of multicolor printing, and(C) a thermoplastic adhesive layer having a layer weight of from about 2 to about 30 g/m.sup.2 on the photo-sensitive layer, wherein the thermoplastic adhesive layer contains from about 0.01 to about 0.5% by weight of a colorless pigment having a mean particle size which corresponds to from 1 to 100% of the layer thickness.
    Type: Grant
    Filed: February 19, 1993
    Date of Patent: July 9, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Stephan J. W. Platzer, Siegfried Nuernberger, Karin Maerz
  • Patent number: 5529879
    Abstract: This invention relates to a photosensitive sheet having on a substrate one or more resin layers that are peelable from the substrate and heat-fusible, and a colored photosensitive layer in this order, said substrate comprising a biaxially stretched plastic film and having a molecular orientation ratio in the range of from 1.0 to 1.4.The object of this invention is to solve the problem of misregister without decreasing productivity during the formation of plastic film (substrate) or during the production of a photosensitive sheet in a method in which said photosensitive sheet having an image formed thereon and an image receiving sheet for receiving the image are superimposed on each other, and pressed and heated for image transfer.
    Type: Grant
    Filed: March 31, 1993
    Date of Patent: June 25, 1996
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Mitsuhide Hoshino, Fukuo Murata, Norio Yabe, Masahide Takano
  • Patent number: 5525454
    Abstract: A photosensitive transfer material is disclosed including a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the transfer material having an interlaminar adhesion which is lowest between the thermoplastic resin layer and the temporary substrate, wherein the alkali-soluble thermoplastic resin layer contains (A) an alkali-soluble thermoplastic resin having a weight average molecular weight of from 50,000 to 500,000 and a glass transition temperature of from 0.degree. to 140.degree. C. and (B) an alkali-soluble thermoplastic resin layer having a weight average molecular weight of from 3,000 to 30,000 and a glass transition temperature of from 30.degree. to 170.degree. C. at an (A)/(B) weight ratio of from 5/95 to 95/5. The transfer material can be transferred to a permanent substrate at a high speed without entrapping air bubbles due to unevenness on the permanent substrate.
    Type: Grant
    Filed: July 8, 1994
    Date of Patent: June 11, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadao Fujikura, Minoru Wada
  • Patent number: 5518857
    Abstract: A method for engraving and/or etching comprising the steps of: (a) a process for exposing, to light, a layer of a water-soluble resin composition of a laminated photo-sensitive film which comprises a supporting sheet, a image mask-protection layer peelablly adhered to the supporting sheet and a layer of a water-soluble resin composition having photocrosslinkability to thus cause crosslinking of the exposed area of the resin layer to thereby form a predetermined pattern on the resin layer; (b) a process for dissolving out the non-crosslinked portion of the layer of the water-soluble photo-sensitive resin composition by developing the layer with water to thus from an image-carrying mask which is constituted from the crosslinked area of the photo-sensitive resin composition remaining on the image mask-protection layer; (c) a process for adhering the photo-sensitive laminate film on which the images are formed to the surface of a material to be processed; (d) a process for peeling off the supporting sheet from th
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: May 21, 1996
    Assignee: Aicello Chemical Co., Ltd.
    Inventors: Tsutomu Suzuki, Ikuo Suzuki
  • Patent number: 5478694
    Abstract: The invention relates to a photosensitive material for the production of color proofing films for multicolor printing comprising:A) a transparent, flexible film support,B) a photopolymerizable layer containing:B1) a polymeric binder,B2) a free radical-polymerizable compound,B3) a compound which is capable of initiating the polymerization of (B2) on exposure to actinic light, andB4) a dye or colored pigment in a primary color of multicolor printing, andC) a thermoplastic adhesive layer on the photosensitive layer,which contains at least about 1.5% by weight of a water-soluble, colorless, low-molecular-weight salt whose aqueous solution is not highly acidic.The material is processed by lamination onto an image-receiving material, exposure and peeling apart of the film support and the image-receiving material, the unexposed areas of the layer and the adhesive layer remaining on the image-receiving material.
    Type: Grant
    Filed: May 17, 1993
    Date of Patent: December 26, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karin Maerz, Ine Gramm, Manfred Hilger, Dieter Mohr, Stephan J. W. Platzer
  • Patent number: 5468596
    Abstract: A photosensitive recording element comprises(A) a dimensionally stable substrate,(B) a photopolymerizable relief-forming recording layer and, if required, an adhesion-promoting layer arranged between (A) and (B), a release layer (C) applied to that side of the recording layer (B) which faces away from the substrate (A), and, if required, a cover sheet (D) applied thereon, the photopolymerizable relief-forming recording layer (B) containingb.sub.1) at least one polymeric binder,b.sub.2) at least one photopolymerizable olefinically unsaturated monomer which is compatible with b.sub.1),b.sub.3) at least one photopolymerization initiator andb.sub.4) at least one aryl alkyl ketone,and is suitable for the production of relief printing plates.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: November 21, 1995
    Assignee: BASF Lacke + Farben AG
    Inventors: Thomas Loerzer, Thomas Telser, Thomas Zwez, Bernhard Albert
  • Patent number: 5443939
    Abstract: A light-sensitive material for producing color-test films for multi-color printing is disclosed. The material has (A) a transparent flexible base film of a plastic, (B) a photopolymerizable layer containing (B1) a polymeric binder, (B2) a compound polymerizable by a free-radical mechanism, (B3) a compound capable of initiating the polymerization of (B2) under the action of actinic light, and (B4) a dye or a colored pigment in one of the basic colors of multi-color printing, and (C) a thermoplastic adhesion layer on the light-sensitive layer is described. A polymer of a vinyl alkyl ether is present in at least one of the layers (B) and (C). The material is processed by lamination to an image-receiving material, with subsequent exposure and peeling-apart of base film and image-receiving material. The unexposed layer areas remain together with the adhesion layer on the image-receiving material. These steps are repeated with at least one further part-color image.
    Type: Grant
    Filed: March 14, 1994
    Date of Patent: August 22, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karin Maerz, Stephan J. W. Platzer
  • Patent number: 5437959
    Abstract: An element comprising, in order: (a) a removable substrate; (b) a transparent, nonphotosensitive, polymeric layer having a thickness of less than about 0.002 cm and a gloss of 45-70; said polymeric layer consisting essentially of at least one thermoplastic polymer having an elongation at break of greater than 30%, a glass transition temperature of 35.degree.-70.degree. C.; and (c) an elastomeric layer and optionally an additional, different removable substrate (d) adjacent to the elastomeric layer, wherein the polymeric layer exhibits improved adhesion to the removable substrate (a) when removable substrate (d) is removed is described.
    Type: Grant
    Filed: January 25, 1994
    Date of Patent: August 1, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Anchi Hou
  • Patent number: 5437960
    Abstract: A process for laminating a photosensitive-layer which includes providing (A) a base having a laminating region and a non-laminating region, and (B) a support having thereon, in order, a photosensitive layer and a protective film, where part of the protective film corresponds to the laminating region and part of the protective film corresponds to the non-laminating region, removing the part of the protective film which corresponds to the laminating region from the photosensitive layer such that the photosensitive layer can be laminated to the base in the laminating region, feeding the base and the support having thereon the photosensitive layer from which protective film has been removed to a nip between a pair of heated pressure rollers, passing the base and photosensitive-layer-covered support forward through the rollers while the base and photosensitive-layer-covered support are being nipped and hot-pressed by the rollers, with the photosensitive layer being in contact with the laminating region of the base
    Type: Grant
    Filed: August 5, 1994
    Date of Patent: August 1, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Nagate, Hiroya Endo, Ken-ichi Miyata
  • Patent number: 5427890
    Abstract: A method for engraving and/or etching comprising the steps of: (a) a process for exposing, to light, a layer of a water-soluble resin composition of a laminated photosensitive film which comprises a supporting sheet, a image mask-protection layer peelablly adhered to the supporting sheet and a layer of a water-soluble resin composition having photocrosslinkability to thus cause crosslinking of the exposed area of the resin layer to thereby form a predetermined pattern on the resin layer; (b) a process for dissolving out the non-crosslinked portion of the layer of the water-soluble photo-sensitive resin composition by developing the layer with water to thus from an image-carrying mask which is constituted from the crosslinked area of the photo-sensitive resin composition remaining on the image mask-protection layer; (c) a process for adhering the photo-sensitive laminate film on which the images are formed to the surface of a material to be processed; (d) a process for peeling off the supporting sheet from the
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: June 27, 1995
    Assignee: Aicello Chemical Co., Ltd.
    Inventors: Tsutomu Suzuki, Ikuo Suzuki
  • Patent number: 5415969
    Abstract: An image-receiving element for use in photographic diffusion transfer film units of the type Wherein the image-receiving element, which includes an image-receiving layer, is designed to be removed, or "peeled-apart", from a photosensitive element after exposure and development have been carried out. The image-receiving element includes an overcoat layer which overlies the image-receiving layer for reducing the time period for which the image-receiving element remains tacky after the element has been separated from the photosensitive element and for improving the handling and/or storage of the resulting photograph under high humidity conditions. The overcoat layer comprises colloidal silica particles and binder material.
    Type: Grant
    Filed: October 6, 1993
    Date of Patent: May 16, 1995
    Assignee: Polaroid Corporation
    Inventor: Kenneth C. Waterman
  • Patent number: 5409800
    Abstract: A photosensitive transfer material comprises a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the interlaminar adhesion in the transfer material being the smallest at the interface between the thermoplastic resin layer and the temporary substrate. The photosensitive resin layer can be transferred to a permanent substrate without involving failure due to fine dust, air bubbles or unevenness of the permanent substrate. An image can be formed with the transfer material by adhering the transfer material to a permanent substrate at least under heat and, after stripping the temporary substrate, imagewise exposing the photosensitive resin layer to light, and processing the transferred layers to develop the photosensitive resin layer.
    Type: Grant
    Filed: March 25, 1994
    Date of Patent: April 25, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morimasa Sato, Masayuki Iwasaki, Fumiaki Shinozaki, Koji Inoue
  • Patent number: 5405731
    Abstract: The use of a two layer photoimageable, aqueous processable, resist with a hydrophic binder in the outermost layer provides a permanent coating highly resistant to printed circuit processing chemicals. This resistance results in levels of adsorbed or absorbed ionic contamination less than 14 micrograms per square inch.
    Type: Grant
    Filed: December 22, 1992
    Date of Patent: April 11, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Karuppiah Chandrasekaran, Mark R. McKeever, James W. O'Neil
  • Patent number: 5391458
    Abstract: A method is provided for forming a high-resolution photoresist layer on a substrate, such as a metal-clad circuit board blank. A dry film is used which comprises a support sheet, a negative-acting, alkaline aqueous developable photoresist layer in direct contact with the support sheet, and a protective sheet. The protective sheet is removed and the photoresist layer is cut sheet laminated to the substrate. Then the support sheet is removed. The photoresist layer is baked until its exposed surface is non-tacky. Artwork is laid directly in contact with the non-tacky exposed surface, and the photoresist layer is exposed to actinic radiation through the art work. The photoresist layer is then developed in alkaline aqueous solution. The photoresist layer is highly resolved. Subsequent processing steps, such as plating or etching and stripping yield a printed circuit board having highly resolved lines and spaces.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: February 21, 1995
    Assignee: Morton International, Inc.
    Inventor: Charles T. Conrad
  • Patent number: 5374184
    Abstract: A photopolymerizable material having(A) a flexible, transparent film support;(B) a colored, polymerizable layer containing an organic binder, a free-radical-polymerizable compound, containing at least one terminal ethylenically unsaturated group, and a dye or colored pigment;(C) an adhesion layer containing a thermoplastic polymer and having a T.sub.g of from 25.degree. to 100.degree. C.; and(D) an uncolored photopolymerizable layer which contains a polymeric organic binder, a free-radical-polymerizable compound containing at least one terminal ethylenically unsaturated group and a photopolymerization initiator between the film support (A) and the colored polymerizable layer (B),where the cohesion of layers (B), (C) and (D) and the adhesion of these layers to one another and to the film support (A) provides the relationship wherein the adhesion (a.sub.2) of the photopolymerizable layer (D) to the colored layer (B) in the unexposed state is lower than: (i) the adhesion (a.sub.
    Type: Grant
    Filed: April 4, 1994
    Date of Patent: December 20, 1994
    Assignee: Hoeschst Aktiengesellschaft
    Inventors: Stephan J. W. Platzer, Gerhard Buhr, Manfred Michel, Andrea Buchmann
  • Patent number: 5366844
    Abstract: The present invention provides a heat mode recording material comprising on the same side of a non-conductive support a conductive recording layer and an elastomeric image forming layer being non-conductive characterised in that a peelable polymeric film is provided as an outermost layer on the side of said support containing said elastomeric image forming layer.
    Type: Grant
    Filed: September 29, 1993
    Date of Patent: November 22, 1994
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Yves Verburgh, Luc Leenders
  • Patent number: 5346800
    Abstract: An image-receiving element for use in photographic diffusion transfer film units of the type wherein the image-receiving element, which includes an image-receiving layer, is designed to be removed, or "peeled-apart", from a photosensitive element after exposure and development have been carried out. The image-receiving element includes a strip-coat layer comprising a hydrophilic colloid, such as gum arabic, and an aluminum salt which overlies the image-receiving layer and significantly reduces striations and/or haze and facilitates the separation of the image-receiving element from the remainder of the film unit subsequent to diffusion transfer photography.
    Type: Grant
    Filed: October 6, 1993
    Date of Patent: September 13, 1994
    Assignee: Polaroid Corporation
    Inventors: James A. Foley, Nicholas S. Hadzekyriakides, James J. Reardon
  • Patent number: 5342745
    Abstract: Disclosed is a silver halide photographic light-sensitive material comprising a base paper support coated with a hydrophilic polymer as a peeling agent, and having thereon, a polyolefin resin layer, and at least one silver halide emulsion layer, wherein the hydrophilic polymer is coated on the side on which the silver halide emulsion layer is provided, and a peel strength between the base paper support and the polyolefin resin layer is within the range of 30 to 160 g in weight per inch, and a maximum color transmission density is not less than 2.0 when the silver halide light-sensitive material is subjected to a color developing.
    Type: Grant
    Filed: October 13, 1993
    Date of Patent: August 30, 1994
    Assignee: Konica Corporation
    Inventors: Akiyoshi Tai, Shun Takada
  • Patent number: 5340693
    Abstract: The present invention provides a heat recording material comprising on a support in the order given a porous layer of an image forming substance, a substance capable of converting radiation into heat, a thermoplastic layer containing a photocurable composition and a stripping layer. The present invention further provides a method for obtaining an image with such an heat recording material. Images of high quality and good wear and scratch resistance are obtained.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: August 23, 1994
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Herman Uytterhoeven, Luc Bastiaens, Rudolf Van den Bergh, Luc Leenders
  • Patent number: 5300395
    Abstract: A white, partially translucent, metallized film article which having a flexible, heat resistant, polymeric film material with opposite sides. The film material has deposited on a first side a metal coating which is spectrally reflective and partially light transmissive in the visible region of the spectrum, is capable of transmitting from about 1% to about 70% of incident visible light cast thereon; the second side having a white outermost surface, and has a visible light opacity of from about 0.5 to about 0.98.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: April 5, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: Robert J. von Trebra, Gerald A. Smith, Roy E. Hensel, Oliver A. Barton, deceased
  • Patent number: 5292613
    Abstract: A photosensitive transfer material is described, comprising a temporary support having formed thereon in sequence a thermoplastic resin layer, a separating layer having only slight permeability to oxygen, and a photosensitive resin layer, wherein the adhesion between the thermoplastic resin layer and the separating layer is weakest. The photosensitive transfer material is useful, for example, for an image-forming process.
    Type: Grant
    Filed: January 29, 1992
    Date of Patent: March 8, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morimasa Sato, Masayuki Iwasaki, Fumiaki Shinozaki
  • Patent number: 5278024
    Abstract: A photothermographic composite structure for use in a solvent-free dye thermal positive imaging diffusion-transfer process comprising:(a) an image-receiving element comprising a polymeric dyeable image-receiving layer having a glass transition temperature in the range of 20.degree. to 200.degree. C., and(b) strippably adhered to said image-receiving element, an imageable photothermographic element comprising in at least one layer thereof a binder, a silver source material, photosensitive silver halide in catalytic proximity to said silver source material, and a formazan dye.
    Type: Grant
    Filed: December 30, 1992
    Date of Patent: January 11, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Richard C. Cotner, David C. Weigel, Kumars Sakizadeh
  • Patent number: 5273858
    Abstract: Method for making lithographic aluminum offset printing plates according to the DTR-process by photo-exposing a photosensitive monosheet layer assemblage comprising a hydrophilic aluminum foil, an intermediate layer comprising hydrophobic polymer beads prepared by polymerization of ethylenically unsaturated monomer(s) and having an average diameter not lower than 0.2 .mu.m, and a silver halide emulsion layer, applying an aqueous alkaline solution to the photo-exposed silver halide emulsion layer in the presence of a developing agent and a silver halide solvent to form a silver image and to allow unreduced silver halide or complexes formed thereof to diffuse imagewise from the developed silver halide emulsion layer to said aluminum foil to produce thereon a silver image, and separating said emulsion layer and said intermediate layer from the imaged aluminum foil. The invention also relates to the photosensitive monosheet layer assemblage used for making such printing plates.
    Type: Grant
    Filed: October 28, 1991
    Date of Patent: December 28, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Paul J. Coppens, Joan T. Vermeersch, Luc H. Leenders, Ludovicus H. Vervloet, Eric M. Hoes, Eddie R. Daems
  • Patent number: 5273855
    Abstract: (Objective) In a color-proof material performed by forming multi-color image on an arbitrary material (ultimate image-receiving material) such as paper using a photosensitive transfer sheet and an intermediate image-receiving sheet, the objective is to bring the quality close to the printed quality formed with inks alone.(Constitution) For the photosensitive sheet, the colored photosensitive layer is formed with a material comprising a synthetic resin emulsion with Tg=-20.degree. to 40.degree. C. such as acrylic ester or ethylene-vinyl acetate copolymer so that the image layer itself has heat-adhesivity. Moreover, the image-receiving layer of the intermediate image-receiving sheet is formed with a material containing a resin cross-linked copolymer of olefin and .alpha., .beta.-unsaturated carboxylic acid with metallic ions and a resin comprising a copolymer of ethylene and vinyl acetate in a proportion by weight of 100/0 to 10/90.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: December 28, 1993
    Assignee: Sanyo-Kokusaku Pulp Co., Ltd.
    Inventors: Hisahiro Omote, Masahiro Yoshikawa, Masahide Takano
  • Patent number: 5270147
    Abstract: A stripping film material comprises a polyethylene terephthalate film base serving as temporary support being coated with a subbing layer essentially consisting of either:(1) hydroxypropylcellulose wherein the molar degree of substitution (DS) with hydroxypropyl groups is in the range of 3 to 1, or:(2) a copoly(vinyl acetate/crotonic acid) having a weight ratio of vinyl acetate to crotonic acid in the range of 85/15 to 99/1, wherein said subbing layer is coated with at least one hydrophilic colloid layer which is adapted to be stripped off after being moistened with an aqueous liquid, e.g. by contact with a wet surface of a permanent support.
    Type: Grant
    Filed: June 23, 1992
    Date of Patent: December 14, 1993
    Assignee: Agfa-Gevaert N.V.
    Inventors: Etienne A. Van Thillo, Eddie R. Daems, Luc H. Leenders, Guido J. Smits
  • Patent number: 5254447
    Abstract: Photographic glass plates are advantageously prepared by a process in which the functional layers are applied to the glass plate support by lamination. In a first form of this process, a multilayer-composite comprising antihalation, silver halide emulsion and protective overcoat layers is transferred from a flexible polymeric film support to the glass support. In carrying out this first form of the process, a release layer, protective overcoat layer, silver halide emulsion layer and antihalation layer are coated, in order, on a flexible polymeric film and laminated via an adhesive layer to a glass plate having suitable thickness and flatness for use as a photographic support. The release layer is designed to have greater adhesion to the flexible polymeric film than to the protective overcoat layer, whereby the film and release layer can be stripped off prior to the plate being put into use.
    Type: Grant
    Filed: April 20, 1992
    Date of Patent: October 19, 1993
    Assignee: Eastman Kodak Company
    Inventors: Arlene L. Meyer, Thomas M. Smith, Richard O. Smith
  • Patent number: 5254435
    Abstract: A CAD driven photoplotter selectively exposes a photographic imaging layer without affecting the underlying UV sensitive resist on a substrate to make a printed wiring board, for example. The image layer is developed on the board and used as an in situ mask for the underlying UV resist during exposure to UV. After UV exposure, the image layer is peeled off to allow conventional processing of the resist. The in situ mask is preferably applied in the form of a baseless, high contrast, high gamma emulsion layer bonded to the protective cover sheet over the uncured resist. To facilitate application, the emulsion layer is carried by a release paper which is removed before photoplotting. After UV exposure, the cover sheet and emulsion layer are integrally peeled from the resist.
    Type: Grant
    Filed: September 16, 1992
    Date of Patent: October 19, 1993
    Assignee: The Foxboro Company
    Inventors: Paul E. Grandmont, Harold Lake
  • Patent number: 5248583
    Abstract: A photosensitive color proofing article comprising in the following order:a) a carrier layer,b) a release layer which acts as an oxygen barrier layer,c) a photopolymerizable layer comprising a multifunctional acrylate oligomer and a colorant,d) a photopolymerizable barrier layer, ande) a thermal adhesive layer.
    Type: Grant
    Filed: August 30, 1991
    Date of Patent: September 28, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Wallace R. Lundquist, Thomas P. Klun, Michael B. Heller, Leonard W. Sachi
  • Patent number: 5246812
    Abstract: A white, partially translucent, metallized film article which having a flexible, heat resistant, polymeric film material with opposite sides. The film material has deposited on a first side a metal coating which is spectrally reflective and partially light transmissive in the visible region of the spectrum, is capable of transmitting from about 1% to about 70% of incident visible light cast thereon; the second side having a white outermost surface, and has a visible light opacity of from about 0.5 to about 0.98.
    Type: Grant
    Filed: March 22, 1990
    Date of Patent: September 21, 1993
    Assignee: Hoechst Celanese Corporation
    Inventors: Robert J. von Trebra, Gerald A. Smith, Roy E. Hensel, Oliver A. Barton, deceased
  • Patent number: 5242781
    Abstract: A process of forming images with a heat-developable color light-sensitive material is disclosed. The process of forming images comprises steps of exposing imagewise a heat-developable color light-sensitive material which comprises a support having thereon a light-sensitive layer containing a binder, light-sensitive silver halide emulsion and dye donating substance capable of forming or releasing a diffusible dye upon heat development and superposing a dye image receiving material which comprises a support having thereon a dye receiving layer, over the light-sensitive material during, or after completion of, heat development to transfer dye images to said dye image receiving layer; wherein the dye image receiving layer contains a hydrophilic binder and polymer particles; a weight ration of the hydrophilic binder to the polymer particles is from 1:05 to 1:20; and the heat development and transfer of dye images to the dye image receiving layer are carried out in the substantial absence of water.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: September 7, 1993
    Assignee: Konica Corporation
    Inventors: Keiji Ohbayashi, Masaru Tsuchiya
  • Patent number: 5234790
    Abstract: A multilayer, photosensitive element comprising a coversheet, a photohardenable layer, a contiguous layer, an isolation layer, an adhesive layer, and a support, is described. The element is used for image reproduction.
    Type: Grant
    Filed: February 25, 1992
    Date of Patent: August 10, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Charles D. Lang, Scott D. McCalmont, John Choi, Anchi Hou, Alan Shobert
  • Patent number: 5217841
    Abstract: An image transfer type recording method and kits for forming images on a receiving medium stably adheres a developer layer to any type of image receiving medium, such as, for example, plain paper, cloths, plastic films or the like. According to an image transfer type recording method, the image formation layer and the image receiving medium are adhered to each other by an adhesive layer. Therefore, the image formation layer can be stably adhered to any type of image receiving medium The image formation layer is adhered to the image receiving medium while being sandwiched between a thermoplastic resin layer and the adhesive layer. Therefore, the color of the image formed on the image formation layer is not faded or reduced in brightness, even if the image is formed on media made from cloth and such media on which the image is formed is washed.
    Type: Grant
    Filed: March 13, 1991
    Date of Patent: June 8, 1993
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventor: Keiko Ishikawa
  • Patent number: 5213943
    Abstract: Method for making lithographic aluminium offset printing plates according to the DTR-process by photo-exposing a photosensitive monosheet layer assemblage comprising a hydrophilic aluminium foil, a water-swellable intermediate layer comprising a non-proteinic hydrophilic film-forming polymer, and a silver halide emulsion layer, applying an aqueous alkaline solution thereto in the presence of a developing agent and a silver halide solvent, allowing to reduce the photo-exposed silver halide, allowing the unreduced silver halide or complexes thereof to diffuse to said aluminium foil to form a silver image thereon, and separating said emulsion layer and said intermediate layer from the imaged aluminium foil. The invention also relates to the photosensitive monosheet layer assemblage used for making such printing plates.
    Type: Grant
    Filed: September 13, 1991
    Date of Patent: May 25, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Paul J. Coppens, Ludovicus H. Vervloet, Luc H. Leenders, Ronald Schuerwegen
  • Patent number: 5213945
    Abstract: A dry film for forming a solder mask includes a cover sheet, a photoimageable composition layer which is curable to form a solder mask and a top coat interposed between the cover sheet and the photoimageable composition layer which is selectively adherent to the photoimageable composition layer. The dry film is applied to a surface of a printed circuit board with a minor portion of the area of the photoimageable composition layer tacked to the printed circuit board. The cover sheet is peeled away. With heat and vacuum, the photoimageable composition layer is laminated to the irregular surface of the printed circuit board, conforming the photoimageable composition layer to the contours thereof and leaving the top coat as a protective covering over the photoimageable composition layer. The photoimageable composition layer is exposed to patterned actinic radiation, developed and cured to form a hard, permanent solder mask.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: May 25, 1993
    Assignee: Morton International, Inc.
    Inventors: Leo Roos, Fredrick J. Axon, James J. Briguglio
  • Patent number: 5178979
    Abstract: An image transfer type recording method for forming a visible image on a developer medium comprising a base sheet, a thermoplastic resin layer, and a developer material layer which is color-reactable with a chromogenic material laminated in this order, and transferring the visible image on the developer medium to any type of image supporting medium, comprising the steps of forming the visible image on the developer material layer through a color-reaction between the developer material and the chromogenic material, providing an adhesive layer on the developer material layer, superposing the developer material layer and the image supporting medium under pressure and heat to fixedly transfer the developer material layer having the visible image thereon to the image supporting medium, and peeling off only the substrate of the developer medium.
    Type: Grant
    Filed: October 30, 1990
    Date of Patent: January 12, 1993
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Shunichi Higashiyama, Keiko Suzuki
  • Patent number: 5158857
    Abstract: A light-sensitive transfer sheet is disclosed, which comprises a support having provided thereon a peeling layer comprising an alcohol-soluble polyamide, an alkali-soluble organic polymer and a basic compound, and a color material-incorporated light-sensitive resin layer or a color material layer and a light-sensitive resin layer, in that order.
    Type: Grant
    Filed: October 11, 1990
    Date of Patent: October 27, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Fumiaki Shinozaki, Tomohisa Tago, Tomizo Namiki, Hideyuki Nakamura
  • Patent number: 5094931
    Abstract: The invention provides a method for protecting an image which comprises providing a multilayered colored image on a permanent receiver which may be any of a wide range of materials. A photosensitive element on a substrate is laminated to a temporary element and exposed with substrate removal before development. After development, the steps are repeated with another color. A protective element is laminated to the colored image. After removal of the support of the temporary element, the colored image with protective element is laminated to a permanent receiver.
    Type: Grant
    Filed: April 23, 1990
    Date of Patent: March 10, 1992
    Assignee: Hoechst Celanese Corporation
    Inventor: Stephan J. W. Platzer
  • Patent number: 5093168
    Abstract: An image-receiving sheet element comprising an image-receiving layer provided on a flexible substrate and a removable cover sheet, wherein said cover sheet comprises a low density copolymer containing 30% by weight or more of a linear polyethylene, is described. This image-receiving sheet element shows improved slip properties and a good workability, and little deterioration in transfer properties upon prolonged storage. Furthermore, it scarcely suffers from any caused by static electricity when the cover sheet is peeled off from the image-receiving sheet.
    Type: Grant
    Filed: September 28, 1990
    Date of Patent: March 3, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tamotsu Suzuki, Tomizo Namiki, Masashi Katayama
  • Patent number: 5087549
    Abstract: Provided are multilayer, tonable peel-apart photosensitive elements which include an esterified polyol plasticizer in the photoadherent layer, together with processes for their use for preparing pre-press color proofs.
    Type: Grant
    Filed: October 19, 1990
    Date of Patent: February 11, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert W. Peiffer
  • Patent number: 5085969
    Abstract: An image-receiving sheet material to be used for the formation of a transferred image by transferring a transferable image formed on an image-forming layer of a photo-sensitive material onto the image-receiving sheet material and then retransferring the image onto a permanent substrate, as well as a process for the formation of a transferred image with the use of the image-receiving sheet material are disclosed.
    Type: Grant
    Filed: March 16, 1990
    Date of Patent: February 4, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tomizo Namiki, Tamotsu Suzuki, Fumiaki Shinozaki