Methane (natural Gas) -containing Product, Or Treatment Or Recovery Process Patents (Class 48/127.3)
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Patent number: 11466631Abstract: A vehicle system having an internal combustion engine and evaporative emission system including a canister is described, wherein canister includes a chamber having a flexible Metal Organic Framework (MOF) material disposed therein. A controllable device is coupled to the flexible MOF material, and a controller is operatively connected to the controllable device and the purge valve. The controller includes an instruction set that is executable to activate the controllable device and control the purge valve to an open state in response to a command to purge the canister, determine an activation parameter for the controllable device, determine a purge flow, integrate the purge flow to determine a total purge mass, and deactivate the controllable device when the total purge mass is greater than a threshold.Type: GrantFiled: February 16, 2021Date of Patent: October 11, 2022Assignee: GM Global Technology Operations LLCInventors: Michael B. Viola, Darrell W. Burleigh, Timothy E. McCarthy, Anne M. Dailly
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Patent number: 11125495Abstract: A method for recovering natural gas liquids from a recycle stream having natural gas liquids includes receiving a carbon dioxide recycle stream that comprises carbon dioxide, natural gas, and the natural gas liquids. The carbon dioxide recycle stream is separated into a purified carbon dioxide recycle stream and a natural gas liquids stream. The purified carbon dioxide recycle stream comprises the carbon dioxide and the natural gas, and the natural gas liquids stream comprises the natural gas liquids. In another embodiment, a system comprises piping and a separator. The piping is configured to receive a recycle stream, and the separator is coupled to the piping and is configured to separate the recycle stream into a purified recycle stream and a natural gas liquids stream.Type: GrantFiled: January 3, 2020Date of Patent: September 21, 2021Assignee: Pilot Energy Solutions, LLCInventor: Eric Prim
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Patent number: 10975766Abstract: The present invention provides methods and system for power generation using a high efficiency combustor in combination with a CO2 circulating fluid. The methods and systems advantageously can make use of a low pressure ratio power turbine and an economizer heat exchanger in specific embodiments. Additional low grade heat from an external source can be used to provide part of an amount of heat needed for heating the recycle CO2 circulating fluid. Fuel derived CO2 can be captured and delivered at pipeline pressure. Other impurities can be captured.Type: GrantFiled: June 13, 2018Date of Patent: April 13, 2021Assignee: 8 Rivers Capital, LLCInventors: Rodney John Allam, Miles R. Palmer, Glenn William Brown, Jr., Jeremy Eron Fetvedt, Brock Alan Forrest
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Patent number: 10619917Abstract: A liquefaction system is capable of sequentially or simultaneously liquefying multiple feed streams of hydrocarbons having different normal bubble points with minimal flash. The liquefying heat exchanger has separate circuits for handling multiple feed streams. The feed stream with the lowest normal boiling point is sub-cooled sufficiently to suppress most of the flash. Feed streams with relatively high normal boiling points are cooled to substantially the same temperature, then blended with bypass streams to maintain each product near its normal bubble point. The system can also liquefy one stream at a time by using a dedicated circuit or by allocating the same feed to multiple circuits.Type: GrantFiled: September 13, 2017Date of Patent: April 14, 2020Assignee: Air Products and Chemicals, Inc.Inventors: Laurent Marc Brussol, David Joseph Holzer, Sylvain Vovard, Russell Shnitser, Adam Adrian Brostow, Mark Julian Roberts
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Patent number: 10393431Abstract: An integrated method for the production of liquefied natural gas (LNG) and syngas is provided. The method can include the steps of: utilizing letdown energy of a high pressure natural gas stream that is withdrawn from a natural gas pipeline to provide a warm temperature cooling; utilizing a refrigeration cycle to provide a cold temperature cooling, wherein the refrigeration cycle comprises a refrigerant recycle compressor that is powered utilizing a steam turbine; and cooling a second high pressure natural gas stream using the warm temperature cooling and the cold temperature cooling to produce an LNG product stream. The second high pressure natural gas stream is withdrawn from the natural gas pipeline, and the steam turbine is powered by high pressure steam that is produced from a syngas production facility.Type: GrantFiled: January 24, 2017Date of Patent: August 27, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Alexander Roesch, Alain Guillard, Michael A. Turney
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Patent number: 10281445Abstract: A headspace sampler includes: a sample gas collection channel whose one end communicates with a needle; a pressure gas introduction channel and an exhaust channel that communicate with the other end of the channel in parallel via a branching pipe; a pressure control device that delivers pressure gas to the pressure gas introduction channel at a predetermined pressure; solenoid valves provided in the pressure gas introduction channel and the exhaust channel, respectively; and switching means for switching a state where a measuring pipe is inserted in the sample gas collection channel and a state where the measuring pipe is shorted away from the channel, wherein a pressure sensor is provided on an upstream side of the solenoid valve in the exhaust channel.Type: GrantFiled: November 30, 2011Date of Patent: May 7, 2019Assignee: SHIMADZU CORPORATIONInventors: Akira Aono, Yoshitake Yamamoto
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Patent number: 10100264Abstract: The present disclosure provides an experimental loop system for fluidization exploitation of solid-state marine gas hydrate, comprising: four modules, namely a gas hydrate sample large-amount and rapid preparation module, a gas hydrate multi-scale smashing and slurry fidelity transfer module, a gas hydrate slurry pipeline conveying characteristic experiment module, and a data collection and monitoring and safety control module. The gas hydrate experimental loop device provided by the present disclosure may be used for researching the synthesis, decomposition, gas storage rate and phase equilibrium of gas hydrate, and researching the pipeline conveying flow resistance and heat transfer characteristics, and is significant for solving the blockage problem in the gas pipeline conveying process, storage and conveying of the gas hydrate, solid-state fluidization exploitation of the marine gas hydrate and pipeline conveying experimental simulation thereof.Type: GrantFiled: March 9, 2017Date of Patent: October 16, 2018Assignee: SOUTHWEST PETROLEUM UNIVERSITYInventors: Jinzhou Zhao, Yanjun Liu, Leilei Jiang, Shouwei Zhou, Mi Zhang, Ping Guo, Guorong Wang, Qingping Li, Zhiqiang Huang
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Patent number: 9441210Abstract: The present invention relates to a method of reducing the level of uric acid in a subject, which comprises administering to said subject an effective amount of a fermentation product of Tenacibaculum sp. Also provided are a method of preventing and/or treating a disease or disorder related to hyperuricemia, a method of increasing the digestion of uric acid and a method of producing uricase.Type: GrantFiled: June 25, 2014Date of Patent: September 13, 2016Assignee: FOOD INDUSTRY RESEARCH AND DEVELOPMENT INSTITUTEInventors: Mei-Huei Chen, Siao-Jhen Chen, Hsun-Yin Hsu, Yen-Lin Chen, Kai-Ping Chen, Yi-Jen Yech, Li-Ting Wang, Hing-Yuen Chan
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Patent number: 9382818Abstract: Methods of making fuel are described herein. A method may include providing a first working fluid, a second working fluid, and a third working fluid. The method may also include exposing each working fluid to a high voltage electric field to produce a first plasma, a second plasma, and a third plasma, respectively. The method may also include providing at least one fueling material and expositing it to one or more fourth high-voltage electric fields to produce a fueling material plasma. The method may also include contacting the plasmas within a processing chamber to form a plasma mixture, cooling the plasma mixture using a heat exchange device to form a cooled plasma mixture, and contacting the cooled plasma mixture with a catalyst to form a fuel.Type: GrantFiled: September 5, 2013Date of Patent: July 5, 2016Assignee: POWERDYNE, INC.Inventors: Geoffrey Hirson, Gus F. Shouse
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Patent number: 9353315Abstract: The present invention provides for a natural gas well vapor processing system and method comprising recovering gaseous hydrocarbons to prevent their release into the atmosphere including providing a method for preventing the gaseous hydrocarbons from returning to a liquid state.Type: GrantFiled: September 22, 2005Date of Patent: May 31, 2016Inventors: Rodney T. Heath, Forrest D. Heath, Gary Heath
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Patent number: 9255731Abstract: A method for recovering a sour natural gas liquids stream is provided. In one embodiment, a carbon dioxide recycle stream that comprises carbon dioxide, natural gas liquids, and acid gas is received. The carbon dioxide recycle stream is separated into a purified carbon dioxide recycle stream and a natural gas liquids stream. The purified carbon dioxide recycle stream comprises the carbon dioxide, and the natural gas liquids stream comprises the natural gas liquids and the acid gas. In another embodiment, a system comprises piping and a separator. The piping is configured to receive a recycle stream that comprises an injection gas, natural gas liquids, and acid gas. The separator is configured to separate the recycle stream into a purified recycle stream and a natural gas liquids stream. The purified recycle stream comprises the injection gas, and the natural gas liquids stream comprises the natural gas liquids and the acid gas.Type: GrantFiled: July 19, 2013Date of Patent: February 9, 2016Assignee: Pilot Energy Solutions, LLCInventors: Eric Prim, Naomi Baker, Jhansi Garikipati
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Patent number: 9089790Abstract: A system and process for removing hydrocarbons and divalent cations from a rich MEG feed stream is presented. A hydrocarbon removal bed containing a solid adsorbent material adsorbs the hydrocarbons in the rich MEG feed stream as it passes through the hydrocarbon removal bed. After the hydrocarbons have been removed, the rich MEG feed stream flows through an ion exchange bed containing an ion exchange resin in order to remove divalent cations. The rich MEG feed stream then flows through a flash separator and a distillation column to reclaim MEG. Spent solid adsorbent material in the hydrocarbon removal beds and spent ion exchange resin in the ion exchange beds may be regenerated in place using by-products of the MEG reclamation process.Type: GrantFiled: August 24, 2012Date of Patent: July 28, 2015Assignee: Cameron International CorporationInventors: Daniel W. Phelps, Luis Eduardo Caires Fernandez
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Patent number: 9086188Abstract: Disclosed is a system for reducing a heating value of natural gas. The system includes a heat exchanger to liquefy a portion of components having high heating values, a gas-liquid separator to separate the liquefied component, and a nitrogen adding mechanism to add nitrogen to remaining non-liquefied components. The system includes an additional heat exchanger to cool and liquefy the remaining non-liquefied components after the gas-liquid separator separates the liquefied component from the natural gas. The heat exchangers employ cold heat generated upon regasification of LNG. The system can reduce the heating value of natural gas composed of a variety of hydrocarbon components according to requirements of a place of demand by separating the component with the higher heating value from the natural gas to allow the separated component to be used as fuel, thereby reducing an overall size and operating costs of the system.Type: GrantFiled: July 21, 2008Date of Patent: July 21, 2015Assignee: DAEWOO SHIPBUILDING & MARINE ENGINEERING CO., LTD.Inventors: Jung Han Lee, Young Sik Moon, Dong Kyu Choi, Young Soo Kim, Jong Hyun Park
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Patent number: 9023310Abstract: A process for recovering sulfur from a hydrogen sulfide-bearing gas utilizes an aqueous reaction medium, a temperature of about 110-150° C., and a high enough pressure to maintain the aqueous reaction medium in a liquid state. The process reduces material and equipment costs and addresses the environmental disadvantages associated with known processes that rely on high boiling point organic solvents.Type: GrantFiled: April 25, 2014Date of Patent: May 5, 2015Assignee: Gas Technology InstituteInventor: Arunabha Basu
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Patent number: 9023123Abstract: Trace levels of mercury in a natural gas are reduced by scrubbing the natural gas in an absorber with an aqueous solution comprising a water-soluble sulfur compound. The water-soluble sulfur compound reacts with a least a portion of the mercury in the natural gas to produce a treated natural gas with a reduced concentration of mercury, and a mercury containing sulfur-depleted solution which can be disposed by injection into a (depleted) underground formation. The produced water extracted with the natural gas from the underground formation can be recycled for use as the scrubbing solution. In one embodiment, a fresh source of water-soluble sulfur compound as feed to the absorber can be generated on-site by reacting an elemental sulfur source with a sulfur reagent in produced water.Type: GrantFiled: May 16, 2013Date of Patent: May 5, 2015Assignee: Chevron U.S.A. Inc.Inventors: Dennis John O'Rear, Russell Evan Cooper, Sujin Yean, Darrell Lynn Gallup, Lyman Arnold Young
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Patent number: 9005566Abstract: A process for advantageously efficiently treating a sulfureous combustible effluent stream by recovering the sulfur in elemental form comprises a step of combustion of the sulfureous combustible effluent stream with an oxidant gas in excess, and then a step of post-combustion of the effluents from the combustion step with an acidic gas. The stream of the post-combustion effluents, free of chemical compounds that are harmful to the efficacy of the Claus catalysts, is treated in a Claus unit, which performs the recovery of the sulfur in elemental form.Type: GrantFiled: August 22, 2012Date of Patent: April 14, 2015Assignee: Total SAInventors: Jean Nougayrede, Soufiene Maktouf
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Patent number: 8980802Abstract: A chemically-modified mixed fuel includes methane gas from at least two methane-production sources and can be utilized in any process that incorporates a Kellogg Primary Reformer. A method for producing the chemically-modified mixed fuel described herein includes providing a first methane-containing gas from a first methane-production source, providing a second methane-containing gas from a second methane-production source and blending the first methane-containing gas with the second methane-containing gas at a suitable pressure to form a chemically-modified mixed fuel. In some cases, at least one additional methane-containing gas can be provided from at least one additional methane-production source and blended with the chemically-modified fuel.Type: GrantFiled: August 21, 2013Date of Patent: March 17, 2015Assignee: Honeywell International Inc.Inventors: Keith A. Togna, Craig T. Euen, Steven W. Weeks, Mohammed I. Loya, Matthew C. Warren, Richard H. Kendrick
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Patent number: 8980211Abstract: An energy conversion process that exports by-product CO2 at elevated pressure where a fuel gas feed stream is mixed with a reactant stream and additional CO2 is added to at least part of, the fuel gas feed stream, the reactant stream or both through desorption by contacting with a CO2-rich solvent stream in a first stage contactor to produce a mixed feed gas stream and a CO2-lean solvent stream; passing said mixed feed gas stream to a chemical conversion step, where further CO2 is produced; chilling at least part of the products of said chemical conversion step and thereby produce a CO2-lean gas stream; and passing at least part of said CO2-lean gas stream said to a second stage contactor where further CO2 is removed, by absorption, to produce a product gas stream and a solvent stream rich in CO2 from which said CO2-rich solvent stream is subsequently derived.Type: GrantFiled: February 24, 2009Date of Patent: March 17, 2015Inventors: Bryan Christopher Timmins, Jacqueline Anne Fisher
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Publication number: 20150056116Abstract: Composite materials and methods of preparing C02 capture include: (1) a porous solid support comprising a plurality of porous channels; and (2) a nucleophilic source associated with the porous channels of the porous solid support. The nucleophilic source is capable of converting the captured C02 to poly(C02). Methods of capturing C02 from an environment include associating the environment with the aforementioned composite materials to lead to the capture of C02 from the environment. Such methods may also include a step of releasing the captured C02 from the composite material. The associating step comprises a conversion of the captured C02 to poly(C02) in the composite material. A releasing step may also include a depolymerization of the formed poly(C02).Type: ApplicationFiled: January 11, 2013Publication date: February 26, 2015Applicant: William Marsh Rice UniversityInventors: James M. Tour, Chih-Chau Hwang
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Publication number: 20150044117Abstract: Cavitand compositions that comprise void spaces are disclosed. The void spaces may be empty, which means that voids are free of guest molecules or atoms, or the void spaces may comprise guest molecules or atoms that are normally in their gas phase at standard temperature and pressure. These cavitands may be useful for industrial applications, such as the separation or storage of gasses. Novel cavitand compounds are also disclosed.Type: ApplicationFiled: March 22, 2013Publication date: February 12, 2015Applicant: GEORGETOWN UNIVERSITYInventors: Kevin Travis Holman, Christopher Kane
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Patent number: 8945422Abstract: A catalytic reactor including: a reaction container filled with a catalyst having ruthenium; and an introduction part for introducing a material fluid to the reaction container. The reaction container is supplied with a mixed gas as material fluid to produce synthetic gas containing hydrogen and carbon monoxide in the presence of the catalyst. The introduction part is connected to the reaction container in a horizontal direction or a direction inclined downward from above a horizontal plane, and a height of the catalyst filled in the reaction container is adjusted above a height at which the material fluid is fed from the introduction part to the reaction container. Also, a method of using the catalytic reactor including monitoring a molar ratio of carbon and oxygen contained in the material fluid and stopping the supply of an oxygen-containing gas to the reaction container before the molar ratio becomes excessively low.Type: GrantFiled: June 11, 2009Date of Patent: February 3, 2015Assignee: Osaka Gas Co., Ltd.Inventors: Kota Yokoyama, Naoki Inoue, Koichiro Ikeda, Fuyuki Noguchi
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Publication number: 20150027055Abstract: A process for increasing the selectivity of an alkanolamine absorption process for selectively removing hydrogen sulfide (H2S) from a gas mixture which also contains carbon dioxide (CO2) and possibly other acidic gases such as COS, HCN, CS2 and sulfur derivatives of C1 to C4 hydrocarbons, comprises contacting the gas mixture with a liquid absorbent which is a severely sterically hindered capped alkanolamine or more basic sterically hindered secondary and tertiary amine. The improvement in selectivity is achieved at the high(er) pressures, typically least about 10 bara at conditions nearing the H2S/CO2 equilibrium at which CO2 begins to displace absorbed hydrosulfide species from the absorbent solution.Type: ApplicationFiled: July 24, 2014Publication date: January 29, 2015Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Pavel Kortunov, Michael Siskin, Robert B. Fedich
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Patent number: 8921626Abstract: The operation of a plant for producing a gas hydrate is stabilized by making the gas phase within a downstream step have the same equilibrium composition as that of the gas phase within a generation step. The gas phase within a mixed-gas hydrate generation step is circulated to the gas phase within a downstream step located downstream of the mixed-gas hydrate generation step, and the gas phase within each step is thereby made to have the same equilibrium composition as that of the gas phase within the generation step.Type: GrantFiled: November 9, 2010Date of Patent: December 30, 2014Assignee: Mitsui Engineering & Shipbuilding Co., Ltd.Inventors: Masahiro Takahashi, Nobuyasu Kanda, Kenichi Sano, Toru Iwasaki
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Patent number: 8915980Abstract: A process for the discharge of slag and ash from a gasification reactor is disclosed. These solids are directed from the gasification reactor into a water bath housed with the gasification reactor in a pressure vessel. There are at least two lock hoppers underneath the water bath which are fed with a stream of water/solids via a pipe and a flow divider element, it being possible to supply the lock hoppers individually and in a controlled manner with a stream of water/solids via shut-off devices. The filling is performed in a manner that encourages the sett-ling process by withdrawing a stream of liquid from the lock hopper being filled, the filling time being controlled so as to prevent the solids settling above the valves and lock hoppers. Also disclosed is an apparatus with at least two lock hoppers underneath the water bath of a gasification reactor, there being, in an advantageous embodiment, a flow divider element and shut-off devices between the water bath and the lock hoppers.Type: GrantFiled: July 11, 2009Date of Patent: December 23, 2014Assignee: UHDE GmbHInventor: Christoph Hanrott
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Publication number: 20140366446Abstract: Systems and methods for gas separation are disclosed. In one exemplary embodiment, a method for gas separation includes the steps of contacting a feed gas stream that includes a product gas and an impurity gas with a liquid-phase absorption solvent and absorbing the impurity gas and a portion of the product gas of the feed gas stream into the liquid-phase absorption solvent. The exemplary method further includes the steps of subjecting the liquid-phase absorption solvent to a first reduced pressure environment to remove the portion of the product gas and a portion of the impurity gas from the liquid-phase absorption solvent and separating the portion of the product gas from the portion of the impurity gas.Type: ApplicationFiled: June 14, 2013Publication date: December 18, 2014Inventors: Bhargav Sharma, Christopher B. McIlroy, Ernest James Boehm, David Farr, Nagaraju Palla
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Patent number: 8900544Abstract: A method for removing sulphur from a fluid by the steps of providing a first fluid comprising a sulphur-containing compound; adsorbing the sulphur of sulphur-containing compound onto an adsorbent; regenerating the adsorbent by oxidation of the adsorbed sulphur to sulphur dioxide thereby yielding an off-gas stream comprising sulphur dioxide; providing a second fluid comprising hydrogen sulphide, using the second fluid and the off-gas stream as reactants in a Claus process for producing elemental sulphur, wherein a part of hydrogen sulphide provided by the second fluid is oxidized to sulphur dioxide and water at reaction temperature, the residual hydrogen sulphide, the resulting sulphur oxide and the sulphur oxide provided by the off-gas stream are converted to elemental sulphur, the oxygen required for the oxidation of the hydrogen sulphide provided by the second fluid is provided by an air stream, and the off-gas stream dilutes the second fluid in the Claus process.Type: GrantFiled: February 28, 2014Date of Patent: December 2, 2014Assignee: Linde AktiengesellschaftInventor: Bernhard Schreiner
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Patent number: 8900334Abstract: The goal of the invention consists in making available a method for supplying fuel to a pressurized gasification system, which ensures, in economically efficient manner, that the emission of pollutants from the coal transfer and the transport is minimized or completely avoided. This is achieved in that a gas that contains at least 10 ppm vol. CO is used for transfer and/or conveying, whereby a gas that contains oxygen is mixed into this gas, and that this gas mixture is heated to a temperature that oxidizes at least 10% of the pollutants contained in the gas.Type: GrantFiled: December 23, 2009Date of Patent: December 2, 2014Assignee: ThyssenKrupp UHDE GmbHInventors: Johannes Kowoll, Stefan Hamel, Michael Rieger
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Patent number: 8894955Abstract: The present invention provides a process for removing mercaptans from a gas stream. In the process, a first mercaptan-comprising gas stream comprising at least a mercaptan of the general formula: R1—SH, wherein R1 is an alkyl group comprising 1 to 4 carbon atoms, and an acid component is contacted with an absorption medium to obtain a mercaptan-depleted gas stream. The absorption medium includes a substituted disulphide and a base. The substituted disulphide is of the general formula R2—SS—R3, wherein R2 and R3 are carbon comprising substituents of which the corresponding R2—SH and R3—SH thiols have a vapor pressure below the vapor pressure of any R1—SH thiol, and at least one of R2 and R3 is an electron withdrawing group.Type: GrantFiled: December 6, 2011Date of Patent: November 25, 2014Assignee: Shell Oil CpmpanyInventors: Jozef Jacobus Titus Smits, Sipke Hidde Wadman
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Patent number: 8894954Abstract: The present invention provides a process for removing mercaptans from a gas stream gas stream, comprising the steps: a) providing a first mercaptan-comprising gas stream comprising at least a mercaptan of the general formula: R1—SH, wherein R1 is an alkyl group comprising 1 to 4 carbon atoms; and b) contacting the mercaptan-comprising gas stream with an absorption medium comprising a substituted disulphide and a nitrogen-containing base to obtain a second mercaptan-depleted gas stream, wherein: the substituted disulphide is of the general formula R2—SS—R3 wherein: R2 and R3 are carbon comprising substituents of which the corresponding R2—SH and R3—SH thiols have a vapor pressure below the vapor pressure of any R1—SH thiol.Type: GrantFiled: November 30, 2011Date of Patent: November 25, 2014Assignee: Shell Oil CompanyInventors: Jozef Jacobus Titus Smits, Sipke Hidde Wadman
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Publication number: 20140290611Abstract: A natural gas storage system includes a container, a natural gas adsorbent positioned in the container, and a heating mechanism operatively positioned to selectively thermally activate the adsorbent. A method for improving efficiency of the natural gas storage system is also disclosed. A predetermined percentage of a capacity of the container for natural gas remaining in the container is identified. In response, a heating mechanism operatively positioned to selectively thermally activate the adsorbent is initiated. The adsorbent is heated and buffer adsorbed gas is released from the adsorbent.Type: ApplicationFiled: March 24, 2014Publication date: October 2, 2014Applicant: GM Global Technology Operations LLCInventors: Mahmoud H. Abd Elhamid, Anne M. Dailly, Mei Cai, Arianna T. Morales
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Patent number: 8840691Abstract: Trace levels of mercury in a natural gas are removed in a gas processing plant in an amine unit and/or a dehydrator. The mercury removal occurs concurrently with the removal of acid gases in an amine unit, e.g., an absorber or scrubber, with an amine solution containing a complexing agent. The mercury removal can also be carried out concurrently with the removal of water in a glycol dehydrator with the addition of a complexing agent to the glycol solution. Volatile mercury in the natural gas is removed by the complexing agent, forming non-volatile mercury species in the rich amine/glycol solution.Type: GrantFiled: September 6, 2013Date of Patent: September 23, 2014Assignee: Chevron U.S.A. Inc.Inventors: Russell Evan Cooper, Dennis John O'Rear, Feng-Ran Sheu, Jordan Taylor Belue
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INTEGRATED STEAM GASIFICATION AND ENTRAINED FLOW GASIFICATION SYSTEMS AND METHODS FOR LOW RANK FUELS
Publication number: 20140250858Abstract: In one aspect, a gasification system for use with low rank fuel is provided. The system includes a first gasifier positioned to receive a feed of low rank fuel, the first gasifier being configured to gasify the low rank fuel to produce hydrocarbons and fixed carbon. The system also includes a second gasifier configured to produce a syngas stream using the received fixed carbon, a cooler configured to receive and cool the syngas stream, and a first conduit coupled between the cooler and the first gasifier. The first conduit is configured to recycle at least a portion of the syngas stream to the first gasifier to facilitate heating low rank fuel within the first gasifier. The recycled syngas stream is mixed with the hydrocarbons to produce a hydrocarbon-rich syngas stream. The system also includes a second conduit coupled to the first gasifier for receiving the hydrocarbon-rich syngas stream.Type: ApplicationFiled: March 7, 2013Publication date: September 11, 2014Applicant: GENERAL ELECTRIC COMPANYInventor: Anindra Mazumdar -
Publication number: 20140212944Abstract: A series of MOF-based hierarchical porous material, namely IPD-mesoMOF-1˜9, based on nanoscale MOFs of MIL-100(Al, Fe, Cr, Sc and In), MIL-53(Al), HKUST-1, DUT-5, DUT-4, MIL-101(Cr), MIL-101NDC(Cr), MIL-101BPDC(Cr) and MIL-110 respectively, forming the permanent interparticle porosities by using close (or relatively close) packing, and preparation methods thereof. Modulated or functionalized IPD-mesoMOFs can be applied for gas adsorption and molecule separation (such as CH4- and CO2-adsorption, gasoline/diesel desulfurization and purification), catalyst loadings and molecular recognition/immobilization of biological macromolecules and enzymes.Type: ApplicationFiled: April 6, 2014Publication date: July 31, 2014Applicant: BEIJING STAR NEW MATERIAL CO., LTD.Inventors: Yunqi Tian, Yan Chen, Xun Liu
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Patent number: 8790427Abstract: Trace levels of mercury in a natural gas are removed in a gas processing plant in an amine unit and/or a dehydrator. The mercury removal occurs concurrently with the removal of acid gases in an amine unit, e.g., an absorber or scrubber, with an amine solution containing a complexing agent. The mercury removal can also be carried out concurrently with the removal of water in a glycol dehydrator with the addition of a complexing agent to the glycol solution. Volatile mercury in the natural gas is removed by the complexing agent, forming non-volatile mercury species in the rich amine/glycol solution.Type: GrantFiled: September 6, 2013Date of Patent: July 29, 2014Assignee: Chevron U.S.A. Inc.Inventors: Dennis John O'Rear, Russell Evan Cooper, Feng-Ran Sheu, Jordan Taylor Belue
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Patent number: 8741246Abstract: Systems containing imidazoles or blends of imidazoles and amines are described herein. Methods of their preparation and use are also described herein. The methods of using the systems include the reduction of volatile compounds from gas streams and liquid streams.Type: GrantFiled: June 10, 2013Date of Patent: June 3, 2014Assignee: Board of Trustees of the University of AlabamaInventor: Jason E. Bara
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Patent number: 8734744Abstract: Aspects of the disclosure relate to the separation of gases and to a process for the removal of carbon dioxide gas using liquid absorbents. A process is disclosed for removing carbon dioxide from a gaseous stream comprising contacting the gaseous stream with a carbon dioxide absorbent comprising a mixture of an ionic liquid and water in a molar ratio of from 10:1 to 1:10, wherein the ionic liquid has the formula: [Cat+][X?].Type: GrantFiled: September 14, 2012Date of Patent: May 27, 2014Assignee: Petroliam Nasional BerhadInventors: David F. Wassell, Kenneth R. Seddon, Martin P. Atkins
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Patent number: 8703084Abstract: A method and apparatus for eliminating COS and/or CS2 from a hydrocarbon-containing feed stream, and further eliminating H2S from such feed stream or converting all sulfur species in such feed stream to H2S and SO2 to allow for easy subsequent conversion of such H2S and SO2 to elemental sulfur in a Claus reaction. The method comprises: (i) injecting water so that the feed stream contains greater than 10 vol % (water equivalent); (ii) passing the feed stream through catalyst means which hydrogenates COS and/or CS2 to H2S; (iii) injecting O2 so that the stoichiometric ratio of O2 to H2S is at least 0.5:1.0; (iv) passing the stream though a reaction zone having oxidation catalyst means which oxidizes H2S to elemental sulfur or SO2 (depending on the amount of oxygen and water added); where the temperature of the reaction zone is above the elemental sulfur dew point.Type: GrantFiled: February 17, 2012Date of Patent: April 22, 2014Assignee: Archon Technologies Ltd.Inventors: Conrad Ayasse, Ahmed M. Shahin, Alan Ayasse
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Patent number: 8673956Abstract: Imido-acid salts and compositions containing imido-acid salts are described herein. Methods of their preparation and use are also described herein. The methods of using the imido-acid salts include the reduction of volatile compounds from gas and liquid streams and the delivery of pharmaceutical agents to subjects.Type: GrantFiled: November 29, 2012Date of Patent: March 18, 2014Assignee: Board of Trustees of The University of AlabamaInventor: Jason E. Bara
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Patent number: 8663589Abstract: The invention relates to a method for recovering sulphur from a sour gas containing hydrogen sulphide and carbon dioxide, comprising: oxidation of the sour gas, wherein a part of the hydrogen sulphide is oxidized to sulphur dioxide and water, reaction of the resulting sulphur dioxide with the residual hydrogen sulphide to elementary sulphur, and removal of elementary sulphur. According to the invention carbon dioxide and/or carbon dioxide generated by oxidation of the sour gas is compressed, and at least a part of the carbon dioxide is injected into an oil well. Furthermore, the invention relates to a plant suitable for performing the above method.Type: GrantFiled: September 20, 2012Date of Patent: March 4, 2014Assignee: Linde AktiengesellschaftInventor: Stephen Rhys Graville
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Patent number: 8658116Abstract: A method of producing sulfur dioxide is provided. A feed gas stream comprising at least 5% by volume hydrogen sulfide is provided. The feed gas stream is separated into a hydrogen sulfide stream and a hydrocarbon gas stream. An oxidant stream is provided and is combusted with the hydrogen sulfide stream to produce thermal power and a combustion stream containing sulfur dioxide and steam. Sulfur dioxide is separated from the combustion stream.Type: GrantFiled: November 15, 2012Date of Patent: February 25, 2014Assignee: Shell Oil CompanyInventors: Stanley Nemec Milam, Ann Marie Lauritzen, Michael Anthony Reynolds, Eswarachandra Kumar Paruchuri, Scott Lee Wellington
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Patent number: 8641890Abstract: The invention relates to a method for removing mercury from mercury containing materials, such as feedstreams, natural gas streams, natural gas condensates, and so forth. The method involves passing a fluid (e.g., gas or liquid) stream containing mercury along a polymeric membrane contact module, while a cleaning or scrubbing solution passes along the other side of the membrane. The scrubbing solution facilitates removal of mercury from the first solution via, e.g., mercury reactive components contained in it.Type: GrantFiled: March 15, 2013Date of Patent: February 4, 2014Assignee: Saudi Arabian Oil CompanyInventors: Feras Hamad, Ahmed A. Bahamdan, Abdulaziz Naser Al-Mulhim, Ayman Khaled Rashwan, Bandar A. Fadhel
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Publication number: 20140020286Abstract: The present document describes a catalyst to initiate microwave pyrolysis of waste, a process for the microwave pyrolysis of waste using the catalyst, as well as a microwave pyrolysis system.Type: ApplicationFiled: January 19, 2012Publication date: January 23, 2014Applicant: Services Kengtek Inc.Inventors: Jocelyn Doucet, Jamal Chaouki, Amr Sobhy
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Patent number: 8632615Abstract: The invention relates to a method and a system for producing synthetic gas from biomass by high temperature gasification, including: feeding raw material, carbonizing, pulverizing the charcoal, and transporting charcoal powder to the gasification furnace for gasification. Prior to pulverizing, the charcoal is reduced to a normal pressure by a decompression feeding system of charcoal, pulverized into powders, and transported to a supercharging feeding system of charcoal powder by normal pressure transport gas. The pressurized charcoal powder is transported to gasifier. The high-temperature charcoal at an outlet of carbonization furnace is cooled to 60-200° C. by a cooler, and transported into the decompression feeding system to be depressurized. The charcoal powder with pressurized is ejected to gasifier by an ejector, pyrolysis gas produced from carbonization furnace is used as carrier gas, and the ratio of solid to gas in the transportation pipe for charcoal powder is controlled at between 0.03 and 0.Type: GrantFiled: June 1, 2011Date of Patent: January 21, 2014Assignee: Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.Inventors: Haiqing Zhang, Shirong Zhang, Qin Sun, Peng Qiu, Shenghua Zheng
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Publication number: 20130326951Abstract: A chemically-modified mixed fuel includes methane gas from at least two methane-production sources and can be utilized in any process that incorporates a Kellogg Primary Reformer. A method for producing the chemically-modified mixed fuel described herein includes providing a first methane-containing gas from a first methane-production source, providing a second methane-containing gas from a second methane-production source and blending the first methane-containing gas with the second methane-containing gas at a suitable pressure to form a chemically-modified mixed fuel. In some cases, at least one additional methane-containing gas can be provided from at least one additional methane-production source and blended with the chemically-modified fuel.Type: ApplicationFiled: August 21, 2013Publication date: December 12, 2013Applicant: Honeywell International Inc.Inventors: Keith A. Togna, Craig T. Euen, Steven W. Weeks, Mohammed I. Loya, Matthew C. Warren, Richard H. Kendrick
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Patent number: 8591846Abstract: A method and apparatus for processing a sour gas rich in carbon dioxide in a Claus process, so sulfur compounds are removed by a selective solvent in a gas scrubbing process. Sulfur components and carbon dioxide, are separated into at least two sour gas fractions, wherein at least one sour gas fraction having a higher content of sulfur components is obtained, wherein the fraction having the highest hydrogen sulfide content is introduced in the thermal reaction stage of the Claus furnace with a gas containing oxygen by means of a burner. The sulfur is converted to sulfur dioxide in the thermal reaction stage of the Claus furnace and exhaust gases are discharged into the closed Claus reaction chamber behind the burner. The remaining sour gas fractions stripped of sulfur components are fed to the Claus reaction chamber and are mixed with the combustion gases leaving the burner.Type: GrantFiled: March 22, 2011Date of Patent: November 26, 2013Assignee: Thyssenkrupp UHDE GmbHInventor: Johannes Menzel
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Publication number: 20130306520Abstract: A method for processing raw natural gas for storage and transport in a storage vessel at a storage pressure greater than the raw natural gas dense phase pressure, which includes the steps of receiving the raw natural gas in a flow path at an inlet pressure greater than the storage pressure; if necessary, dehydrating the raw natural gas; and continuously releasing the dehydrated raw natural gas from the flow path at a release pressure and a release temperature into a storage vessel until the pressure of the dehydrated raw natural gas in the storage vessel reaches the storage pressure, avoiding the solidification of any impurities in the raw natural gas.Type: ApplicationFiled: May 17, 2013Publication date: November 21, 2013Inventor: Colin NIKIFORUK
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Patent number: 8580019Abstract: An apparatus and method is presented for removing acid gases and other trace contaminants to very low levels in combustible gases generated from thermal gasification of biomass or refuse-derived fuels. The invention includes optimization of geometric variables, temperature and pressure set points via use of a pressurized bubbling fluidized bed reactor to convert granular raw (non-activated) sorbents and auto-generated biochar sorbents) into activated, highly dispersed, and ideally sized particles for removing acid gases and toxic metals. The system can incorporate a generated gas cooler, a gas-sorbent contact chamber or zone, and a novel filter (with or without additional gas cooling and residence time stages).Type: GrantFiled: May 13, 2011Date of Patent: November 12, 2013Assignee: Frontline BioEnergy, LLCInventors: John P. Reardon, Thomas J. Paskach, Paul Evans
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Patent number: 8568676Abstract: A process for workup of an industrial carbon dioxide-rich gas to be freed of sulfur components, in which an industrial gas to be freed of sulfur components is purified by a gas scrubbing, and the laden solvent is freed of carbon dioxide and hydrogen sulfide by a regeneration to obtain at least one acid gas fraction having a relatively high content of sulfur components, and the fraction with the highest hydrogen sulfide (H2S) content is supplied to a Claus plant with downstream Claus process gas hydrogenation, and at least one carbon dioxide-laden, low-hydrogen sulfide acid gas fraction from the regeneration device, which has a reduced sulfur content compared to the fraction with the highest hydrogen sulfide (H2S) content, is combined with the hydrogenated Claus process gas to give a combined process gas stream, which is supplied to further processing or to recycling into the process.Type: GrantFiled: March 22, 2011Date of Patent: October 29, 2013Assignee: Thyssenkrupp Uhde GmbHInventor: Johannes Menzel
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Patent number: 8562928Abstract: A process for making molecular hydrogen, elemental sulfur and sulfur dioxide from hydrogen sulfide. The process involves contacting a gas stream of hydrogen sulfide within a contacting zone with a contacting composition comprising metal sulfide in a lower sulfided state and yielding from the contacting zone a product gas stream comprising hydrogen and a recovered contacting composition comprising metal sulfide in a higher sulfided state. The higher metal sulfide is regenerated with oxygen to yield elemental sulfur and sulfur dioxide.Type: GrantFiled: September 21, 2011Date of Patent: October 22, 2013Assignee: Shell Oil CompanyInventor: Puneet Gupta
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Patent number: 8562927Abstract: The degradation of an absorbent solution comprising organic compounds provided with an amine function in aqueous solution is reduced considerably in the presence of a small amount of degradation inhibiting additives whose structure comprises a 5-atom heterocycle composed of a nitrogen atom, a sulfur atom or an oxygen atom, and 3 carbon atoms, at least one of which is joined to a sulfur atom not belonging to the ring. The absorbent solution is employed for deacidifying a gaseous effluent.Type: GrantFiled: November 19, 2010Date of Patent: October 22, 2013Assignee: IFPInventors: P-Louis Carrette, Bruno Delfort