And Yttrium Or Rare Earth (i.e., Elements With Atomic Numbers 39 Or 57-71) Patents (Class 501/64)
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Patent number: 8598056Abstract: Described herein are alkali-free, boroalumino silicate glasses exhibiting desirable physical and chemical properties for use as substrates in flat panel display devices, such as, active matrix liquid crystal displays (AMLCDs). In accordance with certain of its aspects, the glasses possess good dimensional stability as a function of temperature.Type: GrantFiled: October 3, 2011Date of Patent: December 3, 2013Assignee: Corning IncorporatedInventors: Adam J. Ellison, Timothy J. Kiczenski
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Patent number: 8592333Abstract: A green light-emitting glass and the method of preparing the same are provided. The components with parts by mole of the green light-emitting glass are alkali oxide 25-40, Y2O3 0.01-15, SiO2 40-70, Tb2O3 0.01-15. The method of preparing the glass includes mixing alkali salt with Y2O3, SiO2 and Tb4O7, firing the mixture at 1200° C.-1500° C. for 1-5 hours, cooling the precursor to the room temperature and annealing the precursor in a reducing atmosphere at 600° C.-1200° C. for 1-20 hours. A green light-emitting glass with good transparence, high uniformity, easily being made into big bulk and high stability is provided. The process of capsulation of parts by using the glass is simple. And a method of preparing the glass with simple process and low cost is provided.Type: GrantFiled: March 25, 2009Date of Patent: November 26, 2013Assignee: Ocean's King Lighting Science & Technology Co., Ltd.Inventors: Mingjie Zhou, Wenbo Ma, Zhaopu Shi, Yanbo Qiao, Qingtao Li
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Publication number: 20130296157Abstract: Described herein are alkali-free, boroalumino silicate glasses exhibiting desirable physical and chemical properties for use as substrates in flat panel display devices, such as, active matrix liquid crystal displays (AMLCDs) and active matrix organic light emitting diode displays (AMOLEDs). In accordance with certain of its aspects, the glasses possess good dimensional stability as a function of temperature. The glasses comprise in mol percent on an oxide basis: 70-74.5 SiO2, 10.5-13.5 AL2O3, 0-2.5 B2O3, 3-7 MgO, 3-7 CaO, 0-4 SrO, 1.5-6 BaO, 0-0.3 SnO2, 0-03 CeO2, 0-0.5 As2O3, 0-0.5 Sb2O3, 0.01-0.08 Fe2O3 and F+Cl+BrRO/Al2O31.7 and 0.2MgO/RO0.45, RO being the sum of MgO, BaO, SrO and CaO.Type: ApplicationFiled: January 25, 2012Publication date: November 7, 2013Inventors: Adam J. Ellison, Timothy J. Kiczenski
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Publication number: 20130281281Abstract: A fusion formable and ion exchangeable silicate glass having a seed concentration of less than about 1 seed/cm3.Type: ApplicationFiled: June 19, 2013Publication date: October 24, 2013Inventors: Matthew John Dejneka, Sinue Gomez
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Patent number: 8551899Abstract: The present invention relates to a dark neutral green gray soda-lime glass composition comprising, as a colorant ingredient per 100 weight parts of a base glass composition, 1.4 to 2.5 weight parts of total Fe2O3, 0.02 to 0.04 weight parts of CoO, 0.0001 to 0.004 weight parts of Se, 0.005 to 0.5 weight parts of MnO2, and 0.05 to 1 weight parts of CeO2. The glass composition of the present invention has a visible light transmittance (LTA) of 15% or less, an ultraviolet ray transmittance (Tuv) of 0 to 1%, and a solar transmittance (Tsol) of 15% or less, measured for a reference thickness of 4 mm. As described above, the glass composition of the present invention is excellent in absorbing ultraviolet rays and solar heat, and therefore can be valuably used in privacy glass or a sunroof of a motor vehicle, or in glass used for construction.Type: GrantFiled: February 24, 2010Date of Patent: October 8, 2013Assignee: KCC CorporationInventors: Yong Yi Kim, Si Moo Lee, Seon Jin Kim, Jin Hyuk Lee
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Patent number: 8546282Abstract: A glass for a light guide fiber GA1 is used in a core of a fiber 10 of a light guide, and has a refractive index nd between 1.56 and 1.74. The glass for a light guide fiber GA1 has the following composition: (A) SiO2: 20 to 55 wt %, (B11) B2O3: 0 to 2.0 wt %, (B2) does not contain P2O5 and GeO2, (C1) (BaO+SrO+La2O3+Lu2O3+Ta2O5+Gd2O3+WO3): 39 to 46 wt %, (D1) ZnO: 4 to 16 wt %, (E) does not contain Al2O3, (F) does not contain ZrO2, (G) does not contain PbO and As2O3, (H1) (Na2O+K2O): 4 to 10 wt %, (I) Sb2O3: 0 to 0.050 wt %, and (J1) (Na2SO4+K2SO4): 0.32 to 0.78 wt %.Type: GrantFiled: April 27, 2012Date of Patent: October 1, 2013Assignees: Olympus Medical Systems Corp., Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek TnoInventors: Hiroaki Kinoshita, Anne Jans Faber, Mathi Rongen, Atsushi Goto, Makoto Tanabe, Yuko Katahira
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Patent number: 8536078Abstract: Lithium silicate glass ceramics and glasses containing at least 6.1 wt.-% ZrO2 are provided which can advantageously be applied to zirconium oxide ceramics in particular by pressing-on in the viscous state and forming a solid bond with the zirconium oxide ceramics.Type: GrantFiled: April 5, 2011Date of Patent: September 17, 2013Assignee: Ivoclar Vivadent AGInventors: Christian Ritzberger, Ricardo Dellagiacomo, Marcel Schweiger, Harald Burke, Wolfram Holand, Volker Rheinberger
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Publication number: 20130230692Abstract: Provided is a high refractive index glass, comprising, as a glass composition in terms of mass %, 0.1 to 60% of SiO2+Al2O3+B2O3, having a mass ratio (BaO+La2O3+Nb2O5+TiO2+ZrO2)/(SiO2+Al2O3+B2O3) of 0.1 to 50, amass ratio (MgO+CaO+SrO+BaO)/(BaO+La2O3+Nb2O5+TiO2+ZrO2) of 0 to 10, and a mass ratio (TiO2+ZrO2)/(BaO+La2O3+Nb2O5) of 0.001 to 40, and having a refractive index nd of 1.55 to 2.3.Type: ApplicationFiled: December 7, 2011Publication date: September 5, 2013Inventors: Tomoki Yanase, Takashi Murata
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Publication number: 20130225388Abstract: Provided is a Li2O—Al2O3—SiO2-based crystallizable glass characterized by comprising, as a glass composition in terms of mass %, 55 to 75% of SiO2, 19 to 24% of Al2O3, 3 to 4% of Li2O, 1.5 to 2.8% of TiO2, 3.8 to 4.8% of TiO2+ZrO2, and 0.1 to 0.5% of SnO2, and satisfying a relationship of 4?Li2O+0.741MgO+0.367ZnO?4.5.Type: ApplicationFiled: November 4, 2011Publication date: August 29, 2013Applicant: Nippon Electric Glass Co., Ltd.Inventors: Shingo Nakane, Kosuke Kawamoto
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Publication number: 20130202715Abstract: An aluminosilicate glass for touch screens is provided. The glass includes, calculated based on weight percentage: SiO2, 55 to 65%; Na2O, 12 to 17%; Al2O3, 15 to 20%; K2O, 2 to 6%; MgO, 3.9 to 10%; ZrO2, 0 to 5%; ZnO, 0 to 4%; CaO, 0 to 4%; Na2O+K2O+MgO+ZnO+CaO, 15 to 28%; SnO2, 0 to 1%; TiO2+CeO2, ?1%. A chemical strengthening method for glass also provided that includes ion exchange strengthening in a 100% KNO3 salt bath, wherein a preheating temperature ranges from 370° C. to 430° C. and the treatment time is from 0.5 to 16 hours.Type: ApplicationFiled: December 10, 2010Publication date: August 8, 2013Applicants: SCHOTT GLASS TECHNOLOGIES (SUZHOU) CO., LTD., SCHOTT AGInventors: Chong Wang, José Zimmer
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Patent number: 8467123Abstract: Disclosed is an optical fiber that includes a central core that is suitable for transmitting and amplifying an optical signal and an inner optical cladding that is suitable for confining the optical signal transmitted within the central core. The central core is formed from a core matrix that contains silica-based nanoparticles doped with at least one rare earth element. The disclosed optical fiber can be used with limited optical losses even in an environment with strong ionizing radiation.Type: GrantFiled: December 8, 2009Date of Patent: June 18, 2013Assignee: Draka Comteq B.V.Inventors: Elise Regnier, Alain Pastouret, Ekaterina Burov
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Patent number: 8466075Abstract: An optical glass comprising SiO2, B2O3 and La2O3 and one or more oxides selected from the group consisting of ZrO2, Nb2O5 and Ta2O5, having a refractive index of 1.83 or over and an Abbe number of 35 or over and being free of F.Type: GrantFiled: December 16, 2008Date of Patent: June 18, 2013Assignee: Kabushiki Kaisha OharaInventor: Koji Shimizu
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Patent number: 8455066Abstract: An insulating unit having a neutral grey color and a solar heat gain coefficient less than 0.40 includes a clear glass sheet spaced from a coated glass sheet. The coated glass sheet includes a colored glass substrate having a solar infrared reflective coating. The composition of the coated substrate includes a base glass portion and a glass colorant portion, the glass colorant portion including total iron in the range of 0.04 to less than 0.28 weight percent; CoO in the range of 32 to 90 parts per million, and Se in the range of greater than 0 to less than 5.5 parts per million. In one non-limiting embodiment of the invention the glass substrate at a thickness of 0.223 inches has a* chromaticity coordinates of ?3.5 to +2.5 and b* chromaticity coordinates of ?1 to ?15, and a visible light transmittance of 40 to 80%.Type: GrantFiled: August 20, 2012Date of Patent: June 4, 2013Assignee: PPG Industries Ohio, Inc.Inventors: Robert B. Heithoff, Glenn T. Miner
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Patent number: 8440583Abstract: A blue colored, infrared and ultraviolet absorbing glass composition uses a standard soda-lime-silica glass base composition and additionally iron, cobalt, and additional colorants selected from the group of Er2O3, Cr2O3, CuO, NiO, TiO2, Nd2O3 and combinations thereof. The glass of the present invention has a luminous transmittance of up to 60 percent, a dominant wavelength in the range of 480 to 489 nanometers and an excitation purity of at least 8 percent at a thickness of 0.160 inches (4.06 millimeters). The glass composition can form transparent glass panels that have varying limited LTA from one another as panel sets for mounting in automobiles.Type: GrantFiled: May 27, 2010Date of Patent: May 14, 2013Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, Mehran Arbab
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Publication number: 20130116108Abstract: The invention relates to a silica glass compound having improved physical and chemical properties. In one embodiment, the present invention relates to a silica glass having a desirable brittleness in combination with a desirable density while still yielding a glass composition having a desired hardness and desired strength relative to other glasses. In another embodiment, the present invention relates to a silica glass composition that contains at least about 85 mole percent silicon dioxide and up to about 15 mole percent of one or more dopants selected from F, B, N, Al, Ge, one or more alkali metals (e.g., Li, Na, K, etc.), one or more alkaline earth metals (e.g., Mg, Ca, Sr, Ba, etc.), one or more transition metals (e.g., Ti, Zn, Y, Zr, Hf, etc.), one or more lanthanides (e.g., Ce, etc.), or combinations of any two or more thereof.Type: ApplicationFiled: July 2, 2012Publication date: May 9, 2013Applicant: MOMENTIVE PERFORMANCE MATERIALS, INC.Inventors: Nathan J. Cassingham, Ben Matthew Gauthier, Martin Panchula, Robert Stephen Pavlik, Yan Zhou, Konstantin S. Zuyev
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Publication number: 20130090227Abstract: The technical task of the present invention is to provide a lead-free glass for semiconductor encapsulation, which is easy to automate an appearance inspection, and furthermore, has excellent refinability and encapsulatability of semiconductor devices. In the lead-free glass for semiconductor encapsulation according to the present invention, a temperature at which the viscosity of glass is 106 dPa·s is 670° C. or lower, and, as a glass composition, the content of CeO2 is from 0.01 to 6% by mass, and the content of Sb2O3 is 0.1% by mass or less.Type: ApplicationFiled: June 17, 2011Publication date: April 11, 2013Applicant: NIPPON ELECTRIC GLASS CO., LTD.Inventor: Koichi Hashimoto
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Patent number: 8415017Abstract: The present invention relates to a luminescent glass element comprising a luminescent glass substrate, which a metal layer is positioned on a surface thereof. The metal layer is provided with a metal microstructure. The luminescent glass substrate has composite oxides represented as the following formula: aM2O.bY2O3.cSiO2.dDy2O3, wherein M represents alkali metal element, a, b, c and d are, by mol part, 25-60, 1-30, 20-70 and 0.001-10 respectively. The present invention also provides a producing method of the luminescent glass element and a luminescing method thereof. The metal layer is positioned on the luminescent glass substrate, thereby improving luminescence efficiency of the luminescent glass substrate. The luminescent glass element can be used in luminescent devices with ultrahigh brightness or high-speed operation.Type: GrantFiled: September 9, 2011Date of Patent: April 9, 2013Assignee: Ocean's King Lighting Science & Technology Co., Ltd.Inventors: Mingjie Zhou, Wenbo Ma, Yugang Liu
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Publication number: 20130085058Abstract: An object of the present invention is to provide a Li2O—Al2O3—SiO2 based crystallized glass with excellent bubble quality even without using As2O3 or Sb2O3 as a fining agent and a method for producing the same. The Li2O—Al2O3—SiO2 based crystallized glass of the present invention is a Li2O—Al2O3—SiO2 based crystallized glass which does not substantially comprise As2O3 and Sb2O3 and comprises at least one of Cl, CeO2 and SnO2, and has a S content of not more than 10 ppm in terms of SO3.Type: ApplicationFiled: May 30, 2011Publication date: April 4, 2013Applicant: NIPPON ELECTRIC GLASS CO., LTD.Inventors: Shingo Nakane, Kosuke Kawamoto
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Patent number: 8404606Abstract: The lead-free and arsenic-free optical glasses have a refractive index of 1.83?nd?1.95 and an Abbé number of 24??d?35, good chemical resistance, excellent crystallization stability and a composition, in wt. % based on oxide content, of SiO2, 2-8; B2O3, 15-22; La2O3, 35-42; ZnO, 10-18; TiO2, 9-15; ZrO2, 3-10; Nb2O5, 4-10; and WO3, >0.5-3. Besides containing at most 5 wt. % of each of GeO2, Ag2O and BaO and conventional fining agents, they may also contain at most in total 5 wt. % of Al2O3, MgO, CaO, SrO, P2O5 and up to at most in total 5 wt. % of the components F, Ta2O5. The glasses are preferably free of alkali metal oxides, Bi2O3, Y2O3, Gd2O3 and/or Yb2O3. Optical elements made from the optical glass are also described.Type: GrantFiled: February 24, 2010Date of Patent: March 26, 2013Assignee: Schott AGInventors: Silke Wolff, Karl Mennemann, Uwe Kolberg, Ute Woelfel, Thomas Lifka
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Publication number: 20130059716Abstract: The invention relates to an alumino-silicate glass which has a thermal expansion coefficient in the range of 8 to 10×10?6/K in a temperature range of 20 to 300° C., a transformation temperature Tg in a range of 580° C. to 640° C., and a processing temperature VA in a range of 1065° C. to 1140° C. and which can therefore be used as an alternative for soda lime glasses. An object of the invention is also the use of the inventive glasses in applications where a high temperature stability of the glasses is advantageous, in particular as substrate glass, superstrate glass and/or cover glass in the field of semiconductor technology, preferably for Cd—Te or for CIS or CIGS photovoltaic applications and for other applications in solar technology.Type: ApplicationFiled: February 29, 2012Publication date: March 7, 2013Inventors: Jörg H. Fechner, Franz Ott, Erhard Dick, Christof Kass
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Publication number: 20130047672Abstract: Transparent, essentially colorless ?-quartz glass-ceramic materials, the composition of which is free of As2O3 and of Sb2O3, where said composition contains a specific combination of three nucleating agents: TiO2, ZrO2 and SnO2; TiO2 being present in low quantity.Type: ApplicationFiled: October 25, 2012Publication date: February 28, 2013Inventors: Marie Jacqueline Monique Comte, Lothar Wondraczek
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Patent number: 8383530Abstract: A glass substrate for a display, which is formed of a glass having a light weight and having high refinability with decreasing environmental burdens, the glass comprising, by mass %, 50 to 70% of SiO2, 5 to 18% of B2O3, 10 to 25% of Al2O3, 0 to 10% of MgO, 0 to 20% of CaO, 0 to 20% of SrO, 0 to 10% of BaO, 5 to 20% of RO (in which R is at least one member selected from the group consisting of Mg, Ca, Sr and Ba), and over 0.20% but not more than 2.0% of R?2O (in which R? is at least one member selected from the group consisting of Li, Na and K), and containing, by mass %, 0.05 to 1.5% of oxide of metal that changes in valence number in a molten glass, and substantially containing none of As2O3, Sb2O3 and PbO.Type: GrantFiled: June 15, 2010Date of Patent: February 26, 2013Assignee: Avanstrate Inc.Inventors: Junji Kurachi, Akihiro Koyama, Yoichi Hachitani
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Publication number: 20130045855Abstract: The invention relates to red-dyed glass, comprising the components of a base glass, coloring additives, reductants, and stabilizers, wherein the coloring additives comprise copper oxides and neodymium oxides and wherein the reductants comprise tin oxides and wherein the stabilizers comprise antimony oxides, wherein the fraction of the copper oxides in the red-dyed glass is between 0.02 and 0.08 weight percent.Type: ApplicationFiled: October 23, 2012Publication date: February 21, 2013Applicant: D. SWAROVSKI KGInventor: D. Swarovski KG
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Publication number: 20130037105Abstract: A compositional range of high strain point and/or intermediate expansion coefficient alkali metal free aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates or superstrates for photovoltaic devices, for example, thin film photovoltaic devices such as CdTe or CIGS photovoltaic devices or crystalline silicon wafer devices. These glasses can be characterized as having strain points ?600° C., thermal expansion coefficient of from 35 to 50×10?7/° C.Type: ApplicationFiled: August 8, 2012Publication date: February 14, 2013Inventors: Bruce Gardiner Aitken, James Edward Dickinson, JR., Timothy James Kiczenski, John Christopher Mauro, Adama Tandia
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Patent number: 8367574Abstract: The alkaline earth metal aluminosilicate glass for light bulbs with molybdenum parts has a composition (in percent by weight on an oxide basis) of SiO2, 56-60; Al2O3, 17-18; B2O3, 0.5-2; MgO, 0.5-2; CaO, >14-15.5; SrO, 0-3; BaO, 6-8; ZrO2, 0-5; CeO2, 0-0.1 and TiO2, 0-0.5.Type: GrantFiled: August 24, 2010Date of Patent: February 5, 2013Assignee: Schott AGInventors: Erhard Dick, Ingo Kipnik
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Patent number: 8361915Abstract: The present invention provides a glass composition having a base glass composition, comprising, in weight percentage, from about 0.005 to about 0.08% wt of ferric oxide, from 0.00002 to about 0.0004% wt of Se, from about 0.00003 to about 0.0010% wt of Co3O4, from 0 to about 0.01% wt of CuO, from about 0 to about 0.6 of CeO2, from 0.02 to about 1 of TiO2, and from about 0 to about 2 of NaNO3. The glass having a visible light transmission of at least 87%; a ultraviolet radiation transmittance less than 85%; and a solar direct transmittance of no more than 90%.Type: GrantFiled: May 22, 2009Date of Patent: January 29, 2013Assignee: Vidrio Plano de Mexico, S.A. de C.V.Inventors: José Guadalupe Cid-Aguilar, Roberto Marcos Cabrera-Llanos, Miguel Angel Kiyama-Rodriguez
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Patent number: 8361917Abstract: The invention relates to aluminoborosilicate-based glasses suitable for use as a solid laser medium. In particular, these aluminoborosilicate-based laser glasses exhibit broad emission bandwidths of rare earth lasing ions. Although not entirely understood, the broadening of the emission bandwidth is believed to be achieved by the presence of significant amounts of lanthanide ions in the glass matrix. In addition, because of the high values of Young's modulus, fracture toughness and hardness, the rare earth aluminoborosilicate glass system according to the invention is also suitable as transparent armor window material.Type: GrantFiled: August 5, 2010Date of Patent: January 29, 2013Assignee: Schott CorporationInventors: Hong Li, Carsten Weinhold
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Publication number: 20130017387Abstract: Disclosed are a phase separable glass compositions used to produce chemically durable porous glass, e.g., porous glass powder, and the application of a sol gel coating to the glass to enhance chemical durability of the glass in alkaline solutions, and to the use of the glass, e.g., glass powder, as substrates for separation technology where harsh alkaline environments (pH?12 e.g., pH 12-14) are routinely prevalent.Type: ApplicationFiled: July 12, 2011Publication date: January 17, 2013Inventors: William H. JAMES, III, Sally Pucilowski, Eric H. Urruti, Matthias Bockmeyer
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Publication number: 20130011695Abstract: To provide a substrate for information recording medium having various properties, in particular higher fracture toughness, required for application of the substrate for information recording medium of the next generation such as perpendicular magnetic recording system, etc. and a material with excellent workability for such purpose. A crystallized glass substrate for information recording medium, consisting of a crystallized glass which comprises one or more selected from RAl2O4 and R2TiO4 as a main crystal phase, in which R is one or more selected from Zn, Mg and Fe, and in which the main crystal phase has a crystal grain size in a range of from 0.5 nm to 20 nm, a degree of crystallinity of 15% or less, and a specific gravity of 3.00 or less.Type: ApplicationFiled: July 18, 2012Publication date: January 10, 2013Applicant: OHARA INC.Inventors: Toshitaka YAGI, Noyuki GOTO
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Publication number: 20130011607Abstract: Provided is a high refractive index glass, comprising, as a glass composition in terms of mass %, 0 to 10% of B2O2, 0.001 to 35% of SrO, 0.001 to 30% of ZrO2+TiO2, and 0 to 10% of La2O2+Nb2O5, having a mass ratio of BaO/SrO of 0 to 40 and a mass ratio of SiO2/SrO of 0.1 to 40, and having a refractive index nd of 1.55 to 2.3.Type: ApplicationFiled: May 18, 2012Publication date: January 10, 2013Inventors: Atsushi MUSHIAKE, Takashi MURATA, Tomoki YANASE
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Publication number: 20120319015Abstract: There is provided a glass composition containing an oxide containing Lu, Si, and Al, in which the composition of the glass composition lies within a compositional region of a ternary composition diagram of Lu, Si, and Al in terms of cation percent, the compositional region being defined by the following six points: (32.3% Lu03/2, 30.0% SiO2, 37.7% AlO3/2), (32.3% Lu03/2, 37.7% SiO2, 30.0% AlO3/2), (20.8% Lu03/2, 55.0% SiO2, 24.2% AlO3/2), (10.0% Lu03/2, 45.0% SiO2, 45.0% AlO3/2), (20.8% Lu03/2, 24.2% SiO2, 55.0% AlO3/2), and (30.0% Lu03/2, 25.0% SiO2, 45.0% AlO3/2). For the glass composition, a glassy state having low or no intrinsic birefringence in the ultraviolet region is stably obtained.Type: ApplicationFiled: February 23, 2011Publication date: December 20, 2012Applicant: CANON KABUSHIKI KAISHAInventors: Tomohiro Watanabe, Taihei Mukaide
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Publication number: 20120318356Abstract: A photovoltaic cell, for example a thin-film photovoltaic cell, having a substrate glass made of aluminosilicate glass, has a glass composition which has SiO2 and Al2O3 as well as the alkaline oxide Na2O and the alkaline earth oxides CaO, MgO, and BaO, and optionally further components. The glass composition includes 10 to 16 wt.-% Na2O, >0 to <5 wt.-% CaO, and >1 to 10 wt.-% BaO, and the ratio of CaO:MgO is in the range of 0.5 to 1.7. The aluminosilicate glass used is crystallization stable because of the selected quotient of CaO/MgO and has a transformation temperature >580° C. and a processing temperature <1200° C. Therefore, it represents a more thermally stable alternative to soda-lime glass. The aluminosilicate glass is used as a substrate glass, superstrate glass, and/or cover glass for a photovoltaic cells, for example for thin-film photovoltaic cells, in particular those based on semiconductor composite material, such as CdTe, CIS, or CIGS.Type: ApplicationFiled: July 27, 2012Publication date: December 20, 2012Inventors: Jörg Hinrich Fechner, Christof Kass, Franz Ott
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Publication number: 20120309607Abstract: The invention relates to glass-ceramics based on the lithium disilicate system which can be mechanically machined easily in an intermediate step of crystallisation and, after complete crystallisation, represent a very strong, highly-translucent and chemically-stable glass-ceramic. Likewise, the invention relates to a method for the production of these glass-ceramics. The glass-ceramics according to the invention are used as dental material.Type: ApplicationFiled: December 23, 2010Publication date: December 6, 2012Applicants: FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V., DEGUDENT GMBH, VITA ZAHNFABRIK H. RAUTER GMBH & CO. KGInventors: Bernhard Durschang, Jorn Probst, Norbert Thiel, Joachim Bibus, Markus Vollmann, Udo Schusser
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Patent number: 8318621Abstract: The invention relates to a glass sheet, the composition of which is of the soda-lime-silica type and comprises the following constituents in contents varying within the weight limits defined below: Fe2O3 (total iron) 0 to 0.02%; and WO3 0.1 to 2%.Type: GrantFiled: September 19, 2008Date of Patent: November 27, 2012Assignee: Saint-Gobain Glass FranceInventors: Dominique Sachot, Octavio Cintora-Gonzalez
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Patent number: 8304358Abstract: A soda-lime-silica glass for solar collector cover plates and solar mirrors has less than 0.010 weight percent total iron as Fe2O3, a redox ratio of less than 0.350, less than 0.0025 weight percent CeO2, and spectral properties that include a visible transmission, and a total solar infrared transmittance, of greater than 90% at a thickness of 5.5 millimeters, and reduced solarization. In one non-limiting embodiment of invention, the glass is made by heating a pool of molten soda-lime-silica with a mixture of combustion air and fuel gas having an air firing ratio of greater than 11, or an oxygen firing ratio of greater than 2.31. In another non-limiting embodiment of the invention, streams of oxygen bubbles are moved through a pool of molten glass. In both embodiments, the oxygen oxidizes ferrous iron to ferric iron to reduce the redox ratio.Type: GrantFiled: November 21, 2008Date of Patent: November 6, 2012Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, Ronald L. Shewenninger
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Publication number: 20120251743Abstract: A housing/enclosure/cover can include an ion-exchanged glass exhibiting the following attributes (1) radio, and microwave frequency transparency, as defined by a loss tangent of less than 0.03 and at a frequency range of between 15 MHz to 3.0 GHz; (2) infrared transparency; (3) a fracture toughness of greater than 0.6 MPa·m1/2; (4) a 4-point bend strength of greater than 350 MPa; (5) a Vickers hardness of at least 450 kgf/mm2 and a Vickers median/radial crack initiation threshold of at least 5 kgf; (6) a Young's Modulus ranging between about 50 to 100 GPa;; (7) a thermal conductivity of less than 2.0 W/m° C., and (9) and at least one of the following attributes: (i) a compressive surface layer having a depth of layer (DOL) greater and a compressive stress greater than 400 MPa, or, (ii) a central tension of more than 20 MPa.Type: ApplicationFiled: May 15, 2012Publication date: October 4, 2012Inventors: Jaymin Amin, Matthew John Dejneka, Linda Ruth Pinckney, Katherine Rose Rossington, Robert Sabia
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Publication number: 20120252652Abstract: A fusion formable and ion exchangeable silicate glass having a seed concentration of less than about 1 seed/cm3.Type: ApplicationFiled: June 13, 2012Publication date: October 4, 2012Inventors: Matthew John Dejneka, Sinue Gomez
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Patent number: 8268741Abstract: An insulating unit having a neutral grey color and a solar heat gain coefficient less than 0.40 includes a clear glass sheet spaced from a coated glass sheet. The coated glass sheet includes a colored glass substrate having a solar infrared reflective coating. The composition of the coated substrate includes a base glass portion and a glass colorant portion, the glass colorant portion including total iron in the range of 0.04 to less than 0.28 weight percent; CoO in the range of 32 to 90 parts per million, and Se in the range of greater than 0 to less than 5.5 parts per million. In one non-limiting embodiment of the invention the glass substrate at a thickness of 0.223 inches has a* chromaticity coordinates of ?3.5 to +2.5 and b* chromaticity coordinates of ?1 to ?15, and a visible light transmittance of 40 to 80%.Type: GrantFiled: March 28, 2007Date of Patent: September 18, 2012Assignee: PPG Industries Ohio, Inc.Inventors: Robert B. Heithoff, Glenn T. Miner
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Patent number: 8262877Abstract: Disclosed is a sensitive glass for use in a pH-sensitive glass electrode, which comprises at least Me2O3 (Me represents a lanthanoid) and further comprises Y2O3 or Sc2O3 in an amount smaller than that of the Me2O3. Also disclosed is a sensitive glass for use in a cation-sensitive glass electrode, which comprises at least Y2O3 or Sc2O3.Type: GrantFiled: September 6, 2007Date of Patent: September 11, 2012Assignee: HORIBA STEC, Co., Ltd.Inventors: Yasukazu Iwamoto, Yuji Nishio
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Publication number: 20120183785Abstract: High-temperature-resistant devitrifying solder glasses that contain 20-45 mol % BaO, 40-60 mol % SiO2, 0-30 mol % ZnO, 0-10 mol % Al2O3, 0-5 mol % BaF2, 0-2 mol % MgO, 0-2 mol % CaO, 0-2 mol % TiO2 and 0-10 mol % B2O3, as well as 0.5-4 mol % M2O3 (M=Y, La or rare earth metals) and/or 0.5-4 mol % ZrO2. The application, of said solder glasses are also disclosed.Type: ApplicationFiled: August 25, 2010Publication date: July 19, 2012Applicants: BORSIG PROCESS HEAT EXCHANGER GMBH, THYSSENKRUPP UHDE GMBHInventors: Steffen Schirrmeister, Bernd Langanke, Thomas Schiestel, Bjoern Hoting
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Publication number: 20120183812Abstract: Provided are a glass substrate for information recording media wherein air bubbles can be sufficiently removed, and an information recording medium using the glass substrate. The glass substrate contains 65 to 90 mass % of SiO2+Al2O3+B2O3 (where SiO2 is 45 to 75 mass %, Al2O3 is 1 to 20 mass %, and B2O3 is 0 to 8 mass %), 7 to 20 mass % of R2O (where R represents Li, Na, or K), 0.1 to 12 mass % of R?O (where R? represents Mg, Ca, Sr, Ba, or Zn), and 0.5 to 10 mass % of TiO2+ZrO2. Moreover, the glass substrate contains at least one multivalent element selected from among a group consisting of V, Mn, Ni, Mo, Sn, Ce, and Bi; the molar ratio of the total amount of the oxide of the multivalent element to the total amount of TiO2+ZrO2 is within the range of 0.05 to 0.50.Type: ApplicationFiled: September 6, 2010Publication date: July 19, 2012Inventor: Hiroshi Kajita
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Patent number: 8216671Abstract: The present invention relates to a luminescent glass element comprising a luminescent glass substrate, which a metal layer is positioned on a surface thereof. The metal layer is provided with a metal microstructure. The luminescent glass substrate has composite oxides represented as the following formula: aM2O.bY2O3.cSiO2.dCe2O3, wherein M represents alkali metal element, a, b, c and d are, by mol part, 25-60, 1-30, 20-70 and 0.001-10 respectively. The present invention also provides a producing method of the luminescent glass element and a luminescing method thereof. The metal layer is positioned on the luminescent glass substrate, thereby improving luminescence efficiency of the luminescent glass substrate. The luminescent glass element can be used in luminescent devices with ultrahigh brightness or high-speed operation.Type: GrantFiled: September 9, 2011Date of Patent: July 10, 2012Assignee: Ocean's King Lighting Science & Technology Co., Ltd.Inventors: Mingjie Zhou, Wenbo Ma, Yugang Liu
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Publication number: 20120148770Abstract: A high silica glass composition comprising about 82 to about 99.9999 wt. % SiO2 and from about 0.0001 to about 18 wt. % of at least one dopant selected from Al2O3, CeO2, TiO2, La2O3, Y2O3, Nd2O3, other rare earth oxides, and mixtures of two or more thereof. The glass composition has a working point temperature ranging from 600 to 2,000° C. These compositions exhibit stability similar to pure fused quartz, but have a moderate working temperature to enable cost effective fabrication of pharmaceutical packages. The glass is particularly useful as a packaging material for pharmaceutical applications, such as, for example pre-filled syringes, ampoules and vials.Type: ApplicationFiled: August 20, 2010Publication date: June 14, 2012Applicant: MOMENTIVE PERFORMANCE MATERIALS, INC.Inventors: Tianjun Rong, Samuel Conzone, Martin Lawrence Panchula
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Patent number: 8193108Abstract: A clad glass composition that is excellent in devitrification resistance and that prevents the whole mother glass rod from devitrifying by preventing a core glass composition from devitrifying in forming a mother glass rod using a concentric crucible drawing method, is provided. The clad glass composition forms a clad of a mother glass rod for a gradient-index rod lens having a core/clad structure.Type: GrantFiled: September 3, 2009Date of Patent: June 5, 2012Assignee: Nippon Sheet Glass Company, LimitedInventors: Teruhide Inoue, Kunihiro Nomiyama, Koichi Sakaguchi
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Publication number: 20120135851Abstract: To provide a high transmittance light-colored glass having a high Tva (at least 60%), a low Te (at most 60%), a low Pe (at most 6.0%) and ?d of from 560 to 780 nm or ?c of from ?550 to ?492 nm. A high transmittance light-colored glass comprising, as a glass matrix composition, SiO2: from 63 to 75 mass %, Al2O3: from 0 to 5 mass %, Na2O: from 5 to 15 mass %, K2O: from 0 to 5 mass %, CaO: from 5 to 15 mass %, and MgO: from 0 to 10 mass %, and as coloring components, Er2O3: from 0.3 to 3.0 mass %, t-Fe2O3: from 0.05 to 0.5 mass %, and Se: from 1 to 30 ppm, and having Redox: more than 62%.Type: ApplicationFiled: February 7, 2012Publication date: May 31, 2012Applicant: Asahi Glass Company, LimitedInventors: Shoshiro OKADA, Shuichi Akada
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Patent number: 8187715Abstract: A rare-earth-containing glass material having a composition, expressed in mole percentages on and oxide basis, comprising: SiO2: 66-75 Al2O3: 11-17 B2O3: 0-4 MgO: 1-6.5 CaO: 2-7 SrO: 0-4 BaO: 0-4 Y2O3: 0-4 La2O3: 0-4 Y2O3+La2O3: 0.1-4. The inclusion of Y2O3 and/or La2O3 in the composition reduces the T2.3 of the glass thereby allowing higher annealing-point glasses to be produced. The glass is particularly useful for low-temperature polycrystalline silicon-based semiconductor devices.Type: GrantFiled: May 12, 2009Date of Patent: May 29, 2012Assignee: Corning IncorporatedInventors: Paul Stephen Danielson, Matthew John Dejneka, Adam James Ellison, Timothy J Kiczenski
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Patent number: 8183170Abstract: Disclosed are CuX-containing, Nd2O3-containing, UV-absorbing and contrast-enhancing glasses and article comprising the same. The glass has improved UV-absorption and color enhancing capabilities compared to glasses described in the prior art. The glass can be used in sunglass lenses and light filters of information displays.Type: GrantFiled: October 11, 2007Date of Patent: May 22, 2012Assignee: Corning IncorporatedInventor: Yves Andre Henri Brocheton
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Patent number: 8178595Abstract: Zirconium-containing BaO- and PbO-free X-ray opaque glasses having a refractive index nd of about 1.480 to about 1.517 and a high X-ray opacity with an aluminum equivalent thickness of at least about 180% are provided. Such glasses are based on a SiO2—B2O3—Cs2O—K2O—La2O3 system with additions of Al2O3, Li2O, Na2O and/or ZrO2. Such glasses may be used, in particular, as dental glasses or as optical glasses.Type: GrantFiled: January 28, 2010Date of Patent: May 15, 2012Assignee: Schott AGInventors: Simone Monika Ritter, Oliver Hochrein, Sabine Pichler-Wilhelm
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Publication number: 20120107647Abstract: An aspect of the present invention relates to a glass substrate for a magnetic recording medium, which is comprised of glass comprising, denoted as molar percentages, 56 to 75 percent of SiO2, 1 to 11 percent of Al2O3, more than 0 percent but equal to or less than 4 percent of Li2O, equal to or more than 1 percent but less than 15 percent of Na2O, equal to or more than 0 percent but less than 3 percent of K2O, and substantially no BaO, with a total content of Li2O, Na2O, and K2O falling within a range of 6 to 15 percent, with a molar ratio (Li2O/Na2O) being less than 0.50, with a molar ratio {K2O/(Li2O+Na2O+K2O)} being equal to or less than 0.13, with a total content of MgO, CaO, and SrO falling within a range of 10 to 30 percent, with a total content of MgO and CaO falling within a range of 10 to 30 percent, with a molar ratio {(MgO+CaO)/(MgO+CaO+SrO)} being equal to or more than 0.Type: ApplicationFiled: November 8, 2010Publication date: May 3, 2012Applicant: HOYA CORPORATIONInventors: Naomi MATSUMOTO, Kinobu OSAKABE, Yoichi HACHITANI
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Patent number: 8168259Abstract: An article for use in aggressive environments is presented. In one embodiment, the article comprises a substrate and a self-sealing and substantially hermetic sealing layer disposed over the bondcoat. The substrate may be any high-temperature material, including, for instance, silicon-bearing ceramics and ceramic matrix composites. A method for making such articles is also presented. The method comprises providing a substrate; disposing a self-sealing layer over the substrate; and heating the sealing layer to a sealing temperature at which at least a portion of the sealing layer will flow.Type: GrantFiled: October 15, 2010Date of Patent: May 1, 2012Assignee: General Electric CompanyInventors: Reza Sarrafi-Nour, Krishan Lal Luthra, Peter Joel Meschter, Curtis Alan Johnson