Abstract: The present invention relates to a method of producing novel chromatography media and use thereof for purification of biomolecules, such as proteins. The chromatography media comprises shell beads having an inner porous core and an outer shell. The method comprises providing buffering ligands in the core of the beads, and providing binding ligands aimed for biomolecule binding in the outer shell of the beads. This method makes it possible to optimize binding properties and buffering properties independently of each other which is especially to advantageous for production of chromatofocusing media.
Abstract: The invention relates to an adsorptive system, in particular on the basis of an agglomerate, comprising a plurality of absorber particles, wherein the absorber particles are fixed, in particular adhered, to a binding agent carrier and are combined by means of the binding agent carrier to form the adsorptive system, in particular to form an agglomerate, and wherein the absorber particles have a first particulate adsorption material and a second particulate adsorption material which is different from the first particulate adsorption material.
Type:
Application
Filed:
January 24, 2011
Publication date:
December 6, 2012
Inventors:
Jann-Michael Giebelhausen, Bertram Böhringer, Sven Fichtner
Abstract: Nanomaterials of the JT phase of the titanium oxide TiO2-x, where 0?x?1 having as a building block a crystalline structure with an orthorhombic symmetry and described by at least one of the space groups 59 Pmmn, 63 Amma, 71 Immm or 63 Bmmb. The nanomaterials are in the form of nanofibers, nanowires, nanorods, nanoscrolls and/or nanotubes and are obtained from a hydrogen titanate and/or a mixed sodium and hydrogen titanate precursor compound that is isostructural to the JT crystalline structure. The titanates are the hydrogenated, the protonated, the hydrated and/or the alkalinized phases of the JT crystalline phase that are obtained from titanium compounds such as titanium oxide with an anatase crystalline structure, amorphous titanium oxide, and titanium oxide with a rutile crystalline structure, and/or directly from the rutile mineral and/or from ilmenite.
Type:
Application
Filed:
June 19, 2012
Publication date:
November 29, 2012
Applicant:
INSTITUTO MEXICANO DEL PETROLEO
Inventors:
José Antonio Toledo Antonio, Carlos Angeles Chávez, Maria Antonia Cortés Jacome, Fernando Alvarez RamÍrez, Yosadara Ruiz Morales, Gerardo Ferrat Torres, Luis Francisco Flores Ortiz, Esteban López Salinas, Marcelo Lozada y Cassou
Abstract: Compositions, and processes utilizing such compositions, are provided for reducing mercury emissions during fuel combustion Such compositions comprise a sorbent, a bromine source and a chlorine source Such compositions exhibit improved thermal stability as compared to that of the sorbent by itself.
Abstract: The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.
Type:
Grant
Filed:
February 28, 2007
Date of Patent:
November 20, 2012
Assignees:
The Regents of the University of Michigan, The Regents of the University of California
Inventors:
Omar M. Yaghi, Hideki Hayashi, Rahul Banerjee, Kyo Sung Park, Bo Wang, Adrien P. Cote
Abstract: Methods and systems for reducing mercury emissions are provided herein. The methods, generally, include the steps of burning a heavy metal containing fuel source and introducing sorbent materials and introducing one or more halogen compounds into the combustion chamber and/or exhaust stream to remove the heavy metal.
Abstract: This invention relates to an oil-absorbent polymer and the preparation method thereof, and disclosed a preparation method of quick oil absorbent material, which comprises: (1) Mixing and stirring well monomer A, vinyl monomer, initiator and vesicant to form a copolymerization system, wherein the amount of monomer A is in the range of approximately 10-50 wt %, the amount of vinyl monomer is in the range of approximately 48-88 wt %, the amount of initiator is in the range of approximately 0.01-5 wt %, the amount of vesicant is in the range of approximately 1-5 wt %; (2) And then immersing fiber carriers into the liquid of above-said copolymerization system to adsorb the liquid on the fiber carriers, then heating the fiber carriers under a temperature between 60˜80° C. for 1˜4 hours to synthesize polymers on the fiber carriers.
Abstract: A process is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron oxide in the catalyst converts to catalytically active iron sulfide in the presence of hydrogen and sulfur.
Type:
Grant
Filed:
August 26, 2011
Date of Patent:
October 2, 2012
Assignee:
UOP LLC
Inventors:
Alakananda Bhattacharyya, Beckay J. Mezza
Abstract: In one embodiment, a composite ink absorber includes a porous layer and an absorbent layer integrated together into a single part. The porous layer is configured to trap inky sludge while simultaneously allowing ink liquids to pass through to the absorbent layer and the absorbent layer is configured to absorb ink liquids passing through the porous layer. In one embodiment, a printer platen assembly includes a platen and a composite, single part ink absorber covering the floor of the platen for capturing ink overspray in the platen area.
Abstract: The present invention is powder constituted from particles of a compound represented by the following general formula (1), (Ca1-aMa)10(PO4)6((OH)1-bFb)2 (1), where in the formula M is a divalent metal element, and the following relations are satisfied: 0<a?1 and 0?b?1. Each of the particles has a surface, a central part, a specific distance part in which a distance from the surface toward the central part is 15 nm, and an area part from the specific distance part to the central part. An amount of the divalent metal element is 3.2 wt % or more in the area part.
Type:
Application
Filed:
October 4, 2010
Publication date:
September 20, 2012
Applicant:
HOYA CORPORATION
Inventors:
Yukiko Murakami, Mari Yokoyama, Shintaro Kobayashi
Abstract: A compacted block of material constructed of one or more units consisting of matter comprising an ammonia-saturated material capable of reversibly desorbing and ad- or absorbing ammonia surrounded by a gas-permeable enclosure made of a flexible material having a thermal conductivity of at least about five times the thermal conductivity of said ammonia-saturated material at ?70° C.. to 250° C.. and methods for producing the same are described.
Type:
Application
Filed:
September 30, 2010
Publication date:
September 13, 2012
Applicant:
Amminex A/S
Inventors:
Jakob Svagin, Ulrich J. Quaade, Johnny Johansen, Henrik Wagner-Pedersen, Tue Johannessen
Abstract: Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.
Abstract: A new class of carbon-based sorbents for vapor-phase mercury removal is disclosed in this invention. The optimum structure of the sorbent particles, and a method to produce the sorbent, are described. The sorbent is based on carbon particles with a metal-oxide coating on the surface. The thin metal-oxide layer acts as a barrier for the adsorption of Air Entrainment Admixture (AEA), the component used to stabilize bubbles in cement), thereby enhancing its concrete friendliness. The metal-oxide is coated on the surface of carbon, using a solution-based method. The metal-oxide coated carbon was further modified with sulfur molecules, to increase its mercury removal capacity.
Abstract: A new class of sorbents for the removal of mercury from contaminated water. The optimum structure of the sorbent particles and a method to produce the same is described. The newly developed carbon-based particles are differentiated from other sorbent particles by their high accessible surface area and high affinity towards mercury ions that leads to faster and higher mercury adsorption. The sorbent is based on carbon particles with a metal-oxide coating on the surface. The metal-oxide is coated on the surface of carbon, using a solution-based method. The metal-oxide coated carbon was further modified with sulfur molecules, to increase its mercury removal capacity.
Abstract: The present invention generally provides a separation matrix comprising at least two stationary phases and a stationary phase comprising at least one chiral modality and at least one achiral modality. Also provided are methods of using the separation matrix or the stationary phase to separate enantiomers of one or more chiral molecules.
Type:
Application
Filed:
March 3, 2011
Publication date:
September 6, 2012
Applicant:
BOARD OF TRUSTEES OF THE UNIVERSITY OF ARKANSAS
Inventors:
Grover Miller, Drew R. Jones, Gunnar Boysen
Abstract: A system and process for the recovery of at least one halogenated hydrocarbon from a gas stream. The recovery includes adsorption by exposing the gas stream to an adsorbent with a lattice structure having pore diameters with an average pore opening of between about 5 and about 50 angstroms. The adsorbent is then regenerated by exposing the adsorbent to a purge gas under conditions which efficiently desorb the at least one adsorbed halogenated hydrocarbon from the adsorbent. The at least one halogenated hydrocarbon (and impurities or reaction products) can be condensed from the purge gas and subjected to fractional distillation to provide a recovered halogenated hydrocarbon.
Type:
Application
Filed:
August 31, 2010
Publication date:
September 6, 2012
Applicant:
Blue-Zone Technologies Ltd.
Inventors:
Dusanka Filipovic, Laurence Whitby, Biljna Milin, Frederick Cashin
Abstract: An oxidation catalyst, comprising a carbon material prepared by calcining a transition metal compound and a nitrogen-containing organic substance, or a transition metal compound, a nitrogen-containing organic substance, and a carbon compound not containing nitrogen, the oxidation catalyst oxidizing at least one target substance selected from the group consisting of NO, CO, NH3, and an aromatic hydrocarbon.
Abstract: A composition for promoting the formation of clots in blood comprises a zeolite and a binder. The zeolite is adjusted to have a specific moisture content. Processes by which the moisture content is adjusted include drying, re-hydrating, and combinations of drying and re-hydrating. A method of forming the composition comprises the steps of providing a zeolite and adjusting the moisture content such that upon application of the composition to a wound, a heat of hydration is reduced and heat transferred to the wound is reduced. A method of clotting blood flowing from a wound comprises the steps of applying the zeolite to the wound and maintaining the zeolite in contact with the wound for a predetermined amount of time, the zeolite having an adjusted moisture content and being capable of producing a controllable exothermic effect on the wound.
Abstract: Provided is a diesel oxidation catalyst for the treatment of exhaust gas emissions from a diesel engine and a method for treating a diesel exhaust gas stream, the method comprising providing a diesel oxidation catalyst and contacting said diesel exhaust gas stream with said diesel oxidation catalyst for the treatment of exhaust gas emissions. More particularly, the present invention is directed to a catalyst structure comprising three distinct layers; in which layer comprises a precious metal component such as palladium is located between two hydrocarbon storage layers comprising a molecular sieve such as a zeolite.
Type:
Grant
Filed:
January 13, 2010
Date of Patent:
August 28, 2012
Assignee:
BASF Corporation
Inventors:
Torsten W. Müller-Stach, Torsten Neubauer, Alfred H. Punke, Gerd Grubert, Attilio Siani, Corinna Freitag
Abstract: It is an object of the invention to improve the current QuEChERS technology. In one aspect of the invention, the buffer-salt powder mixture of the first stage of the QuEChERS process is compressed into a solid dosage form before it is used in the first stage of the QuEChERS process. Replacing the QuEChERS powders (the buffer-salt powder mixture of the first stage of the QuEChERS process) with solid aliquots eliminates the need for using centrifuge tubes for packaging the product.
Type:
Application
Filed:
April 16, 2010
Publication date:
August 23, 2012
Inventors:
Neil H. Mosesman, Brian A. Jones, Jack W. Cochran
Abstract: Method and apparatus for separating a target substance from a fluid or mixture. Capsules having a coating and stripping solvents encapsulated in the capsules are provided. The coating is permeable to the target substance. The capsules having a coating and stripping solvents encapsulated in the capsules are exposed to the fluid or mixture. The target substance migrates through the coating and is taken up by the stripping solvents. The target substance is separated from the fluid or mixture by driving off the target substance from the capsules.
Type:
Application
Filed:
December 6, 2011
Publication date:
August 23, 2012
Inventors:
Roger D. Aines, Christopher M. Spadaccini, Joshuah K. Stolaroff, William L. Bourcier, Jennifer A. Lewis, Eric B. Duoss, John J. Vericella
Abstract: One exemplary embodiment can be an apparatus for isomerizing a hydrocarbon stream rich in a C4 hydrocarbon and/or at least one of a C5 and C6 hydrocarbon. The apparatus can include: a first drier and a second drier adapted to receive a fluid including at least one reactant; and a reaction zone communicating with the first drier to receive the fluid including at least one reactant and with the second drier to receive the regenerant. Generally, the first drier operates at a first condition to dry the fluid including at least one reactant and the second drier operates at a second condition during regeneration with a regenerant. The regenerant is displaced from the drier using a down-flow regenerant displacement assembly.
Type:
Grant
Filed:
September 1, 2011
Date of Patent:
August 21, 2012
Assignee:
UOP LLC
Inventors:
Bryan S. Garney, Jocelyn C. Daguio, Kurt A. Detrick, Douglas A. Becci, David J. Shecterle, John M. Krupczak, Andrew D. Mezera
Abstract: A regenerable sorbent for the removal of acid gas from a fluid stream. The regenerable sorbent is made from raw materials such as iron mineral, expansive clay and starch. Acid gas is removed from the fluid stream by a process where the raw materials are obtained, crushed, sifted, possibly pelletized, calcined and contacted with the fluid stream containing the acid gas.
Type:
Grant
Filed:
May 13, 2010
Date of Patent:
August 21, 2012
Assignee:
Intevep, S.A.
Inventors:
Alfredo Viloria, Mónica Román, Marvin Ricaurte, Yanine Gonzaléz, Rafael Yoll, Marcos Rosa-Brussin
Abstract: A process for upgrading crude oil fractions or other hydrocarbon oil feedstreams boiling in the range of 36° to 520° C., and preferably naphtha and gas oil fractions boiling in the range of 36° to 400° C., employs a solid adsorption material to lower sulfur and nitrogen content by contacting the hydrocarbon oil, and optionally a viscosity-reducing solvent, with one or more solid adsorbents such as silica gel or silica, silica alumina, alumina, attapulgus clay and activated carbon in a mixing vessel for a predetermined period of time; passing the resulting slurry to a membrane separation zone, optionally preceded by a primary filtration step (i.e.
Abstract: This invention relates to high surface area materials, such as nanoparticles, that are coated with metal ions. These modified nanoparticles have active sites that bind various gases and/or odorous compounds, thereby removing these compounds from a medium such as air or water. Metal ions are adsorbed onto the surface of the nanoparticle and bound strongly to the surface. By selection of the metal ion, specific gaseous compounds and/or odorous compounds can be targeted and removed efficiently and effectively from both aqueous phase and from the air. The modified nanoparticles are useful in numerous article of manufacture for industrial and consumer use.
Abstract: An object of the present invention is to provide an adsorbent suitable as an adsorbent for a canister which is capable of reducing an amount of evaporated fuel gas released into the atmosphere even where a motor vehicle is allowed to park for a prolonged period of time, a process for producing the adsorbent as well as a canister using the adsorbent and a method for using the canister. The above object can be accomplished by an adsorbent in which an integrated volume of pores having an average diameter of 3,000 to 100,000 nm as measured with a mercury porosimeter is 6.5 mL/dl or more and an equilibrium adsorption as measured in an n-butane volume concentration of 2,000 ppm is 0.16 g/dL or more, a process for producing the adsorbent, as well as a canister and a method for using the canister.
Abstract: Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.
Abstract: An air purification device that is decorative and effective in removing contaminants from indoor air. The air purification device includes a carbon matrix composite.
Abstract: The invention provides an adsorbent for removing sulfur from cracking gasoline or diesel fuel, which adsorbent comprises: (1) a carrier consisting of a source of silica, an inorganic oxide binder, and at least one oxide of metal selected from Groups IIB, VB and VIB; (2) at least one accelerant metal which is capable of reducing the sulfur in oxidized state to hydrogen sulfide and has a ?<0.5, wherein ?=(the amount in percentage of accelerant metal in crystal phase)/(the amount in percentage of accelerant metal in the adsorbent). The active components in the adsorbent can be evenly dispersed on the carrier in a matter close to monolayer dispersion, and which greatly improves the activity of the adsorbent. The preparation method and the use of the above adsorbent are provided.
Type:
Grant
Filed:
June 30, 2009
Date of Patent:
July 17, 2012
Assignees:
China Petroleum & Chemical Corporation, Research Institute of Petroleum, Sinopec
Abstract: The present invention relates to a adsorbent composition for removing refractory sulphur compounds from refinery streams comprising of base component in the range of 10 to 50 wt %, spinel oxide in the range of 20 to 60 wt % as a reactive metal oxide component and bimetallic alloy in the range of 10 to 40 wt % acting as an adsorption enhancer component, wherein the adsorption enhancer component acts in synergy with base component. The invention also relates to a process for the preparation of said composition by mixing in solid state fine particles of base component, spinel oxide and bimetallic alloy, homogenizing the mixture thus obtained with solvent, peptizing the wet solid with dilute mineral acid, extruding the peptized material with extrusion aiding agents, drying the extrudates, further calcining the dried extrudates and reducing the calcined material under hydrogen flow.
Type:
Grant
Filed:
February 13, 2006
Date of Patent:
July 17, 2012
Assignee:
Indian Oil Corporation Limited
Inventors:
Sarvesh Kumar, Alex C. Pulikottil, Alok Sharma, Ujjwal Manna, Manoranjan Santra, Ram P. Verma
Abstract: Methods of making unique water treatment compositions are provided. In one embodiment, a method of making a doped metal oxide or hydroxide for treating water comprises: disposing a metal precursor solution and a dopant precursor solution in a reaction vessel comprising water to form a slurry; and precipitating the doped metal oxide or hydroxide from the slurry.
Type:
Grant
Filed:
June 14, 2007
Date of Patent:
July 10, 2012
Assignees:
Inframat Corporation, University of Houston
Inventors:
Huimin Chen, Dennis A. Clifford, Meidong Wang, T. Danny Xiao
Abstract: The invention relates to a solid mineral composition of heavy metals, in particular mercury, in flue gas, to a method for preparing such a solid mineral compound and to the use thereof for reducing heavy metals, in particular mercury, in flue gas, by placing the flue gas in contact with the solid mineral composition.
Abstract: The present invention relates to materials having improved and useful properties and to methods relating to the manufacture of said materials. In particular the present invention relates to a method of modifying the surface of a material, preferably a fibrous material, to enable carbon dioxide to be carried by the surface. The carbon dioxide may be bound to the surface in a reversible or irreversible manner. The method of treating the surface of a material comprises (a) contacting the surface of the material with a composition comprising an amino compound; and (b) contacting the surface of the material with a composition comprising carbon dioxide or a source thereof.
Abstract: Provided is a catalyst composition, in particular a diesel oxidation catalyst, for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO). More particularly, the present invention is directed to a catalyst structure comprising at least two, specifically three distinct layers, at least one of which contains an oxygen storage component (OSC) that is present in a layer separate from the majority of the platinum group metal (PGM) components, such as palladium and platinum.
Type:
Grant
Filed:
January 13, 2010
Date of Patent:
July 3, 2012
Assignee:
BASF Corporation
Inventors:
Gerd Grubert, Torsten Neubauer, Alfred H. Punke, Torsten W. Müller-Stach, Attilio Siani, Stanley A. Roth, Jeffrey B. Hoke, Shiang Sung, Yuejin Li, Xinyi Wei, Michel Deeba
Abstract: The present invention relates to a gas-absorbing substance that contains at least Li and a solid material having a hardness of 5 or more, and absorbs at least nitrogen or oxygen at 25° C. under normal pressure, and a gas-absorbing alloy that contains at least two kinds of metals that are not allowed to mutually form an intermetallic compound, with a mixing enthalpy of the two kinds of metals being greater than 0 and at least one portion of the two kinds of metals being atomically mixed, and also concerns a gas-absorbing material that contains the gas-absorbing substance and the gas-absorbing alloy.
Type:
Grant
Filed:
January 13, 2006
Date of Patent:
July 3, 2012
Assignees:
Panasonic Corporation, Kyoto University
Abstract: The present disclosure describes using the naturally present dissolved chemicals as precipitants from local water sources to form an adsorbent and a process of purifying the water using natural resources. The adsorbent may be processed at the right pH and temperature to purify and remove heavy metals from waste water. Once the heavy metals are removed the concentration of the heavy metals are estimated in the reusable water. The local authority acceptable level heavy metal containing reusable water is reclaimed for non-human consumption. This disclosure enables to conserve water and provide a cheap and an effective method to decontaminate industrial waste water.
Type:
Grant
Filed:
March 6, 2012
Date of Patent:
July 3, 2012
Assignee:
King Abdulaziz City for Science and Technology “KACST”
Abstract: Composite adsorbent beads have a porous and non-adsorbent core comprising at least one inorganic material and a porous and adsorbent shell comprising at least one adsorbent layer comprising a porous adsorbent material on the surface of the core. The core preferably comprises agglomerated inorganic particles having a mean particle size equal to or smaller than the mean particle size of the surrounding agglomerated adsorbent particles. The beads preferably are manufactured by calcining together a non-sintered core and the adsorbent layer. The beads can be used at the outlet end of an adsorption column to improve performance.
Type:
Application
Filed:
December 22, 2009
Publication date:
June 21, 2012
Applicants:
AIR PRODUCTS AND CHEMICALS, INC., GLATT SYSTEMTECHNIK GMBH
Inventors:
Almuth Gerds, Norman Reger-Wagner, Wolfgang Hungerbach, Constant Johan Van Lookeren, Roger Whitley, Jeffrey Raymond Hufton, Timothy Christopher Golden
Abstract: An adsorbent for desulfurizing cracking gasoline or diesel fuel comprising 1) pillared clay, (2) inorganic oxide binder, (3) an oxide of one or more metals selected from Groups IIB, VB and VIB, and (4) at least one metal accelerant selected from cobalt, nickel, iron and manganese. The adsorbent exhibits excellent abrasion-resistant strength and desulfurization performance.
Type:
Grant
Filed:
May 19, 2009
Date of Patent:
June 19, 2012
Assignees:
China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, Sinopec
Abstract: The present invention relates to a method for removing heavy metals from aqueous solutions by contacting heavy metal-contaminated water with a sorption media, or in particular with carbonate minerals. The present invention also relates to methods of using modified sorption media, such as aggregates of carbonate minerals and modified carbonate minerals, for the removal of heavy metals.
Type:
Application
Filed:
October 14, 2011
Publication date:
June 14, 2012
Inventors:
Arden D. DAVIS, Cathleen J. Webb, Jenifer Sorensen, Terrence E. Williamson, David J. Dixon
Abstract: An absorbent composition suitable for removing mercury, arsenic or antimony from fluid streams includes 5-50% by weight of a particulate sulphided copper compound, 30-90% by weight of a particulate support material, and the remainder one or more binders, wherein the metal sulphide content of the absorbent, other than copper sulphide, is below 5% by weight.
Type:
Grant
Filed:
January 29, 2009
Date of Patent:
June 12, 2012
Assignee:
Johnson Matthey PLC
Inventors:
Matthew John Cousins, Robert Logan, Christopher John Young
Abstract: A bromination process includes contacting fly ash with liquid bromine to increase the mercury adsorbing ability of the fly ash. The resultant brominated fly ash can be used to adsorb mercury in a high temperature combustion gas.
Type:
Grant
Filed:
September 29, 2009
Date of Patent:
June 12, 2012
Assignee:
EPCOR Power Generation Services, Inc.
Inventors:
Rajender P. Gupta, Zhenghe Xu, Ian Clark, Hongqun Yang
Abstract: The present invention relates to the selective separation of methane (“CH4”) from higher carbon number hydrocarbons (“HHC”s) in streams containing both methane and higher carbon number hydrocarbons (e.g. ethylene, ethane, propylene, propane, etc.) utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in a process to separate methane from higher carbon number hydrocarbons in natural gas streams.
Type:
Grant
Filed:
January 30, 2009
Date of Patent:
June 5, 2012
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Sebastian C. Reyes, Jose G. Santiesteban, legal representative, Zheng Ni, Charanjit S. Paur, Pavel Kortunov, John Zengel, Harry W. Deckman
Abstract: The present invention relates to the preparation of chiral zeolites and their use in liquid chromatography. The zeolite material may be used in the chromatographic separation of mixtures of components, such as the separation of enantiomers.
Abstract: A mercury absorbent comprising a metal sulphide, a support material, a first binder and a second binder, wherein the first binder is a cement binder and the second binder is a high aspect ratio binder having an aspect ratio >2. A mercury removal process comprises contacting a mercury containing feed stream with the absorbent.
Abstract: A flow-through sorbent comprising at least 30 wt % of a metal sulfide, and a binder. The sorbent may be used, for example, for the removal of a contaminant, such as mercury, from a fluid stream.
Type:
Application
Filed:
January 13, 2012
Publication date:
May 10, 2012
Applicant:
CORNING INCORPORATED
Inventors:
Kishor Purushottam Gadkaree, Anbo Liu, Joseph Frank Mach
Abstract: A method for the preparation of a supported metal nitrate, suitable as a precursor for a catalyst or sorbent, includes the steps of: (i) impregnating a support material with a metal nitrate, (ii) optionally drying the impregnated material at low temperature, and (iii) exposing the impregnated material to a gas mixture comprising nitric oxide at a temperature in the range 0-150° C., to form a dispersed supported metal nitrate. The metal nitrate may subsequently be converted to the corresponding oxide by calcining the metal nitrate to effect its decomposition. Preferred metals are iron, ruthenium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper or a mixture thereof.
Type:
Application
Filed:
March 11, 2010
Publication date:
May 10, 2012
Applicant:
Johnson Matthey PLC
Inventors:
Mariska Wolters, Peter Munnik, Johannes Hendrik Bitter, Petra Elisabeth De Jongh, Krijn Pieter De Jong
Abstract: A sorbent, suitable for removing heavy metals, including mercury, from fluids containing hydrogen and/or carbon monoxide at temperatures up to 550° C., in the form of a shaped unit comprising one or more mixed-valency metal sulphides of vanadium, chromium, manganese, iron, cobalt or nickel.
Type:
Application
Filed:
January 14, 2010
Publication date:
May 3, 2012
Applicant:
JOHNSON MATTHEY PLC
Inventors:
Lucy Jane Hetherington, Matthew John Cousins
Abstract: Disclosed herein provide compositions and hydrogen release methods for a high-capacity complex hydrogen storage material. The hydrogen storage material is mainly composed of metal borohydride and NH3. The invention advantageously adopt ammonia, one cheap and easily supplied material with high hydrogen content (17.6 wt %), as one of the hydrogen source, offering a safe and efficient way to store hydrogen and release hydrogen. Furthermore, the hydrogen storage material can be further catalyzed by a transition metal catalyst to improve the dehydrogenation kinetics. With the addition of catalyst, 0.2-10 equiv. H2 could be evolved at ?100˜600° C., which might be applied on vehicles which are fueled by hybrid or fuel cell.
Abstract: A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.
Type:
Grant
Filed:
June 17, 2008
Date of Patent:
April 17, 2012
Assignee:
Battelle Memorial Institute
Inventors:
Liyu Li, David L. King, Jun Liu, Qisheng Huo