Silicon Containing Patents (Class 502/407)
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Patent number: 8076263Abstract: The present invention is directed to an improved catalyst support and to the resultant catalyst suitable for treating exhaust products from internal combustion engines, especially diesel engines. The support of the present invention is a structure comprising alumina core particulate having high porosity and surface area, wherein the structure has from about 1 to about 40 weight percent silica in the form of cladding on the surface area of said alumina core. The resultant support has a normalized sulfur uptake (NSU) of up to 15 ?g/m2.Type: GrantFiled: September 12, 2007Date of Patent: December 13, 2011Assignee: W. R. Grace & Co.-Conn.Inventors: Manoj Mukund Koranne, James Neil Pryor, David Monroe Chapman, Rasto Brezny
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Patent number: 8075859Abstract: A nanocomposite particle, its use as a catalyst, and a method of making it are disclosed. The nanocomposite particle comprises titanium dioxide nanoparticles, metal oxide nanoparticles, and a surface stabilizer. The metal oxide nanoparticles are formed hydrothermally in the presence of the titanium dioxide nanoparticles. The nanocomposite particle is an effective catalyst support, particularly for DeNOx catalyst applications.Type: GrantFiled: July 14, 2009Date of Patent: December 13, 2011Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Guoyi Fu, Steven M. Augustine
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Patent number: 8071655Abstract: A catalyst applicable to the synthesis gas conversions especially E-T slurry processes, said catalyst comprising: a) a support containing at least a first aluminate element of mixed spinel structure of formula MxM?(1?x)Al2O4/Al2O3.SiO2, x ranging between and excluding 0 and 1, or of simple spinel structure of formula MAl2O4/Al2O3.SiO2, said support being calcined in an at least partly oxidizing atmosphere, at a temperature ranging between 850° C. and 900° C., and b) an active phase deposited on said support, which contains one or more group VIII metals, selected from among cobalt, nickel, ruthenium or iron. Said catalyst is used in a fixed bed or suspended in a three-phase reactor for hydrocarbon synthesis from a CO, H2 mixture.Type: GrantFiled: November 17, 2005Date of Patent: December 6, 2011Assignees: IFP Energies Nouvelles, ENI S.p.A.Inventors: Fabrice Diehl, François Hugues, Marie-Claire Marion, Denis Uzio
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Publication number: 20110269217Abstract: A hazardous substance adsorbing tablet prepared by direct compression of a dry powder mixture which includes a porous particulate adsorbent having an average particle diameter of 100 ?m or less and containing 200 mesh pass particles in an amount of more than 80% by weight, and a particulate binder having an apparent specific gravity of at least 1.Type: ApplicationFiled: April 4, 2011Publication date: November 3, 2011Applicants: TOKYO SINCOL CO., LTD., NATIONAL INSTITUTE FOR AGRO-ENVIRONMENTAL SCIENCESInventors: Heesoo EUN, Hiroaki FUKUI
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Patent number: 8043989Abstract: A system is provided for desulfurizing a hydrocarbon fuel containing a light amount of methanol and a slight amount of water. The desulfurization system uses a Y-type zeolite-based desulfurizing agent containing at least copper arranged upstream of the system and an X-type zeolite-based desulfurizing agent containing at least silver arranged downstream of the system and thus can maintain desulfurization effect for a long period of time.Type: GrantFiled: March 4, 2009Date of Patent: October 25, 2011Assignee: Nippon Oil CorporationInventors: Yoshiyuki Nagayasu, Atsushi Segawa, Kazunori Miyazawa, Yoshihiro Kobori
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Publication number: 20110257008Abstract: Methods for making high-surface area, high-porosity, stable metal oxides, such as, but not limited to materials used as adsorbents and catalyst supports include (i) forming a solvent deficient precursor mixture from a metal salt and a base and reacting the metal ions and base ions in the solvent deficient precursor mixture to form an intermediate hydroxide product (e.g., metal hydroxide or metal oxide hydroxide), (ii) causing the intermediate hydroxide to form nanoparticles (e.g., by heating), and (iii) calcining the intermediate nanoparticles to sinter the nanoparticles together and yield a highly porous, stable metal oxide aggregate having a pore structure.Type: ApplicationFiled: March 22, 2011Publication date: October 20, 2011Applicant: BRIGHAM YOUNG UNIVERSITYInventors: Calvin H. Bartholomew, Brian F. Woodfield, Baiyu Huang, Rebecca Elizabeth Olsen, Lynn Astle
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Patent number: 8034740Abstract: A moisture- or protein-adsorbability imparting agent, comprising a porous silica having a hexagonal pore structure, an average pore size of from 0.8 to 20 nm, an average particle size of 50 nm to 100 ?m, a specific surface area of from 400 to 2000 m2/g, and a pore volume of from 0.1 to 3.0 cm3/g; a material having an adsorbability of moisture or a protein, comprising the moisture- or protein-adsorbability imparting agent; and use of the moisture- or protein-adsorbability imparting agent for imparting absorbability of moisture or a protein to a material selected from the group consisting of food wrapping materials; filtration aid agents; sanitary articles; compositions containing a synthetic resin; moisture-controlled material; covering materials for wounds; insulation substrates; coating materials for semiconductor devices; cosmetics; inkjet recording media; and compositions containing synthetic fibers.Type: GrantFiled: February 3, 2005Date of Patent: October 11, 2011Assignees: Taiyo Kagaku Co., Ltd., Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Kouichi Kitahata, Masaaki Yanagi, Yuuki Kasama, Noriko Nomura, Kanae Teramoto, Hironobu Nanbu, Yoshiki Yamazaki, Mitsumasa Horii, Yoshiaki Fukushima
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Patent number: 8029842Abstract: An oxygen-absorbing composition, device, and method for oxygen scavenging in a low moisture environment are provided. The present invention provides an oxygen absorbing composition which includes an oxygen reducing agent, water, a carrier, an electrolyte salt, and a humectant salt, which may be the same as the electrolyte salt, present in an amount sufficient to reduce the water activity of the composition to below 0.6. Also included are methods of using the composition.Type: GrantFiled: March 19, 2007Date of Patent: October 4, 2011Assignee: Multisorb Technologies, Inc.Inventor: Thomas Powers
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Patent number: 8029662Abstract: The disclosed sorbents are for adsorbing sulfur compounds, particularly sulfur-containing aromatic compounds, from liquid hydrocarbon fuels such as gasoline, cracked gasoline, diesel, high sulfur liquid fossil fuels, ultra-low sulfur fuel (ULSF) in fuel cell applications, and mixtures thereof. The sorbent compositions comprise one or more silicates having one or more metal nitrates admixed together. The one or more metal nitrates include iron (II) or (III), zinc (II), cadmium (II) and mercury (II) nitrate. The method of preparing and using the sorbents is also provided.Type: GrantFiled: June 6, 2008Date of Patent: October 4, 2011Assignee: The United States of America as represented by the Administrator of the Environmental Protection AgencyInventors: Rajender S. Varma, Yuhong Ju, Subhas Sikdar
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Patent number: 8030242Abstract: The invention concerns a process for preparing metallic nanoparticles with an anisotropic nature by using two different reducing agents, preferably with different reducing powers, on a source of a metal selected from columns 8, 9 or 10 of the periodic table of the elements.Type: GrantFiled: November 14, 2006Date of Patent: October 4, 2011Assignee: IFP Energies NouvellesInventors: Denis Uzio, Catherine Verdon, Cecile Thomazeau, Bogdan Harbuzaru, Gilles Berhault
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Patent number: 8025160Abstract: The use of a sulfur-impregnated organoclay provides a mercury or arsenic removal media having increased reactivity, stability, and mercury removal ability. The Hg/As removal media described herein is prepared by impregnating an organophilic clay with elemental (free state) sulfur. Alternatively, the clay can be made organophilic by onium ion reaction prior to or simultaneously with impregnating the organoclay with sulfur.Type: GrantFiled: May 7, 2008Date of Patent: September 27, 2011Assignee: Amcol International CorporationInventors: Zhen Wang, Robert Abraham
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Patent number: 8022008Abstract: A method is provided for making a catalyst support, and includes the steps of providing an aqueous suspension of refractory inorganic oxide and refractory inorganic carbide; forming the suspension into droplets; exposing the droplets to a gelling agent whereby the droplets are at least partially solidified so as to provide substantially sphere-shaped portions of refractory inorganic oxide and refractory inorganic carbide; and drying and calcining the sphere-shaped portions so as to provide substantially spherical particles of catalyst support containing refractory inorganic oxide and refractory inorganic carbide. Catalytically active metal phases and hydrogenation processes using the catalyst are also described.Type: GrantFiled: November 30, 2009Date of Patent: September 20, 2011Assignee: Intevep, S.A.Inventors: Jorge M. Martinis, Maria E. Valera, Jose R. Velasquez, Angel R. Carrasquel
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Publication number: 20110212830Abstract: A dry product that permanently removes oil and oil stains from liquid or dry surfaces and is environmentally safe. The dry product is formed by mixing efficacious proportions of untreated amorphous silica with a dry, inert organic, inorganic or synthetic carrier, or combinations of said carriers. Suitable inert carriers include, but are not limited to, (a) inert inorganic carriers including, but not limited to, clays, perlite, vermiculite, crushed glass, volcanic ash and sand; (b) inert organic carriers, including, but not limited to, peat moss, straw, hay, sawdust, ground corncobs, flours, and coconut coir, and (c) inert synthetic carriers, including, but not limited to, polyurethane, polyethylene and polypropylene. The dry product can be applied directly to oil stains either on a hard surface, such as concrete or asphalt, or to oil spills on water.Type: ApplicationFiled: April 5, 2011Publication date: September 1, 2011Applicant: Rousseau Research, Inc.Inventor: Joseph D. Russo
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Patent number: 8007762Abstract: The invention relates to Group 1 metal/silica gel compositions comprising silica gel and an alkali metal or alloy, wherein Group 1 metals or alloys are absorbed into the silica gel pores. The invention relates to producing hydrogen gas comprising contacting a Group 1 metal/silica gel composition with water, and further relates to an alkali metal reduction of an organic compound, the improvement comprising contacting the organic compound with a Group 1 metal/silica gel composition. In these embodiments, the Group 1 metal/silica gel composition reacts with dry O2. The invention also relates to producing hydrogen gas comprising contacting a Group 1 metal/silica gel composition with water, and further relates to an alkali metal reduction of an organic compound, the improvement comprising contacting the organic compound with a Group 1 metal/silica gel composition. In these embodiments, the Group 1 metal/silica gel composition produced does not react with dry O2.Type: GrantFiled: March 12, 2010Date of Patent: August 30, 2011Assignees: SiGNa Chemistry, Inc., Board of Trustees of Michigan State UniversityInventors: Michael Lefenfeld, James L. Dye
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Publication number: 20110197763Abstract: The invention concerns materials for eliminating oxides of nitrogen NO and NO2 present in exhaust gases, in particular from the internal combustion engines of automotive vehicles operating in a medium which is super-stoichiometric in oxidising agents, which can adsorb oxides of nitrogen then desorb the oxides of nitrogen by elevating the temperature with respect to the adsorption temperature or by passage of a rich mixture, said materials comprising mixed oxides the metals of which are in octahedral coordination, with the octahedra connecting together so that the structure generates lamellae. Said materials adsorb oxides of nitrogen by insertion and do not become poisoned in contact with oxides of sulphur and carbon contained in the gases. In the presence of a group VIII metal, said materials are capable of eliminating oxides of nitrogen adsorbed by reduction during the passage of a rich mixture.Type: ApplicationFiled: July 24, 2002Publication date: August 18, 2011Inventors: Thierry Becue, Philippe Villeret
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Publication number: 20110183835Abstract: The invention relates to an adsorber element and to a method for the production thereof, comprising a carrier material (1) on which adsorbent particles (3) are arranged as the adsorber layer using a binding agent (2). According to the invention, the adsorber layer comprises inorganic fibers (4) and the binding agent (2) is designed as a colloid.Type: ApplicationFiled: October 2, 2009Publication date: July 28, 2011Applicant: Viessmann Werke GmbH & Co.KGInventors: Juergen Sauer, Belal Dawoud, Stefanie Chmielewski, Hendrik Van Heyden, Heike Klaschinsky
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Patent number: 7981834Abstract: An object of the present invention is to improve hydrocarbon adsorbing property when zeolite is used as an adsorbent for hydrocarbons. The present invention provides an adsorbent for hydrocarbons characterized by comprising A Type of ?-zeolite having a SiO2/Al2O3 ratio (molar ratio) in a range of 10 or more and less than 200 and B Type of ?-zeolite having a SiO2/Al2O3 ratio (molar ratio) in a range from 200 to 1,000, and a catalyst for exhaust gas purification containing said adsorbent for hydrocarbons.Type: GrantFiled: March 13, 2007Date of Patent: July 19, 2011Assignees: ICT Co., Ltd., International Catalyst Technology, Inc.Inventors: Hideki Goto, Akihisa Okumura
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Patent number: 7981836Abstract: The hydrothermal stability of transition aluminas used as adsorbents and catalyst carriers is improved through their treatment with a soluble silicon inorganic compound such as sodium silicate wherein the silicon compound is mixed with the alumina powder at the production stage of forming particulates by liquid addition. The silicon containing particulates are activated by heating at a temperature lower than 500° C. and treated, before or after the thermal activation, by a colloidal silica solution to produce a hydrothermally stable, low dust alumina. The total silica content of the final product is typically less than 5 mass-%.Type: GrantFiled: May 24, 2006Date of Patent: July 19, 2011Assignee: UOP LLCInventors: Vladislav I. Kanazirev, Peter Rumfola, III
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Patent number: 7977277Abstract: Getter systems are provided having a phase active in the sorption of gas, inserted in the pores of a porous material. The porous material is, in turn, dispersed in a polymeric means having a low permeability to the gas to be sorbed.Type: GrantFiled: July 18, 2006Date of Patent: July 12, 2011Assignee: Saes Getters S.p.A.Inventors: Roberto Giannantonio, Giorgio Longoni, Chiara Vescovi, Lorena Cattaneo
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Patent number: 7972667Abstract: The present invention relates to a packing structure for containers, characterized in that it comprises a material of xonotlite and/or tobermorite and/or foshagite crystal structure crystallized in the form of needles, at least 50% by volume of which have a length ranging from 2 to 10 ?m and a thickness ranging from 0.2 to 1 ?m. Process for manufacturing such a packing structure and gas container containing it.Type: GrantFiled: July 25, 2007Date of Patent: July 5, 2011Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes G eorges ClaudeInventors: Emmanuel Baune, Pascal Del-Gallo, Thierry Chartier, Gilles Cannet
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Publication number: 20110160042Abstract: The present invention provides a method for constructing a fractal network structure in hydrogen storage material to improve the hydrogen uptake at room temperature, the method including the following steps: providing a hydrogen storage material comprising a source and a receptor of hydrogen atoms, wherein the source is disposed above the receptor, and a chemical bridge is disposed between the source and the receptor, wherein the chemical bridge is composed of precursor material; and treating the hydrogen storage material to construct a fractal network structure of mesopores and micropores in the receptor, so as to enhance the hydrogen storage capacity of the hydrogen storage material at room temperature.Type: ApplicationFiled: October 15, 2010Publication date: June 30, 2011Applicant: Institute of Nuclear Energy Research Atomic Energy Council, Executive YuanInventors: CHENG-SI TSAO, Ming-Sheng Yu, Yi-Ren Tzeng, Tsui-Yun Chung, Hsiu-Chu Wu, Haw-Yeu Chuang, Chien-Hung Chen, Kang-Ning Lee, Hua-Wen Chang, Huan-Hsiung Tseng
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Publication number: 20110152065Abstract: A method for producing an oil binding agent, using highly porous natural siliceous material and organic-containing remaining material, wherein the highly porous natural siliceous material having an initial grain size of between 4 and 10 mm is mixed with the organic-containing remaining material and the mixture is calcined at a temperature between 520 and 550° C. and then comminuted to a grain size spectrum substantially ranging between 4 and 0.Type: ApplicationFiled: March 9, 2009Publication date: June 23, 2011Inventor: Franz-Josef Philipp
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Publication number: 20110142752Abstract: In one embodiment, a hydrogen storage system includes a core of hydrogen sorbent material and a shell of crystalline metal hydride material enclosing at least a portion of the core of hydrogen sorbent material. In another embodiment, the hydrogen storage system further includes an intermediate layer of amorphous metal hydride material, at least a portion of which being positioned between the core of hydrogen sorbent material and the shell of crystalline metal hydride material.Type: ApplicationFiled: December 30, 2010Publication date: June 16, 2011Applicant: FORD GLOBAL TECHNOLOGIES, LLCInventors: Jun Yang, Andrea Pulskamp, Shinichi Hirano
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Patent number: 7960307Abstract: A sulfur reduction catalyst useful to reduce the levels of sulfur in a cracked gasoline product comprises a metal vanadate compound. The metal vanadate compound can be supported on a molecular sieve such as a zeolite in which the metal vanadate compound is primarily located on the exterior surface of the pore structure of the zeolite and on the surface of any matrix material used to bind or support the zeolite.Type: GrantFiled: March 6, 2007Date of Patent: June 14, 2011Assignee: BASF CorporationInventors: Xingtao Gao, James Fu
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Patent number: 7955577Abstract: Sorbent components containing calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents are added to the coal ahead of combustion and/or are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.Type: GrantFiled: June 10, 2010Date of Patent: June 7, 2011Assignee: NOx II, LtdInventor: Douglas C. Comrie
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Publication number: 20110130274Abstract: A method for preparing radioactive-substance adsorbent depositing on a carriable structure is revealed. The method uses a supercritical fluid to mix a first solution with a carrier. The first solution includes an extractant dissolved in a first solvent. By low surface tension and high permeability of the supercritical fluid, the extractant in the first solution deposit evenly on the carrier so as to form an adsorbent. Thus the adsorbent formed provides better adsorptivity for the radioactive substances.Type: ApplicationFiled: December 1, 2009Publication date: June 2, 2011Inventors: Shih-Han Wang, Ming-Tsai Liang, Chih-Ching Chang, Chi-Hung Liao, Chao-Yuh Chen, Yih Ping Chen
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Publication number: 20110111955Abstract: The hydrothermal stability of transition aluminas used as adsorbents and catalyst carriers is improved through their treatment with a soluble silicon inorganic compound such as sodium silicate wherein the silicon compound is mixed with the alumina powder at the production stage of forming particulates by liquid addition. The silicon containing particulates are activated by heating at a temperature lower than 500° C. and treated, before or after the thermal activation, by a colloidal silica solution to produce a hydrothermally stable, low dust alumina. The total silica content of the final product is typically less than 5 mass-%.Type: ApplicationFiled: January 17, 2011Publication date: May 12, 2011Applicant: UOP LLCInventors: Vladislav I. Kanazirev, Peter Rumfola, III
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Patent number: 7932209Abstract: Disclosed are a liquid heating element and a method for production thereof, and more particularly a solid ingredient A, a liquid ingredient B produced from the solid ingredient A, a liquid heating element produced from the liquid ingredient B and a method for producing the liquid heating element. The solid ingredient is produced by heating activated carbon, kaolin, copper sulfide and phosphoric acid (H3PO4) to a temperature ranging from 1,000 to 1,200° C. The liquid ingredient H is produced by mixing the solid ingredient A with silicon powder and distilled water and heating the mixture. The liquid heating element is produced by mixing the liquid ingredient B with ethylene glycol, leaving the mixture and then filtering the mixture. Since the liquid heating element is very stable and generates heat with minimum power consumption, it can be applied to various heat management systems.Type: GrantFiled: November 7, 2003Date of Patent: April 26, 2011Inventor: Dong-Soon Kwon
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Patent number: 7915475Abstract: A novel method for remediating metals includes treating the metals with a mesoporous nanocomposite such as HMS, MCM-41 or MCM-48. The metal is preferably lead but can be at least one metal selected from Pb, Hg, Cd, Zn, Sn, As, Sb, In, Se, Ga, Te, Bi, Ni, Cu, Mo, Ni, Cu, Sr, Ba or Co. The treating is preferably performed at a pH of about 4 to about 12. In the invention, the treating can also include desorbing the metal from the mesoporous nanocomposite at a pH of about 2 or less.Type: GrantFiled: July 2, 2004Date of Patent: March 29, 2011Assignee: Christopher Newport UniversityInventors: Tarek Abdel-Fattah, Larry K. Isaacs
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Patent number: 7915196Abstract: A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.Type: GrantFiled: October 7, 2005Date of Patent: March 29, 2011Assignee: Alliance for Sustainable Energy, LLCInventors: Yves O. Parent, Kim Magrini, Steven M. Landin, Marcus A. Ritland
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Patent number: 7910518Abstract: A geometrically shaped solid carrier is provided that improves the performance and effectiveness of an olefin epoxidation catalyst for epoxidizing an olefin to an olefin oxide. In particular, improved performance and effectiveness of an olefin epoxidation catalyst is achieved by utilizing a geometrically shaped refractory solid carrier in which at least one wall thickness of said carrier is less than 2.5 mm.Type: GrantFiled: March 10, 2008Date of Patent: March 22, 2011Assignee: SD Lizenzverwertungsgesellschaft mbH & Co. KGInventors: Serguei Pak, Andrzej Rokicki, Howard Sachs
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Patent number: 7910514Abstract: An inorganic fiber catalyst includes an alumina-silica fiber base material, and a plurality of catalyst component particles contained in the alumina-silica fiber base material. A mean particle diameter of the catalyst component particles contained in at least a surface portion of the alumina-silica fiber base material is 50 nm or less, and a standard deviation of particle diameters of the catalyst component particles is 30 or less.Type: GrantFiled: July 10, 2008Date of Patent: March 22, 2011Assignees: Nissan Motor Co., Ltd., Nitivy Co., Ltd.Inventors: Hideaki Morisaka, Masahiro Takaya, Yasunari Hanaki, Kouji Masuda, Michiaki Sagesaka, Naoki Harakawa
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Publication number: 20110053766Abstract: The present invention is a method and material for using a sorbent material to capture and stabilize mercury. The method for using sorbent material to capture and stabilize mercury contains the following steps. First, the sorbent material is provided. The sorbent material, in one embodiment, is nano-particles. In a preferred embodiment, the nano-particles are unstabilized nano-Se. Next, the sorbent material is exposed to mercury in an environment. As a result, the sorbent material captures and stabilizes mercury from the environment. In the preferred embodiment, the environment is an indoor space in which a fluorescent has broken.Type: ApplicationFiled: August 27, 2010Publication date: March 3, 2011Applicant: BROWN UNIVERSITYInventors: ROBERT H. HURT, STEVEN P. HAMBURG, LOVE SARIN, INDREK KULAOTS
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Patent number: 7897538Abstract: The present invention is an adsorbent for removing sulfur from hydrocarbon streams. The adsorbent includes nickel particles distributed in a phase containing silica and alumina.Type: GrantFiled: May 21, 2004Date of Patent: March 1, 2011Assignee: ExxonMobil Research and Engineering CompanyInventors: Miron Landau, Mordechay Herskowitz, Iehudit Reizner, Zhiguo Hou, James E. Kegerreis
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Publication number: 20110031179Abstract: Disclosed are porous-shell particles, methods of making the particles, and uses thereof. In one aspect, the porous-shell particles are superficially porous particles.Type: ApplicationFiled: October 15, 2010Publication date: February 10, 2011Inventors: Wu Chen, Ta-Chen Wei
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Publication number: 20110024680Abstract: Metal sorbent compositions for removing a metal contaminant from a fluid, such as removal of mercury from a coal-fired flue gas stream, and methods for making and using the same are provided. The subject metal sorbent compositions comprise an effective amount of an aqueous dispersion of microfine elemental sulfur particles on an adsorbent substrate, and optionally, a metal capture enhancing agent such as a halogen source and/or an oxidizing agent in an amount providing a metal capture enhancing effect on the metal sorbent composition. The subject metal sorbent compositions are prepared by drying an aqueous dispersion of microfine elemental sulfur particles on an adsorbent substrate, such as on a substrate of microfine particles of a refractory material and the like. Also provided are kits for use in preparing the subject compositions, and compositions produced by the methods. The subject compositions, kits and systems find use in a variety of different applications.Type: ApplicationFiled: January 25, 2010Publication date: February 3, 2011Applicant: Zeox Corporation, Inc.Inventors: Francis A. Via, William Ahrens, Daniel T. Eyde
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Patent number: 7875738Abstract: This invention relates to an amorphous non-glassy ceramic composition that may be prepared by curing, calcining and/or pyrolyzing a precursor material comprising silicon, a Group III metal, a Group IVA metal, and/or a Group IVB metal.Type: GrantFiled: September 29, 2008Date of Patent: January 25, 2011Assignee: Sigma-Aldrich Co.Inventors: William R. Betz, Christopher M. Linton
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Publication number: 20110015064Abstract: An agglomerate for use in economical bulk treatment of contaminated sediments with minimal environmental impact is formed from a sorbent, bentonite clay and sand. The agglomerate has sufficient density so as to sink through a water column into sediment below the water column and is still sufficiently light as to be capable of mixing with the sediment when subjected only to bioturbation. The agglomerate can be formed into pellets and applied to a water column over contaminated sediment by broadcast methods, so as to permit economical remediation of contaminated sediment with negligible environmental impact.Type: ApplicationFiled: September 22, 2010Publication date: January 20, 2011Inventors: Upal Ghosh, Charles A. Menzie, Craig B. Amos
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Publication number: 20110000855Abstract: Sorption media for removal of contaminants from fluid streams are provided. The sorption media comprise an active compound bound or linked to a support substrate or matrix. Support substrates can include iron- and alumina-based materials. A method for making sorption media for the removal of contaminants from fluid streams is also described. The method includes selecting a support substrate, and, optionally, providing a doping mixture comprising an active compound. The selected support substrate can be contacted with the doping mixture to form a doped mixture. The doped mixture can be reacted at a predetermined temperature and atmospheric environment for a predetermined duration to form an active media, wherein the active compound is bound or linked to the support substrate.Type: ApplicationFiled: July 6, 2010Publication date: January 6, 2011Inventors: Anthony E. Kuhel, Harry A. Adams, Gina Sacco
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Publication number: 20110000370Abstract: A micro-porous material having agglomerates of precipitated silica, according to the formula MeOx.HiSiO2, The agglomerates are composed of porous particles, and the agglomerates exhibit a size in the range 0.5-500 ?m. A gas filter having the micro-porous material, and a method of filtering air through the micro-porous material.Type: ApplicationFiled: April 23, 2010Publication date: January 6, 2011Applicant: SVENSKA AEROGEL ABInventors: Sven-Peter NORBERG, Jörgen Abrahamsson, Lars Gösta Lindahl
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Patent number: 7863216Abstract: The invention provides a discharge gas treatment catalyst which can effectively decreases NOx and SO3 contained in a discharge gas. The discharge gas treatment catalyst, for removing nitrogen oxide and sulfur trioxide from a discharge gas, includes a carrier which is formed of titania-tungsten oxide and which carries ruthenium, and a titania-tungsten oxide-based NOx removal catalyst serving as a substrate which is coated with the carrier. When a discharge gas to which ammonia has been added and which contains SO3 and NOx is brought into contact with the catalyst, decomposition of ammonia is suppressed by ruthenium, and reduction of SO3 and NOx contained in the discharge gas is promoted, whereby SO3 concentration and NOx concentration can be further decreased.Type: GrantFiled: September 22, 2005Date of Patent: January 4, 2011Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Yoshiaki Obayashi, Toshiyuki Onishi, Kozo Iida
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Publication number: 20100331177Abstract: The present invention provides amorphous silica particles having high oil absorbency and high structural characteristics, wherein the oil absorbency is hardly decreased even when a high load is applied to the amorphous silica particles. In particular, amorphous silica particles are provided, wherein the maximum value of ?Vp/?Rp (where Vp is the pore volume [mm3g] and Rp is the pore radius [nm]) is 20 mm3/nm·g?1 or more in the pore distribution curve obtained by a benzene adsorption isotherm, and the pore peak radius when the ?Vp/?Rp value is maximum is from 20 nm or more to 100 nm or less.Type: ApplicationFiled: March 22, 2010Publication date: December 30, 2010Applicant: DSL JAPAN CO. LTD.Inventors: Shugo NISHI, Tatsuya Tokunaga, Hisayo Oyama
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Patent number: 7858554Abstract: A porous cordierite substrate and a method of forming a porous cordierite substrate including providing a fiber that includes at least one cordierite precursor material and providing at least one organic binder material. The fiber and the organic binder material are mixed with a fluid. The mix of fiber, organic binder material and fluid is extruded into a green substrate. The green substrate is fired to enable the formation of bonds between the fibers and to form a porous cordierite fiber substrate.Type: GrantFiled: May 24, 2007Date of Patent: December 28, 2010Assignee: Geo2 Technologies, Inc.Inventors: James Jenq Liu, Bilal Zuberi, Jerry G. Weinstein, Rachel A. Dahl, William M. Carty
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Publication number: 20100320153Abstract: An absorbent composition suitable for removing mercury, arsenic or antimony from fluid streams includes 5-50% by weight of a particulate sulphided copper compound, 30-90% by weight of a particulate support material, and the remainder one or more binders, wherein the metal sulphide content of the absorbent, other than copper sulphide, is below 5% by weight.Type: ApplicationFiled: January 29, 2009Publication date: December 23, 2010Applicant: JOHNSON MATTHEY PLCInventors: Matthew John Cousins, Robert Logan, Christopher John Young
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Patent number: 7855162Abstract: The present invention provides a needle-shaped ceramic body and needle-shaped ceramic catalyst body in which a base material is a high specific surface area porous cordierite body that is stable at high temperatures, and also provides methods of producing this needle-shaped ceramic body and needle-shaped ceramic catalyst body. The present invention relates to a needle-shaped ceramic body and needle-shaped ceramic catalyst body in which a base material is a high temperature-stable, high specific surface area porous cordierite body comprising a porous structure having a prescribed porosity and formed of a needle-shaped cordierite crystal phase, and further relates to methods of producing this needle-shaped ceramic body and needle-shaped ceramic catalyst body, and by using porous cordierite constituted of needle-shaped crystals as a catalyst-supporting honeycomb structure, the present invention is able to inhibit sintering-induced reduction in the specific surface area.Type: GrantFiled: December 13, 2004Date of Patent: December 21, 2010Assignees: National Institute of Advanced Industrial Science and Technology, Denso Corporation, Nippon Soken, Inc.Inventors: Jayaseelan Daniel Doni, Hideki Kita, Naoki Kondo, Shunkichi Ueno, Tatsuki Ohji, Shuzo Kanzaki, Kazuhiko Koike, Takumi Suzawa, Tomohiko Nakanishi
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Publication number: 20100313468Abstract: A process, adsorbent and apparatus for treating biofuel is disclosed.Type: ApplicationFiled: December 18, 2008Publication date: December 16, 2010Inventors: Massoud Jalalpoor, Vasilios Zafirakis
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Publication number: 20100314321Abstract: A spill control material has a combination of a pre-defined blended granule size mixture of amorphous alumina silicate in an aggregate blend of a plurality of predefined sieve grades where the combination has enhanced encapsulation properties greater than a single granule formulation. The pre-defined blended granule size mixture of amorphous alumina silicate has granules ranging in sizes larger than five microns and less than sixty-six microns in an aggregate blend of sieve grades #3 and #0.Type: ApplicationFiled: June 14, 2010Publication date: December 16, 2010Inventor: Lewis Scott Niles
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Patent number: 7850012Abstract: The present invention provides methods for separating one or more components of interest from a sample containing particulates and soluble materials. The method comprises the steps of: (a) filtering a sample through silica filter media whose surface silanol groups have reacted with one or more silanes, and (b) simultaneously capturing particulates and binding a soluble component to the silica filter media. The bound soluble component of interest is subsequently eluted from the silica filter media. In one embodiment of the invention, unwanted soluble materials are captured by the treated silica filter media and desired component of interest is recovered from the flow-through. In another embodiment, different components of interest are recovered from both the eluate and the flow-through. Preferred treated silica filter media are silane-treated rice hull ash or diatomaceous earth with functional quarternary ammonium group or functional sulphonate group.Type: GrantFiled: April 11, 2008Date of Patent: December 14, 2010Assignees: Dow Corning Corporation, Danisco US Inc.Inventors: Gary L. Gibson, Keith Hayes, Meng H. Heng, Csilla Kollar, Thomas H. Lane, Anthony Revis, Landon M. Steele
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Patent number: 7846333Abstract: A porous media, a housing containing a porous media and methods for fabricating the housing containing a porous media are provided. The porous media is composed of varying amounts of sorptive binding particles in combination with polymer particles, for example silica particles mixed with polyethylene beads. The porous media is sintered into target housings, for example pipette tips, for use in desalting, purifying and separating biomolecules in target samples. The porous media is also formed into porous media discs via pressure and heating for insertion into housing devices.Type: GrantFiled: November 18, 2004Date of Patent: December 7, 2010Inventors: Wilhelm Pluester, Christian Ziegmann
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Patent number: 7846867Abstract: A method for the production of a composition comprising a metal containing compound, a silica containing material, a promoter, and alumina is disclosed. The composition can then be utilized in a process for the removal of sulfur from a hydrocarbon stream.Type: GrantFiled: August 30, 2007Date of Patent: December 7, 2010Assignee: China Petroleum & Chemical CorporationInventors: Uday T. Turaga, Tushar V. Choudhary, Glenn W. Dodwell, Marvin M. Johnson, Deborah K. Just