Developing Patents (Class 430/434)
  • Patent number: 7524605
    Abstract: An image-recording materials containing (A) a compound having a specific partial structure and at least one group selected from an acid group having a pKa of 11 or less, the derivative of the acid group and a group capable of generating the acid group, a lithographic printing plate precursor having an image-recording layer containing the compound (A), and a lithographic printing method using the lithographic printing plate precursor, are provided.
    Type: Grant
    Filed: April 8, 2005
    Date of Patent: April 28, 2009
    Assignee: Fujifilm Corporation
    Inventors: Ryuki Kakino, Kazuto Kunita, Hidekazu Oohashi, Yasuhito Oshima
  • Patent number: 7498124
    Abstract: A method and apparatus for developing a resist on a substrate in which a sacrificial surfactant-containing liquid is first applied to a resist as a pretreatment to reduce developing process defects and to improve the development process time and the uniformity of the resist. The pretreatment is followed by supplying a developing solution to the resist and thereafter developing the resist.
    Type: Grant
    Filed: September 30, 2003
    Date of Patent: March 3, 2009
    Assignee: Tokyo Electron Limited
    Inventor: John M. Kulp
  • Patent number: 7462437
    Abstract: A presensitized lithographic plate comprises a support and a hydrophilic image-recording layer. The hydrophilic image-recording layer contains a hydrophilic polymer and an agent capable of converting hydrophilic to hydrophobic when the agent is heated. The hydrophilic polymer comprises a main chain and branched chains. Each of the branched chain comprises a hydrophilic chain having a molecular weight in the range of 200 to 1,000,000. A hydrophilic substrate and a lithographic printing process are also disclosed.
    Type: Grant
    Filed: August 30, 2005
    Date of Patent: December 9, 2008
    Assignee: Fujifilm Corporation
    Inventors: Satoshi Hoshi, Kazuto Shimada, Gaku Kumada
  • Patent number: 7462441
    Abstract: An object of the present invention is to provide a planographic printing plate material as well as a printing method in which excellent properties of on-press development, exposure image visualization, scratch resistance, background contamination resistance, and printing durability are exhibited. Disclosed is a planographic printing plate material possessing a hydrophilic layer and an image formation layer provided on a plastic support, wherein the image formation layer contains polyolefin wax having a melting point of 105-120° C. and a melt viscosity of 1-1200 mPa·s, the hydrophilic layer contains spherical silica particles having a particle diameter of 5.0-7.0 ?m, and a content ratio of the spherical silica particles having a particle diameter of 5.0-7.0 ?m is not less than 60% by volume, based on a total volume of particles having a particle diameter of 2-10 ?m contained in the hydrophilic layer.
    Type: Grant
    Filed: February 21, 2006
    Date of Patent: December 9, 2008
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventor: Hidetoshi Ezure
  • Patent number: 7455959
    Abstract: The invention provides a color photographic element comprising at least one light-sensitive silver halide emulsion layer or a non silver-containing light-insensitive layer, in which at least one of these layers contains a colorless imidazole compound of formula (I) that undergoes less than 10% chemical or redox reaction with oxidized developer and which enables the photographic speed of the element to be increased by at least 0.
    Type: Grant
    Filed: October 1, 2004
    Date of Patent: November 25, 2008
    Assignee: Eastman Kodak Company
    Inventors: Bernard A. Clark, Philip A. Allway, Tania Zuberi, Stephen P. Singer, Charles E. Heckler, Louis E. Friedrich
  • Patent number: 7442492
    Abstract: The present invention provides a planographic printing plate precursor having a support, a photosensitive layer and a protective layer. The photosensitive layer contains at least an infrared absorbing agent, a polymerization initiating agent, a polymerizable compound and a binder polymer having repeating units represented by the following Formula (i). Further, the protective layer contains at least an inorganic lamellar compound. In Formula (i), R1 represents a hydrogen atom or a methyl group; R2 represents a connecting group having two or more types of atom selected from the group consisting of a carbon atom, a hydrogen atom, an oxygen atom, a nitrogen atom, and a sulfur atom and having 2 to 82 atoms in total; A represents an oxygen atom or —NR3—, and R3 represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 10 carbon atoms; and n is an integer of 1 to 5.
    Type: Grant
    Filed: August 29, 2005
    Date of Patent: October 28, 2008
    Assignee: FUJIFILM Corporation
    Inventor: Takahiro Goto
  • Patent number: 7442493
    Abstract: A printing method comprising: imagewise exposing a lithographic printing plate precursor comprising a support and an image recording layer being removable with a fountain solution or a combination of a printing ink and a fountain solution and loading the exposed lithographic printing plate precursor on a plate cylinder of a printing press, or loading the lithographic printing plate precursor on a plate cylinder of a printing press and imagewise exposing the loaded lithographic printing plate precursor, supplying at least a fountain solution comprising a compound represented by the formula (I) defined herein to the exposed lithographic printing plate precursor so as to remove an unexposed area of the image recording layer; and performing printing.
    Type: Grant
    Filed: October 6, 2005
    Date of Patent: October 28, 2008
    Assignee: Fujifilm Corporation
    Inventors: Koji Sonokawa, Kuniharu Watanabe
  • Patent number: 7427465
    Abstract: A method of on-press developing a laser sensitive lithographic printing plate with ink and/or fountain solution is described. The printing member comprises on a substrate a photosensitive layer soluble or dispersible in ink and/or fountain solution and capable of hardening upon exposure to a laser. The plate is exposed with a laser and on-press developed with ink and/or fountain solution. The exposure and development are performed with the plate under lightings that contain no or substantially no radiation below a wavelength selected from 400 to 650 nm, or in the dark or substantially dark.
    Type: Grant
    Filed: February 14, 2005
    Date of Patent: September 23, 2008
    Inventor: Gary Ganghui Teng
  • Patent number: 7425405
    Abstract: A method for making a lithographic printing plate is disclosed which comprises the steps of: (i) providing a negative-working, heat-sensitive lithographic printing plate precursor comprising a support having a hydrophilic surface or which is provided with a hydrophilic layer and a coating provided thereon, the coating comprising an image-recording layer which comprises hydrophobic thermoplastic polymer particles and a hydrophilic binder, wherein the hydrophobic thermoplastic polymer particles have an average particle size in the range from 45 nm to 63 nm, and wherein the amount of the hydrophobic thermoplastic polymer particles in the image-recording layer is at least 70% by weight relative to the image-recording layer; (ii) exposing the coating to heat or infrared light, thereby inducing coalescence of the thermoplastic polymer particles at exposed areas of the coating; (iii) developing the precursor by applying an aqueous alkaline solution, thereby removing non-exposed areas of the coating from the su
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: September 16, 2008
    Assignee: Agfa Graphics, N.V.
    Inventors: Joan Vermeersch, Pascal Meeus
  • Patent number: 7425400
    Abstract: A planographic printing plate precursor, including: a substrate; a photosensitive layer containing an IR absorber, a polymerization initiator, a polymerizable compound and a binder polymer; and a protective layer containing a UV absorber, disposed in this order. The photosensitive layer exhibits reduction in solubility in an alkaline developing solution upon being exposed to light having a wavelength of 750 nm to 1400 nm.
    Type: Grant
    Filed: February 18, 2004
    Date of Patent: September 16, 2008
    Assignee: FUJIFILM Corporation
    Inventor: Takahiro Goto
  • Patent number: 7422835
    Abstract: The invention provides an imaging element comprising a support having thereon, in order, at least one imaging layer, at least one interlayer containing a lubricant which provides scratch-resistance and at least one outermost layer containing a different lubricant which provides abrasion-resistance and a method of processing the element. The element has increased durability, especially with regard to scratch- and abrasion- (especially photoabrasion-) resistance, whilst retaining performance and ease of manufacture. Preferably the element is for use in the manufacture of printed circuit boards or the production of printing plates, wherein abrasion and scratches are particularly acute.
    Type: Grant
    Filed: November 25, 2004
    Date of Patent: September 9, 2008
    Assignee: Eastman Kodak Company
    Inventor: Sean D. Slater
  • Patent number: 7419766
    Abstract: A laser imageable flexographic printing plate precursor comprises a thermoset elastomeric upper layer that is at least partially ablatable and comprises a radiation sensitive compound, and a non-ablatable elastomeric underlayer. This flexographic printing plate precursor can be imaged to provide a printing plate that is primarily useful for “high quality” printing because the resulting relief image is generally not greater than 600 ?m and has an extremely even “floor”. The imaged flexographic printing plate also can have a high visual contrast between the imaged areas and the non-imaged background areas.
    Type: Grant
    Filed: February 13, 2006
    Date of Patent: September 2, 2008
    Assignee: Eastman Kodak Company
    Inventors: Jankiel Kimelblat, Murray Figov, Yariv Y. Pinto
  • Patent number: 7399575
    Abstract: A relief printing original plate including a substrate, a photosensitive resin layer thereon that is photosensitive to ultraviolet radiations, and a mask layer thereon having both ultraviolet and non-ultraviolet absorbability, the ultraviolet absorbability being deactivatable in response to receiving non-ultraviolet radiation. A method for producing a relief printing plate by using the original plate is also provided.
    Type: Grant
    Filed: September 1, 2004
    Date of Patent: July 15, 2008
    Assignee: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Toshiya Takagi, Takashi Fujimoto
  • Patent number: 7358034
    Abstract: A method of deactivating and on-press developing an exposed lithographic printing plate is disclosed. The plate comprises on a substrate a photosensitive layer developable with ink and/or fountain solution and capable of hardening upon exposure to a radiation. The plate is exposed with the radiation, deactivated, and then on-press developed with ink and/or fountain solution. The deactivation of the exposed plate allows the handling of the plate under regular office light or any other light without causing the hardening of the non-exposed areas of the photosensitive layer.
    Type: Grant
    Filed: February 18, 2006
    Date of Patent: April 15, 2008
    Inventor: Gary Ganghui Teng
  • Patent number: 7348132
    Abstract: High speed violet or ultraviolet laser sensitive lithographic printing plate comprising on a hydrophilic substrate a specific photosensitive composition is described. The photosensitive layer comprises a polymeric binder, a multifunctional (meth)acrylate monomer, a free-radical initiator, and a sensitizing dye, with specific weight ratio of the monomer to the polymer. Combination of multifunctional urethane (meth)acrylate monomer and multifunctional non-urethane (meth)acrylate monomer can be advantageously used. The plate is imagewise exposed with a violet or ultraviolet laser at a dosage of less than 300 ?J/cm2, and then developed with an aqueous developer or with ink and/or fountain solution.
    Type: Grant
    Filed: January 21, 2006
    Date of Patent: March 25, 2008
    Inventor: Gary Ganghui Teng
  • Patent number: 7318994
    Abstract: The present invention relates to an improved compressible flexographic printing plate that uses a compressible layer comprising a polyurethane (meth)acrylate resin and microspheres. The process of the invention produces a chemically fused printing plate that eliminates the need for an adhesive to secure the compressible layer to the back of the printing plate.
    Type: Grant
    Filed: October 14, 2004
    Date of Patent: January 15, 2008
    Inventors: Donald Long, Ryan Vest
  • Patent number: 7316891
    Abstract: A method of making a lithographic printing plate is disclosed which comprises the steps of providing a lithographic printing plate precursor comprising (i) a support having a hydrophilic surface or which is provided with a hydrophilic layer and (ii) a coating provided thereon which comprises hydrophobic thermoplastic polymer particles; exposing the coating to heat, thereby inducing coalescence of the thermoplastic polymer particles at exposed areas of the coating; developing the precursor by applying a gum solution to the coating, thereby removing non-exposed areas of the coating from the support. According to the above method, the plate precursor can be developed and gummed in a single step.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: January 8, 2008
    Assignee: Agfa Graphics NV
    Inventors: Joseph Vander Aa, Joan Vermeersch, Dirk Kokkelenberg, Huub Van Aert
  • Publication number: 20070298355
    Abstract: There is disclosed a resist top coat composition, comprising at least a polymer that has an amino group or a sulfonamide group at a polymer end and that is represented by the following general formula (1); and a patterning process comprising: at least, a step of forming a photoresist film on a substrate; a step of forming a resist top coat on the photoresist film by using the resist top coat composition; a step of exposing the substrate; and a step of developing the substrate with a developer. There can be provided a resist top coat composition that makes it possible to provide more certainly rectangular and excellent resist patterns when a top coat is formed on a photoresist film; and a patterning process using such a composition.
    Type: Application
    Filed: June 11, 2007
    Publication date: December 27, 2007
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Yuji Harada, Jun Hatakeyama
  • Patent number: 7312022
    Abstract: A method of forming color image, comprising processing a silver halide color photosensitive material with a development processing solution containing a color developing agent, the silver halide color photosensitive material comprising a support and, superimposed thereon, a blue-sensitive layer unit composed of at least one silver halide emulsion layer, a green-sensitive layer unit composed of at least two silver halide emulsion layers, a red-sensitive layer unit composed of at least two silver halide emulsion layers and at least one non-light-sensitive layer, wherein the development processing solution or processing solution applied to the silver halide color photosensitive material before the use of the development processing solution contains compound (A), the compound (A) being a heterocyclic compound having three or more heteroatoms which when added, is capable of substantially enhancing the sensitivity of the silver halide color photosensitive material as compared with that exhibited when not added.
    Type: Grant
    Filed: December 2, 2004
    Date of Patent: December 25, 2007
    Assignee: FUJIFILM Corporation
    Inventors: Naoharu Kiyoto, Junichiro Hosokawa, Takanori Hioki
  • Patent number: 7300740
    Abstract: A lithographic printing plate precursor capable of forming an image without alkali development, comprising a hydrophilic support and a laser-sensitive photopolymerizable layer, wherein the photopolymerizable layer or other layer included in the lithographic printing plate precursor contains a copolymer containing at least a repeating unit having at least one ethylenically unsaturated bond and a repeating unit having at least two functional groups capable of interacting with a surface of the support or a copolymer containing at least a repeating unit having at least two ethylenically unsaturated bonds and a repeating unit having at least one functional group capable of interacting with a surface of the support.
    Type: Grant
    Filed: February 27, 2006
    Date of Patent: November 27, 2007
    Assignee: Fujifilm Corporation
    Inventors: Sumiaki Yamasaki, Akihiro Endo
  • Patent number: 7297462
    Abstract: A heat sensitive lithographic printing plate precursor is disclosed comprising on a support having a hydrophilic surface or which is provided with a hydrophilic layer, a coating comprising an infrared light absorbing agent and a copolymer which comprises a plurality of recurring units X having a hydrophilic polymeric pendant group and a plurality of recurring units Y having a hydrophobic polymeric pendant group. Said coating is capable of switching from a hydrophilic state into a hydrophobic state after exposure to heat and/or infrared light.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: November 20, 2007
    Assignee: AGFA Graphics NV
    Inventors: Huub Van Aert, Bert Groenendaal, Hieronymus Andriessen, Martin Moeller, Uwe Beginn, Ahmed Mourran
  • Publication number: 20070254246
    Abstract: A developer used for developing a planographic printing plate material is disclosed and the developer is an alkaline solution comprising a compound represented by formula: R1—O—(R2—O)n—H wherein R1 is a branched alkyl group having carbon atoms of not more than 20 which may be interrupted by —NH—; R2 is an alkylene group having carbon atoms of 1 to 10; and n is an integer of 2 to 100. There is also disclosed a method of processing a planographic printing plate material with the developer.
    Type: Application
    Filed: April 23, 2007
    Publication date: November 1, 2007
    Inventor: Kazuhiro Oikawa
  • Patent number: 7288361
    Abstract: A lithographic printing process which comprises the steps of: imagewise exposing to infrared light a presensitized lithographic plate which comprises a hydrophilic support and a removable image-forming layer containing an infrared absorbing agent having the absorption maximum within an infrared region and a dye precursor having substantially no absorption within a visible region to change the dye precursor to a visible dye having an absorption within a visible region within the exposed area, and to make the image-forming layer irremovable within the exposed area; removing the image-forming layer within the unexposed area of the lithographic plate mounted on a cylinder of a printing press; and then printing an image with the lithographic plate mounted on the cylinder of the printing press. The other processes are also disclosed.
    Type: Grant
    Filed: August 20, 2004
    Date of Patent: October 30, 2007
    Assignee: Fujifilm Corporation
    Inventors: Ryuki Kakino, Naonori Makino, Sumiaki Yamasaki, Yasuhito Oshima
  • Patent number: 7270933
    Abstract: An organic anti-reflective coating composition and a method for forming a photoresist pattern using the same in order to improve uniformity of the pattern in an ultra-fine pattern formation process of the photoresist. In one aspect, organic anti-reflective coating composition contains a light absorbent agent, a cross-linking agent, a thermal acid generator, and a formanilide photo-base generator.
    Type: Grant
    Filed: November 2, 2004
    Date of Patent: September 18, 2007
    Assignee: Hynix Semiconductor Inc.
    Inventor: Jae Chang Jung
  • Patent number: 7244543
    Abstract: A positive-working lithographic printing starting plate for an infrared laser is provided that includes a support having a hydrophilic surface and a heat-sensitive layer provided above the support. The heat-sensitive layer includes a water-insoluble and alkali-soluble resin, an infrared-absorbing dye, and a sulfonium salt represented by Formula below. The heat-sensitive layer increases its solubility in aqueous alkaline solution upon exposure to an infrared laser.
    Type: Grant
    Filed: September 22, 2004
    Date of Patent: July 17, 2007
    Assignee: Fujifilm Corporation
    Inventor: Toshiaki Aoai
  • Patent number: 7238462
    Abstract: This invention provides an undercoating layer material and a filler material containing a resin component having at least a substituent group which is capable of releasing a terminal group to form a sulfonic acid residue upon application of predetermined energy, and a solvent. The resin component has at least a repeating unit represented by formula (1): wherein n is an integer of 1 or more, X represents a C1 to C10 linear or branched alkyl chain, an aromatic or alicyclic alkyl chain or an alkyl ester chain, and Y is a substituent group forming a sulfonic acid residue upon application of predetermined energy.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: July 3, 2007
    Assignee: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Etsuko Nakamura, Kazumasa Wakiya
  • Patent number: 7235346
    Abstract: The present invention relates to a photosensitive flexographic printing element for the production of flexographic newspaper printing plates, comprising at least a flexible, metallic support, an adhesive layer applied thereto, a photopolymerizable layer which can be developed in organic media and which itself comprises at least one elastomeric binder, ethylenically unsaturated monomers, a photoinitiator or photoinitiator system and a plasticizer, a transparent substrate layer, and optionally a removable protective film, where the total thickness of the flexographic printing element is from 300 to 1000 ?m, the elastomeric binder has a weight average molecular weight Mw of from 80,000 to 150,000 g/mol and a Shore A hardness of from 50 to 80, and the amount of plasticizer is from 5 to 50% by weight, based on the amount of all constituents of the photopolymerizable layer, and to a process for the production of flexographic newspaper printing plates by imagewise exposure of the flexographic printing element to act
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: June 26, 2007
    Assignee: XSYS Print Solutions Deutschland GmbH
    Inventors: Rolf Knöll, Hartmut Sandig, Uwe Stebani, Thomas Telser, Thomas Zwez
  • Patent number: 7229744
    Abstract: A method for preparing lithographic printing plates is disclosed. Imaged positive-working, thermally imageable, multi-layer imageable elements useful as lithographic printing plate precursors are developed using solvent based developers. Development may be carried out by immersing the imaged imageable element in the developer.
    Type: Grant
    Filed: March 21, 2003
    Date of Patent: June 12, 2007
    Assignee: Eastman Kodak Company
    Inventor: Jayanti Patel
  • Patent number: 7205094
    Abstract: A coating fluid for printing plates which can be suitably used to make printing plates that permit images to be written in response to input digital data and that can be easily regenerated and reused. This coating fluid for printing plates comprises at least a carrier liquid, thermoplastic resin particles and an IR absorber, and the IR absorber has a decomposition starting temperature higher than the melt starting temperature of the thermoplastic resin particles.
    Type: Grant
    Filed: October 13, 2004
    Date of Patent: April 17, 2007
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Yasuharu Suda, Hideaki Sakurai, Toyoshi Ohto
  • Patent number: 7205087
    Abstract: New photoresists are provided that are suitable for short wavelength imaging, including sub-200 nm, particularly 193 nm. Resists of the invention comprise a polymer that is preferably substantially free of aromatic moieties and comprises photoacid-labile repeat units, a photoactive components such as one or more photoacid generator compounds and a solvent component that comprises methyl isoamyl ketone (5-methyl-2-hexanone).
    Type: Grant
    Filed: April 18, 2003
    Date of Patent: April 17, 2007
    Assignee: Shipley Company, L.L.C.
    Inventors: Robert J. Kavanagh, James W. Thackeray
  • Patent number: 7198876
    Abstract: A method for preparation of a lithographic printing plate, which comprises the steps of: imagewise recording on a lithographic printing plate precursor comprising a support having a hydrophilic surface and a thermosensitive layer, the thermosensitive layer comprising at least one of polymer particles and a microcapsule encapsulating an oleophilic compound therein; and rubbing the printing plate precursor by a rubbing member in the presence of a processing liquid to remove the thermosensitive layer of non-image portions.
    Type: Grant
    Filed: April 23, 2003
    Date of Patent: April 3, 2007
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshifumi Inno
  • Patent number: 7198883
    Abstract: A positive-working, heat-sensitive material for making a lithographic printing plate by direct-to-plate recording is disclosed. The material comprises a hydrophobized grained and anodized aluminum support and a layer comprising a compound capable of converting light into heat provided onto said support, said support being obtainable by RF plasma treatment of a grained and anodized aluminum support in the presence of a fluorine containing gas.
    Type: Grant
    Filed: September 16, 2005
    Date of Patent: April 3, 2007
    Assignee: AGFA-Gevaert
    Inventors: Hieronymus Andriessen, Catherine Brigouleix, Alain Tressaud
  • Patent number: 7192691
    Abstract: A method of manufacturing a light sensitive planographic printing plate which has an image forming layer containing (A) a coloring material having an absorption in a wavelength range of 700 nm through 1200 nm and (B) a radical generator on a support and is exposed by a laser beam with a light emission wavelength in a wavelength range of 700 nm through 1200 nm, the method comprising: at least coating process, dry process, cutting process, and inspection/sorting process, wherein either of the coating process, the dry process, the cutting process, or the inspection/sorting process is carried out under light of a light source comprising a light-emitting diode with an emission wavelength maximum in a range of 400 nm through 500 nm and a fluorescent phosphor to emit an yellow light by absorbing a light emission of the light-emitting diode.
    Type: Grant
    Filed: August 11, 2005
    Date of Patent: March 20, 2007
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventor: Kazuhiko Hirabayashi
  • Patent number: 7189494
    Abstract: The present invention provides an imageable element including a lithographic substrate and an imageable layer disposed on the substrate. The imageable layer includes a radically polymerizable component, an initiator system, and a polymeric binder. The imageable element further includes a tetraarylborate salt. The presence of the tetraarylborate salt may provide improved imaging speed and may enhance press life due to better adhesion between the imageable layer and the substrate. The tetraarylborate salt may be present in the imageable layer, an interlayer, or a separate layer between the substrate and the imageable layer. The imageable element may be imaged and mounted on-press without a separate development step.
    Type: Grant
    Filed: May 26, 2005
    Date of Patent: March 13, 2007
    Assignee: Eastman Kodak Company
    Inventors: Elizabeth Knight, Paul R. West
  • Patent number: 7175964
    Abstract: Disclosed is a manufacturing process of a printing plate material comprising a boehmite treated aluminum support, and provided thereon, an image formation layer containing water soluble resins or water dispersible resins, the process comprising the steps of surface roughening an aluminum plate, anodizing the surface roughened aluminum plate, boehmite treating the anodized aluminum plate to produce the boehmite treated aluminum support having boehmite protrusions with an average height of from 30 to 200 nm and an average base size of from 10 to 100 nm, coating a coating solution for the image formation layer on the resulting aluminum support to form a coated layer, and drying the coated layer to form the image formation layer on the aluminum support.
    Type: Grant
    Filed: January 18, 2005
    Date of Patent: February 13, 2007
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventor: Yasunobu Kobayashi
  • Patent number: 7159511
    Abstract: A manufacturing line for manufacturing a print belt comprising a support-forming strip and a photopolymerized resin forming printing characters, the line comprises spreader means adapted to spread the resin on the strip, photopolymerizer means adapted to solidify that portion of the resin that is to correspond to the printing characters, remover means adapted to remove the non-photopolymerized resin from the strip, and drive means adapted to drive the strip in translation in such a manner that each of its transverse sections passes in succession in register with the spreader means, the photopolymerizer means, and the remover means.
    Type: Grant
    Filed: June 6, 2003
    Date of Patent: January 9, 2007
    Assignee: Chevrillon-Philippe Industrie
    Inventors: Arnaud De Ponnat, Mickael Bernou, Damien Leleu, Faye Renaud
  • Patent number: 7153627
    Abstract: A negative-working CTP plate which is superior in resolution and printing resistance of the image area of a press plate is provided, which is obtained by forming a latent image on a heat-sensitive layer in a heat-sensitive lithographic printing plate comprising a substrate having a hydrophilic surface and a heat-sensitive layer made of an alkali-soluble polymer formed on the surface of the substrate, using heat generated upon irradiation with laser light, and developing the heat-sensitive layer using an alkaline developing solution. In the heat-sensitive lithographic printing plate comprising a substrate having a hydrophilic surface, and a heat-sensitive layer made of an alkali-soluble polymer formed on the surface of the substrate, an advancing contact angle (?f1) of the surface of the heat-sensitive layer with water at 25° C. is within a range from 70° to 110°, a receding contact angle (?b2) of the surface of the heat-sensitive layer with water at 25° C. after heating at 150° C.
    Type: Grant
    Filed: September 12, 2003
    Date of Patent: December 26, 2006
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Yasuyuki Watanabe, Naohito Saito, Hisatomo Yonehara, Yasuyuki Suzuki
  • Patent number: 7150962
    Abstract: A method for forming images on a silver halide color photographic photosensitive material having a substrate and photographic structural layers thereon, including at least three silver halide color photosensitive layers having different photosensitive regions, respectively, and at least one non-photosensitive hydrophilic colloid layer, is disclosed. At least one of the photosensitive layers contains 90 mol % or more of silver chloride. Shortly after the silver halide color photographic photosensitive material has been scan-exposed with laser beams, the material is rapid-processed with a low replenishing amount.
    Type: Grant
    Filed: January 18, 2006
    Date of Patent: December 19, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Ohshima, Akito Yokozawa, Naoya Shibata
  • Patent number: 7147986
    Abstract: A compound including a polymeric chain, and an acid labile group attached to the polymeric chain at an anhydride linkage is disclosed. Compositions including the compound, and methods of using the compositions are also disclosed.
    Type: Grant
    Filed: March 31, 2004
    Date of Patent: December 12, 2006
    Assignee: Intel Corporation
    Inventors: Wang Yueh, Heidi B. Cao
  • Patent number: 7138219
    Abstract: Disclosed is a planographic printing plate material comprising a hydrophilic support and provided thereon, a light sensitive layer and an overcoat layer in that order, wherein the light sensitive layer contains (a) an alkali soluble polymer, (b) a polymerizable compound having an ethylenically unsaturated bond, (c) a polymerization initiator, and (d) an anionic dye represented by the following formula (1),
    Type: Grant
    Filed: August 20, 2004
    Date of Patent: November 21, 2006
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventor: Takaaki Kuroki
  • Patent number: 7081331
    Abstract: An improved method of manufacturing a photosensitive printing element that minimizes relief variation and improves image fidelity. The method involves a step of pre-curing the first (floor layer) of photocurable material prior to depositing an additional layer or layers of photocurable material that may be imaged and developed to produce a desired relief image on the surface of the photosensitive printing element. The photosensitive printing element is then thermally developed by contacting the photosensitive printing element with at least one roll that is capable of moving over at least a portion of the imaged surface of the flexographic printing element to remove the softened or melted non-crosslinked photopolymer.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: July 25, 2006
    Inventor: Ryan Vest
  • Patent number: 7081330
    Abstract: A method of making a printing plate from a heat-sensitive PS plate of a positive-working mode for lithographic printing includes the steps of exposing the heat-sensitive PS plate to light and developing the PS plate using an alkaline developing solution containing at least one compound selected from the group consisting of cationic surfactants and compounds having three or more of an ethylene oxide-terminal group in the molecule thereof. The PS plate has a substrate and an image forming layer formed thereon, said image forming layer comprising a lower layer which is formed on the substrate and contains a water-insoluble and alkali-soluble resin and an upper heat-sensitive layer which is overlaid on the lower layer and contains a water-insoluble and alkali-soluble resin and an infrared absorption dye and exhibits an elevated solubility with respect to alkaline aqueous solutions when heated.
    Type: Grant
    Filed: September 17, 2003
    Date of Patent: July 25, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shuichi Takamiya
  • Patent number: 7063937
    Abstract: A method for making a lithographic printing plate comprising the steps of: light-exposing to infrared radiation, a heat-sensitive presensitized plate of a positive-working mode for use in making a lithographic printing plate, said presensitized plate comprising a substrate and an image recording layer which is formed thereon and comprises a novolak resin containing xylenol as a monomer component and an infrared absorbing dye; and developing the light-exposed plate with an alkaline developing solution comprising at least one surfactant selected from the group consisting of anionic surfactants and amphoteric surfactants.
    Type: Grant
    Filed: March 25, 2004
    Date of Patent: June 20, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shuichi Takamiya
  • Patent number: 7060417
    Abstract: An automated method of preventing edge curing of cut surfaces of photosensitive printing elements is disclosed. Once a photosensitive printing element is cut in a pattern of a desired size and shape, a portion of the coversheet on a periphery of the cut edges of the printing plate is removed, while leaving intact the layer of photocurable material and the optional ablation layer beneath the coversheet. Next, an edge cure prevention composition is applied to the optional ablation layer or the layer of photocurable material revealed by the removal of the portion of the coversheet. Once the edge cure prevention composition is dried, the remainder of the coversheet may be removed from the photosensitive printing element and the printing element may be mounted on a sleeve or cylindrical carrier for further processing. The method ensures that the edge cure prevention composition is applied only to areas where it is needed and does not affect imageable areas of the printing plate.
    Type: Grant
    Filed: November 18, 2004
    Date of Patent: June 13, 2006
    Inventors: Chris Carlsen, David Recchia
  • Patent number: 7056642
    Abstract: A method of graft polymerization which includes a step of forming a polymerization initiating layer in which a polymer having, on a side chain thereof, a crosslinking group and a functional group having polymerization initiating capability is immobilized on a support by a crosslinking reaction, and a step of conatacting a compound having a polymerizable functional group with the polymerization initiating layer, and then bonding the compound to the polymerization initiating layer supplying energy thereto, as well as a hydrophilic member, a printing plate precursor, a pattern forming material, a pattern forming method, a method of producing a particle-adsorbed material, and a method of producing a metal particle-dispersed thin layer film, to which the above-mentioned method of graft polymerization can be applied.
    Type: Grant
    Filed: September 16, 2003
    Date of Patent: June 6, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takeyoshi Kano, Koichi Kawamura
  • Patent number: 7049045
    Abstract: Multilayer, positive working, thermally imageable, bakeable imageable elements are disclosed. The elements have a substrate, an underlayer, and a top layer. The underlayer comprises a resin or resins having activated methylol and/or activated alkylated methylol groups, such as a resole resin, and a polymeric material that comprises, in polymerized form about 5 mol % to about 30 mol % of methacrylic acid; about 20 mol % to about 75 mol % of N-phenylmaleimide, N-cyclohexylmaleimide, N-benzylmaleimide, or a mixture thereof; optionally, about 5 mol % to about 50 mol % of methacrylamide; and about 3 mol % to about 50 mol % of a compound represented by the formula: CH2C(R2)C(O)NHCH2OR1, in which R1 is C1 to C12 alkyl, phenyl, C1 to C12 substituted phenyl, C1 to C12 aralkyl, or Si(CH3)3; and R2 is H or methyl. The elements produce bakeable lithographic printing plates that are resistant to press chemistries.
    Type: Grant
    Filed: August 14, 2003
    Date of Patent: May 23, 2006
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Paul Kitson, Kevin B. Ray, S. Peter Pappas
  • Patent number: 7045269
    Abstract: A method for forming images useful as lithographic printing plate precursors is disclosed. An imageable element in which the imageable layer comprises an acid generator, a crosslinking agent, and a binder is imaged with ultraviolet radiation and developed with a solvent based developer. The acid generator is an iodonium, sulfonium, or diazonium salt in which the anion is an organic sulfate or thiosulfate anion. The binder comprises a copolymer that contains a reactive pendent group capable of undergoing acid crosslinking, in which the reactive pendent group is hydroxyl, carboxylic acid, sulfonamide, alkoxymethyl, or a mixture thereof. The method is especially suited for use with direct digital ultraviolet imaging devices. The resulting image is useful as a lithographic printing plate.
    Type: Grant
    Filed: November 21, 2003
    Date of Patent: May 16, 2006
    Assignee: Eastman Kodak Company
    Inventors: Jeffrey Collins, Thomas Jordan, Joanne Ray, Ting Tao, Chris McCullough, Scott A. Beckley, Jianbing Huang
  • Patent number: 7033089
    Abstract: The present invention provides a resist development processor consisting of a development processing chamber for storing a resist substrate having an exposed resist on the substrate and for developing the exposed resist by means of a development solvent consisting of a supercritical fluid; and a supercritical fluid container for storing a supercritical fluid, where the supercritical fluid container is connected to the development processing chamber through a valve.
    Type: Grant
    Filed: November 13, 2003
    Date of Patent: April 25, 2006
    Assignee: Hitachi Science Systems, Ltd.
    Inventors: Hisayuki Takasu, Kouichi Miyazawa, Toru Iwaya
  • Patent number: 7018773
    Abstract: Disclosed are a printing plate material comprising a substrate and provided thereon, a component layer comprising a hydrophilic layer and an image formation layer, the hydrophilic layer being provided closer to the substrate than the image formation layer, wherein the hydrophilic layer contains an electron providing dye precursor, the image formation layer contains an organic electron accepting developing agent, and the component layer contains a light heat conversion material.
    Type: Grant
    Filed: September 22, 2003
    Date of Patent: March 28, 2006
    Assignee: Konica Corporation
    Inventor: Takahiro Mori
  • Patent number: 7018777
    Abstract: A method of making a printing plate from a heat-sensitive PS plate of a positive-working mode for lithographic printing includes the steps of exposing the heat-sensitive PS plate to light and developing the PS plate using an alkaline developing solution containing at least one surfactant selected from the group consisting of anionic surfactants and ampholytic surfactants, and a salt selected from the group consisting of alkali metal salts and ammonium cation salts. The PS plate has a substrate and an image forming layer formed thereon, the image forming layer including a lower layer which is formed on the substrate and contains a water-insoluble and alkali-soluble resin and an upper heat-sensitive layer which is overlaid on the lower layer and contains a water-insoluble and alkali-soluble resin and an infrared absorption dye and exhibits an elevated solubility with respect to alkaline aqueous solutions when heated.
    Type: Grant
    Filed: September 10, 2003
    Date of Patent: March 28, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hironori Ohnishi