Color Development Patents (Class 430/351)
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Patent number: 4985346Abstract: A photo and heat sensitive recording medium has a front side coated with a layer of photo-curable composition which has photo-curability and heat fusibility in an uncured state. In an image recording method, the recording medium is exposed to light on the basis of image information, to photo-cure light-illuminated areas of the layer of photo-curable composition. Subsequently, the recording medium is superimposed upon a side of a subject being transferred. The superimposed recording medium and subject are heated to transfer an image corresponding to uncured areas on the recording medium, onto the side of the subject.Type: GrantFiled: February 23, 1989Date of Patent: January 15, 1991Assignee: Brother Kogyo Kabushiki KaishaInventor: Kouji Suzuki
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Patent number: 4983494Abstract: An image is formed in a photographic element by a process comprising a step of heating a heat-developable photosensitive material in the presence of a specific compound which typically releases a phenylmercaptotetrazole having a substituted benzene ring and serving as a development retarder.Type: GrantFiled: October 18, 1989Date of Patent: January 8, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Kitaguchi, Masatoshi Kato
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Patent number: 4980261Abstract: An image-forming method which comprises:imagewise exposing a light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support to form a latent image of the silver halide;simultaneously or thereafter developing the light-sensitive material to polymerize the polymerizable compound within the area where the latent image of the silver halide has been formed; andpressing the light-sensitive material on an image-receiving material having a porous support which has such a surface characteristic that a filtered maximum waviness of not less than 4 .mu.m is observed in not more than 10 positions among 100 positions which are determined at random on a filtered waviness curve, to transfer the unpolymerized polymerizable compound to the image-receiving material.The filtered maximum waviness is determined within basic length of 2.Type: GrantFiled: September 26, 1988Date of Patent: December 25, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Makoto Yamada
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Patent number: 4960681Abstract: A process for forming an image comprising heating a heat-developable light-sensitive material comprising a support having thereon at least a light-sensitive silver halide and a high molecular weight compound containing a repeating unit derived from a vinyl monomer having at least one of a group -COOM and a group -SO.sub.3 M wherein M represents a hydrogen atom or an alkali metal atom, simultaneously with or after imagewise exposure thereof in the presence of water and at least one of a base and a base precursor.Type: GrantFiled: March 9, 1990Date of Patent: October 2, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Yasuo Aotsuka
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Patent number: 4957848Abstract: A heat-developable color light-sensitive material is disclosed, comprising a support having thereon at least one layer containing a light-sensitive silver halide, a binder, a compound containing a color moiety represented by formula (A), and a compound or a precursor thereof which reacts with an oxidized compound formed from the compound of formula (A), thereby converting the oxidized compound into a nondiffusible form, said compound of formula (A) being represented by ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 each represents a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group, an aralkyl group, an alkoxy group, an aryloxy group, an acylamino group, an alkylthio group, an arylthio group, or a halogen atom, provided that at least one of R.sub.1, R.sub.2, and R.sub.Type: GrantFiled: May 10, 1988Date of Patent: September 18, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Osamu Takahashi, Koichi Koyama, Keizo Koya
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Patent number: 4952969Abstract: A method for forming an image by the steps of:(a) imagewise exposing a heat-developable color light-sensitive material;(b) uniformly exposing at least a portion of the heat-developable light-sensitive material; and(c) heat developing the imagewise exposed and uniformly exposed heat-developable light-sensitive material to form a color image.Type: GrantFiled: January 2, 1990Date of Patent: August 28, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroshi Hara
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Patent number: 4950584Abstract: The method of processing a heat-processable color photosensitive material is disclosed. The photosensitive material comprises a support, provided thereon, a photosensitive layer containing a photosensitive silver halide, a dye-donor, a reducing agent and a binder, and a non-photosensitive layer containing at least a binder, wherein a coupler capable of coupling with an oxydized product of the reducing agent to form a substantially colorless product is contained in at least one of the photosensitive layer and the non-photosensitive layer, and is represented by Formula (1); ##STR1## wherein R represents one selected from the group consisting of an alkyl group and an aryl group; and X represents a group of the atoms necessary to form a 5- or 6-membered heterocyclic ring containing at least one selected from the group consisting of nitrogen, sulfur and oxygen.Type: GrantFiled: November 29, 1988Date of Patent: August 21, 1990Assignee: Konica CorporationInventors: Tawara Komamura, Masaru Tsuchiya, Ken Okauchi
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Patent number: 4927730Abstract: A light-sensitive material comprising a light-sensitive layer containing silver halide, a reducing agent, a polymerizable compound and a color image forming substance provided on a support, characterized in that the color image forming substance is a triazene compound having the following formula: ##STR1## in which Ar is an aryl group or a heterocyclic group, each of which may have one or more substituent groups; each of R.sup.1 and R.sup.2 independently is a group selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an aralkyl group, an alkenyl group, an aryl group and a heterocyclic group, each of which may have one or more substituent groups, or R.sup.1 and R.sup.2 form, together with the neighboring nitrogen, a heterocyclic group which may have one or more substituent groups; and n is 1, 2 or 3. An image forming method utilizing the light-sensitive material is also disclosed.Type: GrantFiled: April 27, 1987Date of Patent: May 22, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Kazo Sato
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Patent number: 4923792Abstract: A photothermographic element comprising:(A) a coating comprising a support bearing a photothermographic medium, the medium comprising a light sensitive silver halide in reactive association with a silver salt of an organic acid and a color generating reducing agent which is a leuco compound which is oxidizable by silver ions into a colored dye of the general formula: ##STR1## in which: n=0, 1 or 2,R.sup.1 represents H, CN, lower alkyl of 1 to 5 carbon atoms, aryl or COOR.sup.6 in which R.sup.6 is lower alkyl of 1 to 5 carbon atoms or aryl,R.sup.2 and R.sup.3 independently represent CN, NO.sub.2, COOR.sup.6, SO.sub.2 R.sup.6, CONHR.sup.6 in which R.sup.6 is as defined above or R.sup.2 and R.sup.3 together represent the necessary atoms to form a 5- or 6-membered carbocyclic or heterocyclic ring having ring atoms selected from C, N, O and S atoms, whch carbocyclic or heterocyclic rings possess at least one conjugated electron withdrawing substituent,R.sup.4 and R.sup.Type: GrantFiled: June 20, 1989Date of Patent: May 8, 1990Assignee: Minnesota Mining and Manufacturing CompanyInventors: Duncan M. A. Grieve, Stephen S. C. Poon, Tran V. Thien, Kumars Sakizadeh, David C. Weigel
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Patent number: 4904573Abstract: A method for forming an image by the steps of:(a) imagewise exposing a heat-developable color light-sensitive material;(b) uniformly exposing at least a portion of the heat-developable light-sensitive material; and(c) heat developing the imagewise exposed and uniformly exposed heat-developable light-sensitive material to form a color image.Type: GrantFiled: November 10, 1988Date of Patent: February 27, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroshi Hara
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Patent number: 4891299Abstract: An image-forming method which comprises: imagewise exposing a light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support to form a latent image of the silver halide; simultaneously or thereafter developing the light-sensitive material to polymerize the polymerizable compound within the area where the latent image of the silver halide has been formed; and pressing the light-sensitive material on an image-receiving material having a transparent support to transfer the obtained image to the image-receiving material.Type: GrantFiled: March 11, 1987Date of Patent: January 2, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Makoto Yamada
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Patent number: 4883747Abstract: A photothermographic element comprising a support bearing a photothermographic medium, the medium comprising a light sensitive silver halide in reactive association with a silver salt of an organic acid and a color generating reducing agent which is a leuco compound which is oxidisable by silver ions into a colored dye of the general formula: ##STR1## in which: n=0, 1 or 2,R.sup.1 represents H, CN, lower alkyl of 1 to 5 carbon atoms, aryl or COOR.sup.6 in which R.sup.6 is lower alkyl of 1 to 5 carbon atoms or aryl,R.sup.2 and R.sup.3 independently represent CN, NO.sub.2, COOR.sup.6, SO.sub.2 R.sup.6, CONHR.sup.6 in which R.sup.6 is as defined above or R.sup.2 and R.sup.3 together represent the necessary atoms to form a 5- or 6-membered carbocyclic or heterocyclic ring having ring atoms selected from C, N, O and S atoms, which carbocyclic or heterocyclic rings possess at least one conjugated electron withdrawing substituent,R.sup.4 and R.sup.Type: GrantFiled: May 31, 1988Date of Patent: November 28, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Duncan M. A. Grieve, Stephen S. C. Poon, Tran V. Thien, Kumars Sakizadeh, David C. Weigel
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Patent number: 4880725Abstract: A color image is formed by imagewise exposing a color photosensitive material comprising at least a silver halide and a coupler and subjecting the material to intensified development with a processing solution containing a reducing agent and an intensifier. A substantially water-insoluble basic metal compound is previously contained in the silver halide based color photosensitive material, while the processing solution contains a compound capable of complexing reaction with the metal ion of the substantially water-insoluble basic metal compound to release a base.Type: GrantFiled: December 27, 1988Date of Patent: November 14, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Haruhiko Iwano
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Patent number: 4868097Abstract: A color image is formed by imagewise exposing a photosensitive material comprising at least (a) a photosensitive silver halide, (b) a binder, (c) a dye-providing substance which forms or releases a diffusible dye in response or counter-response to the reduction of the silver halide into silver at elevated temperatures, and (d) a specific-surface-active agent on a support, and heat developing the photosensitive material to form an image.Type: GrantFiled: April 25, 1988Date of Patent: September 19, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuo Aotsuka, Masatoshi Kato, Masakazu Yoneyama
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Patent number: 4868098Abstract: The processing of exposed silver dye bleach materials by applying, to the uppermost layer of the material, an amount of processing liquid which corresponds to not more than the swelling volume of the material, followed by a heat treatment.The process is particularly suitable for the production of positive colored images, especially in automatic copying or photographing machines.Type: GrantFiled: January 5, 1988Date of Patent: September 19, 1989Assignee: Ciba-Geigy AGInventors: Rolf Steiger, Urs J. Furholz
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Patent number: 4859580Abstract: A heat-developable photosensitive material having, on a support, a layer comprising a binder, a light-sensitive silver halide, a reducing agent, and at least one compound selected from cyclic imino compounds or mercapto compounds, which can produce images of high quality by heat development when said light-sensitive silver halide is selected from the group consisting of silver chloride, silver bromide, silver chlorobromide, mixed crystals of silver iodide and silver chloroiodide, mixed crystals of silver iodide and silver iodobromide, and mixed crystals of silver iodide and silver chloroiodobromide.Type: GrantFiled: March 29, 1988Date of Patent: August 22, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiaki Aono, Hiroshi Hara
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Patent number: 4847188Abstract: A thermally developable light-sensitive material having at least a light-sensitive silver halide, a reducing agent, a binder and a dye-providing material on a support is disclosed. The dye-providing material is a compound that releases or forms a diffusible dye as a function of development and which has a group capable of reacting with the nucleophilic agent.Type: GrantFiled: February 1, 1988Date of Patent: July 11, 1989Assignee: Konica CorporationInventors: Tawara Komamura, Hidenobu Ohya
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Patent number: 4839272Abstract: A heat-developable photosensitive material comprising (1) a silver halide emulsion, (2) a reducing agent, and (3) a binder on a support can be quickly heat developed to produce images having a high density and less fog by using the silver halide emulsion comprising an emulsion of silver halide grains having a distinct double-layered structure, that is, core/shell structure in the grain interior and an average grain size of at least 0.3 .mu.m in combination with (4) a specific compound of formula (I) or (II).Type: GrantFiled: March 27, 1987Date of Patent: June 13, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Hideki Ohmatsu, Hiroyuki Hirai
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Patent number: 4824759Abstract: A method for forming an image, which comprises heating a light-sensitive material in the presence of a compound capable of forming a 2-mercaptobenzazole ring by a ring closing reaction when heated.In accordance with the method of the present invention, development is stopped at an appropriate time of development whereby an image having a high maximum density and low fog is obtained.A heat-developable light-sensitive material containing the compound is also disclosed.Type: GrantFiled: February 7, 1986Date of Patent: April 25, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Hiroshi Kitaguchi, Masashi Takeuchi, Masaaki Tsukase, Masatoshi Kato
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Patent number: 4820622Abstract: An image is formed by imagewise exposing a heat-developable photosensitive material comprising (a) a photosensitive silver halide, (b) a reducing agent or a precursor thereof, (c) a dye-providing substance which forms or releases a diffusible dye in proportion or counter-proportion to the reduction of the silver halide into silver, and (d) a binder on a support, during or after the imagewise exposure of the photosensitive material, maintaining the photosensitive material in such a pH and a temperature lower than the heat-developing temperature for a predetermined time that the reaction between the silver halide and the reducing agent preferentially takes place rather than the reaction of forming or releasing a diffusible dye, and thereafter heat developing the exposed material in the presence of a base and/or a base precursor to imagewise produce a diffusible dye.Type: GrantFiled: April 8, 1988Date of Patent: April 11, 1989Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroyuki Hirai
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Patent number: 4795697Abstract: Alkyl ketazine dyes are stabilized by the presence of poly(vinyl chloride) and/or poly(vinylidene chloride) binders in photothermographic emulsions.Type: GrantFiled: December 29, 1986Date of Patent: January 3, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kim M. Vogel, David C. Weigel, Roger A. Mader
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Patent number: 4794069Abstract: Spirobenzanthracene phthalide compounds are disclosed of the formula (I) ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently represent C.sub.1 -C.sub.8 alkyl optionally substituted by C.sub.1 -C.sub.5 alkoxy; C.sub.5 or C.sub.6 cycloalkyl; or aralkyl or aryl optionally substituted by C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy, and R.sup.1 and R.sup.2, R.sup.3 and R.sup.4, and R.sup.5 and R.sup.6 taken together with the nitrogen atom to which they are attached, may form pyrrolidino, piperidino or morpholino ring, and R.sup.7, R.sup.8, R.sup.9 and R.sup.10 independently represent hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy or trifluoromethyl. The compounds are used, together with a developer, in color for materials such as pressure-sensitive copying papers, heat-sensitive recording papers and the like.Type: GrantFiled: July 14, 1987Date of Patent: December 27, 1988Assignee: Shin Nisso Kako Co., Ltd.Inventors: Yutaka Ohnishi, Shinji Yoshinaka, Toshiyuki Tanaka, Minoru Koguchi, Takeo Obitsu
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Patent number: 4792514Abstract: A light-sensitive material is described, comprising a support having provided thereon a light-sensitive layer containing at least a light-sensitive silver halide, a polymerizable compound, a color image forming substance, and a hydrazine derivative represented by formula (I): ##STR1## wherein R.sub.1 represents a monovalent group derived from a substituted or unsubstituted aromatic ring or aromatic heterocyclic ring; R.sub.2 and R.sub.3 each represents a substituted or unsubstituted aryl group; and R.sub.4 represents a hydrogen atom or a substituted or unsubstituted alkyl, aryl, alkoxycarbonyl, or carbamoyl group,in which the color image forming substance is immobilized by imagewise exposure to light followed by heat development under conditions substantially not containing water. The material exhibits high sensitivity and provides a color image through a simple, easy, and rapid dry processing step, with a reduced exposure time.Type: GrantFiled: October 10, 1986Date of Patent: December 20, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Taku Nakamura, Kozo Sato
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Patent number: 4789623Abstract: A method for forming an image comprising heating in the presence of at least one of a base and a base generating agent, a heat-developable color light-sensitive material which comprises a support having thereon at least: (1) a light-sensitive silver halide, (2) a coupler capable of coupling with an oxidation product of a developing agent, (3) a hydrophilic binder, and (4) at least one compound represented by formula (Z) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 each represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, a hydroxy group, an amino group, a substituted amino group, an alkoxy group, an acylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, an aryl group, a carbamoyl group, a substituted carbamoyl group, a sulfamoyl group, a substituted sulfamoyl group, an acyl group, an acyloxy group, or an alkoxycarbonyl group, or R.sub.1 and R.sub.2, or R.sub.3 and R.sub.Type: GrantFiled: December 3, 1986Date of Patent: December 6, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Hideki Naito
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Patent number: 4788134Abstract: The present invention provides a heat-developable photographic light-sensitive material comprising, on a support, at least containing a light-sensitive silver halide, a binder, a reducing agent, and an organic silver salt, wherein said organic silver salt is a silver salt of a pyrazolazole-type compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom or a substituent; Za, Zb, and Zc each represents a methine group, a substituted methine group, .dbd.N-- or --NH--; and one of the Za-Zb bond and Zb-Zc bond is a double bond and the other is a single bond.The present heat-developable photographic light-sensitive materials are capable of forming images of high density, with low fog, in a short period of time.Type: GrantFiled: October 23, 1986Date of Patent: November 29, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Ozaki, Ken Kawada
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Patent number: 4782006Abstract: An optical recording method comprises the steps of:(A) irradiating a radiation corresponding to a recording information on an optical recording medium having a recording layer containing a diacetylene derivative and at least one selected from the group (hereinafter called the group B) consisting of azulenium salt compounds, pyrylium dyes, diene compounds, croconic methine dyes and polymethine compounds, thereby forming a latent image; and(B) irradiating a radiation on the recording medium having said latent image formed thereon to thereby visualizing said latent image.Type: GrantFiled: December 10, 1986Date of Patent: November 1, 1988Assignee: Canon Kabushiki KaishaInventors: Yukuo Nishimura, Ken Eguchi, Kunihiro Sakai, Haruki Kawada, Hiroshi Matsuda, Takashi Nakagiri, Toshihiko Miyazaki, Yoshinori Tomida, Toshiaki Kimura, Kenji Saito
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Patent number: 4782010Abstract: The use of phenazine, phenoxazine and phenothiazine color forming developers in photothermographic dry silver emulsions provides a stable imaging system under both light and dark storage.Type: GrantFiled: December 29, 1986Date of Patent: November 1, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventors: Roger A. Mader, David C. Weigel, Louis M. Leichter, Kristen A. Hoff
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Patent number: 4775613Abstract: A heat-developable light-sensitive material comprising a support having thereon at least one layer containing a light-sensitive silver halide, a reducing agent, a binder and an acetylene silver compound.The heat-developable light-sensitive material which contains the novel organic silver compound can provide images having high density and low fog when subjected to a short period of developing time even when a small amount of a base processor is used.Type: GrantFiled: March 31, 1986Date of Patent: October 4, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Hiroshi Hara, Ken Kawata
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Patent number: 4772544Abstract: A heat-developable photographic material is disclosed wherein the photographic material comprising at least one of an acid or a salt thereof having an acid dissociation constant pKa of 7 or less.Type: GrantFiled: August 7, 1985Date of Patent: September 20, 1988Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroyuki Hirai
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Patent number: 4770981Abstract: There is provided a multi-layer heat-developement-type color light-sensitive material comprising a support having thereon a layer containing light-sensitive silver halide grains, an organic silver salt, a reducing agent, a yellow dye donator substance and a binder, e.g. gelatin, a layer containing light-sensitive silver halide grains, an organic silver salt, a reducing agent, a magenta dye donator substance and a binder, and a layer containing light-sensitive silver halide grains, an organic silver salt, a reducing agent, a cyan dye donator substance and a binder, the binder of the respective layers amounting in total to from 3 g to 10 g per m.sup.2 of said support; preferably at least one layer of the light-sensitive material contains a heat solvent.Type: GrantFiled: June 17, 1987Date of Patent: September 13, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Tawara Komamura, Masaru Iwagaki, Toyoaki Masukawa
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Patent number: 4770989Abstract: A heat-developable color photosensitive element having a support bearing thereon at least one photographic component layer containing a photosensitive silver halide, an organic silver salt, a reducing agent, a dye donor substance and a binder. The photosensitive element is characterized by the photographic component layer which contains a thermal solvent and a binder which contains both a gelatin and a vinyl pyrrolidone polymer.Type: GrantFiled: May 4, 1987Date of Patent: September 13, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Tawara Komamura, Masaru Iwagaki, Takashi Sasaki, Fumio Ishii, Kunihiro Koshizuka
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Patent number: 4766056Abstract: A heat-developable color light-sensitive material is disclosed, comprising a support having thereon at least one layer containing a light-sensitive silver halide, a binder, a compound containing a color moiety represented by formula (A), and a compound or a precursor thereof which reacts with an oxidized compound formed from the compound of formula (A), thereby converting the oxidized compound into a non-diffusible form, said compound of formula (A) being represented by ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 each represents a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group, an aralkyl group, an alkoxy group, an aryloxy group, an acylamino group, an alkylthio group, an arylthio group, or a halogen atom, provided that at least one of R.sub.1, R.sub.2, and R.sub.Type: GrantFiled: February 21, 1986Date of Patent: August 23, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Osamu Takahashi, Koichi Koyama, Keizo Koya
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Patent number: 4764453Abstract: A method of processing a silver halide color photographic material is disclosed. This method comprises developing said photographic material, removing the residual image-forming silver, treating, in the substantial final stage of color processing, the material with an aqueous solution containing a compound which releases ammonium ions in the solution, thereafter drying the material at a temperature not lower than 30.degree. C., and adjusting the pH of the surface of the dried emulsion layer to between 3.0 and 6.8.Type: GrantFiled: June 12, 1986Date of Patent: August 16, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Shigeharu Koboshi, Masayuki Kurematsu
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Patent number: 4755831Abstract: A multi- and full-color thermosensitive recording method of recording multi- or full-color images on a multi-color thermosensitive recording sheet capable of forming 2 to 4 different colors by use of a thermal head is disclosed, with the improvement that the picture elements of a thermal head are grouped so as to be operative in the form of a matrix consisting of n picture elements in the main scanning direction and m picture elements in the sub-scanning direction, each matrix is assigned to 2 to 4 alternatively independent colorings and thermal recording is performed in such a manner that, of the n.times.m picture elements in each matrix, the number of the picture elements for each color formation is changed, whereby multi- and full-color recording with a multi-step pseudo density gradation is attained.Type: GrantFiled: June 30, 1986Date of Patent: July 5, 1988Assignee: Ricoh Company, Ltd.Inventor: Hiroshi Sakamoto
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Patent number: 4752547Abstract: A dye-forming electrothermographic element comprises an electrically activatable recording layer comprising (a) a reducing agent or reducing agent precursor capable of being activated by a Lewis base; (b) a cobalt(III) Lewis base complex; and (c) at least one of (i) a reducible dye-forming compound that has an oxidation state above that of the conjugate dye, (ii) a dye capable of changing its wavelength of absorption by reaction with a Lewis base, and (iii) a dye-forming coupler capable of reacting with the oxidized form of the reducing agent in (a) to form a dye. A negative or positive dye image is formed in such a dye-forming electrothermographic element by applying an electrical potential imagewise to the element of a magnitude and for a time sufficient to produce in the image areas a charge density sufficient to produce a latent image; and, then, heating the element to a temperature and for a time sufficient to form a dye image in the element.Type: GrantFiled: June 4, 1986Date of Patent: June 21, 1988Assignee: Eastman Kodak CompanyInventors: Stanley W. Cowen, James C. Fleming, Mark Lelental
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Patent number: 4751175Abstract: A heat developable color light-sensitive material is disclosed, which comprises a support having provided thereon at least a light-sensitive silver halide emulsion, a binder, and a compound having a dye moiety within the molecule and which is capable of releasing, upon reduction of light-sensitive silver halide to silver at elevated temperatures, said dye moiety corresponding to or inversely corresponding to the reduction to form a dye different from said compound in terms of diffusibility, wherein said light-sensitive silver halide emulsion is prepared by forming silver halide grains in the presence of a sensitizing dye.Type: GrantFiled: March 6, 1987Date of Patent: June 14, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuo Aotsuka, Takanori Hioki, Kiyohiko Yamamuro
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Patent number: 4745043Abstract: A method for forming an image, which comprises heating a light-sensitive material comprising a support having thereon at least a light-sensitive silver halide, a binder, and a dye providing substance simultaneously with or after imagewise exposure thereof in the presence of water, a reducing agent, and at least one kind of intensifying agent. In accordance with the method of the present invention, images having a high density can be obtained in a short period of time using reduced amounts of silver and base. A heat-developable photographic material containing intensifying agent is also described.Type: GrantFiled: July 25, 1986Date of Patent: May 17, 1988Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroyuki Hirai
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Patent number: 4740445Abstract: A color image is formed in an image forming reaction system comprising a photographic heat-developable silver halide light-sensitive material by reacting a difficultly soluble metal compound, for example, calcium carbonate with a compound capable of water-mediated complexing reaction with the metal ion of the difficultly soluble metal compound and having an organic base, for example, guanidine oxalate in the presence of water to increase the pH of the system.Type: GrantFiled: July 30, 1986Date of Patent: April 26, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Yoshiharu Yabuki, Kozo Sato
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Patent number: 4738917Abstract: A method for processing a silver halide photographic material by processing a silver halide color photographic light-sensitive material containing at least a silver halide emulsion layer comprising a silver halide grain essentially consisting of silver chlorobromide and a binder having a swelling rate of T 1/2 of 2 sec. to 30 sec. The color developer contains a n-hydroxyalkyl-p-phenylenediamine derivative at a temperature not less than 30.degree. C. for a time not more than 150 sec. The time and temperature are effective to process the silver halide color photographic light-sensitive material without decreasing the stability of the resulting dye image.Type: GrantFiled: May 15, 1986Date of Patent: April 19, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Shigeharu Koboshi, Satoru Kuse, Kazuhiro Kobayashi, Masao Ishikawa, Masayuki Kurematsu
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Patent number: 4732846Abstract: A heat-developable light-sensitive material is described, comprising a support having provided thereon at least(a) a binder;(b) a light-sensitive silver halide;(c) at least one silver salt of a compound represented by formula (I) or (II) ##STR1## wherein Z represents a non-metallic atomic group forming a heterocyclic ring together with the nitrogen atom,A--C.tbd.Type: GrantFiled: April 30, 1986Date of Patent: March 22, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiaki Aono, Masatoshi Kato, Hiroshi Hara
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Patent number: 4731321Abstract: A heat developable light-sensitive material comprising a support having thereon at least one light-sensitive layer wherein at least one layer comprises a compound represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, a heterocyclic group each of which may be substituted or unsubstituted; a carboxy group or a salt thereof; R.sub.3 and R.sub.Type: GrantFiled: December 16, 1986Date of Patent: March 15, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Yoshiharu Yabuki, Hiroyuki Hirai, Ken Kawata
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Patent number: 4729942Abstract: A method for forming an image comprising heating a light-sensitive material comprising a support having provided thereon at least a light-sensitive silver halide and a dye developer in the presence of a base and/or a base precursor after or simultaneously with imagewise exposure to imagewise distribute a mobile non-oxidation type dye developer, wherein the dye developer is a compound having a dye moiety having a ballast group which is split off upon heating in the presence of the base and/or base precursor and a developer moiety against the silver halide in one molecule, is disclosed. According to the method of the present invention, images which are improved in image identification and color separation characteristics are obtained by heat development of the light-sensitive material.Type: GrantFiled: August 19, 1986Date of Patent: March 8, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Osamu Takahashi, Kiyoshi Morimoto
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Patent number: 4728600Abstract: A heat-developable light-sensitive material is described, comprising a support having thereon at least (1) a light-sensitive silver halide, (2) a silver salt oxidizing agent, (3) silver salt particles having adsorbed thereon at least one compound selected from a cyclic imino compound represented by formula (I) described below and a mercapto compound represented by formula (II) described below, (4) a reducing agent, and (5) a binder.Formula (I) is represented by ##STR1## wherein Z represents a non-metallic atomic group forming a heterocyclic ring containing an imino group together with the nitrogen atom of formula (I).Formula (II) is represented byR--S--M (II)wherein M represents a hydrogen atom or an alkali metal atom; and R represents a substituted or unsubstituted aliphatic hydrocarbon group, a substituted or unsubstituted aromatic hydrocarbon group, or a substituted or unsubstituted heterocyclic group.Type: GrantFiled: April 17, 1986Date of Patent: March 1, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Hara, Toshiaki Aono
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Patent number: 4727008Abstract: A dye-forming electrically activatable recording (EAR) element which is capable of forming at least two dye images comprises an electrically conductive support bearing on one side of the support at least a dye-forming layer (A) responsive to negative polarity charge exposure and at least one dye-forming layer (B) responsive to positive polarity charge exposure and, optionally, other dye-forming layers. A multicolor dye image can be formed in the dye-forming electrically activatable recording element by multistep imagewise charge exposure in which the exposure steps are reversed in electrical polarity at each step. The reversal of polarity of exposure at differing charge density levels enables formation of a dye image in at least one layer without formation of a dye image in another layer. Processing of the exposed dye-forming electrically activatable recording element is carried out by thermal processing or by means of processing solutions or baths.Type: GrantFiled: June 4, 1986Date of Patent: February 23, 1988Assignee: Eastman Kodak CompanyInventors: Mark Lelental, Scott A. Brownstein
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Patent number: 4716100Abstract: A heat developable light-sensitive material containing a novel base precursor (I), which is stable during storage and rapidly decomposes to release a basic component upon heating higher than a certain temperature, has excellent storability and provides an image having a good image quality, i.e., a low fog density and a high image density within a short period of developing time.Type: GrantFiled: August 26, 1985Date of Patent: December 29, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshiharu Yabuki, Kozo Sato, Ken Kawata, Hiroyuki Hirai
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Patent number: 4713316Abstract: A heat-developable photographic material having improved preservability, which comprises a support having thereon at least one heat-developable photographic layer, said photographic material containing a dye represented by formula (I) ##STR1## wherein n and m each represents 0, 1, 2 or 3;p and q each represents 0 or 1;L represents a methine group or a substituted methine group;R.sub.1 and R.sub.2 are same or different and each represents an unsubstituted or substituted alkyl group;R.sub.3 and R.sub.4 are same or different and each represents a hydrogen atom, an alkyl group, an alkoxy group, a hydroxyl group, an unsubstituted or substituted amino group or a halogen atom; or said R.sub.3 and R.sub.4 form a condensed 6-membered ring;Z and Z' are same or different and each represents a non-metallic atomic group necessary for forming a substituted or unsubstituted 5-membered or 6-membered ring, or substituted or unsubstituted 5-membered or 6-membered ring which is condensed with another ring;X.sup..crclbar.Type: GrantFiled: December 4, 1985Date of Patent: December 15, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiiti Kubodera, Toshinao Ukai, Hisashi Okada
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Patent number: 4710450Abstract: A photographic element comprising photosensitive and image-receiving layers on a support further includes a primary exothermic electroconductive layer serving as a heating element and an auxiliary exothermic electroconductive layer thereon, wherein the primary conductive layer containing conductive substance like carbon black so that it is heated upon electric conduction, contributing to heat development.Type: GrantFiled: February 13, 1986Date of Patent: December 1, 1987Assignee: Fuji Photo Film Co., Ltd.Inventor: Hideki Naito
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Patent number: 4708928Abstract: Photothermographic imaging chemistry, and particularly color chemistry, can be contained within solid particles. Photothermographic media can then be made by dispersing these particles within a binder in the concentrations and proportions desired.Type: GrantFiled: August 29, 1986Date of Patent: November 24, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventor: Thomas C. Geisler
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Patent number: 4705737Abstract: A heat developable photographic material comprising a support having thereon at least a photosensitive silver halide, a binder, and at least on of base precursors represented by following formula (I) or (II): ##STR1## wherein R represents an alkyl group, an alkylene group, an aryl group, an arylene group, a monovalent or divalent heterocyclic group, each of which may be unsubstituted or substituted; B represents a mono- or di-acidic, nitrogen-containing, sulfur-free base having a pKa of not lower than about 7 and containing 12 carbon atoms or less; x is an integer of 1 when R represents a monovalent group or an integer of 2 when R represents a divalent group, y is the same as x when B represents the mono-acidic base or an integer of 1 when B represents the di-acidic base; and z is an integer of 2 when R represents a monovalent group and B represents the di-acidic base or otherwise an integer of 1; R' represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl gType: GrantFiled: August 20, 1985Date of Patent: November 10, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Kozo Sato, Yoshiharu Yabuki, Ken Kawata
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Patent number: H456Abstract: A thermodevelopable photographic material is described, comprising a support, at least one photographic silver halide emulsion layer coated thereon, and a dye donating substance capable of forming or releasing a mobile dye in response to, or in inverse response to, the reduction of silver halide in said emulsion to silver by heating, wherein the color of an image formed by the fixing of each of said mobile dyes released by exposure and heating to a dye fixing layer is within the range of a*=10 to -18 and b*=10 to -18 determined from tristimulus values in the 10 degree visual field XYZ system under standard light C.Type: GrantFiled: February 1, 1985Date of Patent: April 5, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Hara, Noboru Ohta, Tsuneo Suzuki