From Ethylenically Unsaturated Monomer Patents (Class 430/263)
-
Patent number: 5609985Abstract: Disclosed are a color image-formable material which comprises a support, a cushion layer provided on the support and a color light-sensitive layer containing a light-sensitive composition and a coloring agent provided on the cushion layer and gives a transferred image by forming a color image portion by imagewise exposure and developing treatment and then transferring the color image portion alone to an image-receiving material,wherein the surface at a color light-sensitive layer side of the cushion layer has an average gloss (GS (60.degree. )) of 30 or more and the color light-sensitive layer is provided on the cushion layer, a process for preparing the same.Type: GrantFiled: September 20, 1994Date of Patent: March 11, 1997Assignees: Konica Corporation, Mitsubishi Chemical CorporationInventors: Tetsuya Taniguchi, Kiyoshi Goto, Takeo Akiyama, Miyuki Hosoi, Tetsuya Masuda, Hideaki Mochizuku
-
Patent number: 5609984Abstract: An element comprising, in order: (a) a removable substrate; (b) a transparent, nonphotosensitive, polymeric layer having a thickness of less than about 0.002 cm and a gloss of 45-70; said polymeric layer consisting essentially of at least one thermoplastic polymer having an elongation at break of greater than 30%, a glass transition temperature of 35.degree.-70.degree. C.; and (c) an elastomeric layer and optionally an additional, different removable substrate (d) adjacent to the elastomeric layer, wherein the polymeric layer exhibits improved adhesion to the removable substrate (a) when removable substrate (d) is removed is described.Type: GrantFiled: May 4, 1995Date of Patent: March 11, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Anchi Hou
-
Patent number: 5599648Abstract: Surface reforming of a polymeric article containing a polymerizable compound is effectively performed by polymerizing the polymeric article in contact with a surface reforming medium because the transfer of the material constituting the surface reforming medium to the polymeric article is enhanced by the polymerization. The surface reforming can be performed locally selectively, i.e., imagewise. The remaining un-polymerized part may be subjected to further surface reforming, e.g., by using another type of surface reforming medium or attachment of powder, to provide an enhanced contrast of surface property. Such an enhanced contrast of surface property can be effectively used, e.g., for production of a printing plate.Type: GrantFiled: November 26, 1993Date of Patent: February 4, 1997Assignee: Canon Kabushiki KaishaInventors: Yuji Kondo, Masato Katayama, Akihiro Mouri
-
Patent number: 5597676Abstract: The present invention provides a method for obtaining an imaging element suitable for use in a silver salt diffusion transfer process by the steps of:preparing an image receiving element by coating the anodized surface of an aluminum foil with an image-receiving layer comprising physical development nuclei,preparing a photosensitive layer packet by coating a temporary base with at least one photosensitive silver halide emulsion layer,pressing the thus formed photosensitive layer packet with its photosensitive silver halide emulsion coated side against said image receiving layer, which has been wet with an aqueous moistening liquid, andoptionally removing said temporary base, characterized in that between said temporary base and said at least one photosensitive silver halide emulsion layer a barrier layer is present which is substantially free of developing agents, is substantially unhardened, comprises one or more hydrophilic binders in an amount of at least 0.25 g/m.sup.Type: GrantFiled: August 17, 1995Date of Patent: January 28, 1997Assignee: AGFA-Gevaert. N.V.Inventors: Ludo Van Rompuy, Paul Coppens
-
Patent number: 5593811Abstract: (A) being a photosensitive relief-forming layer in which imagewise exposure to actinic light results in different solubilities of the exposed and unexposed parts, and this layer consists of a mixture of:(a1)one or more polymeric binders,(a2)one or more photopolymerization initiators,(a3)one or more organic compounds which are compatible with the binder (a1) and contain photopolymerizable olefinically unsaturated groups and, if required,(a4)one or more assistants,(B) being a smooth or dull, nontacky release layer (B) which is transparent to light, soluble or swellable in the relevant liquid media and formed by a polymer forming strong films and additives contained therein, and(C) being a cover sheet which can be detached from the release layer (B), the release layer (B) containing a metal salt as an additive,is suitable for the production of printing plates.Type: GrantFiled: December 21, 1995Date of Patent: January 14, 1997Assignee: BASF Lacke+Farben AktiengesellschaftInventors: Thomas Loerzer, Stefan Wegener, Friedrich Goffing
-
Patent number: 5593809Abstract: There are described a diffusion transfer photographic film unit of the type wherein an image-receiving element is designed to be separated from a photosensitive element after photoexposure and processing and a photographic process which utilizes the film unit. The photographic film unit comprises a photosensitive element including a support carrying at least one silver halide emulsion, an image-receiving element comprising a support, an image-receiving layer and, optionally, an overcoat layer and/or a strip-coat layer. At least one of the image-receiving layer, overcoat layer or strip-coat layer includes a "crosslinkable material" which is crosslinked during processing. The film unit further includes means for providing an aqueous alkaline processing composition to the photosensitive element and the image-receiving element for developing an image. The aqueous alkaline processing composition includes a borate compound for crosslinking the crosslinkable material of the image-receiving element during processing.Type: GrantFiled: December 7, 1995Date of Patent: January 14, 1997Assignee: Polaroid CorporationInventors: Gia Y. Kim, Lloyd D. Taylor, Kenneth C. Waterman
-
Patent number: 5591560Abstract: An image-receiving element for use in photographic and photothermographic diffusion transfer film units of the type wherein the image-receiving element is designed to be removed or "peeled-apart" from a photosensitive element following exposure and processing. The present image-receiving element comprises in sequence, a support, an image-receiving layer, and a strip-coat layer. The strip-coat layer serves to facilitate separation of the image-receiving layer from a photosensitive element after processing. The strip-coat layer comprises a copolymer including: 1) at least about 50% by weight of monomer units, the same or different, derived from an ethylenically unsaturated carboxylic acid or salt thereof, 2) at least about 15% by weight of monomer units of vinyl pyrrolidone, and 3) at least about 5% by weight of monomer units, the same or different, represented by the formula: ##STR1## wherein R.sub.Type: GrantFiled: December 7, 1995Date of Patent: January 7, 1997Inventors: Agota F. Fehervari, James A. Foley, Gia Y. Kim, Diana R. Koretsky, Lloyd D. Taylor, Kenneth C. Waterman
-
Patent number: 5587272Abstract: This invention makes available processes for preparing images, especially color proofs. A layer with imagewise tacky and nontacky areas is toned. Toner adhering to the tacky areas is transferred first onto a temporary support and from there onto an image receptor.Type: GrantFiled: December 7, 1995Date of Patent: December 24, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Mario Grossa, Udo D. Bode, Manfred Sondergeld, Karl-Heinz Wiedenmann, Ronald J. Convers, Steven M. Kalo, Ashok K. Kudva
-
Patent number: 5578413Abstract: A photosensitive transfer material is disclosed including a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the transfer material having an interlaminar adhesion which is lowest between the thermoplastic resin layer and the temporary substrate, wherein the alkali-soluble thermoplastic resin layer contains (A) an alkali-soluble thermoplastic resin having a weight average molecular weight of from 50,000 to 500,000 and a glass transition temperature of from 0.degree. to 140.degree. C. and (B) an alkali-soluble thermoplastic resin layer having a weight average molecular weight of from 3,000 to 30,000 and a glass transition temperature of from 30.degree. to 170.degree. C. at an (A)/(B) weight ratio of from 5/95 to 95/5. The transfer material can be transferred to a permanent substrate at a high speed without entrapping air bubbles due to unevenness on the permanent substrate.Type: GrantFiled: March 15, 1996Date of Patent: November 26, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Sadao Fujikura, Minoru Wada
-
Patent number: 5576140Abstract: An image-receiving sheet material for forming a transfer image by heat-transferring an ink layer from a transfer material having a heat-transferable ink layer onto an image-receiving sheet material, and re-transferring the ink layer onto a permanent support. The image-receiving sheet material comprises a support having thereon at least two image-receiving layers, at least one of the image-receiving layers is transferred onto the permanent support, and at least the image-receiving layer onto which the ink layer is transferred contains a modified resin prepared from a polyvinyl acetal resin containing hydroxyl groups in which from 0.1 to 1 equivalent of the hydroxyl groups of the polyvinyl acetal resin have been converted to a group represented by formula (I). In a preferred embodiment, the image-receiving layer onto which the ink layer is transferred further contains a high molecular weight compound having at least a repeating unit represented by formula (II) and/or formula (III).Type: GrantFiled: March 7, 1996Date of Patent: November 19, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Yuichi Wakata, Hideyuki Nakamura
-
Patent number: 5534384Abstract: A photosensitive material for the production of color proofing films for multicolor printing, having(A) a transparent, flexible film support of plastic,(B) a photopolymerizable layer which contains(B1) a polymeric binder,(B2) a free-radically polymerizable compound,(B3) a compound which is capable of initiating the polymerization of (B2) on exposure to actinic light, and(B4) a dye or a colored pigment in a primary color of multicolor printing, and(C) a thermoplastic adhesive layer having a layer weight of from about 2 to about 30 g/m.sup.2 on the photo-sensitive layer, wherein the thermoplastic adhesive layer contains from about 0.01 to about 0.5% by weight of a colorless pigment having a mean particle size which corresponds to from 1 to 100% of the layer thickness.Type: GrantFiled: February 19, 1993Date of Patent: July 9, 1996Assignee: Hoechst AktiengesellschaftInventors: Stephan J. W. Platzer, Siegfried Nuernberger, Karin Maerz
-
Patent number: 5529879Abstract: This invention relates to a photosensitive sheet having on a substrate one or more resin layers that are peelable from the substrate and heat-fusible, and a colored photosensitive layer in this order, said substrate comprising a biaxially stretched plastic film and having a molecular orientation ratio in the range of from 1.0 to 1.4.The object of this invention is to solve the problem of misregister without decreasing productivity during the formation of plastic film (substrate) or during the production of a photosensitive sheet in a method in which said photosensitive sheet having an image formed thereon and an image receiving sheet for receiving the image are superimposed on each other, and pressed and heated for image transfer.Type: GrantFiled: March 31, 1993Date of Patent: June 25, 1996Assignee: Nippon Paper Industries Co., Ltd.Inventors: Mitsuhide Hoshino, Fukuo Murata, Norio Yabe, Masahide Takano
-
Patent number: 5525454Abstract: A photosensitive transfer material is disclosed including a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the transfer material having an interlaminar adhesion which is lowest between the thermoplastic resin layer and the temporary substrate, wherein the alkali-soluble thermoplastic resin layer contains (A) an alkali-soluble thermoplastic resin having a weight average molecular weight of from 50,000 to 500,000 and a glass transition temperature of from 0.degree. to 140.degree. C. and (B) an alkali-soluble thermoplastic resin layer having a weight average molecular weight of from 3,000 to 30,000 and a glass transition temperature of from 30.degree. to 170.degree. C. at an (A)/(B) weight ratio of from 5/95 to 95/5. The transfer material can be transferred to a permanent substrate at a high speed without entrapping air bubbles due to unevenness on the permanent substrate.Type: GrantFiled: July 8, 1994Date of Patent: June 11, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Sadao Fujikura, Minoru Wada
-
Patent number: 5518857Abstract: A method for engraving and/or etching comprising the steps of: (a) a process for exposing, to light, a layer of a water-soluble resin composition of a laminated photo-sensitive film which comprises a supporting sheet, a image mask-protection layer peelablly adhered to the supporting sheet and a layer of a water-soluble resin composition having photocrosslinkability to thus cause crosslinking of the exposed area of the resin layer to thereby form a predetermined pattern on the resin layer; (b) a process for dissolving out the non-crosslinked portion of the layer of the water-soluble photo-sensitive resin composition by developing the layer with water to thus from an image-carrying mask which is constituted from the crosslinked area of the photo-sensitive resin composition remaining on the image mask-protection layer; (c) a process for adhering the photo-sensitive laminate film on which the images are formed to the surface of a material to be processed; (d) a process for peeling off the supporting sheet from thType: GrantFiled: January 13, 1995Date of Patent: May 21, 1996Assignee: Aicello Chemical Co., Ltd.Inventors: Tsutomu Suzuki, Ikuo Suzuki
-
Patent number: 5478694Abstract: The invention relates to a photosensitive material for the production of color proofing films for multicolor printing comprising:A) a transparent, flexible film support,B) a photopolymerizable layer containing:B1) a polymeric binder,B2) a free radical-polymerizable compound,B3) a compound which is capable of initiating the polymerization of (B2) on exposure to actinic light, andB4) a dye or colored pigment in a primary color of multicolor printing, andC) a thermoplastic adhesive layer on the photosensitive layer,which contains at least about 1.5% by weight of a water-soluble, colorless, low-molecular-weight salt whose aqueous solution is not highly acidic.The material is processed by lamination onto an image-receiving material, exposure and peeling apart of the film support and the image-receiving material, the unexposed areas of the layer and the adhesive layer remaining on the image-receiving material.Type: GrantFiled: May 17, 1993Date of Patent: December 26, 1995Assignee: Hoechst AktiengesellschaftInventors: Karin Maerz, Ine Gramm, Manfred Hilger, Dieter Mohr, Stephan J. W. Platzer
-
Patent number: 5468596Abstract: A photosensitive recording element comprises(A) a dimensionally stable substrate,(B) a photopolymerizable relief-forming recording layer and, if required, an adhesion-promoting layer arranged between (A) and (B), a release layer (C) applied to that side of the recording layer (B) which faces away from the substrate (A), and, if required, a cover sheet (D) applied thereon, the photopolymerizable relief-forming recording layer (B) containingb.sub.1) at least one polymeric binder,b.sub.2) at least one photopolymerizable olefinically unsaturated monomer which is compatible with b.sub.1),b.sub.3) at least one photopolymerization initiator andb.sub.4) at least one aryl alkyl ketone,and is suitable for the production of relief printing plates.Type: GrantFiled: January 13, 1995Date of Patent: November 21, 1995Assignee: BASF Lacke + Farben AGInventors: Thomas Loerzer, Thomas Telser, Thomas Zwez, Bernhard Albert
-
Patent number: 5443939Abstract: A light-sensitive material for producing color-test films for multi-color printing is disclosed. The material has (A) a transparent flexible base film of a plastic, (B) a photopolymerizable layer containing (B1) a polymeric binder, (B2) a compound polymerizable by a free-radical mechanism, (B3) a compound capable of initiating the polymerization of (B2) under the action of actinic light, and (B4) a dye or a colored pigment in one of the basic colors of multi-color printing, and (C) a thermoplastic adhesion layer on the light-sensitive layer is described. A polymer of a vinyl alkyl ether is present in at least one of the layers (B) and (C). The material is processed by lamination to an image-receiving material, with subsequent exposure and peeling-apart of base film and image-receiving material. The unexposed layer areas remain together with the adhesion layer on the image-receiving material. These steps are repeated with at least one further part-color image.Type: GrantFiled: March 14, 1994Date of Patent: August 22, 1995Assignee: Hoechst AktiengesellschaftInventors: Karin Maerz, Stephan J. W. Platzer
-
Patent number: 5437959Abstract: An element comprising, in order: (a) a removable substrate; (b) a transparent, nonphotosensitive, polymeric layer having a thickness of less than about 0.002 cm and a gloss of 45-70; said polymeric layer consisting essentially of at least one thermoplastic polymer having an elongation at break of greater than 30%, a glass transition temperature of 35.degree.-70.degree. C.; and (c) an elastomeric layer and optionally an additional, different removable substrate (d) adjacent to the elastomeric layer, wherein the polymeric layer exhibits improved adhesion to the removable substrate (a) when removable substrate (d) is removed is described.Type: GrantFiled: January 25, 1994Date of Patent: August 1, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: Anchi Hou
-
Patent number: 5437960Abstract: A process for laminating a photosensitive-layer which includes providing (A) a base having a laminating region and a non-laminating region, and (B) a support having thereon, in order, a photosensitive layer and a protective film, where part of the protective film corresponds to the laminating region and part of the protective film corresponds to the non-laminating region, removing the part of the protective film which corresponds to the laminating region from the photosensitive layer such that the photosensitive layer can be laminated to the base in the laminating region, feeding the base and the support having thereon the photosensitive layer from which protective film has been removed to a nip between a pair of heated pressure rollers, passing the base and photosensitive-layer-covered support forward through the rollers while the base and photosensitive-layer-covered support are being nipped and hot-pressed by the rollers, with the photosensitive layer being in contact with the laminating region of the baseType: GrantFiled: August 5, 1994Date of Patent: August 1, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Nagate, Hiroya Endo, Ken-ichi Miyata
-
Patent number: 5427890Abstract: A method for engraving and/or etching comprising the steps of: (a) a process for exposing, to light, a layer of a water-soluble resin composition of a laminated photosensitive film which comprises a supporting sheet, a image mask-protection layer peelablly adhered to the supporting sheet and a layer of a water-soluble resin composition having photocrosslinkability to thus cause crosslinking of the exposed area of the resin layer to thereby form a predetermined pattern on the resin layer; (b) a process for dissolving out the non-crosslinked portion of the layer of the water-soluble photo-sensitive resin composition by developing the layer with water to thus from an image-carrying mask which is constituted from the crosslinked area of the photo-sensitive resin composition remaining on the image mask-protection layer; (c) a process for adhering the photo-sensitive laminate film on which the images are formed to the surface of a material to be processed; (d) a process for peeling off the supporting sheet from theType: GrantFiled: September 3, 1993Date of Patent: June 27, 1995Assignee: Aicello Chemical Co., Ltd.Inventors: Tsutomu Suzuki, Ikuo Suzuki
-
Patent number: 5415969Abstract: An image-receiving element for use in photographic diffusion transfer film units of the type Wherein the image-receiving element, which includes an image-receiving layer, is designed to be removed, or "peeled-apart", from a photosensitive element after exposure and development have been carried out. The image-receiving element includes an overcoat layer which overlies the image-receiving layer for reducing the time period for which the image-receiving element remains tacky after the element has been separated from the photosensitive element and for improving the handling and/or storage of the resulting photograph under high humidity conditions. The overcoat layer comprises colloidal silica particles and binder material.Type: GrantFiled: October 6, 1993Date of Patent: May 16, 1995Assignee: Polaroid CorporationInventor: Kenneth C. Waterman
-
Patent number: 5409800Abstract: A photosensitive transfer material comprises a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the interlaminar adhesion in the transfer material being the smallest at the interface between the thermoplastic resin layer and the temporary substrate. The photosensitive resin layer can be transferred to a permanent substrate without involving failure due to fine dust, air bubbles or unevenness of the permanent substrate. An image can be formed with the transfer material by adhering the transfer material to a permanent substrate at least under heat and, after stripping the temporary substrate, imagewise exposing the photosensitive resin layer to light, and processing the transferred layers to develop the photosensitive resin layer.Type: GrantFiled: March 25, 1994Date of Patent: April 25, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Morimasa Sato, Masayuki Iwasaki, Fumiaki Shinozaki, Koji Inoue
-
Patent number: 5405731Abstract: The use of a two layer photoimageable, aqueous processable, resist with a hydrophic binder in the outermost layer provides a permanent coating highly resistant to printed circuit processing chemicals. This resistance results in levels of adsorbed or absorbed ionic contamination less than 14 micrograms per square inch.Type: GrantFiled: December 22, 1992Date of Patent: April 11, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Karuppiah Chandrasekaran, Mark R. McKeever, James W. O'Neil
-
Patent number: 5391458Abstract: A method is provided for forming a high-resolution photoresist layer on a substrate, such as a metal-clad circuit board blank. A dry film is used which comprises a support sheet, a negative-acting, alkaline aqueous developable photoresist layer in direct contact with the support sheet, and a protective sheet. The protective sheet is removed and the photoresist layer is cut sheet laminated to the substrate. Then the support sheet is removed. The photoresist layer is baked until its exposed surface is non-tacky. Artwork is laid directly in contact with the non-tacky exposed surface, and the photoresist layer is exposed to actinic radiation through the art work. The photoresist layer is then developed in alkaline aqueous solution. The photoresist layer is highly resolved. Subsequent processing steps, such as plating or etching and stripping yield a printed circuit board having highly resolved lines and spaces.Type: GrantFiled: December 18, 1992Date of Patent: February 21, 1995Assignee: Morton International, Inc.Inventor: Charles T. Conrad
-
Patent number: 5374184Abstract: A photopolymerizable material having(A) a flexible, transparent film support;(B) a colored, polymerizable layer containing an organic binder, a free-radical-polymerizable compound, containing at least one terminal ethylenically unsaturated group, and a dye or colored pigment;(C) an adhesion layer containing a thermoplastic polymer and having a T.sub.g of from 25.degree. to 100.degree. C.; and(D) an uncolored photopolymerizable layer which contains a polymeric organic binder, a free-radical-polymerizable compound containing at least one terminal ethylenically unsaturated group and a photopolymerization initiator between the film support (A) and the colored polymerizable layer (B),where the cohesion of layers (B), (C) and (D) and the adhesion of these layers to one another and to the film support (A) provides the relationship wherein the adhesion (a.sub.2) of the photopolymerizable layer (D) to the colored layer (B) in the unexposed state is lower than: (i) the adhesion (a.sub.Type: GrantFiled: April 4, 1994Date of Patent: December 20, 1994Assignee: Hoeschst AktiengesellschaftInventors: Stephan J. W. Platzer, Gerhard Buhr, Manfred Michel, Andrea Buchmann
-
Patent number: 5366844Abstract: The present invention provides a heat mode recording material comprising on the same side of a non-conductive support a conductive recording layer and an elastomeric image forming layer being non-conductive characterised in that a peelable polymeric film is provided as an outermost layer on the side of said support containing said elastomeric image forming layer.Type: GrantFiled: September 29, 1993Date of Patent: November 22, 1994Assignee: AGFA-Gevaert, N.V.Inventors: Yves Verburgh, Luc Leenders
-
Patent number: 5346800Abstract: An image-receiving element for use in photographic diffusion transfer film units of the type wherein the image-receiving element, which includes an image-receiving layer, is designed to be removed, or "peeled-apart", from a photosensitive element after exposure and development have been carried out. The image-receiving element includes a strip-coat layer comprising a hydrophilic colloid, such as gum arabic, and an aluminum salt which overlies the image-receiving layer and significantly reduces striations and/or haze and facilitates the separation of the image-receiving element from the remainder of the film unit subsequent to diffusion transfer photography.Type: GrantFiled: October 6, 1993Date of Patent: September 13, 1994Assignee: Polaroid CorporationInventors: James A. Foley, Nicholas S. Hadzekyriakides, James J. Reardon
-
Patent number: 5342745Abstract: Disclosed is a silver halide photographic light-sensitive material comprising a base paper support coated with a hydrophilic polymer as a peeling agent, and having thereon, a polyolefin resin layer, and at least one silver halide emulsion layer, wherein the hydrophilic polymer is coated on the side on which the silver halide emulsion layer is provided, and a peel strength between the base paper support and the polyolefin resin layer is within the range of 30 to 160 g in weight per inch, and a maximum color transmission density is not less than 2.0 when the silver halide light-sensitive material is subjected to a color developing.Type: GrantFiled: October 13, 1993Date of Patent: August 30, 1994Assignee: Konica CorporationInventors: Akiyoshi Tai, Shun Takada
-
Patent number: 5340693Abstract: The present invention provides a heat recording material comprising on a support in the order given a porous layer of an image forming substance, a substance capable of converting radiation into heat, a thermoplastic layer containing a photocurable composition and a stripping layer. The present invention further provides a method for obtaining an image with such an heat recording material. Images of high quality and good wear and scratch resistance are obtained.Type: GrantFiled: February 18, 1993Date of Patent: August 23, 1994Assignee: Agfa-Gevaert, N.V.Inventors: Herman Uytterhoeven, Luc Bastiaens, Rudolf Van den Bergh, Luc Leenders
-
Patent number: 5300395Abstract: A white, partially translucent, metallized film article which having a flexible, heat resistant, polymeric film material with opposite sides. The film material has deposited on a first side a metal coating which is spectrally reflective and partially light transmissive in the visible region of the spectrum, is capable of transmitting from about 1% to about 70% of incident visible light cast thereon; the second side having a white outermost surface, and has a visible light opacity of from about 0.5 to about 0.98.Type: GrantFiled: July 6, 1993Date of Patent: April 5, 1994Assignee: Hoechst Celanese CorporationInventors: Robert J. von Trebra, Gerald A. Smith, Roy E. Hensel, Oliver A. Barton, deceased
-
Patent number: 5292613Abstract: A photosensitive transfer material is described, comprising a temporary support having formed thereon in sequence a thermoplastic resin layer, a separating layer having only slight permeability to oxygen, and a photosensitive resin layer, wherein the adhesion between the thermoplastic resin layer and the separating layer is weakest. The photosensitive transfer material is useful, for example, for an image-forming process.Type: GrantFiled: January 29, 1992Date of Patent: March 8, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Morimasa Sato, Masayuki Iwasaki, Fumiaki Shinozaki
-
Patent number: 5278024Abstract: A photothermographic composite structure for use in a solvent-free dye thermal positive imaging diffusion-transfer process comprising:(a) an image-receiving element comprising a polymeric dyeable image-receiving layer having a glass transition temperature in the range of 20.degree. to 200.degree. C., and(b) strippably adhered to said image-receiving element, an imageable photothermographic element comprising in at least one layer thereof a binder, a silver source material, photosensitive silver halide in catalytic proximity to said silver source material, and a formazan dye.Type: GrantFiled: December 30, 1992Date of Patent: January 11, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Richard C. Cotner, David C. Weigel, Kumars Sakizadeh
-
Patent number: 5273858Abstract: Method for making lithographic aluminum offset printing plates according to the DTR-process by photo-exposing a photosensitive monosheet layer assemblage comprising a hydrophilic aluminum foil, an intermediate layer comprising hydrophobic polymer beads prepared by polymerization of ethylenically unsaturated monomer(s) and having an average diameter not lower than 0.2 .mu.m, and a silver halide emulsion layer, applying an aqueous alkaline solution to the photo-exposed silver halide emulsion layer in the presence of a developing agent and a silver halide solvent to form a silver image and to allow unreduced silver halide or complexes formed thereof to diffuse imagewise from the developed silver halide emulsion layer to said aluminum foil to produce thereon a silver image, and separating said emulsion layer and said intermediate layer from the imaged aluminum foil. The invention also relates to the photosensitive monosheet layer assemblage used for making such printing plates.Type: GrantFiled: October 28, 1991Date of Patent: December 28, 1993Assignee: Agfa-Gevaert, N.V.Inventors: Paul J. Coppens, Joan T. Vermeersch, Luc H. Leenders, Ludovicus H. Vervloet, Eric M. Hoes, Eddie R. Daems
-
Patent number: 5273855Abstract: (Objective) In a color-proof material performed by forming multi-color image on an arbitrary material (ultimate image-receiving material) such as paper using a photosensitive transfer sheet and an intermediate image-receiving sheet, the objective is to bring the quality close to the printed quality formed with inks alone.(Constitution) For the photosensitive sheet, the colored photosensitive layer is formed with a material comprising a synthetic resin emulsion with Tg=-20.degree. to 40.degree. C. such as acrylic ester or ethylene-vinyl acetate copolymer so that the image layer itself has heat-adhesivity. Moreover, the image-receiving layer of the intermediate image-receiving sheet is formed with a material containing a resin cross-linked copolymer of olefin and .alpha., .beta.-unsaturated carboxylic acid with metallic ions and a resin comprising a copolymer of ethylene and vinyl acetate in a proportion by weight of 100/0 to 10/90.Type: GrantFiled: November 21, 1991Date of Patent: December 28, 1993Assignee: Sanyo-Kokusaku Pulp Co., Ltd.Inventors: Hisahiro Omote, Masahiro Yoshikawa, Masahide Takano
-
Patent number: 5270147Abstract: A stripping film material comprises a polyethylene terephthalate film base serving as temporary support being coated with a subbing layer essentially consisting of either:(1) hydroxypropylcellulose wherein the molar degree of substitution (DS) with hydroxypropyl groups is in the range of 3 to 1, or:(2) a copoly(vinyl acetate/crotonic acid) having a weight ratio of vinyl acetate to crotonic acid in the range of 85/15 to 99/1, wherein said subbing layer is coated with at least one hydrophilic colloid layer which is adapted to be stripped off after being moistened with an aqueous liquid, e.g. by contact with a wet surface of a permanent support.Type: GrantFiled: June 23, 1992Date of Patent: December 14, 1993Assignee: Agfa-Gevaert N.V.Inventors: Etienne A. Van Thillo, Eddie R. Daems, Luc H. Leenders, Guido J. Smits
-
Patent number: 5254447Abstract: Photographic glass plates are advantageously prepared by a process in which the functional layers are applied to the glass plate support by lamination. In a first form of this process, a multilayer-composite comprising antihalation, silver halide emulsion and protective overcoat layers is transferred from a flexible polymeric film support to the glass support. In carrying out this first form of the process, a release layer, protective overcoat layer, silver halide emulsion layer and antihalation layer are coated, in order, on a flexible polymeric film and laminated via an adhesive layer to a glass plate having suitable thickness and flatness for use as a photographic support. The release layer is designed to have greater adhesion to the flexible polymeric film than to the protective overcoat layer, whereby the film and release layer can be stripped off prior to the plate being put into use.Type: GrantFiled: April 20, 1992Date of Patent: October 19, 1993Assignee: Eastman Kodak CompanyInventors: Arlene L. Meyer, Thomas M. Smith, Richard O. Smith
-
Patent number: 5254435Abstract: A CAD driven photoplotter selectively exposes a photographic imaging layer without affecting the underlying UV sensitive resist on a substrate to make a printed wiring board, for example. The image layer is developed on the board and used as an in situ mask for the underlying UV resist during exposure to UV. After UV exposure, the image layer is peeled off to allow conventional processing of the resist. The in situ mask is preferably applied in the form of a baseless, high contrast, high gamma emulsion layer bonded to the protective cover sheet over the uncured resist. To facilitate application, the emulsion layer is carried by a release paper which is removed before photoplotting. After UV exposure, the cover sheet and emulsion layer are integrally peeled from the resist.Type: GrantFiled: September 16, 1992Date of Patent: October 19, 1993Assignee: The Foxboro CompanyInventors: Paul E. Grandmont, Harold Lake
-
Patent number: 5248583Abstract: A photosensitive color proofing article comprising in the following order:a) a carrier layer,b) a release layer which acts as an oxygen barrier layer,c) a photopolymerizable layer comprising a multifunctional acrylate oligomer and a colorant,d) a photopolymerizable barrier layer, ande) a thermal adhesive layer.Type: GrantFiled: August 30, 1991Date of Patent: September 28, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Wallace R. Lundquist, Thomas P. Klun, Michael B. Heller, Leonard W. Sachi
-
Patent number: 5246812Abstract: A white, partially translucent, metallized film article which having a flexible, heat resistant, polymeric film material with opposite sides. The film material has deposited on a first side a metal coating which is spectrally reflective and partially light transmissive in the visible region of the spectrum, is capable of transmitting from about 1% to about 70% of incident visible light cast thereon; the second side having a white outermost surface, and has a visible light opacity of from about 0.5 to about 0.98.Type: GrantFiled: March 22, 1990Date of Patent: September 21, 1993Assignee: Hoechst Celanese CorporationInventors: Robert J. von Trebra, Gerald A. Smith, Roy E. Hensel, Oliver A. Barton, deceased
-
Patent number: 5242781Abstract: A process of forming images with a heat-developable color light-sensitive material is disclosed. The process of forming images comprises steps of exposing imagewise a heat-developable color light-sensitive material which comprises a support having thereon a light-sensitive layer containing a binder, light-sensitive silver halide emulsion and dye donating substance capable of forming or releasing a diffusible dye upon heat development and superposing a dye image receiving material which comprises a support having thereon a dye receiving layer, over the light-sensitive material during, or after completion of, heat development to transfer dye images to said dye image receiving layer; wherein the dye image receiving layer contains a hydrophilic binder and polymer particles; a weight ration of the hydrophilic binder to the polymer particles is from 1:05 to 1:20; and the heat development and transfer of dye images to the dye image receiving layer are carried out in the substantial absence of water.Type: GrantFiled: August 26, 1991Date of Patent: September 7, 1993Assignee: Konica CorporationInventors: Keiji Ohbayashi, Masaru Tsuchiya
-
Patent number: 5234790Abstract: A multilayer, photosensitive element comprising a coversheet, a photohardenable layer, a contiguous layer, an isolation layer, an adhesive layer, and a support, is described. The element is used for image reproduction.Type: GrantFiled: February 25, 1992Date of Patent: August 10, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventors: Charles D. Lang, Scott D. McCalmont, John Choi, Anchi Hou, Alan Shobert
-
Patent number: 5217841Abstract: An image transfer type recording method and kits for forming images on a receiving medium stably adheres a developer layer to any type of image receiving medium, such as, for example, plain paper, cloths, plastic films or the like. According to an image transfer type recording method, the image formation layer and the image receiving medium are adhered to each other by an adhesive layer. Therefore, the image formation layer can be stably adhered to any type of image receiving medium The image formation layer is adhered to the image receiving medium while being sandwiched between a thermoplastic resin layer and the adhesive layer. Therefore, the color of the image formed on the image formation layer is not faded or reduced in brightness, even if the image is formed on media made from cloth and such media on which the image is formed is washed.Type: GrantFiled: March 13, 1991Date of Patent: June 8, 1993Assignee: Brother Kogyo Kabushiki KaishaInventor: Keiko Ishikawa
-
Patent number: 5213943Abstract: Method for making lithographic aluminium offset printing plates according to the DTR-process by photo-exposing a photosensitive monosheet layer assemblage comprising a hydrophilic aluminium foil, a water-swellable intermediate layer comprising a non-proteinic hydrophilic film-forming polymer, and a silver halide emulsion layer, applying an aqueous alkaline solution thereto in the presence of a developing agent and a silver halide solvent, allowing to reduce the photo-exposed silver halide, allowing the unreduced silver halide or complexes thereof to diffuse to said aluminium foil to form a silver image thereon, and separating said emulsion layer and said intermediate layer from the imaged aluminium foil. The invention also relates to the photosensitive monosheet layer assemblage used for making such printing plates.Type: GrantFiled: September 13, 1991Date of Patent: May 25, 1993Assignee: Agfa-Gevaert, N.V.Inventors: Paul J. Coppens, Ludovicus H. Vervloet, Luc H. Leenders, Ronald Schuerwegen
-
Patent number: 5213945Abstract: A dry film for forming a solder mask includes a cover sheet, a photoimageable composition layer which is curable to form a solder mask and a top coat interposed between the cover sheet and the photoimageable composition layer which is selectively adherent to the photoimageable composition layer. The dry film is applied to a surface of a printed circuit board with a minor portion of the area of the photoimageable composition layer tacked to the printed circuit board. The cover sheet is peeled away. With heat and vacuum, the photoimageable composition layer is laminated to the irregular surface of the printed circuit board, conforming the photoimageable composition layer to the contours thereof and leaving the top coat as a protective covering over the photoimageable composition layer. The photoimageable composition layer is exposed to patterned actinic radiation, developed and cured to form a hard, permanent solder mask.Type: GrantFiled: July 25, 1991Date of Patent: May 25, 1993Assignee: Morton International, Inc.Inventors: Leo Roos, Fredrick J. Axon, James J. Briguglio
-
Patent number: 5178979Abstract: An image transfer type recording method for forming a visible image on a developer medium comprising a base sheet, a thermoplastic resin layer, and a developer material layer which is color-reactable with a chromogenic material laminated in this order, and transferring the visible image on the developer medium to any type of image supporting medium, comprising the steps of forming the visible image on the developer material layer through a color-reaction between the developer material and the chromogenic material, providing an adhesive layer on the developer material layer, superposing the developer material layer and the image supporting medium under pressure and heat to fixedly transfer the developer material layer having the visible image thereon to the image supporting medium, and peeling off only the substrate of the developer medium.Type: GrantFiled: October 30, 1990Date of Patent: January 12, 1993Assignee: Brother Kogyo Kabushiki KaishaInventors: Shunichi Higashiyama, Keiko Suzuki
-
Patent number: 5158857Abstract: A light-sensitive transfer sheet is disclosed, which comprises a support having provided thereon a peeling layer comprising an alcohol-soluble polyamide, an alkali-soluble organic polymer and a basic compound, and a color material-incorporated light-sensitive resin layer or a color material layer and a light-sensitive resin layer, in that order.Type: GrantFiled: October 11, 1990Date of Patent: October 27, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Fumiaki Shinozaki, Tomohisa Tago, Tomizo Namiki, Hideyuki Nakamura
-
Patent number: 5094931Abstract: The invention provides a method for protecting an image which comprises providing a multilayered colored image on a permanent receiver which may be any of a wide range of materials. A photosensitive element on a substrate is laminated to a temporary element and exposed with substrate removal before development. After development, the steps are repeated with another color. A protective element is laminated to the colored image. After removal of the support of the temporary element, the colored image with protective element is laminated to a permanent receiver.Type: GrantFiled: April 23, 1990Date of Patent: March 10, 1992Assignee: Hoechst Celanese CorporationInventor: Stephan J. W. Platzer
-
Patent number: 5093168Abstract: An image-receiving sheet element comprising an image-receiving layer provided on a flexible substrate and a removable cover sheet, wherein said cover sheet comprises a low density copolymer containing 30% by weight or more of a linear polyethylene, is described. This image-receiving sheet element shows improved slip properties and a good workability, and little deterioration in transfer properties upon prolonged storage. Furthermore, it scarcely suffers from any caused by static electricity when the cover sheet is peeled off from the image-receiving sheet.Type: GrantFiled: September 28, 1990Date of Patent: March 3, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Tamotsu Suzuki, Tomizo Namiki, Masashi Katayama
-
Patent number: 5087549Abstract: Provided are multilayer, tonable peel-apart photosensitive elements which include an esterified polyol plasticizer in the photoadherent layer, together with processes for their use for preparing pre-press color proofs.Type: GrantFiled: October 19, 1990Date of Patent: February 11, 1992Assignee: E. I. Du Pont de Nemours and CompanyInventor: Robert W. Peiffer
-
Patent number: 5085969Abstract: An image-receiving sheet material to be used for the formation of a transferred image by transferring a transferable image formed on an image-forming layer of a photo-sensitive material onto the image-receiving sheet material and then retransferring the image onto a permanent substrate, as well as a process for the formation of a transferred image with the use of the image-receiving sheet material are disclosed.Type: GrantFiled: March 16, 1990Date of Patent: February 4, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Tomizo Namiki, Tamotsu Suzuki, Fumiaki Shinozaki