Titanate Containing Patents (Class 501/136)
  • Publication number: 20120094824
    Abstract: The invention is to provide an aluminum titanate-based ceramics showing a good mechanical strength. The invention is an aluminum titanate-based ceramics obtained by firing a starting material mixture which contains a titanium element and an aluminum element, and further contains a chromium element and/or a tungsten element. Preferably, a content of a chromium source which contains the chromium element is from 0.001 to 5 parts by mass, and a content of a tungsten source which contains the tungsten element is from 0.001 to 1.0 part by mass relative to 100 parts by mass of the starting material mixture.
    Type: Application
    Filed: February 16, 2010
    Publication date: April 19, 2012
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kentaro Iwasaki, Akiyoshi Nemoto
  • Patent number: 8142678
    Abstract: A perovskite type oxide of a single crystal structure or a uniaxial-oriented crystal structure is represented by ABO3. Site A includes Pb as a main component and site B includes a plurality of elements. The perovskite type oxide includes a plurality of crystal phases selected from the group consisting of tetragonal, rhombohedral, orthorhombic, cubic, pseudo-cubic and monoclinic systems and the plurality of crystal phases are oriented in the direction of <100>.
    Type: Grant
    Filed: August 7, 2006
    Date of Patent: March 27, 2012
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takanori Matsuda, Katsumi Aoki, Toshihiro Ifuku, Kenichi Takeda, Tetsuro Fukui, Hiroshi Funakubo, Shintaro Yokoyama
  • Publication number: 20120063056
    Abstract: A dielectric ceramic composition includes a compound having perovskite type crystal structure shown by a general formula ABO3, where A is at least one selected from Ba, Ca and Sr, and B is at least one selected from Ti and Zr. The dielectric ceramic composition includes, as subcomponents, an oxide of RA (Dy, Gd and Tb); an oxide of RB (Ho and Y); an oxide of RC (Yb and Lu); Mg oxide and an oxide including Si in terms of RA2O3, RB2O3, RC2O3, Mg and Si, respectively. Also, when contents of the oxide of RA, RB and RC with respect to 100 moles of the compound are defined as “?”, “?” and “?”, respectively, they satisfy relations of 1.2?(?/?)?5.0 and 0.5?(?/?)?10.0.
    Type: Application
    Filed: September 6, 2011
    Publication date: March 15, 2012
    Applicant: TDK Corporation
    Inventors: Kosuke Takano, Tomohisa Fukuoka, Makoto Maeda, Yuhta Matsunaga, Masahide Ishizuya, Tamotsu Ishiyama, Takahiro Yamada
  • Patent number: 8114801
    Abstract: Multilayer ceramic chip capacitors which satisfy COG requirements and which are compatible with reducing atmosphere sintering conditions so that non-noble metals such as nickel and nickel alloys thereof may be used for internal and external electrodes are made in accordance with the invention. The capacitors exhibit desirable dielectric properties (high capacitance, low dissipation factor, high insulation resistance), excellent performance on highly accelerated life testing, and very good resistance to dielectric breakdown. The dielectric layers comprise a strontium zirconate matrix doped with other metal oxides such as TiO2, MgO, B2O3, CaO, Al2O3, SiO2, and SrO in various combinations.
    Type: Grant
    Filed: November 15, 2010
    Date of Patent: February 14, 2012
    Assignee: Ferro Corporation
    Inventors: Walter J. Symes, Jr., Mohammed H. Megherhi, Elisabeth W. J. Römer, Mike S. H. Chu, Willibrordus J. L. M. J. Coppens
  • Publication number: 20120028784
    Abstract: The invention is to provide a process which can produce a fired body comprising aluminum titanate-based ceramics being excellent in thermal decomposition resistance and having high mechanical strength. The invention is a process for producing an aluminum titanate-based fired body, comprising a step of firing a shaped body of a starting material mixture which contains an aluminum source powder and a titanium source powder, and the aluminum source powder satisfies the following formula (1). In the formula, D90 is a particle diameter corresponding to a cumulative percentage of 90% on a volume basis and D10 is a particle diameter corresponding to a cumulative percentage of 10% on a volume basis, and these are determined from a particle size distribution of the aluminum source powder measured by a laser diffractometry.
    Type: Application
    Filed: December 25, 2009
    Publication date: February 2, 2012
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kousuke Uoe, Keiichiro Suzuki, Masahiro Kan, Hajime Yoshino
  • Patent number: 8101536
    Abstract: A glass-free microwave dielectric ceramic that can be sintered at low temperature is provided. The glass-free microwave dielectric ceramic composition includes (M1-x2+M?x2+)N4+B2O6 (wherein M and M? are different each other, each being one among Ba, Ca and Sr; N is one among Sn, Zr and Ti; and 0<x<1), M2+(N1-y4+N?y4+)B2O6 (wherein M is one among Ba, Ca and Sr; N and N? are different from each other, each being one among Sn, Zr and Ti; and 0<y<l), or (M1-x2+M?x2+)(N1-y4+)B2O6 (wherein M and M? are different from each other, each being one among Ba, Ca and Sr; N and N? are different from each other, each being one among Sn, Zr and Ti; 0<x<1; and 0<y<l). In addition, the glass-free microwave dielectric ceramic composition may further includes approximately 1 wt % to approximately 7 wt % of a sintering aid represented by a formula, 0.12CuO+0.88Bi2O3. As such, the glass-free microwave dielectric ceramic composition may be sintered at a low temperature at lowest 875° C.
    Type: Grant
    Filed: November 22, 2007
    Date of Patent: January 24, 2012
    Assignee: Korea Institute of Ceramic Engineering & Technology
    Inventors: Hyo Tae Kim, Jong Hee Kim, Myung Hwa Nam
  • Publication number: 20120015198
    Abstract: Disclosed is a dielectric ceramic composition which has high dielectric constant and suppressed low thermal expansion coefficient. Also disclosed are a multilayer dielectric substrate using the dielectric ceramic composition, and an electronic component. Specifically disclosed is a dielectric ceramic composition which contains an ATiO3 (wherein A represents either Ca and/or Sr) phase and an AAl2Si2O8 phase, said dielectric ceramic composition being characterized in that the dielectric constant is not less than 10 at 3 GHz and the average thermal expansion coefficient over the temperature range of 40-600° C. is less than 7 ppm/° C.
    Type: Application
    Filed: March 19, 2010
    Publication date: January 19, 2012
    Applicant: HITACHI METALS, LTD.
    Inventors: Junichi Masukawa, Koji Ichikawa
  • Patent number: 8097546
    Abstract: A composition for ceramic extrusion-molded bodies includes a ceramic material, a water-soluble cellulose ether, a styrenesulfonate and water. A method for manufacturing a ceramic extrusion-molded body using the composition is also provided.
    Type: Grant
    Filed: July 29, 2009
    Date of Patent: January 17, 2012
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Shingo Niinobe, Kazuhisa Hayakawa
  • Patent number: 8093170
    Abstract: A semiconductor ceramic material which contains no Pb and has a high Curie point, low resistivity, and PTC characteristics is represented by the formula ABO3 wherein A includes Ba, Ca, an alkali metal element, Bi, and a rare-earth element, and B includes Ti. The semiconductor ceramic material contains 5 to 20 molar parts and preferably 12.5 to 17.5 molar parts of Ca per 100 molar parts of Ti. The ratio of the content of the alkali metal element to the sum of the content of the bismuth plus the content of the rare earth element, is preferably from 1.00 to 1.06. The semiconductor ceramic material preferably further contains 0.01 to 0.2 molar parts of Mn per 100 molar parts of Ti.
    Type: Grant
    Filed: December 11, 2009
    Date of Patent: January 10, 2012
    Assignee: Murata Manufacturing Co., Ltd.
    Inventor: Hayato Katsu
  • Publication number: 20120003464
    Abstract: The process for producing a porous ceramics shaped body comprises a step of firing a shaped body of a starting material mixture which contains an aluminum source powder and a titanium source powder, and the aluminum source powder satisfies the below formula (1a): (Da90/Da10)1/2<2??(1a) wherein Da90 is a particle diameter corresponding to a cumulative percentage of 90% on a volume basis and Da10 is a particle diameter corresponding to a cumulative percentage of 10% on a volume basis, and these are determined from a particle size distribution of the aluminum source powder measured by a laser diffractometry.
    Type: Application
    Filed: January 7, 2010
    Publication date: January 5, 2012
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kousuke Uoe, Keiichiro Suzuki, Hajime Yoshino
  • Patent number: 8076257
    Abstract: A bismuth sodium titanate (Bi0.5Na0.5TiO3) base material is modified by the partial substitution of aliovalent A-site cations such as barium (as BaO) or strontium (as SrO), as well as certain b-site donor/acceptor dopants and sintering aids to form a multi-phase system, much like known “core/shell” X7R dielectrics based solely on BaTiO3. The resulting ceramic dielectric composition is particularly suitable for producing a multilayer ceramic capacitor (10) that maintains high dielectric constant (and thus the capability of maintaining high capacitance) over a broad temperature range of from about 150° C. to about 300° C. Such capacitors (10) are appropriate for high temperature power electronics applications in fields such as down-hole oil and gas well drilling.
    Type: Grant
    Filed: April 22, 2009
    Date of Patent: December 13, 2011
    Assignee: MRA Laboratories, Inc
    Inventor: James M. Wilson
  • Publication number: 20110287921
    Abstract: The invention is to provide a process for producing a fired body comprising an aluminum titanate-based ceramic of which the shrinkage ratio in firing (firing shrinkage ratio) can be suppressed low and which is excellent in thermal decomposition resistance. The invention is a process for producing an aluminum titanate-based fired body comprising a step of firing a shaped body of a starting material mixture containing an aluminum source powder, a titanium source powder and a magnesium source powder, wherein the titanium source powder has a specific particle diameter distribution characteristic.
    Type: Application
    Filed: December 11, 2009
    Publication date: November 24, 2011
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kousuke Uoe, Keiichiro Suzuki, Masahiro Kan, Hajime Yoshino
  • Publication number: 20110281718
    Abstract: A dielectric material is provided. The material includes ?[Ca1-x-yBaxSry(Ca1-zCuz)Cu2-pLa2p/3Ti4-qMqO12-?]+(1??)[BarSr1-rTiO3], wherein M is aluminum, chromium, zirconium, or combinations thereof; x can vary between the value of zero and 0.1 such that 0?x?0; y, z, and r can vary between the value of zero and 1 such that 0?y?1, 0?z?1, and 0?r?1; p and q can vary between the value of zero and 0.1 such that 0?p?0.1 and 0?q?0.1; ? can vary between the value of zero and 0.05 such that 0??Z?0.05; and ? can vary between the value of 0.5 and 1 such that 0.5???1, with a proviso that when x=y=0 and z=?=1, p and q are greater than zero; and when x=y=z=0, p and q are not simultaneously zero. A dielectric component including the dielectric material and a system including the dielectric component are provided.
    Type: Application
    Filed: March 30, 2011
    Publication date: November 17, 2011
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Kalaga Murali Krishna, Lohit Matani
  • Patent number: 8052954
    Abstract: A barium calcium titanate of the present invention has a remarkable effect that a fine barium calcium titanate powder having excellent dispersibility, reduced impurities and high crystallinity and being solid-dissolved at an arbitrary ratio, and a production process thereof are provided. The barium calcium titanate represented by the compositional formula: (Ba(1-X)CaX)YTiO3 (wherein 0<X<0.2 and 0.98?Y?1.02), which contains 3 mol % or less (including 0 mol %) of an orthorhombic perovskite compound and in which the specific surface area D is from 1 to 100 m2/g.
    Type: Grant
    Filed: August 26, 2005
    Date of Patent: November 8, 2011
    Assignee: Showa Denko K.K.
    Inventors: Tadatoshi Kurozumi, Akihiko Shirakawa
  • Publication number: 20110267739
    Abstract: A polyimide resin is provided. The polyimide resin comprises the reaction product of a polyimide resin and an amine comprising a C1-10 hydrocarbon substituted with CN, F, SO2, SO, S, SO3, SO3?, PO, PO2H, PO3H, PO2?, PO3?2, CO, CO2?, CO2H, CONH, CONH2, NHCOHN, OCONH, OCO2, N, NH, NH2, NO2, CSNH, CSNH2, NHCSNH, OTi(OR4)3, or OSi(OR4)3 or combinations of these, wherein R4 is a C1-10 aliphatic or aromatic hydrocarbon. The resin may be used to provide a thin film that in turn, may advantageously be used to form, wholly or in part, articles such as capacitors, sensors, batteries, flexible printed circuit boards, keyboard membranes, motor/transformer insulations, cable wrappings, industrial tapes, interior coverage materials, and the like. In particular, a capacitor comprising the thin film and methods of making the same are also provided.
    Type: Application
    Filed: April 30, 2010
    Publication date: November 3, 2011
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Gary William Yeager, Norberto Silvi, Patricia Chapman Irwin, Robert Colin McTigue
  • Patent number: 8043987
    Abstract: A ceramic composition comprising a binary system solid solution represented by the formulae: (1-x)(Sr1-yBiy)TiO3+x(Na0.5Bi0.5)TiO3 and (1-x)(Sr1-1.5yBiy)TiO3+x(Na0.5Bi0.5)TiO3, wherein 0<x<1 and 0<y?0.2.
    Type: Grant
    Filed: November 18, 2005
    Date of Patent: October 25, 2011
    Assignee: The University of Akron
    Inventors: Ang Chen, Yu Zhi
  • Publication number: 20110254642
    Abstract: Disclosed is a dielectric ceramic which contains, as the main component, a crystal containing La, Al, Ca and Ti and additionally contains a molybdenum oxide.
    Type: Application
    Filed: December 25, 2009
    Publication date: October 20, 2011
    Applicant: KYOCERA CORPORATION
    Inventors: Shiho Enokida, Shunichi Murakawa
  • Publication number: 20110248106
    Abstract: The invention is to provide a novel process for producing aluminum titanate-based ceramics having a low coefficient of thermal expansion. The invention is a process for producing an aluminum titanate-based ceramic comprising firing a starting material mixture containing a titanium source powder, an aluminum source powder and a silicon source powder, wherein the particle diameter corresponding to a cumulative percentage of 50% (D50) on a volume basis of the silicon source powder is not greater than 5 ?m. The invention includes the process wherein the starting material mixture further contains a magnesium source powder.
    Type: Application
    Filed: November 5, 2009
    Publication date: October 13, 2011
    Applicant: Sumitomo Chemical Company, Limited
    Inventors: Hajime Maki, Kousuke Uoe, Kentaro Iwasaki
  • Publication number: 20110236634
    Abstract: There is provided a dielectric ceramic composition for high-frequency use represented by a composition formula of a(Sn,Ti)O2-bMg2SiO4-cMgTi2O5-dMgSiO3. In the composition formula, a, b, c and d (provided that a, b, c and d are mol %) are within the following ranges: 4?a?37, 34?b?92, 2?c?15 and 2?d?15, respectively, and a+b+c+d=100. The dielectric ceramic composition for high-frequency use has a relative permittivity ?r of 7.5-12.0, a Qm×fo value of not less than 50000 (GHz) and an absolute value of a temperature coefficient ?f of resonance frequency fo of not more than 30 ppm/° C.
    Type: Application
    Filed: November 25, 2009
    Publication date: September 29, 2011
    Applicant: Ube Industries Ltd
    Inventors: Takafumi Kawano, Masataka Yamanaga, Atsushi Okabe
  • Publication number: 20110236688
    Abstract: The invention is to provide a process of producing the powder of aluminum titanate-based ceramics in which the formation of fine particulate component and coarse particulate component is inhibited, and having a very sharp grain size distribution, efficiently and at good yield. The invention is a process for producing a powder of aluminum titanate-based ceramics, comprising a step of keeping a precursor mixture containing a titanium source powder, an aluminum source powder and a silicon source powder at a temperature range of from 1100° C. to 1350° C. for 3 hours or more, followed by a step of heating the precursor mixture up to 1400° C.
    Type: Application
    Filed: October 6, 2009
    Publication date: September 29, 2011
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Keiichiro Suzuki, Masayuki Narumi
  • Publication number: 20110228443
    Abstract: A dielectric ceramic composition enabling one to obtain a laminated capacitor which hardly causes degradation of insulation resistance with time under high-humidity even in using a base metal such as Ni as an internal electrode, contains as a main constituent, a constituent represented by (CaxSr1-x)(TiyZr1-y)O3 in which x and y are 0?x?1 and 0?y?0.50, and, as accessory constituents, at least 0.5 parts by mol and at most 15 parts by mol of SiO2, at least 0.1 parts by mol and at most 10 parts by mol of MnO, and at least 0.01 parts by mol and at most 0.079 parts by mol of Al2O3, with respect to 100 parts by mol of the main constituent.
    Type: Application
    Filed: March 17, 2011
    Publication date: September 22, 2011
    Applicant: MURATA MANUFACTURING CO., LTD.
    Inventors: Hitoshi Nishimura, Masahiro Naito
  • Patent number: 8021568
    Abstract: A piezoceramic composition of a calculated empirical formula Pb1-aREbAEc[ZrxTiy(NinMom)z]O3, wherein RE represents a rare earth metal having a rare earth metal content b, AE represents an alkaline earth metal having an alkaline earth metal content c, nickel is provided with a nickel content n.z, and molybdenum is provided with a molybdenum content m.z. Furthermore, the following correlations apply: a<1; 0=b=0.15; 0=c=0.5; n>0; m>0; 0.1=n/m=5; x>0; y>0; z>0, and x+y+z=1. In a method for producing a piezoceramic component a) a green ceramic member containing the piezoceramic composition is supplied; and b) the green member is subjected to a thermal treatment such that the piezoceramic material of the component is produced from the piezoceramic composition. The thermal treatment encompasses calcining and/or sintering of the piezoceramic composition. The piezoceramic composition is compressed below 1000° C.
    Type: Grant
    Filed: December 18, 2006
    Date of Patent: September 20, 2011
    Assignee: Siemens Aktiengesellschaft
    Inventors: Francois Bamiere, Katrin Benkert, Stefan Denneler, Morgane Radanielina, Carsten Schuh
  • Publication number: 20110222206
    Abstract: A dielectric ceramic composition includes, as a main component, a compound having perovskite type crystal structure shown by a general formula ABO3, as subcomponents, in terms of respective element with respect to 100 moles of the compound, and 0.6 to 2.0 moles of an oxide of Mg, 0.010 to 0.6 mole of oxide of Mn and/or Cr, 0.010 to 0.2 mole of an oxide of at least one selected from V, Mo and W, 0.10 to 1.0 mole of an oxide of R1 (R1 is at least one selected from Y, Yb, Er and Ho), 0.10 to 1.0 mole of an oxide of R2 (R2 is at least one selected from Dy, Gd and Tb) and 0.2 to 1.5 moles of a component consisting of an oxide of Ba and/or oxide of Ca and an oxide of Si. According to the present invention, even when a dielectric layer is made thinner, a dielectric ceramic composition having good characteristics can be provided.
    Type: Application
    Filed: March 9, 2011
    Publication date: September 15, 2011
    Applicant: TDK CORPORATION
    Inventors: Kazuhiro KOMATSU, Yoichiro HOSHI, Shuhei YOSHIKAWA, Yuichiro SUEDA
  • Publication number: 20110216473
    Abstract: A dielectric ceramic composition includes a compound having perovskite type crystal structure shown by a general formula ABO3, where A is at least one selected from Ba, Ca and Sr, and B is at least one selected from Ti and Zr, as a main component. The dielectric ceramic composition includes, as subcomponents, with respect to 100 moles of the compound, 1.0 to 2.5 moles of an oxide of RA (Dy, Gd and Tb); 0.2 to 1.0 mole of an oxide of RB (Ho and Y); 0.1 to 1.0 mole of an oxide of RC (Yb and Lu); 0.8 to 2.0 moles of Mg oxide and 1.2 to 3.0 moles of an oxide including Si in terms of RA2O3, RB2O3, RC2O3, Mg and Si, respectively. Also, when contents of the oxide of RA, RB and RC with respect to 100 moles of the compound are defined as “?”, “?” and “?”, respectively, the “?”, “?” and “?” satisfy relations of 2.5?(?/?)?5.0 and 1.0?(?/?)?10.0. According to the present invention, a dielectric ceramic composition having good properties can be provided.
    Type: Application
    Filed: March 1, 2011
    Publication date: September 8, 2011
    Applicant: TDK CORPORATION
    Inventors: Kosuke Takano, Tomohisa Fukuoka, Makoto Maeda, Yuhta Matsunaga, Masahide Ishizuya, Tamotsu Ishiyama, Takahiro Yamada
  • Publication number: 20110212382
    Abstract: Dielectric compositions that include compound of the formula [(M?)1?x(A?)x][(M?)1?y?z,(B?)y(C?)z]O3??(VO)? and protonated dielectric compositions that include a protonated dielectric compound within the formula [(M?)1?x(A?)x](M?)1?y?z(B?)y(C?)z]O3??+h(Vo)?(H*)2h are disclosed. Composite materials that employ one or more of these dielectric compounds together with an electrolyte also are disclosed. Composite material that employs one or more of these dielectric compounds together with an electrochemally active material also are disclosed.
    Type: Application
    Filed: October 7, 2010
    Publication date: September 1, 2011
    Applicants: The Penn State Research Foundation, Recapping, Inc.
    Inventors: Clive A. Randall, Leslie E. Cross, Aram Yang, Niall J. Donnelly, Ramakrishnan Rajagopalan, Amanda Lou Baker
  • Patent number: 7993611
    Abstract: Wet-chemical methods involving the use of water-soluble hydrolytically stable metal-ion chelate precursors and an ammonium oxalate precipitant can be used in a coprecipitation procedure for the preparation of ceramic powders. Both the precursor solution and the ammonium oxalate precipitant solution are at neutral or near-neutral pH. A composition-modified barium titanate is one of the ceramic powders that can be produced. Certain metal-ion chelates can be prepared from 2-hydroxypropanoic acid and ammonium hydroxide.
    Type: Grant
    Filed: August 2, 2006
    Date of Patent: August 9, 2011
    Assignee: EEStor, Inc.
    Inventors: Richard D. Weir, Carl W. Nelson
  • Publication number: 20110190120
    Abstract: The invention relates to a particle blend comprising mainly or consisting of an oxide phase of the pseudo-brookite type comprising at least titanium and aluminum, said blend being obtained from at least two particle size fractions, namely a coarse particle size fraction, the median diameter d50 of which is greater than 12 microns, and a fine particle size fraction, the median diameter d50 of which is between 0.5 and 3 microns, the mass ratio of said coarse fraction to said fine fraction being between 1.5 and 20, limits inclusive, and the ratio of the median diameter of the coarse fraction to that of the fine fraction being greater than 12.
    Type: Application
    Filed: July 2, 2009
    Publication date: August 4, 2011
    Applicant: SAINT-GOBAIN CENTRE DE RECH. ET D'ETUDES EUROPEEN
    Inventors: Carine Dien-Barataud, Matthias Schumann
  • Publication number: 20110183834
    Abstract: Provided is a modified perovskite type composite oxide in which the dielectric characteristics are equal to or better than those prior to modification, there is no substantial elution of coating components from the modifying coating components, and elution of the A-site metals is suppressed effectively, while the cracking traits are good. A modified perovskite type composite oxide in which the particle surface of a perovskite type composite oxide is firstly coated with at least one selected from a group consisting of TiO2, Al2O3, ZrO2, and Nd2O3, wherein the first coating is formed by hydrolyzing at least one selected from a group consisting of a hydrolyzable TiO2 precursor, a hydrolyzable Al2O3 precursor, a hydrolyzable ZrO2 precursor, and a hydrolyzable Nd2O3 precursor, and then calcining it at 700° C. to 1200° C.
    Type: Application
    Filed: July 16, 2009
    Publication date: July 28, 2011
    Applicant: Nippon Chemical Industrial Co., Ltd.
    Inventor: Shinji Tanabe
  • Publication number: 20110171421
    Abstract: The invention relates to a mixture of fused grains mainly comprising or composed of an oxide phase of pseudo-brookite type and comprising titanium, aluminum and magnesium, said fused grains having the following chemical composition, in weight percentages on the basis of the oxides: less than 55% of Al2O3; more than 30% and less than 70% of TiO2; more than 1% and less than 15% of MgO, said fused grains also corresponding to the following composition, in molar percentages and on the basis of the single oxides Al2O3, TiO2, MgO: 180?3t+a?220, a?50, m=100?a?t, in which: a is the molar percentage of Al2O3; t is the molar percentage of TiO2; m is the molar percentage of MgO. The invention also relates to a ceramic product obtained from such fused grains.
    Type: Application
    Filed: July 2, 2009
    Publication date: July 14, 2011
    Applicant: Saint-Gobain Centre De Rech. Et D'Etudes Europeen
    Inventors: Yves Boussant-Roux, Isabelle Cabodi, Samuel Marlin
  • Publication number: 20110152075
    Abstract: The invention relates to a porous structure comprising a ceramic material comprising mainly or consisting of an oxide material of the pseudobrookite type comprising titanium, aluminum, magnesium and zirconium in proportions such that the phase of the pseudobrookite type substantially satisfies the formula: (Al2TiO5)x(MgTi2O5)y(MgTiZrO5)z said material satisfying the following composition, in mol % on the basis of just the oxides Al2O3, TiO2, MgO and ZrO2: 90<2a+3m<110; 100+a<3t<210?a; and a+t+m+zr=100, in which: a is the molar content of Al2O3; t is the molar content of TiO2; m is the molar content of MgO; and zr is the molar content of ZrO2.
    Type: Application
    Filed: July 2, 2009
    Publication date: June 23, 2011
    Applicant: Saint-Gobain Centre de Rech. Et D'Etudes European
    Inventors: Stephane Raffy, Philippe Auroy
  • Publication number: 20110143911
    Abstract: A transparent, polycrystalline ceramic is described. The ceramic comprises crystallites of the formula AxCuByDvEzFw, whereby A and C are selected from the group consisting of Li+, Na+, Be2+, Mg2+, Ca2+, Sr2+, Ba2+, Al3+, Ga3+, In3+, C4+, Si4+, Ge4+, Sn2+/4+, Sc3+, Ti4+, Zn2+, Zr4+, Mo6+, Ru4+, Pd2+, Ag2+, Cd2+, Hf4+W4+/6+, Re4+, Os4+, Ir4+,, Pt2+/4+, Hg2+ and mixtures thereof, B and D are selected from the group consisting of Li+, Na+, K+, Mg2+, Al3+, Ga3+, In3+, Si4+, Ge4+, Sn4+, Sc3+, Ti4+, Zn2+, Y3+, Zr4+, Nb3+, Ru3+, Rh3+, La3+, Lu3+, Gd3+ and mixtures thereof, E and F are selected mainly from the group consisting of the divalent anions of S, Se and O and mixtures thereof, x, u, y, v, z and w satisfy the following formulae 0.125<(x+u)/(y+v)?0.55 z+w=4 and at least 95% by weight of the crystallites display symmetric, cubic crystal structures of the spinel type, with the proviso that when A=C=Mg2+ and B=D=Al3+, E and F cannot both be O.
    Type: Application
    Filed: November 18, 2010
    Publication date: June 16, 2011
    Inventors: Yvonne Menke, Peter Blaum, Ulrich Peuchert, Yoshio Okano
  • Publication number: 20110143912
    Abstract: A transparent, polycrystalline ceramic is described. The ceramic comprises crystallites of the formula AxCuByDvEzFw, whereby A and C are selected from the group consisting of Li+, Na+, Be2+, Mg2+, Ca2+, Sr2+, Ba2+, Al3+, Ga3+, In3+, C4+, Si4+, Ge4+, Sn2+/4+, Sc3+, Ti4+, Zn2+, Zr4+, Mo6+, Ru4+, Pd2+, Ag2+, Cd2+, Hf4+, W4+/6+, Re4+, Os4+, Ir4+, Pt2+/4+, Hg2+ and mixtures thereof, B and D are selected from the group consisting of Li+, Na+, K+, Mg2+, Al3+, Ga3+, In3+, Si4+, Ge4+, Sn4+, Sc3+, Ti4+, Zn2+, Y3+, Zr4+, Nb3+, Ru3+, Rh3+, La3+, Lu3+, Gd3+ and mixtures thereof, E and F are selected mainly from the group consisting of the divalent anions of S, Se and O and mixtures thereof, x, u, y, v, z and w satisfy the following formulae 0.125<(x+u)/(y+v)?0.
    Type: Application
    Filed: November 18, 2010
    Publication date: June 16, 2011
    Inventors: Yvonne MENKE, Peter Blaum, Ulrich Peuchert, Yoshio Okano
  • Publication number: 20110135947
    Abstract: A two-layer system made of ceramic powder and metallic powder is provided. The ceramic powder may include zirconium oxide, aluminum oxide, titanium oxide, a perovskite, a spindle, a pyrochore and/or boron nitride and mixtures thereof. The metallic powder may include nickel, aluminum, cobalt and/or chromium, and mixtures or alloys thereof. A masking layer and a process for masking a substrate are also provided.
    Type: Application
    Filed: December 2, 2010
    Publication date: June 9, 2011
    Inventors: Thomas Berndt, Francis-Jurjen Ladru
  • Publication number: 20110128670
    Abstract: Disclosed are ceramic-polymer composite consisting of aggregates of dielectric ceramic particles and polymer resin, and a fabrication method thereof, the method including aggregating dielectric ceramic particles to create aggregates, melting polymer resin in a solvent to prepare a polymer solution, dispersing the aggregates in the polymer solution to prepare a mixed solution, and hardening the mixed solution to obtain ceramic-polymer composites.
    Type: Application
    Filed: December 2, 2009
    Publication date: June 2, 2011
    Inventors: Hae June Je, Byung Kook Kim, Min Park, Dong Ho Lee
  • Publication number: 20110130267
    Abstract: The present invention is related to producing fine nano or submicron-scale precision ceramic powder by applying an innovative chemical reactor with powder collection to the glycine-nitrate combustion process (GNC-P). The unique feature lies in the utilization of a simple-operating process to massively produce nano or submicron-scale ceramic oxide powder with multiple metal components. The present invention not only provides very high powder collection efficiency and production yield as well as safety but also satisfies requirements of industrial safety and environmental safety, and lowers production cost.
    Type: Application
    Filed: December 1, 2009
    Publication date: June 2, 2011
    Inventors: Chun-Hsiu Wang, Maw-Chwain Lee, Yang-Chuang Chang, Wei-Xin Kao, Tai-Nan Lin
  • Publication number: 20110105318
    Abstract: The invention relates to a mixture of fused grains having the following chemical composition, in weight percentages on the basis of the oxides: less than 55% of Al2O3; more than 35% and less than 80% of TiO2; more than 1% and less than 20% of MgO; more than 0.7% and less than 20% of ZrO2; and less than 20% of SiO2, said fused grains also corresponding to the following composition, in molar percentages, on the basis of the single oxides Al2O3, TiO2, MgO, ZrO2: 90<2a+3m<110, 100+a<3t<210?a with a+t+m+zr=100, in which: a is the molar percentage of Al2O3; t is the molar percentage of TiO2; m is the molar percentage of MgO; and zr is the molar percentage of ZrO2. The invention also relates to a ceramic product obtained from such fused grains.
    Type: Application
    Filed: July 2, 2009
    Publication date: May 5, 2011
    Applicant: Saint-Gobain Centre De Recherches Et D'etudes Eur.
    Inventor: Stephane Raffy
  • Publication number: 20110097478
    Abstract: A novel lead zirconium titanate (PZT) material having unique properties and application for PZT thin film capacitors and ferroelectric capacitor structures, e.g., FeRAMs, employing such thin film material. The PZT material is scalable, being dimensionally scalable, pulse length scalable and/or E-field scalable in character, and is useful for ferroelectric capacitors over a wide range of thicknesses, e.g., from about 20 nanometers to about 150 nanometers, and a range of lateral dimensions extending to as low as 0.15 ?m. Corresponding capacitor areas (i.e., lateral scaling) in a preferred embodiment are in the range of from about 104 to about 10?2 ?m2. The scalable PZT material of the invention may be formed by liquid delivery MOCVD, without PZT film modification techniques such as acceptor doping or use of film modifiers (e.g., Nb, Ta, La, Sr, Ca and the like).
    Type: Application
    Filed: December 23, 2010
    Publication date: April 28, 2011
    Applicant: Advanced Technology Materials, Inc.
    Inventors: Peter C. Van Buskirk, Jeffrey F. Roeder, Steven M. Bilodeau, Michael W. Russell, Stephen T. Johnston, Daniel J. Vestyck, Thomas H. Baum
  • Publication number: 20110097582
    Abstract: An object of the invention is to provide a ceramic having a small thermal expansion coefficient and having more excellent mechanical strength. The invention is an aluminum magnesium titanate-alumina composite ceramic containing aluminum magnesium titanate and alumina and, the elemental composition ratio of Al, Mg and Ti therein is represented by a compositional formula (1): Al2(1?x)MgxTi(1+x)O5+aAl2O3 ??(1), wherein coefficient x satisfies 0<x?1, and coefficient a satisfies 0.4x?a<2x.
    Type: Application
    Filed: January 20, 2009
    Publication date: April 28, 2011
    Applicant: Sumitomo Chemical Company, Limited
    Inventors: Tetsuro Tohma, Satoko Iwato, Rina Hatemata
  • Patent number: 7931821
    Abstract: An oxynitride piezoelectric material, which exhibits ferroelectricity and has good piezoelectric properties, and a method of producing the oxynitride piezoelectric material. The oxynitride piezoelectric material includes a tetragonal perovskite-type oxynitride represented by the following general formula (1): A1?xBix+?1B1?yB?y+?2O3?zNz??(1), where A represents a divalent element, B and B? each represent a tetravalent element, x represents a numerical value of 0.35 or more to 0.6 or less, y represents a numerical value of 0.35 or more to 0.6 or less, z represents a numerical value of 0.35 or more to 0.6 or less, and ?1 and ?2 each represent a numerical value of ?0.2 or more to 0.2 or less, in which the A includes at least one kind selected from Ba, Sr, and Ca and the B and the B? each include at least one kind selected from Ti, Zr, Hf, Si, Ge, and Sn.
    Type: Grant
    Filed: December 16, 2009
    Date of Patent: April 26, 2011
    Assignees: Canon Kabushiki Kaisha, Kyoto University, Tokyo Institute of Technology, University of Yamanashi, National Institute of Advanced Industrial Science and Technology, Tokyo University of Science Educational Foundation Administrative Organization
    Inventors: Hiroshi Saito, Takanori Matsuda, Kaoru Miura, Kenji Takashima, Masaki Azuma, Takashi Iijima, Hiroshi Funakubo, Soichiro Okamura, Nobuhiro Kumada, Satoshi Wada
  • Publication number: 20110085282
    Abstract: An embodiment relates to a liquid composite dielectric material (LCDM) comprising a metal-containing dispersed phase material in an organic liquid phase material, wherein the liquid composite dielectric material has a dielectric permittivity (?r) of 10000 or more at 40 Hz and a dielectric loss (tan ?) of 1 or less at 40 Hz.
    Type: Application
    Filed: December 23, 2009
    Publication date: April 14, 2011
    Applicant: INDIAN INSTITUTE OF TECHNOLOGY MADRAS
    Inventors: Ramachandra M.S. RAO, Ramachandran B.
  • Patent number: 7923395
    Abstract: A dielectric ceramic composition in a multilayer ceramic capacitor with a composition of formula: {[(CaO)t(SrO)1-t]m[(ZrO2)v(TiO2)1-v]}1-s-xAsEx wherein: A is a transition metal oxide; E is an oxide of an element selected from the group consisting of Ge, Si, Ga and combination thereof; m is 0.98 to 1.02; t is 0.50 to 0.90; v is 0.8 to 1.0; s and x are selected from the group consisting of: a) 0?x?0.08, 0.0001?s?0.043 and x?1.86s; and b) 0?0.0533, 0.0001?s?0.08 and x?0.667s.
    Type: Grant
    Filed: October 22, 2007
    Date of Patent: April 12, 2011
    Assignee: Kemet Electronics Corporation
    Inventors: Michael S. Randall, Corey Antoniades, Daniel E. Barber, Xilin Xu, James Beeson, Pascal Pinceloup, Abhijit Gurav, Thomas Poole, Azizuddin Tajuddin, Ian Burn
  • Publication number: 20110077143
    Abstract: The invention is to provide a process capable of producing aluminium magnesium titanate having a small coefficient of thermal expansion at a firing temperature lower than 1500° C. The production process of the invention comprises maintaining a pre-mixture containing a titania source powder, an alumina source powder, a magnesia source powder and a silica source powder within a temperature range of from 1100° C. to 1350° C. for at least 3 hours, followed by heating up to a temperature not lower than 1400° C. and firing at the temperature. The silica source powder is preferably a powder of alkali feldspar. Aluminium magnesium titanate is prepared according to the production process of the invention, and the resulting aluminium magnesium titanate is ground to give an aluminium magnesium titanate powder.
    Type: Application
    Filed: January 19, 2009
    Publication date: March 31, 2011
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Tetsuro Tohma, Keiichiro Suzuki, Satoko Iwato, Rina Yamanaka
  • Patent number: 7916451
    Abstract: A dielectric ceramic composition in a multilayer ceramic capacitor with a composition of formula: {[(CaO)t(SrO)1-t]m[(ZrO2)v(TiO2)1-v]}1-s-xAsEx wherein: A is a transition metal oxide; E is an oxide of an element selected from the group consisting of Ge, Si, Ga and combinations thereof; m is 0.98 to 1.02; t is 0.50 to 0.90; v is 0.8 to 1.0; s and x are selected from the group consisting of: a) 0?x?0.08, 0.0001?s?0.043 and x?1.86s; and b) 0?x?0.0533, 0.0001?s?0.08 and x?0.667s.
    Type: Grant
    Filed: June 11, 2009
    Date of Patent: March 29, 2011
    Assignee: Kemet Electronics Corporation
    Inventors: Michael S. Randall, Corey Antoniades, Daniel E. Barber, Xilin Xu, James Beeson, Pascal Pinceloup, Abhijit Gurav, Thomas Poole, Azizuddin Tajuddin, Ian Burn
  • Patent number: 7914755
    Abstract: Wet-chemical methods involving the use of water-soluble hydrolytically stable metal-ion chelate precursors and the use of a nonmetal-ion-containing strong base can be used in a coprecipitation procedure for the preparation of ceramic powders. Examples of the precipitants used include tetraalkylammonium hydroxides. A composition-modified barium titanate is one of the ceramic powders that can be produced. Certain metal-ion chelates can be prepared from 2-hydroxypropanoic acid and ammonium hydroxide.
    Type: Grant
    Filed: March 7, 2006
    Date of Patent: March 29, 2011
    Assignee: EEStor, Inc.
    Inventors: Richard D. Weir, Carl W. Nelson
  • Patent number: 7910509
    Abstract: The invention intends to provide a dielectric porcelain composition for use in electronic devices, in which the relative dielectric constant ?r is high, the Qf value is high and, the temperature coefficient ?f can be controlled while maintaining the temperature coefficient ?f at the resonant frequency small and the Qf value high. According to the invention, when, in an LnAlO3—CaTiO3-based dielectric porcelain composition, a molar ratio of LnAlO3 and CaTiO3 is optimized and Al is substituted by a slight amount of Ga, a structure that has an LnAlO3—CaTiO3 solid solution as a main phase and a solid solution of Al—Ga-based oxide as a secondary phase and does not substantially contain ?-Al2O3 in the structure can be obtained, and the temperature coefficient ?f can be controlled while maintaining the temperature coefficient ?f at the resonant frequency small and the Qf value high.
    Type: Grant
    Filed: June 24, 2005
    Date of Patent: March 22, 2011
    Assignee: Hitachi Metals, Ltd.
    Inventors: Tomoyuki Tada, Kazuhiro Nishikawa, Kazuya Toji, Kazuhiro Kura, Takeshi Shimada
  • Patent number: 7911764
    Abstract: A dielectric ceramic contains a BaTiO3-based compound as a main ingredient, and can be represented by the general formula: 100AmBO3+aNiO+bROn+cMOv+dMgO+eXOw where R represents a rare earth element such as Dy, M represents a metal element such as Mn, and X represents a sintering aid component containing Si. Ni is uniformly solid-solved in crystal grains, and the solid-solution region of the rare earth element in the crystal grains is an average 10% or less in terms of a cross section ratio. 0.96?m?1.030, 0.05?a?3, 0.1?b?1.5, 0.1?c?1.0, 0.1?d?1.5, and 0.05?e?3.5 are satisfied. A laminated ceramic capacitor has dielectric layers formed of the dielectric ceramic. As a result, a dielectric ceramic, and a laminated ceramic capacitor having excellent AC voltage characteristics, capable of keeping desired dielectric characteristics and excellent temperature characteristics, and having excellent withstand voltage and capable of ensuring reliability can be realized.
    Type: Grant
    Filed: March 15, 2010
    Date of Patent: March 22, 2011
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Takehisa Sasabayashi, Tomoyuki Nakamura, Masayuki Ishihara, Takayuki Yao
  • Publication number: 20110053759
    Abstract: The present invention relates to a high dielectric constant paste composition comprising (A) inorganic particles having a perovskite crystal structure or a complex perovskite crystal structure, (B) a compound represented by any one of the general formulas (1) to (4) shown below, and (C) an organic solvent. The present invention provides a high dielectric constant paste composition for producing a high dielectric constant dielectric composition which has high insulation reliability and exhibits satisfactory resistance in a high-temperature high-humidity bias test.
    Type: Application
    Filed: January 14, 2009
    Publication date: March 3, 2011
    Applicant: Toray Industries ,Inc.
    Inventors: Yoichi Shimba, Yoshitake Hara, Tsukuru Mizuguchi, Toshihisa Nonaka
  • Patent number: 7898793
    Abstract: A multilayer ceramic capacitor having a laminate including alternately stacked dielectric layers of a sintered compact composed of crystal particles of a dielectric porcelain composite and internal-electrode layers. The dielectric porcelain composite comprises a primary constituent containing barium titanate; a first accessory constituent composed of at least one of MgO, CaO, BaO, and SrO; a second accessory constituent containing silicon oxide as a major constituent; a third accessory constituent composed of at least one of V2O5, MoO3, and WO3; a fourth accessory constituent composed of an oxide of R1 (wherein R1 is at least one of Sc, Er, Tm, Yb, and Lu); a fifth accessory constituent composed of CaZrO3 or a combination of CaO and ZrO2; and a sixth accessory constituent composed of an oxide of R2 (wherein R2 is at least one of Y, Dy, Ho, Tb, Gd, and Eu).
    Type: Grant
    Filed: February 23, 2005
    Date of Patent: March 1, 2011
    Assignee: TDK Corporation
    Inventors: Kazushige Ito, Haruya Hara, Toshihiro Iguchi, Shigeki Sato, Akira Sato, Takashi Kojima
  • Patent number: 7884042
    Abstract: An antiferroelectric ceramic material that can be formed into a multilayer capacitor is disclosed. The antiferroelectric ceramic material is selected from the Pb(Sn, Zr, Ti)O3 (PSnZT) composition family.
    Type: Grant
    Filed: July 16, 2010
    Date of Patent: February 8, 2011
    Assignee: TRS Technologies, Inc.
    Inventors: Wesley S. Hackenberger, Seongtae Kwon
  • Patent number: RE42352
    Abstract: The present invention provides a process for preparing a sintered body comprising as a basic component aluminum magnesium titanate represented by the composition formula: MgxAl2(1?x)Ti(1+x)O5 wherein the value of x is 0.1?x<1. The process comprises a step of sintering a formed product from a raw material mixture comprising 100 parts by weight, calculated on an oxide basis, of a mixture comprising a Mg-containing compound, an Al-containing compound and a Ti-containing compound at the same metal component ratio as the metal component ratio of Mg, Al and Ti in the above composition formula, and 1–10 parts by weight of an alkali feldspar represented by the composition formula: (NayK1?y)AlSi3O8 wherein the value of y is 0?y?1.
    Type: Grant
    Filed: October 9, 2003
    Date of Patent: May 10, 2011
    Assignee: Ohcera Co., Ltd.
    Inventors: Tsutomu Fukuda, Masahiro Fukuda, Masaaki Fukuda, Toshinobu Yoko, Masahide Takahashi