Electrically Insulating Overlayer Patents (Class 430/67)
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Patent number: 5357320Abstract: An electrophotographic apparatus is disclosed which has an electrophotographic photosensitive member and a transfer member. The photosensitive member has a conductive support and a photosensitive layer, and further has a surface layer formed of a binder resin, fluorine atom- or silicon atom-containing compound particles incompatible with the binder resin, and a fluorine atom- or silicon atom-containing compound compatible with the binder resin. In the surface layer, the proportion of fluorine atoms and silicon atoms to carbon atoms, (F+Si)/C, as measured by X-ray photoelectron spectroscopy is 0.01 to 1.0. Additionally, the transfer member is a multiple-transfer member.Type: GrantFiled: September 2, 1993Date of Patent: October 18, 1994Assignee: Canon Kabushiki KaishaInventors: Noboru Kashimura, Harumi Sakoh, Kazushige Nakamura, Shoji Amamiya, Takashige Kasuya, Haruyuki Tsuji, Masaaki Yamagami, Tatsuya Ikezue
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Patent number: 5352552Abstract: An image-bearing member suitable for carrying an electrostatic image and/or a toner image is formed by forming a surface layer on a substrate or a photosensitive layer. The surface layer comprises a polymerized and cured product of a photoionically polymerizable compound having two or more functional groups, and shows excellent mechanical and electrical resistance as well as excellent charge-retaining characteristic. As a result, the surface layer provides an image-bearing surface suitable for electrophotography. The surface layer may be a protective layer or a photoconductive layer when it constitutes a photosensitive member.Type: GrantFiled: February 25, 1992Date of Patent: October 4, 1994Assignee: Canon Kabushiki KaishaInventors: Akio Maruyama, Naoto Fujimura, Kiyoshi Sakai, Shin Nagahara, Noriko Ohtani, Seiko Nakano
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Patent number: 5344733Abstract: Disclosed is an electrophotographic receptor provided with an overcoat layer comprising a cured fluororesin and a nitrogen-containing compound selected from the group consisting of an aromatic amine antioxidant and a charge transport substance on the surface of a photosensitive layer containing a charge generating substance.Type: GrantFiled: November 4, 1992Date of Patent: September 6, 1994Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Shinichi Suzuki, Yasuyuki Shigematsu, Takashi Kojima, Hiroe Kizaki, akira Itsubo
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Patent number: 5342718Abstract: An electrophotographic photoconductor is composed of an electroconductive support, a photoconductive layer formed on the electroconductive support, and a protective layer formed on the photoconductive layer which is composed of a polyol curing-type urethane resin, and satisfies the condition of b/a.ltoreq.0.2, wherein a is the absorbance at 2920 cm.sup.- and b is the absorbance at 2260 cm.sup.-1 in an IR spectrum of the protective layer.Type: GrantFiled: July 24, 1992Date of Patent: August 30, 1994Assignee: RICOH Company, Ltd.Inventors: Shinji Nousho, Mitsuru Seto, Junichiro Hashimoto, Takashi Rokutanzono
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Patent number: 5334477Abstract: A method is provided for non-electrostatically transferring dry toner particles which comprise a toner binder and have a particle size of less than 8 micrometers from the surface of an element to a receiver. The element comprises a conductive substrate and a surface layer which contains an electrically insulating polymeric binder resin matrix which comprises a block copolyester or copolycarbonate having a fluorinated polyether block and the receiver comprises a substrate having a coating of a thermoplastic addition polymer on a surface of the substrate in which the Tg of the polymer is less than approximately 10.degree. C. above the Tg of the toner binder. The method involves contacting the toner particles with the receiver which is heated to a temperature such that the temperature of the thermoplastic polymer coating on the receiver substrate during transfer is at least approximately 15.degree. C.Type: GrantFiled: November 13, 1992Date of Patent: August 2, 1994Assignee: Eastman Kodak CompanyInventors: Douglas E. Bugner, David S. Hays, Jeanne E. Kaeding, Steven J. Spinelli
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Patent number: 5328790Abstract: A photoreceptor for contact charging to be used in an electrophotographic process, which includes an electrically conductive base and a photosensitive layer formed on the base so as to be charged by contact charging, and is characterized in that even when pin holes or photosensitive layer lacking portions in the form of pin holes are present on he photosensitive layer, short-circuiting is safely and positively prevented over a long period. The electrically conductive base further includes a base main body of aluminum alloy having Brinell hardness higher than 40 H.sub.B, and an alumite treatment applied over the surface of the aluminum alloy base main body.Type: GrantFiled: September 23, 1992Date of Patent: July 12, 1994Assignee: Minolta Camera Kabushiki KaishaInventors: Masaki Asano, Shuji Iino, Akihito Ikegawa, Izumi Osawa
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Patent number: 5324609Abstract: An electrophotographic photoreceptor comprising a conductive substrate, a photoconductive layer formed on the substrate, and a surface layer formed on the photoconductive layer, wherein the surface layer comprises a polymer mainly composed of a siloxane bond and an imide bond. The photoreceptor has small dark decay and excellent mechanical strength and causes no image blurring under high humidity conditions and therefore can be used in a general electrophotographic process. When used in a laser printer using a coherent light source, the photoreceptor produces high quality images free from a Moire fringe.Type: GrantFiled: June 17, 1992Date of Patent: June 28, 1994Assignee: Fuji Xerox Co., Ltd.Inventors: Shigeru Yagi, Yuzuru Fukuda, Masato Ono, Masaki Yokoi, Masao Watanabe, Taketoshi Higashi
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Patent number: 5308727Abstract: The present invention relates to a photosensitive member comprising:an electrically conductive substrate,an organic photosensitive layer formed on or over the electrically conductive substrate, the organic photosensitive layer comprising an antioxidant and/or a charge transporting material, anda surface protective layer formed on the organic photosensitive member,characterized by that the antioxidant and/or the charge transporting material is (are) contained in a more increased quantity with being closer to the interface between the surface protective layer and the organic photosensitive layer.Type: GrantFiled: September 27, 1991Date of Patent: May 3, 1994Assignee: Minolta Camera Kabushiki KaishaInventors: Izumi Osawa, Isao Doi
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Patent number: 5303007Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.Type: GrantFiled: April 14, 1993Date of Patent: April 12, 1994Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Shunpei Yamazaki
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Patent number: 5292603Abstract: The present invention discloses an image bearing member having a surface layer comprising a high-melting point polyester resin, a cured resin and an antioxidant, and an apparatus which uses the same.Type: GrantFiled: February 28, 1992Date of Patent: March 8, 1994Assignee: Canon Kabushiki KaishaInventors: Kiyoshi Sakai, Naoto Fujimura, Seiko Nakano
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Patent number: 5284729Abstract: A coating composition for an electrophotographic photosensitive member contains a volatile levelling agent. A method for forming a coating film of an electrophotographic photosensitive member, comprises applying a coating composition for the electrophotographic photosensitive member, the coating composition containing a volatile levelling agent, and drying the coating composition by heating with volatilization of the levelling agent to form a coating film.Type: GrantFiled: July 6, 1990Date of Patent: February 8, 1994Assignee: Canon Kabushiki KaishaInventors: Shigemori Tanaka, Takashi Tanaka
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Patent number: 5283142Abstract: The present invention provides an image-holding member which comprises an electroconductive support and a resin layer formed on the support, wherein the surface layer of the image-holding member contains a copolymer having the structure units represented by the formulas [I] and [II]: ##STR1## where A is a linear, branched or cyclic alkylidene group of 1 to 10 carbon atoms, an aryl-substituted alkylidene group, arylene-dialkylidene group, --O--, --S--, --CO--, --SO--, or --SO.sub.2 --; and R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are respectively hydrogen, halogen, or an alkyl or alkenyl group of 1 to 4 carbons; ##STR2## where R.sub.5 is an alkylene or alkylidene group of 2 to 6 carbons; R.sub.6 and R.sub.7 are respectively an alkyl group of 1 to 3 carbons, a phenyl or substituted phenyl group; and n is an integer of from 1 to 200, and the copolymer containing the structure unit of the formula [II] in an amount of from 0.1 to 50% by weight Of the total weight of the copolymer.Type: GrantFiled: February 19, 1992Date of Patent: February 1, 1994Assignee: Canon Kabushiki KaishaInventors: Shinya Mayama, Naoto Fujimura, Kiyoshi Sakai, Noriko Ohtani, Katsumi Aoki, Noriyoshi Ogawa, Satoshi Kanayama
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Patent number: 5272029Abstract: An image-bearing member suitable for carrying an electrostatic image and/or a toner image is formed by forming a surface layer on a substrate or a photosensitive layer. The surface layer comprising a high-melting point polyester resin shows a good dispersibility of the cured resin to provide a durable layer in combination with the cured resin, and also a lubricant, preferably a silicone-type one, whereby the surface layer provides an image-bearing surface suitable for electrophotography. The surface layer may be a protective layer or a photoconductive layer when it constitutes a photosensitive member.Type: GrantFiled: February 26, 1992Date of Patent: December 21, 1993Assignee: Canon Kabushiki KaishaInventors: Kiyoshi Sakai, Naoto Fujimura, Seiko Nakano
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Patent number: 5268247Abstract: A printing drum (An electrophotographic member) for electrophotographic copying machines comprises a substrate, a photosensitive film formed on the substrate and a protective film formed on the photosensitive film and mainly comprising carbon at no lower than 50 atom % and including hydrogen at 10 to 40 atom % and nitrogen at 1 to 10 atom %. The protective film may further include fluorine at 0 to 1 atom %. The transparency of the protective film is controlled by adjusting the concentration of hydrogen. The resistivity of the protective film is controlled by adjusting the concentration of nitrogen. By this configuration, requirements for the protective film on the hardness, the transparency and the resistivity of the protective film are satisfied at the same time.Type: GrantFiled: September 24, 1991Date of Patent: December 7, 1993Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Shigenori Hayashi
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Patent number: 5262262Abstract: An electrophotographic photoreceptor having excellent dark resistance is disclosed, which comprises a photoconductive layer and a surface layer formed successively on a conductive substrate, wherein the photoconductive layer mainly comprises hydrogen-containing amorphous silicon, and the surface layer comprises amorphous carbon which contains not more than 50 atomic percent of hydrogen.Type: GrantFiled: September 30, 1991Date of Patent: November 16, 1993Assignee: Fuji Xerox Co., Ltd.Inventors: Shigeru Yagi, Masayuki Nishikawa, Te Nam Roh, Ken-ichi Karakida, Masahito Tokuhiro, Yuzuru Fukuda, Noriyoshi Takahashi
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Patent number: 5260157Abstract: An electrophotographic photosensitive element comprising a photosensitive layer and a surface protective layer on the photosensitive layer, the surface protective layer comprising a thermosetting silicone resin, and a methyl-butyl etherified melamine-formaldehyde resin in an amount of from 0.1 to 30 parts by weight per 100 parts by weight of the non-volatile solid components of the thermosetting silicone resin, an electrophotographic photosensitive element comprising a photosensitive layer and a surface protective layer on the photosensitive layer, the surface protective layer comprising a thermosetting silicone resin, and an acrylic copolymer having an average molecular weight of 6,000 or less in an amount of from 0.Type: GrantFiled: October 19, 1990Date of Patent: November 9, 1993Assignee: Mita Industrial Co., Ltd.Inventors: Yasufumi Mizuta, Akihiko Kawahara, Kaname Nakatani, Nariaki Tanaka
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Patent number: 5258250Abstract: A photoconductive member, comprises a support for a photoconductive member and an amorphous layer which is constituted of silicon atoms as matrix containing at least one of hydrogen atom and halogen atom and exhibits photoconductivity, said amorphous layer having a layer region containing carbon atoms in at least a part thereof, the content of the carbon atoms in said layer region being distributed unevenly in the direction of the thickness of said layer.Type: GrantFiled: June 17, 1992Date of Patent: November 2, 1993Assignee: Canon Kabushiki KaishaInventors: Shigeru Shirai, Junichiro Kanbe, Tadaji Fukuda
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Patent number: 5256509Abstract: An image-forming member for electrophotography and a manufacturing method for the same and an electrostatic photocopying machine are disclosed. The image-forming member comprises an organic photoconductive layer formed on a conductive substrate and a protective layer formed on the organic photoconductive layer. Hollows such as pinholes and cracks in the organic photoconductive layer are filled with insulating material, so that the organic photoconductive layer surface becomes even and thereby the protective layer such as a carbonaceous film having high hardness is formed on the organic photoconductive layer with a surface of the protective layer even such that foreign matters can not gather thereon.Type: GrantFiled: November 19, 1990Date of Patent: October 26, 1993Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Shigenori Hayashi, Shunpei Yamazaki
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Patent number: 5254423Abstract: The present invention provides an electrophotographic photosensitive member comprising a conductive support and a photosensitive layer provided thereon, wherein the surface layer of the electrophotographic photosensitive member contains a polymer having a component unit represented by the following Formula (1) and a polymer having a component unit represented by the following Formula (2) and a component unit represented by the following Formula (3) in a certain proportion.Type: GrantFiled: October 16, 1992Date of Patent: October 19, 1993Assignee: Canon Kabushiki KaishaInventors: Shinya Mayama, Naoto Fujimura, Toshiyuki Yoshihara, Kiyoshi Sakai, Hideki Anayama, Hideyuki Ainoya, Katsumi Aoki
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Patent number: 5252418Abstract: An electrophotographic photoreceptor comprising a photoconductive layer comprising a photoconductor, a support for the photoconductive layer and a surface layer formed on the photoconductive layer and comprising a curable resin film and an inorganic insulator pieces having a size larger than the film thickness of the curable resin film. In order to prevent the image blurring of an a-Si:H photoreceptor, on the outermost surface of the photoreceptor was formed a surface layer having a structure in which inorganic insulator pieces have protruded from the curable resin film. Since the curable resin is of high resistance and shows no quality change by corona irradiation, and besides the protruding inorganic insulator pieces prevent the abrasion of the resin, the surface layer having a long life and excellent humidity resistance, durability for corona irradiation and abrasion resistance can be realized.Type: GrantFiled: August 14, 1990Date of Patent: October 12, 1993Assignee: Hitachi, Ltd.Inventors: Fuminori Ishikawa, Akira Sato, Kunihiro Tamahashi, Masatoshi Wakagi, Katsumi Tamura, Masanobu Hanazono, Mitsuyoshi Shoji, Takayuki Nakakawaji, Yutaka Ito, Shigeki Komatsuzaki, Motoo Akagi, Masaaki Imamura
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Patent number: 5246807Abstract: The present invention relates to an electrophotographic photosensitive member. The photosensitive member has an electroconductive support and a photosensitive layer formed thereon containing oxytitanium phthalocyanine, and a surface layer of the photosensitive member contains a copolymer having a first and second structural units represented by the formulas ##STR1## Further the invention relates to an electrophotographic apparatus, device unit, and facsimile machine utilizing the electrophotographic photosensitive member.Type: GrantFiled: August 3, 1992Date of Patent: September 21, 1993Assignee: Canon Kabushiki KaishaInventors: Tetsuro Kanemaru, Hideyuki Takai, Itaru Yamazaki, Shinya Mayama, Masato Tanaka
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Patent number: 5242776Abstract: The present invention relates to a photosensitive member in which a vacuum thin layer is formed as a surface protective layer on or over the roughened surface of the photosensitive layer.Type: GrantFiled: November 7, 1991Date of Patent: September 7, 1993Assignee: Minolta Camera Kabushiki KaishaInventors: Isao Doi, Seishi Ojima, Kenji Masaki, Shuji Iino, Izumi Osawa
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Patent number: 5242773Abstract: The present invention relates to a photosensitive layer comprising:a substrate;a photosensitive layer formed on the substrate;a surface protective layer formed on the photosensitive layer, the surface protective layer being a deposited layer formed by a vacuum vapor deposition method to have no less than 400/cm.sup.2 solvent-penetrable spots formed in its thickness direction.Type: GrantFiled: November 7, 1991Date of Patent: September 7, 1993Assignee: Minolta Camera Kabushiki KaishaInventors: Shuji Iino, Kenji Masaki, Seishi Ojima, Isao Doi, Izumi Osawa
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Patent number: 5242775Abstract: A photosensitive device is described. The photosensitive member of the device is made of an organic photoconductive film which is suitable for mass-production and unlikely to have cracks therein. The photoconductive film is provided with an abrasion-proof surface by coating the same with an amorphous film having a vickers Hardness higher than 2000 Kg/mm.sup.2.Type: GrantFiled: December 16, 1992Date of Patent: September 7, 1993Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Shunpei Yamazaki
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Patent number: 5240802Abstract: A photoconductive element of smooth surface comprises a single aggregate photoconductive layer which contains an aggregate photoconductor and at least three organic charge transport agents. In a preferred embodiment the aggregate photoconductive composition is formed from a high molecular weight alkylidene diarylene polycarbonate and is mixed with at least five organic charge transport agents and the element is overcoated with a thin, smooth, abrasion-resistant layer of silicon carbide. The smooth surface of the photoconductive element has a 20.degree. gloss greater than about 6 and is resistant to scumming by fine toner particles.Type: GrantFiled: December 31, 1991Date of Patent: August 31, 1993Assignee: Eastman Kodak CompanyInventors: Michel F. Molaire, Paul M. Borsenberger, James H. Peters
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Patent number: 5240801Abstract: An image-forming member for electrophotography and a manufacturing method for the same and an electrostatic photocopying machine are disclosed. The image-forming member comprises an organic photoconductive layer formed on a conductive substrate and a protective layer formed on the organic photoconductive layer. Hollows such as pinholes and cracks in the organic photoconductive layer are filled with insulating material, so that the organic photoconductive layer surface becomes even and thereby the protective layer such as a carbonaceous film having high hardness is formed on the organic photoconductive layer with a surface of the protective layer even such that foreign matters can not gather thereon. Alternatively, hollows such as pinholes and cracks in a protective layer are filled with insulating material. Thereby the protective layer surface is made even.Type: GrantFiled: December 16, 1992Date of Patent: August 31, 1993Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Shigenori Hayashi, Shunpei Yamazaki
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Patent number: 5229239Abstract: An electrostatographic imaging member having a supporting substrate, the substrate including at least one material selected from the group consisting of polyether ether ketones, polyphenylene sulfide, polysulfones, polyether imides, polyamide imides and compounds (1), (2) and (3) as follow: ##STR1## (where n represents the degree of polymerization).Type: GrantFiled: December 30, 1991Date of Patent: July 20, 1993Assignee: Xerox CorporationInventor: Robert C. U. Yu
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Patent number: 5213928Abstract: An electrostatographic imaging member including a supporting substrate and an outer layer on the imaging side of the imaging member, the outer layer including minute spheres of a high molecular weight polysiloxane homopolymer homogeneously dispersed in a continuous film forming polymer matrix. This imaging member may be used in an electrostatographic imaging process which includes the steps of forming an electrostatic latent image on the imaging surface, developing the electrostatic latent image with marking particles to form marking particle images in conformance with the electrostatic latent image, transferring the marking particles image to a receiving member, cleaning the imaging surface and repeating the electrostatic latent image forming, developing, transferring and cleaning steps at least once.Type: GrantFiled: November 4, 1991Date of Patent: May 25, 1993Assignee: Xerox CorporationInventor: Robert C. U. Yu
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Patent number: 5204201Abstract: An improved organic photoreceptor is disclosed which is coated with a clear polymer film to prevent aromatic amine transport molecule leakage and binder cracking when exposed to liquid toner developers. The polymer film may also be overcoated with a polysiloxane layer to provide additional abrasion resistance.Type: GrantFiled: December 18, 1991Date of Patent: April 20, 1993Assignee: Xerox CorporationInventors: Richard L. Schank, John A. Bergfjord
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Patent number: 5202206Abstract: Disclosed is an imaging process for simultaneous printing of fixed and variable data which comprises, in the order states, (1) providing a migration imaging member comprising a substrate, a softenable layer comprising a softenable material and migration marking material contained at or near the surface of the softenable layer, and a charge transport material capable of transporting charges of one polarity; (2) uniformly charging the imaging member; (3) exposing the charged imaging member to activating radiation in an imagewise pattern corresponding to the fixed data, thereby forming an electrostatic latent image on the imaging member; (4) thereafter causing the softenable material to soften by the application of heat, thereby enabling the migration marking material exposed to radiation to migrate through the softenable material toward the substrate in an imagewise pattern corresponding to the fixed data; (5) uniformly charging the imaging member to the same polarity as the polarity of the charges that the chaType: GrantFiled: October 4, 1991Date of Patent: April 13, 1993Assignee: Xerox CorporationInventor: Man C. Tam
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Patent number: 5190838Abstract: An electrophotographic image-forming member which comprises a substrate for electrophotography and a light receiving layer being disposed on said substrate, said light receiving layer comprising a photoconductive layer formed of a non-single-crystal silicon carbide film containing silicon atoms as a matrix, carbon atoms in an amount of 5 to 15 atomic % and hydrogen atoms in an amount of 1 to 10 atomic %, containing graphite structure domains in a proportion of 1% or less per unit volume and having an intensity ratio of 0.01 to 0.05 between the C--H bond stretching mode and the Si--H bond stretching mode in an infrared adsorption spectrum.The light receiving layer may further comprise a charge injection inhibition layer or/and a surface layer.Type: GrantFiled: August 27, 1990Date of Patent: March 2, 1993Assignee: Canon Kabushiki KaishaInventors: Keishi Saitoh, Masafumi Sano, Koichi Matsuda
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Patent number: 5168023Abstract: A photosensitive body has an electrically conductive substrate, and a photoconductive film formed on the substrate. A multiple optical film is formed on the photosensitive layer. The multiple optical film allows permeation of light beams in specific wavelength. Further, a diamond-like carbon film is formed on the multiple optical film. The diamond-like carbon film has thickness of at least 1,500.ANG. and Noop hardness of at least 1,000 kg/mm.sup.2. The multiple optical film and the diamond-like carbon film are provided in order to improve resistance against wear, ozone, and light.Type: GrantFiled: July 2, 1991Date of Patent: December 1, 1992Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Tsutomu Mitani, Hirokazu Nakaue, Hideo Kurokawa
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Patent number: 5166438Abstract: A charge transporting material comprising a 1,3-pentadiene derivative having formula (I):A--CH.dbd.CH--CH.dbd.CH--CH.sub.2 --A (I)wherein A represents a 9-anthryl group which may have a substituent, a N-substituted carbazolyl group which may have a substituent, a N-substituted phenothiazinyl group which may have a substituent or ##STR1## in which Ar represents an arylene group which may have a substituent, R.sup.1 and R.sup.2 each represent an alkyl group which may have a substituent, an aralkyl group which may have a substituent, or an aryl group which may have a substituent; an electrophotographic photoconductor comprising an electroconductive support and a photoconductive layer formed thereon, which comprises as an effective component at least one of the 1,3-pentadiene derivatives of the above formula (I); and novel 1,3-pentadiene derivatives of the formula (I), provided that in the formula (I), R.sup.1 and R.sup.2 cannot be a methyl group at the same time, are disclosed.Type: GrantFiled: August 23, 1991Date of Patent: November 24, 1992Assignees: Ricoh Company, Ltd., Hodogaya Chemical Co., Ltd.Inventors: Mitsuru Hashimoto, Masaomi Sasaki, Tomoyuki Shimada, Nobuo Suzuki, Takayuki Sakai, Susumu Suzuka
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Patent number: 5162180Abstract: The present invention relates to a xeroprinting process, in particular a xeroprinting process comprising the following steps:(a) image-wise exposing to actinic radiation an electrostatic master having a photopolymerizable conductive layer to selectively polymerize and thereby increase resistivity in exposed areas of the layer;(b) forming a latent image of electrostatic charge by charging the master by corona discharge;(c) reversal developing the latent electrostatic image by depositing toner particles in the non-exposed areas of the layer;(d) transferring the toner image to another substrate and subsequent fusing;(e) resetting the process by cleaning and discharging the electrostatic master.According to a preferred embodiment the reversal development is effected by means of a development electrode inducing charges in the photopolymer plate opposite to the initial electrostatic image, and by means of dry electrophotographic toner.Type: GrantFiled: October 18, 1990Date of Patent: November 10, 1992Assignee: Agfa-Gevaert, N.V.Inventors: Luc H. Leenders, Robert C. Van Haute, Eddy A. Michiels, Serge M. Tavernier, Robert F. Janssens, Andre Verhecken
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Patent number: 5162183Abstract: A surface layer on an imaging member has a surface roughness which reduces the force necessary for blade cleaning, reduces blade edge truck, reduces blade/substrate friction, inhibits the formation of toner-type deposits on the imaging surface, and/or reduces or eliminates light interference patterns resulting from coherent light, for example, from a raster output scanner.Type: GrantFiled: May 10, 1991Date of Patent: November 10, 1992Assignee: Xerox CorporationInventors: Nero R. Lindblad, Richard L. Schank, Richard W. Bigelow, Herbert C. Relyea, Robert E. Trott, Andrew R. Melnyk, Merlin E. Scharfe, Walter F. Leising
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Patent number: 5162875Abstract: Hard, mechanically and chemically stable protective layers for electroactive passivation layers of semiconductor components, which also act as diffusion barriers against moisture and ions, comprise a thin layer of amorphous, hydrogenated carbon.Type: GrantFiled: February 1, 1990Date of Patent: November 10, 1992Assignee: Siemens AktiengesellschaftInventors: Siegfried Birkle, Johann Kammermaier, Gerhard Schmidt, Rolf-W. Schulte
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Patent number: 5162184Abstract: An electrophotographic photoreceptor comprising a charge transport layer, a charge generation layer and a surface protection layer sequentially laminated on a conductive substrate wherein the binder of the charge transport layer is a resin having a molecular weight of not less than 20,000 and not more than 45,000.Type: GrantFiled: August 9, 1989Date of Patent: November 10, 1992Assignee: Fuji Electric Co., Ltd.Inventor: Koichi Aizawa
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Patent number: 5162182Abstract: A photosensitive member for electrophotography has a conductive substrate provided thereon with, in order, a charge transport layer, a charge generation layer, an interference control layer and an overcoating layer. The interference control layer has a refractive index substantially equal to the geometrical mean of the refractive indexes of the charge generation layer and the overcoating layer and a thickness such that the optical phase difference is substantially equal to .pi./2 radian or 3.pi./2 radian.Type: GrantFiled: October 28, 1991Date of Patent: November 10, 1992Assignee: Fuji Electric Co., Ltd.Inventor: Yukihiro Maruta
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Patent number: 5144367Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.Type: GrantFiled: October 31, 1990Date of Patent: September 1, 1992Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Shunpei Yamazaki
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Patent number: 5143808Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.Type: GrantFiled: October 31, 1990Date of Patent: September 1, 1992Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Shunpei Yamazaki
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Patent number: 5139911Abstract: An electrophotographic photoreceptor comprising a conductive support having thereon an amorphous silicon photoconductive layer and a surface protective layer is disclosed, the surface protective layer having a laminated structure comprised of a lower layer comprising nitrogen-containing amorphous silicon and an upper layer comprising amorphous carbon.The photoreceptor causes no image deletion even after repeated use under a high temperature and high humidity condition and exhibits excellent scratch resistance.Type: GrantFiled: December 28, 1989Date of Patent: August 18, 1992Assignee: Fuji Xerox Co., Ltd.Inventors: Shigeru Yagi, Masato Ono, Noriyoshi Takahashi, Masayuki Nishikawa, Yuzuru Fukuda, Kenichi Karakida
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Patent number: 5139912Abstract: An electrophotographic photoreceptor of laminate-type comprises in sequence a conductive substrate, a carrier transport layer and carrier generation layer, both of an organic substance, and a surface protective layer. The surface protective layer exhibits greatly improved humidity resistance and comprises either a fluorine-containing acrylic graft copolymer or a urethane resin such that the layer has a pure water contact angle of at least 70 degrees.Type: GrantFiled: March 20, 1989Date of Patent: August 18, 1992Assignee: Fuji Electric Co., Ltd.Inventor: Kouichi Aizawa
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Patent number: 5135834Abstract: An electrophotographic photosensitive element having a layer containing polyvinyl acetal, wherein the layer is formed by coating a coating composition containing the polyvinyl acetal and being compounded with a solution comprising an acetylacetone complex salt, an alcohol and water, and a process of producing an electrophotographic photosensitive element having a layer containing polyvinyl acetal, wherein the layer is provided by the steps of:preparing (A) a solution of an acetylacetone complex salt dissolved in a mixed solvent of an alcohol and water, and (B) a solution containing polyvinyl acetal;mixing the solutions (A) and (B) to provide a coating composition (C);coating the coating composition (C) on a constituting layer or a conductive substrate; and drying.Type: GrantFiled: October 29, 1990Date of Patent: August 4, 1992Assignee: Mita Industrial Co., Ltd.Inventors: Yasuyuki Hanatani, Yasufumi Mizuta, Kaname Nakatani
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Patent number: 5128228Abstract: This invention relates to a photosensitive member with a charge generating layer and a charge transporting layer laminated on an electrically conductive substrate, in which the charge transporting layer comprises a charge transporting material and an aniline derivative represented by the following general formula [I] below; ##STR1## in which R.sub.1 and R.sub.2 are respectively an alkyl group or an aralkyl group, each of which may have a substituent; R.sub.3 -R.sub.7 are respectively a hydrogen atom, an alkyl group, an alkoxy group, a hydroxy group, an aryl group, an aralkyl group or a halogen atom.Type: GrantFiled: October 4, 1990Date of Patent: July 7, 1992Assignee: Minolta Camera Kabushiki KaishaInventors: Hideaki Ueda, Mitsutoshi Sakamoto, Kimiyuki Ito, Yuki Shimada
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Patent number: 5124220Abstract: The use of a barrier layer between photoconductor layers and release layers in electrographic imaging materials provides enhanced performance, particularly in multiple use of the imaging materials in liquid toned imaging processes.Type: GrantFiled: April 27, 1990Date of Patent: June 23, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: David E. Brown, Susan K. Jongewaard, Roger I. Krech, Gregory L. Zwadlo
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Patent number: 5124219Abstract: This invention relates to a photosensitive member for electrophotography with a photoconductive layer on an electrically conductive substrate and a surface protective layer on the photoconductive layer, wherein the surface protective layer comprises a ternary polymer of nylon or a multicomponent polymer of nylon having 10% or less in saturated degree of water absorption under 65% of relative humidity at 24.degree. C. The surface protective layer may have protuberances and hollows thereon. The surface protective layer may further comprises an inorganic layer on the photoconductive layer.Type: GrantFiled: March 14, 1990Date of Patent: June 23, 1992Assignee: Minolta Camera Kabushiki KaishaInventors: Yuji Shintani, Tetsuo Kyogoku, Toshikazu Suzuki, Masamitsu Ishiyama
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Patent number: 5120625Abstract: An electrophotographic member and method of using same where the electrophotographic member includes an organic photosensitive member and a passivation film formed on the organic photosensitive member where the film includes a first carbon containing layer including halogen atoms and being in direct contact with the organic photosensitive member and a second carbon containing layer including halogen atoms and formed on the first carbonaceous layer, wherein the concentration of halogen atoms in the first layer is lower than that in the second layer and the thickness of the first layer is substantially less than that of the second layer.Type: GrantFiled: September 26, 1990Date of Patent: June 9, 1992Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Shunpei Yamazaki, Shigenori Hayashi
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Patent number: 5112709Abstract: A red reproduction-improving electrophotographic image-forming method to be practiced in an electrophotographic image-forming system having a halogen lamp image-forming light source, characterized by using:(a) an image-forming light of a continuous wavelength in the region of from 400 to 700 nm from said halogen lamp light source,(b) a magnet roller capable of forming toner brush comprising magnetic materials of said magnetic toner in said cleaning mechanism, and(c) an amorphous silicon system photosensitive member in a cylindrical form as said cylindrical photosensitive member: said amorphous silicon system photosensitive member comprising a substrate and a light receiving layer which comprises a 0.01 to 10 .mu.m thick charge injection inhibition layer composed of an amorphous material containing silicon atoms as the matrix, a 1 to 100 .mu.m thick photoconductive layer of 3.2 to 3.Type: GrantFiled: January 9, 1991Date of Patent: May 12, 1992Assignee: Canon Kabushiki KaishaInventors: Koji Yamazaki, Shigenori Ueda, Toshiyuki Ehara
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Patent number: 5103262Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.Type: GrantFiled: October 31, 1990Date of Patent: April 7, 1992Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Shunpei Yamazaki
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Patent number: 5102756Abstract: Disclosed is a printing plate precursor which comprises a base layer, a layer of photohardenable material, and a layer of softenable material containing photosensitive migration marking material. Alternatively, the precursor can comprise a base layer and a layer of softenable photohardenable material containing photosensitive migration marking material. Also disclosed are processes for preparing printing plates from the disclosed precursors.Type: GrantFiled: December 31, 1990Date of Patent: April 7, 1992Assignee: Xerox CorporationInventors: Paul S. Vincett, Rafik O. Loutfy, Gregory J. Kovacs, Man C. Tam, Ronald Forstinger, Brian D. Lesser, Arnold L. Pundsack, Christopher Rodgers, Philip H. Soden