And Boron Patents (Class 501/65)
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Patent number: 7157392Abstract: An alkali-free aluminoborosilicate glass having a coefficient of thermal expansion ?20/300 of between 2.8×10?6/K and 3.8×10?6/K, which has the following composition (in % by weight, based on oxide): silicon dioxide (SiO2)>58–65, boric oxide (B2O3)>6–11.5, magnesium oxide (MgO) 4–8, barium oxide (BaO) 0–<0.5, zinc oxide (ZnO) 0–2 and aluminum oxide (Al2O3)>14–25, calcium oxide (CaO) 0–8, strontium oxide (SrO) 2.6–<4, with barium oxide (BaO)+strontium oxide (SrO)>3, or aluminum oxide (Al2O3)>14–25, calcium oxide (CaO) 0–<2, strontium oxide (SrO)>0.5–<4, or aluminum oxide (Al2O3)>21–25, calcium oxide (CaO) 0–8, strontium oxide (SrO)>2.6–<8, with barium oxide (BaO)+strontium oxide (SrO)>3, and which is highly suitable for use as a substrate glass both in display technology and in thin-film photovoltaics.Type: GrantFiled: May 10, 2004Date of Patent: January 2, 2007Assignee: Schott GlasInventors: Ulrich Peuchert, Peter Brix
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Patent number: 7155934Abstract: The method of making borosilicate glass with a surface having reactive SiOH groups on it includes preparing a borosilicate glass melt and dissolving at least 30 mMol per liter of water in the borosilicate glass melt. The borosilicate glass contains from 70 to 87 percent by weight, SiO2; from 7 to 15 percent by weight, B2O3; from 0 to 8 percent by weight, Al2O3; from 0 to 8 percent by weight, Na2O and from 0 to 8 percent by weight of K2O. The borosilicate glass with the easily modified reactive surface can be used as a substrate for chemically covalent immobilization of reactive substances. This substrate can be used to make a biochemical chip, such as a DNA or gene chip, or dirt-proof window glass.Type: GrantFiled: November 18, 2002Date of Patent: January 2, 2007Assignee: Schott AGInventors: Gerhard Lauten-Schlaeger, Thomas Kloss, Sandra Von Fintel, Klaus Schneider
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Patent number: 7153797Abstract: The invention relates to an alkali-free aluminoborosilicate glass having a coefficient of thermal expansion ?20/300 of between 2.8 and 3.9·10?6/K, which has the following composition (in % by weight, based on oxide) : SiO2>58–65, B2O3>6–11.5; Al2O3>14–20, MgO>3–6, CaO>4.5–10, SrO 0–<1.5, BaO>1.5–6, or SrO 0–<4, BaO>2.5–6, respectively, with SrO+BaO>3, ZnO 0–<2, and which is highly suitable for use as a substrate glass both in display technology and in thin-film photovoltaics.Type: GrantFiled: June 1, 2004Date of Patent: December 26, 2006Assignee: Schott GlasInventor: Ulrich Peuchert
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Patent number: 7144835Abstract: The aluminum-free borosilicate glass has a composition in percent by weight based on oxide content of: SiO2, 65–77; B2O3, 7–20; Li2O, 0–2; Na2O, 0–4; K2O, 3–12; MgO, 0–2; CaO, 0–2; with MgO+CaO, 0–3; BaO, 0–3; ZnO, 0–2; ZrO2, 0.8–12; TiO2, 0–10; CeO2, 0–1; and F?, 0–0.6. This glass advantageously has a coefficient of thermal expansion ? (20° C.; 300° C.) of between 3.0×10?6/K and 6×10?6/K, good chemical resistance and a working point VA of between 990° C. and 1290° C.Type: GrantFiled: August 18, 2003Date of Patent: December 5, 2006Assignee: Schott AGInventors: Christof Kass, Jourg-Hinrich Fechner
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Patent number: 7144834Abstract: The invention concerns an optical colored glass with a composition (in percent by weight based on oxide) of SiO2 30–75; K2O 5–35; B2O3>4–17; ZnO 5–37; F 0.01–10; CdO 0.1–1, S+Se+Te 0.1–1.5 as well as the use of this glass as a long-pass cutoff filter.Type: GrantFiled: August 20, 2002Date of Patent: December 5, 2006Assignee: Schott AGInventors: Rolf Clasen, Monika Gierke, Jochen Freund, Magdalena Winkler-Trudewig, Uwe Kolberg
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Patent number: 7138348Abstract: An optical glass has optical constants which are an refractive index (nd) of 1.70–1.75 and an Abbe number (vd) of 45.0–54.0; a glass transformation temperature (Tg) of 500–580° C. The glass has the following composition in mass percent of: SiO2 more than 5–15%; B2O3 20-less than 30%; a total amount of SiO2+B2O3 more than 25–40%; La2O3 more than 21-less than 30%; Y2O3 more than 5–15%; Gd2O3 0-less than 10%; ZrO2 1–8%; Nb2O5 0.1–5%; Ta2O5 more than 5–12%; a total amount of ZrO2+Nb2O5+Ta2O5 7–20%; ZnO 0–10%; CaO 0–10%; SrO 0–5%; BaO 0–10%; a total amount of ZnO+CaO+SrO+BaO 5–15%; Li2O 1–8%; Sb2O3 0–1%; and As2O3 0–1%. The glass is substantially free of Yb2O3 and Al2O3. Devitrification is not generated when the optical glass is kept at a temperature of 920° C. for two hours.Type: GrantFiled: December 10, 2003Date of Patent: November 21, 2006Assignee: Kabushiki Kaisha OharaInventor: Susumu Uehara
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Patent number: 7102242Abstract: The lead-free glass tubing of the SiO2—B2O3—R2O—BaO—ZnO—TiO2 system has a composition, in percent by weight on an oxide basis, consisting essentially of: SiO2, 34 to 52; B2O3, 10 to 25; Al2O3, 0 to 25; Li2O, 2 to 6; Na2O, 4 to 10; K2O, 2 to 6; CaO, 0 to 4; BaO, 1 to 5; ZnO, 4 to 12; TiO2, 2 to 6, and at least one refining agent in an effective amount for refining. An encapsulated diode consisting of a diode encapsulated with this lead-free glass tubing is also disclosed.Type: GrantFiled: January 18, 2005Date of Patent: September 5, 2006Assignee: Schott AGInventors: Peter Brix, Helmar Vetter, Oliver Fritz
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Patent number: 7090937Abstract: Disclosed are a glass substrate for an information recording medium, having excellent scratch resistance and a light weight and having high fracture toughness, the glass substrate having a fragility index value, measured in water, of 12 ?m?1/2 or less or having a fragility index value, measured in an atmosphere having a dew point of ?5° C. or lower, of 7 ?m?1/2 or less, or the glass substrate comprising, by mol %, 40 to 75% of SiO2, 2 to 45% of B2O3 and/or Al2O3 and 0 to 40% of R?2O in which R? is at least one member selected from the group consisting of Li, Na and K), wherein the total content of SiO2, B2O3, Al2O3 and R?2O is at least 90 mol %, and a magnetic information recording medium comprising a magnetic recording layer formed on the glass substrate.Type: GrantFiled: March 29, 2004Date of Patent: August 15, 2006Assignee: Hoya CorporationInventors: Mikio Ikenishi, Atsuko Morita, Xuelu Zou
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Patent number: 7087543Abstract: An optical glass having a refractive index (nd) of 1.57 to 1.67, an Abbe's number (?d) of 55 to 65 and a glass transition temperature (Tg) of 560° C. or lower and having a low-temperature softening property and excellent climate resistance or a haze value of 3% or less, or an optical glass comprising, by mol %, 22 to 40% of B2O3, 12 to 40% of SiO2, 2 to 20% of Li2O, 5 to 15% of CaO, 2 to 14% of ZnO, 0.5 to 4% of La2O3, 0 to 3% of Gd2O3, 0 to 3% of Y2O3, the total content of La2O3, Gd2O3 and Y2O3 being at least 1%, 0 to 5% of Al2O3, 0 to 3% of ZrO2 and 0 to 5% of BaO, the total content of the above components being more than 96%, and having a refractive index (nd) of 1.57 to 1.67 and an Abbe's number (?d) of 55 to 65.Type: GrantFiled: June 30, 2003Date of Patent: August 8, 2006Assignee: Hoya CorporationInventors: Yoshiko Kasuga, Xuelu Zou
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Patent number: 7087307Abstract: The present invention provides a glass sheet formed on molten tin, that exhibits a high transmittance that is originally inherent to its composition. In this glass sheet, the difference between a visible light reflectance of a surface formed in contact with the molten tin and a visible light reflectance of a surface on the opposite side thereof is not greater than 0.25%. And when the glass sheet's thickness is 4 mm, a light transmittance at 540 nm wavelength is at least 91.5%, and a light transmittance at 450 nm wavelength is at least 91.0%, and after irradiating UV light for 6 hours as specified in the radiation-proofing test according to JIS R3212, a light transmittance at 540 nm wavelength is at least 91.0% and a light transmittance at 450 nm wavelength is at least 90.5%.Type: GrantFiled: December 27, 2002Date of Patent: August 8, 2006Assignee: Nippon Sheet Glass Company, LimitedInventors: Yukihito Nagashima, Masahiro Hirata, Akihiro Koyama, Akira Fujisawa
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Patent number: 7045475Abstract: Glass formulations, and a method of converting such glass formulations to glass beads having a refractive index of at least 1.59 and a high level of retroreflectivity, are provided. The methods and formulations provide beads also having high levels of resistance to degradation by environmental exposure.Type: GrantFiled: April 28, 2004Date of Patent: May 16, 2006Assignee: PQ CorporationInventors: Ufuk Senturk, Michael P. Lanci, Raymond Jackson, John W. Lau
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Patent number: 6989633Abstract: An alkaline-earth aluminosilicate glass having a composition (in % by weight, based on oxide) of SiO2>55-64; Al2O3 13-18; B2O3 0-5.5; M5O 0-7; CaO 5.5-14; SrO 0-8; BaO 6-17; ZrO2 0-2; CeO2 0-0.3; TiO2 0-0.5; CoO 0.01-0.035; Fe2O3 0.005-0.05; and NiO 0-0.Type: GrantFiled: February 3, 2003Date of Patent: January 24, 2006Assignee: Schott AGInventors: Christian Kunert, Karin Naumann, Franz Ott, Ottmar Becker
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Patent number: 6946415Abstract: An insulating ceramic composition includes a mixture of a ceramic powder containing MgAl2O4 and a glass powder containing 30-60% by mole of silicon oxide on the basis of SiO2 and 20-55% by mole of magnesium oxide on the basis of MgO, and the ceramic powder further includes Mg2SiO4 and TiO2. The insulating ceramic composition can be fired at 1000° C. and co-sintered with Ag and Cu. An insulating ceramic obtained by sintering the insulating ceramic composition has a high Q-factor and is therefore suitable for ceramic multilayer substrates used at high frequencies.Type: GrantFiled: March 26, 2002Date of Patent: September 20, 2005Assignee: Murata Manufacturing Co., Ltd.Inventors: Osamu Chikagawa, Sadaaki Sakamoto, Yoichi Moriya
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Patent number: 6936556Abstract: The present invention provides partially crystallizing lead-free and cadmium-free glass enamel composition that fuse at low temperatures. Glass enamel compositions according to the present invention form predominantly bismuth titanate and optionally zinc titanate crystals upon firing. Preferably, glass enamel compositions according to the invention include a glass component that includes by weight from about 11% to about 52% SiO2, from 10.2% to about 40% TiO2, from about 5% to about 75% Bi2O3, up to about 8% B2O3, up to about 14% BaO+SrO, and up to about 45% by weight ZnO, where the sum of Bi2O3 and ZnO comprises from about 30% to about 85% of the glass component by weight.Type: GrantFiled: April 7, 2003Date of Patent: August 30, 2005Assignee: Ferro CorporationInventors: Srinivasan Sridharan, George C. Korn, Jérôme Anquetil, Robert Blonski, Ivan H. Joyce
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Patent number: 6905990Abstract: The present invention provides a ceramic color composition which comprises, as a solid powder, 50 to 90 wt. % of a mixture containing 5 to 95 parts by weight of a first lead-free glass powder comprising at least SiO2, ZnO, and B2O3 as glass components, and 5 to 95 parts by weight of a second lead-free glass powder comprising at least SiO2, Bi2O3, and B2O3 as glass components, 10 to 40 wt. % of an inorganic pigment, and 0 to 10 wt. % of an inorganic filler. The composition is free of lead and exhibits an excellent mold release property during the heat-molding process of a glass plate having the composition printed thereon. After firing, the composition is excellent in acid resistance, coloration in the bus bar portion, and plating resistance.Type: GrantFiled: December 14, 2000Date of Patent: June 14, 2005Assignee: Okuno Chemical Industries Co., Ltd.Inventors: Shigehiro Sanichi, Yoshito Nokami
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Patent number: 6878464Abstract: A glass-ceramic composite material for use in forming a multilayered circuit substrate is provided which has a low dielectric constant, but exhibits a relatively high thermal expansion coefficient. Specifically, the glass-ceramic composite material comprises a glass power and a ceramic powder. The glass powder contains: about 30 to 60 mol % of SiO2, about 20 to 40 mol % of BaO, 0 to about 40 mol % of MgO, 0 to about 40 mol % of ZnO, 0 to about 20 mol % of B2O3, with the total content of MgO and ZnO being about 10 to 40 mol %. The ceramic powder contains an alumina powder. The content of the glass powder is set to be at least about 50 wt %. A sintered compact formed by sintering the above glass powder and the above ceramic powder contains a BaO.Al2O3.2SiO2 (BaAl2Si2O8) crystal, and its Q value becomes about 400 or more when a measured frequency is 10 GHz.Type: GrantFiled: October 22, 2002Date of Patent: April 12, 2005Assignee: Murata Manufacturing Co., Ltd.Inventors: Yoichi Moriya, Osamu Chikagawa, Yasutaka Sugimoto
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Patent number: 6867158Abstract: Flat panel liquid-crystal displays, such as for laptop computers. The displays include twisted nematic displays, supertwisted nematic displays, active matrix liquid-crystal displays, thin film transistor displays, and plasma addressed liquid-crystal displays. The displays are furnished with glass substrates. The glass substrates exhibit high resistance to thermal shock, a high transparency over a broad spectral range in the visible and ultra violet ranges and the glass being configured to be free of bubbles, knots, inclusions, streaks, and surface undulations, which glass substrates are made from alkali-free aluminoborosilicate glasses. There are also provided analogous thin-film photovoltaics.Type: GrantFiled: January 11, 2001Date of Patent: March 15, 2005Assignee: Schott GlasInventors: Ulrich Peuchert, Peter Brix
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Patent number: 6864197Abstract: The lead-free glass tubing of the SiO2—B2O3—R2O—BaO—ZnO—TiO2 system has a composition, in percent by weight on an oxide basis, consisting essentially of: SiO2, 34 to 52; B2O3, 10 to 25; Al2O3, 0 to 25; Li2O, 2 to 6; Na2O, 4 to 10; K2O, 2 to 6; CaO, 0 to 4; BaO, 1 to 5; ZnO, 4 to 12; TiO2, 2 to 6, and at least one refining agent in an effective amount for refining. An encapsulated diode consisting of a diode encapsulated with this lead-free glass tubing is also disclosed.Type: GrantFiled: October 10, 2002Date of Patent: March 8, 2005Assignee: Schott GlasInventors: Peter Brix, Helmar Vetter, Oliver Fritz
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Patent number: 6858552Abstract: The invention relates to an alkali-free aluminoborosilicate glass having a coefficient of thermal expansion ?20/300 of between 2.8 and 3.9·10?6/K, which has the following composition (in % by weight, based on oxide): SiO2>58-65, B2O3>6-11.5; Al2O3>14-20, MgO>3-6, CaO>4.5-10, SrO 0-<1.5, BaO>1.5-6, or SrO 0-<4, BaO >2.5-6, respectively, with SrO+BaO>3, ZnO 0-<2, and which is highly suitable for use as a substrate glass both in display technology and in thin-film photovoltaics.Type: GrantFiled: December 21, 2001Date of Patent: February 22, 2005Assignee: Schott GlasInventor: Ulrich Peuchert
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Patent number: 6852657Abstract: The invention concerns an optical colored glass of the composition (in % in weight on oxide basis) SiO2 50-62; K2O 10-25; Na2O 0-14; Al2O3 0-2; B2O3 3-5; ZnO 13.5-37; F 0-1; TiO2 0-7; In2O3 0-2; Ga2O3 0-2; SO3 0-1; SeO2 0-1; C 0-1; MIMIIIY2II 0.1-3, whereby MI=Cu+ and/or Ag+ and/or MIII=In3+ and/or Ga3+ and/or Al3+ and/or YII=S2? and/or Se2? and at least 0.1% in weight of the oxide (M2O3) of the MIII, which is/are present in MIMIIIYII2, and with at least 0.2% in weight of the oxide, of the YII, which is/are present in MIMIIIYII2.Type: GrantFiled: August 20, 2002Date of Patent: February 8, 2005Assignee: Schott GlasInventors: Uwe Kolberg, Ruediger Hentschel, Simone Ritter
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Patent number: 6852658Abstract: Flat panel liquid-crystal displays, such as for laptop computers. The displays include twisted nematic displays, supertwisted nematic displays, active matrix liquid-crystal displays, thin film transistor displays, and plasma addressed liquid-crystal displays. The displays are furnished with glass substrates. The glass substrates exhibit high resistance to thermal shock, a high transparency over a broad spectral range in the visible and ultra violet ranges and the glass being configured to be free of bubbles, knots, inclusions, streaks, and surface undulations, which glass substrates are made from alkali-free aluminoborosilicate glasses. There are also provided analogous thin-film photovoltaics.Type: GrantFiled: January 11, 2001Date of Patent: February 8, 2005Assignee: Schott GlasInventors: Ulrich Peuchert, Peter Brix
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Patent number: 6846762Abstract: An optical glass which is free of PbO which causes environmental pollution and also is free of expensive Ta2O5 and Nb2O5 comprises, in mass %, SiO2 40-60% B2O3 1 to less than 5% Al2O3 0-3% TiO2 15.5-19%?? ZrO2 0-1% WO3 0-5% ZnO 0-5% CaO 0-4% SrO 0-10% BaO 10.5-20%?? Na2O + K2O 11-20% in which Na2O 0-9% and K2O ?6-20% a refining agent 0-1% and has optical constants of a refractive index (nd) within a range from 1.55 to less than 1.67 and an Abbe number (?d) within a range from 30 to 45.Type: GrantFiled: March 31, 2003Date of Patent: January 25, 2005Assignee: Kabushiki Kaisha OharaInventors: Shinya Mashiko, Masahiro Onozawa
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Publication number: 20040242397Abstract: An optical glass that has a refractive index (nd) of 1.56-1.66, an Abbe number (vd) of 52-63, and a transformation temperature of 420° C.-580° C., as provided by compositions including as essential components (a) SiO2, (b) B2O3, (c) BaO, (d) Y2O3, (e) Li2O, and (f) one or more from CaO, MgO, SrO, and ZnO, and optionally one or more components from (g) Na2O, (h) K2O, (i) Al2O3, and (j) ZrO2.Type: ApplicationFiled: May 21, 2004Publication date: December 2, 2004Applicant: HIKARI GLASS CO., LTD.Inventor: Yoshiyuki Nakayama
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Patent number: 6818576Abstract: Disclosed are a glass substrate for an information recording medium, having excellent scratch resistance and a light weight and having high fracture toughness, the glass substrate having a fragility index value, measured in water, of 12 &mgr;m−1/2 or less or having a fragility index value, measured in an atmosphere having a dew point of −5° C. or lower, of 7 &mgr;m−1/2 or less, or the glass substrate comprising, by mol %, 40 to 75% of SiO2, 2 to 45% of B2O3 and/or Al2O3 and 0 to 40% of R′2O in which R′ is at least one member selected from the group consisting of Li, Na and K), wherein the total content of SiO2, B2O3, Al2O3 and R′2O is at least 90 mol %, and a magnetic information recording medium comprising a magnetic recording layer formed on the glass substrate.Type: GrantFiled: May 29, 2002Date of Patent: November 16, 2004Assignee: Hoya CorporationInventors: Mikio Ikenishi, Atsuko Morita, Xuelu Zou
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Patent number: 6818577Abstract: An optical waveguide element that can stably and inexpensively form an optical waveguide of low loss and low stress in a glass material by ion exchange of Ag ions, and to provide a process for producing the same are provided. The optical waveguide element is made of a multicomponent glass material, which is Na2O—B2O3—Al2O3—SiO2 glass containing from 5 to 13% by mole of Na2O, in which an optical waveguide is formed by doping with Ag ions by ion exchange. The composition is preferably SiO2: 60 to 75% by mole, B2O3: 10 to 20% by mole, Al2O3: 2 to 10% by mole, Na2O: 5 to 13% by mole, Li2O: 0 to 1% by mole, As2O3: 0 to 0.5% by mole, and Sb2O3: 0 to 0.5% by mole (provided that As2O3+Sb2O3: 0.01 to 1% mole).Type: GrantFiled: November 20, 2002Date of Patent: November 16, 2004Assignee: FDK CorporationInventors: Yasuhiro Anma, Tomoyuki Hayashi, Junko Ishizu, Tatsushi Kunou
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Patent number: 6764972Abstract: A compositional range for a mother glass composition for graded index lenses which has a desired refractive index and is less apt to be devitrified and to develop cracks upon ion exchange was obtained by incorporating at least a given amount of one or more ingredients which are selected from oxides of metal elements ranging from yttrium, atomic number 39, to tantalum, atomic number 73, and which are less apt to cause glass coloration into a glass based on SiO2—TiO2—Li2O—Na2O and containing no lead oxide. In particular, a compositional range in which a large angular aperture is obtained and devitrification is less apt to occur was obtained by incorporating Ta2O5 and ZrO2 in a specific proportion and in specific amounts.Type: GrantFiled: October 11, 2001Date of Patent: July 20, 2004Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Tetsuro Yoshii, Jun Yamaguchi
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Publication number: 20040132604Abstract: A borosilicate glass, having a spectral edge situation in a UV range of 280 to 325 nm, which can be set in a simple and defined manner, with the composition in percent by weight on an oxide basis of 60-75% SiO2, 10-15% B2O3, 5-15% Na2O, 5-10% K2O, 0-5% Li2O, 0.1-1 CaO, 0.5-3% BaO, >0-1.7% TiO2, 0-0.5% Sb2O3, and normal refining agents.Type: ApplicationFiled: September 30, 2003Publication date: July 8, 2004Inventors: Steffen Grun, Johann Faderl, Simone Ritter
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Publication number: 20040132605Abstract: There is provided an optical glass suitable for mold pressing having optical constants of a refractive index (nd) within a range from 1.60 to 1.69 and Abbe number (&ngr;d) within a range from 35 to 45, having a glass transition point (Tg) within a range from 300° C. to 500° C., being free from devitrification when the optical glass is held at a temperature which is higher by 100° C.Type: ApplicationFiled: December 17, 2003Publication date: July 8, 2004Inventor: Susumu Uehara
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Publication number: 20040079258Abstract: The invention relates to the use of ions of weakly basic oxides as linking ions for polyacids in cements, preferably polyelectrolyte cements. Suitable ions comprise elements of the scandium series, for example, Sc3+, Y3+, La3+, Ce4+ and all subsequent tri- and tetra-valent lanthanides and the ions Mg2+, Zn2+, Ga2+, In2+. The application of said ions permits a regulation of the cement reaction without surface treatment of the glass powder.Type: ApplicationFiled: December 8, 2003Publication date: April 29, 2004Inventors: Stefan Hoescheler, Markus Mikulla, Gabriele Rackelmann, Volker Bambach
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Publication number: 20040053766Abstract: Disclosed herein are a self-foamed porous ceramic composition and a method for making a porous ceramic using the self-foamed porous ceramic composition. The self-foamed porous ceramic is obtained by fabricating a glass consisting of 41˜47 mole % of calcium oxide (CaO), 41˜47 mole % of silica (SiO2) and 6˜18 mole % of borate (B2O3), pulverizing the glass into a finely-divided glass powder having an average particle size of 1˜10 &mgr;m, molding the glass powder, and sintering the molded glass powder.Type: ApplicationFiled: August 27, 2003Publication date: March 18, 2004Inventors: Hyun Seung Yu, Kug Sun Hong, Hwan Kim, Dong Ho Lee, Choon Ki Lee, Bong Soon Chang, Deug Joong Kim, Jun Hyuk Seo, Jae Hyup Lee, Ki Soo Park
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Patent number: 6677046Abstract: A glass ceramic having properties of low thermal expansion, high transmittance in a visible light region and low specific gravity, and a glass ceramic substrate made of the glass ceramic are provided. The glass ceramic has a crystal phase containing a &bgr;-quartz solid solution precipitated by heat treatment of a matrix glass for a glass ceramic, and the matrix glass has a glass composition comprising 55 to 70 mol % of SiO2, 13 to 23 mol % of Al2O3, 11 to 21 mol % of an alkali metal oxide, provided that the alkali metal oxide contains 10 to 20 mol % of Li2O and contains 0.1 to 3 mol % of Na2O and K2O in total, 0.1 to 4 mol % of TiO2 and 0.1 to 2 mol % of ZrO2, the total content of said components being at least 95 mol %, and further comprising 0 to less than 0.2 mol % of BaO, 0 to less than 0.1 mol % of P2O5, 0 to less than 0.3 mol % of B2O3 and 0 to leas than 0.1 mol % of SnO2.Type: GrantFiled: March 27, 2002Date of Patent: January 13, 2004Assignee: Hoya CorporationInventors: Yoichi Hachitani, Keiji Hosoda, Kenji Matsumoto
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Patent number: 6667256Abstract: When ceramic electronic parts such as multilayer ceramic substrates that have a substrate body and metal wiring conductors comprising silver are manufactured, a composition comprising not only a borosilicate glass powder and a ceramic powder, but also an additive powder comprising at least one of cerium oxide, bismuth, bismuth oxide, antimony and antimony oxide is used as a composition for preparing the substrate body. Gray discoloration of the substrate body and yellow discoloration in the vicinities of the metal wiring conductors can be prevented.Type: GrantFiled: May 2, 2003Date of Patent: December 23, 2003Assignee: Murata Manufacturing Co., Ltd.Inventor: Kenji Masuko
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Patent number: 6667259Abstract: An optical colored glass with a composition (in percent by weight based on oxide) of SiO2 30-75; K2O 5-35; TiO2 0-5; B2O3>4-17; ZnO 5-37; F 0.01-10 MIMIIIY2II 0.1-3, whereby MI=Cu+, Ag+, MIII=In3+, Ga3+, Al3+, YII=S2−, Se2−, Te2−, as well as the use of this glass as a long-pass cutoff filter.Type: GrantFiled: August 20, 2002Date of Patent: December 23, 2003Assignee: Schott GlasInventors: Rolf Clasen, Monika Gierke, Jochen Freund, Simone Ritter, Uwe Kolberg
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Publication number: 20030203803Abstract: The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods.Type: ApplicationFiled: May 19, 2003Publication date: October 30, 2003Inventors: Carol M. Jantzen, John B. Pickett, Connie A. Cicero-Herman, James C. Marra
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Publication number: 20030199383Abstract: An optical glass having a positive anomalous dispersion comprises, in mass %, 1 SiO2 40-60% B2O3 3-9% TiO2 3-15% Nb2O5 0.1-5.0% Al2O3 3-15% WO3 0.5-5.Type: ApplicationFiled: April 7, 2003Publication date: October 23, 2003Inventors: Junko Ishioka, Masahiro Onozawa
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Publication number: 20030191007Abstract: An optical glass which is free of PbO which causes environmental pollution and also is free of expensive Ta2O5 and Nb2O5 comprises, in mass %, 1 SiO2 40-60% B2O3 1 to less than 5% Al2O3 0-3% TiO2 15.5-19% ZrO2 0-1% WO3 0-5% ZnO 0-5% CaO 0-4% SrO 0-10% BaO 10.Type: ApplicationFiled: March 31, 2003Publication date: October 9, 2003Inventors: Shinya Mashiko, Masahiro Onozawa
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Patent number: 6610621Abstract: When ceramic electronic parts such as multilayer ceramic substrates that have a substrate body and metal wiring conductors comprising silver are manufactured, a composition comprising not only a borosilicate glass powder and a ceramic powder, but also an additive powder comprising at least one of cerium oxide, bismuth, bismuth oxide, antimony and antimony oxide is used as a composition for preparing the substrate body. Gray discoloration of the substrate body and yellow discoloration in the vicinities of the metal wiring conductors can be prevented.Type: GrantFiled: November 28, 2001Date of Patent: August 26, 2003Assignee: Murata Manufacturing Co., Ltd.Inventor: Kenji Masuko
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Publication number: 20030158029Abstract: An optical colored glass with a composition (in percent by weight based on oxide) of SiO2 30-75; K2O 5-35; TiO2 0-5; B2O3>4-17; ZnO 5-37; F 0.01-10 MI MIII Y2II 0.1-3, whereby MI=Cu+, Ag+, MIII=In3+, Ga3+, Al3+, YII=S2−, S2−, Te2−, as well as the use of this glass as a long-pass cutoff filter.Type: ApplicationFiled: August 20, 2002Publication date: August 21, 2003Inventors: Rolf Clasen, Monika Gierke, Jochen Freund, Simone Ritter, Uwe Kolberg
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Publication number: 20030153451Abstract: The invention concerns an optical colored glass with a composition (in percent by weight based on oxide) ofType: ApplicationFiled: August 20, 2002Publication date: August 14, 2003Inventors: Rolf Clasen, Monika Gierke, Jochen Freund, Magdalena Winkler-Trudewig, Uwe Kolberg
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Patent number: 6602946Abstract: A photosensitive insulating paste contains a borosilicate glass powder and a crystalline SiO2 powder, wherein the powders are dispersed in a photosensitive organic vehicle and the paste contains the crystalline SiO2 component in an amount of about 3-40 wt. % after sintering. A thick-film multi-layer circuit substrate (e.g., chip inductor) comprising an insulating substrate on which insulating layers are formed, wherein the insulating layers are formed through exposure, development and sintering, after the application of the photosensitive insulating paste.Type: GrantFiled: July 26, 2001Date of Patent: August 5, 2003Assignee: Murata Manufacturing Co.Inventors: Makoto Tose, Hiromichi Kawakami, Shizuharu Watanabe
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Publication number: 20030114292Abstract: The invention concerns an optical colored glass of the composition (in % in weight on oxide basis) SiO2 50-62; K2O 10-25; Na2O 0-14; Al2O3 0-2; B2O3 3-5; ZnO 13.5-37; F 0-1; TiO2 0-7; In2O30-2; Ga2O3 0-2; SO30-1; SeO20-1; C 0-1; MIMIIIY2II 0.1-3, whereby MI=Cu+ and/or Ag+ and/or MIII=In3+ and/or Ga3+ and/or Al3+ and/or YII═S2− and/or Se2− and at least 0.1% in weight of the oxide (M2O3) of the MIII, which is/are present in MIMIIIYII2, and with at least 0.2% in weight of the oxide, of the YII, which is/are present in MIMIIIYII2.Type: ApplicationFiled: August 20, 2002Publication date: June 19, 2003Inventors: Uwe Kolberg, Ruediger Hentschel, Simone Ritter
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Patent number: 6579636Abstract: A high temperature oxidation resistant coating performs a self-repairing function of self-repairing the cracks under a heated environment and has low catalytic properties. The high temperature oxidation resistant coating is prepared by dispersing silicate particles containing a composite oxide consisting of an oxide of a lanthanoide series rare earth element including yttrium and silicon oxide into a glass-based matrix.Type: GrantFiled: September 12, 2001Date of Patent: June 17, 2003Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Kazuyuki Oguri, Takahiro Sekigawa
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Patent number: 6562523Abstract: A narrowly defined range of zinc silicate glass compositions is found to produce High Energy Beam Sensitive-glass (HEBS-glass) that possesses the essential properties of a true gray level mask which is necessary for the fabrication of general three dimensional microstructures with one optical exposure in a conventional photolithographic process. The essential properties are (1) A mask pattern or image is grainiless even when observed under optical microscope at 1000× or at higher magnifications. (2) The HEBS-glass is insensitive and/or inert to photons in the spectral ranges employed in photolithographic processes, and is also insensitive and/or inert to visible spectral range of light so that a HEBS-glass mask blank and a HEBS-glass mask are permanently stable under room lighting conditions. (3) The HEBS-glass is sufficiently sensitive to electron beam exposure, so that the cost of making a mask using an e-beam writer is affordable for many applications.Type: GrantFiled: February 18, 2000Date of Patent: May 13, 2003Assignee: Canyon Materials, Inc.Inventors: Che-Kuang Wu, Laurie Ann Wu
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Publication number: 20030087744Abstract: Panel glass, for a cathode ray tube, which has an SrO/(SrO+BaO) ratio of from 0.35 to 0.70, an X-ray absorption coefficient of 36.0 cm−1 or more at the wavelength of 0.6 angstrom, wherein Na2O/R2O, K2O/R2O and Li2O/R2O (R2O: Na2O+K2O+Li2O) molar ratios fall within a range surrounded by the points A (0, 0.2, 0.8), B (0.2, 0.2, 0.6), C (0.4, 0.6, 0), D (0.2, 0.8, 0) and E (0, 0.4, 0.6) in the ternary phase diagram as shown in FIG. 1.Type: ApplicationFiled: October 23, 2002Publication date: May 8, 2003Inventors: Hiroshi Komori, Hiroki Yamazaki
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Patent number: 6544654Abstract: A thick-film resistor contains RuO2 and an SiO2—B2O3—K2O glass having a composition of 60 wt %≦SiO2≦85 wt %, 15 wt %≦B2O3≦40 wt %, 0.1 wt %≦K2O≦10 wt %, and impurity ≦3 wt %. A ceramic circuit board includes a thick-film resistor printed on it, the thick-film resistor containing RuO2 and an SiO2—B2O3—K2O glass having the above composition.Type: GrantFiled: October 27, 2000Date of Patent: April 8, 2003Assignee: Sumitomo Metal (SMI) Electronics Devices, Inc.Inventors: Masashi Fukaya, Koji Shibata, Chiaki Higuchi, Yoshinobu Watanabe
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Publication number: 20030064875Abstract: A polarizing glass comprising geometrically anisotropic particles dispersed in an oriented manner in at least the surface of a glass base body. The glass base body is denoted by the weight percentages of 50-65 percent SiO2, 15-22 percent B2O3, 0-4 percent Al2O3, 2-8 percent ZrO2, 6 percent <Al2O3+ZrO2<12 percent, 6-16 percent R2O (where R denotes at least one from among Li, Na, and K), 0-3 percent Li2O, 0-9 percent Na2O, 4-16 percent K2O, Li2O+Na2O<K2O, 0-7 percent BaO and/or SrO, and 0-3 percent TiO2. The glass base body comprises per 100 weight percent of essentially the above composition at least 0.15-1.0 percent Ag and at least the chemical equivalent to Ag of Cl and/or Br; and the geometrically anisotropic silver particles are metallic Ag particles. The polarizing glass is employed in optical products such as optical isolators.Type: ApplicationFiled: January 2, 2002Publication date: April 3, 2003Applicant: HOYA CORPORATIONInventors: Toshiharu Yamashita, Yoshitaka Yoneda
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Publication number: 20030064874Abstract: The present invention provides a composition for use in forming an opaque porcelain enamel coating on a metal substrate. A porcelain enamel coating formed using a composition according to the invention readily adheres to metal substrates such as, for example, steel, that are degreased-only. Furthermore, such a porcelain enamel coating displays an acid resistance of A according to ISO 2722 and good easy-to-clean properties. The composition according to the invention includes a glass component including by weight from about 45% to about 55% SiO2, from about 8% to about 17% B2O3, from about 1.8% to about 17.7% SrO+BaO, from about 1.9% to about 10% Li2O, up to about 6% ZrO2, from about 2% to about 11% TiO2, from about 1.5% to about 6% K2O, from about 1% to about 4% MoO3, from about 0.3% to about 13% Na2O, up to about 2% NiO, up to about 3% Al2O3, up to about 2.9% MnO, up to about 0.8% CoO, up to about 3% MgO, up to about 5% CaO, and up to about 2% Sb2O3.Type: ApplicationFiled: April 8, 2002Publication date: April 3, 2003Applicant: Ferro France - S.A.R.L.Inventors: Jean-Christophe Eckmann, Moha Ait Ali Oumoumene, Francois Roques
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Patent number: 6515795Abstract: A borosilicate glass composition comprises SiO2 having a concentration of about 40 mole percent to about 60 mole percent, B2O3 having a concentration of about 10 mole percent to about 30 mole percent, and an alkaline earth and/or alkali compound having a concentration of 10 mole percent to about 40 mole percent. An optical fiber amplification device comprises a borosilicate glass material cladding. The core comprises a germanate glass material doped with Tm3+. The germanate glass material has a first surface configured to receive an optical signal having a wavelength of from about 1400 nm to about 1540 nm and a second surface configured to output an amplified optical signal. In this manner, low cost fiber amplifiers in the 1450-1530 nm wavelength region (corresponding to the S-band) can be achieved.Type: GrantFiled: June 29, 2001Date of Patent: February 4, 2003Assignee: Corning IncorporatedInventors: Matthew J. Dejneka, Ji Wang
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Patent number: 6514893Abstract: High-strength sinterable lithium disilicate glass ceramics are described which can be further processed in particular by pressing in the viscous state to shaped dental products.Type: GrantFiled: October 19, 1999Date of Patent: February 4, 2003Assignee: Ivoclar AGInventors: Marcel Schweiger, Martin Frank, Volker Rheinberger, Wolfram Hoeland
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Patent number: 6511932Abstract: A graded index lens is obtained by treating a raw glass material having a rod shape by ion exchange using silver to form a refractive index distribution in the radial direction of the rod, wherein the raw glass material comprises a glass composition of the following components: 15<Na2O≦30 mol %; 10<Al2O3≦25 mol %; 27.5≦SiO2≦55 mol %; 3≦B2O3≦18 mol %; 2.5≦MgO≦18 mol %; 0≦Ta2O5≦5 mol %; 0≦La2O3≦3 mol %; 0≦BaO≦3 mol %; and 0≦ZrO2≦3 mol %.Type: GrantFiled: December 1, 2000Date of Patent: January 28, 2003Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Jun Yamaguchi, Shigeo Kittaka