Preparing Catalyst Or Precursor Patents (Class 502/104)
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Patent number: 9012347Abstract: The present invention relates to a preparation method of a metallocene catalyst. More particularly, the present invention relates to a preparation method of a supported hybrid metallocene catalyst, including the steps of treating a support having a water content of 4 to 7% by weight with trialkyl aluminum at a predetermined temperature; supporting alkyl aluminoxane on the support; and supporting a metallocene compound on the alkyl aluminoxane-supported support. According to the present invention, it is possible to prepare a supported hybrid metallocene catalyst which shows a high activity in the polymerization of olefins and enables the preparation of polyolefins having a high bulk density, by a simple process.Type: GrantFiled: September 28, 2011Date of Patent: April 21, 2015Assignee: LG Chem, Ltd.Inventors: Hyeon-Gook Kim, Ki-Soo Lee, Dae-Sik Hong, Eun-Kyoung Song, Man-Seong Jeon
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Patent number: 8993693Abstract: A Ziegler-Natta catalyzed ethylene copolymer having a novel composition distribution in which comonomers are incorporated into the high molecular weight polymer molecules and distributed evenly among the entire polyethylene chains, and a method for making the same are provided. The resins having a novel composition distribution have controlled molecular weight distribution which is narrower than conventional ZN-ethylene copolymers but broader than single-site catalyzed ethylene copolymers. The resins having a novel composition distribution exhibit a superior tear strength and impact strength.Type: GrantFiled: March 23, 2012Date of Patent: March 31, 2015Assignee: Formosa Plastics CorporationInventors: Honglan Lu, Guangxue Xu
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Publication number: 20150080541Abstract: The present invention provides a new process for preparing a catalyst for the gas phase polymerization of olefins wherein the sequence of addition of the catalyst components and the selection of the said components provides a catalyst composition which exhibits a superior response to hydrogen, a surprisingly high productivity and an improved activity profile. The catalyst consists of compounds of a group IV transition metal, Mg, C1 and A1 supported on a silica support.Type: ApplicationFiled: April 16, 2013Publication date: March 19, 2015Inventors: Fabien Bini, Paul Fiasse, Luc Girardot, Benoit Koch
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Patent number: 8981023Abstract: This invention relates to a supported nonmetallocene catalyst and preparation thereof. The supported nonmetallocene catalyst can be produced with a simple and feasible process and is characterized by an easily controllable polymerization activity. This invention further relates to use of the supported nonmetallocene catalyst in olefin homopolymerization/copolymerization, which is characterized by a lowered assumption of the co-catalyst as compared with the prior art.Type: GrantFiled: October 13, 2010Date of Patent: March 17, 2015Assignees: China Petroleum & Chemical Corp., Sinopec Yangzi Petrochemical Co. Ltd.Inventors: Hongping Ren, Chuanfeng Li, Xiaoli Yao, Feng Guo, Zhonglin Ma, Haibin Chen, Kaixiu Wang, Jingwei Liu, Yaming Wang
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Publication number: 20150073108Abstract: The present invention relates to a high surface area silicon derivative free magnesium-titanium catalyst system for ethylene polymerization comprising: magnesium mixed alkoxide and titanium chloride. The present invention also provides a simple process for the preparation of high surface area silicon derivative free magnesium-titanium catalyst system for ethylene polymerization by reacting magnesium alkoxide precursor with titanium compound using dialkyl dialkoxy silane as external donor. The invention further relates to the process for ethylene polymerization using the silicon derivative free magnesium-titanium catalyst system and polyethylene produced by the catalyst system having narrow molecular weight distribution and higher bulk density.Type: ApplicationFiled: July 26, 2012Publication date: March 12, 2015Applicant: Reliance Industries LimitedInventors: Harshad Ramdas Patil, Virendrakumar Gupta, Ajay Vinoklal Kothari
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Publication number: 20150065668Abstract: This invention relates to racemic bridged bis(indenyl)metallocene transition metal compounds, rac-directing metallation reagents and a process to produce the racemic bridged bis(indenyl)metallocene transition metal compounds using the rac-directing metallation regents.Type: ApplicationFiled: August 4, 2014Publication date: March 5, 2015Inventor: Glen E. Alliger
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Patent number: 8962774Abstract: Regular shaped magnesium particles containing attrition resistant precursors and procatalysts thereof and processes for their synthesis and their use in the manufacture of polyolefins are described. A process for the synthesis of precursor particles which give highly active and improved surface area procatalysts for producing high bulk density polyolefin resins containing low fines and capable of incorporating high rubber content are described. A process for the synthesis of an attrition resistant precursors to prepare an attrition resistant Zeigler Natta procatalysts synthesized by using the precursors and to the polyolefin resin synthesized using the procatalysts is also described.Type: GrantFiled: July 11, 2011Date of Patent: February 24, 2015Assignee: Reliance Industries LimitedInventors: Virendrakumar Gupta, Saurabh Singh, Jomichan Joseph, Kamlesh J. Singala, Bhavesh K. Desai
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Patent number: 8962509Abstract: Process for the preparation of a solid catalyst system (CS) comprising the steps of preparing a liquid clathrate (LC) comprising (a) a lattice (L) being the reaction product of (i) aluminoxane (A), (ii) an organometallic compound (O) of a transition metal (M) of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, and (i) a compound (B) being effective to form with the aluminoxane (A) and the organometallic compound (O) the lattice (L), and (b) a guest (G) being an hydrocarbon compound (HC), and subsequently precipitating said liquid clathrate (LC) obtaining said solid catalyst system (SC).Type: GrantFiled: April 28, 2011Date of Patent: February 24, 2015Assignee: Borealis AGInventors: Kalle Kallio, Marja Mustonen, Pertti Elo, Peter Denifl, John Severn
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Patent number: 8956989Abstract: The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.Type: GrantFiled: January 31, 2013Date of Patent: February 17, 2015Assignee: Novomer, Inc.Inventors: Scott D. Allen, Anna E. Cherian, Chris A. Simoneau, Jay J. Farmer, Geoffrey W. Coates, Alexei Gridnev, Robert E. LaPointe
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Patent number: 8957169Abstract: This invention relates to a supported nonmetallocene catalyst and preparation thereof. The supported nonmetallocene catalyst can be produced with a simple and feasible process and is characterized by an easily controllable polymerization activity. This invention further relates to use of the supported nonmetallocene catalyst in olefin homopolymerization/copolymerization, which is characterized by a lowered assumption of the co-catalyst as compared with the prior art.Type: GrantFiled: October 13, 2010Date of Patent: February 17, 2015Assignees: China Petroleum & Chemical Corp., Sinopec Yangzi Petrochemical Co. Ltd.Inventors: Xiaoli Yao, Chuanfeng Li, Hongping Ren, Zhonglin Ma, Feng Guo, Kaixiu Wang, Jingwei Liu, Yaming Wang
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Patent number: 8952112Abstract: This invention relates to a supported nonmetallocene catalyst and preparation thereof. The supported nonmetallocene catalyst can be produced with a simple and feasible process and is characterized by an easily controllable polymerization activity. This invention further relates to use of the supported nonmetallocene catalyst in olefin homopolymerization/copolymerization, which is characterized by a lowered assumption of the co-catalyst as compared with the prior art.Type: GrantFiled: October 13, 2010Date of Patent: February 10, 2015Assignees: China Petroleum & Chemical Corp., Sinopec Yangzi Petrochemical Company Ltd.Inventors: Chuanfeng Li, Hongping Ren, Xiaoli Yao, Zhonglin Ma, Feng Guo, Kaixiu Wang, Jingwei Liu, Yaming Wang, Lijuan Yang
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Patent number: 8951930Abstract: The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.Type: GrantFiled: January 31, 2013Date of Patent: February 10, 2015Assignee: Novomer, Inc.Inventors: Scott D. Allen, Anna E. Cherian, Chris A. Simoneau, Jay J. Farmer, Geoffrey W. Coates, Alexei Gridnev, Robert E. LaPointe
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Patent number: 8952113Abstract: This invention relates to a supported nonmetallocene catalyst and preparation thereof. The supported nonmetallocene catalyst can be produced with a simple and feasible process and is characterized by an easily controllable polymerization activity. This invention further relates to use of the supported nonmetallocene catalyst in olefin homopolymerization/copolymerization, which is characterized by a lowered assumption of the co-catalyst as compared with the prior art.Type: GrantFiled: October 13, 2010Date of Patent: February 10, 2015Assignees: China Petroleum & Chemical Corp., Sinopec Yangzi Petrochemical Company Ltd.Inventors: Chuanfeng Li, Hongping Ren, Xiaoli Yao, Lin Kan, Bo Liu, Zhonglin Ma, Feng Guo, Kaixiu Wang, Yaming Wang, Lijuan Yang
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Publication number: 20150038660Abstract: The present invention relates to a catalyst component for polymerization of an olefin comprising a compound represented by the Fischer projection of: wherein R5 is substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R6 and R7 are different and independently selected from the group consisting of hydrogen, halogen and substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R5-R7 optionally containing one or more hetero-atoms replacing one or more carbon atoms, one or more hydrogen atom or both, wherein said hetero-atom is selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen; and wherein the compound of Formula (I) is the only internal electron donor in the catalyst component.Type: ApplicationFiled: February 21, 2013Publication date: February 5, 2015Applicant: SAUDI BASIC INDUSTRIES CORPORATIONInventors: Mansour I. Taftaf, Nourdin Ghalit, Gennadii Dimitrievich Bukatov, Sergei Andreevich Sergeev, Vladimir Aleksandrovich Zakharov, Jaiprakash Brijlal Sainani, Aurora Alexandra Batinas-Geurts
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Patent number: 8946368Abstract: The present invention relates to a multi-component catalytic system that can be used for the cis-1,4 stereospecific polymerization of conjugated dienes. The system is based on: (i) a rare-earth complex of Formula (II) Ln(A)3(B)n, Ln being a rare-earth metal, A a ligand, B a Lewis base or a solvent molecule and n a number from 0 to 3; (ii) an alkylating agent; (iii) a compound based on an aromatic ring and having at least two heteroatoms chosen from the elements O, N, S, P, and corresponding to the Formula (III): in which the R groups each denote hydrogen, an alkyl radical optionally comprising one or more heteroatoms (N, O, P, S, Si) or one or more halogen atoms, a halogen atom, a group based on one or more heteroatoms (N, O, P, S, Si); x and y are integers from 0 to 6; D is a group having a chemical function, one of the atoms of which has a non-bonding pair; L being an atom from column 1 of the Periodic Table.Type: GrantFiled: April 27, 2010Date of Patent: February 3, 2015Assignees: Compagnie Generale des Etablissements, Michelin Recherche et Technique S.A.Inventors: Christophe Boisson, Olivier Rolland, Julien Thuilliez
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Patent number: 8946109Abstract: The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.Type: GrantFiled: January 31, 2013Date of Patent: February 3, 2015Assignee: Novomer, Inc.Inventors: Scott D. Allen, Anna E. Cherian, Chris A. Simoneau, Jay J. Farmer, Geoffrey W. Coates, Alexei Gridnev, Robert E. LaPointe
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Publication number: 20150031844Abstract: Disclosed is a metallocene catalyst composition for polyolefin polymerization. The metallocene catalyst composition is in a non-supported, heterogeneous form where an ansa-metallocene is bound to a cocatalyst without a support. Also, a method for preparing the catalyst composition, and a method for preparing polyolefin using the catalyst are disclosed. Capable of readily controlling microstructures of olefin polymers in addition to having high catalytic activity, the non-supported heterogeneous catalyst composition can be applied to the preparation of polyolefin polymers at high yield without altering preexisting processes.Type: ApplicationFiled: November 2, 2012Publication date: January 29, 2015Inventors: Jin-Woo Lee, Churl-Young Park, Yeongg-Ah Choi, Nan-Young Lee, Dong-Gil Lee
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Publication number: 20150018504Abstract: The present invention discloses an active metallocene catalyst system prepared with a hafnium-based metallocene catalyst system and an activating agent comprising an aluminoxane and a sterically hindered Lewis base.Type: ApplicationFiled: September 26, 2014Publication date: January 15, 2015Inventors: Vincenzo Busico, Roberta Cipullo, Roberta Pellecchia, Abbas Razavi
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Patent number: 8933180Abstract: The present disclosure relates to solid catalyst components comprising titanium, magnesium, halogen and an internal electron donor compound containing at least one 9-(alkoxymethyl)-9H-fluorene compound. The 9-(alkoxymethyl)-9H-fluorene compound include octyl-9-(methoxymethyl)-9H-fluorene-9-carboxylate; 7-methyloctyl-9-(methoxymethyl)-9H-fluorene-9-carboxylate; 2-ethylhexyl-9-(methoxymethyl)-9H-fluorene-9-carboxylate; and 9-(methoxymethyl)-9H-fluorene-9-yl benzoate. The present disclosure further relates to catalyst systems containing the catalyst solid components, organoaluminum compounds, and organosilicon compounds. The present disclosure also relates to methods of making the solid catalyst components and the catalyst systems, and methods of polymerizing or copolymerizing alpha-olefins using the catalyst systems.Type: GrantFiled: March 14, 2013Date of Patent: January 13, 2015Assignee: BASF CorporationInventor: Main Chang
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Publication number: 20140378298Abstract: The invention relates to a particulate Group 2 metal/transition metal olefin polymerisation catalyst component comprising a special 1,3-diether as internal donor, to a process for preparing same and to the use of such a catalyst component for pre paring a catalyst used in the polymerisation of olefins.Type: ApplicationFiled: December 19, 2012Publication date: December 25, 2014Inventors: Georgy Kipiani, Timo Leinonen, Peter Denifl, Reijo Mulari, Tommi Krogerus
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Publication number: 20140378634Abstract: Catalysts comprising thio-salalen ligands. Also, catalyst systems comprising the catalyst and an activator; methods to prepare the ligands, catalysts and catalyst systems; processes to polymerize olefins using the catalysts and/or catalyst systems; and the olefin polymers prepared according to the processes.Type: ApplicationFiled: May 28, 2014Publication date: December 25, 2014Applicants: ExxonMobil Chemical Patents Inc., Ramot at Tel-Aviv University Ltd.Inventors: Moshe Kol, Konstantin Press, Ayellet Lynn Stopper, Matthew W. Holtcamp, Meagan E. Evans, David A. Cano
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Patent number: 8916494Abstract: Methods for the vapor phase preparation of fluorided solid oxide activator-supports, using certain calcining temperatures and fluoriding temperatures, are disclosed.Type: GrantFiled: August 27, 2012Date of Patent: December 23, 2014Assignee: Chevron Phillips Chemical Company LPInventors: Max P. McDaniel, Kathy S. Collins, Qing Yang, Tony R. Crain
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Publication number: 20140364576Abstract: Disclosed is a supported nonmetallocene catalyst and preparation thereof. The supported nonmetallocene catalyst is characterized by a high catalyst activity for olefin polymerization and a significant monomer effect. Further disclosed is use of the supported nonmetallocene catalyst in olefin homopolymerization/copolymerization. The polymer produced therewith is characterized by superior particle morphology, a high bulk density, and/or a narrow molecular weight distribution.Type: ApplicationFiled: June 9, 2014Publication date: December 11, 2014Applicants: SINOPEC YANGZI PETROCHEMICAL COMPANY LTD., CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Chuanfeng LI, Hongping REN, Lin KAN, Feng GUO, Wenrui WANG, Yuming YI, Shaohui CHEN, Jiye BAI
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Patent number: 8907029Abstract: An olefin polymerization catalyst is prepared by (a) in a diluent, combining a diorganomagnesium compound with less than 2 molar equivalents of a first source of chloride to produce a “chloride deficient” magnesium chloride support; (b) without isolating any solids, adding a second source of chloride which reduces the amount of soluble un-reacted diorganomagnesium compound present; (c) without isolating any solids present, adding a tetravalent titanium species and; (d) adding an activator. The catalyst is active for solution polymerization of olefins.Type: GrantFiled: March 8, 2011Date of Patent: December 9, 2014Assignee: NOVA Chemicals (International) S.A.Inventors: Qinyan Wang, Peter Zoricak
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Patent number: 8901027Abstract: A method of forming a Fischer-Tropsch catalyst by providing at least one metal nitrate solution, combining each of the at least one metal nitrate solutions with a precipitating agent whereby at least one catalyst precipitate is formed, and incorporating a strong base during precipitation, subsequent precipitation, or both during and subsequent precipitation. Catalysts produced via the disclosed method are also provided.Type: GrantFiled: November 15, 2011Date of Patent: December 2, 2014Assignee: Res USA, LLCInventors: Deena Ferdous, Belma Demirel
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Patent number: 8895679Abstract: An imine phenol compound having Structure I: wherein O and N represent oxygen and nitrogen respectively; R comprises a halogen, a hydrocarbyl group, or a substituted hydrocarbyl group; R2 and R3 can each independently be hydrogen, a halogen, a hydrocarbyl group, or a substituted hydrocarbyl group; and Q is a donor group. A method comprising contacting a catalyst composition with a monomer under conditions suitable for the formation of a polymer wherein the catalyst composition comprises a metal salt complex of an imine (bis)phenolate compound, a solid oxide, and an optional metal alkyl and wherein the metal salt complex of an imine (bis)phenolate compound has Structure XIV where M is titanium, zirconium, or hafnium; OEt2 is ethoxide, R comprises a halogen, a hydrocarbyl group, or a substituted hydrocarbyl group; and R2 comprises hydrogen, a halogen, a hydrocarbyl group, or a substituted hydrocarbyl group.Type: GrantFiled: October 25, 2012Date of Patent: November 25, 2014Assignee: Chevron Phillips Chemical Company LPInventor: Mark L. Hlavinka
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Patent number: 8859696Abstract: A process for producing an oligomeric product by oligomerization of at least one olefinic compound, the process including a) providing an activated oligomerization catalyst, by combining, in any order, i) a source of chromium, ii) a ligating compound, iii) a catalyst activator or combination of catalyst activators, b) providing a zinc compound, and c) contacting the at least one olefinic compound with a composition containing the activated oligomerization catalyst and the zinc compound, the zinc compound being present in a sufficient quantity such that the ratio of the molar amount of zinc in the zinc compound to the molar amount of chromium in the source of chromium is between 1 and 10,000. The invention also provides a process of activating an oligomerization catalyst to be used to produce an oligomeric product from at least one olefinic compound.Type: GrantFiled: October 13, 2010Date of Patent: October 14, 2014Assignee: Sasol Technology (PTY) LimitedInventors: Martin John Hanton, David Matthew Smith, William Fullard Gabrielli, Mark William Kelly
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Patent number: 8859451Abstract: The present invention refers to a process for the preparation of supported catalysts for the polymerization of olefins comprising at least a late transition metal complex, wherein the process comprises two steps. In the first step a catalytically active component comprising at least one late transition metal complex, optionally in the presence of one or more cocatalysts is mixed with a support; and in the second step the obtained mixture is treated at a reduced pressure under a flow of inert gas at a temperature equal to or below 40° C. to obtain a supported catalyst. The method is especially useful for the preparation of dual supported catalysts, useful in the gas-phase polymerization of olefins.Type: GrantFiled: December 16, 2010Date of Patent: October 14, 2014Assignee: Basell Polyolefine GmbHInventors: Shahram Mihan, Volker Fraaije, Harald Schmitz
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Patent number: 8840769Abstract: A catalyst precursor resin composition includes an organic polymer resin; a fluorinated-organic complex of silver ion; a monomer having multifunctional ethylene-unsaturated bonds; a photoinitiator; and an organic solvent. The metallic pattern is formed by forming catalyst pattern on a base using the catalyst precursor resin composition reducing the formed catalyst pattern, and electroless plating the reduced catalyst pattern. In the case of forming metallic pattern using the catalyst precursor resin composition, a compatibility of catalyst is good enough not to make precipitation, chemical resistance and adhesive force of the formed catalyst layer are good, catalyst loss is reduced during wet process such as development or plating process, depositing speed is improved, and thus a metallic pattern having good homogeneous and micro pattern property may be formed after electroless plating.Type: GrantFiled: July 23, 2013Date of Patent: September 23, 2014Assignee: LG Chem, Ltd.Inventors: Min Kyoun Kim, Min Jin Ko, Sang Chul Lee, Jeong Im Roh
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Patent number: 8841392Abstract: The invention relates to a catalyst system comprising I. a solid reaction product obtained by reaction of: (a) a hydrocarbon solution comprising (1) an organic oxygen containing magnesium compound (2) an organic oxygen containing titanium compound and (3) at least one compound containing zirconium and/or hafnium (b) a mixture comprising a metal compound having the formula MeRnX3-n wherein X is a halogenide, Me is a metal of Group III of Mendeleev's Periodic System of Chemical Elements, R is a hydrocarbon radical containing 1-10 carbon atoms and 0<n<3 and a silicon compound of formula RmSiCI4-m wherein 0<m?2 and R is a hydrocarbon radical containing 1-10 carbon atoms wherein the molar ratio of metal from (b): titanium from (a) is lower than 1:1 and II. an organo aluminum compound having the formula AIR3 in which R is a hydrocarbon radical containing 1-10 carbon atoms. The catalyst is applied during the polymerization of ethylene, preferably ultra high molecular weight polyethylene.Type: GrantFiled: August 13, 2010Date of Patent: September 23, 2014Assignee: Saudi Basic Industries CorporationInventors: Nicolaas Hendrika Friederichs, Raymond Gerlofsma
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Publication number: 20140275451Abstract: The present disclosure relates to solid catalyst components comprising titanium, magnesium, halogen and an internal electron donor compound containing at least one 9-(alkoxymethyl)-9H-fluorene compound. The 9-(alkoxymethyl)-9H-fluorene compound include octyl-9-(methoxymethyl)-9H-fluorene-9-carboxylate; 7-methyloctyl-9-(methoxymethyl)-9H-fluorene-9-carboxylate; 2-ethylhexyl-9-(methoxymethyl)-9H-fluorene-9-carboxylate; and 9-(methoxymethyl)-9H-fluorene-9-yl benzoate. The present disclosure further relates to catalyst systems containing the catalyst solid components, organoaluminum compounds, and organosilicon compounds. The present disclosure also relates to methods of making the solid catalyst components and the catalyst systems, and methods of polymerizing or copolymerizing alpha-olefins using the catalyst systems.Type: ApplicationFiled: March 14, 2013Publication date: September 18, 2014Applicant: BASF CATALYSTS LLCInventor: Main CHANG
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Publication number: 20140275452Abstract: Solid catalyst components are disclosed, which include titanium, magnesium, halogen and a combination of internal electron donor compounds containing at least one 1,8 naphthyl diester compound of Formula (II-1) and at least one 3,3-bis(methoxymethyl) alkane of Formula (II-2): wherein R1, R2, R3, R4, R5, R6, R7, R8, A, and B are described herein. Catalyst systems containing the catalyst solid components, organoaluminum compounds, and organosilicon compounds are also discussed. This disclosure relates to methods of making the solid catalyst components and the catalyst systems, and methods of polymerizing or copolymerizing alpha olefins using the catalyst systems.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: BASF CATALYSTS LLCInventor: Main CHANG
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Patent number: 8829128Abstract: Process for the preparation of a polypropylene, wherein propylene is polymerized optionally with a comonomer selected from the group consisting of ethylene, a C4-C20 ?-olefin and mixtures thereof, in the presence of a catalyst system comprising solid catalyst particles, wherein the solid catalyst particles (a) comprise a transition metal compound of formula (I) LmRnMXq (I) wherein “M” is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC), each “X” is independently a monovalent anionic ?-ligand, each “L” is independently an organic ligand which coordinates to the transition metal (M), each “R” is a bridging group linking two organic ligands (L), “m” is 2 or 3, preferably 2, “n” is 0, 1 or 2, preferably 1, “q” is 1, 2 or 3, preferably 2, m+q is equal to the valency of the transition metal (M), (c) comprise a cocatalyst (Co) comprising an element (E) of group 13 of the periodic table (IUPAC), preferably a cocatalyst (Co) comprising a compound of A1, wherein further the loss of activType: GrantFiled: June 16, 2010Date of Patent: September 9, 2014Assignee: Borealis AGInventors: Lauri Huhtanen, Kalle Kallio, Pascal Castro
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Patent number: 8828901Abstract: Process for the preparation of a solid catalyst system comprising the steps of generating an emulsion by dispersing a liquid clathrate in a solution wherein (i) the solution constitutes the continuous phase of the emulsion and (ii) the liquid clathrate constitutes in form of droplets the dispersed phase of the emulsion, solidifying said dispersed phase to convert said droplets to solid particles and optionally recovering said particles to obtain said catalyst system, wherein the liquid clathrate comprises a lattice being the reaction product of aluminoxane, an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, and a further compound being effective to form with the aluminoxane and the organometallic compound the lattice, and a guest being an hydrocarbon compound, and the solution comprises a silicon fluid and a hydrocarbon solvent.Type: GrantFiled: April 28, 2011Date of Patent: September 9, 2014Assignee: Borealis AGInventors: Kalle Kallio, Marja Mustonen, Pertti Elo, John Severn, Peter Denifl
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Patent number: 8822365Abstract: Process for the preparation of a solid olefin polymerization catalyst system, comprising an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) in the form of solid particles comprising the steps of I) generating an emulsion by dispersing a liquid clathrate in a solvent (S) wherein (i) the solvent (S) constitutes the continuous phase of the emulsion and comprises a nonreactive fluorinated synthetic oil having a viscosity at 20° C.Type: GrantFiled: April 28, 2011Date of Patent: September 2, 2014Assignee: Borealis AGInventors: Jenni Valonen, Marja Mustonen
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Patent number: 8809219Abstract: The present invention provides metal-containing sulfated activator-supports, and polymerization catalyst compositions employing these activator-supports. Methods for making these metal-containing sulfated activator-supports and for using such components in catalyst compositions for the polymerization of olefins are also provided.Type: GrantFiled: December 20, 2013Date of Patent: August 19, 2014Assignee: Chevron Phillips Chemical Company LPInventors: Qing Yang, Max P. McDaniel, Tony R. Crain
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Publication number: 20140221584Abstract: A racemic complex of formula (I), wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R?2C—, —R?2C—CR?2, —R?2Si—, —R?2Si—SiR?2—, —R?2Ge—, wherein each R? is independently a hydrogen atom, C1-20-hydrocarbyl, tri(C1-20-alkyl)silyl, C6-20-aryl, C7-20-arylalkyl or C7-20-alkylaryl; R2 and R2? are each independently a C1-20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16; R5? is a C1-20 hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 and optionally substituted by one or more halo atoms.Type: ApplicationFiled: July 6, 2012Publication date: August 7, 2014Applicant: BOREALIS AGInventors: Norbert Hafner, Pascal Castro, Pavel Sergeevich Kulyabin, Vyatcheslav Izmer, Alexander Voskoboynikov, Luigi Resconi, Dmitry Kononovich, Ville Virkkunen, Dmitry Uborsky
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Patent number: 8791217Abstract: Catalyst compositions containing N,N-bis[2-hydroxidebenzyl]amine transition metal compounds are disclosed. Methods for making these transition metal compounds and for using such compounds in catalyst compositions for the polymerization or oligomerization of alpha olefins also are provided.Type: GrantFiled: December 28, 2011Date of Patent: July 29, 2014Assignee: Chevron Phillips Chemical Company LPInventors: Mark L. Hlavinka, Qing Yang, Brooke L. Small, Youlu Yu
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Patent number: 8791042Abstract: Process for the preparation of an unsupported, heterogeneous olefin polymerization catalyst system, comprising an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) in the form of solid particles comprising the steps of a) preparing a solution (A) comprising ai) an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, a2) a cocatalyst comprising an element of group 13 of the Periodic Table (IUPAC 2007) and a3) a solvent (A-1), b) preparing a liquid/liquid emulsion system by dispersing the solution (A) in a solvent (B) essentially immiscible with said solution (A) in the presence of a polystyrene-b-fluoro polystyrene copolymer of the formula (I) in which n is a number from 10 to 100, m is a number from 1 to 40, x is a number from 5 to 16, y is a number from 11 to 33, provided that m, n, x and y are selected in a way that the block copolymer is soluble in the solvent B or the solution A inType: GrantFiled: December 3, 2010Date of Patent: July 29, 2014Assignee: Borealis AGInventors: Nicolas Ronan, Peter Denifl
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Publication number: 20140206827Abstract: A method for producing a solid catalyst component for olefin polymerization includes bringing a magnesium compound, a tetravalent titanium halide compound, and an electron donor compound represented by a general formula (1) into contact with each other, reacting the mixture, washing the resulting reaction product to obtain a solid component, bringing the solid component, a tetravalent titanium halide compound, and an electron donor compound represented by a general formula (2) into contact with each other, reacting the mixture, and washing the resulting reaction product. (R1)kC6H4-k(COOR2)(COOR3)??(1) R4R5C(COOR6)2??(2) A polymer that exhibits high activity with respect to hydrogen, high stereoregularity, and high bulk density can be obtained using a catalyst including a solid catalyst component obtained by the method.Type: ApplicationFiled: August 3, 2012Publication date: July 24, 2014Applicant: TOHO TITANIUM CO., LTD.Inventors: Toshiya Uozumi, Shingo Yamada
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Publication number: 20140206828Abstract: The present invention relates to a method for preparing a supported metallocene catalyst, and a method for preparing polyolefin using the same, in which the supported metallocene catalyst prepared from the simple process according to the method for preparing the supported metallocene catalyst of the present invention can apply to the polymerization of the polyolefin that is polymerized at low pressure or high pressure; the molecular weight distribution of polyolefin prepared can be easily controlled; and there are effects such that its catalyst activity is significantly higher than that of the existed supported metallocene catalyst, and the molecular weight distribution can be easily controlled.Type: ApplicationFiled: March 21, 2014Publication date: July 24, 2014Applicant: LG CHEM, LTD.Inventors: Hyuck-Ju KWON, San-Ak HWANG, Dong-Gil LEE, Churl-Young PARK
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Patent number: 8785340Abstract: The catalyst exhibiting hydrogen spillover effect relates to the composition of a catalyst exhibiting hydrogen spillover effect and to a process for preparing the catalyst. The catalyst has a reduced transition base metal of Group VIB or Group VIIIB, such as cobalt, nickel, molybdenum or tungsten, supported on a high porous carrier, such as saponite, the base metal being ion-exchanged with at least one precious metal of Group VIIIB. The process includes the steps of loading the base metal onto the support, reducing the base metal, preferably with H2 at 600° C., and thereafter ion-exchanging the precious metal with the base metal. Preferred examples of the catalyst include a saponite support loaded with about 10-20 wt % cobalt and about 0.1-1 wt % precious metal. The catalyst is optimized for reactions that occur in commercial processes at about 360-400° C., such as in hydrocracking.Type: GrantFiled: October 20, 2011Date of Patent: July 22, 2014Assignee: King Fahd University of Petroleum and MineralsInventors: Takuma Kimura, Mohammad Abdullah Al-Saleh, Halim Hamid Redhwi, Mohammad Ashraf Ali, Shakeel Ahmed, Masayuki Inui
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Patent number: 8785592Abstract: Provided is preparation of poly(alkylene carbonate) through alternating copolymerization of carbon dioxide and epoxide. According to the disclosure, by introducing a diepoxide compound to alternating copolymerization of carbon dioxide and epoxide compound using a metal(III) prepared with salen-type ligands containing quaternary ammonium salt as a catalyst, some of the polymer chains may be cross-linked to thus increase an average molecular weight of the copolymer and extend a distribution of molecular weight. A resin prepared according to this method may have high mechanical strength and rheological advantages.Type: GrantFiled: September 7, 2011Date of Patent: July 22, 2014Assignee: SK Innovation Co., Ltd.Inventors: Ji Su Jeong, Sung Jae Na, Sujith Sudevan, Myung Ahn Ok, Yong Gyu Han, Kwang Jin Chung, Bun Yeoul Lee, Anish Cyriac
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Patent number: 8765632Abstract: A process for preparing a catalyst comprising palladium supported on a carrier via a layered precursor, comprising the following steps: (1) synthesis of hydrotalcite layered precursor which comprises promoting metal element and aluminium on the surface of the carrier of A12O3 microspheres, the atoms of the promoting metal and aluminium being highly dispersed by each other and bonded firmly to the carrier due to the crystal lattice positioning effect of the hydrotalcite crystal; (2) introduction of palladium into the carrier through impregnation; (3) drying; and (4) calcination and reduction with H2, the hydrotalcite layered precursor being converted into a composite oxide which consists of oxides of the promoting metal and aluminium, and the promoting metal element and aluminium being highly dispersed by each other and being able to separate and disperse the mainly active palladium element loaded later.Type: GrantFiled: June 25, 2009Date of Patent: July 1, 2014Assignee: Beijing University of Chemical TechnologyInventors: Fazhi Zhang, Peng Chen, Rong Hou, Jiali Chen, Chao Gao, Hui Zhang, Dianqing Li, Feng Li, Xue Duan
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Patent number: 8765626Abstract: The presently disclosed and claimed inventive concept(s) relates to solid catalyst components comprising titanium, magnesium, halogen and an internal electron donor compound having at least one ester group and at least one alkoxy group, and catalyst systems containing the catalyst solid components, organoaluminum compounds, and organosilicon compounds. The presently disclosed and claimed inventive concept(s) further relates to methods of making the catalyst components and the catalyst systems, and methods of polymerizing or copolymerizing alpha-olefins using the catalyst systems.Type: GrantFiled: November 30, 2011Date of Patent: July 1, 2014Assignee: BASF CorporationInventor: Main Chang
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Patent number: 8748335Abstract: A photodegradation catalyst or a photodegradation catalyst precursor comprises a plurality of domains of an oxide of a first metal distributed in a substrate of a halide or oxyhalide of a second metal, wherein the mole percentage of the halide or oxyhalide of the second metal is above 50%. Additionally, a method of preparing a photodegradation catalyst or a photodegradation catalyst precursor, a photodegradation catalyst or a photodegradation catalyst precursor obtained from the method and a method of treating organic pollutants or substances in air or water by using the photodegradation catalyst or the photodegradation catalyst precursor are illustrated.Type: GrantFiled: June 1, 2007Date of Patent: June 10, 2014Assignee: Microvast, Inc.Inventors: Xiao Ping Zhou, Fei Chen, Jeff Qiang Xu
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Publication number: 20140148565Abstract: A method for making a solid catalyst component for use in a Ziegler-Natta catalyst includes combining in a hydrocarbon solvent a porous particulate support with a hydrocarbon soluble organomagnesium compound to form a suspension. The organomagnesium compound is halogenated followed by addition of an alcohol and the mixture is then reacted with a titanium compound followed by a reaction with at least one diether compound to form the solid catalyst component. Afterwards the reaction product is extracted with a mixture of a titanium compound and a hydrocarbon solvent. The solid catalyst component recovered is combined with an aluminum cocatalyst to form a Ziegler-Natta catalyst system for the polymerization of olefins. In particular, the catalyst system including a diether internal electron donor may have an activity and hydrogen response suitable for the production of propylene polymers having a molecular weight distribution (PI(GPC)) in the range from about 5.75 to about 9.Type: ApplicationFiled: November 18, 2013Publication date: May 29, 2014Applicant: Lummus Novolen Technology GmbHInventors: Yvonne Denkwitz, Oliver Schuster, Andreas Winter
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Patent number: 8735315Abstract: A composition comprising a base component and a polymer, and a method of making said composition, are disclosed. The composition thereby obtained is then used as a catalyst for isoparaffin-olefin alkylation.Type: GrantFiled: December 17, 2009Date of Patent: May 27, 2014Assignee: UOP LLCInventors: Bruce B. Randolph, Marvin M. Johnson, Glenn W. Dodwell
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Publication number: 20140128556Abstract: Solid catalyst components for use in olefin polymerization, olefin polymerization catalyst systems containing the solid catalyst components, methods of making the solid catalyst components and the catalyst systems, and methods of polymerizing and copolymerizing olefins involving the use of the catalyst systems. The solid catalyst components are formed by (a) dissolving a magnesium compound and an auxiliary intermediate electron donor in at least one first solvent to form a solution; (b) contacting a first titanium compound with said solution to form a precipitate of the magnesium compound and the first titanium compound; (c) washing the precipitate with a mixture of a second titanium compound and at least one second solvent and optionally an electron donor at a temperature of up to 90° C.; and (d) treating the precipitate with a mixture of a third titanium compound and at least one third solvent at 90-150° C. to form a solid catalyst component.Type: ApplicationFiled: November 8, 2013Publication date: May 8, 2014Applicant: BASF CorporationInventors: Vladimir P. MARIN, Ahmed HINTOLAY, Michael Donald SPENCER
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Patent number: 8716165Abstract: A method for providing a catalyst on a substrate is disclosed comprising providing a first washcoat comprising a soluble washcoat salt species, a polar organic solvent, and an insoluble particulate material, contacting the first washcoat with a substrate to form a coated substrate, and then contacting the coated substrate with a second washcoat comprising an oxide or an oxide-supported catalyst to physisorb, chemisorb, bond, or otherwise adhere the oxide or the oxide-supported catalyst to the coated substrate. Also disclosed is a catalyst on a substrate comprising: a substrate; an anchor layer comprising a soluble washcoat salt species, a polar organic solvent, and an insoluble particulate material; and a second layer comprises an oxide or an oxide-supported catalyst. The catalyst on a substrate can be in either green or fired form.Type: GrantFiled: April 30, 2008Date of Patent: May 6, 2014Assignee: Corning IncorporatedInventor: William Peter Addiego