And Aluminum Or Iron Compound Patents (Class 501/68)
  • Publication number: 20140099501
    Abstract: There is provided a glass for chemical strengthening having a black color tone and excelling in characteristics preferred for the purposes of housing or decoration of an electronic device, that is, bubble quality, strength, and light transmittance characteristics. A glass for chemical strengthening contains, in mole percentage based on following oxides, 55% to 80% of SiO2, 3% to 16% of Al2O3, 0% to 12% of B2O3, 5% to 16% of Na2O, 0% to 4% of K2O, 0% to 15% of MgO, 0% to 3% of CaO, 0% to 18% of ?RO (where R represents Mg, Ca, Sr, Ba or Zn), 0% to 1% of ZrO2, and 0.1% to 7% of a coloring component having at least one metal oxide selected from the group consisting of oxides of Co, Mn, Fe, Ni, Cu, Cr, V and Bi.
    Type: Application
    Filed: September 17, 2013
    Publication date: April 10, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Hiroyuki YAMAMOTO, Kazuhide KUNO
  • Patent number: 8691711
    Abstract: Glass for a display device, which comprises, as represented by mole percentage based on the following oxides, from 61 to 72% of SiO2, from 8 to 17% of Al2O3, from 6 to 18% of Li2O, from 2 to 15% of Na2O, from 0 to 8% of K2O, from 0 to 6% of MgO, from 0 to 6% of CaO, from 0 to 4% of TiO2, and from 0 to 2.5% of ZrO2, and having a total content R2O of Li2O, Na2O and K2O of from 15 to 25%, a ratio Li2O/R2O of the Li2O content to R2O of from 0.35 to 0.8, and a total content of MgO and CaO of from 0 to 9%.
    Type: Grant
    Filed: May 25, 2011
    Date of Patent: April 8, 2014
    Assignee: Asahi Glass Company, Limited
    Inventors: Tetsuya Nakashima, Seiki Ohara, Tatsuo Nagashima
  • Patent number: 8685873
    Abstract: A lithium-aluminosilicate glass or a corresponding glass ceramic that has a content of 0-0.4SnO2, 1.3-2.7% by weight of ?SnO2+TiO2, 1.3-2.5% by weight of ZrO2, 3.65-4.3% by weight of ?ZrO2+0.87 (TiO2+SnO2), ?0.04% by weight of Fe2O3, 50-4000 ppm of Nd2O3 and 0-50 ppm of CoO is described. The glass or the glass ceramic is color-neutral, has a turbidity of less than 1% HAZE and a high light transmission. The glazing time for conversion of the glass into glass ceramic is especially short with less than 2.5 hours.
    Type: Grant
    Filed: August 6, 2012
    Date of Patent: April 1, 2014
    Assignee: Schott AG
    Inventors: Friedrich Siebers, Ulrich Schiffner, Wolfgang Schmidbauer, Klaus Schonberger
  • Patent number: 8679631
    Abstract: A tempered glass substrate of the present invention is a tempered glass substrate, which has a compression stress layer on a surface thereof, and has a glass composition comprising, in terms of mass %, 40 to 71% of SiO2, 3 to 21% of Al2O3, 0 to 3.5% of Li2O, 7 to 20% of Na2O, and 0 to 15% of K2O.
    Type: Grant
    Filed: September 2, 2011
    Date of Patent: March 25, 2014
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventor: Takashi Murata
  • Patent number: 8664130
    Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit ?-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 Si O2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; and 0.05-0.2 SnO2. Additionally, these glasses and glass-ceramics exhibit the following criteria: a. a ratio: [ Li 2 ? O + Na 2 ? O + K 2 ? O + MgO + ZnO ] [ Al 2 ? O 3 + B 2 ? O 3 ] between 0.7 to 1.5; b. a ratio: [ TiO 2 + SnO 2 ] [ SiO 2 + B 2 ? O 3 ] greater than 0.04. Furthermore, the glass-ceramics exhibit an opacity ?about 85% over the wavelength range of 400-700 nm for an about 0.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: March 4, 2014
    Assignee: Corning Incorporated
    Inventors: George Halsey Beall, Marie Jacqueline Monique Comte, George Owen Dale, Linda Ruth Pinckney, Charlene Marie Smith, Ronald Leroy Stewart, Steven Alvin Tietje
  • Patent number: 8652979
    Abstract: Provided is a glass substrate satisfying ion exchange performance and devitrification resistance of a glass simultaneously and having higher mechanical strength compared to a conventional glass substrate. A tempered glass substrate which has a compression stress layer on a surface thereof, has a glass composition including, in terms of mole %, 50 to 85% of SiO2, 5 to 30% of Al2O3, 0 to 20% of Li2O, 0 to 20% of Na2O, 0 to 20% of K2O, 0.001 to 10% of TiO2, and 15 to 35% of Li2O+Na2O+K2O+Al2O3, has a (Li2O+Na2O+K2O)/Al2O3 value of 0.7 to 3 in terms of mole fraction, and is substantially free of As2O3 and F.
    Type: Grant
    Filed: October 10, 2007
    Date of Patent: February 18, 2014
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventor: Takashi Murata
  • Publication number: 20140023865
    Abstract: According to one embodiment, a glass article may include SiO2, Al2O3, Li2O and Na2O. The glass article may have a softening point less than or equal to about 810° C. The glass article may also have a high temperature CTE less than or equal to about 27×10?6/° C. The glass article may also be ion exchangeable such that the glass has a compressive stress greater than or equal to about 600 MPa and a depth of layer greater than or equal to about 25 ?m after ion exchange in a salt bath comprising KNO3 at a temperature in a range from about 390° C. to about 450° C. for less than or equal to approximately 15 hours.
    Type: Application
    Filed: July 10, 2013
    Publication date: January 23, 2014
    Inventors: Marie Jacqueline Monique Comte, Melinda Ann Drake, Karen Leslie Geisinger, Sinue Gomez, Robert Michael Morena, Charlene Marie Smith, Randall Eugene Youngman
  • Patent number: 8623776
    Abstract: A fusion formable and ion exchangeable silicate glass having a seed concentration of less than about 1 seed/cm3.
    Type: Grant
    Filed: June 19, 2013
    Date of Patent: January 7, 2014
    Assignee: Corning Incorporated
    Inventors: Matthew John Dejneka, Sinue Gomez
  • Patent number: 8609561
    Abstract: A colorless transparent colloid-former-containing glass that is convertible into a colorless transparent glass ceramic or a metal colloid-colored glass ceramic via respective heat treatments contains a combination of one or more metal colloid formers and one or more redox partners. The metal colloid formers are preferably oxides containing Au, Ag, As, Bi, Nb, Cu, Fe, Pd, Pt, Sb and/or Sn. The redox partners are preferably oxides containing As, Ce, Fe, Mn, Sb, Sn and/or W, with the proviso that the redox partner must be different from the metal colloid former. The glass advantageously contains from 0.97 to 1.9 wt. % SnO2, 0.93 to 3.0 wt. % As2O3, or 1.59 to 6.0 wt. % of Sb2O3 as redox partner.
    Type: Grant
    Filed: July 17, 2012
    Date of Patent: December 17, 2013
    Assignee: Schott AG
    Inventors: Meike Schneider, Thilo Zachau, Friedrich Siebers, Wolfgang Schmidbauer
  • Publication number: 20130316162
    Abstract: Provided is a tempered glass sheet having a compression stress layer in a surface thereof, comprising, as a glass composition expressed in mass % in terms of oxides, 50 to 70% of SiO2, 5 to 20% of Al2O3, 0 to 5% of B2O3, 8 to 18% of Na2O, 2 to 9% of K2O, and 30 to 1,500 ppm of Fe2O3, and having a spectral transmittance in terms of a thickness of 1.0 mm at a wavelength of 400 to 700 nm of 85% or more, a chromaticity x of 0.3095 to 0.3120 in xy chromaticity coordinates (illuminant C, in terms of a thickness of 1 mm), and a chromaticity y of 0.3160 to 0.3180 in xy chromaticity coordinates (illuminant C, in terms of a thickness of 1 mm).
    Type: Application
    Filed: February 7, 2012
    Publication date: November 28, 2013
    Applicant: NIPPON ELECTRIC GLASS CO., LTD.
    Inventors: Takashi Murata, Kosuke Kawamoto
  • Patent number: 8561429
    Abstract: A strengthened glass that does not exhibit frangible behavior when subjected to impact or contact forces, and a method of strengthening a glass. The glass may be strengthened by subjecting it to multiple, successive, ion exchange treatments. The multiple ion exchange treatments provide a local compressive stress maximum at a depth of the strengthened layer and a second local maximum at or near (e.g., within 10 ?m) the surface of the glass.
    Type: Grant
    Filed: July 10, 2009
    Date of Patent: October 22, 2013
    Assignee: Corning Incorporated
    Inventors: Douglas Clippinger Allan, Adam James Ellison, Sinue Gomez
  • Patent number: 8546280
    Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.
    Type: Grant
    Filed: July 1, 2011
    Date of Patent: October 1, 2013
    Assignee: Ivoclar Vivadent AG
    Inventors: Elke Apel, Wolfram Höland, Marcel Schweiger, Christian Ritzberger, Harald Bürke, Volker M. Rheinberger
  • Patent number: 8541327
    Abstract: A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO2; one or more compounds from the group of compounds consisting of La2O3, Al2O3, B2O3, and Ni; the La2O3 less than about 20 mole percent; the Al2O3 less than about 25 mole percent; the B2O3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: September 24, 2013
    Assignee: U.S. Department of Energy
    Inventors: Peizhen Kathy Lu, Manoj Kumar Mahapatra
  • Patent number: 8536078
    Abstract: Lithium silicate glass ceramics and glasses containing at least 6.1 wt.-% ZrO2 are provided which can advantageously be applied to zirconium oxide ceramics in particular by pressing-on in the viscous state and forming a solid bond with the zirconium oxide ceramics.
    Type: Grant
    Filed: April 5, 2011
    Date of Patent: September 17, 2013
    Assignee: Ivoclar Vivadent AG
    Inventors: Christian Ritzberger, Ricardo Dellagiacomo, Marcel Schweiger, Harald Burke, Wolfram Holand, Volker Rheinberger
  • Publication number: 20130224491
    Abstract: Glass compositions that may be used to produce chemically strengthened glass sheets by ion exchange. The glass compositions are chosen to promote simultaneously high compressive stress and deep depth of layer or, alternatively, to reduce the time needed to ion exchange the glass to produce a predetermined compressive stress and depth of layer.
    Type: Application
    Filed: February 29, 2012
    Publication date: August 29, 2013
    Inventors: Morten Mattrup Smedskjaer, Marcel Potuzak, John Christopher Mauro
  • Patent number: 8518545
    Abstract: To provide glass to be used for chemically tempered glass which is hardly broken even when flawed. Glass for chemical tempering, which comprises, as represented by mole percentage based on the following oxides, from 65 to 85% of SiO2, from 3 to 15% of Al2O3, from 5 to 15% of Na2O, from 0 and less than 2% of K2O, from 0 to 15% of MgO and from 0 to 1% of ZrO2, and has a total content SiO2+Al2O3 of SiO2 and Al2O3 of at most 88%.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: August 27, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Shusaku Akiba, Kazutaka Ono, Jun Endo, Shigeki Sawamura, Tetsuya Nakashima, Yuichi Kuroki
  • Patent number: 8509588
    Abstract: An amplifying optical fiber includes a core containing oxides of elements selected from the group consisting of silicon, germanium, phosphorus, bismuth, aluminum, gallium with a concentration of bismuth oxide of 10-4-5 mol %, a total concentration of silicon and germanium oxides of 70-99.8999 mol %, a total concentration of aluminum and gallium oxides of 0.1-20 mol % wherein both aluminum and gallium oxide are present and a ratio of aluminum oxide to gallium oxide is at least two, and a concentration of phosphorus oxide from 0 to 10 mol %, and provides a maximum optical gain at least 10 times greater than the nonresonant loss factor in the optical fiber. An outside oxide glass cladding comprises fused silica. The core has an absorption band in the 1000 nm region, pumping to which region provides an increased efficiency of power conversion of pump light into luminescence light in the 1000-1700 nm range.
    Type: Grant
    Filed: September 8, 2006
    Date of Patent: August 13, 2013
    Assignee: Fiber Optics Research Center of The Russian Academy of Sciences
    Inventors: Evgeny Mikhailovich Dianov, Vladislav Vladimirovich Dvoirin, Valery Mikhailovich Mashinsky, Alexei Nikolaevich Guryanov, Andrei Alexandrovich Umnikov
  • Patent number: 8497220
    Abstract: The glass substrate for a solar cell of the present invention is characterized by having a glass composition including, in terms of mass %, 50 to 80% of SiO2, 5 to 20% of Al2O3, 0 to 20% of B2O3, 0 to 20% of MgO, 0 to 20% of CaO, 0 to 20% of SrO, 0 to 20% of BaO, 0.001 to 2% of SnO2, 0 to 1% of As2O3, having a mass ratio SnO2/(Fe2O3+SnO2) of 0.9 or more, and having a difference between transmittances at a wavelength of 400 nm before and after irradiation with ultraviolet ray of 2% or less.
    Type: Grant
    Filed: July 9, 2009
    Date of Patent: July 30, 2013
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventor: Takashi Murata
  • Patent number: 8476353
    Abstract: Provided are an amorphous polyamide resin composition having high transparency, and is excellent in heat resistance and stiffness, and a molded product thereof. The glass filler contains, expressed in terms of oxides by mass %, 68 to 74% of silicon dioxide (SiO2), 2 to 5% of aluminum oxide (Al2O3), 2 to 5% of boron oxide (B2O3), 2 to 10% of calcium oxide (CaO), 0 to 5% of zinc oxide (ZnO), 0 to 5% of strontium oxide (SrO), 0 to 1% of barium oxide (BaO), 1 to 5% of magnesium oxide (MgO), 0 to 5% of lithium oxide (Li2O), 5 to 12% of sodium oxide (Na2O), and 0 to 10% of potassium oxide (K2O), where a total amount of lithium oxide (Li2O), sodium oxide (Na2O), and potassium oxide (K2O) is 8 to 12%.
    Type: Grant
    Filed: September 25, 2008
    Date of Patent: July 2, 2013
    Assignee: Asahi Fiber Glass Company, Limited
    Inventors: Hideyuki Higashiyama, Keiji Sekine
  • Publication number: 20130165312
    Abstract: A cover glass for semiconductor package having thermal expansion coefficient conformable to plastic packages and allowing accurate detection of existence of foreign substances, dusts, etc. in an imaging test always having a low emission amount of alpha-ray, and a related production method. The cover glass comprises, in terms of percentage by mass, of from 58 to 75% of SiO2, of from 1.1 to 20% of Al2O3, of from 0 to 10% of B2O3, of from 0.1 to 20% of Na2O, of from 0 to 11% of K2O, and of from 0 to 20% of alkaline earth metal oxide. The cover glass has average thermal expansion coefficient of from 90 to 180×10?7/° C. in the temperature range of from 30 to 380° C., a Young's modulus of 68 GPa or more, and an emission amount of alpha-ray from the glass of 0.05 c/cm2·hr or less.
    Type: Application
    Filed: September 8, 2011
    Publication date: June 27, 2013
    Applicant: NIPPON ELECTRIC GLASS CO., LTD.
    Inventors: Takako Komai, Takashi Murata, Masahiro Yodogawa
  • Publication number: 20130134859
    Abstract: To provide a glass ceramic composition with which a substrate for a light emitting element having a high reflectance and a high thermal conductivity can be obtained, and which can suppress breakage at the time of production of the substrate for a light emitting element. A glass ceramic composition to be used for production of a substrate on which a light emitting element is to be mounted, which comprises from 30 to 45 mass % of a glass powder, from 35 to 50 mass % of an alumina powder and from 10 to 30 mass % of a zirconia powder, to the total amount of the glass powder, the alumina powder and the zirconia powder, wherein the average particle size of the zirconia powder is at most ¼ of the average particle size of the alumina powder.
    Type: Application
    Filed: January 29, 2013
    Publication date: May 30, 2013
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventor: Asahi Glass Company, Limited
  • Publication number: 20130115422
    Abstract: Provided is a glass sheet, comprising, as a glass composition in terms of mass %, 40 to 80% of SiO2, 0 to 30% of Al2O3, 0 to 15% of B2O3, 0 to 25% of an alkali metal oxide (one kind or two or more kinds of Li2O, Na2O, and K2O), and 0 to 15% of an alkaline earth metal oxide (one kind or two or more kinds of MgO, CaO, SrO, and BaO), and being used as a viewing zone control member for covering partially or wholly a two-dimensional display.
    Type: Application
    Filed: June 3, 2011
    Publication date: May 9, 2013
    Inventor: Takashi Murata
  • Publication number: 20130116108
    Abstract: The invention relates to a silica glass compound having improved physical and chemical properties. In one embodiment, the present invention relates to a silica glass having a desirable brittleness in combination with a desirable density while still yielding a glass composition having a desired hardness and desired strength relative to other glasses. In another embodiment, the present invention relates to a silica glass composition that contains at least about 85 mole percent silicon dioxide and up to about 15 mole percent of one or more dopants selected from F, B, N, Al, Ge, one or more alkali metals (e.g., Li, Na, K, etc.), one or more alkaline earth metals (e.g., Mg, Ca, Sr, Ba, etc.), one or more transition metals (e.g., Ti, Zn, Y, Zr, Hf, etc.), one or more lanthanides (e.g., Ce, etc.), or combinations of any two or more thereof.
    Type: Application
    Filed: July 2, 2012
    Publication date: May 9, 2013
    Applicant: MOMENTIVE PERFORMANCE MATERIALS, INC.
    Inventors: Nathan J. Cassingham, Ben Matthew Gauthier, Martin Panchula, Robert Stephen Pavlik, Yan Zhou, Konstantin S. Zuyev
  • Patent number: 8431502
    Abstract: A fusion formable and ion exchangeable silicate glass having a seed concentration of less than about 1 seed/cm3.
    Type: Grant
    Filed: June 13, 2012
    Date of Patent: April 30, 2013
    Assignee: Corning Incorporated
    Inventors: Matthew John Dejneka, Sinue Gomez
  • Publication number: 20130102454
    Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In another embodiment, a glass composition may include from about 70 mol. % to about 80 mol. % SiO2; from about 3 mol. % to about 13 mol. % alkaline earth oxide; X mol. % Al2O3; and Y mol. % alkali oxide. The alkali oxide may include Na2O in an amount greater than about 8 mol. %. A ratio of Y:X may be greater than 1 and the glass composition may be free of boron and compounds of boron. In some embodiments, the glass composition may also be free of phosphorous and compounds of phosphorous. Glass articles formed from the glass composition may have at least a class S3 acid resistance according to DIN 12116, at least a class A2 base resistance according to ISO 695, and a type HGA1 hydrolytic resistance according to ISO 720.
    Type: Application
    Filed: October 25, 2012
    Publication date: April 25, 2013
    Inventors: Paul Steven Danielson, Steven Edward DeMartino, Melinda Ann Drake, Robert Michael Morena, Santona Pal, Robert Anthony Schaut
  • Patent number: 8426327
    Abstract: A technical object of the present invention is to satisfy various properties required in glass for liquid crystal displays and the like, in particular, fusibility, devitrification resistance, and like properties, and then to design a glass composition in which components harmful to the environment are reduced or substantially not contained, thereby obtaining a glass substrate that takes the environment into consideration. An alkali-free glass of the present invention contains the following glass composition in percent by weight based on oxide: 50 to 70% of SiO2, 10 to 20% of Al2O3, 8 to 12% of B2O3, 0 to 3% of MgO, 4 to 15% of CaO, 0 to 10% of SrO, 0 to 1% of BaO, and 0 to 5% of ZnO, and substantially free of alkali metal oxide and As2O3.
    Type: Grant
    Filed: May 22, 2007
    Date of Patent: April 23, 2013
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Tomoki Yanase, Shinkichi Miwa
  • Patent number: 8415013
    Abstract: A strengthened glass article having a central tension that is below a threshold value above which the glass exhibits frangible behavior. The central tension varies non-linearly with the thickness of the glass. The glass article may be used as cover plates or windows for portable or mobile electronic devices such as cellular phones, music players, information terminal (IT) devices, including laptop computers, and the like.
    Type: Grant
    Filed: April 20, 2012
    Date of Patent: April 9, 2013
    Assignee: Corning Incorporated
    Inventors: Kristen L Barefoot, James Joseph Price, Jose Mario Quintal, Ronald Leroy Stewart
  • Publication number: 20130085058
    Abstract: An object of the present invention is to provide a Li2O—Al2O3—SiO2 based crystallized glass with excellent bubble quality even without using As2O3 or Sb2O3 as a fining agent and a method for producing the same. The Li2O—Al2O3—SiO2 based crystallized glass of the present invention is a Li2O—Al2O3—SiO2 based crystallized glass which does not substantially comprise As2O3 and Sb2O3 and comprises at least one of Cl, CeO2 and SnO2, and has a S content of not more than 10 ppm in terms of SO3.
    Type: Application
    Filed: May 30, 2011
    Publication date: April 4, 2013
    Applicant: NIPPON ELECTRIC GLASS CO., LTD.
    Inventors: Shingo Nakane, Kosuke Kawamoto
  • Publication number: 20130045386
    Abstract: A tempered glass of the present invention having a compression stress layer is characterized in that a ?-OH value is 0.01 to 0.5/mm. Here, the “?-OH value” is a value obtained from the following equation by measuring the transmittance of glass by FT-IR.
    Type: Application
    Filed: October 12, 2012
    Publication date: February 21, 2013
    Applicant: NIPPON ELECTRIC GLASS CO., LTD.
    Inventor: NIPPON ELECTRIC GLASS CO., LTD.
  • Publication number: 20130040169
    Abstract: Disclosed are a glass substrate for an information recording medium, having excellent scratch resistance and a light weight and having high fracture toughness, the glass substrate having a fragility index value, measured in water, of 12 ?m?1/2 or less or having a fragility index value, measured in an atmosphere having a dew point of ?5° C. or lower, of 7 ?m?1/2 or less, or the glass substrate comprising, by mol %, 40 to 75% of SiO2, 2 to 45% of B2O3 and/or Al2O3 and 0 to 40% of R?2O in which R? is at least one member selected from the group consisting of Li, Na and K), wherein the total content of SiO2, B2O3, Al2O3 and R?2O is at least 90 mol %, and a magnetic information recording medium comprising a magnetic recording layer formed on the glass substrate.
    Type: Application
    Filed: June 7, 2012
    Publication date: February 14, 2013
    Applicant: HOYA CORPORATION
    Inventors: Mikio Ikenishi, Atsuko Morita, Xuelu Zou
  • Patent number: 8367208
    Abstract: The invention is directed to a high strength, chemically toughened protective glass article, the glass article having a high damage tolerance threshold of at least 1500 g as measured by the lack of radial cracks when the load is applied to the glass using a Vickers indenter; preferably greater than 2000 g s measured by the lack of initiation of radial cracks when the load is applied to the glass using a Vickers indenter.
    Type: Grant
    Filed: February 6, 2009
    Date of Patent: February 5, 2013
    Assignee: Corning Incorporated
    Inventors: Gregory Scott Glaesemann, James Joseph Price, Robert Sabia, Nagaraja Shashidhar
  • Publication number: 20130011607
    Abstract: Provided is a high refractive index glass, comprising, as a glass composition in terms of mass %, 0 to 10% of B2O2, 0.001 to 35% of SrO, 0.001 to 30% of ZrO2+TiO2, and 0 to 10% of La2O2+Nb2O5, having a mass ratio of BaO/SrO of 0 to 40 and a mass ratio of SiO2/SrO of 0.1 to 40, and having a refractive index nd of 1.55 to 2.3.
    Type: Application
    Filed: May 18, 2012
    Publication date: January 10, 2013
    Inventors: Atsushi MUSHIAKE, Takashi MURATA, Tomoki YANASE
  • Publication number: 20130011650
    Abstract: To provide glass to be used for chemically tempered glass which is hardly broken even when flawed. Glass for chemical tempering, which comprises, as represented by mole percentage based on the following oxides, from 65 to 85% of SiO2, from 3 to 15% of Al2O3, from 5 to 15% of Na2O, from 0 and less than 2% of K2O, from 0 to 15% of MgO and from 0 to 1% of ZrO2, and has a total content SiO2+Al2O3 of SiO2 and Al2O3 of at most 88%.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 10, 2013
    Applicant: Asahi Glass Company, Limited
    Inventors: Shusaku Akiba, Kazutaka Ono, Jun Endo, Shigeki Sawamura, Tetsuya Nakashima, Yuichi Kuroki
  • Patent number: 8349454
    Abstract: An object of the invention is to obtain a glass substrate having high mechanical strength by reconciling suitability for ion exchange and devitrification proof in a glass. The strengthened glass substrate of the invention is a strengthened glass substrate having a compression stress layer in the surface thereof, the glass substrate having a glass composition including, in terms of % by mass, 40-70% of SiO2, 12-25% of Al2O3, 0-10% of B2O3, 0-8% of Li2O, 6-15% of Na2O, 0-10% of K2O, 13-20% of Li2O+Na2O+K2O, 0-3.9% of MgO, 0-5% of CaO, 0-5% of ZnO, 0-6% of ZrO2, and 0-5% of SrO+BaO, the value of (MgO+ZrO2+ZnO)/(MgO+ZrO2+ZnO+Al2O3) in terms of mass proportion being from 0.25 to 0.45. The above-mentioned strengthened glass can be produced by melting raw glass materials mixed together so as to result in the given glass composition, forming the melt into a sheet by an overflow downdraw process, and then conducting an ion exchange treatment to form a compression stress layer in the glass sheet surface.
    Type: Grant
    Filed: June 3, 2008
    Date of Patent: January 8, 2013
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Takashi Murata, Hiroki Yamazaki
  • Patent number: 8349455
    Abstract: Glass comprising, as represented by mole percentage based on the following oxides, from 50 to 75% of SiO2, from 1 to 15% of Al2O3, from 6 to 21% of Na2O, from 0 to 15% of K2O, from 0 to 15% of MgO, from 0 to 20% of CaO, from 0 to 21% of ?RO (wherein R is Mg, Ca, Sr, Ba and/or Zn), from 0 to 5% of ZrO2, from 1.5 to 6% of Fe2O3, and from 0.1 to 1% of Co3O4.
    Type: Grant
    Filed: August 18, 2010
    Date of Patent: January 8, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Yuki Kondo, Hiroyuki Ohkawa, Makoto Sano, Kazutaka Hayashi, Shusaku Akiba
  • Publication number: 20130004758
    Abstract: An aluminosilicate glass article having a high compressive stress layer. The glass article comprises at least about 50 mol % SiO2 and at least about 11 mol % Na2O, and has a layer under a compressive stress of at least about 900 MPa and the depth of layer that extends at least about 30 ?m from the surface of the glass article into the glass. A method of making such a glass article is also provided.
    Type: Application
    Filed: June 26, 2012
    Publication date: January 3, 2013
    Inventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
  • Patent number: 8338524
    Abstract: Disclosed is a glass composition which can be suitably used as a glass filler to be blended into a polycarbonate resin. This glass composition contains, in mass %, 50?SiO2?60, 8?Al2O3?15, 0?MgO?10, 10?CaO?30, 0?Li2O+Na2O+K2O<2, and 5<TiO2?10, and does not substantially contain B2O3, F, ZnO, SrO, BaO and ZrO2.
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: December 25, 2012
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Kosuke Fujiwara, Akihiro Koyama
  • Publication number: 20120308803
    Abstract: A silicate glass that is tough and scratch resistant. The toughness is increased by minimizing the number of non-bridging oxygen atoms in the glass. In one embodiment, the silicate glass is an aluminoborosilicate glass in which ?15 mol %?(R2O+R?O—Al2O3—ZrO2)—B2O3?4 mol %, where R is one of Li, Na, K, Rb, and Cs, and R? is one of Mg, Ca, Sr, and Ba.
    Type: Application
    Filed: August 17, 2012
    Publication date: December 6, 2012
    Inventors: Matthew John Dejneka, Adam James Ellison, Sinue Gomez, Robert Michael Morena
  • Publication number: 20120308827
    Abstract: Ion exchangeable glass articles are disclosed. In one embodiment, a glass article formed from alkali aluminosilicate glass which may include Ga2O3, Al2O3, Na2O, SiO2, B2O3, P2O5 and various combinations thereof. The glass article may generally include about X mol % of Ga2O3 and about Z mol % of Al2O3, wherein 0?x?20, 0?z?25 and 10?(X+Z)?25. The glass article may also include from about 5 mol % to about 35 mol % Na2O, SiO2 may be present in an amount from about 40 mol % to about 70 mol % SiO2. The glass article may further include Y mol % B2O3 where Y is from 0 to about 10. The glass article may further include (10-Y) mol % of P2O5. Glass articles formed according to the present invention may be ion-exchange strengthened. In addition, the glass articles may have a low liquid CTE which enables the glass articles to be readily formed into complex shapes.
    Type: Application
    Filed: May 31, 2011
    Publication date: December 6, 2012
    Inventors: Heather Debra Boek, Mark Owen Weller, Randall Eugene Youngman
  • Publication number: 20120309607
    Abstract: The invention relates to glass-ceramics based on the lithium disilicate system which can be mechanically machined easily in an intermediate step of crystallisation and, after complete crystallisation, represent a very strong, highly-translucent and chemically-stable glass-ceramic. Likewise, the invention relates to a method for the production of these glass-ceramics. The glass-ceramics according to the invention are used as dental material.
    Type: Application
    Filed: December 23, 2010
    Publication date: December 6, 2012
    Applicants: FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V., DEGUDENT GMBH, VITA ZAHNFABRIK H. RAUTER GMBH & CO. KG
    Inventors: Bernhard Durschang, Jorn Probst, Norbert Thiel, Joachim Bibus, Markus Vollmann, Udo Schusser
  • Publication number: 20120289394
    Abstract: To provide a colored glass plate, which uses sodium sulfate (Na2SO3) as a refining agent and which is capable of stably maintaining the mass percentage of divalent iron calculated as Fe2O3 in the total iron calculated as Fe2O3 at a high level, while suppressing development of an amber color that is derived from sodium sulfate. A colored glass plate made of alkali-containing silica glass containing elements of iron, tin and sulfur, wherein the percentage of the total sulfur calculated as SO3 is at least 0.025% as represented by mass percentage based on oxides, the percentage of divalent iron calculated as Fe2O3 in the total iron calculated as Fe2O3 is from 60 to 80% as represented by mass percentage, and the percentage of divalent tin calculated as SnO2 in the total tin calculated as SnO2 is at least 0.1% as represented by mol percentage.
    Type: Application
    Filed: July 12, 2012
    Publication date: November 15, 2012
    Applicant: Asahi Glass Company, Limited
    Inventors: Kensuke NAGAI, Yuichi Suzuki, Terutaka Maehara
  • Patent number: 8304484
    Abstract: Disclosed is a glass composition having a stable quality, which can be easily obtained. This glass composition can be used as a glass filler to be blended into a polycarbonate resin, and enables to reduce the load imposed on a glass manufacturing apparatus. Specifically, this glass composition contains, in mass %, 50?SiO2?60, 8?Al2O3?15, 0?MgO?10, 5?CaO<21, 0<SrO+BaO?25, 10<MgO+SrO+BaO?30, 0?Li2O+Na2O+K2O<2, 2<TiO2?10 and 0?ZrO2<2 and does not substantially contain B2O3, F, and ZnO.
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: November 6, 2012
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Kosuke Fujiwara, Akihiro Koyama
  • Patent number: 8304078
    Abstract: Chemically strengthened lithium aluminosilicate glass is characterized by a surface compression of at least 100,000 psi and a compression case depth of at least 600 microns. The glass also may be characterized by a compression at 50 microns below a surface of the glass that is at least 30,000 psi. A method of making this glass includes providing a lithium aluminosilicate glass having a composition comprising (in weight %): Li2O in an amount ranging from 3 to 9%, Na2O+K2O in an amount not greater than 3%, and Al2O3 in an amount ranging from 7 to 30%. The composition provides the glass with an annealing point temperature of at least 580° C. A mixed potassium and sodium salt bath is provided comprising predominantly potassium salt. A ratio of moles of sodium salt to moles of potassium salt in the mixed salt bath can range from 1:10 to 1:2. The temperature of the salt bath is maintained in a range of 450° C. up to an annealing point temperature of the glass.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: November 6, 2012
    Assignee: Saxon Glass Technologies, Inc.
    Inventor: Arun K. Varshneya
  • Patent number: 8283270
    Abstract: The neutral glass according to the present invention is characterized by excellent hydrolytic stability, a relatively low processing temperature and low content of boron oxide. Here, the neutral glass has the following composition, in percent by weight based on oxide content: SiO2, 70-79; B2O3, 0-<5; Al2O3, <5; ZrO2, 0.5-<5; TiO2, 0.5-6; Na2O, 1-6; K2O, 3 to 8; and Li2O, 0-0.5, wherein a total amount of SiO2 and B2O3 is less than 83 percent by weight.
    Type: Grant
    Filed: June 11, 2010
    Date of Patent: October 9, 2012
    Assignee: Schott AG
    Inventors: Joerg Hinrich Fechner, Christof Kass
  • Publication number: 20120251743
    Abstract: A housing/enclosure/cover can include an ion-exchanged glass exhibiting the following attributes (1) radio, and microwave frequency transparency, as defined by a loss tangent of less than 0.03 and at a frequency range of between 15 MHz to 3.0 GHz; (2) infrared transparency; (3) a fracture toughness of greater than 0.6 MPa·m1/2; (4) a 4-point bend strength of greater than 350 MPa; (5) a Vickers hardness of at least 450 kgf/mm2 and a Vickers median/radial crack initiation threshold of at least 5 kgf; (6) a Young's Modulus ranging between about 50 to 100 GPa;; (7) a thermal conductivity of less than 2.0 W/m° C., and (9) and at least one of the following attributes: (i) a compressive surface layer having a depth of layer (DOL) greater and a compressive stress greater than 400 MPa, or, (ii) a central tension of more than 20 MPa.
    Type: Application
    Filed: May 15, 2012
    Publication date: October 4, 2012
    Inventors: Jaymin Amin, Matthew John Dejneka, Linda Ruth Pinckney, Katherine Rose Rossington, Robert Sabia
  • Publication number: 20120252652
    Abstract: A fusion formable and ion exchangeable silicate glass having a seed concentration of less than about 1 seed/cm3.
    Type: Application
    Filed: June 13, 2012
    Publication date: October 4, 2012
    Inventors: Matthew John Dejneka, Sinue Gomez
  • Publication number: 20120251827
    Abstract: A tempered glass substrate of the present invention is a tempered glass substrate, which has a compression stress layer on a surface thereof, and has a glass composition comprising, in terms of mass %, 40 to 71% of SiO2, 3 to 21% of Al2O3, 0 to 3.5% of Li2O, 7 to 20% of Na2O, and 0 to 15% of K2O.
    Type: Application
    Filed: June 8, 2012
    Publication date: October 4, 2012
    Inventor: Takashi MURATA
  • Patent number: 8231961
    Abstract: A low temperature co-fired ceramic material includes a SiO2—BaO—Al2O3-based primary component, and, as secondary components, 0.044 to 0.077 parts by weight of iron in terms of Fe2O3 and 0.30 to 0.55 parts by weight of zirconium in terms of ZrO2 relative to 100 parts by weight of the SiO2—BaO—Al2O3-based primary component. The SiO2—BaO—Al2O3-based primary component preferably includes 47% to 60% by weight of SiO2, 20% to 42% by weight of BaO, and 5% to 30% by weight of Al2O3.
    Type: Grant
    Filed: October 18, 2010
    Date of Patent: July 31, 2012
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Tomoya Yokoyama, Yuzo Kawada, Akira Baba, Hiromichi Kawakami, Isao Kato
  • Patent number: 8232218
    Abstract: A glass that is ion exchangeable to a depth of at least 20 ?m (microns) and has a internal region having a tension of less than or equal to 100 MPa. The glass is quenched or fast cooled from a first temperature above the anneal point of the glass to a second temperature that is below the strain point of the glass. In one embodiment, the glass is a silicate glass, such as an alkali silicate glass, an alkali aluminosilicate glass, an aluminosilicate glass, a borosilicate glass, an alkali aluminogermanate glass, an alkali germanate glass, an alkali gallogermanate glass, and combinations thereof.
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: July 31, 2012
    Assignee: Corning Incorporated
    Inventors: Matthew John Dejneka, Adam James Ellison, Sinue Gomez
  • Publication number: 20120178613
    Abstract: The invention provides an alkali-free glass substrate small in the variation of the thermal shrinkage and a process for producing the same. An alkali-free glass substrate of the invention has an absolute value of a thermal shrinkage of 50 ppm or more when the alkali-free glass substrate is heated at a rate of 10° C./min from a room temperature, kept at a holding temperature of 450° C. for 10 hr and then cooled at a rate of 10° C./min.
    Type: Application
    Filed: February 22, 2012
    Publication date: July 12, 2012
    Applicant: NIPPON ELECTRIC GLASS CO., LTD.
    Inventors: Yoshinari KATO, Tatsuya Takaya