Sequential Etching Steps On A Single Layer Patents (Class 438/734)
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Patent number: 8703604Abstract: Embodiments of the invention provide a method of creating vias and trenches with different length. The method includes depositing a plurality of dielectric layers on top of a semiconductor structure with the plurality of dielectric layers being separated by at least one etch-stop layer; creating multiple openings from a top surface of the plurality of dielectric layers down into the plurality of dielectric layers by a non-selective etching process, wherein at least one of the multiple openings has a depth below the etch-step layer; and continuing etching the multiple openings by a selective etching process until one or more openings of the multiple openings that are above the etch-stop layer reach and expose the etch-stop layer. Semiconductor structures made thereby are also provided.Type: GrantFiled: March 8, 2012Date of Patent: April 22, 2014Assignee: International Business Machines CorporationInventors: Shom Ponoth, David V. Horak, Takeshi Nogami, Chih-Chao Yang
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Patent number: 8696919Abstract: A method for manufacturing a nozzle and an associated funnel in a single plate comprises providing the single plate, the plate being etchable; providing an etch resistant mask on the plate, the mask having a pattern, wherein the pattern comprises a first pattern part for etching the nozzle and a second pattern part for etching the funnel; covering one of the first pattern part and the second pattern part using a first cover; etching one of the nozzle and funnel corresponding to the pattern part not covered in step (c); removing the first cover; etching the other one of the nozzle and funnel; and removing the etch resistant mask.Type: GrantFiled: November 16, 2012Date of Patent: April 15, 2014Assignee: Oce-Technologies B.V.Inventors: René J. Van Der Meer, Hubertus M. J. M. Boesten, Maarten J. Bakker, David D. L. Wijngaards
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Patent number: 8691703Abstract: A semiconductor device is manufactured by, inter alia: forming second gate lines, arranged at wider intervals than each of first gate lines and first gate lines, over a semiconductor substrate; forming a multi-layered insulating layer over the entire surface of the semiconductor substrate including the first and the second gate lines; etching the multi-layered insulating layer so that a part of the multi-layered insulating layer remains between the first gate lines and the first and the second gate lines; forming mask patterns formed on the respective remaining multi-layered insulating layers and each formed to cover the multi-layered insulating layer between the second gate lines; and etching the multi-layered insulating layers remaining between the first gate lines and between the first and the second gate lines and not covered by the mask patterns so that the first and the second gate lines are exposed.Type: GrantFiled: August 14, 2012Date of Patent: April 8, 2014Assignee: SK Hynix Inc.Inventors: Suk Ki Kim, Hyeon Soo Kim
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Patent number: 8691701Abstract: A method for forming etched features in a low-k dielectric layer disposed below the photoresist mask in a plasma processing chamber is provided. Features are etched into the low-k dielectric layer through the photoresist mask. The photoresist mask is stripped, wherein the stripping comprising at least one cycle, wherein each cycle comprises a fluorocarbon stripping phase, comprising flowing a fluorocarbon stripping gas into the plasma processing chamber, forming a plasma from the fluorocarbon stripping gas, and stopping the flow of the fluorocarbon stripping gas into the plasma processing chamber and a reduced fluorocarbon stripping phase, comprising flowing a reduced fluorocarbon stripping gas that has a lower fluorocarbon flow rate than the fluorocarbon stripping gas into the plasma processing chamber, forming the plasma from the reduced fluorocarbon stripping gas, and stopping the flow of the reduced fluorocarbon stripping gas.Type: GrantFiled: May 8, 2009Date of Patent: April 8, 2014Assignee: Lam Research CorporationInventors: Bing Ji, Andrew D. Bailey, III, Maryam Moravej, Stephen M. Sirard
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Publication number: 20140094037Abstract: A method for combinatorially processing a substrate is provided. The method includes introducing a first etchant into a reactor cell and introducing a fluid into the reactor cell while the first etchant remains in the reactor cell. After initiating the introducing the fluid, contents of the reactor cell are removed through a first removal line and a second removal line, wherein the first removal line extends farther into the reactor cell than the second removal line. A level of the fluid above an inlet to the first removal line is maintained while removing the contents. A second etchant is introduced into the reactor cell while removing the contents through the first removal line and the second removal line. The method includes continuing the introducing of the second etchant until a concentration of the second etchant is at a desired level, wherein the surface of the substrate remains submerged.Type: ApplicationFiled: December 4, 2013Publication date: April 3, 2014Applicant: Intermolecular, Inc.Inventors: Edwin Adhiprakasha, Shuogang Huang
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Patent number: 8685862Abstract: A micropattern is joined to a substrate (W1) by: a first group of covering step and micropattern forming step by etching in a transfer step; and a second group of covering step and micropattern forming step by etching in the transfer step.Type: GrantFiled: July 23, 2012Date of Patent: April 1, 2014Assignee: Toshiba Kikai Kabushiki KaishaInventors: Hiroshi Goto, Hiroshi Okuyama, Mitsunori Kokubo, Kentaro Ishibashi
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Patent number: 8679983Abstract: A method of suppressing the etch rate for exposed silicon-and-nitrogen-containing material on patterned heterogeneous structures is described and includes a two stage remote plasma etch. The etch selectivity of silicon relative to silicon nitride and other silicon-and-nitrogen-containing material is increased using the method. The first stage of the remote plasma etch reacts plasma effluents with the patterned heterogeneous structures to form protective solid by-product on the silicon-and-nitrogen-containing material. The plasma effluents of the first stage are formed from a remote plasma of a combination of precursors, including nitrogen trifluoride and hydrogen (H2). The second stage of the remote plasma etch also reacts plasma effluents with the patterned heterogeneous structures to selectively remove material which lacks the protective solid by-product. The plasma effluents of the second stage are formed from a remote plasma of a fluorine-containing precursor.Type: GrantFiled: April 18, 2012Date of Patent: March 25, 2014Assignee: Applied Materials, Inc.Inventors: Yunyu Wang, Anchuan Wang, Jingchun Zhang, Nitin K. Ingle, Young S. Lee
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Patent number: 8680677Abstract: Electrical connection in an integrated circuit arrangement is facilitated with carbon nanotubes. According to various example embodiments, a carbon nanotube material (120, 135) is associated with another material (130, 125) such as a metal. The carbon nanotube material facilitates the electrical connection between different circuit components.Type: GrantFiled: November 4, 2005Date of Patent: March 25, 2014Assignee: NXP B.V.Inventor: Christopher Wyland
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Patent number: 8679985Abstract: A dry etching method for a silicon nitride film capable of improving throughput is provided. A dry etching method for dry-etching a silicon nitride film 103 includes dry-etching the silicon nitride film 103 without generating plasma by using a processing gas containing at least a hydrogen fluoride gas (HF gas) and a fluorine gas (F2 gas), with respect to a processing target object 100 including the silicon nitride film 103.Type: GrantFiled: February 2, 2010Date of Patent: March 25, 2014Assignee: Tokyo Electron LimitedInventors: Eiichi Nishimura, Yusuke Shimizu
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Patent number: 8673785Abstract: A gas distribution system for supplying different gas compositions to a chamber, such as a plasma processing chamber of a plasma processing apparatus is provided. The gas distribution system can include a gas supply section, a flow control section and a switching section. The gas supply section provides first and second gases, typically gas mixtures, to the flow control section, which controls the flows of the first and second gases to the chamber. The chamber can include multiple zones, and the flow control section can supply the first and second gases to the multiple zones at desired flow ratios of the gases. The gas distribution system can continuously supply the first and second gases to the switching section and the switching section is operable to switch the flows of the first and second gases, such that one of the first and second process gases is supplied to the chamber while the other of the first and second gases is supplied to a by-pass line, and then to switch the gas flows.Type: GrantFiled: March 3, 2010Date of Patent: March 18, 2014Assignee: Lam Research CorporationInventors: Zhisong Huang, Jose Tong Sam, Eric H. Lenz, Rajinder Dhindsa, Reza Sadjadi
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Patent number: 8658543Abstract: A method for fabricating an integrated circuit is disclosed that includes, in accordance with an embodiment, providing an integrated circuit comprising a p-type field effect transistor (pFET), recessing a surface region of the pFET using an ammonia-hydrogen peroxide-water (APM) solution to form a recessed pFET surface region, and depositing a silicon-based material channel on the recessed pFET surface region.Type: GrantFiled: February 7, 2012Date of Patent: February 25, 2014Assignee: GLOBALFOUNDRIES, Inc.Inventors: Joanna Wasyluk, Stephan Kronholz, Yew-Tuck Chow, Richard J. Carter, Berthold Reimer, Kai Tern Sih
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Patent number: 8652345Abstract: A method of forming a patterned substrate is provided. The method includes providing a substrate (300) having a structured surface region comprising one or more recessed features (310). The method includes disposing a first liquid (325) onto at least a portion of the structured surface region. The method includes contacting the first liquid with a second liquid (330). The method includes displacing the first liquid with the second liquid from at least a portion (315) of the structured surface region. The first liquid is selectively located in at least a portion of the one or more recessed features.Type: GrantFiled: May 26, 2009Date of Patent: February 18, 2014Assignee: 3M Innovative Properties CompanyInventors: Cristin E. Moran, Matthew H. Frey, Matthew S. Stay, Mikhail L. Pekurovsky
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Patent number: 8637407Abstract: Methods of forming a semiconductor device may include providing a feature layer having a first region and a second region. The methods may also include forming a dual mask layer on the feature layer. The methods may further include forming a variable mask layer on the dual mask layer. The methods may additionally include forming a first structure on the feature layer in the first region and a second structure on the feature layer in the second region by patterning the variable mask layer and the dual mask layer. The methods may also include forming a first spacer on a sidewall of the first structure and a second spacer on a sidewall of the second structure. The methods may further include removing the first structure while maintaining at least a portion of the second structure.Type: GrantFiled: September 23, 2011Date of Patent: January 28, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Jae-Ho Min, O-Ik Kwon, Bum-Soo Kim, Dong-chan Kim, Myeong-cheol Kim
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Patent number: 8609550Abstract: A structure, such as an integrated circuit device, is described that includes a line of material with critical dimensions which vary within a distribution substantially less than that of a mask element, such as a patterned resist element, used in etching the line. Techniques are described for processing a line of crystalline phase material which has already been etched using the mask element, in a manner which straightens an etched sidewall surface of the line. The straightened sidewall surface does not carry the sidewall surface variations introduced by photolithographic processes, or other patterning processes, involved in forming the mask element and etching the line.Type: GrantFiled: January 13, 2012Date of Patent: December 17, 2013Assignee: Synopsys, Inc.Inventors: Victor Moroz, Lars Bomholt
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Patent number: 8575034Abstract: The present invention relates to a fabricating method of a semiconductor element. First, a substrate is provided and a first layout structure having a first width is formed on the substrate. Then, an etching mask is formed to cover the first layout structure, and the etching mask exposes a portion of the first layout structure. After that, the first layout structure is etched with the etching mask to form a second layout structure having a second width. The second width is less than the first width. This fabricating method is capable of finishing the fabrication of gate structures in two different directions. Accordingly, the layout flexibility is improved.Type: GrantFiled: October 28, 2011Date of Patent: November 5, 2013Assignee: United Microelectronics CorporationInventors: Ming-Te Wei, Po-Chao Tsao, Ming-Tsung Chen
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Patent number: 8569168Abstract: Method of forming a semiconductor structure which includes forming first conductive spacers on a semiconductor substrate; forming second conductive spacers with respect to the first conductive spacers, at least one of the second conductive spacers adjacent to and in contact with each of the first conductive spacers to form combined conductive spacers; recessing the second conductive spacers with respect to the first conductive spacers so that the first conductive spacers extend beyond the second conductive spacers; depositing an ILD to cover the first and second spacers except for an exposed edge of the first conductive spacers; patterning the exposed edges of the first conductive spacers to recess the edges of the first conductive spacers in predetermined locations to form recesses with respect to the ILD; and filling the recesses with an insulating material to leave unrecessed edges of the first conductive spacers as vias to subsequent wiring features.Type: GrantFiled: February 13, 2012Date of Patent: October 29, 2013Assignee: International Business Machines CorporationInventors: Steven J. Holmes, David V. Horak, Charles W. Koburger, III, Shom Ponoth, Chih-Chao Yang
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Patent number: 8569180Abstract: The present invention is related shielding integrated devices using CMOS fabrication techniques to form an encapsulation with cavity. The integrated circuits are completed first using standard IC processes. A wafer-level hermetic encapsulation is applied to form a cavity above the sensitive portion of the circuits using IC-foundry compatible processes. The encapsulation and cavity provide a hermetic inert environment that shields the sensitive circuits from EM interference, noise, moisture, gas, and corrosion from the outside environment.Type: GrantFiled: July 5, 2012Date of Patent: October 29, 2013Assignee: mCube Inc.Inventor: Xiao (Charles) Yang
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Patent number: 8563437Abstract: The invention discloses a treating method to produce various patterns on the surface by using gases with ability to etch the group III nitride semiconductor in certain conditions. The selective etching makes some specific patterns on group III nitride semiconductor surface, and different forms of the patterns can be controlled by the selective etching conditions.Type: GrantFiled: March 16, 2011Date of Patent: October 22, 2013Assignee: National Chiao Tung UniversityInventors: Wei-I Lee, Ying-Chia Hsu, Yen-Hsien Yeh, Kuei-Ming Chen
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Patent number: 8563429Abstract: Methods of forming a metal silicide layer are provided that include exposing polysilicon through just dry etching (JDE) and recessesing an oxide layer through chemical dry etching (CDE). In particular, dry etching is primarily performed to an extent to expose the polysilicon. Then, CDE is secondarily performed to expose the polysilicon. The CDE process includes selecting an etchant source among combinations of NF3 and NH3, HF and NH3, and N2, H2, and NF3, dissociating the etchant source, forming an etchant of NH4F and NH4F.HF through the dissociation, producing solid by-products of (NH4)2SiF6 through the reaction between the etchant and an oxide at a low temperature, and annealing the by-products at a high temperature such that the by-products are sublimated into gas-phase SiF4, NH3, and HF.Type: GrantFiled: February 12, 2010Date of Patent: October 22, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: Won-Goo Hur, Kyu-Tae Na, Min Kim, Hyun-Young Kim, Je-Hyeon Park
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Patent number: 8563367Abstract: A method of fabricating an array substrate for an in-plane switching (IPS)-mode liquid crystal display (LCD) device, which includes a common electrode and a pixel electrode with a fine line width, are provided. The formation of the pixel electrode and the common electrode of the array substrate includes depositing two different metal layers and patterning the two different metal layers using a selective etching process. Thus, the pixel electrode and a central common electrode may be formed to have a fine line width so that the IPS-mode LCD device can have an improved aperture ratio.Type: GrantFiled: December 21, 2012Date of Patent: October 22, 2013Assignee: LG Display Co., Ltd.Inventor: Oh-Nam Kwon
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Patent number: 8557706Abstract: A substrate processing method that forms an opening, which has a size that fills the need for downsizing a semiconductor device and is to be transferred to an amorphous carbon film, in a photoresist film of a substrate to be processed. Deposit is accumulated on a side wall surface of the opening in the photoresist film using plasma produced from a deposition gas having a gas attachment coefficient S of 0.1 to 1.0 so as to reduce the opening width of the opening.Type: GrantFiled: December 20, 2011Date of Patent: October 15, 2013Assignee: Tokyo Electron LimitedInventors: Masanobu Honda, Hironobu Ichikawa
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Patent number: 8551886Abstract: A method for semiconductor processing is provided wherein a workpiece having an underlying body and a plurality of features extending therefrom, is provided. A first set of the plurality of features extend from the underlying body to a first plane, and a second set of the plurality features extend from the underlying body to a second plane. A protection layer overlies each of the plurality of features and an isolation layer overlies the underlying body and protection layer, wherein the isolation has a non-uniform first oxide density associated therewith. The isolation layer anisotropically etched based on a predetermined pattern, and then isotropically etched, wherein a second oxide density of the isolation layer is substantially uniform across the workpiece. The predetermined pattern is based, at least in part, on a desired oxide density, a location and extension of the plurality of features to the first and second planes.Type: GrantFiled: April 9, 2008Date of Patent: October 8, 2013Assignee: Texas Instruments IncorporatedInventors: Kyle P. Hunt, Leila Elvira Noriega, Billy Alan Wofford, Asadd M. Hosein, Binghua Hu, Xinfen Chen
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Patent number: 8546265Abstract: A method for manufacturing a silicon structure according to the present invention includes, in a so-called dry-etching process wherein gas-switching is employed, the steps of: etching a portion in the silicon region at a highest etching rate under a high-rate etching condition such that the portion does not reach the etch stop layer; subsequently etching under a transition etching condition in which an etching rate is decreased with time from the highest etching rate in the high-rate etching condition; and thereafter, etching the silicon region under a low-rate etching condition of a lowest etching rate in the transition etching condition.Type: GrantFiled: April 8, 2009Date of Patent: October 1, 2013Assignee: SPP Technologies Co., Ltd.Inventors: Yoshiyuki Nozawa, Takashi Yamamoto
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Patent number: 8541312Abstract: A method of suppressing the etch rate for exposed silicon-and-nitrogen-containing material on patterned heterogeneous structures is described and includes a two stage remote plasma etch. The etch selectivity of silicon relative to silicon nitride and other silicon-and-nitrogen-containing material is increased using the method. The first stage of the remote plasma etch reacts plasma effluents with the patterned heterogeneous structures to form protective solid by-product on the silicon-and-nitrogen-containing material. The plasma effluents of the first stage are formed from a remote plasma of a combination of precursors, including nitrogen trifluoride and hydrogen (H2). The second stage of the remote plasma etch also reacts plasma effluents with the patterned heterogeneous structures to selectively remove material which lacks the protective solid by-product. The plasma effluents of the second stage are formed from a remote plasma of a fluorine-containing precursor.Type: GrantFiled: January 18, 2013Date of Patent: September 24, 2013Assignee: Applied Materials, Inc.Inventors: Yunyu Wang, Anchuan Wang, Jingchun Zhang, Nitin K. Ingle, Young S. Lee
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Patent number: 8518824Abstract: A method for patterning self-aligned vias in a dielectric. The method includes forming a first trench partially through a hard mask, where the trench corresponds to a desired wiring path in the dielectric. The trench should be formed on a sub-lithographic scale. Then, form a second trench, also of a sub-lithographic scale, that intersects the first trench. The intersection forms a pattern extending through the depth of the hard mask, and corresponds to a via hole in the dielectric. The via hole is etched into the dielectric through the hard mask. Then the first trench is extended through the hard mask and the exposed area is etched to form the wiring path, which intersects the via hole. Conductive material is deposited to form a sub-lithographic via and wiring. This method may be used to form multiple vias of sub-lithographic proportions and with a sub-lithographic pitch.Type: GrantFiled: July 26, 2012Date of Patent: August 27, 2013Assignee: International Business Machines CorporationInventors: John Christopher Arnold, Sean D. Burns, Sivananda K. Kanakasabapathy, Yunpeng Yin
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Patent number: 8513143Abstract: The present application discloses a method of manufacturing a semiconductor structure. According to at least one embodiment, a first etch stop layer is formed over a conductive feature and a substrate, and the conductive feature is positioned over the substrate. A second etch stop layer is formed over the first etch stop layer. A first etch is performed to form an opening in the second etch stop layer, and the opening exposes a portion of the first etch stop layer. A second etch is performed to extend the opening downwardly by removing a portion of the exposed first etch stop layer, and the extended opening exposes a portion of the conductive feature.Type: GrantFiled: August 18, 2011Date of Patent: August 20, 2013Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Mei-Hsuan Lin, Chih-Hsun Lin, Chih-Kang Chao, Ling-Sung Wang
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Patent number: 8507346Abstract: A method of forming a semiconductor device having a substrate, an active region and an inactive region includes: forming a hardmask layer over the substrate; transferring a first pattern into the hardmask layer in the active region of the semiconductor device; forming one or more fills in the inactive region; forming a cut-away hole within, covering, or partially covering, the one or more fills to expose a portion of the hardmask layer, the exposed portion being within the one or more fills; and exposing the hardmask layer to an etchant to divide the first pattern into a second pattern including at least two separate elements.Type: GrantFiled: November 18, 2010Date of Patent: August 13, 2013Assignee: International Business Machines CorporationInventors: Martin Burkhardt, Matthew E. Colburn, Allen H. Gabor, Oleg Gluschenkov, Scott D. Halle, Howard S. Landis, Helen Wang
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Patent number: 8492287Abstract: A silicon-containing film on a substrate is subjected to a plasma process using a process gas containing fluorine and carbon, and is thereafter subjected to plasma process using an ammonia gas, whereby ammonium silicofluoride having toxicity and hygroscopic property is adhered to the substrate. The harmful ammonium silicofluoride is removed by the inventive method. After conducting the plasma process using an ammonia gas, the substrate is heated to a temperature not lower than the decomposition temperature of the ammonium silicofluoride to decompose the ammonium silicofluoride in a process container in which the plasma process was conducted, or in a process container connected with the processing vessel which the plasma process was conducted therein and is isolated from a clean room atmosphere.Type: GrantFiled: May 2, 2011Date of Patent: July 23, 2013Assignee: Tokyo Electron LimitedInventor: Shigeru Tahara
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Patent number: 8492279Abstract: When forming via openings in sophisticated semiconductor devices, a silicon-containing anti-reflective coating (ARC) layer may be efficiently used for adjusting the critical dimension of the via openings by using a two-step etch process in which, in at least one of the process steps, the flow rate of a reactive gas component may be controlled to increase or reduce the resulting width of an opening in the silicon ARC layer. In this manner, the spread of critical dimensions of vias around the target value may be significantly reduced while also reducing any maintenance and rework efforts.Type: GrantFiled: June 21, 2011Date of Patent: July 23, 2013Assignee: GLOBALFOUNDRIES Inc.Inventors: Mohammed Radwan, Johann Steinmetz
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Patent number: 8492285Abstract: A dry etching method for texturing a surface of a substrate is disclosed. The method includes performing a first dry etching onto the surface of the substrate thereby forming a surface texture with spikes and valleys, the first dry etching comprising etching the surface of the substrate in a plasma comprising fluorine (F) radicals and oxygen (O) radicals, wherein the plasma comprises an excess of oxygen (O) radicals. The method may further include performing a second dry etching onto the surface texture thereby smoothening the surface texture, the second dry etching comprising chemical isotropic etching the surface texture, obtained after the first dry etching, in a plasma comprising fluorine (F) radicals, wherein the spikes are etched substantially faster than the valleys.Type: GrantFiled: September 15, 2011Date of Patent: July 23, 2013Assignee: IMECInventor: Boon Teik Chan
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Patent number: 8476122Abstract: A method for manufacturing a semiconductor device with high electric characteristics is provided. Part of a stacked semiconductor film in which an amorphous semiconductor film is provided on a crystalline semiconductor film is etched using a mixed gas including an HBr gas, a CF4 gas, and an oxygen gas, so that part of the crystalline semiconductor film provided in the stacked semiconductor film is exposed. Etching for forming a back channel portion of a thin film transistor is performed with the method for etching, whereby high electric characteristics can be provided for the thin film transistor.Type: GrantFiled: October 14, 2011Date of Patent: July 2, 2013Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Shinya Sasagawa, Hiroshi Fujiki
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Patent number: 8455325Abstract: A method of manufacturing a semiconductor device which includes forming a gate insulating film and a gate electrode over a semiconductor substrate, forming a first recess in the first semiconductor substrate on both sides of the gate electrode by dry etching, forming a second recess by removing a bottom and sidewalls of the first recess by wet etching, and forming a semiconductor layer in the second recess.Type: GrantFiled: January 10, 2012Date of Patent: June 4, 2013Assignee: Fujitsu Semiconductor LimitedInventors: Masahiro Fukuda, Yosuke Shimamune
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Patent number: 8455324Abstract: A method of manufacturing a semiconductor device which includes forming a gate insulating film and a gate electrode over a semiconductor substrate, forming a first recess in the first semiconductor substrate on both sides of the gate electrode by dry etching, forming a second recess by removing a bottom and sidewalls of the first recess by wet etching, and forming a semiconductor layer in the second recess.Type: GrantFiled: October 2, 2009Date of Patent: June 4, 2013Assignee: Fujitsu Semiconductor LimitedInventors: Masahiro Fukuda, Yosuke Shimamune
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Publication number: 20130137276Abstract: A method for combinatorially processing a substrate is provided. The method includes introducing a first etchant into a reactor cell and introducing a fluid into the reactor cell while the first etchant remains in the reactor cell. After initiating the introducing the fluid, contents of the reactor cell are removed through a first removal line and a second removal line, wherein the first removal line extends farther into the reactor cell than the second removal line. A level of the fluid above an inlet to the first removal line is maintained while removing the contents. A second etchant is introduced into the reactor cell while removing the contents through the first removal line and the second removal line. The method includes continuing the introducing of the second etchant until a concentration of the second etchant is at a desired level, wherein the surface of the substrate remains submerged.Type: ApplicationFiled: November 29, 2011Publication date: May 30, 2013Applicant: Intermolecular, Inc.Inventors: Edwin Adhiprakasha, Shuogang Huang
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Patent number: 8450166Abstract: Method of fabricating a semiconductor device includes forming a gate having a first material on a substrate and forming a layer of a second material overlaying the gate. Sidewall spacers are formed on opposite sides of the gate. The substrate is dry etched using the layer of second material and the sidewall spacers as a mask forming a recess in the substrate between two adjacent gates. A liner oxide layer is formed on inner walls of the recess. The liner oxide layer is removed by isotropic wet etching. Orientation selective wet etching is performed on the recess to shape the inner wall of the recess so as to cause the inner wall of the recess to be sigma-shaped. By removing the substrate portions having lattice defects due to dry etching through oxidation and wet etching, defect-free epitaxial growth performance is realized.Type: GrantFiled: November 9, 2011Date of Patent: May 28, 2013Assignee: Semiconductor Manufacturing International (Beijing) CorporationInventors: Yiying Zhang, Qiyang He
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Patent number: 8450167Abstract: A method of fabricating semiconductor device includes forming a plurality of gates on a substrate, forming a top layer on a top surface of each gate, forming sidewall spacers on opposite sides of each gate, and forming sacrificial spacers on the sidewall spacers. The method further includes performing a dry etching process on the substrate using the top layer and the sacrificial spacers as a mask to form a recess of a first width in the substrate between two adjacent gates, performing an isotropic wet etching process on the recess to expand the first width to a second width, and performing an orientation selective wet etching process on the recess to shape the rectangular-shaped recess into a ?-shaped recess.Type: GrantFiled: November 9, 2011Date of Patent: May 28, 2013Assignee: Semiconductor Manufacturing International (Beijing) CorporationInventors: Qiyang He, Yiying Zhang
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Patent number: 8445324Abstract: The present disclosure relates to a method of fabricating a micromachined CMOS-MEMS integrated device as well as the devices/apparatus resulting from the method. In the disclosed method, the anisotropic etching (e.g., DRIE) for isolation trench formation on a MEMS element is performed on the back side of a silicon wafer, thereby avoiding the trench sidewall contamination and the screen effect of the isolation beams in a plasma etching process. In an embodiment, a layered wafer including a substrate and a composite thin film thereon is subjected to at least one (optionally at least two) back side anisotropic etching step to form an isolation trench (and optionally a substrate membrane). The method overcomes drawbacks of other microfabrication processes, including isolation trench sidewall contamination.Type: GrantFiled: December 14, 2010Date of Patent: May 21, 2013Assignee: Oakland UniversityInventor: Hongwei Qu
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Patent number: 8420543Abstract: A method for treating the threading dislocation within a GaN-containing semiconductor layer is provided. The method includes a substrate is provided. A GaN-containing semiconductor layer with the threading dislocation is formed on the substrate. An etching process with an etching gas is performed to remove the threading dislocation in the GaN-containing semiconductor layer so as to increase the efficiency for the light emitting device.Type: GrantFiled: January 10, 2012Date of Patent: April 16, 2013Assignee: National Chiao Tung UniversityInventors: Wei-I Lee, Yen-Hsien Yeh, Yin-Hao Wu, Tzu-Yi Yu
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Patent number: 8421228Abstract: A contact structure and a method of forming the contact structure. The structure includes: a silicide layer on and in direct physical contact with a top substrate surface of a substrate; an electrically insulating layer on the substrate; and an aluminum plug within the insulating layer. The aluminum plug has a thickness not exceeding 25 nanometers in a direction perpendicular to the top substrate surface. The aluminum plug extends from a top surface of the silicide layer to a top surface of the insulating layer. The aluminum plug is in direct physical contact with the top surface of the silicide layer and is in direct physical contact with the silicide layer. The method includes: forming the silicide layer on and in direct physical contact with the top substrate surface of the substrate; forming the electrically insulating layer on the substrate; and forming the aluminum plug within the insulating layer.Type: GrantFiled: February 27, 2012Date of Patent: April 16, 2013Assignee: International Business Machines CorporationInventors: Ying Li, Keith Kwong Hon Wong, Chih-Chao Yang
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Patent number: 8389402Abstract: A method of via formation in a semiconductor device includes the following steps of providing a photoresist with a photoresist pattern defining an opening of a via, wherein the photoresist comprising a thermally cross-linking material is disposed on a structure layer; dry-etching the structure layer to a first depth through the opening; baking the thermally cross-linking material to reduce the opening; and dry-etching the structure layer to a second depth through the reduced opening, wherein the second depth is greater than the first depth.Type: GrantFiled: May 26, 2011Date of Patent: March 5, 2013Assignee: Nanya Technology CorporationInventors: Chih Ching Lin, Yi Nan Chen, Hsien Wen Liu
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Patent number: 8357617Abstract: Provided are methods of patterning metal gate structures including a high-k gate dielectric. In an embodiment, a soluble hard mask layer may be used to provide a masking element to pattern a metal gate. The soluble hard mask layer may be removed from the substrate by water or a photoresist developer. In an embodiment, a hard mask including a high-k dielectric is formed. In a further embodiment, a protection layer is formed underlying a photoresist pattern. The protection layer may protect one or more layers formed on the substrate from a photoresist stripping process.Type: GrantFiled: February 16, 2009Date of Patent: January 22, 2013Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Matt Yeh, Shun Wu Lin, Chi-Chun Chen, Ryan Chia-Jen Chen, Yi-Hsing Chen, Chien-Hao Chen, Donald Y. Chao, Kuo-Bin Huang
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Patent number: 8358010Abstract: A method for realizing a nanometric circuit architecture includes: realizing plural active areas on a semiconductor substrate; realizing on the substrate a seed layer of a first material; realizing a mask-spacer of a second material on the seed layer in a region comprised between the active areas; realizing a mask overlapping the mask-spacer and extending in a substantially perpendicular direction thereto; selectively removing the seed layer exposed on the substrate; selectively removing the mask and the mask-spacer obtaining a seed-spacer comprising a linear portion extending in that region and a portion substantially orthogonal thereto; realizing by MSPT from the seed-spacer an insulating spacer reproducing at least part of the profile of the seed-spacer; realizing by MSPT a nano-wire of conductive material from the seed-spacer or insulating spacer, the nano-wire comprising a first portion at least partially extending in the region and a second portion contacting a respective active area.Type: GrantFiled: February 28, 2005Date of Patent: January 22, 2013Assignee: STMicroelectronics S.r.l.Inventors: Danilo Mascolo, Gianfranco Cerofolini
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Publication number: 20130017687Abstract: A method for forming an opening in a semiconductor device is provided, including: providing a semiconductor substrate with a silicon oxide layer, a polysilicon layer and a silicon nitride layer sequentially formed thereover; patterning the silicon nitride layer, forming a first opening in the silicon nitride layer, wherein the first opening exposes a top surface of the polysilicon layer; performing a first etching process, using gasous etchants including hydrogen bromide (HBr), oxygen (O2), and fluorocarbons (CxFy), forming a second opening in the polysilicon layer, wherein a sidewall of the polysilicon layer adjacent to the second opening is substantially perpendicular to a top surface of the silicon oxide layer, wherein x is between 1-5 and y is between 2-8; removing the silicon nitride layer; and performing a second etching process, forming a third opening in the silicon oxide layer exposed by the second opening.Type: ApplicationFiled: July 14, 2011Publication date: January 17, 2013Applicant: NANYA TECHNOLOGY CORPORATIONInventors: Chih-Ching Lin, Yi-Nan Chen, Hsien-Wen Liu
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Patent number: 8354741Abstract: Provided are a lead frame, a semiconductor package, and a method of manufacturing the lead frame and the semiconductor package. The lead frame includes: a die pad on which a semiconductor chip is installable; a plurality of lead patterns formed around a circumference of the die pad; an insulating organic material filling etching spaces interposed between the die pad and the lead patterns and structurally supporting the die pad and the lead patterns; and a pre-plating layer formed on both upper and lower surfaces of the die pad and the lead patterns.Type: GrantFiled: January 5, 2012Date of Patent: January 15, 2013Assignee: Samsung Techwin Co., Ltd.Inventors: Sung-il Kang, Chang-han Shim
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Patent number: 8324110Abstract: Disclosed are a field effect transistor structure and a method of forming the structure. A gate stack is formed on the wafer above a designated channel region. Spacer material is deposited and anisotropically etched until just prior to exposing any horizontal surfaces of the wafer or gate stack, thereby leaving relatively thin horizontal portions of spacer material on the wafer surface and relatively thick vertical portions of spacer material on the gate sidewalls. The remaining spacer material is selectively and isotropically etched just until the horizontal portions of spacer material are completely removed, thereby leaving only the vertical portions of the spacer material on the gate sidewalls. This selective isotropic etch removes the horizontal portions of spacer material without damaging the wafer surface. Raised epitaxial source/drain regions can be formed on the undamaged wafer surface adjacent to the gate sidewall spacers in order to tailor source/drain resistance values.Type: GrantFiled: February 2, 2010Date of Patent: December 4, 2012Assignee: International Business Machines CorporationInventors: Kangguo Cheng, Bruce B. Doris, Yu Zhu
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Patent number: 8324109Abstract: A method for fabricating a semiconductor device includes forming a gate insulation layer over a substrate, sequentially forming a silicon layer and a metal layer over the gate insulation layer, performing a first gate etching process to etch the metal layer using a gate hard mask layer, formed on the metal layer, as an etch barrier, and then partially etch the silicon layer, thereby forming a first pattern, performing a second gate etching process to partially etch the silicon layer, thereby forming an undercut beneath the metal layer, forming a capping layer on both sidewalls of the first pattern including the undercut, performing a third gate etching process to etch the silicon layer to expose the gate insulation layer using the gate hard mask layer and the capping layer as an etch barrier, thereby forming a second pattern, and performing a gate re-oxidation process.Type: GrantFiled: December 18, 2009Date of Patent: December 4, 2012Assignee: Hynix Semiconductor, Inc.Inventors: Tae-Han Kim, Dong-Hyun Kim
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Patent number: 8314034Abstract: Methods for semiconductor device fabrication are provided. Features are created using spacers. Methods include creating a pattern comprised of at least two first features on the substrate surface, depositing a first conformal layer on the at least two first features, depositing a second conformal layer on the first conformal layer, partially removing the second conformal layer to partially expose the first conformal layer, and partially removing the first conformal layer from between the first features and the second conformal layer thereby creating at least two second features. Optionally the first conformal film is partially etched back before the second conformal film is deposited.Type: GrantFiled: December 23, 2010Date of Patent: November 20, 2012Assignee: Intel CorporationInventors: Elliot N. Tan, Michael K. Harper
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Patent number: 8298943Abstract: A method for patterning self-aligned vias in a dielectric. The method includes forming a first trench partially through a hard mask, where the trench corresponds to a desired wiring path in the dielectric. The trench should be formed on a sub-lithographic scale. Form a second trench, also of a sub-lithographic scale, that intersects the first trench. The intersection forms a pattern extending through the depth of the hard mask, and corresponds to a via hole in the dielectric. The via hole is etched into the dielectric through the hard mask. The first trench is extended through the hard mask and the exposed area is etched to form the wiring path, which intersects the via hole. Conductive material is deposited to form a sub-lithographic via and wiring. This method may be used to form multiple vias of sub-lithographic proportions and with a sub-lithographic pitch.Type: GrantFiled: May 27, 2011Date of Patent: October 30, 2012Assignee: International Business Machines CorporationInventors: John Christopher Arnold, Sean D. Burns, Sivananda K. Kanakasabapathy, Yunpeng Yin
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Patent number: 8298958Abstract: A method for reducing very low frequency line width roughness (LWR) in forming etched features in an etch layer disposed below a patterned organic mask is provided. The patterned organic mask is treated to reduce very low frequency line width roughness of the patterned organic mask, comprising flowing a treatment gas comprising H2, wherein the treatment gas has a flow rate and H2 has a flow rate that is at least 50% of the flow rate of the treatment gas, forming a plasma from the treatment gas, and stopping the flow of the treatment gas. The etch layer is etched through the treated patterned organic mask with the reduced very low LWR.Type: GrantFiled: July 17, 2008Date of Patent: October 30, 2012Assignee: Lam Research CorporationInventors: Yoko Y. Adams, David Yang
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Patent number: 8298961Abstract: A method of forming patterns of a semiconductor device comprises providing a semiconductor substrate comprising a first region wherein first patterns are to be formed and a second region wherein second patterns are to be formed, each of the second patterns having a wider width than the first patterns, forming an etch target layer over the semiconductor substrate, forming first etch patterns over the etch target layer of the first and second regions, forming second etch patterns on both sidewalls of each of the first etch patterns, wherein the second etch pattern formed in the second region has a wider width than the second etch pattern formed in the first region, removing the first etch patterns, forming third etch patterns over the etch target layer of the second region, the third etch pattern overlapping part of the second pattern, and etching the etch target layer using the third etch patterns and the second etch patterns as an etch mask, to form the first and second patterns.Type: GrantFiled: December 30, 2009Date of Patent: October 30, 2012Assignee: Hynix Semiconductor Inc.Inventor: Sung Kee Park