S, Se, Or Te Or Compound Thereof Patents (Class 430/603)
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Publication number: 20040175662Abstract: A silver halide photographic lightsensitive material comprising a support having thereon at least one lightsensitive silver halide emulsion layer, wherein the lightsensitive material contains at least one compound represented by general formula (I) and at least one photographically useful group-releasing compound represented by general formula (II) or (III) that is capable of forming a compound having substantially no contribution to a dye after its coupling with an oxidized form of a developing agent:Type: ApplicationFiled: October 9, 2003Publication date: September 9, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Yoichi Hosoya, Kiyoshi Morimoto, Tadashi Inaba
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Patent number: 6787298Abstract: Disclosed is a highly sensitive photothermographic material containing on a support a silver salt of an organic acid, a photosensitive silver halide, a reducing agent, a binder and, for example, a compound of which one-electron oxidized derivative produced by one electron oxidation of the compound is capable of releasing two or more electrons with a bond cleavage.Type: GrantFiled: October 3, 2002Date of Patent: September 7, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Takahiro Goto, Kohzaburoh Yamada, Tomoyuki Ohzeki, Eiichi Okutsu, Shoji Yasuda
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Publication number: 20040166450Abstract: An object of the present invention is to provide a silver halide photographic light-sensitive material which is reduced in the various problems ascribable to the multilayer adsorption of the sensitizing dye. A silver halide photographic emulsion comprising a silver halide grain having adsorbed on the surface thereof a sensitizing dye in multiple layers is described, wherein the variation coefficient of the light absorption strength distribution among the grains is 100% or less.Type: ApplicationFiled: February 24, 2004Publication date: August 26, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Katsuhiro Yamashita, Katsumi Kobayashi, Takanori Hioki
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Patent number: 6780579Abstract: A silver halide emulsion having a silver chloride content of 90 mol % or more which has been chemically sensitized with a compound capable of releasing an AuICh− ion is described, wherein grains of the silver halide contain in the shell portion thereof 0.01 to 0.50 mol % of silver iodide per mol of the total silver, with Ch representing S, Se or Te.Type: GrantFiled: March 25, 2003Date of Patent: August 24, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirotomo Sasaki, Hiroyuki Suzuki, Tomoki Tasaka, Masafumi Mizuno, Hiroyuki Mifune, Atsushi Matsunaga
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Patent number: 6780578Abstract: The thermally developable photosensitive material of the present invention has a support and including on at least one surface of the support a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for thermal development, a binder and a compound represented by the following general formula (1): wherein R1 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group or a heterocyclic group; X represents a chalcogen atom; and Y represents an amino group, an N-alkylamino group, an N,N-dialkylamino group, an anilino group, a hydroxyl group, an alkoxy group, an aryloxy group, an acylamino group or a sulfonamide group, and wherein when Y represents an alkoxy group, an alkylamino group, a dialkylamino group, an acylamino group or a sulfonamide group, Y and R1 may be bonded to each other to form a 5- to 7-membered ring.Type: GrantFiled: March 25, 2003Date of Patent: August 24, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuhiro Yoshioka, Keiichi Suzuki
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Publication number: 20040157176Abstract: A silver halide emulsion which exhibits superior latent image stability when subjected to subjected to digital exposure at a high intensity for a short time is disclosed, comprising silver halide gains containing at least 90 mol % chloride, 0.02 to 5.0 mol % bromide and 0 to 2.0 mol % iodide, based on silver and occluding at least one Group 8 metal compounds and at least one iridium compound, and the silver halide grains are subjected to selenium sensitization which is undergone in the presence of at least one of compounds represented by the following formulas and silver or gold sulfide grains. A preparation method of the emulsion is also disclosed.Type: ApplicationFiled: February 3, 2004Publication date: August 12, 2004Applicant: KONICA MINOLTA HOLDINGS, INC.Inventors: Toshiya Kondo, Shuji Murakami, Koichiro Kuroda
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Publication number: 20040152026Abstract: The present invention provides a photosensitive silver halide photographic emulsion comprising a silver iodide content of 41 mol % or more and 100 mol % or less and including a silver halide to which reduction sensitization is applied in the course of particle formation, and silver halide photographic emulsion comprising 41 mol % to 100 mol % of silver iodide and subjected to at least one of chalcogen sensitization and gold sensitization to the insides of particles.Type: ApplicationFiled: January 16, 2004Publication date: August 5, 2004Inventor: Hiroyuki Mifune
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Publication number: 20040146816Abstract: A silver halide emulsion comprising silver halide grains containing at least 90 mol % chloride, 0.02 to 5.0 mol % bromide and 0 to 2.0 mol % iodide, which is prepared by a process comprising (i) forming a silver halide grain emulsion, (ii) subjecting the silver halide emulsion to desalting and (iii) subjecting the desalted silver halide emulsion to chemical sensitization by adding a chemical sensitizer, wherein in the step (iii), at least one compound represented by the following formula (1) to (4) is added before adding a chemical sensitizer and at least one compound represented by the following formula (1) to (4) is further added after adding a chemical sensitizer.Type: ApplicationFiled: January 14, 2004Publication date: July 29, 2004Applicant: KONICA MINOLTA HOLDINGS, INC.Inventors: Toshiya Kondo, Shuji Murakami, Koichiro Kuroda
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Patent number: 6762015Abstract: A silver halide photographic emulsion which contains at least two sensitizing dyes represented by the following formula (I): Dye-((A)rQ)q(M)m (I) wherein Dye represents a dye moiety; A represents a linking group; Q represents a dissociable group; r represents 0 or 1; q represents an integer of 2 or more; provided that at least one Q represents —SO3H and at least one Q represents a dissociable group other than —SO3H; M represents a counter ion; and m represents a number of 0 or more necessary to neutralize the electric charge in the molecule, and when 2 represents 2 or more, M's need not be the same.Type: GrantFiled: May 1, 2001Date of Patent: July 13, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuo Nakamura, Takanori Hioki
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Publication number: 20040131982Abstract: A black and white monosheet substantially light-insensitive thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one toning agent, wherein the at least one toning agent is selected from compounds represented by formula (I): 1Type: ApplicationFiled: December 18, 2003Publication date: July 8, 2004Applicant: AGFA-GEVAERTInventors: Ingrid Geuens, Johan Loccufier, Vera Drieghe
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Publication number: 20040131983Abstract: The invention provides a photothermographic material including: a support and an image-forming layer including a non-photosenisitive silver salt, a photosensitive silver halide, a binder, and a reduction agent disposed on the support, wherein a silver iodide content in the photosensitive silver halide is in a range from 40 mol % to 100 mol %; and an average sphere-equivalent diameter of the photosensitive silver halide is in a range from 0.3 &mgr;m to 5.0 &mgr;m. The photothermographic material may further include a silver iodide complex forming agent as a compound which substantially reduces visible light absorption caused by the photosenisitive silver halide after thermal development. At least 50%, in terms of a projected area, of the photosensitive silver halide may be occupied by tabular silver halide grains having an aspect ratio of from 2 to 50 and being deposited with a silver salt in an epitaxial growth manner.Type: ApplicationFiled: December 17, 2003Publication date: July 8, 2004Inventors: Tomoyuki Ohzeki, Eiichi Okutsu
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Patent number: 6759186Abstract: A silver halide photographic material is disclosed, comprising at least one silver halide emulsion layer provided on a support, the emulsion layer comprising a silver halide emulsion containing at least two sensitizing dyes represented by the following general formula (I): wherein X represents an oxygen atom, sulfur atom, selenium atom or NR′; R and R′ each represent a substituted or unsubstituted alkyl, aryl or heterocyclic group; D represents a group required to form a methine dye; M represents a counter ion; and m represents a number of not smaller than 0 required to neutralize the electric charge in the molecule.Type: GrantFiled: January 30, 2002Date of Patent: July 6, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuo Nakamura, Kimiyasu Morimura, Takanori Hioki
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Patent number: 6756191Abstract: A silver halide photographic light-sensitive emulsion comprising a silver halide and a compound represented by the following Formula (I): wherein each X3 and X4 represents independently N, P, S, Se or Te; each Y1 and Y2 represents independently a group of carbon atoms necessary to complete a 6 to 12 membered heterocyclic ring with X3 and X4.Type: GrantFiled: July 19, 2002Date of Patent: June 29, 2004Assignee: Konica CorporationInventors: Tatsuo Tanaka, Nobuaki Kagawa, Yoshiko Iwai, Tomohiro Oshiyama
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Patent number: 6750003Abstract: A silver halide photographic material comprising a support and at least one photosensitive silver halide emulsion layer, wherein the emulsion layer comprises a compound represented by the following formula (1): Dye1-&Parenopenst;L1&Parenopenst;Dye2)m1)m2.CIy (1) wherein Dye1 represents a first chromophore; Dye2 represents a xanthene dye; L1 represents a linking group; m1 represents an integer of from 1 to 5; m2 represents an integer of from 1 to 5; CI represents an ion for neutralizing a charge; and y represents a number necessary for neutralizing the charge.Type: GrantFiled: March 20, 2003Date of Patent: June 15, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroo Takizawa
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Publication number: 20040106074Abstract: A silver salt photothermographic dry imaging material including non-photosensitive aliphatic carboxylic acid silver salts; a photosensitive emulsion containing photosensitive silver halide grains; a silver ion reducing agent; a binder; and a cyan coloring leuco dye. A percentage of the photosensitive silver halide grains having a mean particle size of 0.01 or more &mgr;m and 0.04 &mgr;m or less is 5% or more by mass and 50% or less by mass of total photosensitive silver halide grains by conversion into a silver amount.Type: ApplicationFiled: November 20, 2003Publication date: June 3, 2004Applicant: Konica Minolta Holdings, Inc.Inventors: Hiroshi Kashiwagi, Narito Goto
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Patent number: 6740482Abstract: The invention provides a radiation sensitive emulsion comprised of a dispersing medium and silver iodochloride grains WHEREIN the silver iodochloride grains are partially bounded by {100} crystal faces satisfying the relative orientation and spacing of cubic grains and contain from 0.Type: GrantFiled: December 22, 1994Date of Patent: May 25, 2004Assignee: Eastman Kodak CompanyInventors: Benjamin Teh-Kung Chen, Roger Lok
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Patent number: 6733959Abstract: Photothermographic materials prepared using aqueous formulations include silver halides that are chemically sensitized using certain tellurium-containing compounds. Such tellurium-containing chemical sensitizing compounds are generally provided in aqueous solution or in an aqueous solid particulate dispersion and can be represented by the following Structure I, II, or III: Te(L)m(X1)n (II) Pd(X2)2[Te(R′)2]2 (III) wherein X represents the same or different COR, CSR, CNRRa, CR, PRRa, or P(OR)2 groups, R and Ra are independently alkyl, alkenyl, or aryl groups, L is a ligand derived from a neutral Lewis base, X1 and X2 independently represent a halo, OCN, SCN, S2CNRRa, S2COR, S2CSR S2P(OR)2, S2PRRa, SeCN, TeCN, CN, SR, OR, alkyl, aryl, N3, or O2CR group, R′ is an alkyl or aryl group, p is 2 or 4, m is 0, 1, 2, or 4, and n is 2 or 4 provided that when m is 0 or 2, n is 2 or 4, and when m is 1 or 4, n is 2.Type: GrantFiled: August 6, 2001Date of Patent: May 11, 2004Assignee: Eastman Kodak CompanyInventors: Henry J. Gysling, David A. Dickinson, Mark Lelental, John W. Boettcher
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Patent number: 6727056Abstract: The present invention provides a tabular internal latent image type direct positive photographic silver halide emulsion which provides a high sensitivity and a low re-reversal negative sensitivity and a color diffusion transfer photographic light-sensitive material comprising such an emulsion. The present invention also provides an internal latent image type direct positive photographic silver halide emulsion which can be prepared with a good reproducibility and a color diffusion transfer photographic light-sensitive material less susceptible to variation of sensitivity and S/N ratio comprising such an emulsion. An internal latent image type direct positive photographic silver halide emulsion comprising tabular silver halide grains having an average grain diameter of not less than 0.Type: GrantFiled: August 21, 1997Date of Patent: April 27, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Munehisa Fujita, Atsushi Matsunaga
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Patent number: 6709809Abstract: A silver salt photothermographic material is disclosed, comprising at least a light sensitive layer and at least a light insensitive layer, the light sensitive layer comprising organic silver salt grains, a light sensitive emulsion containing light sensitive silver halide grains and medium, a reducing agent and a binder, wherein at least one of the light sensitive layer and the light insensitive layer contains a silver-saving agent and the photothermographic material which has been subjected to thermal development at 123° C. for 13.5 sec. exhibits an average contrast of 2.0 to 6.0 within the density range of 0.25 to 2.0 on a characteristic curve of the photothermographic material.Type: GrantFiled: June 21, 2001Date of Patent: March 23, 2004Assignee: Konica CorporationInventors: Hiroyuki Yanagisawa, Socman Ho Kimura
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Publication number: 20040053176Abstract: A silver halide emulsion is disclosed, comprising at least one monovalent Au(I) complex coordinated with a compound represented by the following formula (1):Type: ApplicationFiled: August 7, 2003Publication date: March 18, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Hiroyuki Suzuki, Hirotomo Sasaki
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Patent number: 6699647Abstract: Photothermographic imaging materials having increased photospeed are provided by certain tellurium chemical sensitizers that are added during the formulation of a photothermographic emulsion.Type: GrantFiled: October 11, 2001Date of Patent: March 2, 2004Assignee: Eastman Kodak CompanyInventors: Doreen C. Lynch, Andrea L. Opatz, Steven M. Shor, Sharon M. Simpson, Brian C. Willett, Henry J. Gysling
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Publication number: 20040038163Abstract: Disclosed is a photothermographic material comprising, on one side of a support, a photosensitive silver halide, a non-photosensitive silver salt of an organic acid, a reducing agent for silver ions and a binder, which is characterized by containing one or more phenol compounds as the reducing agent and one or more compounds satisfying at least one of the following requirements A and B in combination:Type: ApplicationFiled: August 19, 2003Publication date: February 26, 2004Applicant: Fuji Photo Film Co., Ltd.Inventors: Yasuhiro Yoshioka, Makoto Suzuki
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Publication number: 20040038161Abstract: The present invention provides the photothermographic material including a photosensitive silver halide, a reducing agent for reducing silver ions, a binder and a non-photosensitive organic silver salt, wherein the photosensitive silver halide has a silver iodide content ranging from 40 mol % to 100 mol %, and has a particle size ranging from 5 nm to 80 nm, and wherein the non-photosensitive organic silver salt is prepared in the presence of the photosensitive silver halide which has been preformed, such that the non-photosensitive organic silver salt includes the photosensitive silver halide.Type: ApplicationFiled: August 7, 2003Publication date: February 26, 2004Inventor: Tomoyuki Ohzeki
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Patent number: 6696215Abstract: Disclosed is a silver halide photographic light-sensitive material comprising at least one silver halide emulsion layer on a support, which contains a compound of which one-electron oxidized derivative produced by one electron oxidation of the compound is capable of releasing two or more electrons with a bond cleavage and has a characteristic curve drawn in orthogonal coordinates of logarithm of light exposure (x-axis) and optical density (y-axis) using equal unit lengths for the both axes, on which gamma is 5.0 or more for the optical density range of 0.3-3.0. This silver halide photographic light-sensitive material shows high contrast and high sensitivity.Type: GrantFiled: October 3, 2002Date of Patent: February 24, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Shoji Yasuda, Kohzaburoh Yamada
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Publication number: 20040033451Abstract: The present invention provides a tabular internal latent image type direct positive photographic silver halide emulsion which provides a high sensitivity and a low re-reversal negative sensitivity and a color diffusion transfer photographic light-sensitive material comprising such an emulsion. The present invention also provides an internal latent image type direct positive photographic silver halide emulsion which can be prepared with a good reproducibility and a color diffusion transfer photographic light-sensitive material less susceptible to variation of sensitivity and S/N ratio comprising such an emulsion. An internal latent image type direct positive photographic silver halide emulsion comprising tabular silver halide grains having an average grain diameter of not less than 0.Type: ApplicationFiled: August 21, 1997Publication date: February 19, 2004Inventors: MUNEHISA FUJITA, ATSUSHI MATSUNAGA
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Publication number: 20040033447Abstract: Aqueous-based photothermographic materials comprise a hydrophilic binder, preformed silver halides, an organic silver salt, a reducing agent composition, and one or more benzothiazolium, benzoselenazolium, or benzotellurazolium salts as antifoggants. These photothermographic materials can be used in combination with phosphor intensifying screens for radiographic imaging.Type: ApplicationFiled: August 14, 2003Publication date: February 19, 2004Applicant: Eastman Kodak CompanyInventors: Chaofeng Zou, Roger L. Klaus
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Publication number: 20040033454Abstract: The present invention provides a photothermographic material, comprising a photosensitive silver halide, a non-photosensitive organic solvent salt, a reducing agent for a silver ion, and a binder on one face of a support, for being applied by using an organic solvent, the photothermographic material further comprising at least one compound selected from the group of compounds consisting of: a compound represented by the following general formula (1), a compound having a &bgr;-lactam ring, a compound having a group that is adsorptive to a silver halide and a group that reduces a silver halide and a precursor thereof: 1Type: ApplicationFiled: August 4, 2003Publication date: February 19, 2004Inventors: Tomoyuki Ohzeki, Hiroyuki Mifune, Tadashi Inaba, Kohzaburoh Yamada, Katsuyuki Watanabe
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Patent number: 6689548Abstract: A photothermographic imaging material comprising a support having thereon a photosensitive layer, wherein the photosensitive layer has a silver coverage of 0.8 to 2.5 g/m2 and comprises a compound represented by Formula (A) or Formula (B): wherein each R3, R4 and R5 is independently an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group, provided that R5 includes a silyl containing group, wherein Z2 represents OR22, X2, or OH; n2 is an integer of 1 to 3; each R21 and R22 is independently an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group, provided that R21 contains at least one primary amino group or at least two selected from the group consisting of primary and secondary amino groups; and X is a chlorine atom or a bromine atom.Type: GrantFiled: August 12, 2002Date of Patent: February 10, 2004Assignee: Konica CorporationInventors: Hirobumi Yamashita, Toshihisa Takeyama
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Patent number: 6689554Abstract: A silver halide emulsion comprises an electron-releasing compound of Types 1 to 4: (Type 1) a compound capable of undergoing a one-electron oxidation (1-EO) to form a one-electron oxidation product (1-EOP), the 1-EOP capable of releasing further two or more electrons accompanying a subsequent bond cleavage reaction, (Type 2) a compound capable of undergoing 1-EO to form 1-EOP, the 1-EOP capable of releasing further one electron accompanying a subsequent bond cleavage reaction, and having, in its molecule, two or more adsorptive groups acting on silver halides, (Type 3) a compound capable of undergoing 1-EO to thereby form 1-EOP, the 1-EOP capable of releasing further one or more electrons after going through a subsequent bond forming process, and (Type 4) a compound capable of undergoing 1-EO to form 1-EOP, the 1-EOP capable of releasing further one or more electrons after going through a subsequent intramolecular ring cleavage reaction.Type: GrantFiled: July 30, 2002Date of Patent: February 10, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Kohzaburoh Yamada, Masahiko Taniguchi, Naoki Asanuma, Takashi Hoshimiya, Hirokazu Kyota, Masafumi Mizuno
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Publication number: 20040023175Abstract: The invention provides a photothermographic material including, on a same surface of a substrate, photosensitive silver halide grains, a non-photosensitive organic silver salt, a reducing agent and a binder, in which the photosensitive silver halide grains include iridium and a metal of groups 3 to 10 of the periodic table other than iridium, and 90% or more of the total iridium amount within the grain are contained in a core of 50% or less of the grain.Type: ApplicationFiled: July 8, 2003Publication date: February 5, 2004Inventor: Seiichi Yamamoto
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Patent number: 6686143Abstract: This invention relates to a photographic element comprising a support and a silver halide emulsion layer, the emulsion layer comprising a water soluble Au(I) complex having the formula [L—Au—L]n−M+n wherein the complex is symmetrical; L is an organothiosulfonato ligand which is an antifogging, stabilizing, or sensitizing compound, n is 1 to 4, and M is a cationic counterion. This invention further relates to a silver halide photographic element comprising a support and a silver halide emulsion layer, the emulsion layer comprising an organothiosulfonato Au(I) complex having the formula [A—SO2S—Au—SSO2—A]n−M+n wherein M is a cationic counterion; A is a substituted or unsubstituted organic group; and n is 1 to 4; and wherein the compound is symmetrical. It further relates to a method of preparing a silver halide emulsion utilizing said organothiosulfonato Au(I) complexes.Type: GrantFiled: August 7, 2002Date of Patent: February 3, 2004Assignee: Eastman Kodak CompanyInventors: Roger Lok, Brian P. Cleary, Alton L. Chitty, Weimar W. White
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Patent number: 6686140Abstract: A silver halide photosensitive material comprises at least one light sensitive silver halide emulsion layer on a support. The silver halide photosensitive material contains at least one compound capable of undergoing a one-electron oxidation to thereby form a one-electron oxidation product thereof, the one-electron oxidation product being capable of releasing further one or more electrons, and at least one reducing compound having a C/H value of 3 or less; and another reducing compound having a C/H value of more than 3, the C/H value representing a ratio of (the number of Group IV elements)/(the sum of Groups III, V, VI and VII elements).Type: GrantFiled: March 10, 2003Date of Patent: February 3, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoki Asanuma, Kohzaburoh Yamada, Yasuhiro Shimada
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Publication number: 20040018457Abstract: This invention relates to a silver halide photographic emulsion in which a silver emulsion high in silver iodide content of 80% by mol to 100% by mol based on the silver iodide content is chemically sensitized by at least one of methods of chalcogen sensitization and gold sensitization under the conditions that pAg is from 1.5 to 7.0, as well as a thermally developable photosensitive material having at least one image forming layer containing at least a non-photosensitive organic silver salt, a photosensitive silver halide, a reducing agent and a binder on a support, and having at least one non-image recording protection layer to the image forming layer on the side remote from the support, and exposed by a laser beam in which the material contains the silver emulsion high in silver iodide content.Type: ApplicationFiled: March 28, 2003Publication date: January 29, 2004Inventor: Hiroyuki Mifune
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Publication number: 20040009438Abstract: High-speed black-and-white photothermographic materials can be imaged in any suitable fashion using ultraviolet, visible, infrared, or X-radiation. They can have one or more thermally developable imaging layers on either or both sides of the support and can be imaged with or without a phosphor intensifying screen in an imaging assembly. The photothermographic emulsions and materials have a net Dmin less than 0.25, and require less than 1 erg/cm2 to achieve a density of 1.00 above net Dmin.Type: ApplicationFiled: April 16, 2003Publication date: January 15, 2004Applicant: Eastman Kodak CompanyInventors: Chaofeng Zou, Doreen C. Lynch
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Publication number: 20040005522Abstract: The present invention provides a photothermographic material including a support having disposed on one surface thereof at least one image-forming layer containing a binder, an organic silver salt, a reducing agent for reducing silver ions, an organic polyhalogen compound and a photosensitive silver halide, wherein the photosensitive silver halide has a silver iodide content ranging from 10 mol % to 100 mol %. The silver halide further contains at least one metal selected from a first metal group and one metal selected from a second metal group, with a proviso that none of the at least one metal selected from the first metal group and the at least one metal selected from the second metal group are the same.Type: ApplicationFiled: June 25, 2003Publication date: January 8, 2004Inventors: Yutaka Oka, Seiichi Yamamoto
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Patent number: 6673531Abstract: A silver halide emulsion is disclosed, comprising at least one monovalent Au(I) complex coordinated with a compound represented by the following formula (1): R1—Ch—R2 (1) wherein R1 and R2 each independently represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group, R1 and R2 may combine with each other to form a 3-, 4-, 5-, 6- or 7-membered ring, and Ch represents a sulfur atom, a selenium atom or a tellurium atom.Type: GrantFiled: March 1, 2002Date of Patent: January 6, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Suzuki, Hirotomo Sasaki
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Publication number: 20040002026Abstract: A silver halide emulsion having a silver chloride content of 90 mol % or more which has been chemically sensitized with a compound capable of releasing an AuICh− ion is described, wherein grains of the silver halide contain in the shell portion thereof 0.01 to 0.50 mol % of silver iodide per mol of the total silver, with Ch representing S, Se or Te.Type: ApplicationFiled: March 25, 2003Publication date: January 1, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Hirotomo Sasaki, Hiroyuki Suzuki, Tomoki Tasaka, Masafumi Mizuno, Hiroyuki Mifune, Atsushi Matsunaga
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Publication number: 20040002022Abstract: A color image forming method is disclosed, comprising exposing a silver halide color photographic material and developing the exposed photographic material at 43 to 180° C. to form a color image, wherein at least one light-sensitive layer comprising a silver halide emulsion comprising tabular silver halide grains having an average aspect ratio of at least 8. There is also disclosed a digital image forming process, wherein image recording information of the photographic material which was formed by use of the color image forming method is coverted to digital image information through an image sensor.Type: ApplicationFiled: May 15, 2003Publication date: January 1, 2004Inventors: Hiromoto Ii, Hiroyuki Hoshino, Noriyuki Kokeguchi
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Publication number: 20030232288Abstract: Disclosed are photothermographic materials having, on a support, a layer that contains at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, in which the mean silver iodide content of the photosensitive silver halide falls between 5 and 100 mol %, preferably between 40 and 100 mol %.Type: ApplicationFiled: November 1, 2002Publication date: December 18, 2003Inventors: Yutaka Oka, Tomoyuki Ohzeki, Katsutoshi Yamane, Seiichi Yamamoto, Sumito Yamada, Hiroyuki Mifune, Tadashi Inaba, Kohzaburoh Yamada, Katsuyuki Watanabe
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Patent number: 6664037Abstract: Disclosed is a method for chemical sensitization of a silver halide emulsion comprising a sensitization step of subjecting the silver halide emulsion to chemical sensitization with a chalcogen compound or a chalcogen compound and a gold compound to produce silver chalcogenide or gold silver chalcogenide, wherein the chemical sensitization is performed under such conditions that at least a part of the silver chalcogenide or gold silver chalcogenide produced in the sensitization step can be amorphized. This method can provide a silver halide emulsion showing high sensitivity without increasing fog and degrading storability and such a silver halide emulsion.Type: GrantFiled: June 12, 2002Date of Patent: December 16, 2003Assignee: Fuji Photo Film Co., LTDInventor: Masafumi Mizuno
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Publication number: 20030228549Abstract: To provide a silver halide photographic light-sensitive material having high sensitivity and having a desired spectral sensitivity distribution.Type: ApplicationFiled: July 22, 2002Publication date: December 11, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Takanori Hioki, Hiroo Takizawa, Katsuhiro Yamashita
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Patent number: 6660464Abstract: This invention comprises a silver halide photographic element comprising a support with low oxygen permeability and at least one silver halide emulsion layer containing a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is present in the emulsion layer, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X—Y′ undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y′; and, optionally, 3) the radical X• has an oxidation potential≦−0.7V (that is, equal to or more negative than about −0.7V).Type: GrantFiled: June 19, 2000Date of Patent: December 9, 2003Assignee: Eastman Kodak CompanyInventors: Annabel A. Muenter, Steven P. Szatynski
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Publication number: 20030224309Abstract: A silver halide photosensitive material comprises at least one light sensitive silver halide emulsion layer on a support. The silver halide photosensitive material contains at least one compound capable of undergoing a one-electron oxidation to thereby form a one-electron oxidation product thereof, the one-electron oxidation product being capable of releasing further one or more electrons, and at least one reducing compound having a C/H value of 3 or less, and another reducing compound having a C/H value of more than 3, the C/H value representing a ratio of (the number of Group IV elements)/(the sum of Groups III, V, VI and VII elements).Type: ApplicationFiled: March 10, 2003Publication date: December 4, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Naoki Asanuma, Kohzaburoh Yamada, Yasuhiro Shimada
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Publication number: 20030211431Abstract: Disclosed is a silver halide photographic light-sensitive material comprising at least one silver halide emulsion layer on a support, which contains at least one organic gold compound and has a characteristic curve drawn in orthogonal coordinates of logarithm of light exposure (x-axis) and optical density (y-axis) using equal unit lengths for the both axes, on which gamma is 5.0 or more for the optical density range of 0.3-3.0. This silver halide photographic light-sensitive material provides high contrast and high sensitivity.Type: ApplicationFiled: September 13, 2002Publication date: November 13, 2003Inventor: Shoji Yasuda
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Publication number: 20030203322Abstract: The present invention provides a spectrally sensitized photothermographic silver halide element support having a first surface and a second surface, a photothermographic composition that is to be exposed to a laser being disposed on the first surface of the support. The element has at least one back layer disposed on the second surface of the support. The photothermographic composition comprises silver halide emulsion grains having a number average grain size of less than 0.1 &mgr;m and that are spectrally sensitized with a sensitizing dye having a spectral sensitivity that corresponds to the spectral properties of the laser. The photothermographic composition further comprises an organic silver salt, a reducing agent for silver ions, and at least one dye. In addition, the photothermographic composition has a transmission optical density greater than 0.1 at the exposure wavelength, and the back layer has a transmission optical density greater than 0.1 at the exposure wavelength.Type: ApplicationFiled: December 23, 2002Publication date: October 30, 2003Applicant: Eastman Kodak CompanyInventors: Thomas C. Geisler, Thomas J. Kub, Darlene F. Stewart, Mark C. Skinner, Bryan V. Hunt
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Patent number: 6638705Abstract: A silver halide emulsion chemically sensitized by at least one compound having a bond of anionic chalcogenide to gold(I) cation and capable of releasing a gold-chalcogen anion species and a method for chemically sensitizing a silver halide emulsion, comprising adding at least one compound having a bond of anionic chalcogenide to gold(I) cation and capable of releasing a gold-chalcogen anion species are disclosed.Type: GrantFiled: August 1, 2002Date of Patent: October 28, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Suzuki, Masafumi Mizuno, Kohzaburoh Yamada, Hirotomo Sasaki, Tadashi Inaba
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Publication number: 20030198906Abstract: A silver halide photographic material comprising a support and at least one photosensitive silver halide emulsion layer, wherein the emulsion layer comprises a compound represented by the following formula (1):Type: ApplicationFiled: March 20, 2003Publication date: October 23, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Hiroo Takizawa
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Publication number: 20030190564Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide photographic emulsion layer, wherein the emulsion layer contains at least one compound of formulae (Ia), (Ib) and (Ic) and at least one compound of formula (II): 1Type: ApplicationFiled: December 4, 2002Publication date: October 9, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Takanori Hioki, Tetsuo Nakamura
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Patent number: 6630278Abstract: A system has been disclosed for use in radiographic industrial non-destructive testing materials and personal monitoring, making use therefor, of tabular silver brom(oiod)ide emulsion grains having {111} major faces, an average equivalent circular diameter of at least 0.5 &mgr;m and an average thickness of less than 0.30 &mgr;m, having been chemically sensitized by the steps of adding at least a gold salt in order to provide the surface of said tabular grains with at least 6000 atoms of gold per &mgr;m2 of its grain surface and per (0.1 &mgr;m of thickness)2; and at least a sulfite salt in such an amount that the ratio of the number of gold atoms per &mgr;m2 and (concentration of said sulfite salt, expressed in mmole per mole of silver)2 is at least 200000.Type: GrantFiled: September 19, 2001Date of Patent: October 7, 2003Assignee: AGFA-GevaertInventors: Marc Van den Zegel, Marleen De Vester
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Patent number: 6627375Abstract: A silver halide photographic material is disclosed, comprising a support having provided thereon at least a silver halide emulsion layer, which contains at least one compound represented by the following formula (I), and has a characteristic curve of gamma value being 5.0 or more in optical density of from 0.3 to 3.0 on the characteristic curve shown on the orthogonal axis of coordinates having equal unit length expressed by logarithmic exposure amount (x axis) and optical density (y axis): (X)l—(L)m—(A—B)n (I) wherein X represents a silver halide-adsorptive group having at least one of N, S, P, Se and Te atom, or a light absorptive group; L represents a divalent linking group having at least one of C, N, S and O atom; A represents an electron donative group; B represents a releasing group or a hydrogen atom, which forms radical A. by releasing or deproton after oxidation; l and m each represents an integer of from 0 to 3; and n represents 1 or 2.Type: GrantFiled: December 21, 2001Date of Patent: September 30, 2003Assignee: Fuji Photo Film Co., Ltd.Inventor: Shoji Yasuda