Abstract: A method for processing a transparent silver halide color photographic material is disclosed. The transparent silver halide photographic light-sensitive material is treated with a processing solution containing a compound represented by Formula (I).Formula I ##STR1## wherein Q is a group of atoms necessary for forming a nitrogen-containing heterocyclic ring (including one condensed with a 5- or 6-member unsaturated ring), R.sub.11 is a hydrogen atom, an alkali metal atom, ##STR2## or an alkyl group, Q' is a synonym for Q.sub.1. After the treating, a ratio (E/G) of a light absorbance E of unexposed area of the light-sensitive material at 650 nm to an amount of silver G mg/m.sup.2 remaining in the light-sensitive material is within the range of from 3.0.times.10.sup.-4 to 1.5.times.10.sup.-3 in the silver halide photogrpahic light-sensitive material,A transparent silver halide color photographic material is also disclosed.

Abstract: Color reversal photographic elements can be effectively processed to provide color positive images using biodegradable bleaching compositions when the following fixing compositions contain an uncomplexed aminodisuccinic acid additive. The presence of the additive in the fixing composition seems to reduce the retained iron from use of the biodegradable bleaching composition, thereby reducing yellow stain and other undesirable effects in the color images, and iron precipitates in the fixing bath.

Abstract: A method for processing a silver halide color photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, the method comprising the steps of: exposing the light-sensitive material; color developing the light-sensitive material; and desilvering the light-sensitive material, the desilvering step comprising processing the light-sensitive material with a desilvering processing solution containing at least one compound represented by formula (I) or a salt thereof: ##STR1## wherein Z represents --NR.sub.5 (R.sub.6) or --OR.sub.7, R represents an alkylene group, n represents 0 or 1, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each independently represents a hydrogen atom, an aliphatic group or an aromatic group, and R.sub.7 represents an aliphatic group or an aromatic group, provided that any two of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be combined with each other to form a ring, that the total carbon number of R.sub.5 and R.

Abstract: Methods of selectively silvering photographic materials. A method for selective reflective silvering of color negative photographic materials, whereby an attractive image comprising reflective silver, black, and full color areas may be obtained, comprises the steps of developing the materials using a conventional color developer, applying a reflective silvering bath, and removing silver from selected areas of said materials. A method for selective reflective silvering of color positive photographic materials comprises the steps of developing said materials using a conventional color developer, applying a reflective silvering bath, and removing silver from selected areas of said materials.

Abstract: Color photographic elements are processed with an acidic periodate bleaching composition that may also include chloride ions as a rehalogenating agent. Bleaching is carried out after color development is stopped with an acidic stop bath. The processing method provides relatively rapid bleaching without physical defects such as blistering or vesiculation.

Abstract: A color photographic silver halide material is processed effectively without formation of rust after the bleaching step. Bleaching is accomplished using an iron chelate of a biodegradable aminopolycarboxylic acid chelating ligand that has a tendency to form "rust" or ferrous hydroxide in processing baths conventionally used after bleaching, such as washing solution. This tendency to form rust is overcome by spraying the bleached film with a washing solution before fixing, and without immersion of the film in that washing solution.

Abstract: A silver halide material can be processed using a redox amplification developer solution and a bleach solution. Both solutions contain a peroxide oxidant.

Abstract: Color photographic elements are processed with a highly acidic periodate bleaching solution including a rehalogenating agent and a strong acid. Bleaching is carried out after color development without any intervening processing steps, such as an acidic prebath. The processing method provides rapid bleaching without physical defects such as blistering or vesiculation, and minimizes the formation of Dmin.

Abstract: An aminopolycarboxylic acid compound represented by the following formula or analogous thereof: ##STR1## The aminopolycarboxylic acid compound of the present invention can be used as a chelating agent for various metals, which is excellent in the biodegradability and masking effect on metals.

Abstract: High silver chloride photographic materials can be processed with a process comprising two fixing steps, one before and another after a hydrogen peroxide bleaching step. The first fixing step utilizes a sulfite fixing agent.

Abstract: In the production of a colour photographic image in a continuous process comprising at least the stages a) treatment with a bath containing H.sub.2 O.sub.2 or a bath containing a compound which liberates H.sub.2 O.sub.2 and b) fixing, wherein stage b) immediately follows stage a), precipitation of silver oxide and silver is avoided if the fixing bath contains an anti-oxidant and a buffer substance in addition to the fixing agent, a molar ratio of anti-oxidant to fixing agent of >0.2 is maintained and the quantity of buffer substance is >0.4 mol/l.

Abstract: An illumination system (20) and method for use with an optical web inspection assembly (21) to identify surface defects on a moving material web (25). The illumination system (20) includes an elongated light source (26) having an elongated aperture (46) adapted to transmit a substantially continuous elongated strip of non-collimated light therefrom generally in an entrance direction. An elongated light pipe device (32) is provided having an elongated entrance end (33) and an opposite elongated exit end (36) wherein the entrance end (33) is positioned longitudinally adjacent the light source aperture (46) and configured to substantially receive the strip of light therethrough in the entrance direction. The light pipe (32) includes a smoothly curved interior wall (37) extending from the entrance end (33) to the exit end (36), and defines an optical path configured to reflect and transmit substantially all the light received from the entrance end to the exit end (36).

Abstract: A conditioning or bleach accelerating solution is prepared by diluting a concentrate up to 25 times. The concentrate contains a formaldehyde bisulfite precursor salt at from 200 to 600 g/l, sulfite ions at 0 to 200 g/l, a bleach accelerating agent at from 1.5 to 25 g/l, and a metal ion chelating agent present at up to 60 g/l. The concentrate is free of sodium ions.

Abstract: A ferric-EDTA bleach regenerator composition can be made with bleach overflow to provide a bleach replenisher for reversal color silver halide photographic processes. The bleach regenerator composition has a critically controlled pH between about 6.0 and about 6.5, and comprises a total bromide ion concentration of at least about 210 g/l, and ferric ion in an amount of at least about 50 g/l. At least 50% of the bleach overflow and the bleach regenerator composition are mixed in at least a 1:1 volume ratio. After pH adjustment to from about 5.4 to about 5.6, the pH adjusted replenisher is supplied to the bleach tank for use in the process.

Abstract: A multilayer silver halide color photographic element comprises a support having coated thereon a silver antihalation layer, an interlayer, at least two red-sensitive silver halide emulsion layers, at least two green-sensitive silver halide emulsion layers a yellow filter layer, and at least two blue-sensitive silver halide emulsion layers, wherein the interlayer provided between the silver antihalation layer and the red-sensitive silver halide emulsion layer closest to the support contains a bleach accelerator releasing compound, and the silver antihalation layer contains a water-soluble organic thiol.The invention provides reduction in residual silver levels and backside turbidity after processing, without deleteriously affecting sensitometric properties of the photographic element.

Abstract: The present invention provides a processing method which allows a silver halide color photographic material to be sufficiently desilvered and minimizes the rise in the formation of bleaching fog or stain even when it is processed in a short period of time. A novel process for the processing of a silver halide color photographic material comprising at least silver halide emulsion layer on a support which comprises subjecting the silver halide color photographic material to color development, and then processing the silver halide color photographic material with a processing solution having a bleaching capacity is provided, characterized in that said emulsion layer comprises tabular silver halide grains having ?100! major faces and a silver chloride content of 50 to 100 mol % and said processing solution having a bleaching capacity contains at least one ferric complex salt of a compound represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.

Abstract: The present invention pertains to a process for the stabilization of Holograms formed on gelatin.According to the invention, after (i) exposing, (ii) developing, and (iii) quenching said Hologram, there is added thereto (iv) a bleaching bath based on an oxidative cross-linking agent at a pH value of at least 3 or more, and thereafter, following (v) rinsing, (vi) fixing, (vii) additional rinsing and (viii) a final bath, (ix) said support material is dehydrated by the use of one or more baths in series containing a solvent which is water-miscible and does not affect the cured gelatin structure.In another embodiment, the invention pertains to light-directing wall elements for buildings made of a Holograms obtainable by the process mentioned above and applied to a transparent or opaque substrate.By means of the present invention, silver-free holographic support materials can be prepared.

Abstract: A redox amplification process with minimal steps includes processing a silver halide with an amplifier/bleach/fix solution that includes a redox oxidant capable of bleaching a silver image and a fixing agent that does not react with the redox oxidant.

Abstract: A composition for bleaching or bleach-fixing a silver halide photographic material has a pH of from 2 to 9. The composition comprises a bleaching agent which is either a persulfate or polyvalent metal complex of an aminopolycarboxylic acid, and from 0.01 to 2M of a sulfo-substituted carboxylate represented by Formula I(MO.sub.3 S).sub.n --R--(COOM).sub.m (I)wherein R is a benzene ring or a straight, branched or cyclic saturated aliphatic group having 2 to 8 carbon atoms;M is hydrogen or an organic or inorganic cation; andn is 1 to 7;with the proviso that if R is an aliphatic group, m is 2 to 4 and m and n combined cannot equal more than the number of carbon atoms in R plus two, and if R is a benzene ring, m is 2 to 5 and m and n combined cannot equal more than six.

Abstract: Certain organic carbocyclic and heterocyclic compounds are useful catalysts for hydrogen peroxide bleaching agents in photographic processing methods. These compounds are oxidizable by hydrogen peroxide and reducible by silver metal at a pH of from 1 to 7, and have a chemically reversible redox couple of from about -0.20 to about +1.0 volts at the same pH. The hydrogen peroxide bleaching ability is enhanced by the presence of these compounds which can be used in the bleaching solution itself, or in a prebath solution. The combination of the organic compound with a transition metal ion co-catalyst provides a synergistic effect in bleaching acceleration.

Abstract: A method of accelerating black and white development comprising contacting a negative-type silver halide photographic element during processing with a developer prebath or a developer bath comprising an accelerator compound of the formula: ##STR1## is disclosed, wherein R.sub.1, R.sub.2, and R.sub.3 are substituents; said R.sub.1, R.sub.2, and R.sub.3 may further combine with each other to form a 5-, 6-, or 7-membered ring; and wherein said developer prebath and developer bath do not contain any iron(III) ion complex salt having bleaching activity.A bath selected from the group consisting of developer prebaths and developer baths for black and white development of a negative-type silver halide photographic element comprising an aqueous solution of accelerator compound of the formula: ##STR2## is also disclosed, wherein R.sub.1, R.sub.2, and R.sub.3 are substituents; said R.sub.1, R.sub.2, and R.sub.

Abstract: A simple and effective bleaching method includes the use of a bleaching solution including a peroxide bleaching agent and chloride ion in an amount of at least 0.35 mol/l. An organic phosphonic acid or tertiary aminocarboxylic acid can also be present for stability. The method is useful for bleaching color photographic films containing at least 20 mol % silver bromide and from 0 to about 0.5 mol % silver iodide in at least one silver halide emulsion.

Abstract: A color photographic material is processed first by color development, then is contacted with a solution that both bleaches and provides redox amplification.

Abstract: A simple and effective peroxide bleaching method includes the use of a bleaching solution including a peroxide bleaching agent and chloride ion in an amount of at least 0.35 mol/l. An organic phosphonic acid or tertiary aminocarboxylic acid can also be present for stability. The method is useful for bleaching high silver bromide color negative photographic films containing at least 80 mol % silver bromide and from 0.5 to 5 mol % silver iodide in at least one silver halide emulsion.

Abstract: A method of processing photographic silver halide color material comprises, in order, a dye image-forming development step, a step which has the purpose of stopping further dye formation and a bleaching or bleach-fixing. The bleaching or bleach-fixing solution is made by adding additional components to all or some of the overflow of the stop bath. This decreases stain levels without increasing chemical load.

Abstract: A bleaching bath for photographic black-&-white silver halide materials characterised by the combination of at least 2 oxidising agents having an oxidising potential of .gtoreq.500 mV, optionally together with a metal salt having a stabilising action of a metal of subgroups 1 or 2 of the periodic system of elements, wherein, in the event that dichromate is used as one of the oxidising agents, it is used in a quantity of at most 3.4 mmol/l.

Abstract: A processing solution for processing an exposed silver halide photographic light-sensitive material comprises a compound represented by the following formula (A): ##STR1## wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 each represent --COOM.sub.1, --OH, --PO.sub.3 M.sub.1 M.sub.2 or --CONH.sub.2 in which M.sub.1 and M.sub.2 each represent a hydrogen ion, an alkali metal ion or another cation; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent a hydrogen atom, a lower alkyl group or a hydroxyl group; n.sub.1, n.sub.2, n.sub.3 and n.sub.4 each represent an integer of 0, 1 or 2, provided that none of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen atoms when n.sub.1 +n.sub.2 =1 and n.sub.3 +n.sub.4 =1; and X represents a substituted or unsubstituted alkylene group having 2 to 6 carbon atoms or --(B.sub.1 O)m-B.sub.2 -- in which B.sub.1 and B.sub.2 each represent a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms, and m is an integer of from 1 to 4.

Abstract: A method used for processing a silver halide photographic light sensitive material including steps of developing and treating with a solution having bleaching capability. The solution having bleaching capability comprises a ferric complex salt of a compound represented by the following formula A: ##STR1## wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 are independently a --CH.sub.2 OH group, a --PO.sub.3 M.sub.2 group or a --COOM group, which may be the same or different; M is a cation: and X is an alkylene group having 2 to 6 carbon atoms or a --(B.sub.1 O).sub.n --B.sub.2 -- group, in which is an integer of 1 to 8, B.sub.1 and B.sub.2 are independently an alkylene group having 1 to 5 carbon atoms, which may be the same or different. The solution can be used as a bleaching solution or bleach-fixing solution for color photographic material. The solution may further be used as a reducing solution for reducing an image formed on a photographic light-sensitive material.

Abstract: A bleaching composition is a mixture of two ferric complexes with two different aminopolycarboxylic acid complexing ligands. The first complex is formed of a biodegradable aminopolycarboxylic acid, and acts as the primary bleaching agent. The second complex is formed of a less biodegradable aminopolycarboxylic acid, and acts to inhibit biological growth and rust formation. The molar ratio of the first complex to the second complex is at least 2:1. The first complexing ligand is iminodiacetic acid or an alkyliminodiacetic acid. The second complexing ligand is either ethylenediaminetetraacetic acid or propylenediaminetetraacetic acid.

Abstract: Certain organic carbocyclic and heterocyclic compounds are useful catalysts for hydrogen peroxide bleaching agents in photographic processing methods. These compounds are oxidizable by hydrogen peroxide and reducible by silver metal at a pH of from 1 to 7, and have a chemically reversible redox couple of from about -0.20 to about +1.0 volts at the same pH. The hydrogen peroxide bleaching ability is enhanced by the presence of these compounds which can be used in the bleaching solution itself, or in a prebath solution. The combination of the organic compound with a transition metal ion co-catalyst provides a synergistic effect in bleaching acceleration.

Abstract: Aminosuccinic acid chelants are disclosed which have been found to be applicable in photographic processes. The aminosuccinic acids can be used in a method of bleaching or bleach-fixing a silver halide photographic material comprising contacting the photographic material with a bleaching solution containing at least one metal complex of a polyamino disuccinic acid and one or more metal complexes of a polyamino monosuccinic acid or a monoamino monosuccinic acid.

Abstract: A photographic bleach solution contains hydrogen peroxide, or a compound capable of releasing hydrogen peroxide, and two or more sequestering agents capable of complexing with a transition metal. The bleach solution ha a pH in the alkaline range. A method of using such a photographic bleach solution is also disclosed.

Abstract: A novel process and processing composition for processing a silver halide photographic material is disclosed. The processing composition is an aqueous solution of a ferric (III) complex salt of an ?S,S! optical isomer of a compound represented by formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each represents a hydrogen atom, an aliphatic group, an aromatic group or a hydroxyl group; W represents a divalent linking group containing carbon atoms; and M.sub.1, M.sub.2, M.sub.3 and M.sub.4 each represents a hydrogen atom or a cation. The processing composition is useful for bleaching a silver halide color photographic material. A process for processing a silver halide color photographic material is further disclosed, employing the above described process composition containing a ferric (III) complex salt of the compound of formula (I) as a bleaching agent.

Abstract: A composition for bleach-fixing a silver halide photographic element comprising a fixing agent and a ternary ferric-complex salt formed by a tetradentate ligand and a tridentate ligand and a method of bleach-fixing using said composition.

Abstract: A redox amplification photographic process comprises a sulfite fixing step after development-amplification and prior to peroxide bleaching.

Abstract: Certain organic carbocyclic and heterocyclic compounds are useful catalysts for hydrogen peroxide bleaching agents in photographic processing methods. These compounds are oxidizable by hydrogen peroxide and reducible by silver metal at a pH of from 1 to 7, and have a chemically reversible redox couple of from about -0.20 to about +1.0 volts at the same pH. The hydrogen peroxide bleaching ability is enhanced by the presence of these compounds which can be used in the bleaching solution itself, or in a prebath solution. The combination of the organic compound with a transition metal ion co-catalyst provides a synergistic effect in bleaching acceleration.

Abstract: A ferric-EDTA bleach regenerator composition can be mixed with bleach overflow to provide a bleach replenisher for reversal color silver halide photographic processes. The bleach regenerator composition has a critically controlled pH between about 6.0 and about 6.5, and comprises a total bromide ion concentration of at least about 210 g/l, and ferric ion in an amount of at least about 50 g/l. At least 50% of the bleach overflow and the bleach regenerator composition are mixed in at least a 1:1 volume ratio. After pH adjustment to from about 5.4 to about 5.6, the pH adjusted replenisher is supplied to the bleach tank for use in the process.

Abstract: Aminosuccinic acid chelants are disclosed which have been found to be applicable in photographic processes. The aminosuccinic acids can be used in a method of bleaching or bleach-fixing a silver halide photographic material comprising contacting the photographic material with a bleaching solution containing at least one metal complex of a polyamino disuccinic acid and one or more metal complexes of a polyamino monosuccinic acid or a monoamino monosuccinic acid.

Abstract: A non-rehalogenating bleaching composition for processing imagewise exposed and developed silver halide photographic elements comprising hydrogen peroxide, or a compound which releases hydrogen peroxide, and at least one compound of Formula I[MO.sub.2 C--(L.sup.1).sub.p ].sub.q --R--[(L.sup.2).sub.n --CO.sub.2 M].sub.m (I)wherein R is a substituted or unsubstituted aromatic hydrocarbon group, or a substituted or unsubstituted aromatic heterocyclic group containing at least one oxygen, nitrogen or sulfur atom;L.sup.1 and L.sup.2 are each independently a substituted or unsubstituted linking group wherein the linking group is attached to the carboxyl group by a carbon;n and p are independently 1 or 0;m and q are independently 0, 1, 2, 3, 4, 5, or 6 and the sum of m+q is at least 1; andM is a hydrogen atom, an alkali metal, an alkalineearth metal or an ammonium ion.

Abstract: Imagewise exposed and developed black and white or color silver halide photographic elements are effectively bleached using a non-rehalogenating peroxide bleaching composition. This bleaching composition comprises hydrogen peroxide, or a precursor that can release hydrogen peroxide, and has a pH from 2 to 6, and at least one compound of Formula I:R--(O).sub.n --SO.sub.3 M (I)wherein R is a group having 1 to 10 carbon atoms; n is 0 or 1; and M is a hydrogen atom, an alkali metal, an alkaline earth metal or an ammonium ion. Moreover, the bleaching composition is substantially free of rehalogenating agents, as well as complexes of a high valent metal ion and a polycarboxylic acid, an aminocarboxylic acid or a phosphonic acid.

Abstract: A solution for bleaching or bleach-fixing an exposed and developed silver halide color photographic light-sensitive material contains a ferric complex salt of a compound represented by the following Formula (A-I), (A-II) or (A-III), and a compound represented by the following Formula (B): ##STR1##

Abstract: Photographic elements, especially color papers, can be processed with developer, redox amplification or bleaching solutions that contain hydrogen peroxide or other oxidants. These solutions include a dissolved compound that has a hydrophobic hydrocarbon group and an additional group that enables the compound to adsorb to silver or stainless steel. The dissolved compound inhibits the catalytic effect of the metal on decomposition of the hydrogen peroxide so the processing solutions are more stable.

Abstract: To achieve superior desilvering property and reduced stains even with the use of a biodegradable bleaching agent in a dilute concentration, the processing is conducted with a processing solution comprising a ferric complex salt of the compound of formula (I) or (II) and, for example, a 2-carboxypyridyl and having bleaching ability. (In the formulae, R.sub.1 to R.sub.5 represent, for example, a hydrogen atom or a carboxyl group, L.sub.1 to L.sub.5 represent, for example, an alkylene group, G.sub.1 and G.sub.2 represent, for example, a carboxyl group or an aryl group and X represents, for example, a hydrogen atom).

Abstract: Color photographic elements containing predominantly chloride (greater than or equal to 90 mole %) silver halide emulsions are effectively and rapidly processed using a peroxide bleaching solution which also contains at least 0.45 mol of chloride ion per liter of solution.

Abstract: A method for desilvering an imagewise exposed and color development processed silver halide color light-sensitive material comprising processing the imagewise exposed and color developed silver halide color light-sensitive material with a processing solution exhibiting bleaching ability which contains at least one of hydrogen peroxide and a compound capable of releasing hydrogen peroxide, wherein the silver halide color light-sensitive material has an emulsion layer comprising a light-sensitive silver halide with at least 90 mol % silver chloride and substantially no silver iodide, the processing solution exhibiting a bleaching ability contains at least one water-soluble chloride, the color developed silver halide color light-sensitive material contains 1 mmol/m.sup.2 or less of a color developing agent in the light-sensitive material when introduced into the processing solution exhibiting a bleaching ability and the desilvering is completed within 30 seconds.

Abstract: A silver halide color photographic material which comprises a support having thereon at least one layer containing at least one compound represented by the following general formulaR.sup.1 --SO.sub.2 NH.sub.2wherein R.sup.1 represents an unsubstituted aliphatic group having 6 or more carbon atoms, an unsubstituted aryl group or an aryl group substituted by at least one substituent selected from the group consisting of an aliphatic group, an aryloxy group, a carbamoyl group, an acylamino group, an aliphatic oxycarbonyl group, an arylcarbonyl group and a halogen atom, provided that R.sup.1 does not contain any coupler residue.

Abstract: Polyamino monosuccinic acid chelants are disclosed which have been found to be applicable in photographic processes. The polyamino monosuccinic acids can be used in a method of bleaching or bleach-fixing a silver halide photographic material comprising contacting the photographic material with a bleaching solution containing a metal complex of a polyamino monosuccinic acid as a bleaching agent.

Abstract: A photographic bleaching or bleach/fixing composition contains a water-soluble ternary complex of an iron ion, a polycarboxylate ligand, and a second ligand which has at least one carboxyl group on an aromatic nitrogen heterocycle, such as a pyridinecarboxylic acid. Preferred materials are biodegradable, but all of the ternary complexes can be used in a variety of bleach or bleach/fix processes to good advantage as bleaching agents. They are particularly suitable for use in rehalogenating ferric chelate bleaches.

Abstract: A method for processing silver halide color photographic light-sensitive materials is disclosed.

Abstract: A process for the bleaching of an exposed photographic material utilizes a peroxide bleach solution to remove metallic silver from the exposed photographic material. The silver from the photographic material passes into the bleach solution such that at least part of the excess silver over that required to catalyze the bleaching action is removed from the bleach solution by forming an insoluble silver compound, for example, by the addition of a halide. The invention provides an apparatus for use in the bleaching method.