And Aluminum Compound (e.g., Clay, Aluminum Oxide, Etc.) Patents (Class 501/105)
  • Patent number: 6645585
    Abstract: There is provided a treatment container which enables to prolong a period of time taken for reaction products, such as a halide generated through reaction with corrosive halide gas, to exfoliate and fall down as particles, and decreases the frequency of periodic maintenance operation, thereby implementing increase of operating time. The treatment container constituting a chamber or a bell jar has a portion of the inner surface to be exposed to corrosive halide gas plasma and is formed with a sintered body mainly composed of a compound of yttrium and aluminum with oxygen, and the portion has a roughened surface of a mean roughness Ra of 1.5 to 10 &mgr;m.
    Type: Grant
    Filed: May 29, 2001
    Date of Patent: November 11, 2003
    Assignee: Kyocera Corporation
    Inventor: Shunichi Ozono
  • Patent number: 6632763
    Abstract: A ceramic composite containing alkali-metal-beta- or beta″-alumina and an oxygen-ion conductor is fabricated by converting alpha-alumina to alkali-metal-beta- or beta″-alumina. A ceramic composite with continuous phases of alpha-alumina and the oxygen-ion conducting ceramic, such as zirconia, is exposed to a vapor containing an alkali-metal oxide, such as an oxide of sodium or potassium. Alkali metal ions diffuse through alkali-metal-beta- or beta″-alumina converted from &agr;-alumina and oxygen ions diffuse through the oxygen-ion conducting ceramic to a reaction front where alpha-alumina is converted to alkali-metal-beta- or beta″-alumina. A stabilizer for alkali-metal-beta″-alumina is preferably introduced into the &agr;-alumina/oxygen-ion conductor composite or introduced into the vapor used to convert the alpha-alumina to an alkali-metal-beta″-alumina.
    Type: Grant
    Filed: December 2, 2002
    Date of Patent: October 14, 2003
    Assignee: Materials and Systems Research, Inc.
    Inventors: Anil Vasudeo Virkar, Jan-Fong Jue, Kuan-Zong Fung
  • Patent number: 6624106
    Abstract: The invention provides a sintered, alumina ceramic product comprising about 90-97.5 w/w % Al2O3, about 0.5-1.0 w/w % MgO, about <0.05-1.0 w/w % SiO2, about 4.5-7.5 w/w % ZrO2 and about 0.07-0.13 w/w % HfO2.
    Type: Grant
    Filed: April 23, 2001
    Date of Patent: September 23, 2003
    Inventor: Michael Cohen
  • Publication number: 20030172594
    Abstract: Abrasive particles and methods of making abrasive particles are disclosed. The abrasive particles may be incorporated into a variety of abrasive articles, including bonded abrasives, coated abrasives, nonwoven abrasives, and abrasive brushes.
    Type: Application
    Filed: February 21, 2002
    Publication date: September 18, 2003
    Applicant: 3M Innovative Properties Company
    Inventors: Darren T. Castro, Vincent W. Nehring, Anatoly Z. Rosenflanz, Thomas E. Wood
  • Patent number: 6602813
    Abstract: An electrostatic removing member includes a semiconductive zirconia sintered body having a volume specific resistance value from 105 to 109&OHgr;·cm. Preferably, the semiconductive zirconia sintered body includes 60 to 90 weight % of ZrO2, a stabilizing agent, and 10 to 40 weight % of one or more of oxides of Fe, Co, Ni and Cr. In one embodiment, the semiconductive zirconia sintering body at least partially forms a gripper.
    Type: Grant
    Filed: May 10, 2001
    Date of Patent: August 5, 2003
    Assignee: Kyocera Corporation
    Inventors: Mikaki Shinji, Hamashima Hiroshi, Iwasaki Koichi, Iwamoto Kuniharu, Nakahara Masahiro, Okumura Masahiro, Hino Shouji, Nabeshima Yutaka
  • Patent number: 6582488
    Abstract: Fused, crystalline eutectic material comprising Al2O3-rare earth oxide-ZrO2 eutectic. Examples of useful articles comprising the fused eutectic material include fibers and abrasive particles.
    Type: Grant
    Filed: July 19, 2000
    Date of Patent: June 24, 2003
    Assignee: 3M Innovative Properties Company
    Inventor: Anatoly Z. Rosenflanz
  • Publication number: 20030109372
    Abstract: Rare-earth alloy is cast into a sheet (6) or the like by using a tundish (3, 13). The refractory material of the tundish used for casting does not necessitate preheating for improving the flowability of the melt (2). The refractory material used essentially consists of 70 wt % or more of Al2O3 and 30 wt % or less of SiO2, or 70 wt % or more of ZrO2 and 30 wt % or less of one or more of Y2O3, Ce2O3, CaO, MgO, Al2O3, TiO2 and SiO2. The refractory material has 1 g/cm3 or less of bulk density, has 0.5 kca/(mh° C.) or less of thermal conductivity in the temperature range of from 1200 to 1400° C., and has 0.5 wt % or less of ratio of ignition weight-loss under the heating condition of 1400° C. for 1 hour.
    Type: Application
    Filed: October 23, 2002
    Publication date: June 12, 2003
    Applicant: SHOWA DENKO K.K.
    Inventors: Hiroshi Hasegawa, Nobuhiko Kawamura, Shiro Sasaki, Yoichi Hirose
  • Patent number: 6576580
    Abstract: Oxidized alumina-zirconia-silica (AZS) refractories containing 40 wt % to 55 wt % Al2O3, 32 wt % to 45 wt % ZrO2, 10 wt % to less than 16 wt % SiO2 and 1 wt % to 3 wt % of an alkali metal oxide selected from Na2O, K2O and mixtures thereof have a microstructure essentially comprising alpha-alumina crystals, free zirconia crystals, eutectic crystals and an intercrystalline vitreous phase. At least in an active area, more than 20% by number of the free zirconia crystals have a dendritic shape and are interleaved with each other and with eutectic crystals and at least 40% by number of the dendritic free zirconia crystals have a dimension greater than 300 &mgr;m.
    Type: Grant
    Filed: January 30, 2001
    Date of Patent: June 10, 2003
    Assignee: Societe Europeenne des Produits Refractaires
    Inventors: Michel Marc Gaubil, Yves Marcel Léon Boussant-Roux, Emmanuel Jean-Marie Sertain, Alain Paul Bernard Zanoli
  • Patent number: 6562747
    Abstract: The electrolyte comprises up to about 80 wt % zirconia, up to about 30 wt % stabilizer, and up to about 40 wt % dopant-zirconia. Alternatively, the electrolyte can comprise zirconia having a phase chemistry, wherein the phase chemistry, at about 25° C., is about 15 wt % to about 35 wt % monoclinic, less than about 10 wt % tetragonal, balance cubic, based upon the weight of the zirconia in the electrolyte.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: May 13, 2003
    Assignee: Delphi Technologies, Inc.
    Inventors: Walter Thomas Symons, Kaius Kiiren Polikarpus, Kerry J. Gross, Da Yu Wang, Paul Casey Kikuchi
  • Patent number: 6537940
    Abstract: A ceramic composite containing alkali-metal-&bgr;- or &bgr;″-alumina and an oxygen-ion conductor is fabricated by converting &agr;-alumina to alkali-metal-&bgr;- or &bgr;″-alumina. A ceramic composite with continuous phases of &agr;-alumina and the oxygen-ion conducting ceramic, such as zirconia, is exposed to a vapor containing an alkali-metal oxide, such as an oxide of sodium or potassium. Alkali metal ions diffuse through alkali-metal-&bgr;- or &bgr;″-alumina converted from &agr;-alumina and oxygen ions diffuse through the oxygen-ion conducting ceramic to a reaction front where &agr;-alumina is converted to alkali-metal-&bgr;- or &bgr;″-alumina. A stabilizer for alkali-metal-&bgr;″-alumina is preferably introduced into the &agr;-alumina/oxygen-ion conductor composite or introduced into the vapor used to convert the &agr;-alumina to an alkali-metal-&bgr;″-alumina.
    Type: Grant
    Filed: August 10, 2000
    Date of Patent: March 25, 2003
    Assignee: Materials and Systems Research, Inc.
    Inventors: Anil Vasudeo Virkar, Jan-Fong Jue, Kuan-Zong Fung
  • Patent number: 6524704
    Abstract: A powder of dicalcium silicate is made by spray drying calcia and silica with incorporation of sodium and phosphorus or stabilized zirconia. The spray dried powder is sintered to form a thermal spray powder. Sprayed coatings have a web of interconnected, randomly oriented microcracks substantially perpendicular to the coating surface. The coatings are stable in thermal cycling and a hot corrosive environment.
    Type: Grant
    Filed: October 4, 2000
    Date of Patent: February 25, 2003
    Assignee: Sulzer Metco (US) Inc.
    Inventors: Xiaohan Wei, Mitchell R. Dorfman, Luis F. Correa, Franz Jansen, John Peters
  • Patent number: 6514892
    Abstract: Transparent solid, fused microspheres are provided. In one embodiment, the microspheres contain alumina, zirconia, and silica in a total content of at least about 70% by weight, based on the total weight of the solid, fused microspheres, wherein the total content of alumina and zirconia is greater than the content of silica, and further wherein the microspheres have an index of refraction of at least about 1.6 and are useful as lens elements.
    Type: Grant
    Filed: May 2, 2000
    Date of Patent: February 4, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Toshihiro Kasai, Kenton D. Budd, Stephen L. Lieder, James A. Laird, Chikafumi Yokoyama, Toshinori Naruse, Kenji Matsumoto, Hirohiko Ono
  • Patent number: 6509287
    Abstract: Fused cast AZS products that contain: Al2O3: 45-65 wt. %, ZrO2: 10.0-29.0 wt. %, SiO2: 20.0-24.0 wt. %, SiO2/(Na2O+K2O) weight ratio: 4.5-8, and other species: 0.5-4.0 wt. % These products may be produced from manufacturing waste or recycled spent materials.
    Type: Grant
    Filed: June 19, 2001
    Date of Patent: January 21, 2003
    Assignee: Societe Europeenne des Produits Refractaires
    Inventors: Yves Marcel Leon Boussant-Roux, Michel Marc Gaubil, Thierry Bruno Jacques Colozzi
  • Patent number: 6461991
    Abstract: A re-usable alumina-magnesia graphite refractory suitably used for a refractory for continuous casting, such as a long nozzle used for pouring a molten metal from a ladle capable of re-use or intermittent use to a tundish, an immersion nozzle used for charging a molten metal from a tundish to a mold and a long stopper for controlling the flow rate of the molten steel; and produced by blending 3 to 60 wt % of magnesia having a particle size of 0.02 to 1.0 mm to a compound comprising mainly alumina and graphite, and kneading, molding, and baking the compound. The raw material compound comprising mainly alumina and graphite can contain spinel or zirconia.
    Type: Grant
    Filed: August 24, 2000
    Date of Patent: October 8, 2002
    Assignee: Krosaki Corporation
    Inventors: Koji Ogata, Shoji Iitsuka
  • Patent number: 6452957
    Abstract: The invention relates to a sintered shaped body comprising a matrix material that contains an aluminum oxide/chromium oxide mixed crystal and an additional mixed crystal selected from at least one mixed crystal according to one of the general formulas La0.9Al11.76−xCrxO19, Me1Al11−xCrxO17, Me2Al12−xCrxO19, Me2′Al12−xCrxO19 and/or Me3Al11−xCrxO18, wherein Me1 stands for an alkali metal, Me2 represents an alkaline earth metal, Me2′ stands for cadmium, lead or mercury and Me3 represents a rare earth metal and x has a value ranging from 0.0007 to 0.045.
    Type: Grant
    Filed: July 6, 2000
    Date of Patent: September 17, 2002
    Assignee: Ceramtec AG Innovative Ceramic Engineering
    Inventors: Wolfgang Burger, Gundula Kiefer, Eduardo Bellido, Hans Andersch
  • Patent number: 6399528
    Abstract: The present invention relates to a porous aluminum oxide structure comprising Al2O3 and Zr, the structure having an open porosity greater than about 30% and an average pore size from about 20 nm to about 1000 nm, wherein the Zr, expressed as ZrO2, has a concentration less than about 5 weight % of the weight of the Al2O3.
    Type: Grant
    Filed: March 5, 2001
    Date of Patent: June 4, 2002
    Assignee: Fraunhofer-Gesellschaft zur Forderung der Angewandten Forschung e.V.
    Inventors: Andreas Krell, Frank Buse, Hongwei Ma
  • Patent number: 6383964
    Abstract: The present invention is to provide ceramic members for being used as members constituting a processing chamber for etching or cleaning semiconductor substrates or wafers by halogen plasma. A ceramic member includes at least 10% by volume of a compound of yttrium-aluminum-garnet (YAG) phase and not more than 90% by volume of at least an oxide phase selected from aluminum oxide, yttrium oxide and aluminum nitride. Particularly, the ceramic member contains yttrium within a range of 35 to 80 mole % in terms of yttrium oxide Y2O3 and aluminum within a range of 20 to 65 mole % in terms of aluminum oxide Al2O3 to form a mixture of YAG phase with yttria phase, producing ceramic material having high corrosion resistance to halogenous gas and its plasma. Such ceramic material may be well applicable to members to be exposed by the halogen plasma, for example, a chamber wall, a wafer stage, a clamp ring, a shower head, which are used in systems for etching and cleaning semiconductor wafers.
    Type: Grant
    Filed: November 29, 1999
    Date of Patent: May 7, 2002
    Assignee: Kyocera Corporation
    Inventors: Masahiro Nakahara, Yumiko Itoh
  • Publication number: 20020052288
    Abstract: The present invention relates to a porous aluminum oxide structure comprising Al2O3 and Zr, the structure having an open porosity greater than about 30% and an average pore size from about 20 nm to about 1000 nm, wherein the Zr, expressed as ZrO2, has a concentration less than about 5 weight % of the weight of the Al2O3.
    Type: Application
    Filed: March 5, 2001
    Publication date: May 2, 2002
    Applicant: Fraunhofer-Gesellschaft zur Foderung der Angewandt
    Inventors: Andreas Krell, Frank Buse, Hongwei Ma
  • Patent number: 6380113
    Abstract: The present invention relates to a zirconia/alumina composite and a manufacturing method thereof which provide a zirconia ceramic powder having a composition in a triangle composition range formed of three composition points of 92 mol % ZrO2-4 mol % Y2O3-4 mol % Nb2O5 (or Ta2O5), 89 mol % ZrO2-7 mol % Y2O3-4 mol % Nb2O5 (or Ta2O5), 86 mol % ZrO2-7 mol % Y2O3-7 mol % Nb2O5 (or Ta2O5) in a ternary system of ZrO2—Y2O3—Nb2O5 or Ta2O3 for thereby manufacturing a zirconia/alumina composite having a high strength and high toughness in a state that a low temperature degradation does not occur.
    Type: Grant
    Filed: April 10, 2000
    Date of Patent: April 30, 2002
    Assignee: Korea Institute of Science & Technology
    Inventors: Dae Joon Kim, Deuk Yong Lee, Ju Woong Jang
  • Patent number: 6358874
    Abstract: An optical connector member of the present invention is formed of a zirconia based ceramics which contain ZrO2 as a main component, 2-4 mol % of Y2O3, 0.05-1.0 wt % of A12O3, and 0.01 wt % or less each of siO2 and TiO2, then allowing the connector member to assure the durability even using in the high temperature and humidity circumstances. Also, An optical connector member is formed of a ceramic material having 0.1 wt % or less of a rate of change in weight while the material is held at a temperature of 85° C. and relative humidity of 85% for 2000 hours. For the ceramics, zirconia based ceramics are used to be partially stabilized with Y2O3 and with another stabilizer other than Y2O3. Further, the invention includes a ferrule having a through hole for holding an optical fiber therein, wherein the ferrule is provided, on its periphery, with a marker which indicates a direction of decentering the fiber on the top surface of the ferrule.
    Type: Grant
    Filed: November 30, 1998
    Date of Patent: March 19, 2002
    Assignee: Kyocera Corporation
    Inventors: Yoshihiro Kobayashi, Nobuhiko Matsushita
  • Patent number: 6352951
    Abstract: The invention concerns a refractory material based on chromium corundum, a chromium corundum brick made of said material as well as the use thereof.
    Type: Grant
    Filed: March 12, 2000
    Date of Patent: March 5, 2002
    Assignee: Didier-Werke AG
    Inventors: Karl-Heinz Mossal, Selim Yesiltas, Albert Kleinevoss, Thomas Weichert
  • Publication number: 20020013212
    Abstract: Fused and cast AZS products, characterized in that they contain:
    Type: Application
    Filed: June 19, 2001
    Publication date: January 31, 2002
    Applicant: SOCIETE EUROPEENNE DES PRODUITS REFRACTAIRES
    Inventors: Yves Marcel Leon Boussant-Roux, Michel Marc Gaubil, Thierry Bruno Jacques Colozzi
  • Publication number: 20020010070
    Abstract: A biomedical component comprising zirconia toughened alumina (ZTA), the ZTA comprising 1-69 wt % ZrO2, the ZrO2 being partially stabilized with >2.
    Type: Application
    Filed: April 24, 2001
    Publication date: January 24, 2002
    Inventors: Bernard Cales, Laurence Blaise, Franceline Villermaux
  • Publication number: 20020010071
    Abstract: The invention provides a sintered, alumina ceramic product comprising about 90-97.5 w/w % Al2O3, about 0.5-1.0 w/w % MgO, about <0.05-1.0 w/w % SiO2, about 4.5-7.5 w/w % ZrO2 and about 0.07-0.13 w/w % HfO2.
    Type: Application
    Filed: April 23, 2001
    Publication date: January 24, 2002
    Inventor: Michael Cohen
  • Patent number: 6309749
    Abstract: The present invention is milling media composed of ceramic particles having an average size of 0.1 to 20 mm. The ceramic particles contain a tetragonal zirconia core and a continuous shell on the core comprising cubic zirconia, monoclinic zirconia, spinel or zircon. The present invention is also a method of manufacturing the milling media which includes providing ceramic particles having an average size of 0.1 to 20 mm. The ceramic particles are tetragonal zirconia. The ceramic particles are coated with a clay material and sintered to form a shell of cubic zirconia, monoclinic zirconia, spinel or zircon over the tetragonal zirconia core.
    Type: Grant
    Filed: May 6, 1999
    Date of Patent: October 30, 2001
    Assignee: Eastman Kodak Company
    Inventors: Dilip K. Chatterjee, Thomas N. Blanton, Debasis Majumdar
  • Patent number: 6306794
    Abstract: The composite oxide and the composite oxide carrier are manufactured by the precursor forming step and firing step. The composite oxide catalyst is obtained by preparing a composite of catalytic components simultaneously with the formation of the precursor of composite oxide in the step of forming the precursor of composite oxide. The composite oxide and the composite oxide carrier are composed of a composite oxide in which at least one of cerium and zirconium, and aluminium disperse with extremely high homogeneity. With this structure, the heat resistance of the carrier is improved and consequently, enlargement of particles of the composite oxide defining the carrier, and sintering of adjacent particles of the composite oxide can be restrained, whereby the catalyst using the composite oxide carrier in accordance with the present invention is excellent in heat resistance.
    Type: Grant
    Filed: June 27, 2000
    Date of Patent: October 23, 2001
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Tadashi Suzuki, Hideo Sobukawa
  • Publication number: 20010019992
    Abstract: Oxidized alumina-zirconia-silica (AZS) refractories containing 40 wt % to 55 wt % Al2O3, 32 wt % to 45 wt % ZrO2, 10 wt % to less than 16 wt % SiO2 and 1 wt % to 3 wt % of an alkali metal oxide selected from Na2O, K2O and mixtures thereof have a microstructure essentially comprising alpha-alumina crystals, free zirconia crystals, eutectic crystals and an intercrystalline vitreous phase. At least in an active area, more than 20% by number of the free zirconia crystals have a dendritic shape and are interleaved with each other and with eutectic crystals and at least 40% by number of the dendritic free zirconia crystals have a dimension greater than 300 &mgr;m.
    Type: Application
    Filed: January 30, 2001
    Publication date: September 6, 2001
    Applicant: SOCIETE EUROPEENNE DES PRODUITS REFRACTAIRES
    Inventors: Michel Marc Gaubil, Yves Marcel Leon Boussant-Roux, Emmanuel Jean-Marie Sertain, Alain Paul Bernard Zanoli
  • Patent number: 6281266
    Abstract: Disclosed is a taphole plugging composition for metal melting apparatus, the composition comprising (a) a refractory aggregate having a maximum particle size of 5 mm or less, (b) graphite and silicon nitride each having a maximum particle size of 0.2 mm or less, (c) a refractory clay, (d) a compatibilized binder mixture comprising a phenolic resin, a ketone compound and a pitch, and (e) an organic fine fiber.
    Type: Grant
    Filed: June 16, 2000
    Date of Patent: August 28, 2001
    Assignee: Nippon Crucible Co., Ltd.
    Inventors: Kenzo Takeda, Kunihiko Shiraishi, Fumiyuki Inoue, Norio Honda
  • Patent number: 6274524
    Abstract: The invention provides a semiconductive zirconia sintering body able to be manufactured simply and cheaply and escape static electricity at suitable speed without greatly reducing mechanical characteristics of zirconia. 10 to 40 weight % of one kind or more of oxides of Fe, Co, Ni and Cr as conductivity giving agents is included with respect to 60 to 90 weight % of ZrO2 including a stabilizing agent so that a semiconductive zirconia sintering body having a volume specific resistance value from 105 to 109 &OHgr;·cm is formed.
    Type: Grant
    Filed: December 24, 1998
    Date of Patent: August 14, 2001
    Assignee: Kyocera Corporation
    Inventors: Mikaki Shinji, Hamashima Hiroshi, Iwasaki Koichi, Iwamoto Kuniharu, Nakahara Masahiro, Okumura Masahiro, Hino Shouji, Nabeshima Yutaka
  • Patent number: 6261985
    Abstract: A high temperature cookware is made with material to render it heat more uniformly, at a lower temperature to avoid over-burning, more resistant to cracking due to sudden change in temperature, and less fragile. The material includes cordierite to possess small expansion coefficient, mullite to store more heat, talc to lower the firing temperature, and refractory clay for high heat conductivity. Other ingredients are added to enhance far-infrared radiation with certain kinds of metallic oxide. After the body is fired, the cookware is glazed to be impervious to water and coated with Teflon to make the cookware non-sticking.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: July 17, 2001
    Inventor: Peter Hsu
  • Patent number: 6261983
    Abstract: The present invention discloses novel magnesia-spinel refractory compositions and bricks formed thereof that exhibit longer lining life, greater hot strength and reduced tendency to spall under high thermal loading conditions. The invention is designed to slow or retard the reaction between spinel and lime through the addition of zirconia in the form of an alumina-zirconia grain to the refractory mix. Zirconia reacts more readily with the lime in the refractory composition and surrounding environment to form calcium zirconate.
    Type: Grant
    Filed: January 12, 2000
    Date of Patent: July 17, 2001
    Assignee: Baker Refractories
    Inventor: Steven P. Gruver
  • Patent number: 6197099
    Abstract: A composite mixture of spherical objects and lubricant useful for its cushioning properties is disclosed and claimed. The composite mixture may be composed of microspheres typically less than 2000 microns in diameter with inert atmospheres sealed within their interiors and any of a variety of lubricants facilitating sliding and rolling movement between microspheres. Typically the composite mixture includes lubricant in a quantity sufficient to substantially coat the exterior surface of essentially all of the spherical objects, but in a quantity less than would cause dispersion of the spherical objects in the lubricant sufficient to physically separate the spherical objects from each other and substantially reduce the sliding and rolling contact of the spherical objects with each other. The preferred lubricant is a visco-elastic fluid that has a principle molecule and a cross-linking agent.
    Type: Grant
    Filed: April 9, 1997
    Date of Patent: March 6, 2001
    Inventor: Tony M. Pearce
  • Patent number: 6194084
    Abstract: A powder of dicalcium silicate is made by spray drying calcia and silica with incorporation of sodium and phosphorus or stabilized zirconia. The spray dried powder is sintered to form a thermal spray powder. Sprayed coatings have a web of interconnected, randomly oriented microcracks substantially perpendicular to the coating surface. The coatings are stable in thermal cycling and a hot corrosive environment.
    Type: Grant
    Filed: June 23, 1999
    Date of Patent: February 27, 2001
    Assignee: Sulzer Metco Inc.
    Inventors: Xiaohan Wei, Mitchell R. Dorfman, Luis F. Correa, Franz Jansen, John Peters
  • Patent number: 6187700
    Abstract: Negative thermal expansion materials, methods of preparation and uses therefor are disclosed. The materials are useful for negative thermal expansion substrates, such as those used for optical fiber gratings.
    Type: Grant
    Filed: May 5, 1999
    Date of Patent: February 13, 2001
    Assignee: Corning Incorporated
    Inventor: Gregory A. Merkel
  • Patent number: 6158248
    Abstract: A fused-cast-alumina-zirconia-silica refractory consisting essentially of corundum crystals, baddeleyite crystals and a matrix glass phase and having a chemical composition comprising (a) from 30 to 70 wt % of Al.sub.2 O.sub.3, (b) from 20 to 59 wt % of ZrO.sub.2, (c) from 5 to 12 wt % of SiO.sub.2, (d) from 0.15 to 0.60 wt % of Na.sub.2 O, (e) from 0 to 0.50 wt % of K.sub.2 O, (f) from 0 to 0.40 wt % of Li.sub.2 O, (g) from 0.05 to 0.80 wt % of B.sub.2 O.sub.3, (h) from 0.05 to 0.80 wt % of P.sub.2 O.sub.5, and (i) from 0.05 to 0.50 wt % in total of at least one member selected from the group consisting of SnO.sub.2, ZnO, CuO and MnO.sub.2.
    Type: Grant
    Filed: February 24, 1999
    Date of Patent: December 12, 2000
    Assignee: Asahi Glass Company Ltd.
    Inventor: Yoshihisa Beppu
  • Patent number: 6156685
    Abstract: Zirconia ceramic fibers, for catalytic applications, partially stabilized with yttria by means of a particular sol-gel process, are functionalized with a coating, containing zirconia and, optionally, alumina and/or oxides of Cu, Ni, Co, V, Mo, W, Ce, La, Nd and/or noble metals selected from Rh, Pt, Pd, Ru, Au, mainly obtained with a "dip coating" technique.
    Type: Grant
    Filed: June 18, 1998
    Date of Patent: December 5, 2000
    Assignee: Enirisorse S.p.A.
    Inventors: Marcello Marella, Letizia Meregalli, Michele Tomaselli
  • Patent number: 6150288
    Abstract: The composite oxide and the composite oxide carrier are manufactured by the precursor forming step and firing step. The precursor forming step includes high speed mixing means. The composite oxide catalyst is obtained by preparing a composite of catalytic components simultaneously with the formation of the precursor of composite oxide in the step of forming the precursor of composite oxide. The composite oxide and the composite oxide carrier are composed of a composite oxide in which at least one of cerium and zirconium, and aluminium disperse with extremely high homogeneity. With this structure, the heat resistance of the carrier is improved and consequently, enlargement of particles of the composite oxide defining the carrier, and sintering of adjacent particles of the composite oxide can be restrained, whereby the catalyst using the composite oxide carrier in accordance with the present invention is excellent in heat resistance.
    Type: Grant
    Filed: October 7, 1997
    Date of Patent: November 21, 2000
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Tadashi Suzuki, Hideo Sobukawa
  • Patent number: 6121177
    Abstract: The invention relates to a novel sintered material, characterized in that it is produced from a batch containing 5 to 40% zircon and in that it has the following chemical composition in % by weight:______________________________________ ZrO.sub.2 + HfO.sub.2 82-96 SiO.sub.2 1.7-14 TiO.sub.2 0.2-3 Y.sub.2 O.sub.3 0.4-5 Al.sub.2 O.sub.3 0.2-2.
    Type: Grant
    Filed: April 20, 1999
    Date of Patent: September 19, 2000
    Assignee: Societe Europeenne des Produits Refractaires
    Inventors: Jacques Marius Louis Guigonis, Eric Thierry Georges Jorge, Charles Nicholas McGarry
  • Patent number: 6117807
    Abstract: A ceramic composite containing alkali-metal-.beta.- or .beta."-alumina and an oxygen-ion conductor is fabricated by converting .alpha.-alumina to alkali-metal-.beta.- or .beta."-alumina. A ceramic composite with continuous phases of .alpha.-alumina and the oxygen-ion conducting ceramic, such as zirconia, is exposed to a vapor containing an alkali-metal oxide, such as an oxide of sodium or potassium. Alkali metal ions diffuse through alkali-metal-.beta.- or .beta."-alumina converted from .alpha.-alumina and oxygen ions diffuse through the oxygen-ion conducting ceramic to a reaction front where .alpha.-alumina is converted to alkali-metal-.beta.- or .beta."-alumina. A stabilizer for alkali-metal-.beta."-alumina is preferably introduced into the .alpha.-alumina/oxygen-ion conductor composite or introduced into the vapor used to convert the .alpha.-alumina to an alkali-metal-.beta."-alumina.
    Type: Grant
    Filed: January 2, 1998
    Date of Patent: September 12, 2000
    Assignee: Materials and Systems Research, Inc.
    Inventors: Anil Vasudeo Virkar, Jan-Fong Jue, Kuan-Zong Fung
  • Patent number: 6113802
    Abstract: An insulation material which is substantially free of fibers and which has a density of less than about 2.5 g/cc and a thermal conductivity of less than about 5 W/Km is formed from a composition comprising at least about 2%, by weight, carbon. The insulation material is resistant to thermal shock and is easily machined.
    Type: Grant
    Filed: March 19, 1998
    Date of Patent: September 5, 2000
    Assignee: Micropyretics Heaters International, Inc.
    Inventor: Srinivas Penumella
  • Patent number: 6093366
    Abstract: The present invention provides a ceramic sintered body excellent in oxidation resistance under high temperatures and markedly superior to the conventional ceramic sintered body in the mechanical strength over a wide temperature range of between room temperature and 1,500.degree. C. The ceramic sintered body of the present invention comprises at least one ceramic crystal grain selected from the group consisting essentially of a monosilicate represented by the general formula RE.sub.2 SiO.sub.5, where RE denotes a IIIa group element including yttrium, and a disilicate represented by the general formula RE.sub.2 Si.sub.2 O.sub.7, where RE denotes a IIIa group element including yttrium, and at least one additional element selected from the group consisting of Al, Cr, Hf, Nb, Zr, Ti, V, Ta, Ca and Mg which is segregated in the boundaries of the ceramic crystal grains in an amount of 0.1 to 15% by weight of the sintered body in terms of the oxide thereof.
    Type: Grant
    Filed: November 5, 1998
    Date of Patent: July 25, 2000
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Masahiro Kato, Yasuhiro Goto, Takayuki Fukasawa, Toshiaki Mizutani
  • Patent number: 6090735
    Abstract: A semiconductive ceramic composition having negative resistance-temperature characteristics, wherein the composition comprises lanthanum cobalt oxide as the primary component, and, as secondary components, at least one oxide of an element selected from B, Fe and Al and at least one oxide of an element selected from Si, Zr, Hf, Ta, Sn, Sb, W, Mo, Te, Ce, Nb, Mn, Th and P. A semiconductive ceramic composition having a resistivity of approximately 10 .OMEGA..multidot.cm to 100 .OMEGA..multidot.cm at room temperature is obtained by controlling the amount of additives. Since the resistivity at room temperature can be enhanced to several times or more that of the conventional compositions while characteristics of the conventional compositions are maintained, the composition may be widely applied to control heavy current.
    Type: Grant
    Filed: October 7, 1998
    Date of Patent: July 18, 2000
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Akinori Nakayama, Terunobu Ishikawa, Hideaki Nimi, Ryouichi Urahara, Yukio Sakabe
  • Patent number: 6087285
    Abstract: A novel zirconia sintered body is provided which contains Y.sub.2 O.sub.3 in a solid solution state, and has tetragonal crystal grains oriented at an orientation degree of not higher than 45%. A process for producing the zirconia sintered body is also provided. This zirconium sintered body deteriorates less, and excellent in stability of surface smoothness, and can be produced by a simple process.
    Type: Grant
    Filed: October 8, 1998
    Date of Patent: July 11, 2000
    Assignee: Tosoh Corporation
    Inventors: Nobukatsu Oomichi, Koji Matsui, Akemi Kato, Michiharu Oogai
  • Patent number: 6054402
    Abstract: An improvement in a thermally insulating component for an engine part, made by sintering from ceramic materials, comprises, the thermally insulating component having a composition, consisting of a mixture of zirconium oxide in the range of about 5% to about 25% by volume and mullite in the range of about 75% to about 95% by volume. Further, the mixture of zirconium oxide and mullite is obtained by chemically mixing the zirconium oxide and mullite in their molecular states, rather than mechanically mixing them. Another feature of this invention includes, forming said thermally insulating component by slip casting and pressureless sintering the mixture of zirconium oxide and mullite at a temperature no greater than 1700.degree. C. This improvement in a thermally insulating component for an engine part, made from a mullite-zirconia ceramic composite, embodying the present invention, is particularly useful in making flame decks for cylinder heads, and insulating coverings for pistons and exhaust ports.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: April 25, 2000
    Assignee: Caterpillar Inc.
    Inventors: Michael C. Long, Michael H. Haselkorn, Virgil R. Hester
  • Patent number: 6025065
    Abstract: A ceramic formed body containing a) 5 to 70 vol % of at least on intermetallic aluminide phase which additionally may contain aluminum or/and aluminum alloy, and b) 30 to 95 vol % of one or more ceramic phases which form a solid interconnecting skeleton and wherein the intermetallic phase or phases consist of predominantly interconnected areas with average sizes of 0.1 to 10 .mu.m, is obtained by sintering, in a non-oxidizing atmosphere, of a powder metallurgically green body which consists of a mixture of finely dispersed powder of aluminum, one or more ceramic substances and maybe further metals such that the mixture contains at least one oxide ceramic or/and metallic powder which, during sintering, reacts with aluminum thereby forming an aluminide and maybe Al.sub.2 O.sub.3.
    Type: Grant
    Filed: November 19, 1997
    Date of Patent: February 15, 2000
    Assignee: Nils Claussen
    Inventors: Nils Claussen, Daniel Garcia, Rolf Janssen
  • Patent number: 6017839
    Abstract: The present invention is ceramic article of stabilized zirconia wherein the stabilized zirconia has a molar ratio of rare earth oxide:zirconia of from 1:99 to 15:85, at a weight percent of from about 97 to 75. The ceramic article includes smectite clay from about 3 to 25 weight percent wherein the article is a mass of sintered particles having a continuous tetragonal phase having dispersed therein monoclinic phase particles having size of less than 100 nm.
    Type: Grant
    Filed: February 9, 1998
    Date of Patent: January 25, 2000
    Assignee: Eastman Kodak Company
    Inventors: Debasis Majumdar, Dilip K. Chatterjee, Syamal K. Ghosh
  • Patent number: 6013592
    Abstract: A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composite comprises a plurality of hollow oxide-based spheres of varios dimentions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substates are also provided.
    Type: Grant
    Filed: March 27, 1998
    Date of Patent: January 11, 2000
    Assignee: Siemens Westinghouse Power Corporation
    Inventors: Gary B. Merrill, Jay Alan Morrison
  • Patent number: 6004644
    Abstract: A zirconia diaphragm structure, and a method of producing such structure in which the zirconia diaphragm structure includes a zirconia substrate having at least one window, and a zirconia diaphragm plate formed integrally with the zirconia substrate so as to close each window, the zirconia substrate comprising a zirconia material as a major component, and containing 0.1-3.0% by weight of alumina, 0.1-3.0% by weight of silica, 0.1-5.0% by weight of alumina and silica, 0.1-5.0% by weight of alumina and magnesia, or 0.1-5.0% by weight of alumina, silica and magnesia.
    Type: Grant
    Filed: August 16, 1996
    Date of Patent: December 21, 1999
    Assignee: NGK Insulators, Ltd.
    Inventors: Yukihisa Takeuchi, Hideo Masumori, Katsuyuki Takeuchi, Tsutomu Nanataki
  • Patent number: 6001761
    Abstract: Disclosed are a ceramics sheet which has an area of 400 cm.sup.2 or more, thickness of 0.4 mm or less, maximum waviness height of 100 .mu.m or less, and warp of 0.1% or less and in which frequency of generated cracking and breakage is 10% or less when a load-applying test and a deflection-loading test each described in the text are carried out in succession, and a flat and large ceramics sheet having an area of 600 cm.sup.2 or more and thickness of 1 mm or less.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: December 14, 1999
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kazuo Hata, Norikazu Aikawa, Hideki Imai, Tetuya Yasaka
  • Patent number: 5994250
    Abstract: A sintered ceramic body which can be worked by electrical discharge machining, has high mechanical strength, and can be worked into sintered ceramic tools which have long life is disclosed. Further, sintered ceramic tools which have long life and scarcely cause flaws in work pieces are provided. The sintered ceramic body comprises ceramic particles having specific particle diameter and particle distribution.
    Type: Grant
    Filed: July 9, 1998
    Date of Patent: November 30, 1999
    Assignee: NGK Spark Plug Company Limited
    Inventors: Keiji Suzuki, Takayoshi Morishita, Tetsuji Yogo