Using Specified Radiation-sensitive Composition Other Than A Nominal Sensitized Polyvinyl Alcohol Patents (Class 430/28)
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Patent number: 5858616Abstract: Disclosed are a photosensitive resin composition which comprises:(A) a compound having a carboxyl group;(B) a resin having a carboxyl group;(C) a photopolymerizable unsaturated compound having an ethylenic unsaturated group;(D) a photopolymerization initiator which produces free radical by irradiation of active light; and(E) a phosphor,a photosensitive film and a process for preparing a fluorescent pattern using the same, and a phosphor subjected to surface treatment and a process for preparing the same.Type: GrantFiled: October 11, 1996Date of Patent: January 12, 1999Assignee: Hitachi Chemical Company, Ltd.Inventors: Hiroyuki Tanaka, Hideyasu Tsuiki, Takeshi Nojiri, Koichi Kamijima, Seiji Tai, Seikichi Tanno, Hajime Kakumaru
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Patent number: 5853928Abstract: A method for electrophotographically forming a Braun tube's fluorescent layer coats conductive and photoconductive layers on the internal surface of a Braun tube's panel. The photoconductive layer is formed of a water soluble photoconductive liquid including a water soluble binder, allowing a part of the photoconductive layer to be selectively exposed to a visible ray. The photoresist of the above photoconductive liquid is substituted with dye, which can be processed through general exposure and solvent, allowing the fluorescent layer to be formed on a Braun tube under the same conditions as a typical Braun tube production process without darkroom processing.Type: GrantFiled: December 18, 1995Date of Patent: December 29, 1998Assignee: Samsung Display Devices Co., Ltd.Inventor: Min-Ho Kim
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Patent number: 5849442Abstract: A new method for forming an anode plate for a color flat panel Field Emission Displays (FEDs) having improved gettering, was accomplished. The method involves forming on a transparent insulating plate (glass) an array of pixels of three phosphors comprising the primary colors and having in or/and around the array of pixels gettering material to provide more efficient gettering of volatile material from the FED cavity. The electrons are injected into the pixels when the electron field emitters are electrically accessed via the address and image forming circuits. The injected electrons heat and activate the gettering material in and around the pixels and provide very effective gettering in the FED cavity.Type: GrantFiled: August 18, 1997Date of Patent: December 15, 1998Assignee: Industrial Technology Research InstituteInventors: David Nan-Chou Liu, Jammy Chin-Ming Huang, Jyh-Haur Tyan
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Patent number: 5840450Abstract: The black matrix of the faceplate panel is deposited by a wet-layer photoconductive manner. An organic conductive layer is initially deposited on the faceplate panel, on which an organic photoconductive material is formed to form an organic photoconductive layer. The photoconductive layer is charged to positive or negative potential and a selective area of the organic photoconductive layer is exposed to light radiated from an exposure device, such that the potential can be left on the unexposed area, where the black matrix will be deposited, of the organic photoconductive layer. Then, As novel steps, deposition of the conductive black matrix is achieved according to the following steps. First, a conductive black matrix material is charged having the opposite potential to that left on the unexposed area of the organic photoconductive layer.Type: GrantFiled: December 24, 1996Date of Patent: November 24, 1998Assignee: Samsung Display Devices Co., Ltd.Inventor: Jong-ho Cho
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Patent number: 5837407Abstract: In a method forming a phosphor layer on a screen panel, the black matrix is made of a conductive material. The conductive black matrix is formed by a wet-layer photoconductive method. That is, an organic conductive layer is initially deposited on the screen panel, then an organic photoconductive material is formed on the organic conductive layer. The plotoconductive layer is charged to a positive or negative potential and a selective area of the organic photoconductive layer is exposed to light radiated from an exposure device, such that the potential can be left on the unexposed area where the black matrix will be deposited. Finally, the conductive black matrix material is deposited on the unexposed area.Type: GrantFiled: February 12, 1997Date of Patent: November 17, 1998Assignee: Samsung Display Devices Co., Ltd.Inventors: Jong-ho Cho, Choong-lak Kim
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Patent number: 5834144Abstract: Styrene-acrylic copolymer is used as an organic binder, fluorenone derivative is used as an electron receptor and tetraphenylbutadiene derivative is used as an electron donor to produce a color display panel which has a low decomposition temperature, a high electron transferring ability and a charge maintenance ability to manufacture a color display panel without a change of brightness and color coordinates in a fluorescent screen.Type: GrantFiled: September 23, 1997Date of Patent: November 10, 1998Assignee: Samsung Display Devices Co., Ltd.Inventors: Min Ho Kim, Wan Woo Park
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Patent number: 5827628Abstract: The method of electrophotographically manufacturing a screen on an interior surface of a faceplate for a CRT, according to the present invention comprises the steps of first-coating the faceplate with a volatilizable conductive layer, second-coating the conductive layer with the first photoconductive layer including a dye sensitive to ultraviolet rays, third-coating the ultraviolet-photoconductive layer with a second photoconductive layer including a dye sensitive to visible light, charging the whole area of the second photoconductive layer by exposing the whole surface of the second photoconductive layer to visible light while applying a suitable DC voltage between the conductive layer and the second photoconductive layer, and exposing selected areas of said first photoconductive layer to ultraviolet rays through a shadow mask to discharge the charge from the selected areas of the first photoconductive layer. Then, in developing a uniform density of the screen structure material is obtained.Type: GrantFiled: March 11, 1997Date of Patent: October 27, 1998Assignee: Orion Electric Co., Ltd.Inventors: Dong Ky Shin, Bok Soo Lee, Sang Youl Yoon
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Patent number: 5750296Abstract: A photo-conductive composition and CRT bulb having a photo-conductive layer formed of the same are provided. The photo-conductive composition comprises 5-15 wt % of a charge transmitting substance, represented by the structural formula (1); ##STR1## where R.sub.1 is selected from the group consisting of a phenyl group substituted by one to three substituents selected from the group consisting of amino, dialkylamino, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkyl and cyano groups; 9-alkyl carbazole group; naphthyl group, and R.sub.2 and R.sub.3 are same or different independently from each other, each being selected from the group consisting of hydrogen and C.sub.1 -C.sub.6 alkyl, phenyl and naphthyl groups, and n is between 0 and 2; 1-15 wt % of a charge generating substance which absorbs light in the wavelength range of an ultraviolet region; 70-94 wt % of a binder; and 0.05-1 wt % of a surfactant.Type: GrantFiled: August 14, 1996Date of Patent: May 12, 1998Assignee: Samsung Display Devices Co., Ltd.Inventors: Min-ho Kim, Bong-mo Jeong, Jae-ho Shim, Wan-woo Park, Deuk-yong Yang
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Patent number: 5750295Abstract: A light fixing layer is deposited on the panel during the screening process of a panel. The light fixing layer can be softened when it is subjected to light so as to allow the phosphor layers to be fixed on the panel. That is, the light fixing layer shows adhesive characteristics when subjected to light. Therefore, after developing all phosphor layers on the panel, when the light is radiated to the light fixing layer, the light fixing layer is softened, thereby fixing the phosphor layers.Type: GrantFiled: February 13, 1997Date of Patent: May 12, 1998Assignee: Samsung Display Devices Co., Ltd.Inventors: Choong-lak Kim, Jong-ho Cho
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Patent number: 5725978Abstract: The improved water-soluble photosensitive resin composition comprises a high-polymer compound represented by the general formula(I): ##STR1## (where X is Na, K or NH.sub.4) and a water-soluble polymer which is either polyvinylpyrrolidone or a copolymer of vinylpyrrolidone and vinylimidazole or both. The composition is applied to a substrate, exposed through a mask pattern and developed to form a photocured pattern and, thereafter, a light absorber is applied to the entire surface of the substrate and dried, followed by stripping away the photocured pattern and the overlying light absorber to form a black matrix pattern. The composition is suitable for use as a photoresist in the manufacture of black matrices as on color CRTs and capable of efficient formation of photocured patterns with high sensitivity by shorter times and lower intensities of exposure. In addition, the composition adheres strongly to glass substrates and is capable of pattern formation as thin film that is faithful to the mask pattern used.Type: GrantFiled: January 24, 1996Date of Patent: March 10, 1998Assignees: BASF Aktiengesellschaft, Toyo Ohka Kogyo Co., Ltd.Inventor: Shozo Miyazawa
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Patent number: 5693438Abstract: A new method for forming an anode plate for a color flat panel Field Emission Displays (FEDs) having improved gettering, was accomplished. The method involves forming on a transparent insulating plate (glass) an array of pixels of three phosphors comprising the primary colors and having in or/and around the array of pixels gettering material to provide more efficient gettering of volatile material from the FED cavity. The electrons are injected into the pixels when the electron field emitters are electrically accessed via the address and image forming circuits. The injected electrons heat and activate the gettering material in and around the pixels and provide very effective gettering in the FED cavity.Type: GrantFiled: March 16, 1995Date of Patent: December 2, 1997Assignee: Industrial Technology Research InstituteInventors: David Nan-Chou Liu, Jammy Chin-Ming Huang, Jyh-Haur Tyan
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Patent number: 5578657Abstract: Disclosed herein are adhesive compositions for use in cathode ray tubes comprising a specified epoxy (meth)acrylate, hydroxyl-containing mono (meth)acrylate, a photopolymerization initiator and optionally an urethane (meth)acrylate, the cured products thereof as well as cathode ray tubes obtained by the use thereof. The adhesive compositions of the present invention are excellent in spreadability and the resulting cured products have a good adhesion to glass. Cathode ray tubes in which a sheet of film is bonded to panel-glass by using an adhesive of the present invention exhibit satisfactory screen states comparable to those exhibited by cathode ray tubes subjected to a polishing process.Type: GrantFiled: May 11, 1995Date of Patent: November 26, 1996Assignees: Sony Corporation, Nippon Kayaku Kabushiki KaishaInventors: Takuji Inoue, Tsunenari Saito, Kenji Nakayama, Hiroe Ito, Minoru Yokoshima
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Patent number: 5569571Abstract: A process for preparing a black matrix comprising the steps of producing a developed substrate by coating, drying, exposing and developing a photoresist on the inside of a substrate, producing a dried substrate by drying the developed substrate several times, coating a dye on the dried substrate and then drying the board, coating graphite on the dried substrate, and etching the graphite-coated substrate. This method makes it possible to perfectly etch the black matrix dot and increase volatility in fluorescent coating.Type: GrantFiled: June 6, 1995Date of Patent: October 29, 1996Assignee: Samsung Display Devices Co., Ltd.Inventors: Ik-Cheol Lim, Su-Yeon Cho, Seung-Joon Yoo
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Patent number: 5554468Abstract: In accordance with the present invention, a method of electro-photographically manufacturing a luminescent screen assembly on an interior surface of a faceplate panel 12 for a color CRT 10 includes the steps of coating the interior surface of the faceplate panel with a volatilizable, organic conductive solution to form an organic conductive (OC) layer 32, and overcoating the OC layer with a volatilizable, organic photoconductive solution to form an organic photoconductive (OPC) layer 34. The step of overcoating the OC layer to form the OPC layer is improved by the substeps of: grounding the OC layer; providing an organic photoconductive (OPC) solution comprising a resin, an electron donor material and electron acceptor material, and a suitable solvent; and spraying electrostatically-charged droplets of the OPC solution onto the OC layer, with at least one electrostatic spray gun 47, to provide an OPC layer, having uniform thickness, overlying the OC layer.Type: GrantFiled: April 27, 1995Date of Patent: September 10, 1996Assignee: Thomson Consumer Electronics, Inc.Inventors: Pabitra Datta, Eugene S. Poliniak, Brian T. Collins, Harry R. Stork, Peter M. Ritt, Edward R. Garrity, Jr., Richard LaPeruta, Jr., George M. Ehemann, Jr.
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Patent number: 5498498Abstract: Disclosed is a photosensitive resin composition for use in a light-shielding film, comprising a photosensitive resin and a light-shielding coloring material, wherein light transmission properties after formation of the light-shielding film are controlled by the light-shielding coloring material so that (i) the light transmission through the light-shielding film is 1% or more in at least one wavelength of a light wavelength region of from 330 nm to less than 425 nm, and (ii) the light transmission through the light-shielding film is 2% or less in a light wavelength region of from 425 to 650 nm.Type: GrantFiled: August 1, 1994Date of Patent: March 12, 1996Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Kiyoshi Uchikawa, Hiroshi Komano, Toshimi Aoyama, Katsuyuki Ohta
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Patent number: 5476737Abstract: A phosphor screen (10) formed of respective color phosphor layers (9R), (9G), (9B) and respective color filter layers (4R), (4G), (4B) is formed on the inner surface of the panel (1). In that case, the respective color filter layers (4R), (4G), (4B) are respectively formed between the inner surface of the panel (1) and the phosphor layers (9R), (9G) and (9B). Therefore, the color cathode ray tube can be made high in contrast and in brightness.Type: GrantFiled: August 19, 1994Date of Patent: December 19, 1995Assignee: Sony CorporationInventors: Tsuneo Kusunoki, Norihiro Tateyama, Katsutoshi Ohno
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Patent number: 5474866Abstract: In accordance with the present invention, a method of electrophotographically manufacturing a luminescent screen assembly for a color CRT 10 on an interior surface of a faceplate panel 12 is described. A volatilizable organic conductive (OC) layer 32 is provided on the interior surface of the panel and a volatilizable organic photoconductive (OPC) layer 34 overlies the OC layer 32.Type: GrantFiled: August 30, 1994Date of Patent: December 12, 1995Assignee: Thomson Consumer Electronics, Inc.Inventors: Peter M. Ritt, Harry R. Stork, Brian T. Collins, Pabitra Datta, Nitin V. Desai, Eugene S. Poliniak
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Patent number: 5474867Abstract: In accordance with the present invention, a method of electro-photographically manufacturing a luminescent screen assembly for a color CRT 10 on an interior surface of a faceplate panel 12 is described. A volatilizable, organic conductive (OC) layer 32 is provided on the interior surface of the panel and a volatilizable, organic photoconductive (OPC) layer 34 overlies the OC layer. The method includes the steps of: establishing a substantially uniform electrostatic charge on the OPC layer; exposing selected areas of the OPC layer to visible light to affect the charge thereon; developing the selected areas of the OPC layer with a triboelectrically charged dry-powdered, screen structure materials; fixing the screen structure materials to the underlying OPC layer with a suitable fixative; filming the screen structure materials; aluminizing the screen; and baking the aluminized screen.Type: GrantFiled: September 16, 1994Date of Patent: December 12, 1995Assignee: Thomson Consumer Electronics, Inc.Inventors: Peter M. Ritt, Charles M. Wetzel, Harry R. Stork, John J. Moscony
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Patent number: 5455132Abstract: In accordance with the present invention, a method of electrophotographically manufacturing a luminescent screen assembly on a photoreceptor disposed on an interior surface of a faceplate panel for a color CRT includes the steps of: charging the photoreceptor to establish a substantially uniform electrostatic voltage thereon; positioning the panel on an exposure device having a light source therein; exposing selected areas of the photoreceptor to visible light from the light source to affect the voltage thereon, without affecting the voltage on the unexposed area of the photoreceptor; and depositing a triboelectrically charged, first color-emitting phosphor onto the selected areas of the photoreceptor. The charging, positioning, exposing and depositing steps are repeated for a second and a third triboelectrically charged, color-emitting phosphor.Type: GrantFiled: May 27, 1994Date of Patent: October 3, 1995Assignee: Thomson Consumer Electronics, Inc.Inventors: Peter M. Ritt, Owen H. Roberts, Jr., Robert E. Kreider
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Patent number: 5455133Abstract: In accordance with the present invention, a method of electrophotographically manufacturing a luminescent screen assembly on an interior surface of a faceplate panel 12 of a color CRT 10 comprises the steps of coating the interior surface of the panel with a volatilizable, organic conductive material to form an organic conductive (OC) layer 32, and overcoating the OC layer 32 with a volatilizable, photoconductive material to form an organic photoconductive (OPC) layer 34. Then, a substantially uniform voltage is established on the OPC layer 34, and selected areas of the OPC layer 34 are exposed to visible light to affect the voltage thereon, without affecting the voltage on the unexposed area of the OPC layer 34. Next, triboelectrically charged, light-absorbing screen structure material is deposited onto the unexposed area of the OPC layer 34 to form a substantially continuous matrix 23 of light-absorbing material having open areas therein.Type: GrantFiled: August 30, 1994Date of Patent: October 3, 1995Assignee: Thomson Consumer Electronics, Inc.Inventors: Istvan Gorog, Peter M. Ritt
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Patent number: 5413885Abstract: The method of electrophotographically manufacturing a screen assembly on an interior surface of a faceplate panel for a color CRT, according to the present invention includes the step of forming a photoreceptor by sequentially coating the surface of the panel with a conductive solution to form a volatilizable conductive layer and then overcoating the conductive layer with an organic photoconductive solution comprising a suitable resin, an electron donor material, an electron acceptor material, a surfactant and an organic solvent to form a volatilizable photoconductive layer.Type: GrantFiled: December 22, 1993Date of Patent: May 9, 1995Assignee: RCA Thompson Licensing Corp.Inventors: Pabitra Datta, Nitin V. DeSai, Eugene S. Poliniak, Ronald N. Friel, Wilber C. Stewart
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Patent number: 5407765Abstract: The method of electrophotographically manufacturing a screen assembly on an interior surface of a viewing faceplate of a panel for a color CRT, according to the present invention, includes the steps of forming a volatilisable organic conductive layer on the interior surface of the viewing faceplate and overcoating the organic conductive layer with an organic photoconductive solution to form a volatilizable organic photoconductive layer. The conductive solution, comprising a polyelectrolyte and a diluent, is applied to the interior surface of the viewing faceplate by spraying, to form the conductive layer.Type: GrantFiled: December 22, 1993Date of Patent: April 18, 1995Assignee: Thomson Consumer Electronics, Inc.Inventors: Brian T. Collins, Harry R. Stork, Peter M. Ritt
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Patent number: 5405722Abstract: The invention relates to a method of electrophotographically manufacturing a luminescent screen assembly for a color CRT by utilizing materials whose volatilizable constituents are substantially completely baked-out in the same step in which the faceplate panel is frit sealed to the funnel of the tube envelope. This method eliminates a dedicated panel bake before frit sealing of the panel to the funnel.Type: GrantFiled: December 22, 1993Date of Patent: April 11, 1995Assignee: RCA Thomson Licensing Corp.Inventors: Pabitra Datta, Nitin V. DeSai, Ronald N. Friel, Eugene S. Poliniak
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Patent number: 5391444Abstract: At least partly overlapping patterns are formed on a substrate. The substrate is provided with a photosensitive layer which becomes tacky under the influence of light. The layer is exposed according to a pattern. A powder is provided on the exposed portions of the layer. The powder adheres to the exposed portions. Subsequently, the layer is again exposed according to a pattern which at least partly overlaps the first pattern. It has been found that a second powder adheres to the powder which has been provided first. In this manner, several powder layers can be provided on top or: each other on one photosensitive layer. This saves time.Type: GrantFiled: June 3, 1991Date of Patent: February 21, 1995Assignee: U.S. Philips CorporationInventor: Sebastianus N. G. Cuppen
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Patent number: 5370952Abstract: The method of electrophotographically manufacturing a screen assembly on an interior surface of a faceplate panel for a color CRT, according to the present invention, includes the steps of sequentially coating the surface of the panel with a conductive solution to form a volatilizable organic conductive layer and then overcoating the conductive layer with a photoconductive solution to form a volatilizable organic photoconductive layer. The conductive layer, comprising a quaternary ammonium polyelectrolyte and a surfactant, provides an electrode for the photoconductive layer and has improved electrical and physical properties compared to prior conductive layers.Type: GrantFiled: December 22, 1993Date of Patent: December 6, 1994Assignee: RCA Thomson Licensing Corp.Inventors: Pabitra Datta, Nitin V. DeSai, Ronald N. Friel, Eugene S. Poliniak
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Patent number: 5368991Abstract: Disclosed is a photosensitive resin composition for use in a light-shielding film, comprising a photosensitive resin and a light-shielding coloring material, wherein light transmission properties after formation of the light-shielding film are controlled by the light-shielding coloring material so that (i) the light transmission through the light-shielding film is 1% or more in at least one wavelength of a light wavelength region of from 330 nm to less than 425 nm, and (ii) the light transmission through the light-shielding film is 2% or less in a light wavelength region of from 425 to 650 nm.Type: GrantFiled: July 21, 1993Date of Patent: November 29, 1994Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Kiyoshi Uchikawa, Hiroshi Komano, Toshimi Aoyama, Katsuyuki Ohta
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Patent number: 5366834Abstract: In a cathode-ray tube phosphor, a layer consisting of a substantially uniform SiO.sub.2 film or an organic film consisting essentially of at least one type of a polymer selected from the group consisting of an acrylic resin, gelatin, alginic acid, chitosan, and a urea resin is formed as a first layer on the surface of a phosphor particle, and a layer containing at least one type of a metal selected from the group consisting of Zn, Al, and an alkali earth metal and at least one member selected from the group consisting of a colloidal silica, an alumina sol, and a titania sol each having a particle size of 50 nm or less is formed as a second layer on the first layer. This phosphor is excellent in oxidation resistance and dispersibility.Type: GrantFiled: May 5, 1993Date of Patent: November 22, 1994Assignee: Nichia Kagaku Kogyo K.K.Inventors: Masahiro Yoneda, Shoichi Bando, Ichiro Takeoka
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Patent number: 5340674Abstract: A luminescent screen assembly for a CRT is made by first coating the interior surface of a faceplate panel with a photoconductive layer which overlies a conductive layer. A multiplicity of red-, green- and blue-emitting phosphor screen elements are then deposited in color groups, in a cyclic order, onto the interior surface of the panel. A negative charge is then established on the photoconductive layer. The charge is weakened in the areas where the photoconductive layer underlies the phosphor screen elements, but unaffected in the open areas separating the phosphor screen elements. The charged, open areas of the photoconductive layer are discharged by flood illumination and reversal developed by depositing thereon particles of light-absorptive matrix material having a triboelectric charge of the same polarity as the charge established on the photoconductive layer. The novel process provides a high opacity matrix.Type: GrantFiled: March 19, 1993Date of Patent: August 23, 1994Assignee: Thomson Consumer Electronics, Inc.Inventors: John J. Moscony, George M. Ehemann, Jr.
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Patent number: 5340673Abstract: A method of forming a phosphor screen in which a color filter layer is formed between a phosphor layer and an inner surface of a panel having a slurry in which a fine particle pigment and transparent particles are dispersed into a photosensitive liquid coated on the inner surface of the panel. Then, the color filter layer is formed by exposure and development. When the color filter layer that constitutes one portion of a phosphor screen of a color cathode ray tube is formed in this manner, an adhesive force with which the color filter layer is bonded onto the panel can be increased and a transmittance of the color filter layer can be improved.Type: GrantFiled: March 22, 1993Date of Patent: August 23, 1994Assignee: Sony CorporationInventors: Norihiro Tateyama, Katsutoshi Ohno, Tsuneo Kusunoki
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Patent number: 5336575Abstract: A method of producing luminescent display screens for CRTs using meniscus coating to apply photosensitive slurries to the faceplate, thereby eliminating material waste, reducing particle contamination and improving coating uniformity.Type: GrantFiled: November 3, 1992Date of Patent: August 9, 1994Assignee: Zenith Electronics CorporationInventor: Hua-Sou Tong
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Patent number: 5326663Abstract: According to this invention, there is provided an improved method of manufacturing a shadow mask obtained by independently etching both the surfaces of a metal substrate. After one surface is etched to form a first opening, an etching resistive agent composition containing an acrylic resin, casein, and a leveling agent is applied to the obtained opening to form an etching resistive layer. Subsequently, the other surface is etched to form a second opening in the other surface, and then the etching resistive layer is removed to cause the first and second openings to communicate with each other.Type: GrantFiled: October 23, 1992Date of Patent: July 5, 1994Assignee: Kabushiki Kaisha ToshibaInventors: Hiroshi Tanaka, Makoto Kudou, Katsumi Ichikawa
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Patent number: 5290648Abstract: A method for manufacturing a screen for a cathode ray tube is provided comprising the steps of forming a first phosphor layer through coating a phosphor slurry containing a first phosphor, polyvinyl alcohol having a polymerization degree of 1,500 to 2,000 and distilled water on the inner surface of a panel, drying, exposing and developing the first phosphor layer, and then forming a second phosphor layer through coating a phosphor slurry containing a second phosphor, polyvinyl alcohol having a polymerization degree of 1,500 to 2,000 and distilled water on the surface of the first phosphor layer, drying, exposing and developing the second phosphor layer; wetting the surface of the first and second phosphor layers with distilled water; and forming a third phosphor layer through coating a phosphor slurry containing a third phosphor, polyvinyl alcohol having a polymerization degree of 500 to 600 and distilled water on the surface of the first and second phosphor layers, drying, exposing and developing the third pType: GrantFiled: July 29, 1992Date of Patent: March 1, 1994Assignee: Samsung Electron Devices Co., Ltd.Inventors: Min-ho Kim, Ik-cheol Lim
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Patent number: 5240798Abstract: A luminescent screen assembly for a CRT is made by first coating the interior surface of a faceplate panel with a photoconductive layer which overlies a conductive layer. A multiplicity of red-, green- and blue-emitting phosphor screen elements are then deposited in color groups, in a cyclic order, onto the interior surface of the panel. A substantially uniform charge is established on the photoconductive layer. The charge is weakened in the areas where the photoconductive layer underlies the phosphor screen elements, but unaffected in the open areas separating the phosphor screen elements. The charged open areas of the photoconductive layer are directly developed by depositing thereon particles of light-absorptive matrix material having a triboelectric charge opposite in polarity to the charge established on the photoconductive layer.Type: GrantFiled: January 27, 1992Date of Patent: August 31, 1993Assignee: Thomson Consumer ElectronicsInventor: George M. Ehemann, Jr.
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Patent number: 5229233Abstract: An apparatus for fusing a polymer powder deposited on a surface of a faceplate panel of a cathode-ray tube comprises a housing having a faceplate support surface and enclosing a chamber. A shutter adjacent to the panel support surface separates the faceplate panel from the chamber. A reservoir for holding a solvent is within the chamber and at least one piezoelectric transducer communicates with the reservoir for atomizing the solvent to create a fog. A fan within the chamber distributes the fog onto the polymer powder. A method for fusing the polymer powder onto the faceplate panel also is described.Type: GrantFiled: September 5, 1989Date of Patent: July 20, 1993Assignee: RCA Thomson Licensing Corp.Inventors: George H. N. Riddle, Robert E. Simms
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Patent number: 5229234Abstract: In an electrophotographic process for manufacturing a luminescent screen assembly on an interior surface of a faceplate panel of a CRT, the panel is first coated with a conductive layer and then overcoated with a photoconductive layer. A substantially uniform charge is established on the photoconductive layer. Selected areas of the photoconductive layer are exposed to actinic radiation, through a shadow mask, to affect the charge on the layer. The unexposed areas of the photoconductive layer are developed with triboelectrically-charged, dry-powdered, light-absorptive screen structure material. The photoconductive layer is reexposed to further discharge those open areas free of the light absorptive material while retaining the charge on those areas having light absorptive matrix material thereon. The reexposure increases the voltage contrast between the exposed and the unexposed areas of the photoconductive layer.Type: GrantFiled: January 27, 1992Date of Patent: July 20, 1993Assignee: RCA Thomson Licensing Corp.Inventors: George H. N. Riddle, Louis S. Cosentino
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Patent number: 5219704Abstract: Described is a process for improving a photo sensitive material of polyvinylpyrrolidone type by improving its chemical and ability to maintain a straight line property even after etching. The present invention proposes such that at least one of a nitrate, a sulfate or a hydrochloride of two or three valanced metal ions is added to polyvinylpyrrolidone in the ratio of 0.01 to 10% and then well stirred with the appropriate amount of an aqueous ammonia at the normal or room temperatures to obtain a pH of 7 to 10 thereby producing a metal hydroxide.Type: GrantFiled: December 20, 1991Date of Patent: June 15, 1993Assignee: Samsung Electron Devices Co., Ltd.Inventor: Youngdae Kim
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Patent number: 5190845Abstract: A photosensitive resin composition comprising:(a) a polymer dyeable with an anionic dye(b) an azide photosensitive compound, and(c) a compound having at least two acryloyl and/or methacryloyl groups in the same molecule thereof, and a color filter obtained by using the resin composition.Type: GrantFiled: May 8, 1989Date of Patent: March 2, 1993Assignee: Nippon Kayaku Kabushiki KaishaInventors: Matsuo Hashimoto, Nobuyuki Futamura, Sumio Yoda, Yoshifumi Saiki
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Patent number: 5173382Abstract: A photosensitive composition comprising a water-soluble polymer, a dichromate and at least one aromatic diazonium salt selected from aromatic diazonium sulfates, sulfonates and chromates has high sensitivity, and a pattern having high resolution can be formed therefrom with a shortened exposure time.Type: GrantFiled: January 9, 1990Date of Patent: December 22, 1992Assignee: Hitachi, Ltd.Inventors: Hajime Morishita, Nobuaki Hayashi, Saburo Nonogaki, Masato Ito, Masahiro Nishizawa, Kiyoshi Miura
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Patent number: 5151337Abstract: The method of electrophotographically manufacturing a luminescent screen on a substrate of a color CRT, according to the present invention, includes the steps of forming a photoreceptor by sequentially coating the substrate to form a conductive layer and an overcoating of a photoconductive layer, establishing an electrostatic charge on the photoconductive layer, and exposing selected areas of the photoconductive layer to visible light to affect the charge thereon. Then the photoconductive layer is developed by the application of suitable triboelectrically charged, dry-powdered screen structure materials. The improved process provides at least one wear-resistant, conductive contact patch on a peripheral portion of a surface of the substrate. The contact patch has a first portion which underlies at least one of the layers of the photoreceptor and is in electrical contact with the conductive layer, and a second portion which extends from the photoreceptor.Type: GrantFiled: June 26, 1990Date of Patent: September 29, 1992Assignee: RCA Thomson Licensing Corp.Inventors: Charles M. Wetzel, Peter M. Ritt, Owen H. Roberts, Jr., Harry R. Stork
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Patent number: 5147743Abstract: A process for the preparation of a color filter is described utilizing an exposure step of a light-sensitive material, imagewise exposing, toning and heat treating.Type: GrantFiled: June 28, 1990Date of Patent: September 15, 1992Assignee: E. I. Du Pont de Nemours and CompanyInventor: Mario Grossa
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Patent number: 5135826Abstract: The method of electrophotographically manufacturing a luminescent screen assembly on a substrate for use within a CRT, according to the present invention, includes the steps of: forming a conductive layer on the substrate; overcoating the conductive layer with a photoconductive solution comprising an organic polymeric material, a suitable photoconductive dye, a plasticizer and a solvent to form a photoconductive layer; and, then, establishing an electrostatic charge on the photoconductive layer. Selected areas of the photoconductive layer are exposed to visible light to affect the charge thereon, and the photoconductive layer is developed with charged screen structure material. The improved method utilizes a dialkyl phthalate plasticizer which is selected from the group consisting of dibutylphthalate (DBP), dioctylphthalate (DOP), and diundecylphthalate (DUP).Type: GrantFiled: April 29, 1991Date of Patent: August 4, 1992Assignee: RCA Thomson Licensing Corp.Inventors: Peter M. Ritt, Harry R. Stork, Pabitra Datta
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Patent number: 5134047Abstract: In a method of manufacturing a color cathode ray tube utilizing an external surface exposure process, a fluorescent slurry to be applied to a panel contains a photosensitive resin composition composed of an aqueous emulsion of polyvinyl compound resin containing a saponified polyvinyl acetate with an addition-condensed photosensitive group as a protective colloid and an aqueous solution of a saponified polyvinyl acetate with an addition-condensed photosensitive group. Accordingly, a resistance of a fluorescent layer formed on the panel against an aqueous solution of hydrogen peroxide is improved, and an anti-fogging performance of the fluorescent layer is also improved.Type: GrantFiled: April 12, 1990Date of Patent: July 28, 1992Assignee: Sony CorporationInventors: Koki Inada, Hiroshi Itoh, Hideaki Takazawa, Tadashi Asazuma
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Patent number: 5108858Abstract: The present invention relates to a method for making a viewing screen structure for a cathode-ray tube. The method includes the steps of coating a support surface with a film of a polymeric material, a suitable dichromate and a sensitizer therefor which is a chromium ion migration enhancer having a reduced sensitivity to thermal and dark hardening; exposing the film to an image in the form of radiant energy until the solubility of the irradiated regions thereof is selectively altered, thereby producing in the film regions of greater solubility and regions of lesser solubility; removing those regions of the film with greater solubility to bare portions of the underlying support surface while retaining those regions of the film with lesser solubility. The bare portions of the support surface and the retained film regions are overcoated with a composition of light-absorbing material which is adherent to the support surface.Type: GrantFiled: August 13, 1990Date of Patent: April 28, 1992Assignee: VideocolorInventors: Himanshu M. Patel, Antimo Pezzulo
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Patent number: 5093217Abstract: An apparatus for electrophotographically manufacturing a luminescent screen assembly on a substrate for use within a CRT includes a developer for developing a photoconductive layer, having a latent image thereon, with a dry-powdered, triboelectrially-charged screen structure materials. The photoconductive layer overlies a conductive layer in contact with the substrate. A grid-developing electrode is located at a distance from the photoconductive layer that is large relative to the smallest dimension of the latent image. The electrode is biased with a suitable potential to influence the deposition of the charged screen structure materials onto the latent image on the photoconductive layer. A method for electrophotographically manufacturing the screen assembly utilizing the grid-developing electrode is also disclosed.Type: GrantFiled: October 11, 1989Date of Patent: March 3, 1992Assignee: RCA Thomson Licensing CorporationInventors: Pabitra Datta, Randall E. McCoy, Ronald N. Friel, John A. van Raalte, Wilber C. Stewart
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Patent number: 5073463Abstract: A method of manufacturing a phosphor screen for a cathode ray tube comprises the step of forming a suspension of a phosphor material and a resin particle having an average particle size of 0.5 to 20 micrometers in an aqueous solution containing a photosensitive resin, a dispersing agent and a binder; coating an inner surface of a cathode ray tube with the suspension to form a phosphor screen; then forming an intermediate layer on the phosphor screen; then forming a metal back layer on the intermediate film; and finally baking the whole product so that the brightness of the phosphor screen of the cathode ray tube can be increased.Type: GrantFiled: September 12, 1989Date of Patent: December 17, 1991Assignee: Sony CorporationInventor: Koji Fujita
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Patent number: 5028501Abstract: In accordance with the present invention, a method of manufacturing a luminescent screen assembly on a substrate of a CRT includes the steps of providing a coating of a non-luminescent screen structure material in a predetermined pattern on the substrate and depositing a plurality of color-emitting screen structure materials on the substrate. The color-emitting screen structure materials are surrounded by the non-luminescent material. An electrostatically-charged dry-powdered resin is deposited onto the aforementioned color-emitting and non-luminescent screen structure materials and fused to form a substantially continuous film.Type: GrantFiled: June 14, 1989Date of Patent: July 2, 1991Assignee: RCA Licensing Corp.Inventors: Peter M. Ritt, Harry R. Stork
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Patent number: 5002844Abstract: Photoresist for forming the phosphor screen of color cathode-ray tube made up of the composition rate of pure water 10-50%, polyvinyl alcohol 5-30%, dichromate potassium salt 0.5-5%, diethylene glycol 0.5-10%, ethylene glycol 0.5-5%, urea 0.5-10%, acetamide 0.5-5%, butanediol 0.5-10%, paraaldehyde 0.5-5%, dioxane 0.5-5%, a surfactant 0.5-5%.Type: GrantFiled: August 31, 1988Date of Patent: March 26, 1991Assignee: Samsung Electron Devices Co., Ltd.Inventors: Won-Dae Cheong, Sang-Yul You, Soo-Min Jeong
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Patent number: 4990417Abstract: A method for forming a phosphor pattern on a panel of a cathode ray tube to prevent the peeling of a black matrix from the glass panel when treated with an inversion solvent which involves forming a protective film of a transparent photosensitive material on a glass panel on which a black matrix is formed and using the so-called outer surface exposure method to produce a color cathode ray tube having high definition.Type: GrantFiled: November 13, 1989Date of Patent: February 5, 1991Assignee: Sony CorporationInventors: Koki Inada, Norihiro Tateyama
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Patent number: 4954418Abstract: A photoresist film containing a phosphate of a formalin condensate of diazodiphenylamine, 2.5-bis(4'-azide-2'-sulphobenzilidene) cyclopentanone Na, polyvinylalcohol, and polyvinylpyrrolidone is formed on the inner surface of a faceplate. The photoresist film is hardened by light exposure using a point or linear light source, which is essentially a circular light source, via a shadow mask having a large number of apertures. A light absorbing film is formed on this photoresist film. Then the hardened photoresist film and the light absorbing film on top of it are removed using a peeling agent.Type: GrantFiled: May 31, 1989Date of Patent: September 4, 1990Assignee: Kabushiki Kaisha ToshibaInventor: Norio Koike
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Patent number: 4943512Abstract: A photocurable resin composition is described, which comprises a specific type of photosensitive polymer obtained by copolymerization of a monomer of the following general formula [I] ##STR1## in which R.sup.1 represents H, CH.sub.3 or C.sub.2 H.sub.5, X represents --O-- or --NH--, Y represents a linear or branched hydrocarbon group having from 1 to 4 carbon atoms, and .PHI. represents ##STR2## Z.sup..crclbar., in which Z.sup..crclbar. represents an anion, and R.sup.2, R.sup.3 and R.sup.4 are independently an alkyl group having from 1 to 4 carbon atoms, and a monomer of the following general formula [II] ##STR3## in which R.sup.5 represents H, CH.sub.3 or C.sub.2 H.sub.5, and n and x are independently an integer of from 1 to 4. The photosensitive polymer is photocrosslinked with a diazide compound. The resin composition is particularly suitably for use in formation of a color filter because of good dyeability and good adhesion to a substrate.Type: GrantFiled: October 4, 1988Date of Patent: July 24, 1990Assignee: Chisso CorporationInventors: Hiroshi Kawabata, Katsuhiko Kobayashi, Hideo Sato