The Hetero Ring Has At Least Nitrogen As A Ring Hetero Atom Patents (Class 430/76)
  • Patent number: 5019474
    Abstract: A novel electrophotographic photoreceptor is provided comprising on an electrically conductive support a layer containing a charge-transporting compound and a charge-generating compound or a charge-transporting compound-containing layer and a charge-generating compound-containing layer, characterized in that as said electric charge-generating compound there is contained a tetrakisazo compound represented by the general formula (1): ##STR1## wherein Ar.sup.1, Ar.sup.2, Ar.sup.3, Ar.sup.4, Ar.sup.5, Ar.sup.6 and Ar.sup.7 each represents an arylene group, divalent condensed polycyclic aromatic group or divalent heterocyclic aromatic group; and Cp represents a coupler residue.
    Type: Grant
    Filed: April 4, 1990
    Date of Patent: May 28, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naonori Makino, Shigeru Ohno, Satoshi Hoshi, Katsuji Kitatani
  • Patent number: 4999269
    Abstract: This invention provides an electrophotographic photoreceptor which is high in durability and high in sensitivity. This photoreceptor comprises an electroconductive support and, provided thereon, a photosensitive layer containing an azo pigment represented by the following formula [I] or [II]: ##STR1## wherein A represents a hydrogen atom, an alkyl group, a phenyl group or a heterocyclic ring group, m and n each represents 0 or 1, X represents a hydrogen atom, a lower alkyl group, a cyano group or a halogen atom and Cp represents a coupler residue, or ##STR2## wherein Z represents an alkyl group, a phenyl group or a heterocyclic ring group, X represents a hydrogen atom, a lower alkyl group, a cyano group or a halogen atom and Cp represents a coupler residue.
    Type: Grant
    Filed: July 31, 1990
    Date of Patent: March 12, 1991
    Assignee: Mitsubishi Paper Mills, Limited
    Inventors: Kazuhiro Emoto, Kozo Haino, Akira Itoh, Makoto Okaji
  • Patent number: 4994338
    Abstract: An electrophotographic photosensitive material includes a photosensitive layer which is formed on a conductive support body and which contains an azo pigment expressed by Formula (1) described below, wherein at least one Cp in the Formula (1) is a coupler residue expressed by Formula (2) described below.Ar--N.dbd.N--CP).sub.n (1)wherein Ar is an aromatic hydrocarbon or aromatic heterocyclic group, Cp is a coupler reside having a phenolic hydroxyl group, and n is an integer of 1, 2, 3 or 4. ##STR1## wherein R.sub.1 and R.sub.2 each is a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, a halomethyl group, a cyano group or a nitro group.
    Type: Grant
    Filed: May 23, 1989
    Date of Patent: February 19, 1991
    Assignee: Canon Kabushiki Kaisha
    Inventor: Hideyuki Takai
  • Patent number: 4988571
    Abstract: The present invention relates to the photosensitive member which provides at least a charge generating layer and charge transporting layer on an electrically conductive substrate, the charge transporting layer contains a polycarbonate resin I of at least first type polycarbonate resin having a mean molecular weight of 2-4.times.10.sup.4 and a polycarbonate resin II of at least second type polycarbonate resin having a mean molecular weight of 4-6.5.times.10.sup.4, said polycarbonate resin I contributing between 5 and 50 parts by weight of the combined ratio of polycarbonate resins I and II.
    Type: Grant
    Filed: February 14, 1989
    Date of Patent: January 29, 1991
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hidpaki Ueda
  • Patent number: 4988594
    Abstract: A photoconductor for electrophotography comprises an electroconductive substrate and a photoconductive layer formed on the substrate and including a novel disazo compound as a charge generating layer. The disazo compound is represented by the following general formula: ##STR1## wherein X1 stands for one of an alkyl group, an aryl group and an aromatic heterocyclic group, each of which groups may be or not may be substituted, X.sub.2 stands for one of a hydrogen atom, a cyano group, a carbamoyl group, a carboxyl group, an ester group and an acyl group, each of X.sub.3 and X.sub.4 stands for one of a hydrogen atom, a halogen atom, a nitro group, an alkyl group and an alkoxyl group, both of last two groups may be or not may be substituted, Z stands for one of a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group and an aromatic heterocyclic group, each of which groups may be or not may be substituted and --N.dbd.N--D--N--N.dbd.N-- stands for a disazo residual group.
    Type: Grant
    Filed: July 26, 1989
    Date of Patent: January 29, 1991
    Assignee: Fuji Electric, Co. Ltd.
    Inventors: Yoshimasa Hattori, Noboru Furusho, Youichi Nakamura, Masami Kuroda
  • Patent number: 4988593
    Abstract: An electrophotographic photosensitive member having a photosensitive layer is formed on a support and contains an azo pigment expressed by a general formula [I] or [II]: ##STR1## where A, B.sub.1 and B.sub.2 are aromatic hydrocarbon nucleus groups or heterocyclic groups which may be optionally linked by coupler groups, A is an univalent group, B.sub.1 is an univalent, bivalent or trivalent group, and B.sub.2 is a bivalent or trivalent group; X is a residue necessary for forming a polycyclic aromatic nucleus or a heterocycle by condensation with a benzene nucleus; R is a halogen atom, an alkyl group or an alkoxy group; n.sub.1 is an integer from 1 to 3; and n.sub.2 is an integer from 1 to 3. This photosensitive layer may be composed of a charge generation layer containing the above azo pigment and a charge transport layer.
    Type: Grant
    Filed: September 20, 1989
    Date of Patent: January 29, 1991
    Assignee: Canon Kabushiki Kaisha
    Inventor: Hideyuki Takai
  • Patent number: 4977051
    Abstract: An electrophotographic photoreceptor is disclosed, which comprises an electrically conductive support having thereon a layer which contains a charge carrier transporting compound and a charge carrier generating compound, or a layer which contains charge carrier transporting compound and a layer which contains a charge generating compound, wherein at least one type of tris-azo compound represented by formula (I) is included as a charge carrier generating compound: ##STR1## wherein Ar.sub.1, Ar.sub.2, Ar.sub.3, Ar.sub.4 and A are as defined in the specification.
    Type: Grant
    Filed: November 8, 1989
    Date of Patent: December 11, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeru Ohno, Katsuji Kitatani, Naonori Makino, Satoshi Hoshi, Hideo Sato
  • Patent number: 4975350
    Abstract: A photoreceptor including a carrier transporting layer containing a carrier transporting material and a binder material, and a carrier generating layer containing a carrier generating material and a binder material, the layers being placed one over the other in order of mention, characterized in that said carrier generating layer contains a metal-free phthalocyanine having main peaks of Bragg angles 2.theta. at least at 7.5 degrees.+-.0.2 degrees, 9.1 degrees .+-.0.2 degrees, 16.7 degrees.+-.0.2 degrees, 17.3 degrees.+-.0.2 degrees, and 22.3 degrees.+-.0.2 degrees in relation to CuK.alpha. characteristic X rays (wavelength 1.541 .ANG.), and in that said carrier generating layer also contains a carrier transporting material.
    Type: Grant
    Filed: August 1, 1988
    Date of Patent: December 4, 1990
    Assignee: Konica Corporation
    Inventors: Yoshihide Fujimaki, Akira Hirano, Yasuo Suzuki
  • Patent number: 4973536
    Abstract: An electrophotographic photoreceptor is described, comprising a photosensitive layer disposed on a conductive substrate, said photosensitive layer having a laminated structure comprising an electric charge generating layer and an electric charge transporting layer, said electric charge generating layer containing a phthalocyanine pigment which is selected from .epsilon.-type copper phthalocyanine, X-type or .tau.-type phtalocyanine, indium chloride phthalocyanine, calcium chloride phthalocyanine, and magnesium phthalocyanine, one of the benzene rings of the aluminum chloride or indium chloride phthalocyanine being optionally monochlorinated, and said electric charge transporting layer containing at least one hydrazone compound represented by formula (I) or (II) as set below: ##STR1## wherein the substituents are as defined in the specification.
    Type: Grant
    Filed: May 8, 1989
    Date of Patent: November 27, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Horie, Naonori Makino, Hideo Sato
  • Patent number: 4971877
    Abstract: The first aspect of this invention resides in providing an .alpha.-type titanyl phthalocyanine composition comprising an .alpha.-type titanyl phthalocyanine and metal-free phthalocyanine. This .alpha.-type titanyl phthalocyanine composition is stable, wide in range of absorption wavelengths, and high in spectral sensitivity because it contains an .alpha.-type titanyl phthalocyanine in combination with metal-free phthalocyanine.The second aspect of this invention resides in providing a method for the production of an .alpha.-type titanyl phthalocyanine composition comprising an .alpha.-type titanyl phthalocyanine and a metal-free phthalocyanine, which method comprises pigmenting a concentrated sulfuric acid solution containing at least titanyl phthalocyanine by the acid paste process consisting in pouring said concentrated sulfuric acid solution into water. By this method, an .alpha.-type titanyl phthalocyanine composition stable to withstand the impact of aging can be easily produced.
    Type: Grant
    Filed: October 25, 1988
    Date of Patent: November 20, 1990
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Eiichi Miyamoto, Nariaki Mutou, Tooru Nakazawa, Tatsuo Maeda
  • Patent number: 4968571
    Abstract: An electrophotographic recording element comprising a combination of photoconductive perylene materials that are dispersed in a binder to form layers having excellent photosensitivity and resistance to abrasion. The materials are perylene-3,4,9,10-tetracarboxylic acid imide derivatives that contain a phenethyl radical bonded to a 3,4-dicarboximide nitrogen atom.
    Type: Grant
    Filed: July 21, 1989
    Date of Patent: November 6, 1990
    Assignee: Eastman Kodak Company
    Inventors: William T. Gruenbaum, Khe C. Nguyen, Jeanne E. Kaeding
  • Patent number: 4956255
    Abstract: The present invention relates to a photosensitive member containing a specific azo compound represented by the following general formula [I]; ##STR1## wherein A is a bivalent group of a condensed poly-cyclic ring which may have a substituent, a pyridine which may have a substituent, a diazine which may have a substituent, a quinoline which may have a substituent, or a benzoazine which may have a substituent; Cp is a residual group of a coupler, which is improved in photosensitive porperties, in particular, sensitivity.
    Type: Grant
    Filed: February 22, 1989
    Date of Patent: September 11, 1990
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 4956250
    Abstract: A photoconductor for electrophotography comprises a novel azulenium compound as a charge generating substance. An azulenium compound is represented by the following general formula: ##STR1## Wherein, each of R.sub.1 to R.sub.9 stands for a hydrogen atom, a halogen atom, an alkoxy group, or an alkyl group, an aryl group, both of which may have a substituent(s), and X.sup..crclbar. stands for an anion residual group.
    Type: Grant
    Filed: March 21, 1989
    Date of Patent: September 11, 1990
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Masami Kuroda, Yoshinobu Sugata, Noboru Furusho
  • Patent number: 4945020
    Abstract: High resolution, photosensitive electrostatic master which is positive-working with a single imagewise exposure comprising a conductive support bearing a layer of a photosensitive composition consisting essentially of (A) at least one polymeric binder, (B) a hexaarylbiimidazole photooxidant, (C) leuco dye, preferably stabilized, oxidized by (B), (D) a nonionic halogenated compound, preferably a hydrocarbon, and (E) compatible plasticizer. A process of making positive images by a single imagewise exposure is described. The master is useful in making proofs that duplicate the image achieved by printing, etc.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: July 31, 1990
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Richard J. Kempf, Rolf Dessauer, Steven C. Freilich
  • Patent number: 4945021
    Abstract: The present invention relates to a photosensitive member containing a specific bisazo compound described by general structural formula[I] and formed on an electrically conductive substrate; ##STR1## Wherein X is a hydrogen atom, halogen atom, alkyl radical, alkoxi radical, nitro radical or cyano radical; A is a diatomic radical selected from among the following: ##STR2## B is a coupler described by formulae [II] through [VI]; ##STR3## R is a hydrogen atom, halogen atom, alkyl radical, alkoxi radical, nitro radical or cyano radical; and Y is an aromatic carbocyclic residue or aromatic heterocyclic residue, each of which may have a substituent; G is a carbamoyl radical or sulfamoyl radical and may have a substituent; R.sub.1 is a hydrogen atom, alkyl radical, amino radical or carbamoyl radical, each of which may have a substituent, a carboxyl radical or cyano radical; M is an aryl group which may have a substituent, which is improved in photosensitivity and dispersibility.
    Type: Grant
    Filed: February 10, 1989
    Date of Patent: July 31, 1990
    Assignees: Minolta Camera Kabushiki Kaisha, Osaka Municipal Government
    Inventors: Masakazu Takata, Takamasa Ueda, Kimiyuki Ito, Yuko Mikasa, Yuki Shimada, Tsuneaki Hirashima, Souichi Yamamoto, Yoshio Ishino, Toshinobu Ohno
  • Patent number: 4939058
    Abstract: An electrophotographic photoreceptor having on a conductive support a photoconductive layer containing a specific azo compound is disclosed.
    Type: Grant
    Filed: November 30, 1988
    Date of Patent: July 3, 1990
    Assignee: Konica Corporation
    Inventors: Toyoko Shibata, Takahiro Takagi, Shinchi Suzuki, Hiroko Fukawa, Osamu Sasaki
  • Patent number: 4939053
    Abstract: The present invention relates to a photosensitive member containing a specific azo compound for a charge generating agent, which is improved in photosensitive properties, in particular, sensitivity. The specific azo compound is represented by the formula (1): ##STR1## wherein A represents an aromatic hydrocarbon or a heterocyclic ring; R.sub.1 and R.sub.2 independently represent a hydrogen, a halogen atom, or an alkyl, aralkyl, aryl, condensed polycyclic ring or condensed heterocyclic ring; or R.sub.1 and R.sub.2 combinedly form a cyclic ring; n represents an integer from 1 to 4.
    Type: Grant
    Filed: February 10, 1988
    Date of Patent: July 3, 1990
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 4931349
    Abstract: An electrophotographic photoreceptor is provided with a photosensitive layer, which contains an azo compound having in the molecule thereof at least one azo group coupled with a coupler residuum represented by the following general formula (I): ##STR1## wherein X means a residuum capable of condensing with a benzene ring to form a substituted or unsubstituted aromatic hydrocarbon ring or a substituted or unsubstituted aromatic heterocyclic ring, Y denotes a hydrogen or halogen atom or alkyl or alkoxy group, and n stands for an integer of 0-3.
    Type: Grant
    Filed: December 1, 1987
    Date of Patent: June 5, 1990
    Assignee: Dainichiseika Color & Chemicals Mfg. Co.
    Inventors: Masaru Hasegawa, Osamu Suda, Hisao Kohno, Toshifumi Sekino, Tetsuhiro Umezaki, Norio Tanaka
  • Patent number: 4929525
    Abstract: A photoconductor for electrophotography, including an electroconductive substrate; and a photosensitive layer formed on the electroconductive substrate and including a nobel azo compound or disazo compound as a charge generating substance. An azo compound is represented by the following general formula: ##STR1## wherein each of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 stands for a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkoxy group, an allyl group, an aryl group, an aralkyl group, a carboxyl group or an ester group, and C.sub.p stands for a residual group of a coupler.
    Type: Grant
    Filed: December 6, 1988
    Date of Patent: May 29, 1990
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Masami Kuroda, Yoshimasa Hattori, Noboru Furusho
  • Patent number: 4925758
    Abstract: An electrophotographic photoconductor is disclosed which comprises an electroconductive support and a photoconductive layer formed thereon, which photoconductive layer comprises as a charge generating material an azo pigment having general formula (I): ##STR1## wherein R.sup.1, R.sup.2, X, A and n are respectively defined in the specification.
    Type: Grant
    Filed: September 13, 1989
    Date of Patent: May 15, 1990
    Assignee: Ricoh Company, Ltd.
    Inventors: Mitsuru Hashimoto, Nasaomi Sasaki
  • Patent number: 4921770
    Abstract: Disclosed herein is a photoreceptor for electrophotography comprising a conductive substrate and a photosensitive layer thereon containing an azo compound represented by the formula (I):A-N=N-D-N=N-B (I)wherein A represents a coupling component derived from the following formula (II): ##STR1## wherein Q represents a divalent group derived from an aromatic hydrocarbon which may have one or more substituents or a divalent group derived from a heterocyclic compound which may have one or more substituents, B represents a different coupling component having a phenolic hydroxyl group from said A, and D represents a divalent group in which the carbon atoms bonded to the azo groups are SP.sup.2 carbon atoms forming double bonds.
    Type: Grant
    Filed: August 4, 1988
    Date of Patent: May 1, 1990
    Inventors: Tetsuo Murayama, Shinji Aramaki
  • Patent number: 4921780
    Abstract: An optical recording medium having a recording layer provided on a substrate, said recording layer comprising an organic thin film containing at least one diazulenium salt compound represented by the formula [I], [II] or [III], and a recording method using it.
    Type: Grant
    Filed: June 9, 1988
    Date of Patent: May 1, 1990
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoshihiro Oguchi, Tsuyoshi Santoh
  • Patent number: 4917981
    Abstract: A photosensitive member for electrophotography which comprises a photosensitive layer containing at least one member of the group consisting of thiophene structure-containing azo compounds having one of the general formulae (I) to (X): ##STR1## wherein all the symbols are defined in the specification.
    Type: Grant
    Filed: December 28, 1987
    Date of Patent: April 17, 1990
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Yoichi Nakamura, Masami Kuroda, Noboru Furusho
  • Patent number: 4913997
    Abstract: This provides an electrophotographic photoreceptor high in durability and sensitivity which comprises an electroconductive support and, provided thereon, a photosensitive layer containing an azo pigment represented by the formula [I]: ##STR1## wherein A represents an aryl group, a heterocyclic group or an alkyl group, Z represents a hydrogen atom, --B or --CH.dbd.CH--B wherein B represents an aryl group, a heterocyclic group or an alkyl group and Cp represents a coupler residue.
    Type: Grant
    Filed: January 12, 1989
    Date of Patent: April 3, 1990
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Kazuhiro Emoto, Kozo Haino
  • Patent number: 4912002
    Abstract: According to the present invention, by using in combination a styryl compound expressed by general formula [I] or [II] and a bisazo pigment expressed by general formula [III] below, a highly sensitive and durable photoconductive coat which exhibits a low residual electric potential and is free from deterioration caused by fatigue through repeated use and an electrophotosensitive article provided with such a coat are obtained.Therefore, the present invention finds its applications in electronic photocopying devices, laserbeam printers, LED printers, CRT printers and other devices of electronic photography.
    Type: Grant
    Filed: August 4, 1988
    Date of Patent: March 27, 1990
    Assignee: Alps Electric Co., Ltd.
    Inventors: Setsuo Ishibashi, Katsunori Fujio, Yorihiko Sasaki
  • Patent number: 4910536
    Abstract: An electrophotographic apparatus comprises at least a charging means, an imagewise exposure means with a laser beam having a spot diameter of 100 um or less, a developing means, a transferring means and a cleaning means arranged around an electrophotographic photosensitive member, and said electrophotographic photosensitive member comprises a charge generation material and a charge transport material comprising an organic photoconductive material and has a surface layer containing said charge transport material, wherein the absorption end of visible to UV spectroscopic absorption of the surface layer is substantially unchanged by exposure to nitric acid vapor for 10 minutes; an electrophotographic image forming process; and an electrophotographic photosensitive member.
    Type: Grant
    Filed: March 7, 1988
    Date of Patent: March 20, 1990
    Assignee: Canon Kabushiki Kaisha
    Inventors: Naoto Fujimura, Masami Okunuki, Teigo Sakakibara, Noboru Kashimura
  • Patent number: 4895782
    Abstract: A process for preparing a dispersion liquid containing an organic photoconductive azo pigment by use of a solvent is provided which comprises subjecting the azo pigment to a heating treatment in a ketone type solvent as a dispersion pretreatment. The azo pigment is characterized by the general formula (1) wherein R.sub.1 represents a hydrogen atom or a substituted or unsubstituted alkyl group and A represents a coupler residue having a phenolic hydroxyl group.
    Type: Grant
    Filed: June 1, 1988
    Date of Patent: January 23, 1990
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takashi Koyama, Hajime Miyazaki, Hideki Anayama
  • Patent number: 4895781
    Abstract: An electrophotographic photosensitive member is disclosed which has a photosensitive layer on an electroconductive support. The photosensitive layer contains a trisazo pigment having the specific structural formula.
    Type: Grant
    Filed: March 21, 1989
    Date of Patent: January 23, 1990
    Assignee: Canon Kabushiki Kaisha
    Inventor: Hideyuki Takai
  • Patent number: 4891289
    Abstract: The present invention relates to a photosensitive member containing a specific styryl compound for a charge transporting material, which is improved in photographic propertied such as photosensitivity and repeating properties.
    Type: Grant
    Filed: April 25, 1988
    Date of Patent: January 2, 1990
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 4882250
    Abstract: A photoreceptor comprises a conductive substrate, a charge generating layer and a charge transporting layer, the charge generating layer being formed by bonding to the substrate a film layer having a composition consisting of copper phthalocyanine and a binder and then exposing said bonded film to iodine vapor for 1-120 min at 20 deg C.-90 deg C. The charge transporting layer is formed of a binder and an organic compound selected from hydrazones, pyrazolines, oxazoles, thiazoles and triaryl methane.
    Type: Grant
    Filed: July 22, 1988
    Date of Patent: November 21, 1989
    Assignee: Industrial Technology Research Institute
    Inventors: Jonq-Min Liu, Tai-Jun Chen, Lii-Chyuan Tsai, Li-Wen Pai
  • Patent number: 4882255
    Abstract: A photoconductor for electrophotography comprises a novel disazo compound as a charge generating substance. A disazo compound is represented by the following general formula: ##STR1## wherein, each of Ar.sub.1 and Ar.sub.2 stands for an aromatic hydrocarbon group or an aromatic heterocyclic group, both of which may have a substituent(s),each of R.sub.1 and R.sub.2 stands for an hydrogen atom or an alkyl group or an aryl group, a heterocyclic group which may have a substituent(s); andC.sub.p stands for a coupler residual group.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: November 21, 1989
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Yoshimasa Hattori, Noboru Furusho
  • Patent number: 4882427
    Abstract: This invention provides an optical semiconductor material comprising: (1) a noncrystalline titanium phthalocyanine compound which does not show substantial X-ray diffraction peak in X-ray diffraction chart, (2) a pseudo-noncrystalline titanium phthalocyanine compound which shows broad X-ray diffraction peaks at Bragg angles of 6.9.degree., 15.5.degree., 23.4.degree. and 25.5.degree. measured by using CuK.alpha. beam and (3) an assembly of said noncrystalline titanium phthalocyanine compound and pseudo-noncrystalline titanium phthalocyanine compound. Further, this invention provides an electrophotographic plate comprising an electrically conductive substrate, and a charge-generating layer and charge-transferring layer on the electrically conductive substrate, characterized in that the charge-generating layer contains the above noncrystalline and/or pseudo-noncrystalline titanium phthalocyanine compound(s).
    Type: Grant
    Filed: February 17, 1989
    Date of Patent: November 21, 1989
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Toshio Enokida, Shigemasa Takano
  • Patent number: 4882248
    Abstract: An electrophotographic plate for making a printing plate is provided. Said electrophotographic plate comprises an electrically conductive and hydrophilic base and a photoconductive layer provided thereon, said photoconductive layer containing an alkali and/or alcohol soluble polymer, a phtalocyanine pigment and a compound represented by the formula (I):(X).sub.n Y (I)where X represents thiobarbituric acid residue from which one hydrogen atom at 5-position has been eliminated and in which nitrogen atom in a ring may have a substituent; Y represents an n-valent substituted or unsubstituted alkylene or aralkylene residue; and n represents an integer of 2 to 4. This plate has high sensitivity and resolving power and from this plate a printing plate of high printing endurance and low printing strain can be made.
    Type: Grant
    Filed: March 14, 1988
    Date of Patent: November 21, 1989
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Jun Yamada, Hiromi Eguchi
  • Patent number: 4882249
    Abstract: Disclosed are a photoconductive composition containing a new tetrakisazo compound of the following formula (1) and an electrophotographic photoreceptor having a photosensitive layer which contains the tetrakisazo compound of the formula (1): ##STR1## wherein R.sup.11, R.sup.12, A, Ar.sup.1, Ar.sup.2, Ar.sup.3, Ar.sup.4, Ar.sup.5, and Ar.sup.6 are defined hereinbefore. The electrophotographic photoreceptor has both high sensitivity and high durability, and the sensitivity thereof is barely lowered even after repeated use.
    Type: Grant
    Filed: September 12, 1988
    Date of Patent: November 21, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsugi Kitatani, Satoshi Hoshi
  • Patent number: 4877703
    Abstract: A photoconductor for electrophotography comprising a novel squarylium as a charge generating substance. A squarylium compound is represented by the following general formula: ##STR1## wherein, each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 stands for a hydrogen atom, a halogen atom, an alkyl group, an aryl group, or a nitro group, and each of R.sub.7 and R.sub.8 stands for a hydrogen atom or a hydroxy group.
    Type: Grant
    Filed: December 14, 1988
    Date of Patent: October 31, 1989
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Masami Kuroda, Yoshimasa Hattori, Noboru Furusho, Yoshinobu Sugata
  • Patent number: 4871633
    Abstract: The present invention uses an azo pigment having in the center of an N-oxide heterocyclic structure as a photoelectrical charge-generating material. The pigments are excellent in dispersion stability in a dispersed solution, and enable the provision of a photosensitive member excellent in sensitivity properties.
    Type: Grant
    Filed: November 24, 1987
    Date of Patent: October 3, 1989
    Assignees: Minolta Camera Kabushiki Kaisha, Osaka Municipal Government
    Inventors: Masakazu Takata, Takamasa Ueda, Kimiyuki Ito, Tsuneaki Hirashima, Souichi Yamamoto, Yoshio Ishino, Toshinobu Ohno
  • Patent number: 4865935
    Abstract: The present invention relates to a photosensitive member containing a specific azo compound for a charge generating agent, which is improved in photosensitive properties, in particular, sensitivity.
    Type: Grant
    Filed: February 10, 1988
    Date of Patent: September 12, 1989
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 4859555
    Abstract: An electrophotographic printing plate comprises a substrate having formed thereon a photoconductive layer comprising (a) a disazo based compound, (b) a perynone based compound, (c) a hole transport material, and (d) an alkali-soluble resin.
    Type: Grant
    Filed: October 13, 1987
    Date of Patent: August 22, 1989
    Assignee: Dainippon Ink & Chemical, Inc.
    Inventors: Yoshihiro Nishio, Masanobu Nakamura, Midori Fukawatase, Kenji Takahashi
  • Patent number: 4851315
    Abstract: A photoconductive film includes at least one kind of bis-azo pigments and exhibits a high sensitivity. The film may be used as an electrophotographic light-sensitive element.
    Type: Grant
    Filed: March 17, 1988
    Date of Patent: July 25, 1989
    Assignee: Alps Electric Co., Ltd.
    Inventors: Katsunori Fujio, Setsuo Ishibashi
  • Patent number: 4840862
    Abstract: A photoconductive composition containing at least one of azaazulenium salt compounds represented by the following formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each represents a hydrogen atom, a halogen atom, a hydroxyl group, a nitro group, a carboxyl group, a sulfonic acid group, a mercapto group or a monovalent organic residue; A represents a divalent organic group bonded by the double bond; X.sup..crclbar. represents an anionic group; n is the number of X.sup..crclbar. groups required to balance the positive charge; provided that each X.sup..crclbar. group may be bonded to any of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 or A to form an inner salt; and any two of R.sub.2, R.sup.3, R.sub.4, R.sub.5 and R.sub.6 bonded to adjacent carbon atoms may be linked to form a substituted or unsubstituted aromatic carbocyclic or aromatic heterocyclic ring.
    Type: Grant
    Filed: August 7, 1987
    Date of Patent: June 20, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naonori Makino, Takanori Hioki, Yoshio Inagaki, Seiji Horie
  • Patent number: 4833054
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive support having provided thereon a photosensitive layer composed of a charge generating layer and a charge transport layer, wherein said charge generating layer contains a bisazo compound represented by formula (I) ##STR1## wherein X, Y, and A are defined in the specification, and said charge transport layer contains a benzidine compound represented by formula (II) ##STR2## wherein R.sub.1, R.sub.2, and R.sub.3 are as defined in the specification. The photoreceptor exhibits high photoresponse performance even in a weak electric field and exhibits high sensitivity in a visible light region.
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: May 23, 1989
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yutaka Akasaki, Katsuhiro Sato, Tokita, Hidemi Suto
  • Patent number: 4830944
    Abstract: A function separated type electrophotographic photosensitive member for infrared rays comprises a combination of a charge generation material and a charge transport material, wherein the electrophotographic photosensitive member for infrared rays contains as the charge generation material a disazo pigment represented by Formula (1).
    Type: Grant
    Filed: December 19, 1986
    Date of Patent: May 16, 1989
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shoji Umehara, Masakazu Matsumoto, Takao Takiguchi, Shozo Ishikawa
  • Patent number: 4830942
    Abstract: An electrophotographic photoconductor an electroconductive substrate, an intermediate layer comprising a charge generating azo pigment and a thermosetting resin, a charge generating layer and a charge transporting layer, which layers are successively overlaid on the electroconductive substrate, the charge generating azo pigment being any of the azo pigments (1) through (4): ##STR1##
    Type: Grant
    Filed: May 26, 1987
    Date of Patent: May 16, 1989
    Assignee: Ricoh Company Ltd.
    Inventors: Toshio Fukagai, Michio Kimura, Masafumi Ohta, Mitsuru Hashimoto
  • Patent number: 4820600
    Abstract: An electrophotographic photoreceptor is disclosed, comprising a conductive support having provided thereon a photosensitive layer containing a bisazo compound represented by formula (I) ##STR1## wherein X represents a halogen atom or a nitro group, and A represents a substituted or unsubstituted divalent aromatic hydrocarbon group or a substituted unsubstituted divalent nitrogen-containing heterocyclic group. The photoreceptor exhibits excellent sensitivity and durability.
    Type: Grant
    Filed: August 5, 1987
    Date of Patent: April 11, 1989
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yutaka Akasaki, Akihiko Tokita, Kaoru Torikoshi, Akira Imai, Touru Ishii
  • Patent number: 4814245
    Abstract: An electrophotographic photoreceptor is described, comprising a photosensitive layer disposed on a conductive substrate, said photosensitive layer having a laminated structure comprising an electric charge generating layer and an electric charge transporting layer, said electric charge generating layer containing a phthalocyanine pigment which is selected from .epsilon.
    Type: Grant
    Filed: August 18, 1987
    Date of Patent: March 21, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Horie, Naonori Makino, Hideo Sato
  • Patent number: 4810607
    Abstract: A photosensitive member for electrophotography comprises a photosensitive layer containing a trisazo pigment represented by the formula: ##STR1## wherein Ar.sub.1 is a pyridylene group capable of having a substituent; Ar.sub.2 and Ar.sub.3 are respectively a pyridylene group or an arylene group each capable of having a substituent; and A is a coupler residue having a phenolic OH group. Because the trisazo pigment has a characteristic central skeleton including the central nitrogen atom and an adjacent pyridylene group, the photosensitive member has a sensitivity region expanded to the near-infrared region and shows a stable charging characteristic during a continuous electrophotographic operation.
    Type: Grant
    Filed: July 14, 1987
    Date of Patent: March 7, 1989
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masakazu Matsumoto, Takao Takiguchi, Hideyuki Takai
  • Patent number: 4810608
    Abstract: The present invention relates to a photo sensitive member containing a specific azo compound for a charge generating agent, which is improved in photosensitive properties, in particular, sensitivity.
    Type: Grant
    Filed: February 10, 1988
    Date of Patent: March 7, 1989
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 4792508
    Abstract: An improved layered photoresponsive imaging member comprised of a supporting substrate; a photogenerator layer comprised of cis and trans naphthalene imidazole perylene component of the following formula; ##STR1## and an aryl amine hole transport layer dispersed in a resinous binder.
    Type: Grant
    Filed: June 29, 1987
    Date of Patent: December 20, 1988
    Assignee: Xerox Corporation
    Inventors: Peter M. Kazmaier, Richard A. Burt, Ah-Mee Hor, Cheng-Kuo Hsiao
  • Patent number: 4783387
    Abstract: The present invention provides a new photosensitive member, in which a specific disazo pigment is used as a photoconductive material, which is excellent in whole static properties, especially in sensitivity.
    Type: Grant
    Filed: October 7, 1987
    Date of Patent: November 8, 1988
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 4762760
    Abstract: An electrophotographic recording material is comprised of an electrically conducting film base, an optional, adhesion-promoting, insulating intermediate film and at least one binder-containing photoconductive film that also contains a charge-carrier generating compound and pyrazoline charge-transporting compound represented by the formula ##STR1## in which n denotes zero or 1 andR.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 respectively denote hydrogen or halogen, preferably chlorine or bromine.Such a recording material has a low pre-exposure sensitivity combined with very good photosensitivity, and a low residual charge level in cyclic behavior. The charge-transporting compound has a low tendency to crystallize out in the film.
    Type: Grant
    Filed: January 29, 1987
    Date of Patent: August 9, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wolfgang Wiedemann, Michael Drexler, Juergen Fuerderer