Reversal Process Patents (Class 430/379)
  • Patent number: 4729943
    Abstract: A reversal photographic element comprising at least two dye image-forming units, at least one unit comprising(1) a first silver halide emulsion layer spectrally sensitized to a given region of the spectrum with which is associated a dye image-forming chromogenic coupler and(2) a second silver halide emulsion layer spectrally sensitized to a different region of the spectrum than the first and containing an interimage effect-forming means such as a development inhibitor-releasing coupler, which forms either a colorless compound or a dye which does not substantially take part in the formation of the image.
    Type: Grant
    Filed: October 6, 1986
    Date of Patent: March 8, 1988
    Assignee: Eastman Kodak Company
    Inventors: Maurice Pfaff, Regis Thomas
  • Patent number: 4720451
    Abstract: A silver halide color reversal light-sensitive material comprising a support having thereon at least one red-sensitive emulsion layer, at least one green-sensitive emulsion layer and at least one blue-sensitive emulsion layer, at least one layer of said light-sensitive material comprising (1) an emulsion containing tabular silver halide grains having a diameter/thickness ratio of at least of about 4 and (2) at least one compound represented by the following general formulae (I) to (IV), said tabular silver halide grains being present in amount of at least about 50% of the total projected area of silver halide grains present in the same layer: ##STR1## wherein M.sub.1 represents a hydrogen atom, a cation or a group cleavable in alkaline conditions, and Z represents an atomic group as defined in the specification; ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents an alkyl group, an aryl group or an aralkyl group as defined in the specification, X.sup..
    Type: Grant
    Filed: September 18, 1985
    Date of Patent: January 19, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadanobu Shuto, Naoyasu Deguchi
  • Patent number: 4717648
    Abstract: A process for processing a silver halide color reversal photographic light-sensitive material is disclosed, which comprises developing an imagewise exposed silver halide color reversal photographic light-sensitive material with a black-and-white developer containing at least one compound selected from the compounds of Group A, at least one compound selected from the compounds of Group B, and preferably further at least one compound selected from the compounds of Group C, whereinGroup A consists of organic heterocyclic compounds represented by formulae (A-I), (A-II), (A-III), and (A-IV) ##STR1## Group B consists of benzoimidazole, indazole, benzotriazole, benzooxazole and benzothiazole compounds, not containing a thiol group, a thioether bond, a thioketone group, or a disulfide bond.Group C consists of compounds represented by formulae (C-I) and (C-II). ##STR2## wherein the symbols are as defined in the appended claims.
    Type: Grant
    Filed: February 7, 1986
    Date of Patent: January 5, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Ueda, Junya Nakajima, Tadao Shishido, Sadanobu Shuto
  • Patent number: 4675274
    Abstract: A method for processing an imagewise exposed silver halide color reversal photographic material which comprises processing the color reversal photographic material with a black-and-white developer containing at least one compound represented by the following general formula (I-a) or (I-b): ##STR1## wherein M represents a hydrogen atom, an alkali metal, or an ammonium ion; R represents a hydrogen atom, an unsubstituted or substituted alkyl group, a hydroxy group, --SO.sub.3 M.sup.1, or --COOM.sup.1 ; R.sup.1 represents --SO.sub.3 M.sup.1 or --COOM.sup.1, wherein M.sup.1 represents a hydrogen atom, an alkali metal, or an ammonium ion; and n represents an integer of 1 to 6; and wherein n is 2 to 6, each of said Rs may be the same or different.
    Type: Grant
    Filed: July 19, 1985
    Date of Patent: June 23, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Ueda, Junya Nakajima
  • Patent number: 4626498
    Abstract: A color reversal photographic light-sensitive material is described having at least one light-sensitive silver halide emulsion layer, wherein at least one of said emulsion layer and a layer adjacent thereto contains a silver halide emulsion of silver halide grains containing internal fog centers.
    Type: Grant
    Filed: May 21, 1984
    Date of Patent: December 2, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadanobu Shuto, Yasuhiro Hayashi, Munehisa Fujita, Kazunori Hasebe
  • Patent number: 4623612
    Abstract: An improved method of developing silver halide photographic light-sensitive materials comprising at least one silver halide emulsion layer on a support is disclosed. In the improvement, said silver halide emulsion layer contains core/shell type silver halide grains having a shell thickness of 25 to 150 .ANG. wherein the surface of the core is subjected to chemical sensitization treatment and the surface of the shell is not subjected to chemical sensitization, and a developing solution contains a solvent for silver halide. It is possible to carry out spectral sensitization without causing a reduction in intrinsic sensitivity and to provide high-speed silver halide light-sensitive materials which are excellent in anti-fading property of latent images and excellent in stabilization with the passage of time using the above-described improved method.
    Type: Grant
    Filed: October 21, 1985
    Date of Patent: November 18, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihiro Nishikawa, Hatsumi Tanemura
  • Patent number: 4614707
    Abstract: A color reversal photographic light-sensitive materials comprising a base having thereon (a) at least one light-sensitive silver halide emulsion layer containing a dye forming coupler and (b) a silver halide emulsion layer substantially without light-sensitivity provided adjacent to said light-sensitive layer, or (a) at least one light-sensitive silver halide emulsion layer containing a dye forming coupler, (b) a silver halide emulsion layer substantially without light-sensitivity to light, and (c) an intermediate layer therebetween, wherein said intermediate layer or said silver halide emulsion layer substantially without light-sensitivity, or both said intermediate layer and said silver halide emulsion layer substantially without light-sensitivity contain at least one compound represented by the following formula (I): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each represents a hydrogen atom or a group having 1 to 10 carbon atoms capable of being hydrolyzed with alkali, R.sup.
    Type: Grant
    Filed: February 19, 1985
    Date of Patent: September 30, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Munehisa Fujita, Yasuhiro Hayashi, Takashi Ozawa, Nobutaka Ohki
  • Patent number: 4558000
    Abstract: A color reversal light-sensitive material comprising a support having coated thereon at least a pair of silver halide emulsion layers having mutually different color sensitivities and consisting of an emulsion having a high silver/coupler ratio and an emulsion having a low silver/coupler ratio, the former ratio being greater by a factor of at least 5 than the latter ratio, and the latter emulsion being incorporated with a compound containing recurring units represented by the following General Formula (I): ##STR1## the substituents being defined within the specification. By including the compound of the general formula (I) within the particular emulsion layer which is highly susceptible to changes in sensitivity and maximum density, it is possible to prevent deterioration in color balance which has been found to be due to variation in the concentration of potassium bromide.
    Type: Grant
    Filed: March 16, 1984
    Date of Patent: December 10, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Yamagami, Yasuhiro Hayashi, Naoyasu Deguchi, Kiyoshi Imai
  • Patent number: 4554245
    Abstract: A color reversal photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer, an organic compound and colloid grains of a metal or metal sulfide or silver halide grains the surface of which is previously fogged. The silver halide emulsion layer includes fine grains of silver halide particles having a particle size of 0.3.mu. or less. The fine grain particles are present in the emulsion in an amount in the range of about 30% to about 95% based on the total number of silver halide grains in the emulsion. The silver halide emulsion also includes coarse grains having a particle size of more than 0.3.mu.. The organic compound has a solubility product constant of 10.sup.-14 or less when forming a salt with a silver ion.
    Type: Grant
    Filed: January 30, 1984
    Date of Patent: November 19, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuhiro Hayashi, Naoyasu Deguchi, Hiroyuki Yamagami, Kensuke Goda, Kazunori Hasebe
  • Patent number: 4525449
    Abstract: A method of color reversal treatment of an exposed silver halide photographic material is disclosed. The method involves treating the exposed material with 2 both type black-and-white developing solutions. The first solution contains a compound represented by the general formula (I):R.sub.2 --S--R.sub.1).sub.d --S--R.sub.2 (I)wherein R.sub.1 represents an alkylene group having 2 to 10 carbon atoms, which may have ether bonds, R.sub.2 represents an alkyl group having 2 to 10 carbon atoms which alkyl group may have substituents, ether bonds or ester bonds, and d represents an integer of 0 to 3. The second black-and-white developing solution is a conventional solution. By utilizing the two solutions and specifically the first solution containing the compound of general formula (I) it is possible to obtain good photographic images having a high maximum density and good color balance.
    Type: Grant
    Filed: November 1, 1983
    Date of Patent: June 25, 1985
    Assignee: Fuji Photo Film Company, Limited
    Inventors: Junya Nakajima, Kiyoshi Imai, Takashi Nakamura
  • Patent number: 4497893
    Abstract: A silver halide color reversal photographic material comprising a backing layer containing both gelatin of an isoelectric point of 5.5 or more and a cationic polymer is disclosed. By utilizing the particular backing layer the color reversal photographic material has increased retouchability.
    Type: Grant
    Filed: January 31, 1984
    Date of Patent: February 5, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoyasu Deguchi, Koji Kameyama, Taku Nakamura
  • Patent number: 4458002
    Abstract: A process for the production of a multicolor reversal image with improved color balance is provided which process comprises the steps of directing incident image light dot- or linewise modulated by a light-distributing means onto a multicolor photographic silver halide emulsion material containing a blue-, a green- and a red-sensitive silver halide emulsion layer and processing said silver halide emulsion layers to form a color reversal image.In the maximum density part of the dots or lines of said light distributing means e.g. a contact screen the ratio of the absorption density for the light corresponding with the spectral sensitivity region of the silver halide emulsion layer being during the exposure most remote from the light-distributing means to the absorption density for the light of the whole visible spectrum (400-700 nm) is higher than the said ratio in any other density part of the dots or lines (see FIG. 1).
    Type: Grant
    Filed: May 17, 1983
    Date of Patent: July 3, 1984
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Wilhelmus Janssens, Christiaan G. Thiers, Wilfried F. Liekens
  • Patent number: 4394440
    Abstract: A yellow-dye-forming photographic developing composition having improved stability comprises a haloacetanilide coupler, such as alpha-pivalyl-alpha-(4-carboxyphenoxy)-2,4-dichloroacetanilide, an N-alkyl-N-alkoxyalkyl-p-phenylenediamine developing agent, such as 4-amino-N-ethyl-N-(2-methoxyethyl)-m-toluidine di-p-toluene sulfonate, and a 4,4-disubstituted-1-aryl-3-pyrazolidinone, such as 4,4-dimethyl-1-phenyl-3-pyrazolidinone.
    Type: Grant
    Filed: January 22, 1982
    Date of Patent: July 19, 1983
    Assignee: Eastman Kodak Company
    Inventor: Carl R. Cappel
  • Patent number: 4332885
    Abstract: Photographic sensitive materials for a color-diffusion transfer process which are particularly useful in a wide variety of temperature and climate conditions are disclosed. The materials are comprised of a red-sensitive emulsion layer; a green-sensitive emulsion layer; and a blue-sensitive emulsion layer on a support wherein at least one of the layers is comprised of a plurality of additional layers. Two or more of the additional layers are direct reversal photographic emulsion layers of higher and lower sensitivity which are not previously fogged. The emulsion layer having lower sensitivity has a gradation of 1.8 or more resulting in a hard tone.
    Type: Grant
    Filed: April 7, 1981
    Date of Patent: June 1, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hideki Ohmatsu
  • Patent number: 4322493
    Abstract: A reversal development processing method for black and white silver halide photographic light-sensitive materials which comprises bleaching an imagewise exposed black and white silver halide photographic light-sensitive material with a bleaching solution containing at least one oxidizing agent capable of forming a water-soluble silver salt when reacted with the silver images of said exposed light-sensitive material in the presence of at least one bleach accelerating agent selected from the compounds represented by the general formulae (I) to (VIII) described in the specification.
    Type: Grant
    Filed: September 26, 1979
    Date of Patent: March 30, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Haruo Shibaoka, Katsumi Hayashi
  • Patent number: 4299913
    Abstract: The stability of baths containing fogging agents, especially the stability of baths containing tin-II-ions, is increased by addition of an agent of the following formula ##STR1## respectively, a tautomeric or a salt thereof, the meaning of the substituents being as indicated in the specification.
    Type: Grant
    Filed: October 22, 1979
    Date of Patent: November 10, 1981
    Assignee: Agfa-Gevaert AG
    Inventor: Ubbo Wernicke
  • Patent number: 4276372
    Abstract: A color photographic material is provided in which the interimage effect is adjusted to provide optimum color reproduction. The photographic material comprises an emulsion referred to as type I emulsion, which releases an inhibitor on development and another emulsion with underripened grains which are more soluble than those of the type I emulsion.
    Type: Grant
    Filed: February 11, 1980
    Date of Patent: June 30, 1981
    Assignee: AGFA-Gevaert, A.G.
    Inventors: Ubbo Wernicke, Reinhart Matejec, Franz Moll
  • Patent number: 4269923
    Abstract: Novel photographic imaging process and materials suitable therefor are provided, which can find their application in multi-color motion picture and simultaneous sound recording, in direct-positive image formation, in image-intensification processes, etc. A photographic silver image is formed in at least one hydrophilic colloid layer of a light-sensitive photographic material incorporating silver halide, by means of exposure and alkaline development steps, followed by bleaching of quantities of silver which are present in areas of said layer extraneous to those where imaging silver is required.
    Type: Grant
    Filed: January 22, 1980
    Date of Patent: May 26, 1981
    Assignee: AGFA-GEVAERT N.V.
    Inventors: Raymond A. Roosen, Robert J. Pollet, Antoon L. Vandenberghe
  • Patent number: 4268617
    Abstract: A silver halide color photographic light-sensitive material comprising a support and at least one silver halide emulsion layer, at least one of the layers of said photographic sensitive material containing at least one compound selected from the group consisting of those compounds represented by the formulae (I), (II), (III) and (IV):[Co(NH.sub.3).sub.6 ][R.sup.1 COO].sub.3 (I)[Co(NH.sub.3).sub.6 ][R.sup.2 OOCR.sup.3 COO].sub.3 (II)[Co(NH.sub.3).sub.5 (R.sup.4 COO)]X.sub.2 (III)[Co(NH.sub.3).sub.5 (R.sup.5 NH.sub.2)]X.sub.3 (IV)wherein R.sup.1, R.sup.2 and R.sup.4 each represent an alkyl group having at least 3 carbon atoms or a fluorine-substituted alkyl group having at least 1 carbon atom; R.sup.3 is an alkylene group; R.sup.5 is an alkyl group having at least 1 carbon atom; X is a halogen atom, a nitrate ion, a sulfate ion, or a carboxylate ion is disclosed.
    Type: Grant
    Filed: September 27, 1979
    Date of Patent: May 19, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akio Mitsui, Yoshiaki Suzuki
  • Patent number: 4266013
    Abstract: A light-sensitive silver halide photographic material comprising a support having thereon a layer containing a compound represented by the formula (I): ##STR1## wherein R.sub.1 represents an aliphatic or aromatic residue; R.sub.2 represents a hydrogen atom, an aliphatic or an aromatic residue; and X.sub.1 and X.sub.2, which may be the same or different, each represents a divalent aromatic group; and a method of forming a direct positive image which comprises processing a light-sensitive silver halide photographic material having a support carrying thereon an internal latent image type silver halide emulsion layer in the presence of the compound represented by the said formula (I). The compound is particularly effective in combination with diffusible dye releasing (DRR) compounds having o-hydroxyarylsulfamoyl groups.
    Type: Grant
    Filed: November 17, 1978
    Date of Patent: May 5, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiichi Adachi, Shigeo Hirano, Nobuyuki Tsujino
  • Patent number: 4258127
    Abstract: In a reversal color development process including a black and white development and a color development, the sharpness, granularity and multilayer effect of the color photographic images formed are remarkably improved by subjecting silver halide reversal color photographic materials to black and white development in the presence of a DIR compound, i.e., a non-coupler type compound capable of releasing a development inhibitor upon development, processing the color photographic materials in an aqueous solution of a fogging agent, and then subjecting the color photographic materials to color development.
    Type: Grant
    Filed: October 31, 1975
    Date of Patent: March 24, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Ishibashi, Haruhika Iwano
  • Patent number: 4258117
    Abstract: A method is disclosed of photographically processing a negative-working imagewise exposed silver halide photographic element to produce a reversal dye image comprising (a) developing the imagewise exposed silver halide with an electron transfer agent to produce oxidized electron transfer agent which reacts with a competing oxidizable substance and (b) developing silver halide remaining with the electron transfer agent in the presence of a dye image providing compound capable, after the competing oxidizable substance has been depleted, of reacting with the oxidized electron transfer agent to produce a reversal dye image. Image transfer film units are disclosed useful in the practice of this method. Such film units include those containing in addition to the competing oxidizable substance and initially immobile dye image providing compound a layer containing additional silver halide and a scavenger separating the additional silver halide from the immobile dye image providing compound.
    Type: Grant
    Filed: November 1, 1979
    Date of Patent: March 24, 1981
    Assignee: Eastman Kodak Company
    Inventors: John Morgan, Peter D. Marsden
  • Patent number: 4221860
    Abstract: A process for forming color photographic images having improved granularity, sharpness, and gradation by applying, after image exposure, a color reversal process including a step of performing color development in the presence of a competing coupler. The element processed is a multilayer reversal color photographic material comprising a support having coated thereon at least three differently sensitive photographic silver halide emulsion layers, the outermost layer of the color photographic material being blue-sensitive and containing a nondiffusible coupler forming a yellow dye by a coupling reaction with an oxidized primary aromatic amino color developing agent and represented by the following general formula (I) ##STR1## wherein R.sub.1 represents an alkyl group or an aryl group; R.sub.
    Type: Grant
    Filed: May 20, 1977
    Date of Patent: September 9, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takeshi Hirose, Akia Okumura
  • Patent number: 4194911
    Abstract: An inhibitor removing bath for effecting color formation in a color positive development process which bath comprises a color accelerating agent, a contrast control agent and a pH control agent. The inhibitor removing bath may further contain in a preferred embodiment a color reversal agent. A complete color photographic development process using this inhibitor removing bath is found to provide color positive transparencies of excellent quality.
    Type: Grant
    Filed: July 17, 1975
    Date of Patent: March 25, 1980
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: William A. Huffman, R. Dean Lowrey, Geoffrey C. Nicholson, Bruce Wittnebel
  • Patent number: 4186012
    Abstract: Non-diffusible thioether compounds capable of releasing, on reaction with color developer oxidation compounds, a diffusible silver halide development inhibitor without at the same time forming permanent dyes to any substantial extent are characterized by containing a group of the formula ##STR1## or its tautomeric form, wherein Z.sup.1 represents an electron attracting substituent and X represents an aliphatic, aromatic or heterocyclic group that if released together with the sulfur atom, forms a diffusible silver halide development inhibiting mercaptane.
    Type: Grant
    Filed: March 2, 1978
    Date of Patent: January 29, 1980
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Heinrich Odenwalder, Walter Puschel, Robert J. Pollet, Erwin Ranz
  • Patent number: 4184875
    Abstract: Positive images including color images are obtained by a photographic reversal process by imagewise exposure of a material which comprises at least one light-sensitive silver halide emulsion layer, black and white development, fogging and color development characterized in that the fogging is carried out in the presence of a compound of the formula ##STR1## wherein the symbols are defined as hereinafter.
    Type: Grant
    Filed: April 25, 1978
    Date of Patent: January 22, 1980
    Assignee: AGFA-Gevaert, A.G.
    Inventors: Heinrich Odenwalder, Ubbo Wernicke
  • Patent number: 4183750
    Abstract: A color film and a process for developing it in which the usual color image is given increased sharpness and resolution by the provision of a metallic silver image in a single layer of the emulsion.
    Type: Grant
    Filed: July 15, 1977
    Date of Patent: January 15, 1980
    Inventor: Richard J. Goldberg