With Specified Binder Resin In Transport Layer Patents (Class 430/59.6)
  • Publication number: 20110189603
    Abstract: Electrophotographic photoconductor including a conductive substrate; and a photosensitive layer provided on the conductive substrate and including at least a charge generation material; a charge transport material; and a resin binder including a copolymer polyarylate resin represented by general formula (I) below: and manufacturing method therefore. Good images with less cracking occurrence are obtained during recycling of a photosensitive drum and peripheral members thereof that includes the electrophotographic photoconductor, and also when a liquid development process is employed.
    Type: Application
    Filed: April 2, 2009
    Publication date: August 4, 2011
    Applicant: FUJI ELECTRIC SYSTEMS CO., LTD.
    Inventors: Ikuo Takaki, Yoichi Nakamura, Seizo Kitagawa, Kazuki Nebashi, Fengqiang Zhu
  • Patent number: 7985522
    Abstract: Disclosed is an electrophotographic photoreceptor which is excellent in wear resistance and electrical characteristics. Specifically disclosed is an electrophotographic photoreceptor containing a polyester resin in a photosensitive layer provided on an electroconductive substrate. The polyester resin is composed of a copolymer represented by the general formula 1 below, which has a viscosity average molecular weight (Mv) of 10,000-300,000 and contains a diphenyl ether 4,4?-dicarboxylic acid component and a bivalent phenol component. In the general formula 1, A represents a diphenyl ether 4,4?-dicarboxylic acid residue represented by the formula A below, and B represents a bivalent phenol residue represented by the formula B below. In the formula A, each of Ra1 and Ra2 independently represents a hydrogen atom or a monovalent substituent which may have a substituent, and each of n and m is independently an integer from 0 to 4.
    Type: Grant
    Filed: October 6, 2008
    Date of Patent: July 26, 2011
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hiroyuki Tajima, Yuuta Kumano
  • Patent number: 7955769
    Abstract: Embodiments of a photoconductor for use in a printer or printer cartridge comprise an electrically conductive substrate, a charge generation layer disposed over the electrically conductive substrate, and a charge transport layer disposed over the charge generation layer, wherein the charge transport layer comprises charge transport molecules with octyl/decyl glycidyl ether (OGE) or dodecyl/tetradecyl glycidyl ether (DGE), or combinations thereof, added to improve resistance to crazing, cracking and crystallization in the change transport layer.
    Type: Grant
    Filed: February 12, 2008
    Date of Patent: June 7, 2011
    Assignee: Lexmark International, Inc.
    Inventors: David Glenn Black, James Alan Hartman, Ronald Harold Levin, Weimei Luo, Dat Quoc Nguyen, Tanya Yvonne Thames
  • Patent number: 7951516
    Abstract: The electrophotographic photoreceptor of the present invention includes a cylindrical support; a charge-generating layer and a charge-transporting layer that are layered onto the cylindrical support in this sequence from the cylindrical support side. The charge-transporting layer includes a charge transport material, and resins including a curable resin and a thermoplastic resin. The proportion of the content of the curable resin with respect to the total amount of the resins in the charge-transporting layer increases in the layer thickness direction with distance from the charge-generating layer side.
    Type: Grant
    Filed: May 29, 2007
    Date of Patent: May 31, 2011
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Tomotake Inagaki, Kazuyuki Tada, Tomomasa Sato, Naoki Morita, Kenji Ikeda
  • Patent number: 7935465
    Abstract: Disclosed is an electrophotographic imaging member that includes a lubricant delivering coating having a polymer matrix, a charge transport component, and a lubricant encapsulated within nano- or microcapsules. Also disclosed is an imaging forming apparatus including a charging device, a toner developer device, a cleaning device, and a photoreceptor having a conductive substrate, a charge generating layer, a charge transport layer, and an optional overcoat layer, such that the outmost layer of the photoreceptor contains a lubricant encapsulated within nano- or microcapsules. Additionally provided is a method of forming an image with the disclosed electrophotographic imaging member.
    Type: Grant
    Filed: March 3, 2008
    Date of Patent: May 3, 2011
    Assignee: Xerox Corporation
    Inventors: Kathy L. De Jong, Nan-Xing Hu, Giuseppa Baranyi
  • Publication number: 20110091799
    Abstract: In an electrophotographic photoreceptor having a photosensitive layer on an electroconductive substrate, the photosensitive layer is a positive-charging laminate comprising at least a charge transport layer and a charge generating layer laminated in that order, with the charge generating layer containing at least a resin binder, a charge generating agent, a space filler and an electron transport agent, while the charge transport layer contains at least, as a resin binder, polystyrene and a hole transport agent, and mineral oil of the charge transport layer is in an amount of 1% by mass or less of an amount of polystyrene. Thus, a highly durable and economic positive-charging multilayer electrophotographic photoreceptor and a manufacturing method therefor may be achieved.
    Type: Application
    Filed: May 28, 2009
    Publication date: April 21, 2011
    Inventors: Yoichi Nakamura, Seizo Kitagawa, Hiroshi Emori, Yasushi Tanaka, Hiroyuki Ichiyanagi
  • Patent number: 7927774
    Abstract: An object of the present invention is to provide an electrophotographic photosensitive member having high durability and hardly causing sensitivity decrease even if short wavelength light, particularly light having a wavelength of 380 to 450 nm is used as exposure light, and a process cartridge and an electrophotographic apparatus having the electrophotographic photosensitive member. The present invention includes an electrophotographic photosensitive member comprising a support and a photosensitive layer which is provided on the support and contains a charge generation material and a charge transport material, characterized in that the surface layer of the electrophotographic photosensitive member contains an aliphatic dicarboxylic acid polyester resin with a weight average molecular weight of 80,000 or more having a specific repeating structural unit, and a process cartridge and an electrophotographic apparatus having the electrophotographic photosensitive member.
    Type: Grant
    Filed: September 8, 2009
    Date of Patent: April 19, 2011
    Assignee: Canon Kabushiki Kaisha
    Inventors: Harunobu Ogaki, Takakazu Tanaka, Kenichi Kaku, Akira Yoshida
  • Patent number: 7923187
    Abstract: The presently disclosed embodiments are directed to charge transport layers useful in electrostatography. More particularly, the embodiments pertain to an improved electrostatographic imaging member having a charge transport layer that is partially crosslinked, wherein the crosslinking is achieved by incorporating a small amount of compatible thermalsetting resins into the layer. Incorporation of these resins have been shown to increase charge transport life.
    Type: Grant
    Filed: August 21, 2007
    Date of Patent: April 12, 2011
    Assignee: Xerox Corporation
    Inventors: Liang-Bih Lin, Daniel V. Levy
  • Patent number: 7923188
    Abstract: The presently disclosed embodiments are directed to charge transport layers useful in electrostatography. More particularly, the embodiments pertain to an improved electrostatographic imaging member having a charge transport layer that is partially crosslinked, wherein the crosslinking is achieved by incorporating a small amount of compatible thermalsetting resins into the layer. Incorporation of these resins have been shown to increase charge transport life.
    Type: Grant
    Filed: August 21, 2007
    Date of Patent: April 12, 2011
    Assignee: Xerox Corporation
    Inventors: Liang-Bih Lin, Daniel V. Levy, Jin Wu, Robert W. Hedrick, Linda Ferrarese
  • Patent number: 7901855
    Abstract: A charge transport layer serving as a surface layer of an electrophotographic photosensitive member contains a polyester resin having a repeating structural unit represented by the following formula (1) and a repeating structural unit represented by the following formula (2), as a binder resin; the content of a siloxane moiety of the polyester resin is not less than 5% by mass and not more than 30% by mass relative to the total mass of the polyester resin; and the content of the polyester resin in the charge transport layer is not less than 60% by mass relative to the total mass of the whole binder resin in the charge transport layer.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: March 8, 2011
    Assignee: Canon Kabushiki Kaisha
    Inventors: Harunobu Ogaki, Hiroki Uematsu, Atsushi Ochi
  • Publication number: 20110053069
    Abstract: Embodiments pertain to a flexible imaging member used in electrostatography and processes for making and using the imaging member. More particularly, the embodiments pertain to a structurally simplified flexible electrophotographic imaging member that has reasonable flatness and exhibits good performance without the need of an anticurl back coating layer.
    Type: Application
    Filed: August 31, 2009
    Publication date: March 3, 2011
    Applicant: XEROX CORPORATION
    Inventors: Robert C. U. Yu, Yuhua Tong, Stephen T. Avery, Michael S. Roetker, Jimmy E. Kelly
  • Publication number: 20110053068
    Abstract: Embodiments pertain to a flexible imaging member used in electrostatography and processes for making and using the imaging member. More particularly, the embodiments pertain to a structurally simplified flexible electrophotographic imaging member that has reasonable flatness and exhibits good performance without the need of an anticurl back coating layer.
    Type: Application
    Filed: August 31, 2009
    Publication date: March 3, 2011
    Applicant: XEROX CORPORATION
    Inventors: Robert C. U. Yu, Yuhua Tong, Stephen T. Avery, Michael S. Roetker
  • Patent number: 7893185
    Abstract: A polycarbonate copolymer contains: 0.1 to 50 mol % of a monomer unit represented by the following formula (1); and a monomer unit represented by the following formula (2). In the polycarbonate copolymer, the content of biphenols having a structure represented by the following formula (3) is 90 mass ppm or less. In the formula, R1 and R2 each independently represent a hydrogen atom, an aliphatic hydrocarbon group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms or a halogen atom. In the formula: R3 and R4 each independently represent a hydrogen atom, an aliphatic hydrocarbon group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms or a halogen atom; and X represents any one of bonding groups represented by —O—, —S—, —SO—, —SO2—, —CO— and 9,9-fluorenylidene group. In the formula, R1 and R2 each independently represent a hydrogen atom, an aliphatic hydrocarbon group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms or a halogen atom.
    Type: Grant
    Filed: October 18, 2007
    Date of Patent: February 22, 2011
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Takaaki Hikosaka, Yasushi Hamada
  • Publication number: 20110027705
    Abstract: A photoconductor that includes, for example, a substrate, an optional ground plane layer, an undercoat layer thereover, wherein the undercoat layer contains an aminosilane and an epoxysilane, a photogenerating layer, and at least one charge transport layer.
    Type: Application
    Filed: July 29, 2009
    Publication date: February 3, 2011
    Applicant: XEROX CORPORATION
    Inventors: Jin Wu, Sherri A Toates, J. Robinson Cowdery-Corvan, Mark Muscato, Richard A Williams, Marc J Livecchi, Linda L Ferrarese
  • Patent number: 7875410
    Abstract: A charge transport layer serving as a surface layer of an electrophotographic photosensitive member contains a charge transporting material, polyester resin A containing a siloxane moiety and at least one of polyester resin C and polycarbonate resin D. The content of a siloxane moiety in polyester resin A is not less than 10% by mass and not more than 40% by mass relative to the total mass of polyester resin A. The charge transport layer has a matrix-domain structure having a matrix formed of the charge transporting material and at least one of polyester resin C and polycarbonate resin D and a domain formed of polyester resin A in the matrix.
    Type: Grant
    Filed: December 14, 2009
    Date of Patent: January 25, 2011
    Assignee: Canon Kabushiki Kaisha
    Inventors: Harunobu Ogaki, Hiroki Uematsu, Atsushi Ochi
  • Patent number: 7867677
    Abstract: Provided is an imaging member such as photoreceptor comprising a substrate, a charge generation layer, a first charge transport layer, a second charge transport layer, and an optional overcoat layer. The first charge transport layer is formed from a first CTL formulation comprising an aromatic monoamine and a first polymeric film forming binder material. The second charge transport layer is formed from a second CTL formulation comprising aromatic diamine and a second polymeric film forming binder material. The imaging member has gained improved properties such as removal of anti-curl layer, desirable structural flatness, electrical properties, mechanical robustness, flexibility, longevity, and copy image qualities over extended use, among others.
    Type: Grant
    Filed: September 16, 2009
    Date of Patent: January 11, 2011
    Assignee: Xerox Corporation
    Inventors: Yuhua Tong, John F. Yanus, Jin Wu, Steven M. Sterling, Susan M. VanDusen
  • Publication number: 20100330476
    Abstract: A photoconductor that includes a photogenerating layer and a charge transport layer containing a charge transport component, a fluorinated polymer, and a core shell component, and wherein the core is comprised of a metal oxide and the shell is comprised of silica.
    Type: Application
    Filed: June 29, 2009
    Publication date: December 30, 2010
    Applicant: XEROX CORPORATION
    Inventors: Jin Wu, Kenny-Tuan T. Dinh, Linda L. Ferrarese, Marc J. Livecchi, Edward C. Savage, Michael E. Zak
  • Patent number: 7858278
    Abstract: An electrophotographic photoreceptor is provided, including an electroconductive substrate and a photosensitive layer located overlying the electroconductive substrate, wherein an outermost layer of the electrophotographic photoreceptor includes a resin including a graft copolymer in which a monomer having a polar group is graft polymerized to a polycarbonate resin, a polyarylate resin, or a copolymer thereof, and a filler; along with an image forming apparatus and a process cartridge using the electrophotographic photoreceptor.
    Type: Grant
    Filed: May 18, 2007
    Date of Patent: December 28, 2010
    Assignee: Ricoh Company Limited
    Inventors: Hiroshi Ikuno, Masafumi Ohta, Tomoyuki Shimada, Yuuji Tanaka, Hongguo Li
  • Patent number: 7851113
    Abstract: Overcoat layers, which may be useful for reducing torque in electrophotographic photoreceptors, are provided. The overcoat layers include a polymer matrix having a particulate inorganic lubricant and a particulate fluoropolymer uniformly dispersed therein. Also provided are electrophotographic photoreceptors that include a substrate and the overcoat layers, electrophotographic imaging apparatuses that include such photoreceptors, and methods for forming the photoreceptors.
    Type: Grant
    Filed: December 13, 2006
    Date of Patent: December 14, 2010
    Assignee: Xerox Corporation
    Inventors: Timothy P. Bender, Nan-Xing Hu, John F. Graham, Yvan Gagnon, Cheng-Kuo Hsiao, Sandra J. Gardner, Kathy L. De Jong, James M. Markovics
  • Patent number: 7838189
    Abstract: An imaging member containing a substrate, and an outer layer containing a sulfur-containing additive, and an image forming apparatus for forming images on a recording medium including the imaging member above, a development component to apply a developer material to the charge-retentive surface to develop the electrostatic latent image to form a developed image on the charge-retentive surface; a transfer component to transfer the developed image from the charge-retentive surface to another member or a copy substrate; and a fusing member to fuse the developed image to the copy substrate.
    Type: Grant
    Filed: November 3, 2005
    Date of Patent: November 23, 2010
    Assignee: Xerox Corporation
    Inventors: Jin Wu, James R. Backus, Linda L. Ferrarese, Liang-Bih Lin
  • Patent number: 7838190
    Abstract: An electrophotographic photosensitive member having excellent electrophotographic properties, a method of manufacturing the electrophotographic photosensitive member, and a process cartridge and an electrophotographic apparatus each having the electrophotographic photosensitive member are provided. The surface layer of the electrophotographic photosensitive member includes a polymer having a specific repeating structural unit and fluorine-atom-containing resin particles. The fluorine-atom-containing particles in the surface layer are dispersed so as to be provided with particle sizes almost up to those of primary particles.
    Type: Grant
    Filed: January 14, 2009
    Date of Patent: November 23, 2010
    Assignee: Canon Kabushiki Kaisha
    Inventors: Harunobu Ogaki, Nobumichi Miki, Kazunori Noguchi, Nobuo Kosaka
  • Patent number: 7811729
    Abstract: Disclosed is an imaging member comprising a conductive substrate, a photogenerating layer comprising a photogenerating material in contact with the substrate, a first charge transport layer in contact with the photogenerating layer, the first charge transport layer comprising a charge transport material and a polymer containing carboxylic acid groups or groups capable of forming carboxylic acid groups, and a second charge transport layer in contact with the first charge transport layer, the second charge transport layer comprising a charge transport material and a hydroquinone antioxidant, wherein the first charge transport layer is situated between the second charge transport layer and the photogenerating layer.
    Type: Grant
    Filed: December 11, 2008
    Date of Patent: October 12, 2010
    Assignee: Xerox Corporation
    Inventors: Gregory McGuire, Ah-Mee Hor
  • Patent number: 7811728
    Abstract: An imaging member including a substrate; thereover a charge generating layer; thereover a first charge transport layer comprising a small molecule charge transport material and a polymeric component selected from the group consisting of polyarylamine polyester, polyacylamine, and mixtures and combinations thereof; and a second charge transport layer disposed over the first charge transport layer, the second charge transport layer comprising a small molecule charge transport material and a binder, wherein the second charge transport layer is free of polyarylamine polyester and polyacylamine.
    Type: Grant
    Filed: December 1, 2006
    Date of Patent: October 12, 2010
    Assignee: Xerox Corporation
    Inventors: David M. Skinner, John F. Yanus, Markus R. Silvestri, M. John Hinckel, Kenny-Tuan T. Dinh, Susan VanDusen, Satish Parikh, J. Robinson Cowdery-Corvan
  • Patent number: 7807324
    Abstract: An imaging member containing an optional supporting substrate, a photogenerating layer, a charge transport layer, and an overcoat layer comprised, for example, of a phenolic resin containing a phenolic charge transport component.
    Type: Grant
    Filed: September 15, 2006
    Date of Patent: October 5, 2010
    Assignee: Xerox Corporation
    Inventors: Nan-Xing Hu, Yvan Gagnon, Ah-Mee Hor
  • Patent number: 7803507
    Abstract: An electrophotographic photoreceptor of high durability capable of providing stable excellent electrical characteristics over a prolonged period of time, which electrophotographic photoreceptor excels in mechanical strength. A photosensitive layer (14) of an electrophotographic photoreceptor (1) includes a polyarylate resin having structural units, for example, those of formula (1) and an enamine compound represented by, for example, formula (2) The variables R1, R2, R3, R4, R7˜R10, X1, Ar1, Ar2, Ar3, Ar4, Ar5, R11, R12, R13, R14, a, m, and n are as defined in the specification. By virtue of these, the electrophotographic photoreceptor (1) of excellent mechanical strength and favorable electrical characteristics can be realized.
    Type: Grant
    Filed: February 6, 2004
    Date of Patent: September 28, 2010
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Tatsuhiro Morita, Tomoko Kanazawa, Akihiro Kondoh, Yohichi Takesawa, Takatsugu Obata, Shinya Mimura, Hiroshi Sugimura
  • Patent number: 7799496
    Abstract: An electrophotographic photosensitive member having excellent electrophotographic properties while being prevented from the generation of blade turn-up, a method of manufacturing the electrophotographic photosensitive member, and a process cartridge and an electrophotographic apparatus each having the electrophotographic photosensitive member are provided. The surface layer of the electrophotographic photosensitive member contains a polymer having a specific repeating structural unit.
    Type: Grant
    Filed: April 15, 2008
    Date of Patent: September 21, 2010
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hirotoshi Uesugi, Yukihiro Abe, Daisuke Miura, Nobumichi Miki, Harunobu Ogaki
  • Patent number: 7781134
    Abstract: A photoreceptor is provided having an electroconductive substrate and a photosensitive layer located overlying the electroconductive substrate, wherein an outermost layer of the photoreceptor contains a binder resin, wherein the binder resin solution satisfies the following relationship 2?(T0?T400)/C wherein T0 represents a initial transmittance (%) at 400 nm of the binder resin solution; T400 represents a transmittance (%) at 400 nm of the binder resin solution which has been allowed to settle for 400 hours under conditions of 23° C. and 40% RH; and C represents the concentration of the binder resin solution; and an image forming method, an image forming apparatus and a process cartridge including the photoreceptor.
    Type: Grant
    Filed: December 27, 2005
    Date of Patent: August 24, 2010
    Assignee: Ricoh Company, Ltd.
    Inventors: Takeshi Takada, Takaaki Ikegami, Akihiro Sugino
  • Patent number: 7767373
    Abstract: Imaging members useful in electrostatographic apparatuses, including printers, copiers, other reproductive devices, and digital apparatuses. More particularly, imaging members having a binder of high molecular weight that is included in one or more layers of an imaging member to impart coating consistency and to provide for increased mechanical strength and improved wear.
    Type: Grant
    Filed: August 23, 2006
    Date of Patent: August 3, 2010
    Assignee: Xerox Corporation
    Inventors: Donald J. Goodman, Satish Parikh, Edward F. Grabowski, Kathleen M. Carmichael, David M. Skinner
  • Patent number: 7759032
    Abstract: An electrophotographic imaging member includes a substrate, a charge generating layer, a charge transport layer, and an overcoating layer, where the overcoating layer includes a terphenyl arylamine dissolved or molecularly dispersed in a polymer binder.
    Type: Grant
    Filed: December 13, 2005
    Date of Patent: July 20, 2010
    Assignee: Xerox Corporation
    Inventors: John F. Yanus, Kenny-Tuan T. Dinh, Markus R. Silvestri, Yuhua Tong, Dale S. Renfer, T. Edwin Freeman, M. John Hinckel
  • Patent number: 7740997
    Abstract: An electrophotographic imaging member includes a substrate, a photogenerating layer, and an optional overcoating layer, where the photogenerating layer includes a multi-block polymeric charge transport material at least partially embedded within a carbon nanotube material.
    Type: Grant
    Filed: August 8, 2006
    Date of Patent: June 22, 2010
    Assignee: Xerox Corporation
    Inventors: Timothy P. Bender, Nan-Xing Hu
  • Publication number: 20100151369
    Abstract: Disclosed is an imaging member comprising a conductive substrate, a photogenerating layer comprising a photogenerating material in contact with the substrate, and a charge transport layer in contact with the photogenerating layer, the charge transport layer comprising a charge transport material, a polymer containing carboxylic acid groups or groups capable of forming carboxylic acid groups, and a hydroquinone antioxidant, wherein the photogenerating layer is situated between the charge transport layer and the conductive substrate.
    Type: Application
    Filed: December 11, 2008
    Publication date: June 17, 2010
    Applicant: XEROX CORPORATION
    Inventors: Gregory McGuire, Ah-Mee Hor
  • Publication number: 20100151368
    Abstract: Disclosed is an imaging member comprising a conductive substrate, a photogenerating layer comprising a photogenerating material in contact with the substrate, a first charge transport layer in contact with the photogenerating layer, the first charge transport layer comprising a charge transport material and a polymer containing carboxylic acid groups or groups capable of forming carboxylic acid groups, and a second charge transport layer in contact with the first charge transport layer, the second charge transport layer comprising a charge transport material and a hydroquinone antioxidant, wherein the first charge transport layer is situated between the second charge transport layer and the photogenerating layer.
    Type: Application
    Filed: December 11, 2008
    Publication date: June 17, 2010
    Applicant: XEROX CORPORATION
    Inventors: Gregory McGuire, Ah-Mee Hor
  • Patent number: 7718337
    Abstract: The present invention relates to an electrophotographic photoreceptor comprising an electroconductive substrate and a photosensitive layer formed thereon, wherein the photosensitive layer contains a polyester resin consisting of a repeating ester structure consisting of at least one bivalent phenol residue having formula (1) and at least one of an aromatic dicarboxylic acid residue having formula (2): where, each of R1 to R4, which are independent of one another, represents hydrogen or a methyl group, and R5 represents a methyl group, where (i) R1 to R4 are hydrogen atoms; or (iii) R1 and R3 are methyl groups and R2 and R4 are hydrogen atoms, and where the polyester resin is a copolymer, and an amount of the repeating ester structure consisting of the bivalent phenol residue having the above formula (1) and the aromatic dicarboxylic acid residue having the above formula (2) is at least 10 wt % of the entire polyester resin of the copolymer.
    Type: Grant
    Filed: August 12, 2008
    Date of Patent: May 18, 2010
    Assignee: Mitsubishi Chemical Corporation
    Inventor: Yuuta Kumano
  • Patent number: 7704656
    Abstract: A photoreceptor comprising a charge transport layer doped with a polyarylate polymer is provided. A charge transport layer is doped with about 0.1 to about 10.0% by weight, solids basis, of a polyarylate polymer, such as for example Ardel. Charge transport layers doped with a polyarylate polymer exhibit improved electrical performance in terms of lower Vr and VBG values.
    Type: Grant
    Filed: March 23, 2005
    Date of Patent: April 27, 2010
    Assignee: Xerox Corporation
    Inventors: Min-Hong Fu, Kent J. Evans, David M. Skinner, Kathleen M. Carmichael, June E. Schneider, Susan M. VanDusen
  • Patent number: 7704657
    Abstract: An electrophotographic photosensitive member having excellent electrophotographic properties while being prevented from the generation of blade turn-up, a method of manufacturing the electrophotographic photosensitive member, and a process cartridge and an electrophotographic apparatus each having the electrophotographic photosensitive member are provided. The surface layer of the electrophotographic photosensitive member contains a polymer having a specific repeating structural unit.
    Type: Grant
    Filed: March 10, 2009
    Date of Patent: April 27, 2010
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hirotoshi Uesugi, Yukihiro Abe, Daisuke Miura, Nobumichi Miki, Harunobu Ogaki
  • Patent number: 7700250
    Abstract: A photoconductor containing an optional supporting substrate, a photogenerating layer thereover, and at least one charge transport layer, and wherein the photogenerating layer contains a chelating agent, and a Type V titanyl phthalocyanine prepared, for example, by dissolving a Type I titanyl phthalocyanine in a solution comprising a trihaloacetic acid and an alkylene halide; adding the mixture comprising the dissolved Type I titanyl phthalocyanine to a solution comprising an alcohol and an alkylene halide thereby precipitating a Type Y titanyl phthalocyanine; and treating the Type Y titanyl phthalocyanine with a monohalobenzene.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: April 20, 2010
    Assignee: Xerox Corporation
    Inventors: Jin Wu, John S. Chambers, Francisco J. Lopez, Daniel V. Levy, Liang-Bih Lin
  • Publication number: 20100092212
    Abstract: Disclosed is an electrophotographic photosensitive body which is remarkably improved in pencil scratch resistance and wear resistance. Specifically disclosed is an electrophotographic photosensitive body wherein a polycarbonate resin having a structural unit (1) represented by the formula below is used as a binder resin for a photosensitive layer (or for a charge-transporting layer in case of multilayer type) which is formed on a conductive base. [chemical formula 1] (1) (In the formula, R1-R30 respectively represent a hydrogen atom or a substituent selected from the group consisting of fluorine, chlorine, bromine, iodine, an alkyl group having 1-17 carbon atoms, an aryl group having 6-12 carbon atoms, an alkoxy group having 1-5 carbon atoms, an alkenyl group having 2-12 carbon atoms and an aralkyl group having 7-17 carbon atoms.
    Type: Application
    Filed: August 7, 2007
    Publication date: April 15, 2010
    Inventors: Noriyoshi Ogawa, Toru Oirawa
  • Publication number: 20100092209
    Abstract: A charge transport layer serving as a surface layer of an electrophotographic photosensitive member contains a polyester resin having a repeating structural unit represented by the following formula (1) and a repeating structural unit represented by the following formula (2), as a binder resin; the content of a siloxane moiety of the polyester resin is not less than 5% by mass and not more than 30% by mass relative to the total mass of the polyester resin; and the content of the polyester resin in the charge transport layer is not less than 60% by mass relative to the total mass of the whole binder resin in the charge transport layer.
    Type: Application
    Filed: December 17, 2009
    Publication date: April 15, 2010
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Harunobu Ogaki, Hiroki Uematsu, Atsushi Ochi
  • Publication number: 20100068640
    Abstract: An electrophotographic photoreceptor belt which is excellent in durability and therefore little cracks even when fingerprints of an operator or hand cream adheres to the belt, wherein a binder resin for photosensitive layers comprising as the main component a polycarbonate resin which comprises bisphenol A type constituent units represented by the formula (I) as the main constituent unit (preferably in an amount of at least 90% by weight based on the whole of the constituent units) and which has a limiting viscosity of 1 to 1.6 dl/g and preferably a molecular weight distribution of 3.2 to 4.3 as calculated from the weight-average molecular weight and number-average molecular weight determined by GPC is used in a photosensitive layer (particularly carrier transport layer) of the belt.
    Type: Application
    Filed: August 21, 2007
    Publication date: March 18, 2010
    Inventor: Noriyoshi Ogawa
  • Publication number: 20100047704
    Abstract: A long-life electrophotographic photosensitive body having excellent wear resistance and crack resistance can be obtained by using a polycarbonate resin composition, which is obtained by blending 0.01-5 parts by weight of a silicone-modified polyurethane per 100 parts by weight of a polycarbonate resin, as a binder for photosensitive layer (or in case when the photosensitive layer is of multilayer type, for at least an electron transport layer) of the electrophotographic photosensitive body. The silicone-modified polyurethane is obtained by reacting a diol component (a) represented by the general formula (I) below, an active hydrogen-containing polysiloxane compound (b), a polyisocyanate component (c) and, if necessary, a chain extender (d).
    Type: Application
    Filed: July 25, 2007
    Publication date: February 25, 2010
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Jun Tajima, Takahiro Adachi
  • Publication number: 20100015541
    Abstract: An electrophotographic photoreceptor which is excellent in wear resistance and crack resistance and has a long photoreceptor lifetime can be produced by using a polycarbonate resin composition prepared by blending 100 parts by weight of a polycarbonate resin with 0.01 to 5 parts by weight of a silicone-modified polyurethane obtained by reacting (a) a diol component represented by the general formula (I) with (b) an active hydrogen containing polysiloxane compound, (c) a polyisocyanate component and, if necessary, (d) a chain extender as the material for the backing film of a photoreceptor belt. [Chemical formula 1](I) wherein R1 and R2 are each independently hydrogen or alkyl; R3 is hydrogen, alkyl, alkoxy, halogeno or alkoxycarbonyl; M is a single bond, substituted or unsubstituted alkylene, or oxyalkylene; and n is an integer of 0 to 4.
    Type: Application
    Filed: August 21, 2007
    Publication date: January 21, 2010
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY
    Inventor: Noriyoshi Ogawa
  • Patent number: 7648810
    Abstract: An electrophotographic imaging member comprises a substrate, an electrophotographic imaging layer and an overcoat layer comprising a cross-linkable polymer and a hole transport material, wherein the overcoat layer provides at least one of solvent resistance and hydrocarbon resistance to the electrophotographic imaging layer.
    Type: Grant
    Filed: September 14, 2006
    Date of Patent: January 19, 2010
    Assignee: Xerox Corporation
    Inventors: John F. Yanus, Kenny-Tuan T. Dinh, Dale S. Renfer, Nancy L. Belknap, Anthony M. Horgan
  • Patent number: 7642028
    Abstract: Novel surface layers for photoreceptors are provided. The surface layers are a polymeric composition including a resin and a cyclic polymer.
    Type: Grant
    Filed: September 15, 2005
    Date of Patent: January 5, 2010
    Assignee: Xerox Corporation
    Inventors: Jin Wu, Liang-Bih Lin
  • Patent number: 7642029
    Abstract: A flexible imaging member which does not require the use of an anti-curl back coating is disclosed herein. The flexible imaging member has a layer comprising two charge transport molecules dispersed in a film-forming polymer binder and an overcoat layer. The first charge transport molecule is a biphenyl amine, terphenyl diamine, or bis(triarylamine) stilbene. The second charge transport molecule is a bis(triarylamine), tri-p-tolylamine, or triphenylamine. The weight ratio of second charge transport molecule to first charge transport molecule is from about 90:10 to about 66:34. Trifluoro acetic acid is also added to the layer containing the charge transport material.
    Type: Grant
    Filed: October 28, 2005
    Date of Patent: January 5, 2010
    Assignee: Xerox Corporation
    Inventors: Anthony M. Horgan, Robert C. U. Yu, Kathleen M. Carmichael
  • Publication number: 20090325090
    Abstract: A photoconductor that includes, for example, a substrate, a first layer like a ground plane layer, an undercoat layer thereover wherein the undercoat layer contains an aminosilane and a phenolic resin, a photogenerating layer, and at least one charge transport layer.
    Type: Application
    Filed: June 30, 2008
    Publication date: December 31, 2009
    Applicant: XEROX CORPORATION
    Inventors: Jin Wu, Dennis J. Prosser, Kathleen M. Carmichael, Sherri A. Toates, Kent J. Evans, Edward F. Grabowski
  • Publication number: 20090324282
    Abstract: An object of the present invention is to provide an electrophotographic photosensitive member having high durability and hardly causing sensitivity decrease even if short wavelength light, particularly light having a wavelength of 380 to 450 nm is used as exposure light, and a process cartridge and an electrophotographic apparatus having the electrophotographic photosensitive member. The present invention includes an electrophotographic photosensitive member comprising a support and a photosensitive layer which is provided on the support and contains a charge generation material and a charge transport material, characterized in that the surface layer of the electrophotographic photosensitive member contains an aliphatic dicarboxylic acid polyester resin with a weight average molecular weight of 80,000 or more having a specific repeating structural unit, and a process cartridge and an electrophotographic apparatus having the electrophotographic photosensitive member.
    Type: Application
    Filed: September 8, 2009
    Publication date: December 31, 2009
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Harunobu Ogaki, Takakazu Tanaka, Kenichi Kaku, Akira Yoshida
  • Publication number: 20090324300
    Abstract: The present invention provides an electrophotographic carrier which includes a core particle, a first resin layer containing a charge-generating material for coating the core particle, and a second resin layer containing a hole-transporting material for coating the first resin layer. The invention also provides a two-component developer comprising said carrier, and an image-forming process and apparatus using said developer. According to the invention, high quality images can be formed, with excellent image density (especially when developing solid images) and less fogging.
    Type: Application
    Filed: June 23, 2009
    Publication date: December 31, 2009
    Inventor: Keigo MITAMURA
  • Patent number: 7638248
    Abstract: An electrophotographic photoconductor containing a conductive substrate and at least a charge generating layer and a charge transporting layer successively layered on the substrate, wherein the charge transporting layer contains a charge transporting material (M) and a binder resin (B) and further has a layered structure composed of a plurality of the charge transporting layers wherein the outermost layer of the charge transporting layers show 50% or higher elastic power (?Hu) and hardness (Hplast) of plastic deformation in a range from 220 N/mm2 or higher to 275 N/mm2 or lower.
    Type: Grant
    Filed: November 7, 2006
    Date of Patent: December 29, 2009
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Kotaro Fukushima, Hisayuki Utsumi, Tomoko Kanazawa, Katsuya Takano
  • Patent number: 7618757
    Abstract: Provided is an imaging member such as photoreceptor comprising a substrate, a charge generation layer, a first charge transport layer, a second charge transport layer, and an optional overcoat layer. The first charge transport layer is formed from a first CTL formulation comprising an aromatic monoamine and a first polymeric film forming binder material. The second charge transport layer is formed from a second CTL formulation comprising aromatic diamine and a second polymeric film forming binder material. The imaging member has gained improved properties such as removal of anti-curl layer, desirable structural flatness, electrical properties, mechanical robustness, flexibility, longevity, and copy image qualities over extended use, among others.
    Type: Grant
    Filed: May 11, 2005
    Date of Patent: November 17, 2009
    Assignee: Xerox Corporation
    Inventors: Yuhua Tong, John F. Yanus, Jin Wu, Steven M. Sterling, Susan M. VanDusen
  • Patent number: 7611811
    Abstract: An imaging member having an adhesive charge transport layer is disclosed herein. The charge transport layer comprises a low surface energy polymer having siloxane segments in its backbone and a charge transport compound; it may further comprise a film-forming polymer. The charge transport layer has low surface energy, reduced coefficient of surface contact friction, and improved surface lubricity.
    Type: Grant
    Filed: December 22, 2005
    Date of Patent: November 3, 2009
    Assignee: Xerox Corporation
    Inventors: Robert C. U. Yu, Stephen T. Avery, Kathleen M. Carmichael, Jimmy E. Kelly