Blocked Restrainers Patents (Class 430/960)
  • Patent number: 4358525
    Abstract: Photographically useful compounds such as photographic reagents and photographic dyes are blocked with a grouping which, under alkaline conditions, is cleaved from the compound by an intramolecular nucleophilic displacement reaction. The compounds are resistant to unblocking under storage conditions, but are uniformly unblocked under conditions encountered during photographic processing.
    Type: Grant
    Filed: August 12, 1981
    Date of Patent: November 9, 1982
    Assignee: Eastman Kodak Company
    Inventors: Jared B. Mooberry, William C. Archie, Jr.
  • Patent number: 4358532
    Abstract: A photographic element containing a compound represented by formula (I) ##STR1## wherein G represents --OR.sup.1 or --NHR.sup.2, R.sup.1 represents hydrogen or a hydrolyzable moiety, R.sup.2 represents hydrogen or an alkyl group containing from 1 to 50 carbon atoms, Z represents a photographically useful group, A represents an atomic group forming an aromatic ring, Ball represents an organic immobilizing group on the aromatic ring, which cntains from 8 to 50 carbon atoms, m represents an integer of 1 or 2, X represents a divalent organic group, Nu represents a nucleophilic group, and n represents an integer of 1 or 2, and X with the nucleophilic group Nu is capable of forming a 5- to 12-membered ring by oxidation having an electrophilic center at the carbon atom substituted by the --NHSO.sub.2 Z group.
    Type: Grant
    Filed: July 15, 1981
    Date of Patent: November 9, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Koyama, Shinsaku Fujita
  • Patent number: 4351896
    Abstract: Mesoionic 1,2,4-triazolium-3-thiolate silver halide stabilizer precursors are novel compounds useful in a heat developable and heat stabilizable photographic silver halide materials and processes. After imagewise exposure of the photographic material, a developed and stabilized silver image is produced by heating the element. Mesoionic stabilizer precursors are also useful in photographic silver halide processing compositions.
    Type: Grant
    Filed: November 9, 1981
    Date of Patent: September 28, 1982
    Assignee: Eastman Kodak Company
    Inventors: Henry W. Altland, Daniel D. Shiao
  • Patent number: 4350752
    Abstract: Imidomethyl blocked photographic reagents are useful in photographic elements, film units and processes. The blocked photographic reagents have the structure: ##STR1## wherein: J represents ##STR2## X represents the atoms to complete a 5- or 6-membered ring or ring system; R represents hydrogen, alkyl or 1 to 4 carbon atoms or aryl of 6 to 12 carbon atoms; andPR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the imidomethyl blocking group.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: September 21, 1982
    Assignee: Eastman Kodak Company
    Inventors: James A. Reczek, Thomas R. Welter
  • Patent number: 4350754
    Abstract: There are described novel compounds which are represented by the formula ##STR1## wherein R is ##STR2## A is sulfur or selenium; X represents the nonmetallic atoms necessary to form a nucleus which completes a five or six membered heterocyclic moiety; R.sub.1 is H or lower alkyl; R.sub.2 is H or a hydrolyzable group; and R.sub.3 is H, alkyl or a hydrolyzable group. The compounds are useful in photographic applications and provide controlled release of a photographically useful material during processing of photographic elements with an aqueous alkaline processing composition.
    Type: Grant
    Filed: June 12, 1981
    Date of Patent: September 21, 1982
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Anthony J. Puttick
  • Patent number: 4340664
    Abstract: Latexes suited for homogeneously incorporating compounds with a photographically useful group into photographic silver halide emulsion materials. The latex incorporates a copolymer comprising recurring units of a monomer with photographically useful group, and recurring units of surface active monomer, according to the general formula: ##STR1## wherein: R.sup.1 is hydrogen or methyl,n is 0 or 1 to 20,L is ##STR2## R.sup.2 is hydrogen or a hydrocarbon group, R.sup.3 is a monovalent chemical bond or a bivalent aliphatic hydrocarbon group or such group interrupted by the group --COO-- or --CONR--, andY is a sulpho, sulphato or phosphono group in acid or salt form, and at least one of the groups --(CH.sub.2).sub.n --, R.sup.2 and R.sup.3 is or comprises a hydrocarbon chain of at least 8 C-atoms.
    Type: Grant
    Filed: September 19, 1980
    Date of Patent: July 20, 1982
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Marcel J. Monbaliu, Walter F. De Winter, Raphael K. Van Poucke
  • Patent number: 4324856
    Abstract: A photographic silver halide material is disclosed which contains a precursor of photographic chemicals.
    Type: Grant
    Filed: October 7, 1980
    Date of Patent: April 13, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Satoshi Kawakatsu, Shigeto Hirabayashi, Hidetaka Ninomiya, Yutaka Kaneko
  • Patent number: 4242444
    Abstract: A process for the preparation of a silver halide photographic material is disclosed which provides for the formation of a photographic layer by the use of a coating solution containing a compound represented by formula I or II.C.sub.3n F.sub.(6n)-1 --Y--A--B (I)C.sub.3n F.sub.(6n)-1 --Y--A--X--A--Y--C.sub.3n F.sub.(6n)-1 (II)wherein A represents a simple bond or a divalent group; Y represents oxygen or sulfur, or ##STR1## B represents a monovalent hydrophilic group; X represents a divalent hydrophilic group; n represents an integer of 1 to 4; R.sub.1 represents hydrogen, a lower alkyl group; and A' represents a simple bond or an alkylene group.
    Type: Grant
    Filed: June 30, 1978
    Date of Patent: December 30, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Teiji Habu, Masao Ishihara, Sadatugu Terada, Eiichi Sakamoto, Hiroshi Yamada